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    XII Chemistry

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    rudrarajsharma35

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    XII Chemistry

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    XII Chemistry

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    rudrarajsharma35

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    NATIONAL PUBLIC SCHOOL

    +2 Senior Secondary School, Affiliated to CBSE New Delhi


    New Area, Hazaribagh
    CLASS – XII TIME – 2 HR
    SUBJECT – Chemistry UNIT TEST – II (2024 -25) F.M – 40

    Q1 to 10 carry 1 marks
    Q11 to13 carry 3 marks
    Q14 to 16 carry 2 marks
    Q17 to 18 carry 5 marks

    Q1) The value of rate constant of a pseudo first order reaction


    (a) depends on the concentration of reactants present in a small amount.
    (b) depends on the concentration of reactants present in excess.
    (c) is independent of the concentration of reactants.
    (d) depends only on temperature.
    Q2) A first order reaction has a rate constant 1.15x103s-1 . How long will
    5 g of this reactant take to reduce to 3 g?
    (a) 442.5 sec (b) 400 sec (c) 100 sec (d) 50 sec.
    Q3) The reaction rate constant can be defined as the rate of reaction
    when each reactant's concentration is:
    (a) unity (b) doubled the initial concentration
    (c) infinite. (d) zero
    Q4) Which of the following species is not expected to be a ligand?
    (a) NO (b) NH+4 (c) CO (d) NH2CH2 CH2NH2
    Q5) IUPAC name of [Pt(NH 3 )2 Cl(NO2) ] is:
    (a) platinum diaminechloronitrite
    (b) chloronitrito-N-ammineplatinum(II)
    (c) diamminechloridonitrito-N-platinum(II)
    (d) diamminechloronitrito-N-platinate (II)
    Q6) Identify the incorrect statements for the behaviour of ethane-1, 2-
    diamine as a ligand.
    (a) It is a neutral ligand. (b) It is a didentate ligand.
    (c) It is a chelating ligand. (d) It is a unidentate ligand
    Q7) Which of the following compounds has tetrahedral geometry? Q17) (i) Account for the following:
    (a) [Ni (CN) 4 ]2- (b) [PdCl 4 ]2- (a) Mn shows the highest oxidation state of +7 with oxygen but with
    (c) [Pd (CN) 4 ]2- (d) none of these fluorine, it shows the highest oxidation state of +4.
    Q8) Which metal has lowest melting point? (b) Cr2+ is a strong reducing agent
    (a) Cs (b) Hg (c) Na (d) Sn. (c) Cu2+ salts are coloured, while Z n2+ salts are white.
    Q9) Which transition metal can show highest oxidation state? ii) Complete the following equations:
    (a) Sc (b) Os (c) Ti (d) Zn (a) 2MnO-2 + 4KOH + O2
    (b) Cr2 O22- + 14H+ + 6I-
    Q10) When KMnO, acts as oxidising agent in alkaline medium, the
    oxidation number of Mn decreases by: Q18 (i) Define the following terms:
    (a) 1 (b) 3 (c) 2 (d) 5. (a) Collision frequency
    (b) Rate constant (k).
    Q11) The rate of reaction quadruples, when the temperature changes from
    (ii) The rate constant of a first order reaction increases from 4 x 10-2 to 24
    293 K to 313 K. Calculate the energy of activation of the reaction
    x 10-2 when the temperature changes from 300 K to 350 K. Calculate
    assuming that it does not change with temperature.
    the energy of activation (Ea). (log 2 0.301, log(3) = 0.4771 log(4) =
    Q12) Account for the following: 0.6021 log(6) = 0.7782 )
    (i) Ti (IV) is more stable than the Ti(II) or Ti(III).
    (ii) In case of transition elements, ions of the same charge in a given
    series show progressive decrease in radius with increasing atomic
    number.
    iii) Zinc is a comparatively a soft metal iron and chromium are typically
    hard.
    Q13) Explain with two examples each of the following: coordination entity,
    ligand, coordination - number, coordination polyhedron, homoleptic and
    heteroleptic.
    Q14) The rate of the reaction becomes 100, when pH changes from 2 to pH 1.
    Find order of reaction
    Q15) Explain, giving reasons.
    (i) Transition metals and many of their compounds show paramagnetic
    behaviour.
    (ii) The enthalpies of atomisation of the transition metals are high.
    Q16) Explain why [Fe (H2O) 6 ]3+ has magnetic moment value of 5.92 BM
    whereas has a value of only 1.74 BM. a [Fe (CN) 6 ]3-

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