MSDS For 563-63-3

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ADD: 101,Buliding1,Jinsexixi,Xihu district,Hangzhou City, Zhejiang Province,CHINA

Tel: +86-571-87396430 Fax:+86-571-87396431 Email:sales@jhechem.com


J&H Chemical Co., LTD.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifiers
Product name : Silver acetate
CAS-No. : 563-63-3
1.2 Details of the supplier of the safety data sheet
Company : Hangzhou J & H Chemical Co., Ltd
Block 1,room 101,JinSe Xixi,Jiangcun street,
Xihu district,Hangzhou
Telephone : +86-571-87396430
Fax : +86-571-87396431
1.3 Emergency telephone
Emergency Phone # : +86 571- 87396432
SECTION 2: Hazards identification
Summary of emergency
powder beige Causes skin irritation., Causes serious eye irritation., May cause respiratory
irritation., Very toxic to aquatic life. Show this material safety data sheet to the doctor in
attendance. After inhalation: fresh air. In case of skin contact: Take off immediately all
contaminated clothing. Rinse skin with water/ shower. After eye contact: rinse out with
plenty of water., Call in ophthalmologist., Remove contact lenses. After swallowing:
immediately make victim drink water (two glasses at most)., Consult a physician.
Combustible. Development of hazardous combustion gases or vapours possible in the
event of fire. Violent reactions possible with: Strong oxidizing agents, Strong acids
2.1 GHS Classification
Skin corrosion/irritation (Category 2), H315
Serious eye damage/eye irritation (Category 2A), H319
Specific target organ toxicity - single exposure (Category 3), respiratory tract irritation,
H335
Short-term (acute) aquatic hazard (Category 1), H400
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2 GHS Label elements, including precautionary statements
Pictogram

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ADD: 101,Buliding1,Jinsexixi,Xihu district,Hangzhou City, Zhejiang Province,CHINA
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J&H Chemical Co., LTD.

Signal Word Warning


Hazard Statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
Precautionary Statements
Prevention
P261 Avoid breathing dust.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER/ doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P391 Collect spillage.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
Disposal
P501 Dispose of contents/ container to an approved waste disposal
plant.
Reduced Labeling (<= 125 ml)

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ADD: 101,Buliding1,Jinsexixi,Xihu district,Hangzhou City, Zhejiang Province,CHINA
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J&H Chemical Co., LTD.

Pictogram
Signal Word Warning
Hazard Statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
Precautionary Statements none
2.3 Physical and chemical hazards
Referring to current information, no physical or chemical hazard.
2.4 Health hazards
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
2.5 Environmental hazards
H400 Very toxic to aquatic life.
2.6 Other hazards - none
SECTION 3: Composition/information on ingredients
Substance / Mixture : Substance
3.1 Substances
Synonyms : Acetic acid silver salt
Formula : C2H3AgO2
Molecular weight : 166.91 g/mol
CAS-No. : 563-63-3
EC-No. : 209-254-9
Hazardous ingredients

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ADD: 101,Buliding1,Jinsexixi,Xihu district,Hangzhou City, Zhejiang Province,CHINA
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J&H Chemical Co., LTD.

For the full text of the H-Statements mentioned in this Section, see Section 16.
SECTION 4: First aid measures
4.1 Description of first-aid measures
General advice
Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with
water/ shower.
In case of eye contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact
lenses.
If swallowed
After swallowing: immediately make victim drink water (two glasses at most). Consult a
physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed

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ADD: 101,Buliding1,Jinsexixi,Xihu district,Hangzhou City, Zhejiang Province,CHINA
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No data available
4.4 Notes to physician
No data available
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
Silver/silver oxides
Combustible.
Development of hazardous combustion gases or vapours possible in the event of fire.
5.3 Advice for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by
keeping a safe distance or by wearing suitable protective clothing.
Prevent fire extinguishing water from contaminating surface water or the ground water
system.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact.
Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures,
consult an expert.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions
(see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid
generation of dusts.
6.4 Reference to other sections
For disposal see section 13.

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ADD: 101,Buliding1,Jinsexixi,Xihu district,Hangzhou City, Zhejiang Province,CHINA
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SECTION 7: Handling and storage
7.1 Precautions for safe handling
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Tightly closed. Dry.
Light sensitive.
Storage class
Storage class (TRGS 510): 11: Combustible Solids
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Ingredients with workplace control parameters

8.2 Exposure controls


Appropriate engineering controls
Immediately change contaminated clothing. Apply preventive skin protection. Wash
hands and face after working with substance.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate

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J&H Chemical Co., LTD.
government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN 16523-1 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:KCL 741 Dermatril® L
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN 16523-1 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:KCL 741 Dermatril® L
Body Protection
protective clothing
Respiratory protection
required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following
standards: DIN EN 143, DIN 14387 and other accompanying standards relating to
the used respiratory protection system.
Control of environmental exposure
Do not let product enter drains.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

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a) Physical state powder
b) Color beige
c) Odor No data available
d) Melting
point/freezing point
No data available
e) Initial boiling point
and boiling range
No data available
f) Flammability (solid,
gas)
No data available
g) Upper/lower
flammability or
explosive limits
No data available
h) Flash point Not applicable
i) Autoignition
temperature
No data available
j) Decomposition
temperature
No data available
k) pH No data available
l) Viscosity Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
m) Water solubility No data available
n) Partition coefficient:
n-octanol/water
No data available
o) Vapor pressure No data available
p) Density 3.259 g/cm3 at 20 °C
Relative density No data available

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q) Relative vapor
density
No data available
r) Particle
characteristics
No data available
s) Explosive properties No data available
t) Oxidizing properties none
9.2 Other safety information
No data available
SECTION 10: Stability and reactivity
10.1 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
10.2 Possibility of hazardous reactions
Violent reactions possible with:
Strong oxidizing agents
Strong acids
10.3 Conditions to avoid
no information available
10.4 Incompatible materials
Aluminum, Mild steel, Strong oxidizing agents
10.5 Hazardous decomposition products
In the event of fire: see section 5
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Oral: No data available
Inhalation: No data available
Dermal: No data available
Skin corrosion/irritation
Remarks: Causes skin irritation.
Serious eye damage/eye irritation
Remarks: Causes serious eye irritation.

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ADD: 101,Buliding1,Jinsexixi,Xihu district,Hangzhou City, Zhejiang Province,CHINA
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Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
11.2 Additional Information
RTECS: AJ4100000
May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to
the deposit of insoluble albuminate of silver)., To the best of our knowledge, the chemical,
physical, and toxicological properties have not been thoroughly investigated.
SECTION 12: Ecological information
12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not
conducted
12.6 Endocrine disrupting properties
No data available

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12.7 Other adverse effects
No data available
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
SECTION 14: Transport information
14.1 UN number
ADR/RID: 3077 IMDG: 3077 IATA-DGR: 3077
14.2 UN proper shipping name
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Silver
acetate)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Silver
acetate)
IATA-DGR: Environmentally hazardous substance, solid, n.o.s. (Silver acetate)
14.3 Transport hazard class(es)
ADR/RID: 9 IMDG: 9 IATA-DGR: 9
14.4 Packaging group
ADR/RID: III IMDG: III IATA-DGR: III
14.5 Environmental hazards
ADR/RID: yes IMDG Marine pollutant: yes IATA-DGR: yes
14.6 Special precautions for user
14.7 Incompatible materials
Aluminum, Mild steel, Strong oxidizing agents
Further information
EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and
combination packagings containing inner packagings with Dangerous Goods > 5L for liquids
or > 5kg for solids.Packages smaller than or equal to 5 kg / L , not dangerous goods of
Class 9
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
National regulatory information

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Law on the Prevention and Control of Occupational Diseases
Other regulations
Please pay attention on the waste treatment should also comply with local regulations
requirement.
SECTION 16: Other information
-
Full text of H-Statements referred to under sections 2 and 3.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.

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