18-01-2025

1001CJM202036240013 JM

PART-1 : PHYSICS

SECTION-I

1) Choose correct option regarding given circuit.

(A) Potential difference across 4μF is 20V

(B) Charge at 3μF is 8μC
(C) Energy stored in 2μF is 32μJ
(D) Ratio of charges on 3μF & 11μF are 3 : 11

2) A solid cylinderical wire of radius 'R' carries a current 'I'. The magnetic field is 5μT at a point,
which is '2R' distance away from the axis of wire. Magnetic field at a point which is R/3 distance
inside from the surface of the wire is :-

(A)

(B)

(C)

(D)

3) To verify Ohm’s law, a student is provided with a test resistor RT, a high resistance R1, a small
resistance R2, two identical galvanometers G1 and G2, and a variable voltage source V. The correct
circuit to carry out the experiment is :-

(A)
(B)

(C)

(D)

4) In the circuit shown A and B are two cells of same emf E but different internal resistances r1 and
r2 (r1 > r2) respectively. Find the value of R such that the potential difference across the terminals of

cell A is zero after long time after the key K is closed :-

(A)

(B) R = (r1 – r2)

(C) R = r1 + r2

(D)

5) A fully charged capacitor C with initial charge Q0 is connected to a coil of self inductance L at t =
0. The time at which are energy is stored equally between the electric and the magnetic field is :-

(A)

(B)
(C)
(D)

6) The magnetic field of an electromagnetic wave is given by

The associated electric field will be :

(A)

(B)

(C)

(D)

7) A pipe open at both ends has a fundamental frequency f in air. The pipe is dipped vertically in
water so that half of it is in water. The fundamental frequency of the air column is now :

(A) f

(B)

(C)

(D) 2f

8) The maximum intensity in Young's double-slit experiment is I0. Distance between the slits is d =
5λ, where λ is the wavelength of monochromatic light used in the experiment. What will be the
intensity of light in front of one of the slits on a screen ?
(Given that screen is at a distance D = 10 d)

(A) I0

(B)

(C)

(D)

9) Focal length of a biconvex lens in air is 40 cm. The focal length of the lens in water is 120 cm. If

refractive index of water is , then what is refractive index of the material of the lens

(A) 1.4
(B) 1.5
(C) 1.6
(D) 1.7

10) A particle of mass 'm' is projected from ground with velocity 'u' making angle θ with the vertical.
The de-Broglie wavelength of the particle at the highest point is -

(A)
(B) h/mu sinθ
(C) h/mu cosθ
(D) h/mu

11) What is the number of α and β- particle emitted in the following radioactive decay ?
200
90X → 80Y168

(A) 6 and 6
(B) 8 and 8
(C) 8 and 6
(D) 6 and 8

12) In the network shown in figure determine V :-

(A) 11V
(B) 12V
(C) 9.5 V
(D) 13V

13) Identify the logic gate G in the combination of gates shown in figure. The truth table is shown
here

A B Y

0 0 0

0 1 0

1 0 1

1 1 1

(A) OR gate
(B) AND gate
(C) NOR gate
(D) XOR gate

14) A 15 g mass of nitrogen gas is enclosed in a vessel at a temperature 27°C. Amount of heat
transferred to the gas, so that rms velocity of molecules is doubled, is about :
[Take R = 8.3 J/ K mole]

(A) 10 kJ
(B) 0.9 kJ
(C) 6 kJ
(D) 14 kJ
15) In a rotor a hollow vertical cylindrical structure rotates about its axis and a person rests against
the inner wall. At a particular speed of the rotor, the floor below the person is removed and the
person hangs resting against the wall without any floor. If radius of rotor is 2m and μs = 0.2 what

will be the minimum angular velocity at which floor may be removed :-

(A) 2 rad/s
(B) 5 rad/s
(C) 10 rad/s
(D) None of these

16) A U-tube in which the cross-sectional area of the limb on the left is one quarter, the limb on the
right contains mercury (density 13.6 g/cm3). The level of mercury in the narrow limb is at a distance
of 36 cm from the upper end of the tube. What will be the rise in the level of mercury in the right

limb if the left limb is filled to the top with water :-

(A) 1.2 cm
(B) 2.35 cm
(C) 0.56 cm
(D) 0.8 cm

17) A ball of mass m is fired vertically upwards from the surface of the earth with velocity nve, where
ve is the escape velocity and n < 1. Neglecting air resistance, to what height will the ball rise?
(Take radius of the earth as R)

(A)

(B)

(C)

(D) Rn2

18) A particle travels such that where

a is constant. Its initial velocity is v0. The time at which it stops is :-

(A)
(B)

(C)
(D)

19) A force f is acting on a block of mass m. Coefficient of friction between block & surface is µ. The

block can be pulled along the surface if :-

(A) tan θ ≥ µ
(B) cot θ ≥ µ

(C)

(D)

20) Given the moment of inertia of a disc of mass M and radius R about any of its diameters to be
MR2/4, find its moment of inertia about an axis normal to the disc and passing through a point on its
edge.

(A)

(B)

(C)

(D)

SECTION-II

1) Find out work done by electric field in shifting a point charge μC from point P to S which are

shown in the figure is J. Then find x.

2) A microscope is focused on an object at the bottom of a bucket. If liquid with refractive index 5/3
is poured inside the bucket, then microscope have to be raised by 30 cm to focus the object again.
The height of the liquid in the bucket is (in cm) :

3) A rest helium atom emits a photon of wavelength 0.1Å. The recoil energy of the atom due to the
emission of photon will be (in eV)

4) A thermometer graduated according to a linear scale reads a value x0 when in contact with boiling
water, and x0/3 when in contact with ice. What is the temperature of an object in ºC, if this
thermometer in the contact with the object reads x0/2 ?

5) A particle undergoing simple harmonic motion has time dependent displacement given by

. The ratio of kinetic to potential energy of this particle at t = 210 s will be :

PART-2 : CHEMISTRY

SECTION-I

1) At what ratio of total pressure of reaction

X ⇌ 2Y and Z ⇌ P + Q have same value of Kp if degree of dissociation of X and Z are same :-

(A) 1 : 36
(B) 1 : 4
(C) 1 : 9
(D) 1 : 3

2) For reaction A → B, the rate constant

k1 = A1 and for the reaction
X → Y, the rate constant k2 = A2 .
If A1 = 108, A2 = 1010 and = 600 cal/mol,
= 1800 cal/mol, then the temperature at which k1 = k2 is :
(Given : R = 2 cal/K-mol)

(A) 1200 K
(B) 1200 × 4.606 K

(C)

(D)

3) From the following E° values, of half cells :-

(i) A + e → A–, E° = –0.34
(ii) B– + e → B2–; E° = + 1.30 V
(iii) C– + 2e → C3–; E° = – 1.30
(iv) D + 2e → D2– ; E° = + 0.78 What combination of two half cells would result in a cell with the
largest potential ?

(A) ii and iii

(B) ii and iv
(C) i and iii
(D) i and iv

4) 1 Mole of liquid A and 2 moles of liquid B make a solution having observed vapour pressure of 42
torr. The vapour pressure of pure A and pure B are 45 torr and 36 torr respectively. The described
solution :-

(A) is an ideal solution

(B) shows negative deviation
(C) is a minimum boiling azeotrope
(D) has volume less than the sum of individual volumes of both components.

5) 17.4% (W/V) solution of potassium sulphate

(mol. wt. = 174) is isotonic with 4% (W/V) aqueous solution of NaOH. If NaOH is 100% ionised, the
degree of ionisation of potassium sulphate is :-

(A) 50%
(B) 75%
(C) 40%
(D) 60%

6) Suppose two elements X and Y combine to form two compounds XY2 and X2Y3. If 0.05 mole of XY2
weighs 5 g while 3.011 × 1023 molecules of X2Y3 weighs 85 g, then atomic masses of X and Y are
respectively :

(A) 20, 30
(B) 30, 40
(C) 40, 30
(D) 80, 60

7) Find enthalpy of neutralisation of NH4OH and HCN in aqueous solution if enthalpy of ionisation of
NH4OH and HCN are 7 kJ/mol and 8 kJ/mol. also enthalpy of ionisation of H2O is 57.3 kJ/mole.

(A) –15 kJ/mol

(B) – 42.3 kJ/mol
(C) +1 kJ/mol
(D) 42.3 kJ/mol

8) [Co(NH3)5NO2] Cl2 and [Co(NH3)5ONO]Cl2

are related to each other as :-

(A) Geometrical isomers

(B) Linkage isomers
(C) Coordination isomers
(D) ionisation isomers

9)
Which of the following show colour due to charge transfer ?

(A) MnO4¯
–2
(B) Cr2O7
–2
(C) CrO4
(D) All

10) Which element is having lowest melting and boiling point?

(A) Ti
(B) Cu
(C) Zn
(D) Mn

11) Which of the following pairs is expected to form colourless compound :

(A) La+3, Pr+3

(B) La+3, Lu+3
(C) Nd+3, Pm+3
(D) Eu+3, Tb+3

12) Which of the following reaction is not feasible :-

– –
(A) F2 + 2Cl → 2F + Cl2
– –
(B) Cl2 + 2Br → 2Cl + Br2
– –
(C) Br2 + 2F → 2Br + F2
– –
(D) Br2 + 2I → 2Br + I2

13) Most basic is :-

(A) KOH
(B) NaOH
(C) Mg(OH)2
(D) ClOH

14) Which of the following cations is not precipitated by NH4Cl + NH4OH ?

(A) Al3+
(B) Cr3+
(C) Fe2+
(D) Fe3+

15)
Major product is :

(A)

(B)

(C)

(D)

16)
Compound (B) is :-

(A)

(B)

(C)

(D) (A) and (C) both

17) The correct IUPAC name of the compound :-

(A) (2R, 3R)-3-bromo-2-butanol

(B) (2R, 3S)-3-bromo-2-hydroxy butane
(C) (2R, 3S)-3-bromo-2-butanol
(D) (2S, 3R)-2-bromo-3-butanol

18)
How many molecules of RMgX are consumed in the above given reaction ?

(A) 2
(B) 4
(C) 5
(D) 6

19) The end product (B) of the reaction sequence :-

(A)

(B)

(C)

(D)

20) The best method for synthesis of given ether by Williamson's ether synthesis is :

(A)

(B)

(C)

(D)

SECTION-II

1) A weak acid 0.1M HA is 1% ionised, pH of the solution will be –

2)

How many of the following on heating will produce an oxide of nitrogen ?

(NH4)2Cr2O7, NH4NO3, NH4NO2, KNO3, Pb(NO3)2

3) Out of B2, C2, N2, N2+, O2–, how many species are paramagnetic?

4) Total number of aromatic compounds among the following compounds is _____.

5) X g of ethylamine is subjected to reaction with NaNO2/HCl followed by water; evolved
dinitrogen gas which occupied 2.24 L volume at STP. X is ____ × 10–1 g

PART-3 : MATHEMATICS

SECTION-I

1) Let P(x) = x2 + bx + c be a quadratic polynomial with real coefficients such that P(x)dx = 1
and P(x) leaves remainder 5 when it is divided by (x – 2). Then the value of 9 (b + c) is equal to :

(A) 9
(B) 15
(C) 7
(D) 11

2) Let A = {x1, x2, x3, x4, x5, x6, x7} and

B = {y1, y2, y3} The total number of onto function from f : A → B. If exactly three element x in set A
such that f(x) = y1 is equal to -

7
(A) 12 × C3
7
(B) 15 × C3
7
(C) 16 × C3
7
(D) 14 × C3

3) The number 'a' is randomly selected from the set {0, 1, 2, 3, ...... 98, 99}. The number 'b' is
selected from the same set. Probability that the number 3a + 7b has a digit equal to 8 at the units
place, is :

(A)

(B)

(C)

(D)

4) If matrix A = [aij]3×3, B = [bij]3×3, where

aij + aji = 0 and bij – bji = 0 ∀ i, j, then A4B3 is :-

(A) singular
(B) zero matrix
(C) symmetric
(D) skew symmetric

5) Let M = and N = .
If (a–b)2 +(d–e)2 = 36, (b–c)2 +(e– f)2 = 64,
(a – c)2 + (d – f)2 = 100, then value of |N| is equal to :

(A) 1152
(B) 48
(C) 144
(D) 288

6) If w is an Imaginary fifth root unity, then

(A) 2
(B) 1
(C) 0
(D) None

7) If ,
then range of (fog(x)) is :

(A) (0, 1]
(B) [0, 3)
(C) [0, 1]
(D) [0, 1)

8)
is equal to

(A)

(B)
(C)

(D)

9) Suppose

Then the value of f '(0) is equal to

(A) π
(B) 0
(C)

(D)

10) For 0 < a < 1, the value of the integral

is :

(A)

(B)

(C)

(D)

11) The integral

is equal to :

(A)

(B)

(C)

(D)

12) If y = y(x) is the solution curve of the differential equation (x2 – 4) dy – (y2 – 3y)dx = 0,

x > 2, y(4) = and the slope of the curve is never zero, then the value of y(10) equals :
(A)

(B)

(C)

(D)

13) For , if

then is equal to :

(A)

(B)

(C)

(D)

14) The distance, of the point (7, –2, 11) from the line along the line

is :

(A) 12
(B) 14
(C) 18
(D) 21

15) If the shortest distance of the parabola

y2 = 4x from the centre of the circle
x2 + y2 – 4x – 16y + 64 = 0 is d, then d2 is equal to :

(A) 16
(B) 24
(C) 20
(D) 36

16) Let a1, a2, ….. a10 be 10 observations such that

 and . Then the standard deviation of a1, a2, .., a10 is equal to :

(A) 5
(B)
(C) 10
(D)

17) Let R be the interior region between the lines 3x – y + 1 = 0 and x + 2y – 5 = 0 containing the
origin. The set of all values of a, for which the points (a2, a + 1) lie in R, is :

(A)

(B)

(C)

(D)

18) Let e1 be the eccentricity of the hyperbola and e2 be the eccentricity of the ellipse

, a > b, which passes through

the foci of the hyperbola. If e1e2 = 1, then the length of the chord of the ellipse parallel to the
x-axis and passing through (0, 2) is :

(A)

(B)

(C)

(D)

19) If α, – < α < is the solution of

4 cosθ + 5 sinθ = 0, then the value of tan α is :

(A)

(B)

(C)

(D)
20) The sum of the solutions of the

equation = x3 – x2 + 6 is :

(A) 0
(B) 1
(C) –1
(D) 3

SECTION-II

1) For the series

if the of the first 10 terms is K, then equal to

2) Let f(x) = 2x – x2, x ∈ R. If m and n are

respectively the number of points at which the curves y = f(x) and y = f'(x) intersects the x-axis, then
the value of m + n is :

3) Let ,
where g is a continuous odd function.

If ,
then α is equal to…..

4) The least positive integral value of α, for which the angle between the vectors and
is acute, is :

5) The mean and standard deviation of 15 observations were found to be 12 and 3 respectively. On
rechecking it was found that an observation was read as 10 in place of 12. If µ and σ2 denote the
mean and variance of the correct observations respectively, then 15(μ + μ2 + σ2) is equal to
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B C A A D A B C B C A B A B C C A D A

SECTION-II

Q. 21 22 23 24 25
A. 3 75 2 25 3

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B D A C A C B B D C B C A C A A C B A C

SECTION-II

Q. 46 47 48 49 50
A. 3 2 3 1 45

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C D D A D A D C C C A A D B C B B C C C

SECTION-II

Q. 71 72 73 74 75
A. 5 119 2 5 2521
 SOLUTIONS

PART-1 : PHYSICS

1)

V2 = ∴ V1 = 8V = 24 V
∴ Charge at 3μf = CV = 1μF × 8V = 8μc

2) r = 2R, 5µT =

At distance from suface means from centre.

= =

3) Voltmeter is a galvanometer with high resistance in series. Ammeter is a galvanometer with

small resistance in parallel

4) After long time L → Conductor

C → Blocks current
VA = 0
ε – ir1 = 0
ε = ir1

r1 + r2 + = 2r1
5) As ω2 = or ω =

Maximum energy stored in capacitor =

Let at any instant t, the energy be stored equally between electric and magnetic field. The

energy stored in electric field at instant t is

or or

0
⇒ Q cosωt =

or ωt =

or t =

6) If we use that direction of light propagation will be along . Then (4) option is correct.
Detailed solution is as following.
Magnitude of E = CB
E = 3 × 108 × 1.6 × 10–6 ×
E = 4.8 × 102
and are perpendicular to each other ⇒ . = 0
⇒ either direction of is or
From given option

Also wave propagation direction is parallel to which is ⇒ is along

7)

v = fλ v = f'λ

8) Path difference, Δx =

Here, y =
and D = 10d = 50λ (as d = 5λ)

So, Δx =
 Corresponding phase difference will be

or

9)
μo = R.I. of surrounding

;3=

; =2
μ = 1.6

10)

Velocity at higher point = u sinθ

λD =
0
11) 90X200 → 80Y168 + a × 2α4 + b × –1β

12) Direction of current ID is in the same direction as arrow in the diode symbol. Both the
diodes are in "on" state; hence voltage drops across their terminal and are 0.7 V and
0.3 V respectively. The network function because E = 12 V > (0.7 V + 0.3 V). The circuit is
redrawn as in figure.

V0 = E – VT1 – VT2 = 12 – 0.7 – 0.3 = 11V

14) Q = nCvΔT as gas in closed vessel

Q=
Q = 10000 J = 10 kJ

17) By conservation of energy

Re + h =

h=

h = Re

18)

at t = 0 v = V0

∴
put v = 0

19) F sin θ ≥ f ...(1)

f = µ(mg – F cos θ) ...(2)
mgsinθ ≥ µmg(1-cosθ)

cot ≥µ

20) Given, I = So, MI of disc about an axis passing through centre

and perpendicular to the disc, is given by

→ IC = 2I = (from ⊥r axis theorem)

Now, to calculate MI about an axis normal to the disc and passing through a point on the
edges, we use parallel axis theorem.

So, I = + MR2 =

21) Work done by electric field :

w = PEi – PEf = q [Vi – Vf]
 work done = J

22)

23)

Patom = Pphoton =

KE =

24)

⇒ &

25) k =

U=

Hence ratio is 3 (most appropriate)

PART-2 : CHEMISTRY

26) X ⇌ 2Y Z ⇌ P+Q
1 – α1 2α1 1 – α2 α2 α2
 (α1 = α2) Given

27)

29) vapour pressure expected by Raoult's law,

= 39 torr.
Thus observed vapour pressure (42 torr) is greater than expected value. Hence this solution
shows positive deviation and therefore form minimum boiling azeotrope.

31) 0.05 mol XY2 = 5 gm

1 mol XY2 = = 100

X + 2Y = 100 ...(i)
3.01 × 1023 molecule X2Y3 = 85 gm
1 mol X2Y3 = NA molecule = 170 gm
2X + 3Y = 170 ...(ii)
On solving,
X = 40, Y = 30

35) Zn has no unpaired e–

0
36) La+3 has f & Lu+3 has f14 configuration so no possibility of f–f transition.

37) Br2 + 2F– → 2Br– + F2

(this reaction is not possible)

43)
 46) [H+] = Cα = 0.1 × = 10–3 M
pH = – log [H+] = – log 10–3 = 3
Ions in aq. solution

47)

(NH4)2Cr2O7 N2 + Cr2O3 + 4H2O

NH4NO3 N2O + 2H2O
NH4NO2 N2 + 2H2O
KNO3 KNO2 + O2
Pb(NO2)2 PbO + 2NO2 + O2

49)

50) CH3CH2–OH +
given : N2 evolved is 2.24 L i.e. 0.1 mole.
i.e. CH3CH2NH2 (ethyl amine) will be 4.5 g
(= 0.1 mole)
Hence the answer = 45 × 10–1 g

PART-3 : MATHEMATICS

52) 7C3 × 1 × (24 – 2)

53)
Case-1 : 3a → end with 1 and
7b → end with 7
Case-2 : 3a → end with 7 and
7b → end with 1
Case-3 : 3a → end with 9 and
7b → end with 9

54)

Hence aij = –aij ⇒ AT = –A and BT = B and A, B are 3 × 3 matrices,

Hence |A| = 0 ⇒ |A4B3| = 0 ⇒ A4B3 is singular.
55)

Δ= ×6×8=

; |M| = 48

|N| =

|N| = |M|2 = = 288

56) Here w5 = 1 ;
& also

Now

57)
By (1) x ∈ ϕ
And by (2)

Range of is [0, 1]

58) Using L’ hopital rule

=

= =

59)

= =

60)

61) I =

Let
Hence option (A) is correct

62)

At ;

At x = 10 ;

as

63)
Put sinx = t

∴C=0

64) B = (2λ +7, -3λ – 2, 6λ + 11)

Point B lies on

-3λ – 6 = 0
λ = –2
B ⇒ (3, 4, –1)

65) y2 = 4x
a=1
Point p(t2, 2t)
centre of circle (25)
z = d2 = (t2 – 2)2 + (2t – 8)2

= 2 (t2 – 2). 2t + 2 (2t – 8).2

After solving
t=z
P(4, 4), centre (2, 8)
d2 = (4 – 2)2 + (4 – 8)2
= 4 + 16 = 20

66)
a1 + a2 + … + a10 = 50 ….(i)

....(ii)
If a1 + a2 + … + a10 = 50.
(a1 + a2 + … + a10)2 = 2500

, Standard deviation ‘σ’

67) P(a2, a + 1)
L1 = 3x – y + 1 = 0
Origin and P lies same side w.r.t. L1
L1(0) . L1(P) > 0
3(a2) – (a + 1) + 1 > 0
⇒ 3a2 – a > 0

…….(1)
Let L2 : x + 2y – 5 = 0
Origin and P lies same side w.r.t. L2

......(2)
Intersection of (1) and (2)

68)

Also, ellipse is passing through

a = 5 and b = 3

End point of chord are

∴ LPQ =

69)
Squaring :

and is Rejected.
70) = x3 – x2 + 6

= x3 – x2 + 6

= x3 – x2 + 6

= x3 – x2 + 6
x3 – x2 + 2 = 0 ⇒ (x + 1)(x2 – 2x + 2) = 0
so, sum of real solutions = –1

72)

; ∴ m + n = 119

73)

(g is odd)
is also odd

Now, …..(1)
 …..(2)

;∴ α=2

74)

⇒ α2 – 4α – 4 > 0
⇒ α2 – 4α + 4 > 8 ⇒ (α – 2)2 > 8
or

α∈(– ∞, – 0.82) ∪ (4.82, ∞)

Least positive integral value of a ⇒ 5

75) Let the incorrect mean be and standard deviation be σ'

We have m' = = 12 ⇒ Σxi = 180

As per given information correct
Σxi = 180 – 10 + 12

⇒ μ (correct mean) =
Also

σ' = = 3 ⇒ Σxi2 = 2295

Correct = 2295 – 100 + 144 = 2339

σ2 (correct variance) =
Required value = 15(μ + μ2 + σ2)

= 2521