Sec: SR.

IIT_*COSC(MODEL-A)&APEX PTA-11 Date: 20-10-24

Time: 3 Hrs 2023_P1 Max. Marks: 180
KEY SHEET
MATHEMATICS
1 AB 2 AC 3 CD 4 A 5 C
6 D 7 B 8 3 9 5 10 2
11 7 12 4 13 2 14 B 15 C

16 B 17 B

PHYSICS
18 AD 19 ABD 20 ABCD 21 C 22 C

23 C 24 C 25 5 26 24 27 6

28 6 29 5 30 9 31 B 32 B

33 C 34 B

CHEMISTRY
35 AC 36 ABC 37 ABD 38 B 39 B
150
40 B 41 C 42 60 43 To 44 9250
155
45 4 46 50 47 2 48 1 49 2

50 3 51 4
Narayana IIT Academy 20-10-24_SR.STAR CO-SC(MODEL-A)_JEE-ADV_PTA-11_KEY&SOL
SOLUTIONS
MATHEMATICS

3a  b ab a  3b
1. A1  , A2  , A3 
4 2 4
1/4 1/2 1/4
G1   a 3b  , G2   ab  , G3   ab3 
4ab 2ab 4ab
H1  , H2  , H3 
a  3b ab 3a  b
2. Eliminate  2  6  5   2   2
  2  .  36  25 
2

Also 6   1  5    16   36  25    1   2
2

3. Let An  0  an 1  an  2  .... are zero
 an1 is zero hence all are zero
Also let bn  0  bn 1  0 also let bm be the first non – zero term
 bm 1  0 which is not true
1 1 1
Clearly bn can be taken as 1, , , ,....
2 4 8
So infinite sum exists
For an however if lim  a1  a2 ......an  exists we can find n such that an 1  an  2 ...  1
n
2
Then an  a .....  an  an 1  an 2  ....   an
n 2

Which is not possible

15
4. Divide the numerator & denominator by x and take y  x 
x
5. Let  ,  are the roots of x 2  bx  c  0
Then     b
 one of the roots is ‘2’ (since  ,  are primes and b is odd positive integer)
 f  2   0  2b  c  4 and b  c  35
 b  13, c  22
 13  81
Minimum value  f    
 2 4
6. If t  log 2 x, the given relation between
1 2 1 t
t    t  1  t 4  2t 3  t 2  2t  1  0
t2 1 t
2 1
 t  1, t 2  2t  1   2  0
t t
2
 1  1
or  t    2  t    1  0
 t  t
1
 
 t    2  1  R   2, 2 
t
The sum of its roots is t1  t2    2 1 
The product of the value of x is 2t  t1 t2  2 2

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1 1 1 1
7. Let Sn     ..... 
a1 a2 a3 an
 1 1  1 1
 2       ..... 
 a1 a2  a3 an
a a  1 1
 2   1 2    .... 
 a1a2  a3 an
 1 1  1 1
 2     ... 
 a1a2 a3  a4 an
aa a  1 1
 2   1 2 3    ..... 
 a1a2 a3  a4 an
 lim S n  2
n 

8. D f   5, 4 
25  x 2
Case  i  0   1 and solving x   3, 4 
16
25  x 2
Case  ii   1 and solving x   3,1
16
 solution set x   3,1   3, 4 
 x  2, 1, 0  z  no.of integers = 3
9. 175  52.7.245  5.7 2.875  537.1715  5.73
Let   log 5,   log 7
log175 2  
a 
log 245   2
log 875 3  
b 
log1715   3
1  ab   2    3    2    3   

a  b  2     3     2   3   
5  2  2 
 5
 2  2
10. 2 1  3  5  7  ...a   2 1  3  5  7  ...  b   2 1  3  5  7  7...c 
  a 1   a 1   b 1   b 1   c  1   c 1
 2    1 2  2    1 2  2   1 2
  2   2   2   2   2   2
2 2 2
  a  1   b  1   c  1
 a  6 and a  b  c  21
 a  7, b  5, c  9
a  b  2
11    
p 2 . p  2  30 g  1   9  32   30  7
12. Put x  t to get a cubic equation
Whose roots are  2 ,  2 ,  2 then replace t by 5  y to get y 3  10 y 2  23 y  11  0
13
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Narayana IIT Academy 20-10-24_SR.STAR CO-SC(MODEL-A)_JEE-ADV_PTA-11_KEY&SOL
Let f  x   x 3  3 x 2  5 x  3
3
  x  1  2  x  1
The graph of f (x) is odd w.r.t to x = 1
The if the root of x 3  3x 2  5 x  17  0 is   1  x1
Then the root of x 3  3x 2  5 x  11  0 is   1  x1
So,     2
14. x 2
 ax  c  x 2  bx  d 
 x 4   a  b  x3   c  d  ab  x 2   ad  bc  x  cd
 x 4  8 x 3  23 x 2  28 x  12
2
  x  1 x  2   x  3

15. (P) Given a 2  4a  1  4  a 2  1  4 1  a 

 a  1  a 2  1
a 2  1 4  a  1
y  4
a 2 1 a 1 a 1
x 1 x 2 x 1
(Q) 4 x  3  3 x  3 taking log log x  3
4
x 1 x  2
 log x  3  0 or  0
4 3
 x  4, 2 or x  11 and x  3
(R) critical pts x = 0, 6
Case – I: x  63x  1   3x  1
 2 log 5  6  x   x  11
Case – II: 0  x  63x  1   3 x  1
 2 log 5  6  x   x  11
Case – III: x  0  3 x  1  3x  1
 2 log 5  6  x   3x  log 5  6  x 
 solution
2n n
 S   4   2n  1 3  114   n  1 2 
2 2
 n  11
16.  P  f  sin x   0
 3sin x  1 sin x  2   0  sin x  2 
1
sin x   x   ,    , 2   ,
3
3   , 4   ,5  
 sum  15
 Q  f  sin x   f  cos x   3  7  sin x  cos x   4
7  7 2  7  7  sin x  cos x   7  7 2
Average = 7

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Narayana IIT Academy 20-10-24_SR.STAR CO-SC(MODEL-A)_JEE-ADV_PTA-11_KEY&SOL
g  x   x  2  x  3
 R  0 x 3
f  x   3 x  1 x  2 
 log 2 x  3  x  8
 S  3cos   1 cos  2  cos ec  2  cos ec  3  0
1
cos      1 , 2  1
3
cos ec  2     2 ,    2
cos ec  3    3 ,    2
2
17.  P   3  2a   2  3b   6  c    32  2 2  6 2  .
 4a 2  9b 2  c 2 
i  i  1 2i  1
 Q  ai  12  22  .....i 2 
6
10 10
i  i  1 2i  1
S   ai    1210
i 1 i 1 6
n2
 R  Tn 
500  3n 3
1 500
Let U n   2  3n
Tn n
dTn  500  3n  2n  n 9n n 1000  3n3 
3 2 2

 2
 2
0
dn  500  3n3   500  3n3 
1/3
 1000 
n 
 3 
1/3
 1000 
Now,6    7
 3 
2
2r  1  r  1  r 2 1 1
 S  Tr  2 2
 2
 
r  r  1 r 2  r  1 r  r  12
2

n n
S n   Tr   Vr  Vr 1 
r 1 r 1

1
 V1  Vn 1  1  2
 n  1

PHYSICS
18. Apply conservation of angular momentum about origin and impulse momentum equation along a line
of symmetry passing through origin
1

19. From figure

1 0
 8.06  A 
min  

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20. The energy last by an electron should be exhibited in the form of radiation
21.  13.6  10.2  3.4 eV  1st collision
& 3.4  15  11.6 eV  2nd collision
1 1 1  R
22.  R     (for blamer series)
 4  4

23.

nh
24. The angular momentum is mvr   n 1
2
mu 2 Ze2
Centripetal force, 
r 4 0 r
 0 n 2 h 2   0 h 2   me
 1 0.53  10 10
r   

 m e2 Z   me e 2   m
Z 264 Z
Since r cannot be less than nuclear radius
1
r  1.6 Z 3 1015 m
1
200 1015
 1.6 1015 Z 3
Z

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3
 200 4
Z    37
 1.6 
25. Apply simple F = mvdv/ds and F = mg
E
26. Eatom  27 20
n
27. Conceptual

CHEMISTRY
36. For S N 1 path : r1   3 10 s
4
  RX 
1

For S N 2 path : r2   5 104  

M s   RX   Nu
1 1
 
   0.1M , then r  r
1)  Nu    1.0 M , then r  r
2)  Nu
1 2 1 2
   
   0.6 M , then r  r
3)  Nu    0.4 M , then r1  2
4)  Nu
1 2
    r2 3
39.

40. (a)   1  e  kt
  1when t   for first order

41.

1
rate of reaction   rate of consumption of A 
2
1  0.693 
at 80sec Rate of reaction    0.05 
2  20 
42.
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43.
intially liquids A  5mole, B  5mole
at eq

YA PAo X A

YB PBo X B
x 200  5  x 

 3  x  100  2  x 
soluving x  1.36
Pt  152 torr

44. For the reaction,

Now, rate constant for forward reaction,

At equilibrium,
Rate of forward reaction = Rate of backward reaction i.e.,

After putting the given values Now,

G o   RT ln K eq  2500 ln  2e3 
 2500  ln 2  ln e3   2500  0.7  3 
 9250
45. Let x be the mass of element in 51.0g of saturated solution. Mass of benzene in 51.0g of saturated
solution = (51-x)g
Total mass of benzene containing x g of solute = (50 +51 – x)g = (101 – x
In benzene, it is given that X exist as X 8

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Narayana IIT Academy 20-10-24_SR.STAR CO-SC(MODEL-A)_JEE-ADV_PTA-11_KEY&SOL
8X  X8
1
i
8
nsolute
T f  i.K f .m  i.K f .
wsolvent  kg 
1 x 1000
0.55   5.5 
8 25  101  x 
x  2g
Ans = 4
46. When concentration of A and B are equal

47.
Bn  B  n  4 
t0 a mole 0
t  10 min  a  x  mol x mol
25 N  3  a
34 N   a  x  3  6 x
1 a 1 25
K  .ln  .ln
t a  x 10 min 16
46 10 3 / min

48.

49.

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