IIT/NEET – ACADEMY

XII - IIT MAINS

REVISION PART TEST - 8
Date : 03.12.2023 (NEW PATTERN) Time : 3hrs
Std : XII-IIT CODE- B Max. Marks : 300

INSTRUCTIONS TO THE CANDIDATES

It is mandatory to use BALL POINT PEN to dark appropriate circle in the answer
sheet.
Marks should be dark and should completely fill the circle.
New Model of JEE MAIN comprises of three parts. Part-A, B & C. And Each part
contains two sections. Section I & II.
Carefully read the instructions given at the beginning of each section.

Section : 1 – Contains 20 multiple choice questions. Each question has four

choices (A), (B), (C) and (D) out of which ONLYONE of these option
is correct option.
Section : 2 – Contains 5 questions. The answer to each is a NUMERICAL
VALUE. For each questions write the correct numerical value (in
decimal notation, truncated/rounded-off to the second decimal place;
eg. 6.25, 7.00. –0.33, 30.27, –127.30) in boxes given on OMR Sheet.

Marking Scheme :
For each question in Section-1, you will be awarded 4 marks if you darken the
bubble corresponding to only the correct answer and zero mark if no bubbles
are darkened. In all other cases (–1) minus one will be awarded.
For each question in Section-2 will be evaluated according to the following
scheme.
Full Marks : +4 If ONLY the correct numerical value is write as answer.
Zero Marks : 0 in all other cases.

******** WISH YOU ALL THE BEST ********

SUBJECT SYLLABUS PAPER SETTER

MATRICES, DETERMINANTS, ADDITION OF VECTORS, DOT Mr.NAGABUSHANAM
PRODUCT, CROSS PRODUCT, CROSS PRODUCT, TRIPLE
MATHEMATICS
PRODUCTS, 3D-COORDINATE SYSTEM, DR'S , DC'S, 3D LINES
AND PLANES
PHYSICS RAY OPTICS, WAVE OPTICS, NUCLEI Mr.KISHORE REDDY

PREPARATION OF MOHR'S SALT AND ALUM, QUALITATIVE Mr.RABINARAYANA

ANALYSIS OF ANIONS, AMINES, DETECTION OF AMINO
CHEMISTRY
GROUP, PREPARATION OF ACETANILIDE, PARA NITRO
ACETANILIDE, ANILINE, COORDINATION CHEMISTRY
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MATHEMATICS
I. Single Answer Type Questions:
1. Let ABC be a triangle such that BC  a, CA  b , AB  c, a  6 2, b  2 3 and b.c  12 .
Consider the statements:

(S1): a  b  c  b  c  6 2 2  1 
 2
 S2  : ACB  cos1   . Then ______
 3 
A) Both (S1) and (S2) are true B) Only (S1) is true
C) Only (S2) is true D) Both (S1) and (S2) are false
2. ABC is a triangle in a plane with vertices A(2, 3, 5), B(-1, 3, 2) and C   ,5,   . If the
median through A is equally inclined to the coordinate axes, then the value of
 
 2   2  1 is _____
A) 125 B) 150 C) 50 D) 100
3. If the lines x  ay  b, z  cy  d and x  a z  b , y  c z  d are perpendicular, then _____
1 1 1 1

A) ab1  bc1  1  0 B) cc1  a  a1  0 C) bb1  cc1  1  0 D) aa1  c  c1  0

4. The acute angle between the lines, whose d.c’s are given by l  m  n  0 and
2lm  mn  2nl  0 is _____
   
A) B) C) D)
2 6 4 3
x  1 y 1 z  1
5. The foot of perpendicular of the point (2, 0, 5) on the line   is  ,  ,  
2 5 1
. Then, which of the following is NOT correct?
   5  4
A)  8 B)  5 C)  D) 
   8  15
x  2 y 1 z
6. The vertices B and C of ABC lie on the line   such that BC=5 units.
3 0 4
Then the area (in sq.units) of this triangle, given that the point A(1, -1, 2) is _____
A) 34 B) 2 34 C) 5 17 D) 2 17
The equation of the common tangent touching the circle  x  3  y 2  9 and the
2
7.
parabola y 2  4 x above the x-axis is _____
A) 3y  x  3 B) 3 y  3x  1 C) 3 y    x  3 D) 3 y    3 x  1
If the length of the tangent from any point on the circle  x  3   y  2   5r 2 to the
2 2
8.
 x  3   y  2 
2 2
circle  r 2 is 16 units, then the difference of areas of the two circles
in sq.units is _____
A) 32 B) 4 C) 258 D) 256
9. The equation of the angle bisector of the acute angle between the lines 3x  7  4 y
and 12 x  5 y  2 is given by ______
A) 21x  77 y  101  0 B) 11x  3 y  9  0
C) 11x  3 y  9  0 D) 21x  77 y  101  0
x  2 y 1 z 1
10. If the line   intersects the curve xy  c2 , z  0, then c= _____
3 2 1
A) 1 B)  3 C)  5 D)  7
11. P is an orthogonal matrix and A is a periodic matrix with period “4” and Q = PAPT,
then X  PT Q2023 P will be ______
A) A B) A2 C) A3 D) A4
12. Let M be a 3 3 non-singular matrix with det( M )   . If M-1(adj(adjM))=KI, where I is
the 3 3 unit matrix, then K equals ______
A) 1 B)  C)  2 D)  3

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 r r  1
13. If Ar    , where r is a natural number, then | A1 |  | A2 |  | A3 | .... | A2024 | must
r  1 r 
be equal to ______
D)  2024 
3
A) 2024 B) (2024)2 C) 2024
1 2
14. If A    , then 8A4  _______
3 4
A) 145 A1  27 I ` B) 145 A1  27 I C) 27 I  145 A1 D) 29 A1  9 I
15. Let  ,  be the roots of the equation ax 2  bx  c  0 . Let S n   n   n for n  1. Then the
3 1  S1 1  S 2
value of 1  S1 1  S 2 1  S3 is equal to _______
1  S 2 1  S3 1  S 4

A)
a  b  c
2
b 2
 4ac 
B)
a  b  c
2
b 2
 4ac 
2 2
a a

C)
a  b  c
2
b 2
 4ac 
D)
a  b  c
2
b 2
 4ac 
a4 a4
16. If the system of linear equations 2 x  y  z  7, x  3 y  2 z  1, x  4 y   z  k , where  , k  R
has infinitely many solutions, then   k is equal to _____
A) -3 B) 3 C) 6 D) -6
17. If the four points whose position vectors are 3iˆ  4 ˆj  2kˆ, iˆ  2 ˆj  kˆ,  2iˆ  ˆj  3kˆ and
5iˆ  2 ˆj  4kˆ are coplanar, then  equal to _____
107 107 73 73
A) B) C) D)
17 17 17 17
18. If S is the circumcenter, O is the orthocenter of ABC , then OA  OB  OC  _____
A) SO B) 2SO C) OS D) 2OS
 
ˆ
19. Let   3iˆ  ˆj and   2iˆ  ˆj  3k . If   1   2 . Where 1 is parallel to  and  2 is
perpendicular to  , then 1   2 is equal to ____

A) 3iˆ  9 ˆj  5kˆ B)
1
2
 
3iˆ  9 ˆj  5kˆ C) 3iˆ  9 ˆj  5kˆ D)
1 ˆ
2
3i  9 ˆj  5kˆ 
20. Let a  2iˆ  7kˆ  5kˆ, b  iˆ  kˆ and c  iˆ  2 ˆj  3kˆ be three given vectors. If r is a vector such
that r  a  c  a and r .b  0 then | r | is equal to ____
11 2 11 2 11 914
A) B) C) D)
7 5 5 7
II. Numerical Answer Questions:
21. If the perpendicular bisector of the line segment joining the points P(1, 4) and Q(K, 3)
has Y-intercept equal to “-4” then the value of |k| equals to ______
 4 2 
22. Let A    . If A   A  18I  0, then det  A is equal to _____
2

  
23. Let A is a square matrix of order 3, such that |A| = a and B = adjA such that |B| =b.
S a a2 a3
If a = 3 and 
  3  5  ......, then the value of ab2  a 2b  1 S equals to _____
2 b b b

x  2 y z 5 x  4 y 1 z  3
24. The shortest distance between the lines   and   is
1 2 2 1 2 0
25. Let a  iˆ  ˆj  2kˆ, b  b1iˆ  b2 ˆj  2kˆ and c  5iˆ  ˆj  2kˆ be three vectors such that the
projection vector of b on a is a . If a  b is perpendicular to c , then | b | is equal to ____

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PHYSICS
I. Single Answer Type Questions:
26. In young’s double slit experiment, the angular width of a fringe formed on a distant
screen is 10. The wavelength of the light used is 6000A0. What is the spacing between
the slits?
A) 344 mm B) 0.1344 mm C) 0.0344mm D) None of these
27. Light of wavelength   5890A0 falls on a double slit arrangement having separation
d = 0.2mm. A thin lens of focal length f = 1m is placed near the slit. The linear
separation of fringes on a screen placed in the focal plane of the lens is
A) 3mm B) 4mm C) 2mm D) 1mm
28. The most abundant isotope of helium has a 42 He nucleus whose mass is 6.6447 1027 kg .
For this nucleus the binding energy is m p  1.6726 1027 kg , mn  1.6749 1027 kg 
(Given me  5.485799 104 u, m p  1.007276u, mn  1.008665u )
A) 2.64 1012 J B) 3.76 1012 J C) 4.53 1012 J D) 6.24 1012 J
29. The number of neutrons present in 12g of 12
6 C is (Avagadro number = 6 1023 )
A) 36 1023 B) 72 1023 C) 36 1013 D) 72 1013
30. The ratio of radii of nuclei 13 AC 27 and 52 X
A
is 3 : 5. The number of neutrons in the nuclei
of X will be
A) 52 B) 73 C) 125 D) 13
31. The binding energy per nucleon of deuteron  1 H 2
 and helium atom  2 He 4  are 1.1MeV
and 7MeV. If the deuteron atoms react to form a single helium atom, then the energy
released is
A) 13.9 MeV B) 26.9 MeV C) 23.6 MeV D) 19.2 MeV
32. A metal rod A of 25cm length expands by 0.05cm when its temperature is raised from
00C to 1000C. Another rod B of a different metal of length 40cm expands by 0.04 cm for
the same rise in temperature. A third rod C of 50cm length made up of pieces of rods A
and B placed end to end expands by 0.03cm on heating from 00C to 500C. The length of
each portion of the composite rod C is
A) l A  10cm, lB  40cm B) l A  20cm, lB  50cm
C) l A  25cm, lB  25cm D) l A  40cm, l B  10cm
33. The operating temperature of an incandescent bulb (with tungsten filament) of power
60W is 3000K. If the surface area of the filament be 25mm2, find the emissivity e.
A) 0.32 B) 0.42 C) 0.52 D) 0.62
34. Certain amount of an ideal gas is contained in a closed vessel. The vessel is moving with
a constant velocity v . The molecular mass of the gas is M. The rise in temperature of
 C 
the gas when the vessel is suddenly stopped is    P 
 CV 
Mv 2 Mv 2    1 Mv 2 Mv 2
A) B) C) D)
2 R    1 2R 2 R    1 R    1
35. Heat energy absorbed by the system in going through a cyclic process shown in the
figure is

A) 107  J B) 104  J C) 102  J D) 103  J

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36. A mirror of radius of curvature 20cm and an object which is placed at a distance of
15cm are both moving with velocities 1m/s and 10m/s as shown in the figure. The
velocity of the image at this situation is

A) 15cm/s B) 30cm/s C) 45cm/s D) 60cm/s

37. A glass rod having square cross section is bent in the shape as shown in the figure.
The radius of the inner semi-circle is R and width of the rod is d. Find the maximum
d
value of so that the light that enters at A will emerge at B. (  glass  1.5 )
R

A) 0.5 B) 1.5 C) 4.5 D) 7.5

38. An object is placed at a distance of 15cm from a convex lens of focal length 10cm on
the other side of the lens, a convex mirror is placed at its focus such that the image
formed by combination coincides with the object itself. The focal length of convex
mirror is

A) 2 cm B) 5 cm C) 7cm D) 10 cm
39. A lens has a power of +5 diopters in air. Its power if completely immersed in water is
 4 3
 a  w  and a  g  
 3 2
A) +0.75 dioptre B) +1.25 dioptre C) -0.75 dioptre D) -2 dioptre
40. There is a small air bubble inside a glass sphere    1.5  of radius 10cm. The bubble
is 4.0cm below the surface and is viewed normally from the outside. The apparent
depth of the bubble is
A) 3cm below the surface B) 6cm below the surface
C) 3cm below the centre D) 6cm below the centre
41. In an astronomical telescope in normal adjustment, a straight black line of length L
is drawn on the objective lens. The eye piece forms a real image of this line. The length
of the image is l. The magnification of the telescope is
L L L Ll
A) B)  1 C)  1 D)
l l l Ll

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42. In young’s double slit experiment, the intensity on the screen at a point where the
path difference is  is K. What will be the intensity at the point where the path

difference is ?
4
K K
A) B) C) K D) Zero
4 2
43. In a double slit experiment, fringes are produced using a light of wavelength 4800A0.
One slit is covered by a thin plate of glass of refractive index 1.4 and the other with
another glass plate of same thickness but of refractive index 1.7. By doing so, the
central bright shifts to original fifth bright fringe from centre. Thickness of the glass
plate is
A) 8 m B) 6 m C) 4 m D) 10 m
44. Unpolarised light of intensity 32 W / m2 passes through three polarizers such that
transmission axes of the first and second polarizers make an angle 300 with each
other and the transmission axis of the last polarizer is crossed with the first. The
intensity of finally emerging light will be
A) 32 Wm-2 B) 3 Wm-2 C) 8Wm-2 D) 4Wm-2
45. Two point sources separated by 2m are radiating in phase with   0.5m . A detector
moves in a circular path around the two sources in a plane containing them. How
many maxima are detected?

A) 16 B) 20 C) 24 D) 32
II. Numerical Answer Questions:
46. If the energy released in the fission of one nucleus is 200MeV. Then the number of
nuclei required per second in a power plant of 16kW will be x1014 where x =
 
47. A plane wave front   6 107 m fall on a slit 0.4mm wide. A convex lens of focal length
0.8m placed behind the slits focusses the light on the screen. The linear diameter of
the second maximum _____mm.
48. Magnification of a compound microscope is 30. Focal length of eye piece is 5cm and
image is formed at a distance of distinct vision of 25cm. The magnification of the
objective lens is _____
49. In the arrangement shown in figure a point object O, is placed as shown. If the final
image is formed at object position, the focal length of the concave lens is _______ cm
50. The rms speed of a particle of mass 5 1017 kg in their random motion in air at S.T.P.
(Boltzman’s constant K  1.38 1023 J / K ) is n 103 m / s where n = (Nearest integer)

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CHEMISTRY
I. Single Answer Type Questions:
51. C6 H 6  3Cl2 
hv
 product. Which of the following is incorrect statement about the
product?
A) It is aromatic B) It is non-aromatic
C) It’s name is Benzenehexachloride D) It has 8 geometrical isomers.
52. Which reaction sequence would be best to prepare 3-chloro aniline from benzene?
A) Chlorination, nitration, reduction
B) Nitration, chlorination, reduction
C) Nitration, reduction, chlorination
D) Nitration, reduction, acetylation, chlorination, hydrolysis.
53.

The final product D is

A) PhCH2NH2 B) Ph-NC C) PhCH2NC D) PhCH2CN
54.

55. Total number of stereoisomers possible for [Co(en)2Cl2]+1 are

A) 24 B) 12 C) 3 D) 15
56. Amongst the compound given, the one that would form a brilliant coloured dye with
NaNO2 in dil. HCl followed by addition to an alkaline solution of β-naphthol is

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57. Match the following:
COLUMN – I COLUMN - II
P) Carbylamine test (I) Secondary amine forms ppt. but
insoluble in NaOH
Q) Azo dye test (II) Presence of red orange dye
confirms aromatic amines
R) Hinsberg test (III) Appearance of bubbles confirms
aliphatic primary amine
S) Nitrous acid test (IV) An unpleasant odour confirms
primary amine

(P) (Q) (R) (S) (P) (Q) (R) (S)

A) II III IV I B) IV II I III
C) IV II III I D) III II I IV
58. Which of the following most accurately describes the first step in the reaction of
hydrogen chloride with 1-butene?

59. 4 grams of sodium hydroxide pellets were dissolved in 100 cm3 of water. The
temperature before adding the sodium hydroxide pellets was 25°C, and after
adding the pellets it was 35°C. Calculate the enthalpy change in kJ/mole of the
reaction (Specific heat capacity of water = 4.2 J/K-g)
A) 42 kJ/mole B) 4.2 kJ/mole
C) 4200 kJ/mole D) none
60. Complexes formed in the following methods are: (I) Mond’s process for purification
of nickel (II) Removal of unreacted AgBr from photographic plate (III) Removal of
lead poisoning from the body
I II III I II III
A) Ni(CO)4 [Ag(CN)2] – [Pb(EDTA)] 2– B) Ni(CO)4 [Ag(S2O3)2] [Pb(EDTA)]2–
3–

C) Ni(CO)6 [Ag(S2O3)2]3– [Pb(EDTA)]4– D) Ni(CO)6 [Ag(S2O3)2]– [Pb(EDTA)]2–

61. What will be the correct order for absorption of wavelength of light in the visible
region, for the complex, [Co(NH3)6] 3+, [Co(CN)6] 3–, [Co(H2O)6] 3+ ?
A) [Co(CN)6] 3– > [Co(NH3)6] 3+ > [Co(H2O)6] 3+
B) [Co(NH3)6] 3+ > [Co(H2O)6] 3+ > [Co(CN)6] 3–
C) [Co(H2O)6] 3+ > [Co(NH3)6] 3+ > [Co(CN)6] 3–
D) [Co(CN)6] 3– > [Co(NH3)6] 3+ < [Co(H2O)6] 3+
62. Which of the following compound has/have effective atomic number equal to the
atomic number of noble gas?
A) K2[Co(CO)4] B) K[Fe(CO)4] C) [Co(NH3)6]Cl2. D) [CoCl3(H2O)3]
63. A salt when heated with H2SO4 liberates violet gas which turns starch paper blue;
the salt may be:
A) NaNO3 B) NaBr C) NaI D) NaCl
64. Consider the following complexes [V(CO)6]– , [Cr(CO)6] and [Mn(CO)6]+ . Then correct
statement about metal carbonyls is.
A) ‘C–O’ bond is strongest in the cation and weakest in the anion
B) ‘C–O’ bond order is less in the cation than in anion.
C) ‘C–O’ bond longer in the cation than in anionic or neutral carbonyl.
D) ‘M–C’ bond order is higher in the cation than in anionic or neutral carbonyl.
65. A positive carbylamine test is given by:
A) N, N-dimethylaniline B) Acetanilide
C) N-methyl-o-methylaniline D) p-methylbenzylamine

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2
and  Ni  CO  4  :
2
66. Among  Ni  CN 4  ,  NiCl4 

is square planar and  NiCl4 

2
A)  Ni  CN  4  and  Ni  CO  4  are tetrahedral
2

B)  NiCl4  is square planar and  Ni  CN  4 

2
and  Ni  CO  4  are tetrahedral
2

and  NiCl4 
2
C)  Ni  CO  4  is square planar and  Ni  CN  4 
2
are tetrahedral

D)  Ni  CO  4  ,  Ni  CN  4  and  NiCl4  are square planar.

2 2

67. As per IUPAC nomenclature, the name of the complex [Co(H2O)4(NH3)2]Cl3 is:
A) Tetraaquadiaminecobalt(III) chloride
B) Tetraaquadiamminecobalt(III) chloride
C) Diaminetetraaquacobalt(III) chloride
D) Diamminetetraaquacobalt(III) chloride
68. Two colourless gases on mixing formed dense white fumes. These are:
A) NH3 and SO2 B) SO2 and steam C) NH3 and HCl D) NH3 and HNO2
69. In an alkaline solution, sodium nitroprusside gives a violet colour with:
A) S2- B) SO32- C) SO42- D) NO2–
70. [X] + H2SO4 →[Y], a colourless gas with irritating smell;
[Y] + K2Cr2O7 + H2SO4 gives a green color solution. [X] and [Y] is:
A) SO32–, SO2 B) Cl–, HCl C) S2–, H2S D) CO32–, CO2
II. Numerical Answer Questions :
71. The number of primary amines (including stereo) possible for C4H11N.
N
72. When 2.5 g of a sample of Mohr’s salt reacts completely with 50mL of KMnO4
10
solution then % purity of the Mohr’s salt is __________________(Molar mass of Mohr's
salt = 392 gm/mol).
73. What is the free energy change (ΔG) when 1.0 mole of water at 100°C and 1 atm
pressure is converted into steam at 100°C and 1 atm pressure?
74. Total number of bridging carbonyls present in octacarbonyl dicobalt (0) are _____
75. EDTA4- is ethylenediaminetetraacetate. Total number of N-Co-O bond angles in
[Co(EDTA)]-1 complex anions are _______.

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VELAMMAL BODHI CAMPUS, PONNERI IIT/NEET ACADEMY