Sankalp-2123 S&R (Monthly Test-II) (3)

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FIITJEE– Monthly Test–II (JEE-Advanced)

PHYSICS, CHEMISTRY & MATHEMATICS


Pattern - PT-2 QP CODE: PAPER - 2
Time Allotted: 3 Hours Maximum Marks: 186

▪ Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
BATCHES –2123

1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character
of your Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Two Part.


(i) Part–A (01-08) – Contains eight (08) multiple choice questions which have One or More correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect option is
darkened.
Zero Marks: 0 If none of the bubbles is darkened. Negative Marks: −1 In all other cases.

(ii) Part–A (09-12) – This section contains (02) List-Match Sets, each List-Match set has Two (02) Multiple Choice
Questions. Each List-Match set has two lists: List-I and List-II. FOUR options are given in each Multiple Choice
Question based On List-I and List-II and ONLY ONE of these four options satisfies the condition asked in the
Multiple Choice Question. Each question carries +3 Marks for correct combination chosen and -1 marks for wrong
options chosen.

(iii) Part–B (01-06) contains (06) Numerical based questions, the answer of which maybe positive or negative numbers
or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries
+3 marks for correct answer. There is no negative marking.

Name of the Candidate :__________________________________________________

Batch :__________________________ Date of Examination :___________________

Enrolment Number :______________________________________________________

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
Sankalp 2123S & R_Paper-2-PCM(000000.1)-2

PART – A: (Multi Correct Answer Type)

This section contains 08 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

1. A wire of length , carrying a current i is kept along x-axis as shown in the figure.
(A) Unit vector along magnetic field due to the wire at (a, b, c) is y

independent of x0.
x0 
(B) Unit vector along magnetic field due to the wire at (a, b, 0) is
dependent on x0.
(C) Unit vector along magnetic field due to the wire at (0, b, c) is i
x
independent of b and c
(D) Unit vector along magnetic field due to the wire at (a, 0, c) is
independent of a and c

2. Four particles A, B, C and D of masses mA, mB, mC and mD         


respectively, follow the paths shown in the figure, in a uniform      B   
magnetic field. Each particle moving with same speed. QA, QB, QC         
and QD are the specific charge of particles A, B, C and D    R     
respectively (assume that the motion of each particle is in the         
same plane perpendicular to the magnetic field). A B
  2R
      
(A) QA < QB < QC < QD
      C  
(B) QD < QB < QC < QA
        
(C) charge on the particle B and particle D is of same nature R
        
(D) Work done by magnetic force on the particle C is minimum as
compared to other particle       D  

Space for rough work

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-3

3. In zero gravity region, A point charge +Q of mass M is B V0


connected by a spring of natural length Lo and spring
constant k. A uniform magnetic field B is directed inside the
plane of paper. The point charge is given an initial velocity O + Q, M
k
v0 perpendicular to the length of spring as shown. It is given
Mv 0 L0
that B = Then which of the following quantities remains
QLo
conserved during the motion of particle?
(A) Kinetic energy (B) potential energy
(C) Total energy of system (D) angular momentum of particle about O

4. A uniform magnetic field −B0kˆ exists to the right of the plane y

y = x tan as shown. At t = 0 a particle of mass m and positive


charge q with velocity v0 î enters in magnetic field at origin. Then:
(q, m) 
m
(A) Particle will come out from magnetic field after t = x
qB0 Magnetic
2m field
(B) Particle will come out from magnetic field after time t =
qB0

 mv mv 0 
(C) Co–ordinate of point from which particle will come out is  0 sin2, (1 − cos 2),0 
 0
qB qB 0 
 mv mv 0 
(D) Co–ordinate of point from which particle will come out is  0 sin , (1 − cos ),0 
 qB0 qB0 

5. A large charge sheet of surface charge density  is moving with constant velocity v along its plane.
The magnetic field intensity at any point near the sheet in the middle space above sheet will be
(A) Zero
 vx
(B) 0 , where x is distance of point from sheet
2
 v
(C) 0
2
(D) Independent of small distance from sheet

Space for rough work

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-4

6. A wire frame ABCDEF is kept as shown in figure. I is the current in the


wire frame.
(A) The direction of magnetic field at ‘O’ due to the wire frame will be
 −i − j 
along  
 2 
(B) the direction of magnetic field at P (0, a, 0) due to wire CD and EF
will be along – ĵ
(C) the direction of magnetic field at Q(a, 0, 0) due to wire EF and CD will be along ( − ĵ )
(D) the direction of magnetic field at P(0, a, 0) due to wire AF and CB will be along ( − î )

7. The current density inside a long solid cylindrical wire of radius a is in direction of the axis and its
r
magnitude varies linearly with radial distance r from the axis according to j = j0 , where j0 and a are
a
constants. If the total current carries by the wire is i. Then,
 ir 3
(A) Magnitude of magnetic field inside the wire at a distance r from the axis is 0 4
2a
0ir 2
(B) Magnitude of magnetic field inside the wire at a distance r from the axis is
2a3
 i
(C) Magnitude of magnetic field outside the wire at a distance r from the axis is 0
2r
 ia
(D) Magnitude of magnetic field outside the wire at a distance r from the axis is 0 2
2r

8. A system of four semi-circular wires of radius a , carrying y


current I as shown in the figure. I
(A) The magnetic field at ‘O’ due to current carrying loop is
0I
2R
n( 2 + 1) kˆ () R

(B) The magnetic field at ‘O’ due to current carrying loop is R


I
0I
R
n( 2 + 1) kˆ () I O
R
x

(C) The magnetic moment of the system is 4R2I(2 + )( +k) ˆ

R
ˆ
(D) The magnetic moment of the system is 2R2I(2 + )( +k)
I

Space for rough work

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-5

PART – A: (Matrix Match)

This section contains 4 multiple choice questions. Each question has matching Column(s). The codes for the
Column(s) have choices (A), (B), (C) and (D) out of which only ONE is correct

Answer the following by appropriately matching the list based on the information given in the
paragraph.

A particle with charge Q is moving in fields of combination given below.


List – I List – II
→ A trajectory of charge particle may
(I) Uniform E only (P)
be straight line
→ A trajectory of charge particle may
(II) Uniform B only (Q)
be Parabola
→ → A trajectory of charge particle may
(III) Uniform E and Uniform B parallel to each (R) be non uniform right circular
other cylindrical helix
→ → A trajectory of charge particle may
(IV) Uniform E and Uniform B perpendicular to (S) be uniform right circular cylindrical
each other helix
K.E. of charge particle can not be
(T)
constant

9. Which of the following is the only CORRECT combination?


(A) (I), (P), (Q), (T) (B) (II), (R), (S), (T)
(C) (III), (P), (Q), (S) (D) (IV), (Q), (T)

10. Which of the following is the only CORRECT combination?


(A) (II), (Q), (T) (B) (II), (Q), (S), (T)
(C) (III), (Q), (S), (T) (D) (III), (P), (R), (T)

Space for rough work

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-6

Answer the following by appropriately matching the list based on the information given in the
paragraph.
Some current carrying wires are given in List – I and graph of variation of magnetic field versus position
of point P are given in List – II. Match the graph given in List – II for the current carrying wire in List – I.
List – I List – II
B
A long straight current
carrying wire, placed along
(I) I y-axis. Its magnetic field at (P)
x
point P(x,0,0) is observed
along x-axis.

y
B
Two long parallel wires
placed on xy plane. O is
x
(II) O origin. Its magnetic field is (Q)
I I
observed at point P(0,0,z)
along positive z-axis.
a a
y
Two long parallel wires are B
placed along y-axis and
O parallel to x-axis. Its
(III) I x magnetic field is observed (R)
at point P(x,0,0) along
I wire -2 positive x-axis parallel to
wire -2.
wire -1
y B
A current carrying ring is
placed on y-z plane. Origin
is at the centre of ring. Its
(IV) (S)
magnetic field is observed
O x at point P(x,0,0) along
positive x-axis.

11. Which of the following is the only CORRECT combination?


(A) (I), (R) (B) (II), (P)
(C) (III), (Q) (D) (IV), (S)

12. Which of the following is the only CORRECT combination?


(A) (II), (R) (B) (I), (S)
(C) (III), (P) (D) (IV), (P)

Space for rough work

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PART – B: (Numerical Based Type)

This section contains 6 Numerical based questions, the answer of which maybe positive or negative numbers
or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30).

1. A conductor of mass m = 5 kg and length  = 4m is placed on horizontal surface and a uniform magnetic
field B = 2 Tesla exist parallel to horizontal surface but perpendicular to the conductor. Suddenly, a
certain amount of charge is passed through it, then it is found to jump to a height
h = 5m. Then, find the amount of charge that passes through the conductor in coulomb.
(take g = 10 m/s2)

2. A charged particle of mass m = 5 gm and charge q = D C


        
12 C enters along AB at point A in a uniform magnetic
field of magnitude B = 100 Tesla existing in a         
rectangular region of size (8m  6m) and into the plane         
of paper as shown in figure. The particle leaves the          6m

region at ‘C’. The speed of the charge particle (in m/s)         


as it leaves the region is         
A B
8m

3. A particle having charge ‘q’ and mass ‘m’ is projected with velocity (4iˆ − 6ˆj + 3k)
ˆ m/sec from the origin
in a region occupied by electric field ‘E’ and magnetic field ‘B’ such that B = B ˆj and E = E ˆj (take 0 0
qE0
= 2 ). Find the time (in sec) when the magnitude of velocity of the charge particle becomes 5 5
m
m/sec. (neglect the gravity)

Space for rough work

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4. A positively charged particle is given an initial velocity v0 in XY y


plane as shown in diagram. Initially the particle was at origin
and the region contains uniform, mutually perpendicular
electric and magnetic field. Let E = −Ejˆ and B = Bkˆ . The E
60 v0
minimum magnitude of the magnetic field so that the charge
particle crosses the origin again during its subsequent motion
nE x
is Bmin = , find the integer value n. q, m
v0 B

5. A positive charge particle enters and comes out from a uniform  ‘B’ 
magnetic field which exists with direction inside the paper in a finite   37
space as shown in the figure. If the radius of curvature of the  
charge particle is 4 m, when it is inside the magnetic field. Find the  
width ‘d’ (in cm) of the region in which magnetic field exists.  
 
 
53  
d

6. A conducting rod AB of mass m and length  is


supported by conducting massless wires and carrying
a current I as shown in the figure. The rod is slightly
displaced into the paper such that rod always remains
parallel to x-axis and released to perform SHM. If its B a a
−1/ 4
ka   BI  
2

time period is 2 1 +  y
  . Find the value of
g   mg   m1
  x
k. A B
I

Space for rough work

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PART – A: (Multi Correct Answer Type)

This section contains 08 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
O
||
1. NH2 — CH — C — NH — CH2 — CO2H
|
CH3
Identify the amino acids obtained by hydrolysis of the above compound :
(A) Glycine (B) Phenylalonine
(C) Alanine (D) Glutamic acid

2. An ester A(C 4H8O2) on treatment with excess CH3MgBr followed by hydrolysis gives an alcohol B as
the only organic product.
Which of the following statements is / are true?
(A) A on basic hydrolysis gives formate ion as one of the product
(B) B gives positive iodoform test
(C) A on acid hydrolysis gives acetic acid as one of the products
(D) B gives immediate precipitate with Lucas reagent.

3. ()
CN ⎯⎯⎯⎯
i LDA
+ →?
NC
(ii) H3O
(iii) 
LDA is lithium diisopropylamide. Select the incorrect statements regarding the final product:
(A) It gives iodoform test (B) It undergoes Cannizzaro’s reaction
(C) It is a lactone (D) It is a ketone

Space for rough work

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4. In the following reaction sequence


+
N2 Cl−

→ ( A ) ⎯⎯⎯ → (B ) ⎯⎯⎯ → (C)


+
⎯⎯⎯
CuCN
HCN
H3O Br2
FeBr3

Which is/are not true about compound (C)?


(A) Compound ‘C’ is more acidic than compound ‘B’
(B) Compound ‘C’ on reaction with soda lime can form a compound which can undergo phenol
formation with aq. NaOH treatment under normal conditions of pressure and temperature
(C) Compound ‘C’ is more reactive towards electrophilic aromatic substitution than compound ‘B’
(D) Compound ‘B’ is more reactive towards electrophilic aromatic substitution than benzene

5. Which of the following statement(s) is(are) correct?


(A) Glucose requires phenyl hydrazine to give osazone
(B) Glyceraldehyde on oxidative cleavage with HIO 4 will give three different products
(C) Through Killiani – Fischer synthesis if we add two more C – atoms in chain to (D) – glyceraldehydes
total number of possible compounds will be four
(D) Hydrolysis of lactose gives one unit of  -D-glucose and one unit of  − D-galactose

6. You have a mixture of three amino acids: A (pI =3), B (pI = 5) and C (pI = 10), where pI represents their
isoelectric points. Under electrophoresis at pH = 8, the movement of each component of the mixture is
considered. Which of the following options are incorrect regarding movement of amino acids under
electrophoresis:
(A) A and B to anode; C to cathode
(B) A to anode; B stationary; C to cathode
(C) A to cathode; B stationary; C to anode
(D) A to anode; B and C to cathode

Space for rough work

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7. Identify the correct statement(s) out of the following sugars:


(A)  - D- Glucopyranose has a hemi acetal structure and is a reducing sugar
(B) Methyl  - D-Glucopyranoside has acetal structure and is a non-reducing sugar
(C)  - D-Glucopyranose and -D-Glucopyranose are anomers
(D) Lactose is a disaccharide and is a reducing sugar

8. Which is/are true regarding free radical polymerization of ethene?


(A) Polymerization is invoked by either peroxide initiator or radiation
(B) Polymerization is exothermic in nature
(C) Polymerization is endothermic in nature
(D) Molecular weight gain occur in propagation step of polymerization
PART – A: (Matrix Match)

This section contains 4 multiple choice questions. Each question has matching Column(s). The codes for the
Column(s) have choices (A), (B), (C) and (D) out of which only ONE is correct

Match the following and write the correct pairs.


List – I (Polymer) List – II
(I) Cellulose (P) Natural polymer
(II) Starch (Q) Synthetic polymer
(III) Nylon-6,6 (R) Linear polymer
(IV Protein Amide linkage
(S)
)
(T) Non reducing sugar

9. Which of the following options has the correct combination considering List-I and List-II?
Options
A. (I), (P), (T) B. (II), (Q), (T)
C. (III), (Q), (T) D. (IV), (S), (T)

10. Which of the following options has the incorrect combination considering List-I and List-II?
Options
A. (I), (P), (R) B. (II), (P), (T)
C. (III), (Q), (S) D. (IV), (Q), (R)

Space for rough work

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Match the reaction in LIST – I with their corresponding product(s) in LIST– II:
List – I List– II
(I) Na
R − CN ⎯⎯⎯⎯⎯→
+ C H
2 5 OH (P) 1 – amine
o

(II) (i) CH MgBr (1 mole ) (Q) Alcohol


R − CN ⎯⎯⎯⎯⎯⎯⎯⎯
3
(ii) H O

2

(III) R − CN ⎯⎯⎯⎯⎯
hydrolysis
→ (R) Ketone

(IV) R − NH2 ⎯⎯⎯⎯


2

HNO (S) Carboxylic acid

(T) N2(g) is evolved

11. Which of the following options has the correct combination considering List-I and List-II?
Options
A. (I), (S) B. (II), (S), (T)
C. (III), (P), (Q) D. (IV), (Q), (T)

12. Which of the following options has the correct combination considering List-I and List-II?
Options
A. (I), (P) B. (II), (S), (T)
C. (III), (P), (Q) D. (IV), (P, R)
PART – B: (Numerical Based Type)

This section contains 6 Numerical based questions, the answer of which maybe positive or negative numbers
or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30).

1. O

COOH
NH ⎯⎯⎯⎯⎯⎯
→ A ⎯⎯⎯⎯⎯→ + CH3 − CH2 − NH2
1. NaOH 1. conc. NaOH
2. CH 3 − CH2 − Cl 
80 % 2. dil. HCl/ 
60% yield
COOH
(B)
O
On starting with 2 moles of phthalimide, if x is the mass of A and y is the mass of B formed in gram.
Find the value of (x + y)? [Atomic mass: C = 12, H = 1, O = 16, N = 14 ]

Space for rough work

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2. A tetrapeptide has ⎯COOH group attached to a non – chiral carbon. This produces glycine (Gly),
Valine (Val), Alanine (Ala) and Leucine (Leu) on complete hydrolysis. For this tetrapeptide, the number
of possible sequences (primary structures) with ⎯NH2 group attached to a chiral carbon
is___________.

3. Br

( i) Mg, ether
O () 2
⎯⎯⎯⎯⎯ → ( X)
ii CO
( iii) H O+
3
C O
CH2CH3 H
The number of  - bonds in X is A, then the value of A/2 is __________.

4. How many of the following reagents can be used to detect C6H5NH2


 −
CHCl3/KOH, CS2/HgCl2, C6H5SO2Cl, H2O2/OH–, K 2S2O8, C6H5 N2 Cl

5. Teflon is manufactured by heating tetra fluoroethene with a free radical or per sulphate catalyst at high
pressure. Suppose each Telfon polymeric unit contains same number of carbon atoms. If 100 moles of
monomers form 25 moles of Teflon polymeric units, then find the number of carbon atoms present in
each polymeric unit.

6. Number of compound soluble in aqueous NaOH solution


COOH OH NO2 CH2OH COOH COOH SO3H H3C CH3
N

CH3
NO 2 OCH3

Space for rough work

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PART – A: (Multi Correct Answer Type)

This section contains 08 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

e x −1 ex
1. If  (x
− 5x + 4 )
2
2xdx = A.F(x – 1) + B.F(x – 4) + C and F ( x ) =  x
dx , then

2 4
(A) A = − (B) B =   e3
3 3
2 8 3
(C) A = (D) B =   e
3 3

/2
Let un =  cos
n
2. x cosnx dx it turns out that u1, u2, u3, ..... form a G.P. then
0
1 1
(A) the common ratio of G.P. is (B) the common ratio of G.P. is
2 4
 
(C) un = 2n
(D) un = n +1
2 2

x x
3. If a differentiable function f(x) satisfies the relation 
0

t f ( x − t ) dt = f ( t ) dt + sin x + cos x − x − 1 for all x
0
then which of the following does not hold good?
(A) f(0) = 1 (B) f(0) = 0

 f ( x ) dx = e

(C) f(0) = 2 (D)
0

t
4. 
If f ( x ) = e x , g(x) = x, x > 0 and F ( t ) = f ( t − x ) g ( x ) dx , then
0
(A) F(x) = 1, has two distinct solutions (B) f(x–3) = g(x) + 1, has two distinct solutions
f (x) 9
(C) f(x) / g(x) = e2, has two distinct solutions (D) − e2 = , has four distinct solutions
g( x) 2

Space for rough work

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-15

5. The roots, ,  are the roots of f(x) = 0, where f(x) = ax2 + bx + c = 0 (a  0), lie in the interval [0, 1],
then

(A) the maximum value of


( a − b )( 2a − b ) is 3
a (a − b + c )
( a − b )( 2a − b )
(B) the minimum value of is 2
a (a − b + c )
( a − b )( 2a − b )
(C) If is at its maximum value, then 2 + 2 can be 2
a (a − b + c )
( a − b )( 2a − b )
(D) If is at its maximum value, then 2 + 2 can be 1.
a (a − b + c )

  
 2 x  ln x  2 x  dx

If I1 = f  + 

dx , I2 = f  +  , I3 =
 x f (e + e − x ) dx then
x
6.
x 2 x x 2 x
0 0 −
I1
(A) I1  I2  I3 (B) = ln2
I2
(C) I1 + I2  I3 (D) I1 = (ln 2)I2 + I3

x 10 − x
7. 
For a differentiable function F(x) if , F ( x ) = f ( t ) dt +
0

0
f ( t ) dt , x  (0, 10) where f(x) = x3 – 15x2 + 48x

(A) x = 5 is a point of local minima (B) number of points of local maxima is 1


(C) F(x) is strictly increasing (D) x = 5 is a point of local maxima

8. If x1 and x2 are positive numbers between 0 and 1, then which of the following is/are true?
 x + x2  sin x1 + sin x 2  x + x2  tan2 x1 + tan2 x 2
(A) sin  1  (B) tan  1 
 2  2  2  2
2
 x + x2  log x1 + log x 2  x + x2  x12 + x 22
(C) log  1  (D)  1  
 2  2  2  2

Space for rough work

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-16

PART – A: (Matrix Match)

This section contains 4 multiple choice questions. Each question has matching Column(s). The codes for the
Column(s) have choices (A), (B), (C) and (D) out of which only ONE is correct

Answer the following by appropriately matching the list based on the information given in the
paragraph.

Consider the function f ( x ) = 2x 3 − 9ax 2 + 12a2 x − 5a


List – II
List – I
(exhaustive set of values of “a”)
 1 1  1 
(I) f ( x ) = 0 has only one real root if (P) a   − , −    ,1
 3 4 2 

(II) ( )
f e x = 0 has 3 real roots if (Q)


1  1 
a   −1, −    ,1
6  6 
f ( sin x ) = 0 has no or even number of real
 5
a   1,
(III)   
roots in  − ,  if
(R)  2 
 
 2 2
Exactly one root of f ' ( x ) = 0 lies between the  5  5 
a   −, −   ( −1,1)   , 
( )
(IV) (S)  
roots of x − 8ax + 15a − 2a − 1 = 0 if
2 2
 2   2 
 5 3
a−
 2 2 
(T) ,
 
 5 5
(U) a ,− 
 3 2 

9. Which of the following is the only CORRECT combination?


(A) (II), (T) (B) (II), (Q)
(C) (I), (U) (D) (I), (S)

10. Which of the following is the only CORRECT combination?


(A) (III), (Q) (B) (III), (R)
(C) (IV), (R) (D) (IV), (Q)

Space for rough work

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-17

Answer the following by appropriately matching the list based on the information given in the
paragraph.
List-I List-II
/3

(I)  tan ( x ) tan ( 2x ) tan (3x ) dx
0
(P)
8
ln 2

1
ln ( x + 1)

3
(II) dx (Q) – ln2
0
x2 + 1 2
1
dx
(III) If n – 1 

0 3 + x5 − 1 − x5
 n + 1, n  N, n is equal to (R) –1

2.3
n
 x − x  dx < n + 1, n  Z, then n is equal to
2
(IV) (S) 1
0
(T) ln2
(U) 3

11. Which of the following is the only CORRECT combination?


(A) (II), (T) (B) (II), (P)
(C) (I), (U) (D) (I), (S)

12. Which of the following is the only CORRECT combination?


(A) (III), (P) (B) (III), (S)
(C) (IV), (U) (D) (IV), (P)

Space for rough work

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-18

PART – B: (Numerical Based Type)

This section contains 6 Numerical based questions, the answer of which maybe positive or negative numbers
or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30).

1
29 (1 − x 4 ) dx

7

0
1. The value of 1
is equal to ____
4 (1 − x
 ) 6
4
dx
0

2. If g1(x) and g2(x) are two continuous function for x  [0, ), satisfying the functional equation (2f(x) +

0 ( g1 ( x ) − g2 ( x ) ) dx
3
x)(6f2(x) + 5xf(x) + x2) =0,  x  [0, ), then the value of

 x 2 + x − 1  x − 1
3. If [p, q) is the exhaustive interval of values of x, satisfying the equation  2 =  , then the
 x − x + 1  x + 1
p
 5 + 1
value of    x  + 2 
 dx , (where all the [.] denotes the greatest integer function)
q

x4 + 1 1x+2 2

0 x2 + 1 dx , then the value of ( 4I2 −  )(I1 )


1
0
4
4. If I1 = dx and I2 = is equal to _______
(x )
3/ 4
4
+2

 
ln x x I2
5. Let I1 =  1 + 3x + x 2
dx and I2 =  e− x + ex + 3 dx the value of I1
is _____
0 0

( ) ( )
3 2
6. If f ( x ) = 4 − x2 + 1 + 4 − x2 − 3 + 2 then the maximum value of f(x) is

Space for rough work

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-19

FIITJEE– Monthly Test–II (JEE-


Advanced)
PHYSICS, CHEMISTRY & MATHEMATICS
PT–2 CODE: 000000.1 PAPER–2

ANSWERS
PHYSICS (PART –I)
PART – A
1. A, D 2. B, C 3. A, B, C, D 4. B, C
5. C, D 6. A, B, C, D 7. B, C 8. B, D
9. A 10. D 11. A 12. C
PART – B
1. 6.25 2. 2 3. 8 4. 2
5. 80 6. 1

CHEMISTRY (PART–II)

PART – A
1. A, C 2. A, B 3. A, B, C 4. B, C, D
5. A, C 6. B, C, D 7. A, B, C, D 8. A, B, D
9. A 10. D 11. D 12. A

PART – B
1. 439.36 2. 6 3. 2.5 4. 4
5. 8 6. 5

MATHEMATICS (PART–III)

PART – A
1. A, D 2. A, D 3. A, B, D 4. A, C, B, D
5. A, B, C, D 6. A, B, C, D 7. B, D 8. B, D
9. D 10. A 11. B 12. B

PART – B
1. 7 2. 2.25 3. –1 4. 0.75
5. 0.50 6. 30

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-20

HINTS & SOLUTIONS


PHYSICS (PART –I)
PART – A
MVo 2
3. Fmag = therefore extension in the spring will be zero
L

4. First find centre of circular path and than use y


mv
PC = PQ = C Fm
qB 2
(q, m) Fm Q
arc length 
t=
v P x
Magnetic
field

5. Current per unit length V and then ampere’s law.

( ˆj + k)
ˆ
 k − ˆj 
6. Direction of magnetic field at P due to CD = îx   
2  2 
( ˆj − k)
ˆ  −k − ˆj 
Direction of magnetic field at P due to EF = − îx   
2  2 
Hence direction will be along − ĵ
Direction of magnetic field at ‘O’ due to upper frame along − î
Direction of magnetic field at O due to horizontal frame will be along − ĵ .

7. Let magnitude of magnetic field inside the wire at a distance r from the axis be B.
From Ampere’s circuit law

 Bd = 0iencl
r
r
 B(2r) = 0 j0 
0
a
2r  dr

0 j0r 2
 B= …(i)
3a
a
r 2
Further i = j
0
0
a
2rdr = j0 a2
3
3i
 j0 =
2a2
Outside the wire

 Bd = 0iencl
 B(2r) = 0i
 i
 B= 0
2r

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-21
y
8. Id = IRd sin  ˆi + cos ˆj 

r = R(1 + cos )iˆ − R sin ˆj 


90 − 
(−R cos , R sin )
r = R 1 + cos2  + 2cos  + sin2  a

 
= 2R cos   /2
2 O (R, 0) x
ˆi ˆj kˆ
Id  r = sin  cos  0 IR2 d
1 + cos  − sin  0 a

= IR2 d =  − sin2  − cos  − cos2   kˆ


 ˆ
= 2IR2 cos2   ( −k)d 
2

2IR2 cos2   d
 Id  r 0
dB1 = 0 = ˆ = 0I sec    d( −k)
 2  ( −k) ˆ
16R 2
4 | r |3 4 8R cos 
3 3/2
 
 /2  /2
0I  ˆ I     
B1 =
16R 
− /2
sec   ( −k)d
 2
 = 0 ln sec   + tan   
8 R   2   2   − /2
ˆ
( −k)

 2 + 1
=
0I
8R
ln ( ) (
2 + 1 − ln 2 −1 ) ( −kˆ ) = 8RI ln 
0

 2 − 1
ˆ = 0I ln
 ( −k)
4R
( ) ˆ
2 + 1 ( −k)

0I
B = 4B1 =
R
ln ( ) ˆ
2 + 1 ( −k)

Second Method
 
0Id sin  90 − 
 2 I 
dB = = 0 sec   d
   
2 16R 2
4 2R cos   
  2 
(
M = 4R + 2R I( +k)
2 2
)
ˆ = 2R2I(2 + )( +k)
ˆ

PART – B

1. Impulse, Ft = m 2gh


(iB)t = m 2gh …(i)
it = q …(ii)
m 2gh 5 2  10  5
q = = = 6.25 Coulomb
B 2 4

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-22

mv O
2. r= 
qB r
a r −b
sin  = , cos  =
r r
2
a r −b
2 r         
 r  + r  =1         
   
        
(a2 + b2 ) mv          b
 r= =
2b qB         
qB(a2 + b2 )         
v= = 2 m/s
2mb a

3. v y = uy + a y t
qE0
0 = 6− t1
m
t1 = 3 sec
v 2x + v 2y + v 2z = (5 5)2
42 + v 2y + 32 = 125
v y = 10 m/sec
v y = uy + a y t
qE0
10 = 0 + t2
m
 t2 = 5 sec
So, t = t1 + t2 = 8 sec

4. v=
v0
2
(
3iˆ + ˆj )
For crossing origin,
2m 2(v 0 / 2)
k = ; k is an integer
qB qE / m
 2E 
 B= k
 v0 
For minimum value; k = 1
2E
 Bmin =
v0

5. d = R cos 37 − R cos 53 37


d = 80 cm  
53 ‘B’
  37
 
R  
 
 
 
53  
d

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-23

F BI
6. tan  = =
mg mg 
1/ 2
T
(mg) + (F )   BI 2 
2 2

If gef = = g 1 +   
m2   mg   m F
−1/ 4
a   BI  
2
a
T = 2 = 2 1 +   
gef g   mg  
  mg

CHEMISTRY (PART–II)

PART – A
O
|| hydrolysis
1. NH2 — CH — C — NH — CH2 — CO2H ⎯⎯⎯⎯⎯⎯ → NH2 — CH — COOH + H2N — CH2 — COOH
| | Glycine
CH3 CH3
Alanine

O OH
CH3
1. Ex. CH3MgBr
2. H C O CH ⎯⎯⎯⎯⎯→
+
2CH3 CH CH3
CH3 2. H

3. N O O
N 
NC CN ⎯⎯⎯→
LDA
⎯⎯→ ⎯⎯⎯⎯⎯

Hydrolysis
⎯⎯→

NC NC COOH

4. +
N2 Cl− CN COOH COOH

⎯⎯⎯ →
CuCN +

HCN ⎯⎯⎯
H3 O
→ ⎯⎯⎯
Br2

Br
'B' 'C'
5. Glucose requires 3 moles of phenyl hydrazine to give osazone.
Glyceraldehyde on cleavage with HIO 4 gives
2 moles of HCOOH + 1 mole of HCHO
Through Killiani – Fischer synthesis we will be able to get following four products.
CHO CHO CHO CHO

H OH HO H HO H H OH

H OH H OH HO H HO H

H OH H OH H OH H OH

CH2OH CH2OH CH2OH CH2OH


Hydrolysis of lactose gives one unit of  − D-glucose and  -D-galactose.

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-24

PART – B

1. O O O

OH
NH ⎯⎯⎯⎯⎯⎯ →
1. NaOH
2. CH − CH − Cl
3 2
N CH2CH3 ⎯⎯⎯⎯⎯→
1. conc. NaOH

80% yield 2. dil. HCl/  OH
(A)
(B)
O O O
( 2 moles ) (1.6 moles ) + CH3 − CH2 − NH2
( 0.96 moles )
(Mass of A formed) x = 280 gm
(Mass of B formed) y = 159.36 gm

2. H H H H
H2N CONH CONH CONH COOH
R1 R2 R3 H
Choose R1, R2 and R3 groups from remaining  - amino acid groups. A total of 6 sequences will be
possible

3. COOH

CHO
C2H5
 −
4. Anilline on reaction with CHCl3/KOH, CS2/HgCl2, C6H 5SO2Cl,and C6H5 N2 Cl gives phenyl isocyanide,
mustard oil reaction, sulfonamide and coupling reaction respectively.

5. F F F F
100 C C ⎯⎯⎯⎯⎯→
Polymerization
25 C C
F F F F
4
Each polymeric unit contains a total of (4  2 = 8) carbon atoms.

MATHEMATICS (PART–III)

PART – A

1. A, D
e x −1 ( 2x ) 8 e x −1 2 e x −1
 x2 − 5x + 4 dx = 3  x−4
dx − 
3 x −1
dx

2. A, D
First use integrating by parts to show that
/2

 cos
n −1
un = x sin x sinnx dx
0

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-25
/2 /2

 cos  cos
n −1
= x cos(n − 1)x − n
x cosnx dx (Use sin nx sin x = cos(n – 1)x – cos nx cos x)
0 0
= un – 1 – un
u 1
 n =
un−1 2
 1  
We have, u1 = , un = n−1  = n+1
4 2 4 2
3. A, B, D
x x


0

t f ( x − t ) dt = f ( t ) dt + sin x + cos x − x − 1
0
x x


0
( x − t ) f ( t ) dt =
 f ( t ) dt + sin x + cos x − x − 1
0
x x x


0

0

f ( t ) dt − t f ( t ) dt = f ( t ) dt + sin x + cos x − x − 1
0
Again differentiating
f(x) = f(x) – sin x – cos x
Solving this linear differential equation
We get, f(x) e–x = e–x cos x + c
If x = 0, f(0) = 0  f(x) = ex – cos x

4. A, C, B, D
t t


F ( t ) = f ( t − x ) g ( x ) dx = e t − x xdx
0

0

  t


t
= et  − xe− x 0 − −e− x dx 
 0

= –t – 1 + e t

= et – (t + 1)

5. A, B, C, D
 b  b
 1 − a  2 − a 
   =  +  + 2 . Let 0      1   +    + 1  1
 b c  +1  +1  +1  +1  +1  +1
1 − a + a 
 
Maximum value is 3, if  = 0,  = 1 or  = 1,  = 1 and minimum value = 2, if  =  = 0.

6. A, B, C, D
2
Let = et  t = ln 2 – ln x  x = 2e–t then
x
 
I1 =  f ( e t + e − t ) ( ln2 − t ) dt = ln2  f (e
t
+ e − t ) dt − I3
− −

I2 =  f (e + e − t ) dt
t

−

 x f (e + e x ) dx = 0 as x f(e–x + ex) is an odd function


−x
 I3 =
−

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-26

7. B, D
F(x) = f(x) – f(10 – x)
Now observing the graph of f(x), we can easily see the sign scheme for
+ –
f(x) – f(10 – x) :
5

8. B, D
f(x) = sinx, f(x) = log x are concave down
and f(x) = tanx, f(x) = x2 are concave up.

9. D

10. A
(I) f ( x ) = 2x 3 − 9ax 2 + 12a2 x − 5a
f ( x ) has only one real root.
If f ' ( x ) = 0  6x 2 − 18ax + 12a2 = 0
x 2 − 3ax + 2a2 = 0
x = a,2a
f ( a ) .f ( 2a )  0

( 2a 3
)(
− 9a3 + 12a3 − 5a 16a3 − 36a3 + 24a2 − 5a  0 )
(5a 3
)(
− 5a 4a3 − 5a  0 )
5
a2  or a2  1
4
 5  5 
a   −, −  ,    ( −1,1)
 2   2 
 
(II) ( )
f e x = 0 has three real roots  f ( x ) = 0 has three positive roots
 f (0)  0  a  0
a,2a  0
f ( a ) f ( 2a )  0

(a 2
)(
− 1 4a2 − 5  0 )
5
1  a2 
4
 5
a   1,
 2 
 
(III) If f ( sin x ) = 0 has even number of roots, then f ( x ) has even no. of roots in  −1,1
If f ( x ) = 0 has odd no. of roots in  −1,1 then f ( −1) f (1)  0

( 2 − 9a + 12a 2
)( )
− 5a −2 − 9a − 12a2 − 5a  0

( 9a + 5a )2  ( 2 + 12a2 )
2

( 7a )2  (1 + 6a2 )
2

7a  1 + 6a2 and 7a  −1 − 6a2


1 1
a  (or) a  1and a  −1 or a  −
6 6

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-27

 1  1 
Whose complement is  −1, −    ,1
 6 6 
(IV) f ( x ) = x − 8ax + 15a − 2a − 1
2 2

f ( a )  0 and f ( 2a )  0
 1 1  1
a   − ,  and a   −, −   (1,  )
 4 2  3
a
(or)
f ( a )  0 and f ( 2a )  0
 1  1   1 
a   −, −    ,   and a   − ,1
 4 2   3 
 1 1   1 
 a   − , −    ,1
 3 4 2 

11. B

12. B
(I) We know tan 3x – tan x – tan 2x = tan 3x tan x tan 2x
/3 /3
 
0
( tan3x − tan x − tan2x ) dx =
 tan3x tan x tan2x dx
0
/3 /3
1 /3 1
=– ln | cos3x | + ln | cos x | 0 + ln | cos 2x |
3 0 2 0
1
=– ln1 + ln1/2 + 1/2ln1/2
3
= 3/2 ln1/2
1
ln ( x + 1)
(II) Let I =
0

x2 + 1
dx (put x = tan)

/4
I=
0
 ln (1 + tan ) d
/4
  
I=  ln 1 + tan  4 −    d
0
/4
    
2I =
0
 ln 1 + tan  + tan  4 −   + tan  tan  4 −    d
/4
2I =  ln2d
0

I= ln2.
8
1
dx
(III) Let I = 
0 3 + x − 1 − x5
5

1
Lt f(x) =
3 + x − 1 − x5 5

Clearly f(x) is decreasing


 f(1)  I  f(0)

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Sankalp 2123S & R_Paper-2-PCM(000000.1)-28

1 3 +1
I
2 2
 I  [0, 2]
−1 0  x 1

 0 1 x  1 + 5
 2
(IV) [x2 – x] = 
 1 + 5
1 x 2
2

 2 2  x  2.3
2.3
 1+ 5  3− 5 
 x − x  dx = –1(1) + 0  − 1 + 1 
2
 + 2(0.3)
 2   2 
0

3 5 1− 5 2.2 − 5
= –1 + − + 0.6 = + 0.6 =
2 2 2 2

PART – B
1. 7
1
Let I =  (1 − x )7 dx
4

0
1
 29 I = 28 (1 − x 4 ) dx

6

2. 2.25
x x
f ( x ) = − ,  x  R,f ( x ) = − ,  x  R
2 3
 x  x
− 2 ; x  0 − ; x0
 3
f (x) =  , f (x) = 
− x ; x  0 − x ; x  0
 3  2

3. –1
 5 − 1
[p,q)  0, 
 2 

4. 0.75
31/ 4
I1 = , I2 = 1 +  / 4
2

5. 0.50
I1
= 2.
I2

6. 30
Take x = 2 cos.
And make a cubic equation in |sin|

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