The document is a JEE revision practice sheet focused on thermodynamics and thermochemistry, containing multiple-choice questions and integer-type questions related to various thermodynamic concepts. It covers topics such as heat of reaction, entropy, heat capacity, and work done in different processes. An answer key is provided at the end for self-assessment.
The document is a JEE revision practice sheet focused on thermodynamics and thermochemistry, containing multiple-choice questions and integer-type questions related to various thermodynamic concepts. It covers topics such as heat of reaction, entropy, heat capacity, and work done in different processes. An answer key is provided at the end for self-assessment.
The document is a JEE revision practice sheet focused on thermodynamics and thermochemistry, containing multiple-choice questions and integer-type questions related to various thermodynamic concepts. It covers topics such as heat of reaction, entropy, heat capacity, and work done in different processes. An answer key is provided at the end for self-assessment.
The document is a JEE revision practice sheet focused on thermodynamics and thermochemistry, containing multiple-choice questions and integer-type questions related to various thermodynamic concepts. It covers topics such as heat of reaction, entropy, heat capacity, and work done in different processes. An answer key is provided at the end for self-assessment.
Single Correct Type Questions 5. For the reaction 3O2 → 2O3; ∆H = +ve, we can say: 1. Which of the following statements is/are correct? (1) O3 is more stable than O2 (1) The entropy of the universe decreases and (2) O3 is less stable than O2 increases at a periodic rate (3) Both are equally stable (2) The entropy of the universe increases and (4) Formation of O3 is exothermic tends towards the maximum value (3) For endothermic spontaneous processes the 6. In which of the following process ∆H and ∆U are total entropy change decreases of same magnitude (4) The entropy of the universe decreases and (1) Evaporation of CCl4 (l) tends to zero (2) CaCO3 (s) → CaO(s) + CO2 (g) (3) NH4 Cl(s) → NH4 Cl(g) 2. Calculate magnitude of the work done by system in (4) 2HI(g) → H2 (g)+ I2 (g) an irreversible (single step) adiabatic expansion of 1 mole of a polyatomic gas from 300K and pressure 7. The heat capacity of a diatomic ideal gas subjected 10 atm to 1 atm.( = 1.33). to a process such that absolute temperature is (1) 1.683 kJ (2) 3.36 kJ proportional to cube of its volume is given by : (3) 4.24 kJ (4) 0.84 kJ 5R 7R (1) (2) 3. The heat of neutralization of a strong acid by a 2 2 strong base is a constant for all strong acids and 17R 3R (3) (4) strong bases because: 6 2 (1) The strong acid and strong base react completely 8. The work done (calories) in adiabatic compression (2) The strong acid and strong base dissociate of 2 moles of ideal monoatomic gas against completely and only H+ and OH– ions react in constant external pressure of 2 atm starting from every case initial pressure of 1 atm and initial temperature of (3) The salt formed undergoes hydrolysis 300 K. (4) None of these (R = 2cal / mole degree) (1) 360 4. Statement-1: Adiabatic free expansion of any (2) 720 substance in a closed system will not cause any (3) 800 change in temperature of the substance. (4) 1000 Statement-2: In adiabatic free expansion of any substance in a closed system, internal energy will 9. Calculate magnitude of resonance energy of CO2(g) remain constant. from the following data. (1) Statement-1 is true, statement-2 is true and Hcombustion of CO = –280 kJ / mole statement-2 is correct explanation for Hf CO = –120 kJ/mol statement-1. Hatomisation of C(graphite)= 720 kJ / mole (2) Statement-1 is true, statement-2 is true and HBE O = O = 500 kJ mol–1 statement-2 is NOT the correct explanation for HBE C = O = 710 kJ /mol statement-1. (1) 200 Kj (3) Statement-1 is true, statement-2 is false. (2) 220 kJ (4) Statement-1 is false, statement-2 is true. (3) 140 kJ (4) 100 kJ 1 10. What will be Hneutralization of H2C2O4 with NaOH can be released at constant pressure if total 2600 per mole of H2C2O4 if acid is assumed to be gm of A and B are taken is given by completely unionized in the solution? (1) 200 kJ (2) 1800 kJ (Given Hionization (H2C2O4) = 20 kJ/mol) (3) 900 kJ (4) 450 kJ (1) 37.5 kJ/mole (2) – 75 kJ/mole (3) – 95 kJ/mole (4) –37.5 kJ/mole 15. If a certain mass of gas is made to undergo separately adiabatic and isothermal expansions to 1 the same pressure, starting from the same initial 11. H2 (g) + O2 (g) → H2 O(l) conditions of temperature and pressure, then, as 2 compared to that of isothermal expansion, in the BE (H – H) = x1; BE(O = O) = x2 case of adiabatic expansion, the final BE(O – H) = x3 (1) Volume and temperature will be higher Latent heat of vaporization of water liquid into (2) Volume and temperature will be lower water vapour = x4, then ∆f H (heat of formation of (3) Temperature will be lower but the final liquid water) is volume will be higher x (1) x1 + 2 – x3 + x4 (4) Volume will be lower but the final 2 temperature will be higher x (2) 2 x3 – x1 – 2 – x4 2 16. Match column I with column II x Column-I Column-II (3) x1 + 2 – 2 x3 – x4 2 (A) Enthalpy (p) Intensive property x (B) Temperature (q) Path function (4) x1 + 2 – 2 x3 + x4 2 (C) Free energy (r) Function of U, P and V 12. The dissolution of NH4Cl in water is endothermic (D) Work (s) State function even though NH4Cl dissolves in water A B C D spontaneously. Which one of the following best (1) P R Q S explains this behaviour? (2) Q R P R (1) The bonds on solid NH4Cl are weak (3) R, S P, S S, R Q (2) The entropy-driving force causes dissolution (4) S P Q R (3) Endothermic processes are energetically favourable 17. A solution of 500 mL of 2M KOH is added to 500 (4) The dissolving process is unrelated to energy mL of 2M HCl and the mixture is well shaken. The rise in temperature T1 is noted. The experiment is 13 H2(g) + 1⁄2 O2(g) → H2O(l); ∆H⊖ = –68 kcal then repeated using 250 mL of each solution and K(s) + H2 O(l) + aq → KOH(aq) + 1⁄2 H2; ∆H⊝ = rise in temperature T2 is again noted. Assume all –48 kcal heat is taken up by the solution: KOH(s) + aq → KOH(aq); ∆H⊝ = –14 kcal (1) T1 = T2 From the above data, the standard heat of formation (2) T1 is 2 times as larger as T2 of KOH in kcal is (3) T2 is twice larger as T1 (1) –68 + 48 – 14 (2) –68 – 48 + 14 (4) Cannot be predicted (3) 68 – 48 + 14 (4) 68 + 48 + 14 Integer Type Questions 14. Two solids A and B having molar masses 200 & 18. Water expands when it freezes. Determine amount 300 react to form another solid C as shown. of work in joules, done when a system consisting 2A(s) + 3B(s) ⎯→ C(s) of 1.0 L of liquid water freezes under a constant If Hcombustion of A, B and C are –200 , –300 & pressure of 1.0 atm and forms 1.1 L of ice. magnitude of work –400 kJ respectively then maximum heat which 19. Oxygen is heated from 300 K to 600 K at a constant C2H4(g) + H2(g) → C2H6(g) pressure of 1 bar. What is the increase in molar Data : entropy? The molar heat capacity in JK–1 mol–1 for Bond C – C C=C C–H H–H the O2 is. Bond 336.81 606.68 410.87 431.79 CP = 25.5 + 13.6 × 10–3 T – 42.5 × 10–7 T2 Enth kJ/mol kJ/mol kJ/mol kJ/mol alpy 20. Fixed amount of an ideal gas contained in a sealed rigid vessel (V = 24.6 litre) at 1.0 bar is heated 24. The heat of combustion of formaldehyde(g) is reversibly from 27°C to 127°C. Determine change –134 kcal mole-1 and the heat of combustion of in Gibb's energy (in Joule) if entropy of gas paraformaldehyde(s) is –122 kcal per (1/n) S= 10 + 10–2 T (J/K). Report only magnitude. (CH2O)n. Calculate the heat of polymerization of formaldehyde to paraformaldehyde. report only 1 1 magnitude. 21. The heat of reaction H2(g) + Cl2(g) ⎯⎯ → 2 2 HCl(g) at 27°C is –22.1 kcal. Calculate the heat of 25. From the following data, reaction at 77°C. The molar heat capacities at C(graphite) + O2(g) → CO2(g) H°rxn = – 390 kJmol–1 constant pressure at 27°C for hydrogen, chlorine & 1 HCl are 6.82, 7.70 & 6.80 cal mol–1 respectively. H2(g) + O2(g) → H2O(l) H°rxn = – 285 kJmol–1 2 Report only magnitude. 2C2H6(g) + 7O2(g) → 4CO2(g) + 6H2O(l) H°rxn 22. At 298 K, H°combustion (sucrose) = – 5737 kJ/mol = – 3120 kJmol–1 & G°combustion (sucrose) = –6333 kJ/mol. Estimate Calculate the enthalpy change for the reaction additional non-PV work that is obtained by raising 2C(graphite) + 3H2(g) → C2H6(g) temperature to 310 K. Assume rCP = 0 for this temperature change.
