CHAPTER- 8 ALDEHYDES, KETONES AND CARBOXYLIC ACIDS
1. Addition of water to alkynes occurs in acidic medium and in the presence of Hg2+ ions as a catalyst. Which of the following products will be formed on addition of water to but-1-yne under these conditions.
2. Compounds A and C in the following reaction are __________.
(i) identical (ii) positional isomers (iii) functional isomers (iv) optical isomers 3. Match the common names given in Column I with the IUPAC names given in Column II.
4. Match the example given in Column I with the name of the reaction in Column II.
5. What is Tollen’s reagent? Write one usefulness of this reagent.
6. Arrange the following compounds in increasing order of their property as indicated: (i) CH3COCH3, C6H5COCH3, CH3CHO (reactivity towards nucleophilic addition reaction) (ii) Cl—CH2—COOH, F—CH2—COOH, CH3—COOH (acidic character). 7. Predict the products of the following reactions :
8. Do the following conversions in not more than two steps:
(i) Benzoic acid to benzaldehyde (ii) Ethyl benzene to Benzoic acid (iii) Propanone to Propene 9. (a) Write chemical equations to illustrate the following name bearing reactions : (i) Cannizzaro’s reaction (ii) Hell-Volhard-Zelinsky reaction (b) Give chemical tests to distinguish between the following pairs of compounds : (i) Propanal and Propanone (ii) Acetophenone and Benzophenone (iii) Phenol and Benzoic acid. 10.An organic compound ‘A’ which has characteristic odour, on treatment with NaOH forms two compounds ‘B’ and ‘C’. Compound ‘B’ has the molecular formula C7H8O which on oxidation with CrO3 gives back compound ‘A’. Compound ‘C’ is the sodium salt of the acid. ‘C’ when heated with soda lime yields an aromatic hydrocarbon ‘D’. Deduce the structures of ‘A’, ‘B’, ‘C’ and ‘D’. CHAPTER-9 AMINES 1. The reaction of an arene diazonium chloride with aniline in an acidic medium gives a coloured compound. Which of the following occurs during the reaction? A. Benzene ring is replaced. B. Nitrogen is displaced. C. Diazo group is retained. D. Amino group is displaced 2. Which of the following is TRUE about the solubility of Ethylamine and Aniline? A. Aniline is soluble in HCl. B. Both are insoluble in HCl. C. Both are soluble in water. D. Ethylamine is insoluble in water. 3. During an activity session, the teacher kept some pieces of papers in a box in which the names of chemicals were written. The teacher then asked 4 groups of students to select the appropriate pieces of paper with names of chemicals used to prepare para nitro aniline. The 4 groups have selected pieces of paper as follows; Group-1 Conc. H2SO4, Conc.HNO3, Acetic anhydride, Aniline. Group-2 Aniline, Conc.H2SO4 and Con. HNO3. Group-3 Conc.HNO3 with Pyridine, Aniline Group-4 Conc. HNO3, Conc. H2SO4, Aniline, Acetyl Chloride. Which group or groups of students have selected it appropriately? A. Group1 and 4 B. Group 3 and 4 C. Group 3 D. Group 1 4. The graphs below show the solubility of a primary, a secondary and a tertiary aliphatic amine I, J, and K in water, at the same temperature. The number of carbon atoms in each of the compounds is three. Amine I is the tertiary amine, amine J is the primary amine, and amine K is the secondary amine.
Which of the graphs identifies the three amines correctly?
A. P B. Q C. R D. S 5. Why is an alkyl amine more basic than ammonia? 6. Give a chemical test to distinguish between ethylamine and aniline. 7. Arrange the following compounds in increasing order of solubility in water : C6H5NH2, (C2H5)2NH, C2H5NH2 8. Describe the following giving the relevant chemical equation in each case : (i) Carbylamine reaction (ii) Hofmann’s bromamide reaction 9. How would you account for the following : (a) Aniline is a weaker base than cyclohexyl amine. (b) Methylamine in aqueous medium gives reddish-brown precipitate with FeCl3. 10.Complete the following reaction equations: (All India 2009)
11.Write chemical equations for the following conversions :
(i) Nitrobenzene to benzoic acid. (ii) Benzyl chloride to 2-phenylethanamine (iii) Aniline to benzyl alcohol. 12.Give the structures of A, B and C in the following reactions : (Delhi 2014)
13.An aromatic compound ‘A’ of molecular formula C7H27ON undergoes a series of reactions as shown below. Write the structures of A, B, C, D and E in the following reactions:
14.An aromatic compound ‘A’ of molecular formula C7H6O3 undergoes a series of reactions as shown below. Write the structures of A, B, C, D and E in the following reactions :
