Scribd
Upload
135 views7 pages

Exercise 2

1. The standard enthalpy of combustion of 1-hexene is given as -4003 kJ/mol. 2. The standard enthalpy of combustion of hexane is -4163.12 kJ/mol and of hydrogen is -241 kJ/mol. 3. The standard enthalpy of hydrogenation of 1-hexene to hexane can be calculated using the equation: ΔH°hydrogenation = ΔH°combustion(hexane) - ΔH°combustion(1-hexene) - ΔH°combustion(hydrogen). 4. Using this equation, the standard enthalpy of hydrogenation is calculated to be -

Uploaded by

satrio weka
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPTX, PDF, TXT or read online on Scribd
135 views7 pages

Exercise 2

1. The standard enthalpy of combustion of 1-hexene is given as -4003 kJ/mol. 2. The standard enthalpy of combustion of hexane is -4163.12 kJ/mol and of hydrogen is -241 kJ/mol. 3. The standard enthalpy of hydrogenation of 1-hexene to hexane can be calculated using the equation: ΔH°hydrogenation = ΔH°combustion(hexane) - ΔH°combustion(1-hexene) - ΔH°combustion(hydrogen). 4. Using this equation, the standard enthalpy of hydrogenation is calculated to be -

Uploaded by

satrio weka
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPTX, PDF, TXT or read online on Scribd
You are on page 1/ 7

Exercise 2.

8 (A)
A sample of 1.00 mol H2O(g) is condensed isothermally and
reversibly to liquid at 100°C. The standard enthalpy of vaporization of
methanol at 100°C is 40.656 kJ/mol.
Find w, q, ΔU, and ΔH for this process.

n = 1.00 mol ΔH= -ΔvapH x n


= -1.00 x 40.656 kJ/mol
T = 100°C + 273 = 373 K = -40.656 kJ
w = pxΔv
ΔvapH = 40.656 kJ/mol = nxRxΔT
= 1.00x8.3145x(373)
= 3101 J = 3.101 kJ
Exercise 2.8 (A) Solution
Dikarenakan keadaan system yang bekerja adalah isothermal reversible
maka tekanan luar selalu konstan sehingga:
q = qp = ΔH = -40.656 kJ
Dan dengan mengasumsikan bahwa air bekersa dalam system gas ideal
maka dapat kita simpulkan lagi, bahwa:
ΔU = q + w
ΔU = -40.656 + 3.701
ΔU = -37.525 kJ
Exercise 2.21 (A)
A sample consisting of 3.00 mol of diatomic perfect gas molecules at 200 K is
compressed reversibly and adiabatically until its temperature reaches 250 K. Given
that CV,m = 27.5 J K-1 mol-1 .
Calculate q, w, ΔU, ΔH, and the final volume and pressure

n = 3.00 mol

T = 200 K

T = 250 K

CV,m = 27.5 J K-1 mol-1


Exercise 2.21 (A) Solution
Dikarenakan adiabatic reversible, maka
q = qrev = 0
Sehinggga kita bisa mengatakan bahwa ΔU dan ΔH nya sebagai:
ΔU = n x CV,m x ΔT ΔH = n x Cp,m x ΔT
= 3.0 x 27.5 x (250-200) = n x (CV,m + R) x ΔT
= 4125 J = 4.125 kJ = 3.0 x (27.5+8.3145) x (250-200)
= 5372 J = 5.372 kJ
Dimana kita bisa cari w nya dengan
ΔU = q + w
ΔU = 0 + w
ΔU = w = 4.125 kJ
Exercise 2.21 (A) Solution

Final Volume Final Pressure


Untuk mencari volume akhirnya maka Untuk mencari tekanan akhirnya maka
pertama akan kita cari volume mulanya pertama akan kita cari tekanan mulanya
dengan rumus dengan rumus
Exercise 2.28 (A)
Calculate the standard enthalpy of hydrogenation of 1-hexene into hexana given
that the standard enthalpy of combustion of 1 hexene is -4003 kJ/mol.
CH3(CH2)3CH=CH2 (l) + H2 (g) -------> CH3(CH2)4CH3 (l)

ΔHo298 K, combustion[1-hexene] = -4003 kJ/mol


ΔHo298 K, combustion[hexane] = -4163.12 kJ/mol
o
ΔH 298 K, combustion [hidrogen] = -241 kJ/mol

ΔHo[1-hexene] + ΔHo[hidrogen] - ΔHo[hexana] = Δhhydro

-4003 + (-241) – (-4163.12) = -80.88 kJ/mol


Exercise 2.28 (A) Solution
Alternative
CH3(CH2)3CH=CH2 (l) + H2 (g) -------> CH3(CH2)4CH3 (l)

C6H12 + 9O2 ----> 6CO2 + 6H2O 

 
  𝑓 𝐻 𝜃 (  𝐶 6 𝐻 12 )=( 6 × ( −393.51 ) ) + ( 6 × ( − 285.83 ) ) − ( 9 × ( − 0 ) ) − ( − 4003 )=−70.88 𝑘 𝑗 / 𝑚𝑜𝑙
∆
 
 
 
∆  h𝑦𝑑 𝐻 𝜃=∆ 𝐻 𝜃 ( 𝐶6 𝐻 14 ) −∆ 𝑓 𝐻 𝜃 ( 𝐶6 𝐻 12 ) − ∆ 𝑓 𝐻 𝜃 ( 𝐻 2 ) ∆  h𝑦𝑑 𝐻 𝜃=−198.7 − ( −70.88 ) − 0=− 127.82 kJ /mol

You might also like