Student's Solution Copy [Code - 24878]

12th_ Batch 24A7 A9 A11 A13 A15 24A2 A4 A6 Dhurv Eng.& Hindi_ Major Test_[Mains Pattern]
12th JEE (M) - Phase 1
24A11, 24A13, 24A15, 24A2, 24A4, 24A6, 24A7, 24A9, 24DA1, 24DA2
KOTA

Date: 25-Nov-2024 Duration: 3 Hours Max Marks: 300

Maths - Section A

1. Answer: B 3. Answer: C

Sol: Sol:

ℓog (5
A
.2
B
) = C
The equation possess roots of opposite
200
sign i.e. one positive and one negative
C
root,
A B 2C
⇒ 5 .2 = (200) = 5
⇒ ‘0’ lies between two roots.
2
3C
⇒ A = 2C and B = 3C
By concept of location of roots f(0) < 0
∵ C = 1 has no other factor than 1
⇒ a2 – 3a + 2 < 0
Hence, A = 2, B = 3, C = 1
⇒ (a – 1) (a – 2) < 0
A+B+C=6
⇒ a ∈(1, 2)
Therefore, correct answer is option (B)
4. Answer: A
2. Answer: B
Sol:
Sol:
2
(3 sinx– 4 cosx – 10)(3 sinx + 4 cosx –
x −5x+7

2
>0 10)
−2x +3x+2

2
x −5x+7
= 9 sin2x – 16 cos2 x – 60 sinx + 100
2
<0
2x −3x−2
for minimum
<0
⊕

(x−2)(2x+1) value sinx = + 1

∴ cosx = 0

9 – 60(0) – 60(1) + 100 = 49

x∈(–1/2, 2) Therefore, the correct answer is (A)

Therefore, the correct answer is (B)

5. Answer: A 8. Answer: D

Sol: Sol:

f[g (x)] = a(bx + a) + b Refer to the graph

= abx + a2 + b .....(1)

g[f (x)] = b(ax + b) + a

= abx + b2 + a .....(2)

(1) − (2) f [g(50)] − g[f(50)] = a2 − b2

+b−a

∴ (a2 − b2) + (b − a) = 28

(a − b)(a + b − 1) = 28 = (1 × 28) or (2 9. Answer: B

× 14) or (4 × 7) Sol:
let a − b = 1 and a + b − 1 = 28 x, −∞ < x ≤ −1 and 0 ≤ x ≤ 1
f (x)={
3
x , −1 ≤ x < 0 and x ≥ 1
and, 2a − 2 = 28 ⇒ a = 15; b = 14
∴ clearly f(x) is differentiable at all points
∴ ab = 210 Ans. except, perhaps at x = −1, 0, 1
if a − b = 2 and a + b − 1 = 14 (not
At x = −1LHD = 1, RHD = 3x
2
= 3
possible)
At x = 0, LHD = 0, RHD = 1

if a − b = 4 and a + b − 1 = 7 At x = 1, LHD = 1, RHD = 3

2a − 1 = 11 ⇒ a = 6 and b = 2 Hence f(x) is not differentiable at −1, 0, 1

∴ ab = 12 Ans. 10. Answer: C

6. Answer: B Sol:
Sol: d
g(x)
( )
dx g(g(x))
2
2
(r+1) −r
Since, Tr = tan
−1
( 2
) g(g(x))g'(x)−g(x)⋅g'(g(x))g'(x)
1+((r+1)r)
= 2
(g(g(x)))

Hence,
Now, f(x) = x3 + 3x + 4
−1 2 −1
Sn = tan (n )− tan (0)
f(0) = 4 Or g(4) = 0
π
⇒ S∞ =
2 g'(4) = 1
= 1

f '(0) 3

7. Answer: A
f(–1) = 0 ⇒ g(0) = –1,
Sol:
Put at x = 4
2 2 2 2
cosec x cosec x cosec x cosec x 2
lim (p + q + r + s ) sin x
g(x)
x→0 d
( )
dx g(g(x))
2
2 2 2 sin x
cosec x cosec x cosec x

= lim p(1 + (
q

p
) + (
r

p
) + (
s

p
) )
g(g(4))⋅g'(4)−g(4)⋅g'(g(4))g'(4)
x→0

= 2
(g(g(4)))
q r s
∴ < 1, < 1, < 1
p p p
1
(−1)( )−0
3
1
= p (1 + 0 + 0 + 0)° =p =
1
= −
3

Therefore, the correct answer is (A)

11. Answer: D 13. Answer: A

Sol: Sol:

We have, y
2
= 8x ..... (1)

Tangent to (1) be ....

1 2 2
x
I = ∫ x ( + ln x + lnx)d x y = mx +
x m

(2)
x−1 x 2 x
= ∫ (x + x ln x + x lnx)d x ⇒ x
2
+ y
2
− 12x + 4 = 0

2
2
.....
x−1 x−1 x−1 x−2
= ∫ [x ln x + x(x ln x(ln x +
x
)+x )]d x ⇒ (x + 6) + y = 32

(3)
Use ∫ (f (x) + xf '(x)) d x=xf(x) + C , we
get Tangent to (3)

I = x ⋅ x
x−1
lnx + C y = m(x − 6) ± (√32)√1 + m
2
...... (4)
x
= x lnx + C (2) and (4) represents the same,
Therefore, The correct option is D) . ⇒
2
= √32√1 + m
2
− m (6)
m

12. Answer: C 2
2
6m +2 2
⇒ ( ) = 32 (1 + m )
Sol: m

4 2 2 4
β ⇒ 9m + 1 + 6m = 8m + 8m

Let
x−α
I = ∫ √
β−x 4 2
α
⇒ m − 2m + 1 = 0

2 2 2±√4−4
2
x = αcos t + βsin t ⇒ m =
2

2 2
x − α = (β − α) sin t ⇒ m = 1

β − x = (β − α) cos
2
t Tangent which are common (1) and (3)
are,
(b − a)
⇒ y = ±x ± 2

π/2
⇒ y = ±(x + 2)
∫ (1 − cos 2t) dt

0
14. Answer: C

Sol:
π/2
sin 2t
=(β − α)[t − ]
2 0

π h(x) will be a non-increasing function.

= (β − α)
2

π
So, h(x) ≤ (0)∀x > 0
I = (β − α)
2

⇒ h(x) ≤ 0 ∀x > 0

But co-domain of h(x) is [0, ∞) .

So, h(x) = 0 ∀x ≥ 0
15. Answer: D 16. Answer: C

Sol: Sol:
3 2 π
f (x)= x + x − 5x − 1 x x ∈[0, ]
−1 2
y = cos |cosx|→{
π
π − x x ∈[ , π]
2 2
f '(x)= 3x + 2x − 5=(x − 1)(3x + 5)
2
−1
y = (cos |cosx|) →

2 π
x x ∈[0, ]
2
{
2 π
(π − x) x ∈[ , π]
2

point of local maxima,

5
x = − →
3

x = 1 → point of local minima,

Increasing function in
5
(−∞, − )∪(1, ∞)
3

Decreasing function in
5
(− , 1)
3

Required Area
π
1
2 2 2
= 2[∫ (x − x )dx + ∫ (x − x)dx]
0 1

2
2 π π
= + ( − 1) sq. units
3 4 3

Final Answer: Option (C)

Also, f (0) = −1, f (1) = −4, f (2) = 1, f (−1) = 5

f (−2) = −8 + 4 + 10 − 1 = 5

f (−3) = −27 + 9 + 15 − 1 = −4

⇒ α∈(−3,−2); β ∈(−1,0); γ∈(1,2)

⇒ [α] = −3, [β] = −1, [γ] = 1

⇒ [α] + [β] + [γ] = −3

17. Answer: A 19. Answer: D

Sol: Sol:

Given differential equation,

2 3 2
(xy − e/x )dx = x ydy

2 e 2
⇒ xy dx − 3
dx = x ydy
x

2 2 e
⇒ xy dx − x ydy = 3
dx
x

2 2 2e
⇒ 2 xy dx − 2x ydy = 3
dx.
x

2 2
2x ydy−2 xy dx 2e
⇒ 4
= − 3 4
dx
x x ⋅x

2
y
in y2 = 4x, we get
−2e
⇒ d(
x
2
)=
x
7
dx Putting (λλ)

λ = 0, 4
Integrating both sides, we get
y
2
−2e
but λ ≠ 0 (Given)
∫ d( 2
)= ∫ dx
7
x x
So, λ = 4
2
y −2e 1
⇒ 2
= × 6
+ C ∴ P = (4, 4) ⇒ t1 = 2
x −6 x

Hence (Using 2
)
2
y
t2 = −3 t2 = −t1 −
⇒ 2
=
e
6
+ c ....(i) t1
x 3x

⇒ Q = (9, −6)
∵ y(1) = 0

−3
Now
4
⇒ Put x = 1, y = 0 in eq(i) we get m1 =
3
; m2 =
4

0 e ∘
⇒ = + C ∴ θ = 90
2 6
1 3⋅1

−e
Hence equation of line passing through
⇒ c =
3 (1,2) and inclined.

Therefore the correct answer is (D).

2
y
e e
∴ 2
= −
6
x 3x 3

2
y
e 1
⇒ 2
= ( 6
− 1)
x 3 x

2 4 6
∴ 3y x = e(1 − x )

Therefore the correct answer is (A).

18. Answer: C

Sol:

Given S(-ae,o), T(ae,o), B(o,b) as STB is

an equilateral triangle in ΔToB
∘ OB
tan 60 =
OS

OB b
√3 = =
OS ae

2
2
(√3 ae) = b

2
2 b 2
3a (1 − 2
) = b
a

2
3 b
=
2
4 a

3 1
e = √1 − =
4 2
20. Answer: A

Sol:

The coordinates of any point on the given

2
2
y
ellipse are
x
2
+ 2
= 1
(3√2) (4√2)

(3√2cosθ, 4√2sinθ) .

The slope of tangent

2
2 −b ⋅(3√2cosθ)
−b x1
4
⇒ = = − cotθ
2
a y1 2
3
a ⋅(4√2sinθ)

Given: Slope of the tangent

4
= −
3

∴ −
4

3
cotθ = −
4

3
or tanθ = 1

π
⇒ θ =
4

Thus, the equation of the tangent is

xcosθ ysinθ
+ = 1
3√ 2 4√ 2

1 1
x⋅ y⋅
√2 √2

⇒ + = 1
3√ 2 4√ 2

y
or
x
+ = 1
6 8

Therefore, the coordinates of A and B are

(6, 0) and (0, 8) respectively.

∴ Area of ΔOAB sq.

1
= × 6 × 8 = 24
2

units
 Maths - Section B

21. Answer: 5 22. Answer: 01.00

Sol: Sol:

Let the three boxes be B1 , B2 and B3 → → → → → →

a ⋅ b = b ⋅ c = c ⋅ a = 0

so B1 + B2 + B3 = 21
→ →→
→ →→ →
Value of [ a + b + c a + b b + c ]
B1 + B2 > B3

21 > 2B3 →
→ →
= ( a + b + c )⋅
B3 ≤ 10,

→ → → →
Similarly B1 &B2 will contain less than 10 [( a + b ) × ( b + c )]
balls
B1 , B2 , B3 ≤ 10 → → →
= ( a + b + c )⋅

Now Co-eff of in
21 3
2 3 10
x (x + x + x + ….x )
→ → → → → → → →
[ a × b + a × c + b × b + b × c ]
3
Co-eff of in
18 2 9
x (1 + x + x + …x )
= 0 + 0 + 0 +[ a b c ]+

3 → →
10 → → → →
1−x [ ]+[ ]
Co-eff of x
18
in (
1−x
) b a c c a b

→
3 −3 =[ → →]
Co-eff of x
18
in (1 − x
10
) (1 − x) a b c

→
Co-eff of x
18
in → →
= a ⋅ ( b × c )
10 20 30 −3
[1 − 3x + 3x − x ](1 − x)

→ →
Now Co-eff of = a (1. n̂)(n̂ is vector parallel to a )
18 3+18−1 3+8−1
x =( C − 3 × C )
3−1 2

= 1
=
20
C − 3 ×
10
C =55
2 2
23. Answer: 96
λ 55
∴
11
=
11
= 5 Sol:

Containing the line

∣x + 1 y– 1 z– 3 ∣
∣ ∣
∣ 6 7 8 ∣ = 0
∣ ∣
∣ 3 5 7 ∣

(x + 1)(49 − 40)−(y − 1)(42 − 24)

+(z − 3)(30 − 21)

9(x + 1) – 18 (y – 1) + 9(z– 3) = 0

x – 2y + z = 0

at point (7,-2,13)

∣ 7+4+13 ∣
PQ = = 4√6
∣ √6 ∣

PQ2 = 96
24. Answer: 9 25. Answer: 6

Sol: Sol:

Given , vertices of a triangle are Circle C : x2 + y2 + 4x – 2√2y +c=0

A(−8, 5) , B(−15, −19) and C(1, −7) .

Centre (–2,√2), radius r =

The equation of interior angle bisector of √4 + 2 − c = √6 − c = r
angle A is ax + 2y + c = 0.
Now circle C is director circle of S1
√6−c
So radius of S1 is r1 =
√2

and circle S1 is director circle of S2

√6−c
so radius of S2 is r2 = 2

and so on, now sum of radii = sum of

infinite G.P.
S = 2
∞

a
S∞ =
1−r
AD is the interior angle bisector of angle
A . √6−c
2 = 1
1−
Using distance formula, we get √2

2 2
AB = √7 + 24 = 25 √2√6−c
= 2
√2−1
2 2
AC = √9 + 12 = 15
squaring both sides C = 4√2

AB BD 25 5
⇒ = = =
AC CD 15 3 now compare C = a√b

Point D is divides BC in the ratio 5 : 3 ∴ a+b=6

∴ Coordinate of D are:

−45+5 −57−35 −23

( , )≡(−5, )
8 8 2

Using point-slope form of linear equation,

we get
Equation of line AD is :
−23
−5
2
y − 5 =( )(x + 8)
−5+8

−11
y − 5 =( )(x + 8)
2

2y − 10 = −11x − 88

11x + 2y + 78 = 0

⇒a = 11 and c = 78

Therefore,
c 78
a − = 11 − = 9
39 39
 Physics - Section A

1. Answer: D 3. Answer: A

Sol: Sol:

According to the given diagram, the

2
mv
T = mgcosθ +
ℓ
electric field lines are directed radially
2
inward. When the field lines are directed
..(i)
mv
mg = mgcosθ +
ℓ towards the charge then the charge is a
negative charge. From a hypothesis, we
know the lines of force directed outward in
case of a positive charge and the lines of
force directed inward in case of a negative
charge. So, the charges q1 and q2 are
negatively charged.

4. Answer: A

Sol:
1 2 mgh 1 2
mgl = + mv A
2 2 2 ( )E0 k
3 AE0 k
⇒ C1 = =
2 d 3d
gl = 2gh + v

2 AE0 k
gℓ = 2g(ℓ − ℓcosθ)+v ⇒ C = C1 + C2 = (k + 2)
3d
2
gℓ = 2gℓ– 2gℓ cosθ + v

2A

2 ( )E0
2gℓcos θ − gℓ = v 3 2 AE0
⇒ C2 = =
d 3d

from (1) AE k
0
(k+2)
3d

Option (D)
∴ mg = mgcosθ + mgℓ(2cosθ) C k+2
= AE k
=
C1 0 K
1 = cos θ + 2 cosθ – 1

3d
2 = 3 cos θ

Now, for both the regions, potential

= cosθ
3

from (1) difference across the plates of the

capacitors is same. (let = V)
2
2 mv
mg = mg × +
3 ℓ ⇒ E1 . d = E2 . d = V
2
2g v
g– = ⇒ E1 = E2
3 ℓ

ℓg
Option (A)
2 E1
= v ⇒ = 1
3 E2

√gℓ
v =
3

2. Answer: A

Sol:

We know that

W= 1 2
kx
5. Answer: B
2

⇒ W α k (as x is same)
Sol:
Also as, KA > KB
F.d = 1

2
CV2
⇒ WA > WB
2 –6 5
ϕE
F=
CV
= =
10 ×10

2d 2 2
= 0.05 N

Therefore, the correct answer is (B)

6. Answer: B 10. Answer: B

Sol: Sol:

Q = Q0 (1 – e–t/e )
3Q
series 0
= Q ( 1 − e−t/τ )
4 0

1 −t/τ
4
= e
combination
t
e
τ
=4
t
= ln( ) 2
paralel τ

t= τ l n(2)

t = RC ln(2)
combined
6 −5

I1 = I 2 t = 0. 1 × 10 × 10 ln(2)

2 E E

2r+2
= r t = ln(2)
+2
2

1 2
=
r+1 r+4

r + 4 = 2r + 2 11. Answer: A
2 = r
Sol:
7. Answer: A
y = f(ax ± bt) is general wave equation
Sol:
At
1
t = 0, y =
Theory based.
2
√1+x

8. Answer: D At t = 1, y =
Sol: t = 1, y =
1
=
1

2
√2−2x+x 2
√1+(x−1)

Here a = 1 and b = 1

wave velocity, v =
b

a
= 1 m/sec towards
+ve x.

Therefore, the correct answer is (A)

9. Answer: B

Sol:

For given question

1 2
∝ z
λ

1
∴ λ ∝ 2
z

2
λ z'
= 2
λ z

2
λ 3
= = 9
λ' 12

λ
λ' =
9
12. Answer: C 16. Answer: C

Sol: Sol:

The correct option is v2 > v1 > v3 3×4

q5 =( )(20 − 4 × 4)
3+4

We know that, orbital velocity of a satellite

moving in a circular orbit of radius R q5 =
12
× 4 = +
48
μC
7 7
around the sun of mass M is given by
17. Answer: D
√GM
V1 =
R
Sol:
For an elliptical path taken by the satellite,
using conservation of angular momentum,
mV2 R mV3 5R
=
3 3

⇒ V2 = 5V3 ...(1)

Using conservation of energy,

GMm 1 2 1 2 GMm
(− ) + mV2 = mV3 + (− ) μ0 I
R/3 2 2 5R/3 a
BAB = [2 × ]
4πb/2 a
2
+b
2
2√
Solving (1) and (2) we get, 4

μ0 I
√5GM √GM a
BAB =
V2 = , and V3 = πb
√ a2 + b
2
R 5R

So, V2 > V1 > V3 μ0 I b μ0 Ib

BBc = a =
4π ×2× 2 2 2 2
b +a πa√a +b
2√
2

Hence, option (A) is the correct answer. 4

13. Answer: A
2μ0 Ia
Bneet = 2BAB + 2BBC = +
2 2
bπ√a +b

Sol:
2μ0 Ia 2μ0 I a b
2 = ( + )
r θ 2 2 2 2 b a
A = πa√a +b π √a + b
2

2 2
2μ0 I a +b
1 2
E = Br ω =
2 2 2 ab
π √a + b

14. Answer: D 2μ0 I √ a2 + b

2

=
π
Sol:
ab

2
18. Answer: C
→ I1 ( πb )
2μ0
B1 =
4π 3
(axial point) 19. Answer: B
x

−→ −
→ Sol:
∴ PEsys = −M2 ⋅ B 1
λα
β = = 1 mm
μ0 I 1 d
2 2
U = − 3
b × I2 πa
2x
5β

2 2
Distance = 4β −
2
3μ0 πI1 I2 a b
dU
∴ F = − = 4
dx 2x 3
= β
2

At x = d
3
2 2
= mm
3μ0 πl1 l2 a b 2
F =
4
2d

15. Answer: C

Sol:

As per theory

width is given by
2λ

d
20. Answer: A

Sol:

In ΔOCP, OC = CP = R

∴ The triangle is isosceles

∴ ∠COP = ∠CPO = 60° ⇒ ∠OCP = 60°

∴ ΔOCP is an equilateral triangle

⇒ OP = R

Extension of string
3R R
∴ = R − = = x
4 4

The forces acting are shown in the figure

(i)
The free-body diagram of the ring is
shown in fig (ii)

Force in the tangential direction

= Fcos 30° + mgcos 30° = [kx + mg] cos 30°

5 mg
∴ Ft = √3
8

∴ Ft = mat

5 mg √3 5√ 3
⇒ = mat ⇒ at = g
8 8

Also when the ring is just released

N + Fsin 30° = mgsin 30°

mg 1 3 mg
=(mg − )× =
4 2 8
 Physics - Section B

21. Answer: 20.00 24. Answer: 3

Sol: Sol:
dV
E =∣
∣
∣= ∣(10x + 10)∣
∣ ∣ ∣ = 20 V/m
dx x=1

22. Answer: 1

Sol:
voltmeter
The system can be redraw as

R = (n – 1) ...(i)

4 mg g
Ammeter : →
2
∴ a = = = 5 m/s
8 m 2

∴ v = u + at = 2 × 5 = 10 m/s

23. Answer: 8

Sol:

Current through one bulb

100
=
100

100
8 = N ×
100

...(ii)
G
N = 8 S =
( n−1 )

where N - Number of bulbs. R 2

= (n − 1)
S

2
4 = (n – 1) ⇒ n = 3

25. Answer: 16.00

Sol:

Electric field outside wire is

E =
2kλ

r
, where r = 2R

2
λ = ρπR

2
λ ρπR ρR
E = = =
2πε0 r 2πε0 2R 4ε0
 Chemistry - Section A

1. Answer: C 6. Answer: D

Sol: Sol:

On moving left to right in a period electron The solution of CH3COONa and CH3COOH
affinity increases due to increase in forms an acidic buffer. For acidic buffer
electronegativity (tendency to attract solution.
electron) and on moving down, as the
[H+] =
[Acid]
atomic radii increases, therefore electron Ka ×
[Salt]
affinity decreases.
Ka = 1.8 × 10–5
So from the element F, Cl, O, S
[CH3COOH] = 0.10
The size of Cl is having highest electron
affinity value than F as the size of F being [CH3COONa] = 0.20
small and highly electronegative,it tends to
repel the incoming electron hence has low So, [H+] = 1.8 × 10–5 ×
0.10

0.20
affinity than Cl but have a higher affinity
value than S as sulphur has a large atomic + –6
[H ] = 9 × 10 M
radius compared to Cl but O having
more electronegativity tends to repel the Therefore, the correct answer is (4).
incoming electron hence has high electron 7. Answer: B
affinity than O. Hence the order will be :
Cl>F>S>O Sol:
2. Answer: B Given ;
Sol: µob = 1.5 × 10–29 C-m

PV
γ
= constat, P. γV
γ−1 γ
. dV + V . dP = 0 µcal = q × d

∴
dP
= −γ.
dV = 1.6 × 10–19 C × 150 × 10–12 m
P V

= 2.4 × 10–29 C-m

3. Answer: D
μob.
% ionic character = × 100
Sol: μcal

−29

% ionic character = × 100

1.5×10
−29
2.4×10

= 62.5 %

Therefore, the correct answer is: (B).

4. Answer: B
8. Answer: B
Sol:
Sol:

5. Answer: D

Sol:

Un- Magnetic
Complex O. S HBZ Geometry
paired 'e' property
[Ni(CO)4 ] 0 sp
3
Tetrahedral 0 Diamagnetic
2−
[MnCl4 ] +2 sp
3
Tetrahedral 5 Paramagnetic
2−
[CuCl4 ] +2 sp
3
Tetrahedral 1 Paramagnetic
2+
[Cu (NH3 ) ]
4
Square
shifting of +2 sp
2
1 Paramagnetic
planar
e 3d → 4p
9. Answer: C Sol:

Graph rate V/S (A)

t

(i) For first order

y = mx + C

1
Rate = K [At ] + O

⏐ ⏐ ⏐ ⏐
⏐ ⏐ ⏐ ⏐
↓ ↓ ↓ ↓

y = m x + C

So A → (II) K

(ii) Ist order

ln A0 = ln At + Kt

ln A0 − K t = ln At

↓ ↓↓

C + m x = y

(iii) B → (i) K

t1 V/S A0
2

1
t1 = . A0 + 0
2K
2

⏐ ⏐ ⏐ ⏐
⏐ ⏐ ⏐ ⏐
↓ ↓ ↓ ↓

y = m x C

(iv) t100% V/S A0

Zero order reaction

1
t100% = . A0 + 0
K

y = mx + C
10. Answer: C 15. Answer: A

Sol: Sol:

Therefore, the correct answer is (A).

16. Answer: C
Therefore, the correct answer is (C).
Sol:
11. Answer: A
A2 + B2 ⇌ 2 AB
Sol:
t = 0 2 4 0
Molecular orbital electronic configuration of
at equi. 2– x 4– x 2x
these species are :
2
2 2 2 2 1
4x
4–
− − 2 ∗ 2 2 ∗ 2 ∗ ∗
O2 (17e ) = σ1s σ 1s , σ2s σ 2s , σ2px , π2py π2pz , π 2py π 2pz

(2–x)(4–x)

− − 2 ∗ 2 2 ∗ 2 2 2 2 ∗ 1 ∗ 1

x2=B–6x+x2
O (16e ) = σ1s σ 1s , σ2s σ 2s , σ2px , π2py π2pz , π 2py π 2pz
2

⇒
2− − 2 ∗ 2 2 ∗ 2 2 2 2 ∗ 2 ∗ 2
O (16e ) = σ1s σ 1s , σ2s σ 2s , σ2px , π2py π2pz , π 2py π 2pz 8
2
⇒ x– – 1. 33
6

Hence number of anti-bonding electrons 2x x

⇒ [AB] = = = 0. 665
are 7,6,and 8 respectively. 4 2

12. Answer: B 17. Answer: D

Sol: Sol:

ΔH−ΔG −241.6−(−228.4) On Vigorous oxidation the π- bond will

ΔS = =
T 300
breaks and oxidation takes place forming
ketone and acid.
For of
−1
1 mole H2 O = −44 JK

Hence, for 2 moles = −88 J K

−1

13. Answer: B
Therefore the correct option is (D).
Sol:

18. Answer: B

Sol:

B. E. of (O-O) in Y < B. E of (O-O) in X

19. Answer: C
(Only one configuration is possible)
Sol:
14. Answer: C
Aldol condensation:
Sol:

H2 + Cl2→HCl
1 1

2 2

BDE⇒Bond Broken - Bonds formed

( + ) – (103)
104 58

2 2

⇒ –22Kcal
20. Answer: A

Sol:

Given Po = 90 mm Hg

wB = 10 gm

wA = 390 gm ; MA = 78 gm/mol

Ps = 90 – 8 = 72 mm Hg

MB = M gm/mol = ?
o
P −Ps
∵
P
o
= xB

90−72 10/M
= 390
90
10/M+
78

8 10 10
[ + 5] =
90 M M

8 4 10
+ =
9M 9 M

4 10 8
= −
9 M 9M

=
4 90−8 82
=
9 9M 9M

4 82
=
9 9M

M= = 20.5 gm/mol
82

4
 Chemistry - Section B

21. Answer: 3 23. Answer: 10.00

Sol: Sol:
2− 2+ 2−
[Co (ox) Br (NH3 )] BaSO4 ⇌ Ba + SO
4
2
x+0.5

−9
(x)(x + 0. 5) = 1. 5 × 10

−9
x=3×10 (0. 5 >> x)

24. Answer: 01

Sol:

Total stereoisomer = 2 + 1 Pair of

Enantiomers = 3

The number of stereoisomers possible

for [Co(ox)2(Br)(NH3)]2- is 3. 25. Answer: 16

22. Answer: 3 Sol:

ΔStotal = ΔSsys + ΔSsurr

Sol:

For Cannizzaro reaction absence of α− ΔSsys = nR ln (

P1
) = 10 × 8 × ln2 =
Hydrogen essential condition.
P2

56
So Compound CH3CHO contain α qirr
hydrogen, so it does not undergo ΔSsurr =
T

cannizaro reaction.
w=–q ⇒ (because at isothermal Δ U=
0)
−
CCl3 CHO + OH → CHCl3

in presence of base chloral gives w = –1 (V2 – V1) = –1 × nRT (

1
−
1
)
chloroform, which is not Cannizzaro P2 P1

product.
= –10 × 8 × T (
1

1
−
1

2
) = – 40 T

⇒ q = 40 T
−40T
ΔSsurr = = −40
T

ΔSTotal = 56–40 = 16 J/k