Chapter 5 & 6
Chapter 5 & 6
Chapter 5 & 6
o Land Disposal
Introduction
• After conveying the wastewater through sewers, the next step is its disposal, either after
treatment or even before treatment.
• Treated or untreated sewage dumped into streams can upset the ecological stability of the
stream.
• However, through natural processes and bacterial activity, streams can purify themselves.
• The normal food chain is then established with higher trophic levels.
• The excess wastes upset the system by depleting the dissolved oxygen required by bacteria
for aerobic decomposition of organics.
Introduction
• The study of the sources of disposal is important, because the amount of treatment
required to be given to sewage depends very much upon the source of disposal, its
quality and capacity to tolerate the impurities present in the sewage effluents, without
itself is getting potentially polluted or becoming less useful.
(b) Effluent Irrigation or Broad Irrigation or Sewage Farming, i.e. disposal on land
Disposal by Dilution and Oxygen Sag Curve
• Disposal by dilution is the process whereby the treated sewage or the effluent from the
sewage treatment plant is discharged into a river stream, or a large body of water, such as
a lake or sea.
• The discharged sewage, in due course of time, is purified by what is known as self
purification process of natural waters.
• The degree and amount of treatment given to raw sewage before disposing it off into the
river-stream in question, will definitely depend not only upon the quality of raw sewage
but also upon the self purification capacity of the river stream and the intended use of its
water
Cont.…
Conditions Favoring Disposal by Dilution
When sewage is comparatively fresh (4 to 5 hr old), and free from floating
and settleable solids
When the diluting water (i.e. the source of disposal) has high dissolved
oxygen (DO) content.
Where diluting waters are not used for the purpose of navigation or water
supply for at least some reasonable distance on the downstream from the
point of sewage disposal.
Where the flow currents of the diluting waters are favorable, causing no
deposition, nuisance or destruction of aquatic life.
When the outfall sewer of the city or the treatment plant is situated near
some natural waters having large volumes.
Cont.…
When sewage is discharged into a natural body of water, the
receiving water gets polluted due to waste products, present in
sewage effluents.
But the conditions do not remain so for ever, because the natural
forces of purification, go on acting upon the pollution elements, and
bring back the water into its original condition.
This automatic purification of polluted water, in due course, is called
the self-purification phenomenon.
Ifthe self-purification is not achieved successfully either due to too
much of pollution discharged into it or due to other causes, the river
water itself will get polluted.
Cont.…
• The various natural forces of purification which help in effecting self-
purification process are summarized below:
The various natural forces of purification which help in effecting self-
purification process are summarized below:
Physical forces are:
◦ Dilution and dispersion
◦ Sedimentation
◦ Sunlight (acts through bio-chemical reactions)
Chemical forces aided by biological forces (called bio chemical forces) are:
◦ Oxidation (Bio)
◦ Reduction
Cont.…
Dilution and Dispersion
• When the putrescible organic matter is discharged into a large volume of water
contained in the river-stream, it gets rapidly dispersed and diluted.
• The action, thus, results in diminishing the concentration of organic matter,
and thus reduces the potential nuisance of sewage.
• When sewage of concentration Cs flows at a rate Qs in to a river stream with
concentration CR flowing at a rate QR, the concentration C of the resulting
mixture is given by:
Cont.…
Sedimentation
• The settleable solids, if present in sewage effluents, will settle down into the
bed of the river, near the outfall of sewage, thus, helping in the self
purification process.
Sun-light
• The evolution of oxygen in river water due to sunlight will help in achieving
self-purification through oxidation
Oxidation
• The oxidation of the organic matter present in sewage effluents will start as
soon as the sewage outfalls into the river water containing dissolved oxygen
• The deficiency of oxygen so created, will be filled up by the atmospheric
oxygen
Cont.…
Reduction
• Reduction occurs due to hydrolysis of organic matter settled at the bottom
either chemically or biologically.
• Anaerobic bacteria will help in splitting the complex organic constituents of
sewage into liquids and gases, and thus paving the way for their ultimate
stabilization by oxidation.
The various factors on which these natural forces of purification depend are:
(a)Temperature
(b) Turbulence
(c) Hydrograph such as the velocity and surface expanse of the river-stream
(d) Available dissolved oxygen, and the amount and type of organic matter
present
(e) Rate of re-aeration, e
Cont.…
Zones of Pollution in a River-Stream
A polluted stream undergoing self-purification can be divided into the following
four zones:
1. Zone of degradation
2. Zone of active decomposition
3. Zone of recovery; and
4. Zone of cleaner water
Cont.…
• The different zones of pollution (i.e. various stages in the self-purification
process) and the physical, chemical and biological indices, characteristics of
each zone, are shown in Figure:
Cont.…
Indices of Self-Purification
The stage of self-purification process can be determined by the:
◦ physical,
◦ chemical and
◦ biological analysis of the water
Color and turbidity are the physical indices
DO, BOD and suspended solids are the chemical indices which can mark the
stages of purification.
The biological growth present in water can also indicate the stage of
purification process.
Cont.…
• The oxygen deficit (D) at any time in a polluted river stream is the difference
between the actual DO content of water at that time and the saturation DO content
(The normal saturation for fresh water varies between 14.6mg/l to 7.6mg/l for
temperature varying between 0°c to 30°c.) at the water temperature; i.e.
• In order to maintain clean condition in a river system, the oxygen deficit must be
nil, and this can be found out by knowing the rates of de-oxygenation and re-
oxygenation
Cont.…
De-oxygenation Curve: In a polluted stream, the DO content goes on
reducing due to decomposition of volatile organic matter.
• The rate of de-oxygenation depends upon the amount of the organic matter
remaining to be oxidized at the given time (Lt) as well as on the temperature
of reaction.
Cont.…
•Re-oxygenation Curve: In order to counter the balance of the consumption
of DO due to de-oxygenation, atmosphere supplies O2 to water and the
process is called reoxygenation.
•The rate at which the oxygen is supplied by atmosphere to the polluted
water depends upon:-
Condition of flow
Oxygen deficit
Temperature
Cont.…
• Oxygen Deficit Curve: In a running polluted stream exposed to the
atmosphere, oxygenation go hand in hand.
• If de-oxygenation is more rapid than the re-oxygenation, an oxygen deficit
will result
• The amount of resultant oxygen deficit can be obtained by adding de-
oxygenation and re-oxygenation curves
• The resultant curve so obtained is called the oxygen sag curve or the oxygen
deficit curve
• It can also be seen that when the de-oxygenation rate exceeds the re-
oxygenation rate, the oxygen sag curve shows increasing deficit of oxygen
• But when both the rates become equal, the critical point is reached, and
when the rate of de-oxygenation falls below that of reoxygenation, the
oxygen deficit goes on decreasing till becoming zero
Cont.…
• The entire analysis of super-imposing the rates of de-oxygenation and re-
oxygenation have been carried out mathematically, as suggested by Streeter-
Phelps equation; i.e.,
• Where, Dt = the DO deficit in mg/l after t days; L = Ultimate first stage BOD of
the mix at the point of waste discharge; Do = Initial oxygen deficit of the mix
at the mixing point in mg/l.
Cont.…
• KD = De-oxygenation coefficient for the wastewater,
= BOD rate constant determined in the laboratory,
- varies with temperature as:
• The typical values of KD(20) vary between 0.1 to 0.2, generally taken as 0.1.
• KR = Re-oxygenation coefficient for the stream.
• KR varies with temperature as per the equation:
• Where, KR(T) is the KR value at T°c and KR(20) is the KR value at 20°c.
Cont.…
• Values of Re-oxygenation Coefficient (KR) at 20°c
Cont.…
• The critical time (tc) after which the minimum dissolved oxygen occurs can
be found by:
The first stage BOD of mixture sewage and stream (L) is given by
Cont.…
• Substitute the values as:
Disposal of Wastewaters in Lakes and Management of Lake Waters
1. Lake pollutants
• Disposal of wastewaters in confined lakes or reservoirs is much more harmful
than its disposal in flowing streams and rivers.
• Water quality management in lakes in entirely different from that in rivers.
• It is in fact the phosphorous (a nutrient largely contained in industrial as well as
domestic wastewaters), which seriously affects the water quality of lakes; and is
hence considered as the prime lake pollutant.
• The toxic chemicals from industrial wastewaters may also sometimes very
adversely affect some special classes of the lakes.
• A study of the lake systems is essential to understand the role of phosphorous in
lake pollution.
• The study of lakes is called limnology.
Cont.…
2. Stratification in Lakes
• The water of a lake gets stratified during summers and winters
• During summer season, the surface water of a lake gets heated up by
sunlight and warm air.
• This worm water being lighter remains in upper layers near the surface, until
mixed downward by turbulence from winds, waves, boats and other forces.
• Since limited depth from below the water surface, the top layers of water in
the lake become well mixed and aerobic.
• This warmer, well mixed and aerobic depth of water is called epilimnion
zone.
• The lower depth, which remains cooler, poorly mixed and anaerobic, is called
hypolimnion zone.
Cont.…
• There may also exist an intermediate zone or a dividing line, called
thermocline, as shown in Figure a
Cont.…
3 Biological Zones in Lakes
• Lakes have been found to exhibit distinct zones of biological activity, largely
determined by the availability of light and oxygen.
i. euphotic zone
ii. littoral zone
iii. benthic zone.
Cont.…
i. Euphotic zone
The upper layer of lake water through which sunlight can penetrate
All plant growth occurs in this zone.
In deep water, algae grow as the most important plants
Cont.…
ii. Littoral zone
The shallow water near the shore, in which rooted plants grow, is called the
littoral zone.
The extent of the littoral zone depends on the slope of the lake bottom and the
depth of the euphotic zone.
The littoral zone cannot extend deeper than the euphotic zone
iii. Benthic zone
The bottom sediments in a lake comprise what is called the benthic zone.
As the organisms living in the overlying water die, they settle down to the
bottom, where they are decomposed by the organisms living in the benthic zone.
Bacteria are always present in this zone.
The presence of higher life forms, such as worms, insects and crustaceans
however, depends upon the availability of oxygen at the lake bottom
Disposal of Wastewater in Sea Water
Sea water normally contains 20% less oxygen than that contained in fresh
water of a river stream.
Moreover, sewage solids, when thrown into sea water, chemically react with
the dissolved matter of sea water, resulting in precipitating some of the
sewage solids, giving a milky appearance to sea water and forming sludge
banks
These sludge banks are undesirable, as they are likely to produce offensive
hydrogen sulphide gas by reacting with the sulphate rich water of the sea
As pointed out earlier, the oxygen content of sea water is less than that of
fresh water, and also, its re-aeration is slower.
However, since the sea contains too larger volumes of water, most of these
deficiencies are removed, provided the sewage is taken deep into the sea
and away from the coast line
Cont.…
• Since the specific gravity of sea water is greater than that of sewage, and
temperature of sea water is lower than that of sewage, the lighter and the
warmer sewage will rise up to the surface when thrown into the sea water.
• This will result in spreading of the sewage at the top surface of sea in a thin
film or 'sleek’.
• To prevent the backing up and spreading of sewage on the sea shore, the
sewage should be disposed of only during low tides.
• Large sized tanks may, therefore, be constructed to hold the sewage during
high tides.
• Provision of a large sized sewer, grated with a non-return valve at the end, is
also an alternative to hold the sewage during high tides.
Land Disposal and Treatment
1. Disposal of Sewage Effluents on Land for Irrigation
• In this method, the sewage effluent (treated or diluted) is generally disposed of
by applying it on land.
• The percolating water may either join the water-table, or is collected below by
a system of under drains.
• This method can then be used for irrigating crops.
• This method, in addition to disposing of the sewage, may help in increasing
crop yields (by 33% or so) as the sewage generally contains a lot of fertilizing
minerals and other elements.
• However, the sewage effluent before being used as irrigation water must be
made safe.
• In order to lay down the limiting standards for sewage effluents, and the
degree of treatment required, it is necessary to study as to what happens when
sewage is applied on to the land as irrigation water.
Cont.…
• When raw or partly treated sewage is applied on to the land, a part of it
evaporates, and the remaining portion percolates through the ground soil.
• While percolating through the soil, the suspended particles present in the
sewage are caught in the soil voids. If proper aeration of these voids is
maintained, the organic sewage solids caught in these voids get oxidized by
aerobic process
• The extent of land area required for disposing a certain volume of sewage
effluent can be worked out from the values given in Table
Cont.…
2. Quality Standards for Wastewater Effluents to be discharged on Land for
Irrigation
• These standards are based upon the quality of irrigation water required by
the crops, and thus limit the concentrations of pollutants contained in
sewage or industrial liquid wastes, which may prove harmful to the crops
Cont.…
Summary of Dilution Method Vs Land Disposal Method for Disposal of
Sewage
• For disposal by dilution, large volumes of natural clean waters (with nil or very
low BOD) are required; whereas, for land disposal, large areas of land,
preferably with sandy soils, are required
• The cost of land, in land disposal method, is generally very high, especially in
cities and urban areas, which are generally situated near rivers or oceans, and
thus suggesting the choice of dilution method. Whereas, in the rural areas,
where the amount of sewage produced is less, land being available at lesser
cost, no easy water source being available, the land disposal method is a better
choice.
• When the cost of land is high in land disposal method, some return may be
available due to sewage farming; but then good management is also required.
Dilution method of disposal, however, when possible, is a simple method, and
does not require too much of management.
Cont.…
• Land disposal method requires either no pre-treatment of sewage or only
preliminary treatment; whereas, dilution method of disposal, generally
requires either full or at least partial treatment.
• Dilution method of sewage disposal requires nil or small head pumping,
because rivers flow through the lowest contours, while land disposal requires
high head pumping, thus making the land disposal method costlier.
• Land disposal method is generally found to be a better choice in hot climatic
areas.
This is because of the fact that in hot areas, DO contents of natural waters are
reduced, while fish and aquatic life need higher DO concentrations, thus rendering
rivers (particularly those with small dry weather flows) susceptible to too much
pollution and unfit for throwing untreated or less treated sewage.
A lot of pretreatment, if required, will make the dilution method costlier
Cont.…
Quiz #2 (5%)
1. Discuss zone of pollution
2. Enumerate the two general methods adopted for sewage disposal; and
discuss their merits, and demerits
CHAPTER SIX