11th JEE Main 11 Aug

1.
The pair of species having identical shapes for molecules of both species is
A) CF 4 , SF 4 B) XeF 2 ,CO 2 C) BF 3 , PCl 3 D) PF 5 , IF 5
2. The molecular shapes of SF 4 ,CF 4 and XeF 4 are

A) the same with 2, 0 and 1 lone pairs of electrons.
B) the same with 1,1 and 1 lone pair of electrons on the central atoms, respectively.
C) different with 0,1 and 2 lone pairs of electrons on the central atom, respectively.
D) different with 1, 0 and 2 lone pairs of electrons on the central atom, respectively.
3. In which of the following molecules/ions are all the bonds not equal?
−¿ ¿
A) SF 4 B) S i F 4 C) XeF 4 D) BF 4
4. In which of the following pairs the two species are not isostructural?
−¿¿ +¿ ¿
A) CO 2−¿¿
3 and NO 3 B) PCl4 and SiCl4 C) PF5 and BrF5 D) AlF 3−¿¿
6 and SF6
5. Which one of the following has distorted Octahedral structure?

−¿¿
A) PCl5 B) PCl6 C) XeF6 D) XeO4
6. The group having triangular planar structure is
−¿,SO3 ¿
¿ 2−¿¿ 2−¿¿
A) NCl3 , BCl 3 , SO3 B) CO 2−¿,
3
NO 3
C) NH 3 , SO 3 , CO 3 D) BF3 , NF 3 ,CO 3
−¿¿
7. The correct statement about ICl 5 and ICl 4 is
A) both are isostructural.
−¿¿
B) ICl 5 is trigonal bipyramidal and ICl 4 is tetrahedral.
−¿¿
C) ICl 5 is square pyramidal and ICl 4 is tetrahedral.
−¿¿
D) ICl 5 is square pyramidal and ICl 4 is square planar.
8. The correct statement among the following is
A) ( SiH 3 )3 N has back bonding ( CH 3 )3 N doesn’t
B) ( SiH 3 )3 N , ( CH 3 )3 N both has back bonding
C) ( SiH 3 )3 N central ( CH 3 )3 N . none has back bonding
D) can’t be predicted
9. Hybridization of the underline atom changes in
−¿ ¿ + ¿¿
A) AlH 3 changes to AlH 4 B) H 2 O changes to H 2 O
+¿¿
C) NH 3 changes to NH 4 D) in all cases
10. The maximum number of 90∘ angles between bond pair of electrons is observed in
A) s p3 hybridization. B) s p3 d 2 hybridization.
C) s p2 hybridization. D) s p3 d hybridization.
11. Which of the following conversions involves change in both shape and hybridization?
+¿ ¿ −¿ ¿ +¿ ¿ −¿¿
A) NH 3 → NH 4 B) P C l 3 → PCl4 C) H 2 O→ H 3 O D) BF3 → BF 4
12. Correct regarding hydrogen bond strength and boiling point respectively
A) HF > H2O, H2O > HF B) HF > H2O, HF > H2O
C) H2O > HF, H2O > HF D) HF > H2O, HF = H2O
13. Which of the following has maximum dipole moment?
A) PCl3F2 B) H2O C) NH3 D) NF3
14. Resonance hybrid of nitrate ion is :-
15. Statement-I : CO2 is non polar while SO2 is polar molecule.

Statement-II : S-O bonds are polar while C-O non polar.
These questions contains, Statement-I (assertion) and Statement-II (reason).
(A) Statement-I is True, Statement-II is True; Statement-II is a correct explanation for Statement-I
(B) Statement-I is True, Statement-II is True; Statement-II is NOT a correct explanation for Statement-I
(C) Statement-I is True, Statement-II is False.
(D) Statement-I is False, Statement-II is True.
16. The incorrect order of polarity is shown by
A) H2O>H2S B) NH3>H2O C) NH3>NF3 D) PF2Cl2>PCl2F2
17. In which of the following pair trans isomer has higher dipole moment than the first one?
A) BF3, CO2 B) XeO3, XeO4 C) BF3, CHCl3 D) All of these
18. The correct sequence regarding bond angle
A) NH3 > PH3 > AsH3 B) NH3 = PH3 = AsH3
C) AsH3 > PH3 > NH3 D) PH3 > NH3 > AsH3
+¿¿ +¿¿
19. Shape of the compounds Xe F 3 and Xe F 5 are respectively
A) T-shape, square pyramid B) Sea-saw, square pyramidal
C) Bent T-shaped, square pyramidal D) T-shaped in both
20. STATEMENT-1 : All hybrid orbitals of have same shape and energy.
STATEMENT-2 : All hybrid orbitals on carbon in CH3Cl have same s character.
STATEMENT-3 : Hybridisation is a theoretical process
A) TF T B) TTT C) F F T D) T F F
INTEGER TYPE:
1. A compound has molecular formula XeOn where ‘n’ is number of oxygen atoms, dipole moment of
the compound is minimum when n is
2. The number of sigma bond in XeOF4 molecule is
3. Number of pπ—pπ bond in given compound CN – CH = CH – CN is _____.
4. Among the triatomic molecules/ions, the total number of linear molecule(s)/ion(s)
[Atomic number : S = 16, Cl = 17, I = 53 and Xe = 54]

5. Iodine in IF7 is surrounded by _______ pairs of electrons
6. Total correct statements in the following are:
STATEMENT I: The polarising power of a cation is directly proportional to its size.
STATEMENT II: The polarisability of an anion is directly proportional to its charge.
STATEMENT III: For a given cation, greater the polarisability of the anion, more the covalent
character.
7. Among the following, the number of elements showing only one non-zero oxidation state is
Cl, F, N, P, Sn, Tl, Na, Ti
8. Based on VSEPR theory, the number of 90-degree F–Br–F angles in BrF5 is
9. The hybridisation number of XeO2F2 molecule is
10. The total number of lone pair in the structure XeOF4 is
1-B 2-D 3-A 4-C 5-C 6-B 7-D 8-A 9-A 10-B
11-D 12-A 13-B 14-C 15-C 16-B 17-C 18-A 19-A 20-C
1-4 2-5 3-5 4-5 5-7 6-2 7-2 8-0 9-5 10-15

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1.

2. The molecular shapes of SF 4 ,CF 4 and XeF 4 are

5. Which one of the following has distorted Octahedral structure?

A) ( SiH 3 )3 N has back bonding ( CH 3 )3 N doesn’t

B) ( SiH 3 )3 N , ( CH 3 )3 N both has back bonding

C) ( SiH 3 )3 N central ( CH 3 )3 N . none has back bonding

15. Statement-I : CO2 is non polar while SO2 is polar molecule.

[Atomic number : S = 16, Cl = 17, I = 53 and Xe = 54]

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