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    EQUI WORKSHEET

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    itsankit2725

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    © All Rights Reserved
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    EQUI WORKSHEET

    Uploaded by

    itsankit2725
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    EQUI WORKSHEET

    Uploaded by

    itsankit2725

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    © All Rights Reserved
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    of 2

    WORKSHEET

    EQUILIBRIUM
    1. What will be the conjugate bases for the Brönsted acids:

    HF, H2SO4, HCO3 − , NH4 +

    2. Describe the effect of (a) addition of H2, (b) addition of CH3OH, (c)
    removal of CO (d) removal of CH3OH on the equilibrium of the following
    reaction:

    2H2(g) +CO(g) ⇌ CH3OH(g) .

    3. Calculate the pH of the solution obtained when 1mL of 13.6M HCl is


    diluted with water to give one litre of the solution .( Log 1.36 = 0.1335)

    4. (a) 13.8 g of N2O4 was placed in a 1L reaction vessel at 400K and


    allowed to attain equilibrium: N2O4 (g) ⇌ 2 NO2(g) The total pressure at
    equilibrium was found to be 9.15 bar. Calculate Kp (R = 0.083 bar L mol -
    1 -1
    K )

    (b) Explain the following terms: (i) Common ion effect (ii) Buffer solution

    5. (a) Which of the following are Lewis acids? H2O, BF3, NH3, AlCl3

    (b) The solubility product of Al(OH) 3 is 2.7 × 10-11. Calculate its solubility
    in gL─1 .

    (c) Consider the reaction: 2 SO2(g) + O2 ⇌ 2 SO3(g) + Heat

    Indicate the direction in which the equilibrium is shifted when (i)


    temperature is increased. (ii) pressure is increased.
    6. The value of Kc for the reaction 2HI (g) ⇋ H2 (g) + I2 (g) is 1 × 10-4 . At
    a given time, the composition of the reaction mixture is
    [HI] =2 × 10-5 mol, [H2] =1 × 10-5 mol and [I2] =1 × 10-5 mol. In which
    direction will the reaction proceed?
    7. At 473 K, equilibrium constant Kc for decomposition of phosphorus
    pentachloride, PCl5 is 8.3×10−3. If decomposition is depicted as,
    PCl5 (g) ⇌ PCl3 (g) + Cl2 (g) ∆rH° = 124.0 kJmol–1
    (a) Write an expression for Kc for the reaction.
    (b) What is the value of Kc for the reverse reaction at the same
    temperature?
    (c) What would be the effect on Kc if,
    (i) more PCl5 is added
    (ii) pressure is increased

    8. (a) A sample of pure PCl5 was introduced into an evacuated vessel at


    473 K. After equilibrium was attained, concentration of PCl5 was found to
    be 0.5 × 10–1 mol L–1 . If value of Kc is 8.3 × 10–3 , what are the
    concentrations of PCl3 and Cl2 at equilibrium? PCl5(g) ⇋ PCl3(g) + Cl2(g)

    (b)States Le Chatelier’s principle. Discuss the effect of temperature and


    pressure on synthesis of NH3 by Haber’s process.

    9. At 473 K, equilibrium constant Kc for decomposition of phosphorus


    pentachloride, PCl5 is 8.3 ×10-3 . If decomposition is depicted as, PCl5(g)
    ⇋ PCl3 (g) +Cl2(g) ΔrH0 = 124.0 kJmol–1 (i)Write an expression for Kc for
    the reaction. (ii) What is the value of Kc for the reverse reaction at the
    same temperature?
    10. What is Solubility product ? Explain its role in the precipitation of
    sulphides of group II.

    11. The solubility of Pb(OH)2 in water is 6.7 x 10-6 M. Calculate the


    solubility of Pb(OH)2 in a buffer solution of pH = 8.

    12.Why are the cations of group III precipitated as their hydroxides in the
    presence of ammonium chloride?

    13. Why in group V of qualitative analysis, sufficient NH4OH solution


    should be added before adding (NH4)2CO3 solution?

    14.Calculate the pH of a 1.0 X 10-8 M solution of HCl.

    15.Calculate the solubility of A2X3 in pure water, assuming that neither


    kind of ion reacts with water, [Solubility product of A2X3, Ksp=1.1X10-23 ]

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