SAFETY DATA SHEET

Creation Date 23-Jan-2009 Revision Date 24-Dec-2021 Revision Number 7

1. Identification
Product Name 3-Chloroperoxybenzoic acid

Cat No. : AC255790000; AC255790010; AC255790250; AC255791000;

AC255795000
Synonyms m-Chloroperbenzoic acid; m-CPBA; MCPBA

Recommended Use Laboratory/Industrial use chemical/reagent. Chemical intermediate.

Uses advised against Food, drug, pesticide or biocidal product use.

Details of the supplier of the safety data sheet

Company
Fisher Scientific Company Acros Organics
One Reagent Lane One Reagent Lane
Fair Lawn, NJ 07410 Fair Lawn, NJ 07410
Tel: (201) 796-7100

Emergency Telephone Number For information US call: 001-800-ACROS-01 / Europe call: +32 14 57 52 11
Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99
CHEMTREC Tel. No.US:001-800-424-9300 / Europe:001-703-527-3887

2. Hazard(s) identification
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Organic peroxides Type D

Acute oral toxicity Category 4
Skin Corrosion/Irritation Category 1 C
Serious Eye Damage/Eye Irritation Category 1
Skin Sensitization Category 1
Specific target organ toxicity (single exposure) Category 3
Target Organs - Respiratory system.

Label Elements

Signal Word
Danger

Hazard Statements

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Heating may cause a fire

Harmful if swallowed
Causes severe skin burns and eye damage
May cause respiratory irritation
May cause an allergic skin reaction

Precautionary Statements
Prevention
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Do not breathe dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection
Contaminated work clothing should not be allowed out of the workplace
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep/Store away from clothing/ other combustible materials
Keep only in original container
Response
Immediately call a POISON CENTER or doctor/physician
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Skin
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
If skin irritation or rash occurs: Get medical advice/attention
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Ingestion
Rinse mouth
Do NOT induce vomiting
Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Store at temperatures not exceeding 35 °C/ 95 °F. Keep cool
Protect from sunlight
Store away from other materials
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Very toxic to aquatic life with long lasting effects

3. Composition/Information on Ingredients
Component CAS No Weight %
3-Chloroperoxybenzoic acid 937-14-4 70-76
Water 7732-18-5 >17
Benzoic acid, 3-chloro- 535-80-8 <20

4. First-aid measures

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General Advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Immediate medical attention is required. Keep eye wide open while rinsing.

Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Call a physician immediately.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. Call a physician or poison
control center immediately. Do not use mouth-to-mouth method if victim ingested or inhaled
the substance; give artificial respiration with the aid of a pocket mask equipped with a
one-way valve or other proper respiratory medical device.

Ingestion Immediate medical attention is required. Do NOT induce vomiting. Drink plenty of water.
Never give anything by mouth to an unconscious person.

Most important symptoms and Causes burns by all exposure routes. May cause allergic skin reaction. Product is a
effects corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation
of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe
damage to the delicate tissue and danger of perforation: Symptoms of allergic reaction may
include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness,
lightheadedness, chest pain, muscle pain or flushing
Notes to Physician Treat symptomatically

5. Fire-fighting measures

Suitable Extinguishing Media CO 2, dry chemical, dry sand, alcohol-resistant foam.

Unsuitable Extinguishing Media No information available

Flash Point Not applicable

Method - No information available

Autoignition Temperature No information available

Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available

Specific Hazards Arising from the Chemical

The product causes burns of eyes, skin and mucous membranes. Do not allow run-off from fire-fighting to enter drains or water
courses.

Hazardous Combustion Products

Carbon monoxide (CO). Carbon dioxide (CO2). Hydrogen chloride gas.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

NFPA
Health Flammability Instability Physical hazards
3 1 3 OX

6. Accidental release measures

Personal Precautions Use personal protective equipment as required. Evacuate personnel to safe areas. Avoid
contact with skin, eyes or clothing.

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Environmental Precautions Do not flush into surface water or sanitary sewer system. Do not allow material to
contaminate ground water system. Prevent product from entering drains. Local authorities
should be advised if significant spillages cannot be contained.

Methods for Containment and Clean Sweep up and shovel into suitable containers for disposal. Avoid dust formation.
Up

7. Handling and storage

Handling Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on
clothing. Use only under a chemical fume hood. Do not breathe dust. Do not ingest. If
swallowed then seek immediate medical assistance.

Storage. Keep refrigerated. Keep containers tightly closed in a dry, cool and well-ventilated place. Do
not store near combustible materials. Corrosives area. Incompatible Materials. Reducing
Agent. Combustible material. Strong bases.

8. Exposure controls / personal protection

Exposure Guidelines This product does not contain any hazardous materials with occupational exposure
limitsestablished by the region specific regulatory bodies.

Engineering Measures Use only under a chemical fume hood. Ensure that eyewash stations and safety showers
are close to the workstation location.

Personal Protective Equipment

Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166. Tight sealing safety goggles. Face protection shield.

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.

Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

9. Physical and chemical properties

Physical State paste Solid
Appearance Off-white
Odor Slight
Odor Threshold No information available
pH 4.5 sat.aq.sol
Melting Point/Range 92 - 94 °C / 197.6 - 201.2 °F
Boiling Point/Range 264 °C / 507.2 °F
Flash Point Not applicable
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure 23 hPa @ 20 °C
Vapor Density Not applicable
Density 0.56
Specific Gravity No information available
Solubility slightly soluble

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Partition coefficient; n-octanol/water No data available

Autoignition Temperature No information available
Decomposition Temperature > 88°C
Viscosity Not applicable
Molecular Formula C7 H5 Cl O3
Molecular Weight 172.57
Self-Accelerating Decomposition Temperature (SADT) 55°C

10. Stability and reactivity

Reactive Hazard Yes

Stability Stable under normal conditions. Organic peroxide. Hazardous decomposition may occur.

Conditions to Avoid Incompatible products. Excess heat. Temperatures above 35°C - SADT = 55°C.

Incompatible Materials Reducing Agent, Combustible material, Strong bases

Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Hydrogen chloride gas

Hazardous Polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

11. Toxicological information

Acute Toxicity

Product Information
Oral LD50 Category 4. ATE = 300 - 2000 mg/kg.
Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg.
Mist LC50 Based on ATE data, the classification criteria are not met. ATE > 5 mg/l.
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
3-Chloroperoxybenzoic acid 1807 mg/kg (Rat) Not listed Not listed
Water - - -
Toxicologically Synergistic No information available
Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure

Irritation Causes burns by all exposure routes

Sensitization No information available

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Component CAS No IARC NTP ACGIH OSHA Mexico

3-Chloroperoxybenzoi 937-14-4 Not listed Not listed Not listed Not listed Not listed
c acid
Water 7732-18-5 Not listed Not listed Not listed Not listed Not listed
Benzoic acid, 3-chloro- 535-80-8 Not listed Not listed Not listed Not listed Not listed
Mutagenic Effects No information available

Reproductive Effects No information available.

Developmental Effects No information available.

Teratogenicity No information available.

STOT - single exposure Respiratory system

STOT - repeated exposure None known

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Aspiration hazard No information available

Symptoms / effects,both acute and Product is a corrosive material. Use of gastric lavage or emesis is contraindicated.
delayed Possible perforation of stomach or esophagus should be investigated: Ingestion causes
severe swelling, severe damage to the delicate tissue and danger of perforation: Symptoms
of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the
hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing

Endocrine Disruptor Information No information available

Other Adverse Effects The toxicological properties have not been fully investigated.

12. Ecological information

Ecotoxicity
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following
substances which are hazardous for the environment.

Component Freshwater Algae Freshwater Fish Microtox Water Flea

3-Chloroperoxybenzoic acid EC50 (72h): 0.49 mg/l LC50 (96h): 0.45 mg/l Not listed Not listed
(Pseudokirchneriella (Cyprinus carpio) OECD
subcapitata) OECD Guideline 203
Guideline 201
Persistence and Degradability May persist based on information available.

Bioaccumulation/ Accumulation No information available.

Mobility . Is not likely mobile in the environment due its low water solubility.

Component log Pow

3-Chloroperoxybenzoic acid 1.03
Benzoic acid, 3-chloro- 2.7

13. Disposal considerations

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.

14. Transport information

DOT
UN-No UN3106
Proper Shipping Name ORGANIC PEROXIDE TYPE D, SOLID
Technical Name 3-Chloroperoxybenzoic acid
Hazard Class 5.2
TDG
UN-No UN3106
Proper Shipping Name ORGANIC PEROXIDE TYPE D, SOLID
Hazard Class 5.2
Packing Group II
IATA
UN-No UN3106
Proper Shipping Name ORGANIC PEROXIDE TYPE D, SOLID (3-Chloroperoxybenzoic acid)
Hazard Class 5.2
IMDG/IMO
UN-No UN3106
Proper Shipping Name ORGANIC PEROXIDE TYPE D, SOLID (3-CHLOROPEROXYBENZOIC ACID)
Hazard Class 5.2
15. Regulatory information

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United States of America Inventory

Component CAS No TSCA TSCA Inventory notification - TSCA - EPA Regulatory

Active-Inactive Flags
3-Chloroperoxybenzoic acid 937-14-4 X ACTIVE -
Water 7732-18-5 X ACTIVE -
Benzoic acid, 3-chloro- 535-80-8 X ACTIVE -

Legend:
TSCA US EPA (TSCA) - Toxic Substances Control Act, (40 CFR Part 710)
X - Listed
'-' - Not Listed

TSCA 12(b) - Notices of Export Not applicable

International Inventories
Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), China (IECSC), Korea
(KECL).

Component CAS No DSL NDSL EINECS PICCS ENCS ISHL AICS IECSC KECL
3-Chloroperoxybenzoic acid 937-14-4 X - 213-322-3 X X X X - KE-05526
Water 7732-18-5 X - 231-791-2 X X X X KE-35400
Benzoic acid, 3-chloro- 535-80-8 X - 208-618-4 X X X X X -

KECL - NIER number or KE number (http://ncis.nier.go.kr/en/main.do)

U.S. Federal Regulations

SARA 313 Not applicable

SARA 311/312 Hazard Categories See section 2 for more information

CWA (Clean Water Act) Not applicable

Clean Air Act Not applicable

OSHA - Occupational Safety and Not applicable

Health Administration

CERCLA Not applicable

California Proposition 65 This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know

Regulations

Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island

Water - - X - -

U.S. Department of Transportation

Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N

U.S. Department of Homeland This product does not contain any DHS chemicals.
Security

Other International Regulations

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Mexico - Grade No information available

Authorisation/Restrictions according to EU REACH

Safety, health and environmental regulations/legislation specific for the substance or mixture

Component CAS No OECD HPV Persistent Organic Ozone Depletion Restriction of

Pollutant Potential Hazardous
Substances (RoHS)
3-Chloroperoxybenzoic acid 937-14-4 Not applicable Not applicable Not applicable Not applicable
Water 7732-18-5 Listed Not applicable Not applicable Not applicable
Benzoic acid, 3-chloro- 535-80-8 Not applicable Not applicable Not applicable Not applicable

Component CAS No Seveso III Directive Seveso III Directive Rotterdam Basel Convention
(2012/18/EC) - (2012/18/EC) - Convention (PIC) (Hazardous Waste)
Qualifying Quantities Qualifying Quantities
for Major Accident for Safety Report
Notification Requirements
3-Chloroperoxybenzoic acid 937-14-4 Not applicable Not applicable Not applicable Not applicable
Water 7732-18-5 Not applicable Not applicable Not applicable Not applicable
Benzoic acid, 3-chloro- 535-80-8 Not applicable Not applicable Not applicable Not applicable

16. Other information

Prepared By Regulatory Affairs
Thermo Fisher Scientific
Email: EMSDS.RA@thermofisher.com

Creation Date 23-Jan-2009

Revision Date 24-Dec-2021
Print Date 24-Dec-2021
Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standard
replacing the current legislation under 29 CFR 1910.1200 to align with the Globally
Harmonized System of Classification and Labeling of Chemicals (GHS).

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text

End of SDS

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