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    Adobe Scan 01-Dec-2024

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    joshuasimon198
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    © All Rights Reserved
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    Adobe Scan 01-Dec-2024

    Uploaded by

    joshuasimon198
    1 views9 pages
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    Notes

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    1 views9 pages

    Adobe Scan 01-Dec-2024

    Uploaded by

    joshuasimon198
    Notes

    Copyright:

    © All Rights Reserved
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    Ethens

    Paepoation alcokoe
    ouation of
    I. By deby ie presence og puoti acic
    -Aleolol wndu delyohation in CHSaH, Po4)
    procut alkene a etlu depenol
    Fomation fAeatiok
    e neation concition
    On

    u, So4 CH, CH H,0


    443 k EHene
    CHCH,OH
    Ehanol
    H, So4 CHCHOCH,CHy tHso
    413k
    Emony etone
    Meclanism seation
    mucleophilie bimolecular
    "formation eter is a mmolecule on a proton ated CSN*
    aleokoe
    t imolre atlack a
    alcohol
    CHy-CH,-o
    Protonaled aliokol
    Sy2
    CHy-CH :
    Oxoium ion

    CH CcHp-cHcHs
    Ehongetane
    sutable fo kie pepaaation of etieu
    -This metlod is
    gops ongunkindued and tempate
    kaving pimony olhyfshonlot be
    ’ The alky gonp
    be kept low an tuiay alcohel
    Dekynabior seconolayaesult omaton %alkene
    m
    elinination keactionanol
    CHs H,Soy CH,-ec4,tHo
    CH-c-ou
    2. Williamson bynthess
    Labaatny metlod fa pepouation of symmtuical and
    nsgameticalette to teat with
    aalide is allowed
    Jh fhs alkyl
    Hodium alkoiole
    RoR +Nax
    Çodim Ethe
    ALk alkoniole
    halioe CHOC Hs + Na Ba
    CH-n t GHo Na
    Sodium Metkongettane
    Meybhomde ethoriede

    6ubstatood alhy gopseonotat, n


    Ekes containing this metRod.
    can be prepoed by
    tetiasg)
    . The aeaton nvolve SN ttack o an alkovide ow On
    alkg kalide 'piefeasky be
    Pumany in tte neation shoulo
    - The halide wsed SN2
    CHs
    CH,--oCH, t NaBR
    primany CH
    ¿-6-Na t
    CH, S* CH
    CHs
    CHs Meaye Melye tet butye
    Sooium kutiay bomiole
    butoide
    Ralide mdngo eliminatn
    Seuonday and teutiay
    CH,-t
    CHs O Na t 2Metypopent
    Sodium metloxide CH
    tutbuylhoniole CH,04 + Na B

    - Alkoiole ane mot onk,


    nuleopkle but shong bow as well.
    Phenol an be conveuted to ethu by his method

    t NaoH
    Sodtiumplhemoxide
    ONa t Na
    B
    SN
    Anisole
    Example (1.6
    Il.6 The tollowing i mot an appropiote

    Cz Hs0 Na t chsAeation
    CHs
    would be Ahe majn pocct g -butgety
    Owhat dke paepaalion q
    wute suitale kea ton br sodiu metkoxide
    k-butyl cklaicle sopene
    Ans hpreseMce f Gomation 2-methy
    O Aesuit n
    at as ase and
    CHy--oCHs
    CHy CHs
    CHs
    St S
    Physical psopaubia
    ’C-0bonol in etha is polas
    kave net dipole moment
    - They
    Boibing point pomts ae comparable
    polarty theu boing
    Dueto weak companasle moleculor mass
    tEose of tle
    he alkameos
    to Comparedto alcokol
    point is lone as n alcokol.
    bondl
    But boiling
    due to pre,ence gkyaoeu GHgocHs CHCH,o
    Fomula CH,CH, CHs Butan-l-o
    n-Pemtame Ekkony ettame
    390
    309.1 307.6
    B-P/k
    Solubility waten aesemble
    The mis ciblity o etke wit
    &ame moleculau ms
    those of alcokol of tie
    butan-l-oe aue mmisoYle t tle
    ethoxy ettome anot Kespetively
    ’ BotA l00ml waen
    extent ie 7.5g amod 99 pe
    $ame
    imnis cble n wat
    - Pentane is byologen bondd wite
    cke alolol,etke Can alo tomm watee molecule.

    R
    R

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