PT4/ANNUAL EXAMINATION, 2023

2023-24
CHEMISTRY
Time – 3 hrs. Class – XI M.M. – 70
Name of the student ______________________________________ Section ____ Date - 09.02.2024 (Friday)

GENERAL INSTRUCTIONS:-
a. There are 33 questions in this question paper with internal choice.
b. SECTION A consists of 16 multiple-choice questions carrying 1 mark each.
c. SECTION B consists of 5 very short answer questions carrying 2 marks each.
d. SECTION C consists of 7 short answer questions carrying 3 marks each.
e. SECTION D consists of 2 case-based questions carrying 4 marks each.
f. SECTION E consists of 3 long answer questions carrying 5 marks each.
g. All questions are compulsory.
h. The use of log tables and calculators is not allowed.
SECTION A
(The following questions are multiple choice questions with one correct answer. Each question
carries 1 mark. There is not internal choice in this section.)
Q.1 If the density of a solution is 3.12 g mL–1, the mass of 1.5 mL solution in significant figures is
__________.
a) 4680 × 10–3g b) 4.7g c) 47.80g d) 4.680g
Q.2 What is the mass per cent of carbon in carbon dioxide?
a) 0.034% b) 27.27% c) 3.4% d) 28.7%
Q.3 The kinetic energy of the ejected electrons in the photoelectric effect is:
a) directly proportional to the frequency of the incident radiation
b) inversely proportional to the frequency of the incident radiation
c) not related to the frequency of the incident radiation
d) all of the above
Q.4 The number of radial nodes for 3p orbital is ______.
a) 3 b) 4 c) 2 d) 1
Q.5 The hydrogen bond is strongest in:
a) F-H ---- O b) F-H ----- F c) O-H ----- S d) O-H ----- N
Q.6 The bond order and the magnetic characteristics of CN − are
a) 3, diamagnetic b) 2.5 paramagnetic c) 3, paramagnetic d) 2.5, diamagnetic
Q.7 Which of the following are iso-electronic species?
a) CO2, NO2 b) NO2−, CO2 c) CN − , CO d) SO2, CO2
Q.8 The enthalpies of elements in their standard states are taken as zero. The enthalpy of formation
of a compound is:
a) is never negative. b) may be positive or negative.
c) is always negative. d) is always positive.
Q.9 Enthalpies of formation of CO(g), CO2(g), N2O(g), and N2O4(g) are –110, –393, 81, and 9.7 kJ
mol-1 respectively. Find the value of ΔrH for the reaction:
N2O4(g) + 3CO(g) → N2O(g) + 3CO2(g)
a) – 850 kJ b) –600 kJ c) –778 kJ d) –802 kJ
PT4/ANNUAL EXAM | 2023-24 | CL. 11 | CHEMISTRY | PRINTED Q 33 PRINTED PAGES 5 | PAGE# 1
Q.10 Values of standard electrode potential of three metals X, Y and Z are -1.2V,
1.2V, +0.5V and -3.0V
respectively. The reducing power of these metals will be in order
a) X > Y > Z b) Y > Z > X c) Y > X > Z d) Z > X > Y
Q.11 I.U.P.A.C. name of 4-isopropyl
isopropyl-m-xylene is
a) l-Isopropyl-2, 4-Dimethyl
Dimethyl benzene b) 4-Iso propyl-m-Xylene
c) l-Isopropyl-3, 5-Dimethyl
Dimethyl benzene d) 4-Isopropyl-3, 5-Dimethyl
Dimethyl benzene.
Q.12 An aqueous solution of compound A gives ethane on electrolysis. The compound A is?
a) Sodium propionate b) Sodium acetate c) Sodium ethoxide d) Ethyl acetate
Select the most appropriate answer from the options given below -
a) Both A and R is individually true, and R is the correct explanation of A.
b) Both A and R is individually true, but R is not the correct explanation of A.
c) A is true but R is false
d) A is false but R is true
Q.13 Assertion (A): The resonance structure is hypothetical and individually represents any real
molecules.
Reason (R): According to the resonance theory the actual structure of benzene cannot be
adequately represented by any of these structures.

Q.14 Assertion (A): Addition of HBr on in the presence of peroxide give as

major product.
Reason (R): The addition of HBr on alkene proceeds by carbo
carbocation
cation intermediate.
Q.15 Assertion: N2 + 3 H2 ⇌ NH3; ∆H = –92 kJ. High pressure favours the formation of ammonia.
Reason: An increase of external pressure on the above reaction at equilibrium favours the
reaction in the direction in which the number of moles decreases.
Q.16 Assertion: The gas-phase reaction PCl3(g) + Cl2(g) ⇌ PCl5(g) shifts to the right on increasing
pressure.
Reason: When pressure increases, equilibrium shifts towards more number of moles.
SECTION – B
(This section contains 5 questions with internal choice in one questions.
The following questions are very short answer types and carry 2 marks each.)
Q.17 The empirical formula of a compound is CH2O and its molecular weight is 90. What is the
molecular formula of the compound?
Q.18 Draw the structure
ture of the following compounds.
a) 2-methyl -3-isopropyl
isopropyl heptane b) Dicyclopropyl methane.
OR
Draw the Newman projection formula for different conformations of ethane.
Q.19 Would you expect the second electron to gain enthalpy of oxygen as positive, more negative
or less negative than the first one? Give reason.
Q.20 Write the shape and hybridization of PCl5 and SF6 molecules.
wavelength 3.6 (1 = 10-10 m)
Q.21 Calculate the mass of a photon with wavelen
SECTION – C
(This section contains 7 questions with internal choice in one question.
question
The following questions are very short answer types and carry 3 marks each.)
Q.22 Explain with the help of suitable examples polar and non-polar covalent bonds.
Q.23 Answer the following:
a) Two litres of an ideal gas at a pressure of 10 atm expands isothermally at 25°C into a vacuum
until its total volume is 10 litres. How much heat is absorbed and how much work is done in the
expansion?
b) Identify the state functions and path functions out of the following.
Enthalpy, entropy, heat, temperature, work, free energy
c) If the enthalpy of fusion and enthalpy of vaporisation of sodium metals are 2.6 & 98.2 kJ
mol-1 respectively, what is the enthalpy of sublimation of sodium?
Q.24 In the reactions given below, identify the species undergoing oxidation and reduction.
a) H2S(g) + Cl2(g) → 2HCl(g) + S(s)
b) 3Fe3O4(s) + 8 Al(s) → 9 Fe(s) + 4Al2O3(s)
c) 2Na (s) + H2(g) → 2NaH(s)
OR
Write the net ionic equation for the reaction of potassium dichromate (VI), K2Cr2O7 with
sodium sulphite, Na2SO3, in acid solution to give chromium (III) ion and sulphate ion.
Q.25 What are electrophiles and nucleophiles explain with examples?
Q.26 Write IUPAC names of the products obtained by the ozonolysis of the following compounds?
a) Pent-2-ene b) 3,4-Dimethylhept-3-ene c) 2-Ethylbut-1-ene
Q.27 An element ‘X’ with atomic number 114, has been recently predicted. Write its electronic
configuration and predict.
a) its group b) its block in which this element would be placed
Q.28 Commercially available concentrated hydrochloric acid (HCl) contains 38% HCI by mass.
a) What is the molarity (M) of the solution (density of solution = 1.19 g mL-1)
b) What volume required of concentrated HCI is to make 1.0 L of a 0.10 M HCI?
SECTION - D
The following questions are case-based questions. Read the passage carefully and answer the
questions that follow. Each question carries 4 marks.
Q.29 A process or change is said to be reversible, if a change is brought out in such a way that the
process could, at any moment, be reversed by an infinitesimal change. A reversible process
proceeds infinitely slowly by a series of equilibrium states such that the system and the
surroundings are always in near equilibrium with each other. Processes other than reversible
processes are known as irreversible processes.
In thermodynamics, a distinction is made between extensive properties and intensive properties.
An extensive property is a property whose value depends on the quantity or size of matter
present in the system. For example, mass, volume, internal energy, enthalpy, heat capacity, etc.
are extensive properties. Those properties which do not depend on the quantity or size of matter
present are known as intensive properties. For example, temperature, density, pressure etc. are
intensive properties. A molar property, Xm, is the value of an extensive property X of the
system for 1 mol of the substance. Another example is molar volume.

PT4/ANNUAL EXAM | 2023-24 | CL. 11 | CHEMISTRY | PRINTED Q 33 PRINTED PAGES 5 | PAGE# 3

 Measurement of ∆U and ∆H: We can measure energy changes associated with chemical or
physical processes by an experimental technique called calorimetry. In calorimetry, the process
is carried out in a vessel called a calorimeter, which is immersed in a known volume of a liquid.
Knowing the heat capacity of the liquid in which the calorimeter is immersed and the heat
capacity of the calorimeter, it is possible to determine the heat evolved in the process by
measuring temperature changes. Measurements are made under two different conditions:
i) at constant volume, qV ii) at constant pressure, qP
1) For adiabatic change, q = 0 then …
a) ∆U = wad b) ∆U = q+w c) ∆U = w – q d) ∆U = wrev
2) The technique for measuring energy changes associated with chemical or physical processes by
an experimental technique called …
a) colourimetry b) calorimetry c) titration d) photometry
3) A property whose value depends on the quantity or size of matter present in the system is
known as …
a) Extensive b) Intensive c) Reversible d) Irreversible
4) The enthalpies of all elements in their standard states are equal to –
a) unity b) zero c) < 0 d) different of each element
Q.30 Organic compounds are formed by covalent bonding. The nature of covalent bonding can be
described with the help of hybridisation, sp, Sp2 and sp3. The structure and reactivity depend
upon the type of bonds present in organic compounds. The organic compound can be
represented by various structural formulae, Wedge and Dash's formula is a 3-D representation.
Organic compounds can be classified based on functional groups. Organic reaction mechanisms
are based on the structure of the substrate and the attacking reagent.
The intermediate formed can be free radical, carbocation, carbanion or carbene. The attacking
reagent can be electrophile or nucleophile. The inductive, electromeric, resonance and hyper
conjugative effects may help in the polarisation of covalent bonds. Organic reactions may be
considered substitution, addition, elimination and rearrangement, oxidation and reduction
reactions.
After the compound is obtained in the pure state, qualitative analysis helps to detect elements
present in organic compounds whereas quantitative analysis helps to find the percentage of
various elements. Dumas and Kjeldahl's method helps to determine the percentage of nitrogen,
and Carius's method for halogens and sulphur. Carbon and hydrogen are estimated by the
amount of CO2 and H2O formed. Phosphorus estimation is done by oxidising it to H3 PO4, and
sulphur to H2 SO4, The percentage of oxygen is determined by taking the difference of 100 and
the percentage of all elements. Empirical formula gives simple ratios of elements whereas
molecular formula gives an exact number of atoms of each element present in a compound.
a) What are free radicals?
b) Write the decreasing order of stability of carbocations. (10, 20, 30)
c) In the estimation of sulphur, which compound of sulphur is formed as precipitate.
d) In the Carius method of estimation of halogen, 0.15 g of an organic compound gave 0.12 g of
AgBr. What is the percentage of bromine in the compound?
(Given molar mass of AgBr = 187.78 g/mol)
PT4/ANNUAL EXAM | 2023-24 | CL. 11 | CHEMISTRY | PRINTED Q 33 PRINTED PAGES 5 | PAGE# 4
 SECTION - E
The following questions are long answer type and carry 5 marks each. All questions have an
internal choice.
Q31. Answer the following:
a) What happens to the equilibrium constant when temperature increases for a reaction?
b) State Le Chatelier’s principle.
c) Classify the following into lewis acids and
an lewis bases:
(i) H2O (ii) NH3 (iii) H+ (iv) BF3
(v) AlH3 (vi) ROH (vii) CH3NH2 (viii) CN −
(ix) CH3+
OR
a) What is common ion effect?
b) What is the difference between ionic product and solubility product?
c) pka of acetic acid and pkb of ammonium
ammon hydroxide are 4.76 and 4.75 respectively. Calculate
the pH of the ammonium acetate solution.
Q.32 Write the structure of the following compound :
a) 3− Oxopentanal.
b) 3-Hydroxybutanal
c) 2-Hydroxycyclopentane carbaldehyde
d) Which of the two structures CH3COOH and CH3COO– is more stabilized by resonance?
Explain.
e) Will CCl4 give a white precipitate of AgCl on heating it with Ag
Ag. Explain.
OR
a) How will you convert benzene into
(i) p–nitrobromobenzene (ii) p – nitrotoluene (iii) Acetophenone
b) Arrange the following in decreasing order of acidic behaviour. Also give reason for this.
benzene, n-hexane
hexane and ethyne
Q.33 a) What is de Broglie wave equation? How did de Broglie explain the dual behaviour of
matter?
b) If the position of the electron is measured within an accuracy of ±0.002
0.002 nm, calculate the
uncertainty in the momentum of the electron. Suppo Suppose
se the momentum of the electron
h
is × 0.05 nm,, is there any problem in defining this value?
4πm
OR
(a) How many sub-shells
shells are associated with n = 4
(b) How many electrons will be present in the sub
sub-shells having ms value of -1/2
1/2 for n = 4 ?
(c) What are Quantum Numbers?
(d) Calculate- (i) frequency and (ii) wave
wave-number
number of yellow radiation having wavelength 5800 .