DENSO PROTAL 7200 PART B SDS GHS REV 024_psm2djn6
DENSO PROTAL 7200 PART B SDS GHS REV 024_psm2djn6
DENSO PROTAL 7200 PART B SDS GHS REV 024_psm2djn6
4.2. Eye contact Immediately flush eyes with plenty of water for at least 15 minute, occasionally lifting
the upper and lower eyelids. Check for and remove any contact lenses. Get medical
attention.
4.3. Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or
wear gloves. Continue to rinse for at least 10 minutes. In the event of any complaints
or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes
thoroughly before reuse. For contact with hot product, flush contaminated skin with
large amounts of cold water to dissipate heat. Cover with clean cotton sheeting or
gauze. Get medical attention immediately.
4.4. Ingestion Wash out mouth with water. Remove dentures, if any. Move exposed person to
fresh air. Keep person warm and at rest. If material has been swallowed and the
exposure person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention if adverse
health effects persist or are severe. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband.
4.5 Inhalation Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if
breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. It may be dangerous to the person providing aid to give
mouth‐to‐mouth resuscitation. Get medical attention if adverse health effects persist
or are severe. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
PROTAL 7200 PART B (HARDENER) Page 3 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)
belt, or waistband.
4.6. Most important symptoms and effects, both acute and delayed
Eye contact Corrosive to the eyes and may cause severe damage including blindness. Causes
permanent eye injury. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva.
Skin contact Corrosive. Contact may cause severe burns to skin. Symptoms may include redness,
edema, drying, defatting and cracking of the skin. May cause allergic skin reaction or
sensitization.
Ingestion Harmful if swallowed. May produce burns to the lips, oral cavity, upper airway,
esophagus and possibly the digestive tract. May cause abdominal pain, nausea,
vomiting, or diarrhea.
Inhalation High vapor concentrations are irritating to the eyes, nose, throat, and lungs. May
cause irritation to respiratory system with throat discomfort, coughing or difficulty
breathing.
5.2. Specific hazards Decomposition products may include the following materials: carbon oxides; nitrogen
oxides. Downwind personnel must be evacuated. Burning produces noxious and
toxic fumes.
5.3. Special protective Avoid contact with skin. Fire‐fighters should wear appropriate personal protective
equipment for fire‐fighters equipment and self‐contained breathing apparatus (SCBA) with a full face‐piece
operated in positive pressure mode.
5.4. Further information Do not allow run‐off from fire‐fighting to enter drains or water courses.
6.2. Environmental Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains,
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
6.3. Methods for cleaning up Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Use absorbent with inert
PROTAL 7200 PART B (HARDENER) Page 4 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)
7.2. Storage Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well‐ventilated area, away from incompatible
materials (see Section 10) and food and drink. Keep aware from heat, sparks, and
flames. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage.
Do not store in unlabeled containers. Use appropriate containment to avoid
environmental contamination.
8.2.2. Engineering measures Use only with adequate ventilation. If user operations generate dust, fumes, gas,
vapor or mist, use process enclosures, local exhaust ventilation or other engineering
PROTAL 7200 PART B (HARDENER) Page 5 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)
8.2.3. Hygiene measures Wash hands, forearms, and face after handling chemical products, before eating,
smoking or using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing or discard as necessary. Ensure that eyewash
stations/bottles with pure water and safety showers are close to the workstation
location.
8.2.4. Respiratory protection Use a properly fitted, air‐purifying or air‐fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator. Select equipment to provide protection
from the ingredients in Section 3 of this document.
8.2.5. Eye protection Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. This may include, but is not limited to, safety glasses, goggles and face
shields.
8.2.6. Skin protection Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist before
handling this product. This equipment may include, but is not limited to, impervious
gloves, gauntlets, impervious shoes/boots, and protective clothing. The breakthrough
time of the selected protective glove(s), shoes and clothing must be greater than the
intended use period.
8.2.7. Environmental Emissions from ventilation or work process equipment should be checked to ensure
exposure controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels. Environmental exposure
controls may also include dikes or other liquid containment devices.
10.2. Conditions to avoid May burn but does not ignite readily. When heated, vapors may form explosive
mixtures with air. Containers may explode when heated.
10.3. Materials to avoid Reactive or incompatible with the following materials: Strong oxidizing agents, acids,
alcohols, cresol, glycol, isocyanates, phenol, vinyl acetates, strong bases
10.5. Hazardous Decomposition products may include the following materials: Carbon oxides,
decomposition products Nitrogen oxides, Ammonia, Toxic/Noxious fumes
80‐05‐7
Acute oral toxicity: LD50 (rat): 3,250 mg/kg
Acute dermal toxicity: LD50 (rabbit): 3,000 mg/kg
28064‐14‐4
Acute oral toxicity: LD50 (rat): >2,000 mg/kg
Acute dermal toxicity: LD50 (rabbit): >2,000 mg/kg
25068‐38‐6
Acute oral toxicity: LD50 (rat): 30,000 mg/kg
Acute dermal toxicity: LD50 (rat): >1,200 mg/kg
84852‐15‐3
Acute oral toxicity: LD50 (rat): 580 mg/kg
Acute dermal toxicity: LD50 (rabbit): 2,031 mg/kg
11.2. Skin corrosion or Product: No data available, but may cause skin irritation or burns based on
irritation components present.
Components:
140‐31‐8 adult rabbit corrosive to skin
28064‐14‐4 adult rabbit slight to moderate irritation to skin
25068‐38‐6 adult rabbit slight to moderate irritation to skin
PROTAL 7200 PART B (HARDENER) Page 7 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)
No skin irritation data available or sufficient for classification for other components
present.
11.3. Serious eye damage or Product: No data available, but likely to be corrosive to eyes and may cause severe
irritation damage including blindness based on components present.
Components:
140‐31‐8 adult rabbit corrosive to eyes
28064‐14‐4 adult rabbit slightly irritating
25068‐38‐6 adult rabbit slightly irritating
84852‐15‐3 rabbit severe irritation and burns
No eye irritation data available or sufficient for classification for other components
present.
11.4. Respiratory or skin Product: No data available, but may cause skin sensitization in susceptible persons
sensitization based on components present. Once sensitized, a severe allergic reaction may occur
when subsequently exposed to very low levels. May aggravate pre‐existing skin
conditions like dermatitis.
Components:
140‐31‐8 adult guinea pig Causes skin sensitization
28064‐14‐4 adult guinea pig Causes skin sensitization
25068‐38‐6 adult guinea pig Causes skin sensitization
11.5. Germ cell mutagenicity Product: No data available, but not likely to be mutagenic based on components.
Components: None of the components is known to have significant mutagenic effect.
11.8. STOT – single exposure Product: No data available, but irritation, sensitization and/or burns to respiratory
system, skin, and eyes are likely– Lungs, Skin, and Eyes. Once sensitized, a severe
allergic reaction may occur when subsequently exposed to very low levels. May
aggravate pre‐existing skin conditions like dermatitis.
Components: See Sections 11.2, 11.3, and 11.4 for specific information regarding the
effects of the components.
11.9. STOT – repeated Product: No data available, but, based on components, may cause damage to organs
PROTAL 7200 PART B (HARDENER) Page 8 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)
exposure through prolonged or repeated exposure – Liver, Lungs, Skin, and Eyes.
11.10. Repeated dose toxicity Product: No data available, but, based on components, Causes skin and eye irritation,
damage, burns. Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels. May aggravate pre‐existing skin conditions
like dermatitis. Changes to the liver, lungs, skin and eyes are also possible.
11.12. Further information Likely routes of exposure – inhalation; skin and eye contact.
80‐05‐7
Toxicity to fish – 96 h LC50: 4.6 mg/L
28064‐14‐4
Toxicity to fish – 96 h LC50: >1‐10 mg/L Test Type: Similar material
Toxicity to daphnia and other aquatic invertebrates – 48 h
EC50: >1‐10 mg/L Test Type: Similar material
Toxicity to algae EC50: ND
25068‐38‐6
Toxicity to fish – 96 h LC50: 3.1 mg/L Test type: Fathead minnow
Toxicity to daphnia and other aquatic invertebrates – 48 h
LC50: 1.3 mg/L
84852‐15‐3
Toxicity to fish – 96 h static LC50: 0.05 mg/L
Toxicity to daphnia and other aquatic invertebrates – 48 h static
EC50: 0.085 mg/L
Toxicity to algae – 96 h ErC50: 0.41 mg/L
12.5. Other adverse effects Product: Not determined. An environmental hazard cannot be excluded in the event
of unprofessional handling or disposal, toxic to aquatic life.
Components: No data available
Association IATA: 8
US Code of Federal
Regulations CFR 8
Canadian Transportation of
Dangerous Goods TDG: 8
US Department of
Transportation DOT: 8
15.3. SARA 314 Extremely This material does not contain any components with a section 314 Extremely
Hazardous Substances Hazardous Substances RQ.
Reportable Quantity
15.4. SARA 311/312 Hazards Acute health hazard, Chronic health hazard
15.5. SARA Title III, Section No chemicals in this material are subject to the reporting requirements of SARA Title
302 Reporting III, Section 302.
15.6. SARA Title III, Section The following chemicals in this material are subject to the reporting requirements of
313 Reporting SARA Title III, Section 313: 4,4'‐Isopropylidenediphenol
15.7. Clean Air Act The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12
(40 CFR 61): None.
This product does not contain any chemicals listed under the U.S. Clean Air Act
Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).
The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI
Intermediate or Final VOC’s (40 CFR 60.489): None.
15.8. Clean Water Act The following Hazardous Substances are listed under the U.S. Clean Water Act,
Section 311, Table 116.4A: None.
PROTAL 7200 PART B (HARDENER) Page 11 of 15 Print Date: 26 October 2015
MSDS: 7201 Revision Number: 2.4 Revision Date: 26 October 2015
SAFETY DATA SHEET
According to 29 CFR 1910.1200(g)
The following Hazardous Substances are listed under the U.S. Clean Water Act,
Section 311, Table 117.3: None.
This product contains the following toxic pollutants listed under the U.S. Clean Water
Act, Section 307: None.
California Prop 65
This product contains no chemicals known to the State of California to cause cancer.
This product contains no chemicals known to the State of California to cause birth
defects or other reproductive harm.
16.2. HMIS®
Caution: HMIS ratings are based on a 0‐4 rating scale, with 0 representing minimal
hazards or risks, and 4 representing significant hazards or risks. Although HMIS
ratings are not required on SDS’s under 29 CFR 1910.1200, the preparer may choose
to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association
(NPCA). HMIS materials may be purchased exclusively from J.J. Keller (800) 327‐6868.
The customer is responsible for determining the PPE code for this material.
16.5. Notice to Reader The information provided herein was believed by Denso North America (“Denso”) to
be accurate at the time of preparation and prepared from sources believed to be
reliable, but it is the responsibility of the user to investigate and understand other
pertinent sources of information, to comply with all laws and procedures applicable
to the safe handling and use of the product and to determine the suitability of the
product for its intended use. All products supplied by Denso are subject to Denso’s
terms and conditions of sale. DENSO MAKES NO WARRANTY, EXPRESS OR IMPLIED,
CONCERNING THE PRODUCT OR THE MECHANTABILITY OR FITNESS THEREOF FOR
ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY
DENSO, except that the product shall conform to Denso’s specifications. Nothing
contained herein constitutes an offer for the sale of any product.