-1-

(v) O/C
w' fmd' i' Wiia fm< úNd.h - 2025 (vi) F/D
Paper - 03 (vii) N/B
(viii) N/B
Marking Scheme (ix) F/D -(3)×9= (27)
^ wjika ixfYdaOk we;=<;a lr fkdue; &
(x)
01. (a)(1) O (6) O (11) P (16) O
(2) P (7) O (12) P (17) P ---^3&
(3) P (8) P (13) O (18) O
(4) P (9) P (14) O (19) P I2 úp,kh
(5) P (10) P (15) O (20) P
-(2)×20= (40)
(a fldgig ,l=Kq 40)
(b) (i) N+
(ii) Cu
(iii) MnCl4
(iv) Cr (I2 úp,kh I1 yd I3 w;r msysgk mßÈ we¢h hq;=h')
(v) Cl (b fldgig ,l=Kq 30)
(vi) He
(vii) N (c) (i) c = νλ ---^2&
(viii) Mg 2+ λ = c/ν
(ix) Li yd F w;r = 3 × 108 ms-1 / 6.57 × 1014 Hz ---^2&
(x) BaCl2 - (3) × 10 = (30) = 456 nm ---^2&
(b fldgig ,l=Kq 30)
(ii) E 1 = hνL ---^2&
(c) (i) (i) A,F -(1) × 2 = (2) = 6.626 × 10-34 Js ×22.66× 1014Hz ×
(ii) B, E, G - (2) × 3 = (6) 6.022 × 1023 mol-1 ---^2&
-1
(iii) C,D -(2) × 2 = (4) = 904.2 kJ mol ---^2&
(iv) A,F -(2) × 2 = (4)
(iii) oDIH l,dmh ---^6&
10 (iv) P - ,hsudka fY%K
A h
s
(v) A - B
5 Q - ndu¾ fY%AKsh - (3) × 2 = (6)
1 4 3-
B - N n=7
7 (v)
n=6
C - 3 9 K+ n=5
19
n=4
D - 66 Zn2+
30 n=3
81 -
E - Br
35
n=2 Q 1Q 2 Q 3
11
F - 5
B
18 - n=1
G - 9
F -(2) × 7 = (14) P1 P2 P3
(c fldgig ,l=Kq 30)
^f¾Ld P1, P2, P3... f,i kï lr ke;s kï ,l=Kq ke;'&
02. (a) (i) I < Br < F < Cl (c fldgig ,l=Kq 30)
(ii) IR lsrK < UV lsrK < X lsrK < γ lsrK
(iii) 3s < 3d < 4s < 4p 03 '(a) (i) N2 + 2O2 → 2NO2
(iv) Al3+ < Mg2+ < Ca2+ < K+ (ii) 3Mg + N2 → Mg3N2
(v) OH- < H2O < H3O+
(iii) Ca + 2H2O → Ca(OH)2 + H2
(vi) Li < Na < K < Rb
(vii) HI < HBr < HCl < HF (iv) 2KNO3 → 2KNO2 + O2
(viii) BeSO4 < MgSO4 < CaSO4 < SrSO4 (v) Li3N + 3H2O → 3LiOH + NH3
(ix) O < S < P < Si (vi) 4LiNO3 → 2Li2O + 4NO2 + O2
(x) BeCl2 < MgCl2 < CaCl2 < BaCl2 -(4)×10= (40) (vii) 2Al + 6 HCl → 2AlCl3 + 3H2
(a fldgig ,l=Kq 40) (viii) Mg + 4HNO3 → Mg(NO3)2 + 2NO2 + 2H2O
(b) (i) 14 ldKavh (ix) 2NH3 + 3Cl2 → N2 + 6 HCl
(ii) C / ldnka (x) 2H2S + SO2 → 3S + 2H2O - (4)×10 = (40)
(iii) N/B (a fldgig ,l=Kq 40)
(iv) F/D

CHEMISTRY - Marking Scheme Dayal Herath Target | 2024

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(b) (i) A yd D -(2) × 2 = (4) 04 '(a) (i) NaNO3 : Al = 3 : 8 neúka" ---^4&

(D+ i|yd ,l=Kq ke;') Al m%udKh = (6 mol / 3) × 8
= 16 mol ---^4&
(ii) Ne ---^2&

(iii) B , D, F -(2) × 3 = (6) (ii) NH3 : NaNO3 = 1 : 1 neúka" ---^4&

(D+ yd F2+ i|yd ,l=Kq ke;') NaNO3 m%udKh = 12 mol ---^4&

(iv) MgF2 fyda FC2 ---^3&

(iii) NaNO3 ys
(v) Kr ---^2& ujq,sl ialkaOh = (23 + 14 +16 × 3) g mol-1
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 ---^3& = 85 g mol-1
NaNO3 m%udKh = 10.2 g / 85 g mol-1
(vi) D <A< F < E < B < C fyda = 0.12 mol ---^2&
Na < Li < Mg < O < Ar < F ---^4&
NaNO3 : NH3 = 1 : 1 neúka" ---^2&
(vii) B, F - (3) × 2 = (6) NH3 m%udKh = 0.12 mol ---^4&
(b fldgig ,l=Kq 30)
(iv) NH3 : Al
(c) (i) (n + l) ys w.h jeäjk úg Yla;sh jeäfõ' ujq, wkqmd;h 3 : 8
---^6& ialkaO wkqmd;h 3 × 17 : 8 × 27
51 : 216
(ii) (n + l) ys w.h iudk jk úg n ys w.h jeäjk
úg Yla;sh jeä fõ' ---^6&
NH3 : Al = 51 : 184 neúka" ---^4&
= (10.2 g / 51) × 216
(iii) (I) 3
= 43.2 g ---^4&
(II) 3d < 4p < 5s
(III) 18 -(2) × 3 = (6)
(v) NaNO3 m%udKh = 5.1 g / 85 g mol-1
(iv)(I) ² tla ldCIslhlg tl ne.ska tajdfha neóu = 0.06 mol ---^2&
iudka;r jk mßÈ bf,lafg%dak msf¾' Al m%udKh = 5 g / 27 g mol-1
² bka miqj ;j;a bf,lafg%dak mj;S kï = 0.1852 mol ---^2&
hq.,kh ùu isÿ fõ' - (3) × 2 = (6)
NaNO3 Al NH3
(II) ^w& mjq,s nysIaldr kshuh ujq, wkqmd;h 3 8 3
^wd& yqkâ
a ia kshuh - (3) × 2 = (6) wdrïNl / mol 0.06 0.1852
(c fldgig ,l=Kq 30) m%;sls%hd / mol -0.06 -0.16 +0.06
b;sß / mol - 0.0252 0.06 ---^2&
(d) (i) X - S
Y - Cl
∴ ksmojd .; yels
Z - Ar - (6) × 3 = (18)
NH3 m%udKh = 0.06 mol ---^2&
(ii) X - 1s2 2s2 2p6 3s2 3p4 ∴ NH3 ialkaOh = 0.06 mol / 17 g mol-1
Y - 1s2 2s2 2p6 3s2 3p5 = 1.02 g ---^2&
Z - 1s2 2s2 2p6 3s2 3p6 -(2) × 3 = (6)
(vi)NH3 m%udKh = 1.12 g / 22.4 g mol-1
(iii) (I) Z<Y<X fyda Ar < Cl < S = 0.05 mol ---^2&
(II) Z<X<Y fyda Ar < S < Cl
(III) Z<X<Y fyda Ar < S < Cl NH3 : Al = 3 : 8 neúka" ---^2&
(IV) Z<X<Y fyda Ar < S < Cl Al m%udKh = (0.05 mol / 3) × 8
(V) Z<Y<X fyda Ar < Cl < S = 0.1333 mol ---^2&
-1
(VI) Y<X<Z fyda Cl < S < Ar Al ialkaOh = 0.1333 mol × 27 g mol
- (3) × 6 = (18) = 3.6 g ---^2&
(iv) Cl / Y ---^4& (a fldgig ,l=Kq 50)
(v) (3, 1, +1, +1/2) fyda (3, 1, +1, -1/2) ---^4&
(d fldgig ,l=Kq 50)

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(b) (i) b;sß jk tlu >k fYaIh MgO fõ' ---^2& (iii) 2NO(g) + 5H2(g) → 2NH3(g) + 2H2O(g)
MgO ialkaOh = 8 g × (20 / 100) wdrïNl / cm3 50 100
= 1.6 g ---^2& m%;sls%hd / cm 3
-40 -100 +40 +40 -^2&
MgO m%udKh = 1.6 g / 40 g mol-1 ---^2& b;sß / cm3 10 - 40 40 -^2&
= 0.04 mol ---^2&
² m%;sl%shdjl§ iïmQ¾Kfhkau jehjkqfha iSudldÍ
MgO : Mg(NO3)2 = 1 : 1 neúka" ---^2& m%;l
s h
s% lhhs'
Mg(NO3)2 m%udKh = 0.04 mol ---^2& ² tneúka H2 iSudldÍ m%;sl%shlhhs' -(2)×2= (4)
Mg(NO3)2 ialkaOh = 0.04 mol × 148 g mol-1 ---^2&
= 5.92 g ---^2& (iv) 40 cm3 ---^4&
Mg(NO3)2 (w/w) % = (5.92 g / 8 g) × 100 %---^2& (v) wdrïNl mßudj = (50 + 100) cm3
= 74 % ---^2& = 150 cm3 ---^2&
(ii) (I) CaCl2 + Na2CO3 → CaCO3 + 2NaCl
MgCl2 + Na2CO3 → MgCO3 + 2NaCl wjidk mßudj = (10 + 40 + 40) cm3
- (3) × 2 = (6) = 90 cm3 ---^2&
(II) CaCl2 ialkaOh x úg" ∴ mßud wvqùu = (150 - 90) cm3
MgCl2 ialkaOh = (10 - x) g fõ' ---^2& = 60 cm3 ---^2&

CaCl2 m%udKh = x g / 111 g mol-1 (vi)NH3 ujq, Nd.h = 40 cm3 / 90 cm3 ---^2&
= (x / 111) mol ---^2& = 4 / 9 fyda 0.4444 ---^2&
CaCl2 : CaCO3 = 1 : 1 neúka" ---^2&
CaCO3 m%udKh = (x / 111) mol ---^2& (vii) 2NO(g) + 5H2(g) → 2NH3(g) + 2H2O(g)
∴ CaCO3 ialkaOh = (x / 111) mol × 100 g mol-1 wdrïNl / mol 45/30 12/2
= (100 x / 111) g ---^2& 1.5 6 ---^2&
MgCl2 m%udKh = (10 - x) g / 95g mol-1 m%;sls%hd / mol -1.5 -3.75 +1.5 +1.5 ---^2&
= [(10 - x) / 95] mol ---^2& b;sß / mol - 2.25 1.5 1.5 ---^2&

MgCl2 : MgCO3 = 1 : 1 neúka" ---^2& ∴ iEfok NH3 m%udKh = 1.5 mol ---^2&
MgCO3 m%udKh = [(10 - x) / 95] mol ---^2& ∴ NH3 ialkaOh = 1.5 mol × 17 g mol-1

MgCO3 ialkaOh = [(10 - x)/95] mol×84 g mol-1 = 25.5 g ---^2&

= [84(10 - x)/95] g ---^2& (c fldgig ,l=Kq 50)
∴ uq¿ ialkaOh = 8.925 g

100 x + 84(10 - x) = 8.925 ---^2&

111 95

x = 4.967 g / 5 g
∴ MgCl2 ialkaOh = 4.967 g / 5 g ---^2&
∴ MgCl2 (w/w) % = (4.967 g / 10 g) × 100 %
= 49.67 % fyda 50 % ---^2&
^oYuia:dkhka jeghSfï§ isÿjk fjkialï ksid
49 ] isg 50 ] olajd ish¨u ms<s;=rej,g ,l=Kq
,ndfokak'&
(b fldgig ,l=Kq 50)

(c) (i) 2NO(g) + 5H2(g) → 2NH3(g) + 2H2O(g)-^10&

(ii) wej.dâfrda kshuh wkqj" ---^4&

ujq, m%udKh ∝ mßudj neúka" ---^4&

NO : H2 : NH3 : H2O
∴ mßud wkqmd;h 2 : 5 : 2 : 2 ---^2&

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w' fmd' i' Wiia fm< úNd.h - 2025 x = 0.03 mol wdfoaYfhka (I) g"
2 × 0.03 mol + y = 0.12
ETT Paper - 2025 - MCQ - 03
Pa y = 0.06 mol
Marking Scheme ∴ x :y = 0.03 mol : 0.06 mol
^ wjika ixfYdaOk we;=<;a lr fkdue; & = 1 : 2
ms<s;=re wxlh
∴ ms<s;=r ^2& fõ'
ms<s;=re wxlh ms<s;=re wxlh
1 0 . f*dafgdakhl Yla;h s .ksu'q
1 1 11 4 21 2
E = hc / λ
2 5 12 2 22 3
=6.625×10-34 Js ×3× 108ms-1 / 360 × 10-9 m
3 2 13 1 23 2
4 5 14 3 24 4 = 5.521 × 10-19 J
5 3 15 3 25 4 1 S msgjk Yla;sh = 26.5 J
6 3 16 4 26 3 ∴ msg lrk f*dafgdak
7 2 17 5 (a, b, d) 27 3 .Kk = 26.5 J / 5.521 × 10-19 J
8 2 18 4 28 5 = 4.8 × 10-19 J
9 2 19 2 29 5 ∴ ms<s;=r ^3& fõ'
10 3 20 1 30 4
12. A m%udKh x úg"
Calculations
06. ñks;a;= 1 l§ msgjk XA = nA / (nA + nB)
CO2 m%udKh = 0.667 g / 44 g mol-1 1/3 = x / (x + nB)
= 0.01516 mol nB = 2x
ñks;a;= 1 l§ msgjk A ujq,sl ialkaOh 2y úg"
CO2 m%udKh = 0.01516 mol × 5 B ujq,sl iaalkaOh = 3y
= 0.0758 mol
∴ A ialkaOh = x mol × (2y) g mol-1
CO2 : KO2 = 1 : 1 neúka" = (2xy) g
= 0.0758 mol B ialkaOh = 2x mol × (3y) g mol-1
= (6xy) g
KO2 ialkaOh = 0.0758 mol × 71 g mol-1
= 5.3818 g
∴ uq¿ ialkaOh = (2xy + 6xy) g
≈ 5.38 g = (8xy) g
∴ ms<s;=r ^3& fõ'
08. C2H6 m%udKh x o CH4 m%udKh y o úg" ∴ (w/w) % = (2xy + 8xy) × 100 %
C2H6 + 7/2 CH4 → 2CO2 + 3H2O = 25 %
∴ ms<s;=r ^2& fõ'
CH4 + 2O2 → CO2 + 2H2O
14. CaCO2 m%udKh = 5 g / 100 g mol-1
C2H6 : CO2 = 1 : 2 neúka" = 0.05 mol
C2H6 u.ska msgjk CaCO3 : CO2 = 1 : 1 neúka"
CO2 m%udKh = 2x msgjQ CO2 m%udKh = 0.05 mol
CaCO3 m%udKh x o CaC2O4 m%udKh y o úg"
100 x + 128 y = 5.84 g - (I)
CH4 : CO2 = 1 : 1 neúka"
C2H4 u.ska msgjk CaCO3 : CO2 = 1 : 1 neúka"
CaCO3 u.ska msgjQ
CO2 m%udKh = y
CO2 m%udKh = x
∴ msgjk uq¿ CO2
m%udKh = 5.28 g / 44 g mol-1 CaC2O4 : CO2 = 1 : 1 neúka"
2x + y = 0.12 - (I) CaC2O4 u.ska msgjQ
CO2 m%udKh = y
C2H6 : H2O = 1 : 2 neúka"
C2H6 u.ska msgjk msgjQ uq¿ CO2 m%udKh = 0.05 mol
H2O m%udKh = 2y x+y = 0.05 - (II)
(II) × 100 e 100 x + 100 y = 5 - (II)
msgjQ uq¿ H2O
(III) - (I)
m%udKh = 3.78 g / 18 g mol-1
28 y = 5.84 - 5
3x + 2y = 0.21 - (II)
y = 0.03 mol
x = 0.2 mol
(I) × 2 e 4x + 2y = 0.24 mol - (III)
∴ CaC2O4 ujq, Nd.h = (0.03 mol / 0.05 mol)
(III) - (II)
= 0.6
x = 0.03 mol
∴ ms<s;=r ^3& fõ'

CHEMISTRY - Marking Scheme Dayal Herath Target | 2024