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    Solubility of Some compounds in water_241205_005417

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    Solubility of Some compounds in water_241205_005417

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    Solubility of Some compounds in water_241205_005417

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    heeralmishra07

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    SOLUBILITY OF SOME COMMON COMPOUNDS IN WATER

    1. Carbonates : alkalimetal, ammonium carbonates are soluble other carbonates are


    insoluble.
    2. Sulphites: alkalimetal and ammonium sulphite are soluble the sulphites of other
    metals are insoluble
    3. thiosulphates: Pb, Ag and Ba sulphates are soluble many of them dissolves in excess
    of Na 2S2O3 solultion forming complex salts
    4. Sulphides: Alkalimetal and Ammonium sulphide are soluble other metal sulphides
    are insoluble
    5. Nitrite : AgNO2 insoluble other metal nitrite are soluble
    6. Cynanides : Group-I and Group-II cyanides are soluble Hg(CN)2 is also soluble
    (solution non electrolyte) other metal cyanide are insoluble
    Note: Many metal insoluble cyanides dissolves in excess of KCN due to formation of
    complex.
     
    Thicyantes SCN : Cu(1) Ag(I) thicyanates are insoluble Pb(II) and Hg(II) are sparingly
    soluble of Cu(SCN)2 black ppt Cu(SCN) white ppt Cu(SCN) 2  H 2SO3 
     CuSCN 
    Black ppt or white ppt
    SO 2

    Ferro cyanide  Fe(CN) 6  : group I and group II ferro cyanides are soluble others are soluble.
    4

    Ferricyanide  Fe(CN) 6  : group I and group II are soluble other metal ferricyanides are
    3

    insoluble
    Ferricyanides are more soluble than Ferrocyamides
    Chlorides: Most of the chlorides are soluble:
    AgCl, PbCl2 (cold water); CuCl, BiOCl, SboCl, Hg 2Cl2 are insoluble
    Bromides: Hg 2 Br2 , CuBr, HgBr2 , PbBr2 are in soluble

    (so lub le in
    boiling)

    Iodides: AgI, Hg(I), Hg(II), Cu(I); PbI2 are sparingly or insoluble


    Fluorides: fluorides of group-I (except Li) AgF, BeF2 aluminium, mercury and nickel readily
    soluble: those of Pb, Cu, Iron (III), Ba sparingly soluble (or insoluble)
    Nitrates: All are soluble
    Chlorates: (ClO 3 ) : All are soluble: KClO3 is least soluble LiClO3 most soluble.
    Perchlorates:  ClO 4  : Generally soluble in water potassium perchlorate least soluble NaClO4
    one of the most soluble.
    Borate  BO 33  : group-I borates are soluble others sparingly soluble or insoluble

    Sulphates:  SO 4  : CaSO4 ,SrSO4 , BaSO4 , PbSO4 , HgSO4 are insoluble rest of sulphates are
    2

    soluble
    Soluble Insoluble
    Ag 2CO3 HNO3 , NH3
    Ag 2SO3 dil HNO3 , NH3
    Ag 2S Hot dil HNO3 , (hot con Cold
    HNO3Ag 2S 
    S ) HNO3 , (NH 4 )2 S, (NH 4 )Sx , NH3 , KCN, Na 2

    Ag 2S2O3 Na 2S2O3
    AgNO2
    AgCN KCN
    AgCl dil.NH3soln , KCN, Na 2S2O3 H 2O, dilHNO3
    AgBr conc NH3soln , KCN, Na 2S2 O3 H2O, dil HNO3
    AgI KCN, Na 2S2 O3sol n
    Dil or conc. NH3 , dil HNO3
    Ag 2CrO4 Dil HNO3 , NH3sol n
    (HCl 
     AgCl)
    Ag 2 CrO4
    CH3COOH
    Ag(CH3COO) dil NH3sol , boiling water
    n

    Ag3PO4 dil HNO3 , dilNH3soln


    Ag 2SO4
    Ag(COO)2 NH3Soln , dil HNO3 Water
    white
    Ag 2O HNO3 , NH3soln
    PbCO3 dil HNO3 , acetic acid
    PbSO3 dil HNO3 , NaOH
    PbSO4 hot conc H 2SO4 due of HSO4 
    solubility is much lower in presence
    of ethanol decomposes when con
    HNO3 is added
    PbS2O3 Na 2S2O3
    PbCl2 Boiling water
    PbBr2 Boiling water
    PbI2 Hot water
    PbCrO4 dil HNO3 , in NaOH Acetic acid reprecipitate PbCrO4
    from solns
    BaCO3 Mineral acids, carbonic acid (soda
    water)
    BaSO4 Boiling con.HCl warm dil HCl, dil HNO3
    BaSO 4 
    Conc.HCl
    con HNO3
     
    BaCl2
    Ba ( NO3 ) 2

    PbHPO3 acetic acid
    CaCO3 , BaCO Mineral acids and carbonic acid
    PbSO4 More conc soln of (NH4 )(CH3COO) (or)
    (NH 4 )(C4 H 4O6 ) in presence of NH3 to
    give
    [Pb(CH3COO)4 ]2 ion[Pb(C4 H 4 O6 ) 4 ]2
     

    CrO42
    PbCrO4

    BaS not ppt, in water


    BaCO3 Soluble in acetic acid, dilute mineral
    acids slightly soluble in soln s of NH 4
    salts of strong acids
    BaSO3 Dil HCl (liberates SO2 ),
    Br2 / H2O, HNO3 , H 2O2 (coconuts to
    BaSO4 )
    BaS2O3 Ppts from moderately conc soln Na 2S2O3
    BaNO2 in water
    BaSO4 Boiling conc H 2SO4 , boiling conc HCl Water, dilute acids, in (NH 4 )2 SO4 ,
    warm dil HCl, dil HNO3
    Ba(COO)2 Slightly soluble in water; hot dilute
    CH3COOH (set and by mineral acids
    (distinct from (a) strong acids, NaOH
    Hg 2Cl2 dil.acids
    Hg 2O / HgO dil . HNO3 / acids  distinctn from water, hot dil HNO3 alikali OH 
    Hg 22 / Hg 2 or (NH 4 )2 S colourless
    2 
    CO 3 Alkali and NH are4soluble
    remaining in soluble
    SO32 1 A, NH 4 are soluble, remaining
    insoluble
    HSO3 1 A, soluble. II A known only in
    solutionn
    S2 O32 Pb, Ag, Ba – insoluble
    S2  1A are soluble
    NO2 AgNO2 is sparingly soluble
    CN  IA, IIA, are soluble of hydrolysis,
    Hg(CN)2 soluble but doesn’t exihibet
    ionic xns of CN 
    OCN  IA, IIA are soluble, Ag, Hg(1), Pb, Cu
    are insoluble
    SCN  Ag, Cu(I), Hg(II),Pb are insoluble
     Fe(CN)6  IA, IIA are soluble
    4, 3

    Cl Hg 2Cl2 , AgCl, PbCl2 , CuCl, BiOCl,SbOCl, Hg 2


    are insoluble
    Br  Ag, Hg(I), Cu(I), PbBr2 are insoluble
    I 
    Ag, Hg(I), Hg(II), Cu  , PbI2
    F IA, Ag,Hg, Al, Ni-readily soluble,
    Pb,Cu, Fe3 , Ba, Li  slightly soluble, IIA
    insoluble
    NO3 All are soluble, Hg, Bi yield basic
    salts H 2O soluble in dil. HNO3
    SO24 Ba,Sr,Pb,Ca, Hg(II)
    PO34 IA except Li are soluble HPO4 IIA are soluble

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