Predicting Chemical Reactions Module HS

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Predicting Chemical Reactions

Author(s): ​
Kevin Kimura, Josue San Emeterio, Andrea De Micheli

Date Created: ​
4/10/16

Subject:​
Chemistry

Grade Level: High School

Standards: Next Generation Science Standards (​


www.nextgenscience.org​
)

HS­PS1­7​ Use mathematical representations of phenomena to support claims that


atoms, and therefore mass, are conserved during a chemical reaction.

Schedule: ​
1­Hour long class

CCMR Lending Library Connected Activities:

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Objectives: Vocabulary:

Students will learn about chemical Limiting reactant


reactions and what the signs are for Stoichiometry
them. They will prove the Law of Molar mass
Conservation of Mass. Concentration
Knowing how to balancing reactions pH scale
Identifying the limiting reactant

Students Will: Materials:

­ Understand chemical reactions and For Each Group (1­3 students)


the law of conservation of mass. ___ Narrow mouth bottle
___ 4 pieces of chalk
­ Prove that mass is conserved in ___ Electronic Balance scale
chemical reactions.
For Class
­ Identify the signs of a chemical ___ Bottle of vinegar*
reaction and the limiting reactant. ___ pH paper

­ Learn how to use a scale to measure Teacher Will Need to Provide


mass. ___ Goggles
___ A sink to drain the bottles and
­ Be able to compare the mass of a rinse out the bottles with tap water.
system before and after chemical ___ Outlets for the scales.
reactions.
* We might not be able to ship all the
­ Be able to balance a chemical vinegar needed. You might need to
reaction. purchase some on your own.

­ Understand the pH scale.

When reacting the vinegar and chalk in


Safety the bottle with the cap screwed on,
there will be pressure building up in the
bottle. When opening the bottle, slowly
unscrew the cap. Goggles should be
worn!

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Science Content for the Teacher​
:
Chemical reactions​ are important in our daily lives. From cars burning gasoline to
batteries in our phones, chemical reactions are everywhere. Even our bodies are
constantly performing chemical reactions to keep us alive. Being able to predict
chemical reactions is an important skill for scientists. For example, NASA
engineers need to know exactly how much fuel a rocket will use for it to reach
orbit without using too much or too little. Additionally, when alcohol is distilled
understanding the difference between methanol and ethanol can either lead to
blindness/death or a consumable drink.
This activity is designed for students with a basic understanding of balancing
reactions and stoichiometry. They will learn to apply this knowledge to a real
chemical reaction, vinegar and chalk. This lab is also good for introducing
concepts such as limiting reactant and pH. When chalk and vinegar are mixed to
react, CO​ is released as a gas, decreasing the mass of the system. This change
2​
in mass can be detected with a scale and predicted using the knowledge of the
starting reactants. Chalk will also change the pH of the vinegar and the change in
pH can also be predicted with some understanding of the pH scale.
Classroom Procedure​
:
Notes on the Google presentation:
The presentation is designed to be flexible for each teacher’s needs. Modification
of the slide deck before the class is expected.
The iodine clock reaction demo can be shown at the beginning of the
presentation. We recommend showing this demo when introducing the
“importance of predicting chemical reactions.” This demo is recommended for
three students in front of the class. See the detailed explanation at the end of the
document.
We recommend that students start the lab after introducing how to balance
equations. Ask the students what happens when chalk and vinegar are mixed
together. What are the products? How would you balance this reaction?
Following lab protocol steps 1­5 will help to give a clue for the students to identify
the products. The reaction also needs to be started early on in the class or a
noticeable change in mass may not be observed. The reaction takes 30­45 mins.
The students may not be able to correctly predict the products so the
presentation is designed to explain the correct answer. While the reaction is
taking place, continue to explain limiting reactants, mass lost, and change in pH.
The full presentation is designed for a 1 – 1.5 hour class. At the end of the
presentation measure the change in mass and pH to check and see if the change
in mass is correct.

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Prep work for the lab:
Make sure the scales are plugged in or running on batteries. Prep all materials
for the groups laid out on the table before the class starts. A few big bottle of
vinegar may be placed in the middle of the room for students to fill up their
narrow mouth bottles. A waste bucket or sink should be available to empty out
the bottles. Also fresh water (tap water) should be available for students to
clean out their bottles.

Assessment​
:
Where the students able to meet the objectives of the lab? Did they successfully
predict the change in mass and pH?

Were the students able to answer the discussion questions at the end of the lab?

Extra Activities:
An extra demo could be done by the teacher. Place a candle on a scale and
measure the weight at the beginning of class. Light it and let it burn during the
class, out of the students’ reach. Then measure the weight with the scale at the
end of class. Mass is not conserved because the combustion reaction emits
carbon dioxide, which slowly decreases the mass of the candle. Try to predict the
change in mass of the candle!

Iodine Clock Reaction:


The iodine clock reaction is also a very interesting reaction demo that could be
performed.

Materials for Demonstration:


● Potassium iodate solution, KIO​ , 0.1 M, 175 mL
3​
● Beakers or containers, 100­ and 500­mL, 3 each
● Sodium meta­bisulfite solution, Na2S2O5, 0.2 M, 30 mL
● Graduated cylinders (preferably 100 mL and 250 mL)
● Starch solution, 90 mL
● Stirring rods, 3
● Water, distilled, deionized, or even bottled water, 600 mL

Preparing the solutions:


1. Measure 3.75 grams of potassium iodate and dissolved in water to make a
175 mL solution.
2. Measure 1.33 grams of potassium meta­bisulfate and dissolved in water to

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make a 30 mL solution.
3. Mix a few grams of starch in 90 mL of water to make the starch solution.
4. Label three 500­mL beakers 1, 2, and 3. Using a 100­ and/or 250­mL
graduated cylinder, respectively, measure and add the following amounts
of 0.1 M potassium iodate solution and distilled water to each beaker.
These are Solution A for each experiment.
Experiment KIO​, 0.1 M
3​ Water
1 50 mL 150 mL

2 100 mL 100 mL

3 25 mL 175 mL

5. Using a graduated cylinder for each solution, measure and add 10 mL of


0.2 M sodium meta­bisulfite solution, 30 mL of starch solution, and 40 mL
of distilled water to each 100­mL beaker. These are Solution B for each
experiment. Stir each solution.

Demo protocol:
Ask three students to volunteer for the demo. At the front of the class ask them to
hold one solution A container and one solution B container. Then at the same
time ask them to pour solution B into the container holding solution A. You can
either provide a stir rod or have them gently swirl the containers to mix the
solutions. The solutions will change color from experiment 1 (~5 sec), 2 (~10sec),
and then 3 (~30 sec).

The point of this demo is to show one of the many signs of a chemical reaction,
color change. It is also a good way to show that a chemical reaction can be
controlled and made predictable.

Some recommended precautions: Providing safety glasses to demo participants


helps to promote a safety culture among students. Although the solutions are not
harmful, try to avoid skin contact or spilling on clothes (will stain). Clean out
demo containers immediately after use because the iodine dye will stain the
containers.

See the following link:


http://www.rsc.org/learn­chemistry/resource/res00000744/iodine­clock­reaction?c
mpid=CMP00005152

Acknowledgements​
:

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Prof. Melissa Hines for initiating this outreach project.

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