MSDS Training Presentation

1
What is MSDS
 Material Safety Data Sheet is Horoscope of the

Chemical.
 MSDS Reveals the properties of chemical, its
nature, different hazards, preventive measures in
storage & handling, First Aid measures.
 It has 16 (Ten) sections
Section-1
Identification of the substance or mixture

and of the supplier
•Identification of Chemical/Mixture
•Other means of identification.
•Supplier's details (including name, address, phone

number, etc.)
• Emergency Phone No.

Section-2
Hazards identification
•Hazard Classification
•Hazard symbol including precautionary statements.

(Hazard symbols may be provided as a graphical
reproduction of the symbols in black and white or the
name of the symbol, e.g., flame, skull and crossbones.)
•Any other hazard (dust, explosion etc.)

Hazard Class :
Hazard Class :
Section-2
Composition/information on ingredients
Substance
•Chemical identity.
•Common name, synonyms, etc.
•CAS number, EC number, etc.
•Impurities and stabilizing additives which are themselves
classified and which contribute to the classification of the
substance.
Section-2
Composition/information on
ingredients..contd…
Mixture
The chemical identity and concentration or concentration

ranges of all ingredients which are hazardous within the
meaning of the GHS and are present above their cutoff
levels.
CAS No.
CAS Registry Number-

•is a unique numeric identifier
•designates only one substance
•has no chemical significance
•is a link to a means of information about a specific chemical

substance
A CAS Registry Number is a numeric identifier that can contain up

to 9 digits, divided by hyphens into 3 parts:
the right digit is a check digit used to verify the validity and
uniqueness of the entire number
Section 4 :
First aid measures
Description of different routes of exposure, i.e.,

inhalation, skin and eye contact, and ingestion.
Most important symptoms/effects, acute and

delayed.
Indication of immediate medical attention and

special treatment needed
Section 5 :
Firefighting measures
•Suitable (and unsuitable) extinguishing media.
•Specific hazards arising from the chemical (e.g., nature of

any hazardous combustion products).
• Special Protective equipment and precautions for

firefighters
Section 6 :
Accidental release measures
•Personal precautions, protective equipment and

emergency procedures.
•Environmental precautions.
•Methods and materials for containment and cleaning up

Section 7 :
Handling and storage
•Precautions for safe handling.
•Condition for safe storage including any

incompatibilities
Section 8 :
Exposure controls/personal protection.
Control parameters, e.g., occupational

exposure limit values or biological limit values.
TLV –TWA TLV-STEL
Appropriate engineering controls.
Individual Protection measures : Personal

Protective Equipment
Eye protection
Skin Protection
Respiratory Protection
Definition of Key Words
•Threshold Limit Value-Time-Weighted Average, TLV-TWA -- Time-

weighted average concentration for an 8-hour workday and a 40-hour work
week in which a worker may be repeated exposed without adverse health
effects.
•Threshold Limit Value-Short-Term Exposure Limit, TLV-STEL -- This is

the maximum concentration which workers can be exposed for 15 minutes
continuously without adverse health affects. Only four of these 15-minutes
exposures are permitted per day and must have 60 minutes between
exposures. The TLV-TWA still must not be exceeded.
•Threshold Limit Value-Ceiling -- This is a defined boundary unlike TLVs

which are guidelines. It is the concentration which should never be
exceeded at any time during the working exposure.
•Permissible Exposure Limit, PEL -- This is one of the most important

OSHA limits used. It is defined as the allowable limit for air contaminant in
which workers may be exposed day after day without adverse health
effects.
Section 9 :
Physical and Chemical Properties
Appearance
Molecular Weight :
Flashpoint: oC
Auto ignition Temperature: oC
Boiling Point: oC @ 760 mm Hg
Melting Point: oC
Vapor Pressure: mm Hg @ 23oC
Vapor Density(Air=1):
% Solubility in Water: @ 20ºC
Odor/Odor threshold:
Section 9 :
Physical and Chemical Properties contd..
Lower Flammability Limit: %
Upper Flammability Limit: %
Specific Gravity: @ 20oC
% Volatile:
Evaporation Rate (Water=1):
Viscosity: cP @ 25oC
Octanol/Water Partition Coefficient: log Kow:
pH:
Definitions
•Flash point -- the lowest temperature at which a flammable liquid gives off
enough vapor to form an ignitable mixture with air. In other words, the lowest
temperature at which a liquid can ignite if a spark is present. Liquids with very
low flash points are dangerous fire hazards (e.g., ethyl ether -49 C).
•Auto ignition temperature -- the temperature at which the liquid will set itself
on fire without a flame or spark.
•Lower Explosive Limit -- the minimum concentration of a flammable gas or

vapor (% by vol. in air) in which an explosion can occur if a flame or spark is
present.
•Upper Explosive Limit -- the maximum concentration of a flammable gas or

vapor (% by vol. in air) in which an explosion can occur if a flame or spark is
present.
•Hazardous Products of Combustion -- In most fires, the greatest danger to

human life is not the heat of the flames, but the toxic smoke that can fill the area.
All the anticipated products of combustion are listed here. Fires of the laboratory
are far more dangerous than common fires because the toxic fumes are often far
more dangerous.
Section 10 :
Stability and Reactivity
Chemical stability.
Hazardous Reactions/Decomposition Products
Possibility of hazardous reactions.
Conditions to avoid (e.g., static discharge, shock or vibration).
Incompatible materials
Section 11 :
Toxicological information
Concise but complete and comprehensible description of the
various toxicological (health) effects and the available data used
to identify those effects, including:
 information on the likely routes of exposure (inhalation,
ingestion, skin and eye contact);
Symptoms related to the physical, chemical and toxicological
characteristics;
Target Organ Effects
Acute and also chronic effects from short- and long-term
exposure;
Acute Toxicity Values
Oral LD50 (Rat) :100 mg/kg
Dermal LD50 (Rabbit) : mg/kg
Inhalation LC50 (Rat): ppm/4 hr., ppm vapor/1 hr
Definition :
Routes of entry -- A hazardous materials may enter the body

through the skin or the eye, by inhalation, or ingestion.
Acute health effects -- The adverse health effects from short-
term exposure.
Chronic health effects -- The detrimental health conditions
which may result from long-term exposure.
Symptoms of exposure -- A description of how a victim of
exposure might look or act like.
Medical conditions aggravated by exposure -- These terms
are not easily recognized by non-medical personnel.
Target organs -- Some materials harm a particular organ of the
body, (heart, liver, brain, etc).
Definition :
Lethal Concentration 50, LC-50 -- This concentration of a hazardous
material in air is expected to kill 50% of a group of test animals when
given as a single respiratory exposure in a specific time period.
Lethal Concentration Low, LC-LO -- This value indicates the lowest

concentration of a substance in air that caused death in humans or
laboratory animals. The value may represent periods of exposure that are
less than 24 hours(acute) or greater than 24 hours (sub-acute and chronic).
Lethal Dose 50, LD-50 -- The single dose, other than inhalation, that
causes death in 50% of an animal population from exposure to a
hazardous substance.
Lethal Dose Low, LD-LO --The lowest dose, other than inhalation, that
caused death in humans or animals.
Acute Oral Toxicity :
Section 12 :
Ecological information
Ecotoxicity (aquatic and terrestrial, where available).
Persistence and degradability.
Bioaccumulative potential.
Mobility in soil.
Section 13 :
Disposal considerations
Description of waste residue and information on their safe

handling and disposal including the disposal of any
contaminated packaging.
Section 14 :
Transport information
UN Number.
UN Proper shipping name.
Transport Hazard class(es).
Packing group, if applicable.
Marine pollutant (Yes/No).
Special precautions which a user needs to be aware of or

needs to comply with in connection with transport or
conveyance either within or outside their premises.
Section 14 :
Transport information contd…
U.S. Department of Transportation (DOT)
Proper Shipping Name:
Hazard Class:
UN/NA Number:
Packing Group:
Labels Required:
International Maritime Organization (IMDG)

Proper Shipping Name:
Hazard Class:
UN/NA Number:
Packing Group:
Labels Required:
Transport Pictograms :
Transport Pictograms :
Section 15 :
Regulatory information
Safety, Health & Environment information specific for the

product in question.
Section 16 :
Other Information
National Fire Protection Association (NFPA) Ratings: This
information is intended solely for the use of individuals trained
in the NFPA system.
Health:
Flammability:
Reactivity:
Special Hazard
Revision Indicator:
Thank you
By Shailesh Mistry

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1

 Material Safety Data Sheet is Horoscope of the

Identification of the substance or mixture

•Other means of identification.

•Supplier's details (including name, address, phone

• Emergency Phone No.

•Hazard symbol including precautionary statements.

•Any other hazard (dust, explosion etc.)

The chemical identity and concentration or concentration

CAS Registry Number-

•designates only one substance

•has no chemical significance

•is a link to a means of information about a specific chemical

A CAS Registry Number is a numeric identifier that can contain up

Description of different routes of exposure, i.e.,

Most important symptoms/effects, acute and

Indication of immediate medical attention and

•Suitable (and unsuitable) extinguishing media.

•Specific hazards arising from the chemical (e.g., nature of

• Special Protective equipment and precautions for

•Personal precautions, protective equipment and

•Methods and materials for containment and cleaning up

•Precautions for safe handling.

•Condition for safe storage including any

Exposure controls/personal protection.

Control parameters, e.g., occupational

Appropriate engineering controls.

Individual Protection measures : Personal

•Threshold Limit Value-Time-Weighted Average, TLV-TWA -- Time-

•Threshold Limit Value-Short-Term Exposure Limit, TLV-STEL -- This is

•Threshold Limit Value-Ceiling -- This is a defined boundary unlike TLVs

•Permissible Exposure Limit, PEL -- This is one of the most important

Upper Flammability Limit: %

Specific Gravity: @ 20oC

Evaporation Rate (Water=1):

Octanol/Water Partition Coefficient: log Kow:

•Lower Explosive Limit -- the minimum concentration of a flammable gas or

•Upper Explosive Limit -- the maximum concentration of a flammable gas or

•Hazardous Products of Combustion -- In most fires, the greatest danger to

Stability and Reactivity

Hazardous Reactions/Decomposition Products

Possibility of hazardous reactions.

Conditions to avoid (e.g., static discharge, shock or vibration).

Routes of entry -- A hazardous materials may enter the body

Lethal Concentration Low, LC-LO -- This value indicates the lowest

Ecotoxicity (aquatic and terrestrial, where available).

Persistence and degradability.

Description of waste residue and information on their safe

UN Proper shipping name.

Transport Hazard class(es).

Packing group, if applicable.

Marine pollutant (Yes/No).

Special precautions which a user needs to be aware of or

International Maritime Organization (IMDG)

Safety, Health & Environment information specific for the

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