Chapter 8 The Periodic Table
Chapter 8 The Periodic Table
Chapter 8 The Periodic Table
............................................................................................................................................... [2]
Complete the diagram to show the electron arrangement in the outer shells of the ions present
in potassium chloride.
........ ........
K Cl
[3]
..............................................................................................................................................
........................................................................................................................................ [2]
(ii)
Name the products formed at the positive electrode (anode) and negative electrode
(cathode) when molten potassium chloride undergoes electrolysis.
anode ...................................................................................................................................
cathode ................................................................................................................................
[2]
(i) Write an ionic half-equation for the reaction at the negative electrode (cathode).
........................................................................................................................................ [2]
........................................................................................................................................ [1]
(iii) Name the potassium compound that remains in the solution after electrolysis.
........................................................................................................................................ [1]
(e) Complete the dot-and-cross diagram to show the electron arrangement in a molecule of
chlorine, Cl 2.
Show the outer electrons only.
Cl Cl
[1]
(f) The melting points and boiling points of chlorine and potassium chloride are shown.
(i) Deduce the physical state of chlorine at –75 °C. Use the data in the table to explain your
answer.
explanation ..........................................................................................................................
..............................................................................................................................................
[2]
(ii) Explain, in terms of structure and bonding, why potassium chloride has a much higher
melting point than chlorine.
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[Total: 19]
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Complete the diagram to show the electron arrangement in the outer shells of the ions present
in sodium fluoride.
........ ........
Na F
[3]
..............................................................................................................................................
........................................................................................................................................ [2]
(ii) ame the products formed at the positive electrode (anode) and the negative electrode
N
(cathode) when dilute aqueous sodium fluoride undergoes electrolysis.
anode ...................................................................................................................................
cathode ................................................................................................................................
[2]
(i) ame the products formed at the positive electrode (anode) and the negative electrode
N
(cathode) when molten sodium fluoride undergoes electrolysis.
anode ...................................................................................................................................
cathode ................................................................................................................................
[2]
(ii) Write the ionic half-equation for the reaction at the negative electrode (cathode).
........................................................................................................................................ [1]
(e) Complete the dot-and-cross diagram to show the electron arrangement in a molecule of
fluorine, F2.
Show the outer electrons only.
F F
[1]
(f) The melting points and boiling points of fluorine and sodium fluoride are shown.
(i) Deduce the physical state of fluorine at –195 °C. Use the data in the table to explain your
answer.
explanation ..........................................................................................................................
..............................................................................................................................................
[2]
(ii) Explain, in terms of structure and bonding, why sodium fluoride has a much higher melting
point than fluorine.
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[Total: 18]
name ...........................................................................................................................................
description ..................................................................................................................................
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[4]
(b) Transition elements and Group I elements have some similar physical properties.
(i) Name the term used to describe the ability of elements to be hammered into a shape.
........................................................................................................................................ [1]
(ii) Describe what happens to the particles in iron when it is hammered into a shape.
..............................................................................................................................................
........................................................................................................................................ [1]
(iii) Suggest why copper, rather than other transition elements, is used for wires which conduct
electricity.
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(c) Transition elements are harder and stronger than Group I elements.
Describe how two other physical properties of transition elements are different from those of
Group I elements.
1 ..................................................................................................................................................
2 ..................................................................................................................................................
[2]
(d) Chemical properties of some Group I elements are shown in the table.
flame test
element reaction with cold water reaction with oxygen
colour
● steadily effervesces
lithium very slowly forms an oxide layer red
● forms a colourless solution
● strongly effervesces
sodium slowly forms an oxide layer
● forms a colourless solution
● v ery strongly effervesces
potassium quickly forms an oxide layer
● forms a colourless solution
(ii) Name the gas produced when Group I elements react with water.
........................................................................................................................................ [1]
(iii) Name the solution formed when potassium reacts with water.
........................................................................................................................................ [1]
(iv) Predict the pH of the colourless solution formed when potassium reacts with water.
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(v) Write the chemical equation for the reaction of sodium with oxygen.
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(e) Iron is a typical transition element. It is the catalyst used in the Haber process.
(i) Write the equation for the reaction that occurs in the Haber process.
........................................................................................................................................ [2]
(ii) State the temperature and pressure used in the Haber process. Include units.
temperature .........................................................................................................................
pressure ...............................................................................................................................
[2]
[Total: 22]
(a) Group I elements react with cold water to form alkaline solutions.
(i) Place the Group I elements caesium, lithium, potassium, rubidium and sodium in their
order of reactivity with water.
[1]
(ii) Name the alkaline solution formed when caesium reacts with cold water.
........................................................................................................................................ [1]
(b) Group I elements have lower melting points than transition elements.
Describe one other difference in the physical properties of Group I elements and transition
elements.
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(d) Some Group VII elements react with aqueous solutions containing halide ions.
explanation ..........................................................................................................................
[2]
(e) Bromine monochloride, BrCl, is made by the reaction between bromine and chlorine. The
chemical equation is shown.
Calculate the overall energy change for the reaction using bond energies.
● alculate the total amount of energy required to break the bonds in 1 mole of Br2(g) and
C
1 mole of Cl 2(g).
.............................. kJ
● alculate the total amount of energy released when the bonds in 2 moles of BrCl (g) are
C
formed.
.............................. kJ
.............................. kJ / mol
[3]
[Total: 11]
3 Transition elements are found in the middle block of the Periodic Table.
(a) Chromium has several isotopes. Manganese has only one isotope.
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........................................................................................................................................ [2]
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(iii) Complete the table to show the number of protons, neutrons and electrons in a 24
52
Cr3+ ion.
[3]
(b) One chemical property of transition elements is that they form coloured compounds.
1 ...........................................................................................................................................
2 ...........................................................................................................................................
[2]
(c) T
ransition elements and Group I elements are metals. They share many physical properties
including the ability to:
● conduct electricity
● be hammered into shape.
(i) Explain why transition elements and Group I elements conduct electricity.
........................................................................................................................................ [1]
(ii) State the property that describes a material which can be hammered into shape.
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(d) Transition elements and Group I elements differ in other physical properties. Transition
elements are harder and stronger than Group I elements.
Describe two other ways in which the physical properties of transition elements differ from
Group I elements.
1 ..................................................................................................................................................
2 ..................................................................................................................................................
[2]
[Total: 14]
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(b) Fluorine reacts with sulfur to form a compound which has 25.2% sulfur by mass and a relative
molecular mass of 254.
Complete the dot-and-cross diagram to show the electron arrangement in a molecule of NCl 3.
Cl N Cl
Cl
[3]
Complete the dot-and-cross diagram to show the electron arrangement and charges of the
ions in lithium chloride.
..... .....
Li Cl
[3]
(e) Explain, in terms of attractive forces between particles, why LiCl is a solid at room temperature
but NCl 3 is a liquid with a relatively low boiling point.
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[Total: 13]
(a) The Group I metals react with cold water. Transition elements do not react with cold water.
(i) Describe two other differences in the chemical properties between Group I metals and
transition elements.
1 ...........................................................................................................................................
2 ...........................................................................................................................................
[2]
(ii) Describe the observations when potassium is added to cold water. Write a balanced
equation for the reaction. Include state symbols.
observations ........................................................................................................................
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equation ...............................................................................................................................
[5]
Describe two other differences in the physical properties of Group I metals and transition
elements.
1 ..................................................................................................................................................
2 ..................................................................................................................................................
[2]
(c) Some Group VII elements react with aqueous solutions containing halide ions.
(ii) State the name of the general term given to the type of reaction in which electrons are
transferred from one species to another.
........................................................................................................................................ [1]
(iii) Identify the oxidising agent in this reaction. Give a reason for your answer.
reason ..................................................................................................................................
[2]
(d) Use the key to complete the table to show the results of adding aqueous halogens to aqueous
solutions of halides. One has been completed for you.
halides
KCl (aq) KBr(aq) KI(aq)
Cl 2(aq) key
✓ = reaction
✗ = no reaction
halogens Br2(aq) ✓
I2(aq)
[2]
[Total: 16]
name ...........................................................................................................................................
description ..................................................................................................................................
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[4]
(b) Potassium combines with sulfur to form an ionic compound, potassium sulfide, K2S.
1 ...........................................................................................................................................
2 ...........................................................................................................................................
[2]
(ii) Complete the dot-and-cross diagram to show the electron arrangement and charges of
the ions in potassium sulfide.
....... .......
K S
.......
[3]
(c) When potassium is added to water, it reacts vigorously and a coloured flame is seen.
The equation for the reaction is shown.
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(iv) Calculate the volume, in cm3, of hydrogen gas formed when 2.34 g of potassium is added
to excess water at room temperature and pressure.
= .............................. mol
= .............................. mol
(d) Aqueous potassium hydroxide reacts with a dilute acid to produce aqueous potassium chloride,
KCl (aq), which is a salt.
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(iii) Name the experimental technique used when salts are made by reacting a dilute acid with
an aqueous alkali.
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(e) When aqueous silver nitrate, AgNO3(aq), is added to aqueous potassium chloride, a precipitate
is formed.
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(iii) Write the ionic equation for the reaction. Include state symbols.
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[Total: 23]
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. ...................................................................................................................................... [1]
(ii) State the colour of the flame seen when sodium burns.
. ...................................................................................................................................... [1]
(iii) rite a chemical equation for the reaction which takes place when sodium burns in air to
W
form sodium oxide.
. ...................................................................................................................................... [2]
(iv) Complete the dot-and-cross diagram to show the electron arrangement and charges of
the ions in sodium oxide.
....... .......
Na O
.......
Na
[3]
(c) S
odium reacts vigorously with water to form aqueous sodium hydroxide, NaOH, which is a
strong base.
. ...................................................................................................................................... [1]
. ...................................................................................................................................... [1]
. ...................................................................................................................................... [1]
= .............................. mol
= .............................. mol
(d) When NaOH(aq) is added to aqueous iron(III) chloride, FeCl 3(aq), a solid product is formed.
(i) Name the type of reaction where a solid is formed from two solutions.
. ...................................................................................................................................... [1]
. ...................................................................................................................................... [1]
. ...................................................................................................................................... [1]
(iv) Write the ionic equation for the reaction. Include state symbols.
. ...................................................................................................................................... [3]
[Total: 22]
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(b) Sodium reacts with cold water to form hydrogen gas and a solution of a strong alkali.
test .......................................................................................................................................
pH = .............................. [1]
(iii) Name a substance which can be used to confirm the pH of a solution of a strong alkali.
........................................................................................................................................ [1]
(iv) Write the symbol equation for the reaction between sodium and cold water.
........................................................................................................................................ [3]
(c) Lithium has two naturally occurring types of atoms, 6Li and 7Li.
(i) State the name given to atoms of the same element with different nucleon numbers.
........................................................................................................................................ [1]
(ii) Complete Table 2.1 to show the number of protons, neutrons and electrons in the atom
and ion of lithium shown.
Table 2.1
6
Li 7
Li+
protons
neutrons
electrons
[3]
(iii) Table 2.2 shows the relative abundance of the two naturally occurring atoms of lithium.
Table 2.2
atom 6
Li 7
Li
relative abundance 10% 90%
Complete Fig. 2.1 to show the electronic configurations of the ions in potassium oxide.
Show the charges on the ions.
K O K
Fig. 2.1
[3]
[Total: 16]
2 The elements in Group VII of the Periodic Table are known as the halogens. Halogens can form
halide ions.
(a) Identify the halogen with the lowest density at r.t.p. (room temperature and pressure).
............................................................................................................................................... [1]
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● give the symbol of the halogen with the highest atomic number
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[2]
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(ii) Name one halide ion which bromine molecules can displace.
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(iii) Explain why bromine can displace the halide ion in (d)(ii).
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(e) Name a halide compound which can be used to detect the presence of water.
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Complete the dot-and-cross diagram in Fig. 2.1 for the ions in calcium chloride.
Cl Ca Cl
Fig. 2.1
[3]
(g) Aqueous lead(II) ions are added to aqueous chloride ions. A white precipitate of insoluble
lead(II) chloride, PbCl 2, is formed.
........................................................................................................................................ [1]
(ii) Write the ionic equation for this reaction. Include state symbols.
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........................................................................................................................................ [3]
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[Total: 18]