AITS-2425-PT-II-TD-JEEA-Paper-2-Sol

FIITJEE
ALL INDIA TEST SERIES

JEE (Advanced)-2025
PART TEST – II
PAPER –2
TEST DATE: 08-12-2024
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
SECTION – A
1. B
V0 200
Sol. At resonance, R    40 
i0 5
Now XL  40 and XC = 80 
 z  (40)2  (40  80)2  40 2 
200  5 
i0   A
40 2  2 
xL  xC  
 circuit is capacitive so current will lead voltage by tan1  tan1  
R 4
 5   7 
i=  A  sin  50t  
 2   12 
2. D
Sol. Let charge on C2 is q when current in circuit is (20 q) q
maximum.
20  q 2  q q +   +
  0 S1 i
6 2 2
20  q  6  3q  3q = 0
7q = 14 R L = 2H
q = 2 C
Using conservation of energy
S2
2+q
(20  10 6 )2 (2  106 )2 (18  106 )2 (4  106 )2 (2  10 6 )2 1
6
 6
 6
 6
 6
  2i02
2  6  10 2  2  10 2  6  10 2  2  10 2  2  10 2
7
 i0  mA
3
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AITS-PT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2025 2
3. A
Sol. Instantaneous centre of rotation is O1
R
and OO1  B
2
2
R R 5
O1Q  R 2     Q O
2 2
O1
1 2v  5R2 
VQ  VO1  B 0  
2 R  4  P
1 2v  R2 
VP  VO1  B 0  
2 R  4 
1 2v
VQ  VP   B  0 R2  Bv 0R
2 R
 1  1  1 = 1 volt
Hence, (a + b) = 1 + 1 = 2
4. B
R
Sol. C  CV 
1 k
3 R 3 R
 R  R  2R  
2 3 2 2
1
2
 R
Q  nCT  2      20  20R
 2
Hence 20R heat will be released by the gas.
5. A, B, D
Sol. Torque of couple is same about any point
All points on the rod are accelerating except the centre of mass of the system (C).

= C
IC
 C  IC 
qE
qE sin   IC      (for small )
IC
IC
 T  2
qE
6. B, C
Sol. Case I:
B and  are oppositely directed then magnetic force on electrons will be directed radially outward
and there fore electric field will be directed radially outwards also.
2
(eE  evB) = mr
2
or eE  erB = mr
 mr2  eBr   m2  eB 
 E     r
 e e
   
 Er
Volume charge density should be uniform
3 AITS-PT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2025
Case II:
B and  are directed in same direction, magnetic force on electrons will be in radially inwards.
eB
For   , charge density is zero
m
eB
For   , charge density is negative
m
eB
For   , charge density is positive
m
7. C, D
   i
Sol. B  d  0  , where  is angle subtended at wire by ends of path
2
SECTION – B
8. 17
Sol. Let Q is total change on sphere without cavity
4
Q  R3  …(i)
3
Potential at C1 (after cavity is made)
3kQ kQ / 8
VC1  
2R R/2
3kQ kQ 5kQ
  
2R 4R 4R
Work done in putting charge q at C1
5kQq
W  q  VC1  0  
4R
4 3 
R q 
5  1  3 5 (R2 q)
  
4  40   R  12 0

 
 (a + b) = 5 + 12 = 17
9. 0
Sol. Junction at points Q1 and R1 can be removed due to input- Q1
output symmetry i2
 VQ1  VR1 P2 Q2
i1 i3 i1
S
P1 i
i1 i3 i1
R2 S2
i2
R1
10. 20
Sol. Let mass of ice = m
 mass of water = (100  m)
 m  80 + 150 1  30 = 10  540 + 10  1  70
80m + 4500 = 5400 + 700
80m = 1600
m = 20 gm
11. 3
Sol. When rod makes angle  with E, torque acting on it about the
centre of mass is
L L  2qE 
  2qE sin   qE   sin  
2 2 
d 3 qE
I  qEL sin 
d 2
 
mL2 3qEL
2 
0
 d 
2  (sin ) d
 /3
mL  2  3qEL  1
2

    cos  
2  2  2  2 
6qE  1 
2   cos  
mL  2 
9qE qE
 max  3  3 rad/s
mL mL
12. 2
 m 
Sol. Particle will come out of field in time  
 qB 
qE
Acceleration along y-axis a y 
m
Velocity along y-axis when it comes out
qE m E
vy  4    4  4 m/s
m qB B

 v  2iˆ  4ˆj or v  2 5 m/s
13. 2
Sol. Current in each part of ring will be same
 1E1  2E2
E 2 1
  2
E1 2
SECTION – C
14. 20.00
Sol. At point P x
Let speed of particle is v
cos 
 magnetic force, F = qvB F
m  a y  mg  Fcos  …(i)
m  a x  F sin  …(ii) 
sin 
P
dv
From (ii) m x  qvB sin 
dt
= qB (v sin ) = qBvy v mg y
dv dy
or m x  qB 
dt dt
vx y

 m dv x  qB dy
0

0
mv x  qB  y
At lowest point mv x  qBh …(iii)
Also, v x  2gh …(iv)
Equating (iii) and (iv)
qBh
 2gh
m
q2B2h2
 2gh
m2
2m2 g 2  (10 4 )2  10
h 2 2   20 m
qB (100  106 )2  (1)2
Magnetic force does no work
15. 14.14
Sol. Speed of ball at vertical displacement 10 m is
v  2g  10  2  10  10  10 2 m/s
16. 127.00
V2
Sol.  2R2 T 4  2R2 T04 (R0 = resistance of the resistor)
R0
1 (5 70 )2 1 4
5.6  108  2   (300)4   5.6  108  2  T
5.6 5 5.6
512  2  10 8 T 4
T 4  256  108
 T = 400 K= 127C
17. 146.60
Sol. At steady state
KA( T)
  350
L
350L 350L
T  
KA KR2
350  1 350  5.6
   19.60 C
 1  100
100  
 5.6 
Temperature of the liquid is = 127 + 19.60 = 146.60C
Chemistry PART – II
SECTION – A
18. C
Sol. O OH
Et2 O
C  MeMgBr   Ph C Ph
H /H O
Ph Ph 2
Me
O OH
2Et O
C  PhMgBr  
NH Cl
 Ph C Ph
4
Ph Me
Me
O OH
Et 2O
C  Ph  CH2  MgBr   Ph CH CH2 Ph
H / H O
Ph H 2
O OH
Et 2O
C  2PhMgBr   H3C C Ph
H /H O
H3C OEt 2
Ph
19. A
Sol. C N H2C NH2
CONH2 P2 O5 Re duction
 
LiAlH4
P
N C HN CH3
i  Br2  KOH
Re duction
  
ii  CHCl3  O H LiAlH4
Q 
C N COOH
O O
H /H2 O Ca OH2
   C O 
Hydrolysis
2 Ca  C
P
Benzophenone
NC +
NH2 N2 Cl
H /H O
2 NaNO
2
  
HCl

Q
Mild basic OH
HO N N
Orange red dye

CONH2 NH2 N C

Br KOH
2 CHCl3  O H

Hoffman bromamide deg radation
  
Carbyla min e reaction
 Cl
CHCl3  O H  C  dichlorocarbene 
Cl
20. D
Sol. Ph O Ph OH O
H /H2O Ph OH
   H3C C CH3
O O Ph OH
OH
O
O
Ph C H
Ph C H
O O O O
dil.NaOH
Ph C H  Ph C H  H3C C CH3  
 Ph CH CH C CH CH Ph
P
NH2  OH
OH
N
Ph CH CH C CH CH Ph
Number of stereoisomers  4 
21. B
Sol. x is formed via SNi and y is formed via SN2.
22. A, B, D
Sol. O R2 O R2
R1 C OH R1 C OH
N C HNO2 N C


NH2 H O N2 H O
Hydrolysis
O R2
R1 OH
OH  H2N
OH O
Lactic acid [y]
(R1 = CH3)
R2 O
OH
2 H2N  NH
 
O HN
O
2,5-diketopiperazine(R2 = H)
23. A, B
Sol. CN
P 
COOH
 Q 
COOH
NaOH CaO, aq. NaOH

R       No reaction
Br Br
24. B, D
Sol. OH OH
Br Br
2 Br  excess 

H O

2
SO 3H Br
(Major)
OH OH
Br /CS
2 2
o 
0 C
Br
(Major)
OH OH
Br Br
KBrO3  KBr

H2O
 KBrO 3  KBr  H2 O  Br2 
Br
(Major)
NO 2
Br Br
1. aq. KOH
   No reaction
2. H
Br
SECTION – B
25. 4
Sol. Structure of Nylon-2-nylon-6 is given below:
O
NH CH2 C NH CH2 C
5
O n
26. 10
Sol. 6HCHO  4NH3   CH2 6 N4  6H2O
Urotropine
Number of carbon atom = x = 6
Number of nitrogen atom = y = 4
27. 6
Sol. The following molecules/ions are aromatic
O
CH3
B N
N
O
28. 4
Sol. O
O
A OC2H5
O
O
B OH
  keto acid
O
C
29. 1
Sol. H O
C
H OH
HO H o|| o||
HIO 4  excess 
H OH  5H  C OH  H  C H

H OH
CH2OH
D  Glucos e
30. 4
Sol. The following are less basic than aniline
NH2 NH2 NH2
OCH3
OCH3 N
NO 2 H
SECTION – C
31. 52.00
32. 26.40
Sol. 0.2 mole of PhCHO gives 0.2 mole of Ph – CH = CHCHO (B)
 WPhCHCHCHO  132  0.2  26.40 gm
3  CH CO  O 5  i PCl
PhCHO  2
CH COONa
PhCH  CHCOOH 
 ii Rosenmund reduction
 PhCH  CH  CHO
3
A B 
NaOH / CaO, 
PhCH  CH2
C 
33. 8.40
 1  150
Sol. Meq. of residual H2 SO 4   20   3
 20  50
Meq.of H2 SO 4 taken  60  0.1  6
 Meq. of H2 SO4 consumed  Meq. of NH3  6  3  3
1.4  3
Percentage of nitrogen   100  8.40
0.5
34. 1.68
(Range 1.65 – 1.70)
1 3 1
Sol. Moles of N2  moles of NH3  
2 1000 2
 1.5  10 3
 vol of N2 at STP  22.4  1.5  10 3  0.0336 lit.
 0.0336  50  1.68
Mathematics PART – III
SECTION – A
35. A
Sol. cos( – ) = sin  sin 
sin   sin 
  sin   sin   sin   sin 
sin2 
 sin2   1 
 sin   sin   sin   sin   
 sin2  
Squaring both side
2 2 2 2 2 2 2 2
sin  – sin  – sin  = sin ·sin ·sin  – 2 sin ·sin 
 cosec ·cosec  – cosec ·cosec  – cosec ·cosec2  = 1 – 2 cosec2 
2 2 2 2 2
2 2 2
 (1 + cot )(1 + cot ) = 1 – 2(1 + cot )
2 2 2
 tan  – tan  – tan  = 0
36. D
B
a2 a
Sol. MQ   h2 ; PM  MR 
4 2 2m  1

tan   tan      R
tan  = tan( + ( – ) = Q
1  tan   tan     
 2m  1 h M
tan   h
am  m  1  P
 –
C
A BM = MC = AM
37. B
 c  c
Sol. Let A   ct1,  , B   ct 2 , 
 t1   t2 
2 A
2 1 1
 a 2  c 2  t1  t 2   c 2   
 t1 t 2 
a
2 1 
= c 2  t1  t 2   1  2 2  ..... (1)
 t1  t 2  
B
G(h, k)
t t 
Where 3h = c(t1 + t2) and 3k  c  1 2 
 t1t 2  O
h
  t1t 2 putting in equation (1)
k
2 2 2 2 2 2 2 2
hk·a = (ahk – 4c )(h + k )  (x + y )(9xy – 4c ) = a xy
38. A
3b2  2a2  b2  a2  3b2  2a2 
Sol.   1  2    2
and  1  2 
4b2  3a2  4b  3a2  4b2  3a2
b2 2  b2  a2   2 
f     1   
2
3b  a 2 2
3b  2a 2  2
 1  
39. A, C, D
5  x x    x   
Sol. (x – 3)2 + 5 + sin2 y =  sin  cos   5  sin   
2 12 12    12 4  
L.H.S.  5, R.H.S.  5
 x = 3 and y = n, n  I
40. B, C
 2 
Sol. Inclination of PR    
 3 
P(1, 3)
 2  S
 h  1   cos    
 3  60 
 2   Q(3, )
and k  3   sin    
 3  60 – 
2 60
In PQS; cos     = 2 sec 
 R(h, k) 60–
 1 3  O
h  1  2sec    cos    sin   x=3
 2 2 
3 sin  h
h  1   1   tan   
cos  3
 3 1 
k  3  2 sec    cos   sin   = 3  3  tan 
 2 2 
h
 k  3 3   3 k  3  3  1  h
3
41. B, D
Sol. r  4cos   cos    5 33
A()
R(4 sin  + sin ) = 0
 r2(17 + 4 cos( – )) = 825 r
2r 2  100 33
2
Also, cos     
2r 2 O P  33, 0 
 r = 7, cos( – ) < 0 r 4
B()
SECTION – B
42. 6
r r 2 2
Sol. t® = (sin  + cos )(sin  + cos )
r+2 r 2 r 2 r+2
= sin  + cos ·sin  + sin ·cos  + cos 
 1 
= t  r   t  r  2     sin2  2    t  r  2 
4 
t  25   t  23  1 2 1
   sin  2  

t 21  4 4
 
t 25  t 23  
 24 6
t  21
43. 2
Sol. In OBL A
R OL

   
sin    C  B   sin   A  R
2  2 
2C O
R  cos A R
 OL 
cos  C  B  R  – 2C C
R cos A 2R  sinB  sin C 
 AL  R   L  C  B
cos  C  B  cos  C  B  2
R  sin 2B  sin 2C  B  
     A
AL  4 sin A  sinB  sin C  2 
 1 1 1  2  sin 2A  sin 2B  sin 2C 

 R    2
 AL BM CN  4 sin A  sinB  sin C
44. 1
Sol. S1'   2,  1
S2(–3, 4)
Equation of S2S1' : y  1    x  2
=1
S1(2, 1)
P(1, 0) S1'  2, 1
45. 3
2
3  2
Sol. e     12
2   3  2 
  1 1  
 2  3 

 2 3

46. 8
2 2 2 2
Sol. Given xy = c , x + y = c
 Distance of tangent at A trace origin
c
d  1  distance between tangents
54
1
2c c 54
1
  a
a 2
54
47. 5
 sec    tan  
Sol. Tangent at R() :  x  y 1 0
 a   b 

Passes through (0, –b)   
4
 Equation of normal at R is 2b  y  b   a  x  2a   0
Passes through  2 2 a, 0   a = b  e  2
2 2
SECTION – C
48. 9.40
49. 3.20
Sol. (Q. 48.-49.)
(ABC) = (OPA) + (OPB) + (PAB) B(10, 4)
1
6   3P1  4P2  5P3 
2
 3P1 + 4P2 + 5P3 = 12
P P 5P
 1  2  3 1 4
4 3 12 P 5
12 P3
 = 4,  = 3,     +  +  = 9.4 P2
5 P1
1
3P1  4P2  5P3 x
  60  P1P2P3  3 O 3 A(3, 0)
3
4  16 16
 60·P1P2P3  43  3P1P2P3  
20 5
50. 0.75
51. 10.50
Sol. (Q. 50.-51.) y
Equation of director circle of curve C2 is
x2 + y2 = 16
Point A, B are (4, 0) and (0, 4) B x–y=0
Hence, maximum area = 2  13  4  4 2
A(4, 0)
x
x+y–2=0

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FIITJEE

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ANSWERS, HINTS & SOLUTIONS

Orange red dye

NaOH CaO, aq. NaOH

Mathematics PART – III

 1 1 1  2  sin 2A  sin 2B  sin 2C 

P(1, 0) S1'  2, 1

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