Eor Methods-Msc 1 2013
Eor Methods-Msc 1 2013
Eor Methods-Msc 1 2013
EOR Methods
Instructor:
Office Hours:
Reference:
EOR Methods
EOR Methods
Topics covered: The general description of different natural driving
procedure. The course will introduce the solution gas drive or depletion
drive, the natural water drive, the gas-cap drive, compaction and
liquid expansion drive, and gravitational segregation drive. The course
will introduce the secondary recovery procedures immiscible water
drive and immiscible gas drive. The course will introduce the basic
theory of the different enhanced oil recovery and enhanced gas or gascondensate recovery procedures. The topic will cover the different
water and gas displacement calculation method. The theoretical
basement of recovery factor increasing methods also will be
introduced. The topic also covers miscible gas displacement procedures
(including CO2 injection), the thermal recovery methods, the polymer
and micellar (tenside) flooding. The topic also includes screening
procedure of EOR methods, and the calculation methods that can be
used for panning and forecasting the different type EOR Procedures.
EOR Methods
The course will include the following modules:
EOR Methods
The course will include the following modules:
Chemical flooding
Polymer flooding
Micellar flooding
EOR screening
Enhanced gas recovery methods (EGR)
Enhanced gas recovery of conventional gas reservoirs
Improvement of the gas recovery
Improvement of the gas-condensate recovery
Additional gas-condensate (and gas) recovery
EOR Methods
Pre-requisite Courses:
Reservoir Engineering Fundamentals
Class Attendance: We expect students to come to all
classes, attendance records will be taken and significant
absences reported to university management.
5% of the total course score will be deducted for students
with more than four unexcused absences; in addition, no
make up will be allowed of any quiz or exam taking place
during an unexcused absence.
Note: Students must bring their scientific calculators for
quizzes and tests.
EOR Methods
Getting Help: Every effort will be made to help you master
the course material, and the instructor is usually available
during the office hours shown above, both for this purpose
and to discuss more general course choice issues etc.
Grades: Grades will be assigned on an absolute basis
(criterion-based grading) using the weighting formula
below.
Final mark
91% or above
81% to 90%
71% to 80%
60 to 70%
Below 60%
Grade
5, excellent
4, good
3, satisfactory
2, pass
1, fail
EOR Methods
Final mark
91% or above
81% to 90%
71% to 80%
60 to 70%
Below 60%
Grade
5, excellent
4, good
3, satisfactory
2, pass
1, fail
Grade Weighting:
Attendance
5%
Short Quizzes
35 %
Final Exam
60 %
Total
100 %
EOR Methods
Quizzes: Quizzes (approx. 30-45 mins) will be given at the
end of course sections to provide motivation for keeping up
to date with the course material and to identify problems in
grasping new concepts. Quizzes will cover material
discussed in the previous lectures, homework assignments
and can be both open and closed book.
EOR Methods
Examinations: The major examinations will generally be
closed book but may include open book segments. The final
examination will cover all of the material in the course.
Class Ethics: The Petroleum Engineering Department
enforces a zero-tolerance and maximum-penalty policy on
academic dishonesty. Any and every student attempting or
committing any form of academic dishonesty will be subject
to the maximum sanctions permitted by university rules.
Recovery factor
5% - 25%
Factors give the favorable condition: Large gas cap; High permeability;
Low oil viscosity; Homogenous formation
Recovery factor
35% - 55%
(in special case 75%)
Strong water influx will reduce the recovery from gas reservoir
Energy supplied
by water expansion
Energy supplied
by surface water
Recovery factor
Unfavorable condition
negligible
(in special case 75%)
1.9287 10 3 k o A
qo
0.433 o g sin
o Bo
q o m 3 / d , k o mD, o cP, A m 2
[-]
[m3]
[m3]
[m3]
1
z L z dl z dl
EV
h
h
Lh
h
L
z; (z)
I
EM
Si S
E
Si Sr
*
D
Si Sr
EM
Si
Si S Si Sr Si S
ED
Si Sr Si
Si
where:
Si
Sr
B B
ED i
Si
Bi
where:
Bi - formation volume factor of oil or gas at initial pressure [m 3/m3],
B
ER ED EV EA
k ro o k ro w
krw, kro - relative permeability of water and oil , respectively, at the
average saturation of the water and initial saturation of
the oil (Soi). that is krw = krw( Sw ), kro = kro(Soi),
w, o - viscosity of the water and oil.
The areal efficiency usually is given as a function of mobility ratio
(M), the water cut (fw) and the floodable pore volume of the injected
fluid
V
V
i
VD
Vi
VD
Vp
Sor
Vp S oi S or
Five-spot System
Line-drive System
1 - EA
a1 ln M a 2 a 3 f w a 4 ln M a 5 a 6
EA
R
= ratio of producing rate of corner well to side well,
(p)i.c = pressure difference between injection well and corner well,
(p) i.s = pressure difference between injection well and side well.
Units in these equations are: bbl/day, D, ft, psi, and cP.
R
= ratio of producing rate of corner well to side well,
(p)i.c = pressure difference between injection well and corner well,
(p) i.s = pressure difference between injection well and side well.
Units in these equations are: bbl/day, D, ft, psi, and cP.
R
= ratio of producing rate of corner well to side well,
(p)i.c = pressure difference between injection well and corner well,
(p) i.s = pressure difference between injection well and side well.
Units in these equations are: bbl/day, D, ft, psi, and cP.
2
l
FA
L
EsE
L
2A
lsp2r
Surface- and Interfacial Tension
A
soswwocoswo
T
Wettability
so
wo
sw
- interfacial tension between the rock and the lighter fluid (oil),
- interfacial tension between the two fluids,
- interfacial tension between the rock and the water,
- angle of wetting measured always in the denser phase.
Wettability
V
o
s
p
w
s
p
I
w
otV
t
A
W
lo
g12
Wettability
Amott
USBM
V
V
o
s
p
w
s
p
I
wW
olo
tg
o
t
A
12
Wettability
Amott
USBM
Wettability
Wettability
Absolute water-wet
Strongly water-wet
Intermedier (neutral)
Strongly oil-wet
Absolute oil-wet
Wettability
Krss G10 computer controlled contact angle measuring device
Wettability
Fud2r2hw(ocosw0o)gh(w0)g2wocroswo
Capillarity
po*hogpwc*2howcrgosopwcopwh(wo)g
Capillarity
c
R
1
2
1R
0)
1R
122corswoh(w
Capillarity
Capillarity
P
k
c
J(S
)w
w
1
2
c12c
os
Capillarity
E
EpBA2cros
*
*
i
i
E
rE
r
D
M
DD
M
Residual Oil Saturation
Correlation Relationships
The residual saturation of the non-wetting fluids independent of the
viscosity and the displacement velocity
No correlation relationship between the residual oil saturation and
the permeability
There is a week relationship betweenen the residual oil saturation
and the porosity
E
0.4710.7W
0.13k0.158logpo2cosr112
R
SorvagySgr0.6219
Correlation Relationships
iN
sC
ccap
V
oN
fS
u
r
c
e
v
lcco
yivo
c
o
s
o
w
w
0
.
4
oiovro
rowowcoswoo0.4owV
v
V
cosS
oi
or
Correlation Relationships
(Melrose J.
Bradner C. F. 1974)
v
u
w
ow
v
V
o
i
o
r
0
.
4
N
cSoiorwcos o owV
w
cos
Correlation Relationships
Filtration velosity
S
.0gtorSgit8209.3217Sg2it0.857Sgit
0
Correlation Relationships
Residual saturation for three phases
CRAIG JR. F. F. (197 1) has come to the conclusion that in oil-wet rock the
residual oil saturation is not decreased by the gas saturation using water flooding.
In this case only the mobility of water which is decreased and so the water cut is
decreased (a similar effect is takes place with the displacement by polymers). This
statement follows from the fact that the wetting oil is located on the wall of the
rock and the gas is located inside the pore reducing the cross section of the pore
channel for the water filtration. Consequently, the water effective permeability is
decreasing.
Swgogow
Correlation Relationships
The value of interfacial forces wg, og, ow and its relation to each
other determine the property of crude oil, i.e. whether it spread s or
not. Moreover it determines whether the oil is forming a continuous
phase or not.
S > 0 the oil spreads on the water forming continuous phase. This
render it possible for the oil to flow at even very low oil saturation
S < 0 no continuous oil film is formed the flow becomes more difficult
and the oil recovery will be harmfully influenced
The distribution coefficient at water wet rock has great influence on
the oil recovery factor , but there is no effect on the recovery factor
in case of oil wet rock.
The oil recovery factor in case of water wet rock is greater than the
oil wet rock
- porosity
dt - time (element), [d]
q w Au w Au t f w
dx f u t f w 1 f w 2
q fw1 f w 2
dt
S w 1 S w 2 A S w 1 S w 2
dx
dt
Sw
q df w
A dS w
q df w
A dS w
Sw Sw1
Sw
q f w1 f w 2
A S w1 S w 2
df w
dS w
Welge H. J. (1952)
Sw
fw
S w S wc
Saturations which are larger than the front saturation (S w > Swf) travel
at smaller velocities due to angles of tangents which become smaller and
smaller as the saturation increases.
The angle ( 2) of the tangent is drawn from point (Swc, 0) is larger than
1. Therefore the velocity of the displaced irreducible water is higher
than that of injected water . S*wf means the water saturation at leading
edge of injected water (or trailing edge saturation of displaced connate
water); Swf means leading edge of displaced connate water
Ax f S wi ASwi x f x*f
Sw
x1S w 1 x 2S w 2
x1 x 2
Willhite G. P. (1986)
*
x f S wf x*fS*wf q t t f wf f wf
Swi
*
xf xf
A x f x*f
x f S wf S wi x*fS*wf
xf
qtt
f wf
A S wf S wi
*
f
q
t
x*f t *wf
A S wf
qtt
*
f wf f wf
A
q t t f w
x
A S w
*
f
Buckley-Leverett
*
f w
f wf
*
S wf S w
S*wf
S*wf
Polymer Flood
It is assumed that the polymer dissolves only in water and its
adsorption by the rock takes place instantaneously. According to the
discussed mathematical model the concentration of the polymer
solution is always constant. Consequently, the volume of the polymer
slug decreases continuously due to adsorption, as the slug progresses
through the rock.
In other words: the volume of water ahead of polymer slug is
increasing continuously until the water breakthrough. This water
consists of irreducible water and polymer-free water due to
adsorption.
Polymer Flood
S w C
q f w C
1 r A i
0
t
t
A x
- porosity, [-]
Sw - water saturation, [-]
C - polymer concentration in the injected water, [g/cm 3]
t
- time, [s]
r - density of rock, [g/cm3]
Ai - quantity of adsorbed polymer by 1 g rock, [g/g]
q - rate of the injected polymer solvent, [cm 3/s]
A - cross section, perpendicular to the direction of flow, [cm 2]
fw - water fraction of the stream [-],
x - distance, [cm]
Cs [g/cm3] - the quantity of adsorbed polymer by 1 cm 3 pore volume
Cs
1
r A i
S w C C s q f w C
0
t
A x
Polymer Flood
Determine the additional oil recovery by polymer flooding
S w C C s q f w C
0
t
A x
After differentiation
S w
q f w
0
t
A x
Sw
dCs f w qf w C
dC At A x
S w Di C qf w
t
C
0
A x
C0
dx
dt
q
fw
A S w D i
Polymer Flood
Assume Swi = Swc
The polymer solvent completely displaces the connate water, the
volume of which is increasing continuously due to its accumulation
and polymer adsorption.
During the displacement two shocks are usually formed: oil is
isplaced with low viscosity water and the saturation of this is S w2, and
water fraction is fw2 (first shock).
After this the polymer water displaces the oil and water bank, which
is ahead of it. Saturation in front of the polymer solvent bank is S w3
and the water fraction (with the polymer) is fw3.
Polymer Flood
The process presented in is based on the model of Pppe G. A. (1980 )
Polymer Flood
****
***
q fw 2
A S w 2
q
fw 3
A S w 3 Dp
Polymer Flood
q fw 3 fw 2
v
A S w 3 S w 2
*
q df 3
v
A dS w
**
Sw 3
Polymer Flood
Given that the velocities are the same
f w 3 f w 2 df w
S w 3 S w 2 dS
Sw 3
fw 2
fw3
S w 2 S w 3 Dp
Polymer Flood
During the calculation of the polymer flooding, it can be assumed that
the polymer injection is a continuous one, opposite to the slug injection.
This approach can be accepted due to the polymer displacement
mechanism: because of the polymer adsorption on the rock surface, the
mobility reduction related to the water is constant, regardless of how
the polymer is injected (i.e. in the form of a slug or continuously).
This calculation process has been modified by LAKE L. W. (1989), who
took into consideration the fact that a fraction of the pore volume is
inaccessible for polymer (Vipv) . The velocity of the polymer solvent, if
Vipv is taken into consideration
v ****
fw 3
q
A S w 3 Dp Vipv
Vipv - inaccessible pore volume for the polymer solvent referring to the
pore volume, which should be flooded, in the fraction [-].
Polymer Flood
Considering the breakthrough time, the effect of D p and Vipv is the
opposite. The adsorption holds up the polymer breakthrough, while Vipv
helps it. Cumulative oil production (Np) is calculated using the change of
saturation as a function of time:
Np
X
A
Sw
Swi
AX
Sw S wi
B0
Polymer Flood
Green D. W. and Willhite G. P. (1998) verified that three fronts
could exist
Polymer Flood
In the case of system 1 (or straight line 1) the tangent is drawn from
point (-Dp1, 0) to the fractional curve of the oil-polymer solvent (f *w),
(tangent point is 3), and its intersection with the fractional curve of the
oil-water is marked by II.
Point II is located above point 1; this is the tangent point of that tangent
which is drawn from point (Swc, 0). In this case (rock type 1) the
saturation distribution is
Polymer Flood
Green D. W. and Willhite G. P. (1998) verified that three fronts
could exist
Polymer Flood
In the case of system 2 (or straight line 2) only two front forms have a
Dp2 retardation coefficient (rock type 2). The intersection of tangent 2 to
the polymer solvent oil fractional curve (tangent point 2) and water-oil
fractional curve is marked I. Point 1 is located above point I.
So the water saturation of the water slug, consisting of connate water, is
higher than the water saturation of the oil bank, which follows it.
The "oil bank" makes this "water bank" oily and this results the
disappearance of this front and finally the two fronts remain.
Swi>Swc ???