DENSO PROTAL 7200 PART B SDS GHS REV 024_psm2djn6

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SAFETY DATA SHEET

According to 29 CFR 1910.1200(g)

PROTAL 7200 PART B (HARDENER)


SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name Protal 7200 Part B (Hardener)
1.2. Relevant identified uses of the substance or mixture and uses advised against
Product Use Industrial use as a protective coating in prevention of corrosion.
Restricted Use Not intended for use by general public.
1.3. Details of the supplier of the safety data sheet
Company Denso North America
Address 9747 Whithorn Drive
Houston, TX 77095
Web www.densona.com
Telephone 1 (281) 821‐3355
Fax 1 (281) 821‐0304
Email info@densona.com
1.4. Emergency telephone number
Emergency telephone 1‐801‐629‐0667
number (24 Hour)
SECTION 2: Hazards Identification
2.1. Classification of the substance or mixture
2.1.1. Health Skin Irritation – Category 1
Eye Damage – Category 1
Skin Sensitizer – Category 1
STOT Repeat – Category 2 Inhalation, Ingestion, Contact (Liver, Lungs, Skin, Eyes)

2.1.2. Environmental Acute aquatic toxicity – Category 3

2.1.3. Physical None

2.2. Label elements


Hazard pictograms

Signal Word Danger

Hazard statement H302 – Harmful if swallowed.


H314 – Causes skin severe skin burns and eye damage.
H317 – May cause an allergic skin reaction.
H318 – Causes serious eye damage.
H335 – May cause respiratory irritation.
H373 – May cause damage to organs (Liver, Lungs, Skin, Eyes) through prolonged or
PROTAL 7200 PART B (HARDENER) Page 1 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

repeated exposure if inhaled, swallowed, contacted.


H411 – Toxic to aquatic life with long‐lasting effects.

Precautionary Statement: P102 – Keep out of reach of children.


Prevention P202 – Do not handle until all safety precautions have been read and understood
P233 – Keep container tightly closed.
P234 – Keep only in original container.
P235 – Store in a well ventilated place. Keep cool.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P262 – Do not get in eyes, on skin, or on clothing.
P264 – Wash thoroughly after handling.
P270 – Do not eat, drink, or smoke when using this product.
P271 – Use only outdoors or in a well‐ventilated area.
P272 – Contaminated work clothing should not be allowed out of the workplace.
P273 – Avoid release to the environment.
P280 – Wear protective gloves/protective clothing/eye protection/face protection.
P284 – In case of inadequate ventilation, wear respiratory protection.

Precautionary Statement: P301+P310 – IF SWALLOWED: Immediately call a POISON CENTER or doctor/


Response physician.
P302+P352 – IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
P304+P340 – IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P314 – Get medical advice / attention if you feel unwell.
P331 – Do not induce vomiting.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P363 – Wash contaminated clothing before reuse.
P391 – Collect spillage.

Precautionary Statement: P501 – Dispose of contents/container in accordance with local/regional/national/


Disposal international regulations.
SECTION 3: Composition/information on ingredients
3.1. Substances
Chemical Name CAS No. Concentration (%w/w) Classification
N‐Aminoethylpiperazine 140‐31‐8 40‐70% Skin Irr 2; H315
Eye Irr 2; H319
Aqua Acute/Chronic 2; H411
4,4'‐Isopropylidene‐diphenol 80‐05‐7 1‐10% (1) (2)
Reaction product: bisphenol‐ 28064‐14‐4 5‐20% Skin Irr 2; H315
F‐ epichlorohydrin Eye Irr 2; H319
Skin Sens 1; H317
PROTAL 7200 PART B (HARDENER) Page 2 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

Aqua Chronic 2; H411


Reaction product: bisphenol‐ 25068‐38‐6 5‐20% Xi; R36/38, 43
A‐ (epichlorohydrin); epoxy N; R51/53
resin (number average
molecular weight < 700)
4‐Nonyl phenol, branched 84852‐15‐3 1‐5% Skin Irr 2; H315
Eye Irr 2; H319
Aqua Acute/Chronic 1; H411

NOTES: (1) Substance classified with a health or environmental hazard.


(2) Substance with a workplace exposure limit.

SECTION 4: First aid measures


4.1. General advice Seek medical advice. If breathing has stopped or is labored, give assisted respirations.
Supplemental oxygen may be indicated. If the heart has stopped, trained personnel
should begin cardiopulmonary resuscitation immediately.

4.2. Eye contact Immediately flush eyes with plenty of water for at least 15 minute, occasionally lifting
the upper and lower eyelids. Check for and remove any contact lenses. Get medical
attention.

4.3. Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or
wear gloves. Continue to rinse for at least 10 minutes. In the event of any complaints
or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes
thoroughly before reuse. For contact with hot product, flush contaminated skin with
large amounts of cold water to dissipate heat. Cover with clean cotton sheeting or
gauze. Get medical attention immediately.

4.4. Ingestion Wash out mouth with water. Remove dentures, if any. Move exposed person to
fresh air. Keep person warm and at rest. If material has been swallowed and the
exposure person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention if adverse
health effects persist or are severe. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband.

4.5 Inhalation Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if
breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. It may be dangerous to the person providing aid to give
mouth‐to‐mouth resuscitation. Get medical attention if adverse health effects persist
or are severe. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
PROTAL 7200 PART B (HARDENER) Page 3 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

belt, or waistband.

4.6. Most important symptoms and effects, both acute and delayed
Eye contact Corrosive to the eyes and may cause severe damage including blindness. Causes
permanent eye injury. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva.

Skin contact Corrosive. Contact may cause severe burns to skin. Symptoms may include redness,
edema, drying, defatting and cracking of the skin. May cause allergic skin reaction or
sensitization.

Ingestion Harmful if swallowed. May produce burns to the lips, oral cavity, upper airway,
esophagus and possibly the digestive tract. May cause abdominal pain, nausea,
vomiting, or diarrhea.

Inhalation High vapor concentrations are irritating to the eyes, nose, throat, and lungs. May
cause irritation to respiratory system with throat discomfort, coughing or difficulty
breathing.

SECTION 5: Firefighting measures


5.1. Suitable extinguishing Alcohol‐resistant foam, Carbon dioxide (CO2), Dry chemical, or water spray. Do not
media use a solid water stream as it may scatter and spread fire.

5.2. Specific hazards Decomposition products may include the following materials: carbon oxides; nitrogen
oxides. Downwind personnel must be evacuated. Burning produces noxious and
toxic fumes.

5.3. Special protective Avoid contact with skin. Fire‐fighters should wear appropriate personal protective
equipment for fire‐fighters equipment and self‐contained breathing apparatus (SCBA) with a full face‐piece
operated in positive pressure mode.

5.4. Further information Do not allow run‐off from fire‐fighting to enter drains or water courses.

SECTION 6: Accidental release measures


6.1. Personal precautions No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled materials. Avoid breathing vapor or
mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see Section 8).

6.2. Environmental Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains,
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

6.3. Methods for cleaning up Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Use absorbent with inert
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MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

material. Vacuum or sweep up material and place in a designated, labeled waste


container. Dispose of via a licensed, waste‐disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.

6.4. Additional advice Stop leak if without risk.

SECTION 7: Handling and storage


7.1. Handling Put on appropriate personal protective equipment (see Section 8). Eating, drinking
and smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking or smoking.
Persons with a history of skin sensitization problems should not be employed in any
process in which this product is used. Do not get in eyes or on skin or clothing. Do
not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Keep in the original container
or an approved alternative made from a compatible material, kept tightly closed
when not in use. Empty containers retain product residue and can be hazardous. Do
not reuse container.

7.2. Storage Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well‐ventilated area, away from incompatible
materials (see Section 10) and food and drink. Keep aware from heat, sparks, and
flames. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage.
Do not store in unlabeled containers. Use appropriate containment to avoid
environmental contamination.

7.3. Technical precautions Do not store in reactive metal containers.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters
8.1.1. Exposure Limit Values CAS No. ACGIH TLV
140‐31‐8 None established
80‐05‐7 5 mg/m3 (dust)
28064‐14‐4 None established
25068‐38‐6 None established
84852‐15‐3 None established

8.2. Control measures / Personal Protection


8.2.1. Recommended To meet the exposure limits for the materials listed above, personal workplace
monitoring procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment.

8.2.2. Engineering measures Use only with adequate ventilation. If user operations generate dust, fumes, gas,
vapor or mist, use process enclosures, local exhaust ventilation or other engineering
PROTAL 7200 PART B (HARDENER) Page 5 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

controls to keep worker exposure to airborne contaminants below any recommended


or statutory limits.

8.2.3. Hygiene measures Wash hands, forearms, and face after handling chemical products, before eating,
smoking or using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing or discard as necessary. Ensure that eyewash
stations/bottles with pure water and safety showers are close to the workstation
location.

8.2.4. Respiratory protection Use a properly fitted, air‐purifying or air‐fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator. Select equipment to provide protection
from the ingredients in Section 3 of this document.

8.2.5. Eye protection Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. This may include, but is not limited to, safety glasses, goggles and face
shields.

8.2.6. Skin protection Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist before
handling this product. This equipment may include, but is not limited to, impervious
gloves, gauntlets, impervious shoes/boots, and protective clothing. The breakthrough
time of the selected protective glove(s), shoes and clothing must be greater than the
intended use period.

8.2.7. Environmental Emissions from ventilation or work process equipment should be checked to ensure
exposure controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels. Environmental exposure
controls may also include dikes or other liquid containment devices.

SECTION 9: Physical and chemical properties


Form Liquid Vapor Pressure ND
Color Green Relative vapor density >1
Odor Irritating Relative density 1.08
Odor threshold ND Water solubility Slight
pH about 10 Partition coefficient (n‐octanol/water) ND
Freezing point ND Auto‐ignition temperature ND
Boiling point ND Decomposition temperature ND
Flash Point ND Viscosity 5,500 cP @ 73oF (22oC)
Evaporation rate N/A Oxidizing N/A
Flammable Limits ND Explosion Limits ND

PROTAL 7200 PART B (HARDENER) Page 6 of 15 Print Date: 26 October 2015


MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

SECTION 10: Stability and reactivity


10.1 Stability The product is stable. Under normal conditions of storage and use, hazardous
polymerization will not occur.

10.2. Conditions to avoid May burn but does not ignite readily. When heated, vapors may form explosive
mixtures with air. Containers may explode when heated.

10.3. Materials to avoid Reactive or incompatible with the following materials: Strong oxidizing agents, acids,
alcohols, cresol, glycol, isocyanates, phenol, vinyl acetates, strong bases

10.4. Other hazards Reacts with considerable heat release.

10.5. Hazardous Decomposition products may include the following materials: Carbon oxides,
decomposition products Nitrogen oxides, Ammonia, Toxic/Noxious fumes

SECTION 11: Toxicological information


11.1. Acute health hazard Product:
Acute oral toxicity: ND
Acute dermal toxicity: ND
Components:
140‐31‐8
Acute oral toxicity: LD50 (rabbit): 2097 mg/kg
Acute dermal toxicity: LD50 (rabbit): 866 mg/kg

80‐05‐7
Acute oral toxicity: LD50 (rat): 3,250 mg/kg
Acute dermal toxicity: LD50 (rabbit): 3,000 mg/kg

28064‐14‐4
Acute oral toxicity: LD50 (rat): >2,000 mg/kg
Acute dermal toxicity: LD50 (rabbit): >2,000 mg/kg

25068‐38‐6
Acute oral toxicity: LD50 (rat): 30,000 mg/kg
Acute dermal toxicity: LD50 (rat): >1,200 mg/kg

84852‐15‐3
Acute oral toxicity: LD50 (rat): 580 mg/kg
Acute dermal toxicity: LD50 (rabbit): 2,031 mg/kg

11.2. Skin corrosion or Product: No data available, but may cause skin irritation or burns based on
irritation components present.
Components:
140‐31‐8 adult rabbit corrosive to skin
28064‐14‐4 adult rabbit slight to moderate irritation to skin
25068‐38‐6 adult rabbit slight to moderate irritation to skin
PROTAL 7200 PART B (HARDENER) Page 7 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

84852‐15‐3 rabbit severe irritation and burns

No skin irritation data available or sufficient for classification for other components
present.

11.3. Serious eye damage or Product: No data available, but likely to be corrosive to eyes and may cause severe
irritation damage including blindness based on components present.
Components:
140‐31‐8 adult rabbit corrosive to eyes
28064‐14‐4 adult rabbit slightly irritating
25068‐38‐6 adult rabbit slightly irritating
84852‐15‐3 rabbit severe irritation and burns

No eye irritation data available or sufficient for classification for other components
present.

11.4. Respiratory or skin Product: No data available, but may cause skin sensitization in susceptible persons
sensitization based on components present. Once sensitized, a severe allergic reaction may occur
when subsequently exposed to very low levels. May aggravate pre‐existing skin
conditions like dermatitis.
Components:
140‐31‐8 adult guinea pig Causes skin sensitization
28064‐14‐4 adult guinea pig Causes skin sensitization
25068‐38‐6 adult guinea pig Causes skin sensitization

No sensitization data available or sufficient for classification for other components


present.

11.5. Germ cell mutagenicity Product: No data available, but not likely to be mutagenic based on components.
Components: None of the components is known to have significant mutagenic effect.

11.6. Carcinogenicity Product: No data available.


Components: None of the components is classified as a carcinogen.

11.7. Reproductive toxicity Product: No data available.


Components: None of the components is known to have significant reproductive
effects,

11.8. STOT – single exposure Product: No data available, but irritation, sensitization and/or burns to respiratory
system, skin, and eyes are likely– Lungs, Skin, and Eyes. Once sensitized, a severe
allergic reaction may occur when subsequently exposed to very low levels. May
aggravate pre‐existing skin conditions like dermatitis.
Components: See Sections 11.2, 11.3, and 11.4 for specific information regarding the
effects of the components.

11.9. STOT – repeated Product: No data available, but, based on components, may cause damage to organs
PROTAL 7200 PART B (HARDENER) Page 8 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

exposure through prolonged or repeated exposure – Liver, Lungs, Skin, and Eyes.

11.10. Repeated dose toxicity Product: No data available, but, based on components, Causes skin and eye irritation,
damage, burns. Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels. May aggravate pre‐existing skin conditions
like dermatitis. Changes to the liver, lungs, skin and eyes are also possible.

11.11. Aspiration toxicity Product: Not determined.


Components: Not determined.

11.12. Further information Likely routes of exposure – inhalation; skin and eye contact.

SECTION 12: Ecological information


12.1. Ecotoxicity Product: No data available, but likely to be toxic to aquatic life based on components
present.
Components:
140‐31‐8
Toxicity to fish – 96 h LC50: >100 mg/L
Toxicity to daphnia and other aquatic invertebrates – 48 h
LC50: 32 mg/L
Toxicity to algae – 72 h LC50: >1,000 mg/L

80‐05‐7
Toxicity to fish – 96 h LC50: 4.6 mg/L

28064‐14‐4
Toxicity to fish – 96 h LC50: >1‐10 mg/L Test Type: Similar material
Toxicity to daphnia and other aquatic invertebrates – 48 h
EC50: >1‐10 mg/L Test Type: Similar material
Toxicity to algae EC50: ND

25068‐38‐6
Toxicity to fish – 96 h LC50: 3.1 mg/L Test type: Fathead minnow
Toxicity to daphnia and other aquatic invertebrates – 48 h
LC50: 1.3 mg/L

84852‐15‐3
Toxicity to fish – 96 h static LC50: 0.05 mg/L
Toxicity to daphnia and other aquatic invertebrates – 48 h static
EC50: 0.085 mg/L
Toxicity to algae – 96 h ErC50: 0.41 mg/L

12.2. Persistence and Product: No data available


degradability Components:
140‐31‐8 <60% after 28 days.
28064‐14‐4 Not readily biodegradable.
PROTAL 7200 PART B (HARDENER) Page 9 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

25068‐38‐6 12% after 28 days.


84852‐15‐3 100% after 63 days.

12.3. Bioaccumulative Product: No data available


potential Components: Not determined.

12.4. Mobility in soil Product: Not determined.


Components: Not determined.

12.5. Other adverse effects Product: Not determined. An environmental hazard cannot be excluded in the event
of unprofessional handling or disposal, toxic to aquatic life.
Components: No data available

SECTION 13: Disposal considerations


13.1. Waste disposal The generation of waste should be avoided or minimized wherever possible. Dispose
of surplus and non‐recyclable products via a licensed waste disposal contractor.
Disposal of this product, solutions and any by‐products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional and local authority requirements. Avoid disposal of spilled material and
runoff and contaminated soils in waterways, drains or sewers. Dispose of
contaminated containers, soils, etc. in compliance with the requirements of
environmental protection and waste disposal legislation and any regional and local
authority requirements. Empty any remaining contents from packaging prior to
disposal and dispose of as unused product. Do not reuse empty containers.

SECTION 14: Transport information

14.1. UN number UN3066

14.2. UN proper shipping PAINT


name

14.3. Transport hazard class


International Carriage of
Dangerous Good by
Road/Rail ADR/RID: 8
International Maritime
Dangerous Goods IMDG: 8
International Air Transport

PROTAL 7200 PART B (HARDENER) Page 10 of 15 Print Date: 26 October 2015


MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

Association IATA: 8
US Code of Federal
Regulations CFR 8
Canadian Transportation of
Dangerous Goods TDG: 8
US Department of
Transportation DOT: 8

14.4. Packing group II

14.5. Environmental hazards Environmental hazards: Yes Marine pollutant: Yes


IMDG
EmS Code: F‐A S‐B
IATA
Packing Instruction (Cargo): 855 Maximum quantity: 30 L
Packing instruction (Passenger): 851 Maximum quantity: 1L

SECTION 15: Regulatory information


15.1. OSHA Hazards Irritant, Sensitizer, Corrosive

15.2. CERCLA Reportable Components CAS No. Component RQ Product RQ


Quantity None

15.3. SARA 314 Extremely This material does not contain any components with a section 314 Extremely
Hazardous Substances Hazardous Substances RQ.
Reportable Quantity

15.4. SARA 311/312 Hazards Acute health hazard, Chronic health hazard

15.5. SARA Title III, Section No chemicals in this material are subject to the reporting requirements of SARA Title
302 Reporting III, Section 302.

15.6. SARA Title III, Section The following chemicals in this material are subject to the reporting requirements of
313 Reporting SARA Title III, Section 313: 4,4'‐Isopropylidenediphenol

15.7. Clean Air Act The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12
(40 CFR 61): None.

This product does not contain any chemicals listed under the U.S. Clean Air Act
Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).

The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI
Intermediate or Final VOC’s (40 CFR 60.489): None.

15.8. Clean Water Act The following Hazardous Substances are listed under the U.S. Clean Water Act,
Section 311, Table 116.4A: None.
PROTAL 7200 PART B (HARDENER) Page 11 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

The following Hazardous Substances are listed under the U.S. Clean Water Act,
Section 311, Table 117.3: None.

This product contains the following toxic pollutants listed under the U.S. Clean Water
Act, Section 307: None.

15.9. US State Regulations Massachusetts Right‐To‐Know


4,4'‐Isopropylidenediphenol
Pennsylvania Right‐To‐Know
4,4'‐Isopropylidenediphenol
New Jersey Right‐To‐Know
4,4'‐Isopropylidenediphenol

California Prop 65
This product contains no chemicals known to the State of California to cause cancer.
This product contains no chemicals known to the State of California to cause birth
defects or other reproductive harm.

15.10. International Chemical Inventory Listing


TSCA (US) Yes (All components of this product are on US inventory)
DSL (Canada) Yes (All components of this product are on Canadian inventory)
AICS (Australia) Yes (On Australian inventory or in compliance with inventory)
ICS (New Zealand) Yes (On New Zealand inventory or in compliance with inventory)
ENCS (Japan) Yes (On Japanese inventory or in compliance with inventory)
ISHL (Japan) Yes (On Japanese inventory or in compliance with inventory)
KECI (Korea) Yes (On Korean inventory or in compliance with inventory)
PICCS (Philippines) Yes (On Philippine inventory or in compliance with inventory)
IECSC (China) Yes (On Chinese inventory or in compliance with inventory)

15.11. WHMIS Hazard Classification (Canada)


Class D‐2B: Material causing other toxic effects (Toxic).
Canadian NPRI: None required.

SECTION 16: Other information


16.1. NFPA
1
3 1
ALK

PROTAL 7200 PART B (HARDENER) Page 12 of 15 Print Date: 26 October 2015


MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

16.2. HMIS®

Caution: HMIS ratings are based on a 0‐4 rating scale, with 0 representing minimal
hazards or risks, and 4 representing significant hazards or risks. Although HMIS
ratings are not required on SDS’s under 29 CFR 1910.1200, the preparer may choose
to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association
(NPCA). HMIS materials may be purchased exclusively from J.J. Keller (800) 327‐6868.
The customer is responsible for determining the PPE code for this material.

16.3. Text of Risk phrases in R36/38 – Irritating to eyes and skin.


Section 3 R43 – May cause sensitization by skin contact.
R51/53 – Toxic to aquatic organisms, may cause long‐term adverse effects in the
aquatic environment.

16.4. Text of Hazard H302 – Harmful if swallowed.


statements in Section 3 H314 – Causes skin severe skin burns and eye damage.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H318 – Causes serious eye damage.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H373 – May cause damage to organs through prolonged or repeated exposure.
H411 – Toxic to aquatic life with long‐lasting effects.

16.5. Notice to Reader The information provided herein was believed by Denso North America (“Denso”) to
be accurate at the time of preparation and prepared from sources believed to be
reliable, but it is the responsibility of the user to investigate and understand other
pertinent sources of information, to comply with all laws and procedures applicable
to the safe handling and use of the product and to determine the suitability of the
product for its intended use. All products supplied by Denso are subject to Denso’s
terms and conditions of sale. DENSO MAKES NO WARRANTY, EXPRESS OR IMPLIED,
CONCERNING THE PRODUCT OR THE MECHANTABILITY OR FITNESS THEREOF FOR
ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY
DENSO, except that the product shall conform to Denso’s specifications. Nothing
contained herein constitutes an offer for the sale of any product.

16.6. Key/Legend to ACGIH American Conference Government Industrial Hygienists


abbreviations and acronyms ADR European Agreement for International Carriage of Dangerous Materials Road
used in the safety data sheet AICS Australia, Inventory of Chemical Substances
PROTAL 7200 PART B (HARDENER) Page 13 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

DSL Canada, Domestic Substances List


NDSL Canada, Non‐Domestic Substances List
CAS Chemical Abstract Service
CNS Central Nervous System
DOT Department of Transportation
EC50 Effective Concentration 50%
EGEST EOSCA Generic Exposure Scenario Tool
EOSCA European Oilfield Specialty Chemicals Association
EINECSEuropean Inventory of Existing Chemical Substances
ENCS Japan, Inventory Existing and New Chemical Substances
GHS Global Harmonization System
HMIS Hazardous Materials Identification System
IARC International Agency for Research on Cancer
IATA International Air Transport Association
IC50 Inhibition Concentration 50%
IECSC Inventory of Existing Chemical Substances in China
IMDG International Maritime Dangerous Goods
KECI Korea, Existing Chemical Inventory
LC50 Lethal Concentration 50%
LD50 Lethal Dose 50%
LOAEL Lowest Observed Adverse Effect Level
MAK Germany Maximum Concentration Values
N/A Not Available
ND Not Determined
NFPA National Fire Protection Agency
NIOSH National Institute for Occupational Safety & Health
NOAEL No Observable Adverse Effect Level
NOEC No Observed Effect Concentration
NTP National Toxicology Program
NZIoC New Zealand Inventory of Chemicals
OSHA Occupational Safety & Health Administration
PEL Permissible Exposure Limit
PICCS Philippines Inventory Commercial Chemical Substances
PRNT Presumed Not Toxic
RCRA Resource Conservation Recovery Act
RID European Agreement for International Carriage of Dangerous Materials Rail
RQ Reportable Quantity
SARA Superfund Amendments and Reauthorization Act
STEL Short‐Term Exposure Limit
TDG Transportation of Dangerous Goods (Canada)
TLV Threshold Limit Value
TSCA Toxic Substance Control Act
TWA Time Weighted Average
UVCB Unknown or Variable Composition, Complex Reaction Products, and Biological
Materials
WHMIS Workplace Hazardous Materials Information System
PROTAL 7200 PART B (HARDENER) Page 14 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)

16.7. Prepared by Denso EH & S Department

16.8. Telephone 1‐281‐821‐3355 Corporate


1‐801‐629‐0667 Emergency (24 hour)

PROTAL 7200 PART B (HARDENER) Page 15 of 15 Print Date: 26 October 2015


MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015

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