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NANOTECHNOLOGY:
INTRODUCTION & TOOLS MBP-403 INTRODUCTION
■ The utilization of matter on an atomic, molecular, and
supramolecular scale for industrial purposes is termed as nanotechnology, or just nanotech. The earliest and most common definition of nanotechnology, also known as molecular nanotechnology, focused on the specific technological purpose of accurately manipulating atoms and molecules for the development of macroscale objects. CURRENT RESEARCH: Nanomaterials ■ The field of nano materials encompasses subfields that create or research materials with special attributes brought on their Nano scale dimensions. Many materials that may be beneficial in nanotechnology, including carbon nanotubes and other fullerenes, as well as other nanoparticles and nanorods, have been developed thanks to interface and colloid science. Nanoscale materials can also be utilized for bulk applications; most existing commercial applications of nanotechnology are of this type. CURRENT RESEARCH: Biomimetic approaches ■ Bionics, also referred as bio mimicry, is the study and design of engineering systems and contemporary technology by borrowing biological principles and systems from nature. One of the systems examined is bio mineralization. The term "bio nanotechnology" refers to the utilization of biomolecules, such as viruses and lipid structures, for nanotechnology applications. One potential application at the bulk level is Nano cellulose. CURRENT RESEARCH: The dimensions of nano materials ■ The categorization of nano materials contains 0D, 1D, 2D, and 3D nano materials. The physical, chemical, and biological characteristics of nano materials are significantly influenced by their dimensionality. Surface- to-volume ratio is appears to rise when dimensionality reduces. This shows that, in comparison to 3D nano materials, smaller dimensional nano materials have a higher surface area. Two-dimensional (2D) nano materials are currently being studied in depth for use in biological, electrical, drug delivery, and biosensor applications. TOOLS AND TECHNIQUES ■ There are numerous contemporary developments. Nanotechnology was introduced via the Atomic Force Microscope (AFM) and the Scanning Tunneling Microscope (STM), two early iterations of scanning probes. Other variations of scanning probe microscopy exist. The resolution of most recent scanning probe microscopes is substantially higher since they are not constrained by sound or light wavelengths. Numerous nanolithography techniques, including optical lithography, X-ray lithography, dip pen nanolithography, electron beam lithography, and nano imprint lithography, have also been developed. ■ A top-down fabrication method called lithography shrinks a bulk material to a Nano scale design. Nano imprint lithography, deep ultraviolet lithography, electron beam lithography, focused ion beam machining, molecular vapour deposition, and molecular self-assembly methods are among another group of nano technological techniques. These methods also used to create nanotubes and nanowires, as well as semiconductors. In contrast to methods that were specifically created for the development of nanotechnology and which were the results of nanotechnology research, the ancestors of these methods precede the nanotech period and are progressions in the development of scientific accomplishments. STM ■ The development of the family of scanning probe microscopes started with the original invention of the STM in 1981. Gerd Binnig and Heinrich Rohrer developed the first working STM while working at IBM Zurich Research Laboratories in Switzerland. This instrument would later win Binnig and Rohrer the Nobel prize in physics in 1986. ■ The Quantum Corral – The STM image below shows the direction of standing-wave patterns in the local density of states of the Cu(111) surface. These spatial oscillations are quantum-mechanical interference patterns caused by scattering of the two- dimensional electron gas off the Fe atoms and point defects. STM ■ How an STM Works – The scanning tunneling microscope (STM) works by scanning a very sharp metal wire tip over a surface. By bringing the tip very close to the surface, and by applying an electrical voltage to the tip or sample, we can image the surface at an extremely small scale – down to resolving individual atoms. ■ The STM is based on several principles. One is the quantum mechanical effect of tunneling. It is this effect that allows us to “see” the surface. Another principle is the piezoelectric effect. It is this effect that allows us to precisely scan the tip with angstrom-level control. Lastly, a feedback loop is required, which monitors the tunneling current and coordinates the current and the positioning of the tip. AFM
■ Atomic Force Microscopy (AFM) is a high-
resolution non-optical imaging technique first demonstrated by Binnig, Quate and Gerber in 1985. Since then it has developed into a powerful measurement tool for surface analysis. AFM allows accurate and non-destructive measurements of the topographical, electrical, magnetic, chemical, optical, mechanical, etc. properties of a sample surface with very high resolution in air, liquids or ultrahigh vacuum. This unique combination of capabilities makes AFM indispensable in most advanced science and technology labs around the world. AFM
■ AFM Operation Principle
■ The basic operation principle of a standard AFM system with optical feedback involves scanning an AFM probe with a sharp AFM tip over a sample surface in a raster pattern. The AFM tip is usually made of silicon or silicon nitride and is integrated near the free end of a flexible AFM cantilever. A piezoelectric ceramic scanner controls the lateral and the vertical position of the AFM probe relative to the surface. As the AFM tip moves over features of different height the deflection of the AFM cantilever changes. This deflection is tracked by a laser beam reflected from the back side of the AFM cantilever and directed into a position sensitive photodetector. A feedback loop controls the vertical extension of the scanner in order to maintain near-constant AFM cantilever deflection and hence a constant interaction force. The coordinates that the AFM tip tracks during the scan are combined to generate a three-dimensional topographic image of the surface. STM VS AFM
■ The atomic force microscope (AFM) was developed to
overcome a basic drawback with STM – it can only image conducting or semiconducting surfaces. The AFM has the advantage of imaging almost any type of surface, including polymers, ceramics, composites, glass, and biological samples. APPLICATIONS
■ The majority of applications are limited to "first
generation" passive nanomaterial’s, which include zinc oxide in paints and varnishes for outdoor furniture, titanium dioxide in sunscreen, cosmetics, surface coatings, and some food products, carbon allotropes used to make gecko tape, silver in clothing, home appliances, disinfectants, and food packaging, and cerium oxide as a fuel catalyst. Due to various uses, tennis balls can also last longer, golf balls can already fly straighter, and even bowling balls can have a stronger surface. Nanotechnology may make it possible for current medical applications to become more accessible and economical in locations like the general practitioner's office and at home.