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CHEMISTRY
CLASS – XI
Time Allotted : 3 hrs. Maximum marks : 70

General Instructions :
1. This Question Paper has 4 Sections A, B, C and D.
2. Section A Question nos. 1 to 18 are multiple choice questions carrying 01 mark each.
3. Section B Question nos. 19 to 29 are short answer questions carrying 02 marks each.
4. Section C Question nos. 30 to 34 are also short answer questions carrying 03 marks each.
5. Section D Question nos. 35 to 37 are long answer questions carrying 05 marks each.

SECTION – A
Sl.
QUESTIONS Marks
No.
1. The maximum number of molecules are present in 1
(a) 15 L of H2 gas at STP (b) 0.5 g of H2 gas
(c) 5 L of N2 gas at STP (d) 210 g of O2 gas
2. The number of moles of hydrogen molecules required to produce 20 moles of ammonia 1
through Haber’s process is :
(a) 10 (b) 20 (c) 30 (d) 40
3. A solution contain 4g of NaOH and 16.2 g of water. The mole fraction of solute and 1
solvent are respectively
(a) 0.1, 0.9 (b) 0.2, 0.8 (c) 0.5, 2.5 (d) 0.3, 0.7
4. Two particles A and B are in motion. If the wavelength associated with ‘A’ is 33.33 nm, 1
the wavelength associated with ‘B’ whose momentum is 1/3rd of ‘A’ is :
(a) 1 × 10–8 m (b) 2.5 × 10–8 m (c) 1.25 × 10–7 m (d) 1 × 10–7 m
5. The correct set of quantum number for the unpaired electron of chlorine atom is : 1
1 1 1 1
(a) 2, 0, 0,  (b) 3, 0, 0,  (c) 2, 1, − 1,  (d) 3, 1, 1, 
2 2 2 2
6. Which is the orbital angular momentum of an electron in ‘f’ orbital? 1
h h h h
(a) 1.5 (b) 6 (c) 3 (d) 3
   2
7. The correct order of decreasing ionic radii among the following iso-electronic species is: 1

(a) Ca +2  K+1  S−2  Cl−1 (b) Cl−1  S−2  Ca +1  K+1

(c) S−2  Cl−1  K+1  Ca +2 (d) K+1  Ca +2  Cl−1  S−2
Sl.
QUESTIONS Marks
No.
8. Which of the following represents the correct order of increasing electron gain enthalpy 1
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with negative sign for the elements O, S, F and Cl ?

(a) Cl < F < O < S (b) O < S < F < Cl (c) F < S < O < Cl (d) S < O < Cl < F

9. For the second period elements, the correct increasing order of the first ionization enthalpy 1
is :
(a) Li < Be < B < C < N < O < F < Ne (b) Li < B < Be < C < O < N < F < Ne
(c) Li < B < Be < C < N < O < F < Ne (d) Li < Be < B < C < O < N < F < Ne

10. In which of the following, hydrogen bond is the strongest? 1

(a) O — H F (b) O — H H (c) F — H F (d) O — H O

11. A neutral molecule XF3 has zero dipole moment. The element X is most likely : 1

(a) chlorine (b) Boron (c) nitrogen (d) carbon

12. 1

The IUPAC name of is

(a) 2,3-Dimethylbutanoyl chloride (b) 3,4-Dimethylpentanoyl choloride

(c) 1-chloro-1-oxo-2,3-dimethylpentane (d) 2-Ethyl-3-methylbutanoyl chloride

13. O 1
||
What is the IUPAC name of H − C − CH 2 − CH 2 − OCH3 ?

(a) 2-Formylmethoxyethane (b) Methoxypropanal

(c) 2-methoxypropanal (d) 3-methoxypropanal

14. Structure of the compound whose IUPAC name is 3-Ethyl-2-hydroxy-4-methylhex-3-en- 1

5-ynoic acid is :

Sl.
QUESTIONS Marks
No.
Question Nos. 15 to 18 consist of two statements – Assertion (A) and Reason (R). Answer 1
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these questions by selecting the appropriate option given below:

(a) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of
Assertion (A).
(b) Both Assertion (A) and Reason (R) are true and Reason (R) is not the correct explanation of
Assertion (A).
(c) Assertion (A) is true but Reason (R) is false.
(d) Assertion (A) is false but Reason (R) is true.
15. Assertion (A) : 12 parts by mass of carbon in CO and CO2 molecules combine with 16 1
and 32 parts by mass of oxygen.
Reason (R) : A given compound always consists of same elements combined in a fixed
proportion by mass
16. Assertion (A) : The spectrum of He+ ion is expected to be similar to that of H atom. 1
Reason (R) : He+ ion is also one electron species.
17. Assertion (A) : F atom has a less negative electron affinity than Cl atom. 1
Reason (R) : Additional electrons are repelled more effectively by 3p-electrons in Cl
than by 2p-electrons in F atom.
18. Assertion (A) : Bond energy and bond dissociation on energy have same values for 1
diatomic molecules.
Reason (R) : Greater the bond dissociation energy, less reactive is the bond.
SECTION – B
19. The density of a solution prepared by dissolving 120 g urea (molecular mass = 60 g mol–1) 2
in 1000 g of water is 1.15 g/ml. What is the molarity and molality of the solution?
20. In the crystalline solid MSO4·nH2O of molar mass 250 g mol–1, the percentage anhydrous 2
salt is 64 by weight. What is the value of n ?
21. Answer the following : 2
(a) How many electrons can be filled in all orbitals with  n + l = 5.
(b) Which of the two is paramagnetic, V(IV) or V(V) and why ?
22. (a) If an electron and proton when in motion have the same wavelength associated with 2
each of the which would be moving faster and why ?
(b) When is the energy of an electron regarded as zero ?
23. What transition in a hydrogen spectrum would have same wavelength as in a Balmer 2
transition n = 4 to n = 2 of He+ spectrum ?
24. (a) How do 3s and 2s orbirtals differ in the number of spherical nodes ? 2
(b) Write the values of all four quantu numbers for the last electron in case of K(Z = 19).
25. (a) The formation of F–(g) from F(g) is exothermic whereas that of O –2(g) from O(g) is 2
endothermic. Explain.
(b) Ne and Na+ ions are isoelectronic species. Do they have same ionization enthalpies
also?
Sl.
QUESTIONS Marks
No.
26. Assign reason for the following : 2
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(a) Ethyl alcohol is soluble in water whereas diethyl ether is very slightly solude.
(b) Which out of H2+ and H2– is more stable and why ?
27. (a) BeF2 and H2O are both triatomic molecules but have different shapes. Discuss. 2
(b) Bond angle in NH3 is more than in PH3. Explain.
28. (a) Which compound is a better conductor is electricity in molten state and why? CuO or 2
CuS.
(b) Out of but-1-yne and but-1-ene which has more dipole moment? Why?
29. (a) Calculate the formal charge on each atom in 2

(b) How many sigma and pi-bonds are present in a molecule of naphthalene?
SECTION – C

30. Write the IUPAC nomenclature of the following structures : 3

31. (a) If the uncertainty in the position of a moving electron is equal to its de Broglie 3
wavelength then its velocity will be completely uncertain. Explain. [1]
(b) The mass of an electron is 9.1 × 10–31 kg. If its kinetic energy 3 × 10–25 J, calculate its
wavelength. [2]
32. The first (iH1) and second (iH2) ionization enthalpies (kJ mol–1) of three elements I, II 3
and III are given below :
I II III
iH1 403 549 1142
iH2 2640 1060 2080
Identify the element which is likely to be :
(a) a non-metal (b) an alkali metal (c) an alkali earth metal
33. Write the molecular orbital configuration of O2 , O2− , O22− . Arrange them in increasing 3

order of (i) bond order (ii) bond dissociation energy.

34 Calcium carbonate reacts with aqueous HCl to give CaCl2 and CO2 according to the 3
reaction given below :
CaCO3 + 2HCl(aq) ⎯⎯
→ CaCl2 (aq) + CO2 (g) + H2O( )
What mass of CaCl2 will be formed when 200 ml of 0.76 M HCl reacts with 1000g of
CaCO3? Name the limiting reagent. Calculate the number of moles CaCl2 formed in the
reaction.
Sl.
QUESTIONS Marks
No.
SECTION – D
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35. Give the IUPAC name of the following : 5

CH3 CH2 −CN

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(b) H 2C = C — CH— CH 2CN (c) NC − CH 2 − CH 2 − CH − CH2 − CN
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OH

(d) OHC − CH2 − CH2 − CH − CH2 − CHO (e)

|
CH2 −CHO

36. Give the bond line structure of the following : 5

(a) 3-(4-methylcyclohex-2-en-1 yl) propanoic acid
(b) Phenyl ethane nitrile (c) 3-chloro-1,1,1-trifluoroethane
(d) 5-Amino-3-methylpentan-2-one (e) diphenylmethanone
37. Give the IUPAC name of the following : 5
CH2COOH
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(a) 400C − CH 2 − CH 2 − CH 2 − CH − CH 2 − COOH
CH3
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(b) CH3 − CH − C − COOCH 3 (c)
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Br OH

O CH2 −CH=CH2
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(d) CH3 − C − CH − C  C − CH3 (e)

________