Wastewater Treatment Technology

Wastewater Treatment Technology

Goal and objectives
1. Familiarity with basic wastewater treatment
2. Identify some advantages/disadvantages
3. Recognize the need for qualified
professionals for the selection, design, and
operation of treatment processes
 Wastewater - definition

Definition in DNRE’s Michigan Manufacturer’s

Guide - Chapter on Wastewater:
– “Wastewater is liquid waste that results
from industrial and commercial processes
and municipal operations…”
– Also includes:
• Sanitary sewage
• Storm water in certain cases
 Waste Characterization
• What’s in the wastewater ? (identify
pollutants)

• What needs to be removed from the

wastewater (and to what extent) ?
 Waste Characterization
Pollutant Examples
• Biochemical Oxygen Demand (BOD)
• Chemical Oxygen Demand (COD)
• Solids (suspended or dissolved)
• Oils/Grease
• Temperature
• Phosphorous & Nitrogen Compounds
• pH
• Metals
• Other elements or compounds
 Waste Characterization “examples”
Metals:
 Iron, Lead, Mercury, Chromium, Copper etc…

Other chemical elements/compounds:

 Arsenic, cyanide ….
 Chlorine compounds, Chlorides, Chlorinated
solvents
 (BTEX) benzene, toluene, ethylbenzene, and
xylene
 Waste Characterization
Definitions “Organics”

• Organic compound: large class of

chemical compounds whose molecules
contain carbon

• Organic matter: plant or animal,

“organisms”
 Wastewater Treatment
• Basic process categories
Physical

Chemical

Biological
Some processes may consist of more than one type;
combination of Physical, Chemical and/or Biological
 “Rearrangement & Residuals ”
• Rearrangement : Pollutants are only physically
separated, and/or chemically rearranged…

• Residuals: Treatment often results in a

“residual”, a solid substance (commonly known
as “sludge”) that contains the target pollutants

Sludges typically need additional

treatment &/or disposal (not covered in
this presentation)
 Physical Processes

– Clarification/Settling
– Air flotation
– Filtration (incl. activated carbon,
membrane filters/bioreactors and
reverse osmosis)
– Oil/water separation
– Cooling
 Clarification/Settling
“sedimentation”

Circular settling Rectangular settling

tank tank
Commonly referred to as “clarifiers”
 Clarification/Settling
Circular “upflow” clarifier

Settling
Suspended
solids
velocity settle
downward
vs. Water flow
is up
Overflow
velocity Settled
Incoming Wastewater particles
 Clarification/Settling

Rectangular, horizontal flow clarifier

Wastewater flow
Suspended solids settle
downward

Also a matter of
settling
Sludge removal velocity versus
overflow
velocity
 Clarification/Settling
discrete
• Three types of sedimentation

flocculating
• Settling can be enhanced by
addition of certain chemicals
(coagulants) and by addition of
ballast
• Baffles, typical
zone • Inclined plates, option
 Clarification/Settling

Notable issues/concerns

• Will only address “settleable” solids

• Impaired settling & “bulking

sludge”
 Physical Processes

– Clarification/Settling
– Air flotation
– Filtration
– Oil/water separation
– Cooling
Dissolved Air Flotation (DAF)
 Dissolved Air Flotation (DAF)
Skim off surface solids

Rising air
bubble
Wastewater

AIR

Suspended
neutrally
Pressure “settled
buoyant particle tank SLUDGE”
 Dissolved Air Flotation (DAF)

• Typical application in industry: refineries,

chemical/petrochemical plants, paper
products, food processing, and natural gas
processing plants

• Typically requires addition of certain

chemical “flocculating” aids or “coagulants”
(mixed in waste stream ahead of DAF
unit)
 Dissolved Air Flotation (DAF)
Chemical
addition FLOTATION TANK
Influent
water Effluent
water
CHEMICAL
MIX TANK
AIR

AIR
TANK
Recycle
pump

DAF Example, with recycle

 Dissolved Air Flotation (DAF)
Benefits
Lighter particles removed Compared to
Faster particle removal standard
More rapid startup clarifier type
settling
Thicker sludge's

Issues/concerns
Significant mechanical equipment
More complex/more
maintenance Higher-energy
consumption
 Physical Processes

– Clarification/Settling
– Air flotation
– Filtration
– Oil/water separation
– Cooling
 Filtration
porous medium separates solids from liquid
Larger particles
retained on upstream
side of media
“retentate”
or
“filtrand”

FILTER
MEDIA

“Permeate or filtrate”
 Filtration
Size of particle removed dependent on “pore”
size of media
Log scale, in microns
micron = one thousandth of a millimeter
0.001 0.1 10 1,000
0.01 1.0 0
HYPE
R ULTRA 10
FILTRATION PARTICLE FILTRA TION
FILTR.
(R/O) NANO MICRO
FILTR. FI TRATI N
Atomic L O
Virus Bacteria Pollen Beach
radius sand
 Filtration
• Filter Media • Filter types
– “Screens” –Gravity
– Sand
–Pressure
– Diamataceous earth
–Centrifugal force
– Granular/multi- media
–Vacuum
– Activated carbon
– Membrane
– Fabric • Moving or fluidized
• Filter rates bed filters
– Rapid infiltration
– Slow infiltration
 Could be called
Filters: “Screens” or “macro” filtration, it
“bar racks” is used for
removal of larger
items, rags,
garbage, and
debris (etc)

fine through coarse

screening options available
• Filter Media Anthracite Coal,
– “Sand” or Intermediate Sand,
– Granular/multi- High Density
Sand,
High Density Support
media
Gravel Silica Sand or Gravel
Garnet
“Others”
Backwash trough
(typical).
Influent
wastewater
Filter

Media
Filtration, rapid-gravity type
Accumulated
solids
Filter

media
Under
drains
Backwash
valve (closed)
 Filtration
Issues and concerns
• Subject to routine plugging & bio-fouling, so
influent water characteristics are critical

• Require frequent cleaning or

“backwashing”

• Cleaning & operation are typically mechanized &

dependent on automated and/or computer
controls

• Secondary cleaning methods, chemicals or

air scour

• Periodic replacement of filter media

 Filtration
Pressure type “Fabric” type

Filter media in Gravity flow through

pressure vessel submerged cloth filter disk
 Filtration: Activated carbon filter media
Granular Activated Carbon (GAC)
uses “adsorption” - a
type of attractive force
between molecules

Magnified GAC particle

surface

Granular Activated Carbon particle

Filtration: Membrane biological reactors (MBR)

• Combine biological treatment with a membrane

liquid-solid separation process
• Low pressure micro-filtration or ultra-filtration
• Uses synthetic membranes
• Can be immersed in an aeration tank
Benefits:
• Eliminates need for clarification & “tertiary”
filtration
•Needs small land area, small “footprint”
Issues/concerns
• Higher building & operating costs than conventional
wastewater treatment
• Highly dependent on computer control technology
Membrane bio-reactors
 Filtration
Membrane biological reactors (MBR)

Hollow tube
type, cassette

Flat plate
type, cassette
 Filtration : Reverse osmosis (RO)
• A filter separation process using
pressure to force a solution through
a semi-permeable membrane

• RO process requires high pressure

be exerted on the membrane

• Process is best known for removing

salt from water
 Reverse Osmosis
“detail”
R/O tube detail:
Perforated Brine Seal FEED TION
central tube SOLU
Permeate
Membrane

concentrate
Feed channel spacer
R/O “sorts” at the molecular level
 Reverse Osmosis
Benefits
• Removes wide range of pollutants

Issues/concerns
• Pretreatment . Feed water needs pretreatment to
remove particulates, influent turbidity
• Scaling, fouling, and degradation of membranes
• Ineffective in removal of some lighter, low molecular
weight volatile organics (such as THM's, TCE, vinyl
chloride, carbon tetrachloride).
• Disposal of reject water
 Physical Processes

– Clarification/Settling
– Air flotation
– Filtration
– Oil/water separation
– Cooling
 Oil/water separators
Gravity separation device
OIL
Oil droplets rise (density and
size dependent).
Design based on differences
in specific gravity between oil
WATER
and water.
Standardized Criteria by the
American Petroleum Institute
(API) Settleable solids
 Oil/water separators
“simplified example”

Baffle
OIL

Influent Baffle Effluent

Solids
 Oil/water separators
“Additional
Features”
PARALLEL
PLATE
COALESCER BAFFLE

INLET
OUTLET
BAFFLE
Sludge
SCREEN EFFLUENT
TRANSFER
hopper COALESCER PIPES

“COALESCERS” often added to

enhance separation
 Oil/water separators
Common limitations
Both emulsified and dissolved oils cannot be
removed in physical oil/water separators

Emulsions: fine oil droplets which cannot be

separated from water physically because
of other chemicals in the water, such as
soap.
Routine maintainance! Solids and oils must be removed
& properly disposed. This must occur frequently or
pollutants will pass through.
 Oil/water separator
Relatively simple to operate…

…but the effluent water must often be sent

on for further treatment (dissolved air
flotation unit for example) to remove any
residual oil, followed by biological treatment
unit for removal of dissolved compounds
 Physical Processes

– Clarification/Settling
– Air flotation
– Filtration
– Oil/water separation
– Cooling
 Cooling
• Many industries generate heat in their
processes and often need cooling water
systems

• If need to discharge to natural waters or

public sewer system may be required to cool
that water first

NON CONTACT COOLING WATER is water used

for cooling which does not come into direct
contact with any raw material, product, byproduct,
or waste
 Cooling
• Evaporative cooling
systems include
– cooling towers,
– evaporative
condensers
– spray ponds
– cooling ponds.

• Reduce temperature of
wastewater by transfer of
heat from the wastewater to
another fluid or to the
atmosphere
 Cooling: issues/considerations
Ponds
– Large land area required
– Algae/bacteria growth

Towers
– Power and maintenance requirements
– Impurities in process water can cause scale,
corrosion, and fouling
– Water Treatment Additives (WTAs)
• May be needed to address scale, corrosion,
and fouling
• May complicate suitability for discharge; WTAs
require special approvals from DNRE.
 Chemical Processes

– Air Stripping
– Precipitation
– Ion exchange
– Chemical neutralization
 Air stripping
• Air stripping is the transfer of volatile components
of a liquid into an air stream.

• Volatile compounds with certain properties can be

economically stripped from water.
– Includes BTEX compounds and certain
solvents
– Ammonia can also be removed by air strippers,
typically enhanced by adjustment of pH &
temperature of the waste stream

• Air strippers are usually towers

– “Packed” or “tray” towers of packing media
 Air stripper
Gas & air collection
&/or exhaust Water
Sprayers

Packing

Wastewater material Air

PUMP

Treated water
Air blower
Air Stripping
Packed towers
– Engineered or
random
plastic
packings

Low profile unit

tray
 Air Stripping
Benefits
• Simple. Generally easily built, operated, &
maintained

Issues/concerns
• Noise, very loud
• Cannot remove metals, PCBs, or other chemicals
that do not evaporate
• Air stripping transfers pollutants to the air
– the air exiting the stripper may require
emissions control and air quality permits
• Fouling, deposits of minerals, solids, biological
films
 Air Strippers
Typical plastic
media for
packed tower

Fouled

media
 Chemical Processes

– Air Stripping
– Precipitation
– Ion exchange
– Chemical neutralization
 Chemical Precipitation
• For removal of:
– metals, other inorganic, suspended solids, fats,
oils, greases, and some other organic substances
from wastewater
• Dissolved or suspended contaminants in a solution
settle out of the solution as a solid precipitate
• Precipitate is then separated from the liquid by
clarifiers, filters or centrifuging etc.
• Assisted through the use of coagulants and
polymers
 Chemical precipitation
• Coagulants
– Cause smaller particles suspended in
solution to gather into larger aggregates

• Polymers
– Contain electrically charged molecules
which allow the polymers to act as
connecters between particles
suspended in solution, or to neutralize
particles in solution
 Chemical precipitation
Common uses
• Water softening
• Heavy metal removal (metal plating wastes)
• Oil & grease removal from emulsified
solutions
• Phosphate removal from wash-waters and
other wastewater
 Chemical precipitation
Converts metals to an insoluble hydroxide
(the hydroxides of most metals are insoluble)

Example reaction mechanism for a divalent

metal

M++ + 2NaOH M(OH) + 2Na++

Precipitates

Note:
• Metal precipitation, solubility is pH dependent,
need to optimize pH for each metal
 Chemical Precipitation,
typical design
Chemical
precipitation tank pump

MI Treatment
XER chemical
INFLUENT
Chemical
controller
sensor

EFFLUENT
to
CLARIFIER
 Chemical precipitation
Benefits
• Well-established technology, readily available
• Some systems can be self-operating with low
maintenance
Issues/concerns
• Competing reactions, pH, alkalinity, temperature,
mixing effects, and other factors can make
precipitation delicate and frustrating
• Some chemicals are hazardous and corrosive,
• Transport / handling / storage of large amounts
of chemicals may needed
 Chemical Processes

– Air Stripping
– Precipitation
– Ion exchange
– Chemical neutralization
 Ion Exchange
• Used to remove heavy metals from low–
concentration waste streams

Ion: an atom or molecule that has lost or

gained one or more valance electrons,
making it positively or negatively
charged
• Pass wastewater through a bed of resin
• Resin has groups of ionic charge on its
surface
 Ion Exchange
Regenerant
Wastewater Solution
influent
Distributor
Process steps
• Treatment
• Backwash RESIN
• Regeneration BED
• Rinse

Used Treated
regenerant
effluent
 Ion Exchange Example
Sodium (Na) is initially attached to resin

CNaa
CNa+
CNaa
+++
+ RESIN
CNa+
+++
+ with
negative charge Na+
CNa
a+++ CNaa Na+
Ca+N+a

Ca++ +++ +Exchange process

“releases” sodium and
“catches” the calcium (Ca)
 Ion Exchange
Benefits
• Metal contaminants
can be recovered and Sample resin beads
reused
• Selective, may be
designed to remove
certain metals only

Issues/concerns
• Resins may be fouled
by some organic
substances, oils, & Bead material has a structure
polymers. of pores on the surface
• Wash water disposal which accommodate easily
trapped and released ions
 Chemical Processes

– Air Stripping
– Precipitation
– Ion exchange
– Chemical neutralization
 Chemical Neutralization
• Eliminate either high or low pH values

– to meet discharge limits

– or prior to other treatment processes that
require pH adjustment
• Add acids, such as sulfuric or hydrochloric
acid, to reduce pH

• Add alkalies, such as sodium hydroxides,

to raise pH values

• Typically performed in a holding tank, rapid mix

tank, or an equalization tank
 Chemical Neutralization
Chemical
ACID
Neutralization Tank P

MIXER CAUSTIC
P

INFLUENT
pH monitor
& control

Neutralized
effluent
wastewater
 Chemical Neutralization
• Control pH between 6.5 and 9 in order to meet
typical discharge limitations
• Relatively simple, but typically involves handling
hazardous chemicals
Typical chemicals
ACIDS BASES
Sulfuric Acid (H2SO4) Caustic (NaOH)
Carbonic Acid (H2CO3) Calcium Hydroxide (CaOH2)
Hydrochloric Acid (HCl) Calcium Carbonate
Phosphoric Acid (H3PO4) (CaCO3)-Lime
Nitric Acid (HNO3) Ammonium Hydroxide
(NH4OH)
 Biological Processes
Common background & definitions
• Applies to industrial waste • Aerobic microbes
waters containing require oxygen (O2 )
to grow
organic pollutants
• Anaerobic microbes
• Some oils can also be
will grow only in the
treated biologically absence of O2
• Biological treatment • Facultative microbes
systems use microbes to can grow with or
without O2
consume organics
Aeration is the process by which air (or oxygen) is
added to, dissolved in, circulated and/or mixed in
wastewater
 Biological Processes
The microorganisms used are commonly
referred to as the “bugs”
These organisms:
• Use organic compounds or matter as food
and/or energy
• Degrade (break down) these materials in
metabolic processes

• Produce carbon dioxide, water and other

“smaller” compounds as a result of metabolic
processes
 Biological Processes
– Lagoons/Stabilization Ponds
• Facultative
• Aerated
• Anaerobic
– Suspended growth
• Activated Sludge
• Sequencing batch reactors (SBRs)
• Oxidation ditch
– Attached growth
• Trickling Filters
• RBCs
– Anaerobic digestion
Lagoons/Stabilization Ponds
 Lagoons/Stabilization Ponds
Wind provides surface
Facultative type
mixing and aeration
Sun provides energy to
algae

Aerobic zone Bacteria & algae in the

pond consume organics
Facultative and modify chemical
zone byproducts

Anaerobic
zone (bottom
sludge)
 Lagoons/Stabilization Ponds
Aerobic type, mechanically aerated:
Surface
Add air to aerator
increase
biological
activity, &
extend the
aerobic zone

Bacteria + O2 = BOD reduction & nitrogenous

compound conversion

Organic carbon is oxidized & sulfur compounds are

converted also.
 Lagoons/Stabilization Ponds
Anaerobic type: Anaerobic “bugs” convert organic
materials into stable products such as carbon dioxide &
methane in a 2 phase process:
DEEPER
 Lagoons/Stabilization Ponds
“general comments”
• Simple treatment systems, but the biology
and biochemistry involved are very
complex

• Different types of lagoons often

combined to achieve the best treatment

• Operated at ambient temperature, only

function well in mild or warm climates
 Issues and Concerns
common to all lagoon types

• Removal of settled sludge's & grit

• Sludge reduction limited in cold climates

• Emergent vegetation, insects & burrowing

animals

• Need for composite liners (expensive)

 Biological Processes
– Lagoons/Stabilization Ponds
• Facultative
• Aerated
• Anaerobic
– Suspended growth
• Activated Sludge
• Sequencing batch reactors (SBRs)
• Oxidation ditch
– Attached growth
• Trickling Filters
• RBCs
– Anaerobic digestion
 Conventional biological treatment
Two main categories
Suspended growth Attached growth
Microbes mixed and A media is immersed
suspended in in wastewater, or
wastewater wastewater poured
over media.
Enlarged “microbe”
Microbes attached to
media
 Suspended growth
Biological processes
Suspended growth process variations:
• Activated sludge,
• Oxidation ditches
• Sequencing batch reactors (SBRs)

Speed up the work of aerobic bacteria & other

organisms by providing a highly aerobic environment
to increase their efficiency
Removes or breaks down bio-degradable organic
material & converts organic nitrogen-compounds

Air is added to the water, provides oxygen to the

suspended microbial growth
 Activated sludge (typical)
Aeration tank Clarifier

Return sludge Waste

Influence process/performance sludge

by control of:
• sludge recycle vs. waste
• micro-organisms’ residence time,
• sludge density
 Activated sludge
AIR
DISTRIBUTION
SYSTEM

AERATION TANK
SURFACE

AIR DIFFUSER HEADS

 “aerators”

Bubbles Finer
Coarser
Size
 Activated sludge
Benefits
Issues/concerns
• Treatment units are
• Can be costly to
relatively small, operate compared to
requiring less space attached growth units,
than attached growth higher energy use for
processes aeration system
• Good process control
features and options • Process can be
impacted by elevated
• Process is levels of toxic
generally free of compounds in the
odors wastewater

• Process flexibility, has

many variants
 Biological Processes

– Lagoons/Stabilization Ponds
• Facultative
• Aerated
• Anaerobic
– Suspended growth
• Activated Sludge
• Sequencing batch reactors (SBRs)
• Oxidation ditch
– Attached growth
• Trickling Filters
• RBCs
– Anaerobic digestion
 Attached Growth biological
processes Attached growth
Microbial growth is on the surface of
media, a “film” of microbes
EDIA
M

EDIA
M
Bio film
“slime”

Media: typically made of plastic or stone

 Attached Growth biological processes
Attached growth variations:
• Trickling filters or towers
• Rotating biological contactors (RBCs)

RBC
TRICKLING
FILTER

Wastewater passes The media is rotated

over/through the in and out of the
media along with air wastewater to
to provide oxygen provide oxygen
 Trickling filter or tower
Wastewater passes Rotating
over media of distributor
rock, plastic
spheresororinterlocking
blocks, Air
sheets of corrugated vent
plastic MEDIA holes

Influent P

CLARIFIER
EFFLUENT
Recycle options
 Attached growth: RBC
conventional process

“conventional” version - no recycle

Attached growth: RBC
Air is
provided by
rotation of
disk out of the
water
 Attached growth
Benefits Issues/concerns
• Additional treatment
often needed
• Efficient at
nitrification • Accumulation of
excess biomass can
• Low power impair performance
requirements
• Flexibility & control
are limited (compared
to activated-sludge
processes)
 Biological Processes
common issues and concerns
Supplemental nutrients or carbon may be
needed in order for the process to work
properly if the waste stream is deficient in
carbon or nutrients

Inconsistent waste type and loading can

reduce effectiveness (of some types more
than others)

Toxics can kill the biomass

 Biological Processes

– Lagoons/Stabilization Ponds
• Facultative
• Aerated
• Anaerobic
– Suspended growth
• Activated Sludge
• Sequencing batch reactors (SBRs)
• Oxidation ditch
– Attached growth
• Trickling Filters
• RBCs
– Anaerobic digestion
 Anaerobic Digestion
Used for stabilizing sludge's and industrial wastes

Gas removal and use

Gas
Supernatant OUTLET
INLETS

Digesting sludge Anaerobic bacteria

produce methane
Digested sludge & carbon dioxide,
OU reducing high
TL
E
T strength organic
waste
 Anaerobic Digestion
Two Stage “High Rate” Version
GAS

STRATIFY
ADD HEAT & MIX
 Anaerobic Digestion
Benefits
• Low energy required compared MIXER, in
to aerobic versions tank

• Less biological sludge produced

• End product can be saleable or

useable products such as
biogas (methane production),
soil conditioners, and
fertilizer
• Suitable for high-strength
GAS FLARE
industrial wastes
 Anaerobic Digestion
Issues/concerns
• Longer start-up time to develop
necessary biomass inventory
• May require further treatment Egg shaped
type digester
with an aerobic treatment
process
• Reaction rates are sensitive to Conventional
lower temperatures; heating digester
used to achieve adequate design
reaction rates
• Increased potential for
production of odors and
hazardous and corrosive gases.
Likely need more than one process typically a
“Treatment train” …process examples:
Carbon
Softener
FILTER

RO
Resin I.E.

CLARIFIER
EQ

Neut. Precip. Coag. Floc.

Sludge holding & filter press

 Design Process,
Selection of technologies
– Use a qualified consultant
– Consult with DNRE staff
– Consider capital & operation costs
– Consider complexity of testing & reporting
requirements
– Consider complexity of operation, and
the qualifications needed for operators
– Operator training requirements
 Operator Training
Industrial/Commercial Wastewater Treatment Plant
Operator Certification
Go to www.michigan.gov/deq for information
Click on “WATER” and then “Operator Training and
Certification”
Certification is offered in a variety of classifications,
each relating to a unit process

RULES AND REGULATIONS:

Part 31 of Act 451, Industrial Rules for Industrial
Wastewater Operator Certification
 Other info and resources
 DNRE’s “Michigan Manufacturer’s Guide…”
contains a discussion of Wastewater Treatment
Technology

 The Michigan Fruit and Vegetable Processor's

Guide to Environmental Regulations, Chapter 3,
Wastewater contains a detailed discussion of
Wastewater Treatment Technology

It would likely be useful for sectors that manage

wastewater with similar pollutants and can be found
online at: www.michigan.gov/deq, more specific
website location details provided in your handout
The end

Thank you !