XII CHEM MQP 6 MS

KENDRIYA VIDYALAYA SANGATHAN: HYDERABAD REGION
MODEL QUESTION PAPER -6 (2024-25)

ANSWER KEY
CLASS: XII SUBJECT: CHEMISTRY (THEORY)
SECTION A
Q1 to Q16 each correct answer 1 mark Marks
1. b 1
2. a 1
3. b 1
4. b 1
5. c 1
6. d 1
7. a 1
8. b 1
9. b 1
10 b 1
.
11 a 1
.
12 b 1
.
13 c 1
.
14 a 1
.
15 a 1
.
16 c 1
.
SECTION B
This section contains 5 questions with internal choice in two questions.
Q17 to Q21 each correct carries 2 marks.
17 1
.
18 a)amide linkage between two amino acids 1

. b) linkage between two monosachharide units 1
OR
a) gluconic acid is formed 1
b) sachharic acid is formed 1
19 a) due to sp2 hybrid C atom,greater steric repulsion.higher
. electronegativity of C,partial double bond nature 1
b) intermediate involved is trigonal planar carbocation
1
OR
(CH3)2CH-CH(CH3)2 1
1
20 Reaction at anode: 1
. Pb(s) + SO4 2-(aq)→PbSO4(s)+2e –
Reaction at cathode: 1
2- − +
PbO2(s) + SO4 (aq)+4e +2H →PbSO4(s)+2H2O(l)
The overall reaction :
Pb(s) + PbO2(s) + H2SO4(aq)→2PbSO4(s)+2H2O(l)
21 a) 2HCHO+NaOH→CH3OH+HCOOH 1
. b) RCH2COOH + X2(red P)  RCH(X)COOH 1
SECTION C
This section contains 7 questions with internal choice in two questions.
Q 22 to Q 28 each correct carries 3 marks.
22 1
.
1
1
23 1
.
1
24 a) propan-2-ol 1
. b) salicaldehyde 1
c) methanol + t-butyl iodide 1
25 .a)aniline forms salt with AlCl3.
. b) aryl halides don’t undergo nucleophilic substitution with anion formed 1
by phthalimide
c) due to delocalization of lone pair of electron on nitrogen in aniline
1
1
26 (a) Deficiency of vitamin B12 (cyanocobalamin) causes the disease 1
. pernicious anaemia. 1
(b) Globular protein and its shape is spherical 1
(c )Phosphodiester linkage.
OR
(ii) Glucose on oxidation with HNO3 gives saccharic acid, This indicates 1
the presence
of a one primary alcoholic (-OH) group in glucose. 1+1
(iii) The pentaacetate of glucose dose not react with Hydroxylamine
which shows the
absence of free Aldehydic (---CHO) group.
27 a) C6H5Cl 1
. b) CH3CH2CN
c) pent-2-ene 1
1
28 (a) 3 1
. (b) i)[Zn(OH)4]2- ii) K2[Ni (CN)4] 1
1
SECTION D
Case-based questions. Each question has an internal choice and
carries 4 (1+1+2) marks each.
29 (i) All natural and artificial radioactive decay of unstable nuclei takes 1
. place by first order kinetics.
Hydrogenation of ethene and decomposition of N2O5 and N2O are also the
example of first 1
order reactions.
(ii) If we plot a graph between log[R0] / R0] vs t we get a straight line 1
with the slope = K/2.303
(iii) a. for first order reaction, t1/2 = 0.693 𝑘 And unit of k is s

1
-1
(b) rate constant (k) = 0.0693/ 60 min = 1.925 x 10 -4 s -1 1

OR 1
[R0]=100, [R]=100 – 30 – 70, t = 40min k= 2.303/t log [R0]/[R] =
2.303/40 log 100/70 = 2.303/40 * 0.1548 :. k = 8.91 * 10-3 min -1
30 (i) N,N-dimethylmethanamine 1
. (ii) Pentane 1,5-diamine 1
(iii) N-Ethyl N-Methyl Ethanamine 1
OR 1
4
SECTION E
Long answer type and carry 5 marks each. Two questions have an
internal choice.
31 i) Solute-solvent dipolar interactions exist in the pair of methanol and
. acetone. 1
ii) * To increase the solubility of CO2 in soft drinks and soda water, the
bottle is sealed under high pressure.
* To avoid a dangerous medical condition called bends, scuba divers use 1
oxygen diluted with less soluble helium gas.
iii) In positive deviations, the partial vapour pressure of each component A
and B of a solution and the total pressure of the solution is higher than the 1
vapour pressure calculated from Raoult’s law. For example, Water and
Ethanol.
iv) Gas (B) will have higher value of KH (Henry’s constant) than Gas (A) 1
at the same temperature
v) The phenomenon involved in the melting of snow on snow-covered
roads is the depression in the freezing point which is caused by the 1
addition of non volatile impurities to a liquid. The addition of salt (sodium
chloride) lowers the freezing point temperature of the water and thus,
helps in the melting of snow.
vi) When a non-volatile solute is added to a solvent, the surface area for
escape of solvent molecules decreases and vapour pressure gets lowered.
vii) Water from NaCl solution passes into cells &they swell. Finally they
will burst
32 i) iodoform test 1
. ii) sodium bicarbonate test
b)
½x4
OR
a.Phenol + neutral FeCl3 violet colouration
Benzoic Acid + Na2CO3 Evolution of CO2 or brisk effervescence 1
b.
c.
1
d. C6H5CHO< CH3CHO < HCHO 1
e. 4-methoxy benzoic acid < benzoic acid < 4-nitro benzoic acid 1
33
. a) Cr is stable in d3 state(t2g 3) but Mn is stable in +2 state(d5)
b) due to comparable energies of 5f,6d and 7s orbitals in actinoids. 1
c) due to d-d transition (1m) 1
d) Cr2O7 -2 + 14H+ +6 Fe+2 →2Cr+3 + 6 Fe+3 + 7H2O 1
e)2 Mno4_ +5 C2O4 2-+16 H+ → 2Mn+2 + 8H2O + 10 CO2 1
OR 1
a. Cr is reducing as its configuration changes from d4 to d3 , the latter
2+
having a half-filled t2g level. On the other hand, the change from Mn3+ to
Mn2+ results in the half-filled (d5 ) configuration which has extra stability.
b. Divalent ion  3d5 So μ = [n(n+2)]½ = [5(5+2)]½ = 5.9 BM
c. MnO4- + 5Fe2+ + 8H+ Mn2+ + 5Fe3+ + 4H2O
d. 4 FeCr2O4 + 8 Na2CO3 + 7O2 → 8 Na2CrO4 + 2Fe2O3 + 8CO2
2Na2CrO4 + 2 H+ → Na2Cr2O7 + 2 Na+ + H2O
Na2Cr2O7 + 2KCl K2Cr2O7+2NaCl
************************

XII CHEM MQP 6 MS

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KENDRIYA VIDYALAYA SANGATHAN: HYDERABAD REGION

MODEL QUESTION PAPER -6 (2024-25)

18 a)amide linkage between two amino acids 1

(iii) a. for first order reaction, t1/2 = 0.693 𝑘 And unit of k is s

(b) rate constant (k) = 0.0693/ 60 min = 1.925 x 10 -4 s -1 1

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