Series HFG1E/1

प्रश्न - पत्र कोड

Q.P. Code 56/1/1

रोल. नं. परीक्षाथी प्रश्न - पत्र कोड को उतर - पुस्ततका

Roll No. के मुख - पत
ृ था पर अिश्य ललंखे ।
Candidates must write the Q.P. Code
on the title page of the answer-book.

रसायन विज्ञान(सैद्धान्तिक)
CHEMISTRY (Theory)
निर्धा रित समय : 3 घण्टे अनर्कतम अंक : 70
Time allowed: 3 hours Maximum Marks: 70

• कृपया जााँच कर लें की इस प्रश्न - पत्र में मुद्रित पष्ृ ठ 07 हे ।

• प्रश्न - पत्र में दाद्रहने हाथ की और द्रदए गए प्रश्न - पत्र कोड को परीक्षाथी उतर - पुस्ततका के
मुख - पत
ृ था पर ललंखे ।
• कृपया जााँच कर लें इस प्रश्न - पत्र में 33 प्रश्न हैं।
• कृपया प्रश्न का उतर सुरु करने से पहले , उतर - पस्ु ततका में प्रश्ना का क्रमाांक अबश्य ललखें।
• इस प्रश्न -पत्र को पढ़ने के ललए 15 लमननट का समय द्रदया गया हे । प्रश्न - पत्र का बितरण
पुिाह्ण में 12.40 िजे ककया जाएगा। 12.45 िजे से 1.00 िजे तक परीक्षाथी केिल प्रश्न - पत्र को
पढ़ें गे और इस अिधि के दौरान िे उतर - पुस्ततका पर कोई उतर नहीं ललखेंगे।
• Please check that this question paper contains 07 printed pages .
• Q.P. Code given on the right-hand side of the question paper should be written on the title page
of the answer-book by the candidate.
• Please check that this question paper contains 33 questions.
• Please write down the serial number of the question in the answer-book before attempting it.
• 15-minute time has been allotted to read this questions paper. The question paper will be
distributed at 12.40 p.m. From 12.45 p.m. to 1.00 p.m., the candidates will read the question
paper only and will not write any answer on the answer-book during this period.

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 General Instructions:
(i) There are 33 questions in this question paper with internal choice.
(ii) SECTION A consists of 16 multiple-choice questions carrying 1 mark each.
(iii) SECTION B consists of 5 very short answer questions carrying 2 marks each.
(iv) SECTION C consists of 7 short answer questions carrying 3 marks each.
(v) SECTION D consists of 2 case- based questions carrying 4 marks each.
(vi) SECTION E consists of 3 long answer questions carrying 5 marks each.
(vii) All questions are compulsory.
(viii) (viii) Use of log tables and calculators is not allowed.

SECTION- A
The following questions are multiple-choice questions with one correct answer. Each question carries 1
mark. There is no internal choice in this section:

1. The limiting equivalent conductance for weak electrolytes can be calculated by using;
(a) Faraday’s law (b)Electrolytic conductance
(c)Kohlrausch’s law (d)None of them
2. The quantity of charge required to obtain one mole of aluminium from is Al2O3
(a) 1F (b)3F (c) 6F (d) 2F

3. A first order reaction has rate constant of 10-2 S-1, The half-life for this reaction is:
(a) 69.3 sec (b)6.63 sec (c)0.693 sec (d)0. 069 sec
4. Which of the following is diamagnetic ion?
(a) Co2+ (b) Ni2+ (c) Cu2+ (d) Zn2+
5. What is the oxidation number and the coordination number of iron respectively in [Fe(C2O4)3]3-
(a) 6,3 (b) 3,6 (c) 2,6 (d) 2,4
6. The IUPAC name for [Pt(NH3)3(Br)(NO2)(Cl)]Cl is
(a) triamminechlorobromonitroplatinum(IV) chloride
(b) triamminebromochloronitroplatinum(IV) chloride
(c) triaminenitrochlorobromoplatinum(IV) chloride
(d) triamminechloronitrobromoplatinum(IV) chloride
7. Which of the reaction given below is an example of Swart Reaction
a) C2H5Cl + KOH + H2O → C2H5OH b) C2H5Br + AgF → C2H5F
c) C2H5Br + Na (dry ether) →n- butane d) CH3CH=CH2 + HBr → CH3CH(Br)CH3
8. Monochlorination of toluene in sunlight followed by hydrolysis with aq. NaOH yields
(a) o-Cresol (b) m-Cresol
(c) 2,4-Dihydroxytoluene (d) Benzyl alcohol

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9. Which of the following reagents cannot be used to oxidise primary alcohol to aldehyde?
(a) CrO3 in anhydrous medium (b) KMnO4 in acidic medium
(c) Pyridinium chlorochromate (d) Heat on the presence of copper at 573 K
10. The correct order of increasing acidic strength is _________
(a) Phenol< Ethanol < Chloroacetic acid< acetic acid
(b) Ethanol < Phenol < Chloroacetic acid< acetic acid
(c) Ethanol< Phenol < acetic acid < Chloroacetic acid
(d) acetic acid < Chloroacetic acid< Ethanol< Phenol
11. Methylamine reacts with HNO2 to form _________.
(a) CH3—O—N=O (b) CH3—O—CH3 (c) CH3OH (d) CH3CHO
12. Hoffmann Bromamide Degradation reaction is shown by __________.
(a) ArNH2 (b) ArCONH2 (c) ArNO2 (d) ArCH2NH2
13. Assertion (A): E0 for Mn3+/Mn2+ is much more positive than Cr3+/Cr2+
Reason (R): The third ionization energy of Mn is larger than that of Cr.
(a) Both A and R are true and R is the correct explanation of A.
(b) Both A and R are true but R is not the explanation of A.
(c) A is true and R is false.
(d) Both A and R are false.
14. Assertion (A): 3°alcohols show turbidity within 5 minutes, when treated with Luca’s reagent.
Reason (R): Conc. HCl and anhydrous ZnCl2 in 1: 1 mixture is called Luca’s reagent.
(a) Both A and R are true but R is not the explanation of A.
(b) A is false and R is true.
(c) Both A and R are true and R is the correct explanation of A.
(d) Both A and R are false.
15. Assertion (A): Acetanilide is less basic than aniline.
Reason (R) : Acetylation of aniline results in decrease of electron density on nitrogen.
(a) A and R both are correct, and R is correct explanation of A.
(b) A and R both are correct, but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A and R both are false.
16. Assertion (A): DNA is responsible for transmission of inherent characters from one generation to next.
Reason (R): Nucleic acid is responsible for protein synthesis in a cell.
(a) Both A and R are correct and R is the correct explanation of A.
(b) Both A and R are correct but R is not the correct explanation of A.
(c) Both A and R are not correct.
(d) A is not correct but R is correct.

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 SECTION -B
17. E0cell of the following reaction is 0.59 V.
A(s) + B2+ (aq) <---------> A2+ (aq) + B (s)
Calculate its equilibrium constant.
18. When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per
mole of the compound. Write
(a) Structural formula of the complex
(b) IUPAC name of the complex
19. Give reasons for the following:
(a) Ethyl iodide undergoes SN2 reaction faster than ethyl bromide.
(b) C- X bond length in halobenzene is smaller than C- X bond length in CH3- X.
20. Write the products formed when ethanal reacts with the following reagents:
(a) CH3MgBr and then H3O+
(b) Zn-Hg/conc. HCl
21. Enumerate the reactions of glucose which cannot be explained by its open chain structures. (Any two)
OR
What are essential & non-essential amino acids? Give one example of each type.

SECTION -C
22. (a) State Raoult’s law.
(b) What type of deviation from Rauolt’s law is exhibited by a mixture of phenol and aniline?
(c) Calculate the mass of compound (molar mass = 256 g mol-1) to be dissolved in 75 g of benzene to
lower its freezing point by 0.48 K (Kf = 5.12 K kg mol-1).
23. A first order reaction is 40% complete in 80 minutes. Calculate the value of rate Constant (k). In what
time will the reaction be 90% completed?
[Given: log 2=0·3010, log 3=0·4771, log4=0·6021, log 5 =0·6771, log 6=0·7782]
24. For the reaction; 2A + B → A2B, Rate = k[A] [B]2 with rate constant (k) = 2.0 x 10–6 mol–2 L2 s–1.
(a) Calculate the initial rate of the reaction when [A] = 0.1 mol L–1 and [B] = 0.2 mol L–1.
(b) Calculate the rate of reaction after [A] is reduced to 0.06 mol L–1.
25. (a) Out of which is an example of vinylic halide?

(b) Haloalkanes undergo nucleophilic substitution more readily than haloarenes. Explain.
(c) Which alkyl halide from the following pair is chiral and undergoes faster SN2 reaction?

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26. Using Valence Bond theory, explain the following in relation to the complex [Co(NH3)6]3+
(a)geometry (b)hybridisation (c) magnetic behaviour
OR
(a) With the help of crystal field theory, predict the number of unpaired electrons present in [Fe
(CN)6]4– complex.
(b) Why nickel does not form low spin octahedral complexes?
(c) The π-complexes are known for the transition metals only. Give reason.
27. Write the equations for the following reaction:
(a) Mononitration of 3-methylphenol
(b) Acid catalysed dehydration of 1-methylcyclohexanol
(c) By heating with HI
28. Give reasons for any 3 of the following observations:
(a) Aniline is a weaker base than cyclohexyl amine.
(b) It is difficult to prepare pure amines by ammonolysis of alkyl halides.
(c) Electrophilic substitution in aromatic amines takes place more readily than benzene.
(d) Aniline does not undergo Friedel – Crafts reaction.

SECTION -D
29. Read the passage given below and answer the following questions: (1+1+2)
Boiling point or freezing point of liquid solution would be affected by the dissolved solids in the liquid
phase. A soluble solid in solution has the effect of raising its boiling point and depressing its freezing
point. The addition of non-volatile substances to a solvent decreases the vapor pressure and the added
solute particles affect the formation of pure solvent crystals. According to many researches the
decrease in freezing point directly correlated to the concentration of solutes dissolved in the solvent.
This phenomenon is expressed as freezing point depression and it is useful for several applications
such as freeze concentration of liquid food and to find the molar mass of an unknown solute in the
solution. Freeze concentration is a high-quality liquid food concentration method where water is
removed by forming ice crystals. This is done by cooling the liquid food below the freezing point of the
solution. The freezing point depression is referred as a colligative property and it is proportional to the
molar concentration of the solution (m), along with vapor pressure lowering, boiling point elevation,
and osmotic pressure. These are physical characteristics of solutions that depend only on the identity
of the solvent and the concentration of the solute. The characters are not depending on the solute’s
identity.
(a) What is the effect on Boiling point of pure water when non-volatile solute is added to it?
OR
What are colligative Properties?

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 (b) Ethylene glycol is added in high concentration to water to produce antifreeze in a car. Give reason.
(c)1.00 g of non-electrolyte dissolved is 50 g of benzene causes Δ𝑇𝑓 equal to 0.40 K. Kf for benzene 5.12
K Kg mol-1. Find the molar mass of solute.
30. Read the passage given below and answer the following questions: (1+1+2)
The sequence of bases along the DNA and RNA chain establishes its primary structure which controls
the specific properties of the nucleic acid. An RNA molecule is usually a single chain of ribose-
containing nucleotide. Based on X-ray analysis of DNA, J.D., Watson and F.H.C. crick (shared noble
prize in 1962) proposed a three-dimensional secondary structure for DNA. DNA molecule is a long and
highly complex, spirally twisted, double helix, ladder like structure. The two polynucleotide chains or
strands are linked up by hydrogen bonding between the nitrogenous base molecules of their
nucleotide monomers. Adenine (purine) always links with thymine (pyrimidine) with the help of two
hydrogen bonds and guanine (purine) with cytosine (pyrimidine) with the help of three hydrogen
bonds. Hence, the two strands extend in opposite directions, i.e., are antiparallel and complimentary.
(a) State any two properties of 3d structure of DNA.
(b) How are the polynucleotide chains in the DNA strands link together?
(c) DNA is different from RNA in its structure and composition. Justify.
OR
Two strands of DNA are not identical but are complementary. Explain.
SECTION -E
31. Explain the following observations. (Any Five)
(a) Zr and Hf have similar radii.
(b) Cr2+ is reducing and Mn3+ is oxidising although both have d4 configuration.
(c) Transition metals act as catalyst.
(d) Why is Cu+ ion not stable in aqueous solution?
(e) The enthalpies of atomisation of the transition metals are high.
(f) The lowest oxide of transition metal is basic and the highest is acidic.
(g) First ionisation enthalpy of Cr is lower than that of Zn.
32. (a) State Kohlrausch law of independent migration of ions. Write an expression for the molar
conductivity of CH3COOH at infinite dilution according to Kohlrausch law.
(b) Calculate Ʌ0m for CH3COOH. Given that
Ʌ0m (CH3COONa) = 91 S Cm – 2 mol – 1
Ʌ0m (NaCl) = 126 S Cm – 2 mol – 1
Ʌ0m (HCl) = 426 S Cm – 2mol – 1
OR
(a) For the standard cell
Cu(s)/Cu+(aq)//Ag+(aq)/Ag(s) : E0 Cu2+/Cu = + 0.34 V , E0Ag+/Ag = +0.80 V

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 (i) Identify the cathode and anode as current is drawn from the cell.
(ii) Write the reaction taking place at electrodes.
(iii) Calculate the standard cell potential.
(b) What type of cell is a lead storage battery? Write overall reaction occurring in the lead
storage battery during discharge.
33. (a) Identify A, B and C in the following reaction
CH3CHO i. C2H5MgCl A conc. H2SO4 B HBr + H2O2 C
ii. H2O
(b) Predict the structure of the product when Benzaldehyde is treated with
(i) Concentrated NaOH
(ii) HNO3/H2SO4 (at 273 – 383 K)
OR
(a) What happens when
(i) Acetaldehyde reacts with HCN.
(ii) Propanoic acid is treated with chlorine in the presence of a small amount of red phosphorus.
(iii) Ethanoic acid reacts with thionyl chloride.
(b) Give the reagents to bring about the following transformations:
(i) Butan-1-ol to Butanal.
(ii) But-2-ene to Ethanal

***All the Best***

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