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Introduction
LNG Chain
Liquefaction
WHAT IS LNG?
• A liquid derived from cooled natural gas at the temperature
of -160°C/-163°C (-260°F) at atmospheric pressure.
Colourless and odourless.
• One volume of this liquid takes up about 1/600th the
volume of natural gas at a stove burner tip. LNG weighs
less than one-half that of water, actually about 45% as
much.
• LNG is non-corrosive, and non-toxic. When vaporized it
burns only in concentrations of 5% to 15% when mixed
with air.
• Neither LNG, nor its vapor, can explode in an unconfined
environment.
INTRODUCTION
WHAT IS LNG?
• Natural gas is composed primarily of methane (typically,
at least 90%), but may also contain ethane, propane and
heavier hydrocarbons.
LNG Chain
LNG Chain
A “chain” is not only a technical approach but an
economic strategic approach as well.
A gas field will never be developed without a defined
market. A grass root LNG plant will never be built without
serious guarantees and long term commitment.
The commitment is not only “buying LNG” but giving the
possibility to transport it and regasify it.
On the other hand, it is possible to build a terminal
and/or tanker without LNG commitment but….the
financing will be a real challenge and owners will be at
risk.
LNG tankers are most of the time dedicated to a specific
route.
LNG CHAIN
LNG Chain
Liquefaction Processes
The liquefaction plants are based on refrigeration
cycles with alternatively condensing and evaporating
working fluids.
The cooling and condensation of the natural gas takes
place in heat exchangers between the gas itself and
the refrigerant.
We can say also that the liquefaction process is
similar to the home refrigerator.
But what kind of refrigerant fluid can be used for the
natural gas liquefaction process?
VDO Clip 13.4-13.5 LNG Liquefaction
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Liquefaction Processes
Natural gas liquefaction is
achieved along complex
processes.
They all are based on the same
succession of four basic Steps:
vaporization, compression,
condensation and expansion.
The very low temperature
required for the LNG necessitate
the use of several selected
refrigerants or mixed
refrigerants.
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Liquefaction Processes
There are 2 main types of liquefaction processes
1. Cascade System
2. Mixed Refrigerant System
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Cascade Cycle
• The process involves 3 cycles in cascade, using a pure
refrigerant in each of the cycles.
• First cycle uses C3 and helps to reach -35°C.
• NG is liquefied under pressure at -100°C in a cycle
operating with ethylene and is subcooled to -155°C using
the C1 cycle.
• C3 compressed to 13 bars in the first cycle is condensed
by cooling water.
• Vaporization of the C3 at -35°C cools the natural gas and
condenses ethylene
• C2H4 vaporization at -100°C liquefy natural gas and
condense C1 compressed to 39 bars. Then a last flash of
the liquid phase helps to reach vapor-liquid equilibrium.
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Cascade Cycle
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Cooling Curves
This figure shows a comparison
of the 9 level cascade and MR
process.
Heat Exchanger
Basic types of heat exchangers used
1. Air fin coolers
2. Conventional shell and tube
3. Brazed plate-fin type
4. Wound type exchangers
Ref: www.linde.com
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Ref: www.linde.com
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August 2005
June 2003
Start 2009
Liquefaction Processes
Five main liquefaction processes are available today
on the market:
1. APCI - the most widely used process over the world
2. Conoco-Phillips modified cascade (Kenai, Trinidad-
Tobago, Idku, Darwin, Equatorial Guinea, Angola,
several plants under construction in Australia)
3. Statoil-Linde ( Snovhit)
4. Shell (Sakhalin)
5. Liquefin- Axens
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Liquefaction Processes
Processes are mainly differentiated by the number of
refrigeration cycles (or loops), and the type of
refrigerant.
- Dual loop processes: APCI, Axens, Shell
- Three loop processes: Phillips optimized cascade,
Statoil-Linde, new APCI (for large plants)
Other main differences between various processes are
the type of cooling-exchangers, the type of gas
turbines, the extension of use of electric drivers, the
adjustment of the power balance between the various
cycles.
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Summary: FLNG
1. LNG Chain
2. Liquefaction Processes
3. Other topics including the previous ones
REFERENCES