STP 212 Lecture slide
STP 212 Lecture slide
STP 212 Lecture slide
THERMODYNAMICS AND
ELECTROMAGNETISM
Lecturers: Mr Ashim I. O. , Mr Azeez J. & Mr Makinde O. S.
COURSE OUTLINE
First law of thermodynamics and its applications by Mr
Azeez
Second law of thermodynamics and its applications by Mr
Azeez
Magnetic Effect of Current and its applications by Mr
Makinde
The Concept of electromagnetic induction and its
application by Mr ASHIM
The principles of A. C. circuits and their application by Mr
ASHIM
Topic:
1. The first law of thermodynamics and its applications.
1.1 Introduction:
Thermodynamics deals with processes which cause energy changes as a result of heat flow to or from a system
and/or of work done on or by a system. A thermodynamic system consists of a fixed mass of mater, often or gas,
separated from its surroundings, perhaps by a cylinder and a piston. Heat engines such as petrol engine, a steam
turbine and a jet engine all contain thermodynamic systems designed to convert heat into mechanical work. Heat
pumps and refrigerators are thermodynamic devices for transferring heat from a cold body to a hotter one.
1.2 First law of thermodynamics:
The first law of thermodynamics is commonly called the law of conservation of energy. A move general form of
conservation of energy includes the effects of heat transfer and internal energy changes. This move general form is
called the first law of thermodynamics.
The first law of thermodynamics was stated for a cycle: the net heat transfer is equal to the net work done for a
system undergoing a cycle or
When a system undergoes a thermodynamic cycle then the net heat transfer is equal to the net work done for a
system undergoing a cycle or
When system undergoes a thermodynamic cycle then the net heat supplied to the system from the surroundings is
equal to the net work done by the system on its surroundings.
ჶdQ = ჶdw
Where ჶ represents the sum over a complete cycle and dQ and dw are respectively
infinitesimal quantity of heat and work done.
The statement above are various forms of the first law of thermodynamics. The first
law cannot be proved analytically, but experimental evidence has repeatedly confirmed
its validity.
Heat supplied to a gas (or a liquid or solid) may (i) raise its internal energy and (ii)
enable it to expand and thereby do external work by pushing back the atmosphere or, if
it is in a cylinder, by moving a piston against a force.
In general, the internal energy of a gas consists of two components.
a. Kinetic energy due to translational and vibrational motion of the molecules, all
of which depend only on the temperature.
b. Potential energy due to the intermolecular, i.e. the volume of the gas.
If dQ is the heat supplied to a mass of gas and if dw is the external work done by it then
the increase of internal energy du equals (dQ – dw) if energy is conserved.
du = dQ – dw
or
dQ = du + dw --- (1)
The equation (I) is the mathematical statement of the first law of thermodynamics and
1.3 Thermodynamic processes
(a) Isothermal Change
Isothermal changes refer to changes of pressure and volume of a
gas which occurs at constant temperature. In an isothermal
change heat is extracted from the system or supplied to it as the
pressure and volume vary at such a rate that the temperature
remains constant.
For a gas that approximates an ideal gas, the internal energy
depends only on the temperature and thus du = o for an
isothermal process; for such a process
dQ = du + dw (du = o)
dQ = dw
This means that increase in the quantity of heat energy to the system
increases the work done by the system. For an ideal gas, pv = a constant
for a constant temperature. Plotting the pressure of the gas against volume
for different temperatures give series of curves called isotherms, as shown
Fig 1.1: Isothermal Change
(b) Adiabatic Change
An adiabatic change refers to the change in volume and temperature of a gas such
that there is no heat exchange between the gas and its surroundings. That is no
heat enters or leaves the gas so dQ = 0. Using first equation (I)
dQ = du + dw
0 = du + dw
or
du = - dw
This means that the change in internal energy of the system decreases, then work
is done by the system and this causes a drop in temperature, but when the internal
energy change increase, then work is done on the system and this causes a
temperature rise. Examples of processes for which there is no, or negligibly small,
Heat transfer, e.g. the compression of air in an automobile engine.
When a graph of pressure P is plotted against volume V, pv curves are obtained
which are steeper than the isotherms as shown in the figure below. The
relationship between P and V is of the form PV૪ = a constant where is a constant
for the gas.
(d). Isobaric Process
∫dw = ∫Pdv
by the continuous summation of dw, ie
W = ∫P dv
Work done by the gas on expanding is taken as positive, where as
when a gas is compressed, work is done on it. This work is negative.
1.5 Work done on a gas during an isothermal process
Suppose a unit of gas undergoes an isothermal change from a volume V 1 to a
volume V2 at a constant pressure. Then the total work done by the gas W is equal to
the area under the p-v curve, and is given by
W = ∫Pdv
But PV = RT or P = RT/V
Substituting for P in the above expression for W, we get
W = ∫RT/V dv
= RT∫dv/V
= RT {log V}
= RT {logV2- logV1}
= RT log { V2/V1} for one mole of the gas
Also P1 V1 = P2 V2
V2 / V1 = P2 /P1
∴ W = RT log {V2 / V1 } = RT log {P2 /P1}
1.6 Work done in an adiabatic process
The work done for a reversible adiabatic process is given by
W = ∫P dv --- (1)
Where the pressure and volume are related by the expression
PV૪ = constant --- (2)
where ૪ = CP/ CV, the ratio of the molar heat capacity at constant
pressure to that at constant volume.
from (2) P = C/ V૪ substituting in (1)
w = ∫C/V૪ dv = ∫C V-૪ dV = C {V-૪ + 1}
Substituting the upper and lower units, we arrived at
W = C { V-1-2 – V11-૪ } /1 ૪ 1- ૪
= C { V2 .V ૪ 2 – V1.-૪ } /1- ૪ , the constant C can be written as P2V2 ૪.
Hence, W = {P2 V2 ૪. V2 ૪ – P1 V1 V1-૪}/ 1 - ૪
W = {P2 V2 - P1 V1}1 – ૪
or since {RT2 - RT1}/ {1 – ૪} = {R (T2 - T2 )}/{1 – ૪},m,
2 The second law of thermodynamics and its application.
2.1: Equation of state of an ideal gas
Experimental evidence provide the following information above an ideal gas.
First, when the gas in kept at a constant temperature its pressure is inversely
proportional to the volume (Boyeles law).
Second, when the pressure of the gas is kept constant, the volume is directly
proportional to the temperature (the law of Charles and Gay-Lussas).
These observations can be summarized by the following equation of state for an
ideal gas.
PV = nRT
In this experiment, called the ideal gas law, R is a constant for a specific gas that
can be determined from experiments, and T is the temperature in Kelvin.
Experiments on several gases show that, as the pressure approaches zero, the
quantity PV/nT approaches the same value of R for all gasses. For this reason R is
called the universal gas constant. R has a value equal to 8.13 Jmol-1 k-1
2.2: Internal Energy of a Gas
The internal energy U of a substance is defined as the sum of the kinetic and
potential energy of its molecules. We do not include any k.e, (or p.e) which the gas
as a whole might have, through being in a container which is moving, or because of
the position of the gas container. In the case of the ideal gas of our simple kinetic
theory U is simply calculated as the number of molecule multiplied by their mean
translational k.e.
U = N (3/2 k T )
= 3/2nRT
If we heat the gas while its volume remains constant, the energy transferred by
heating DQ is equal to the gain in internal energy of the gas DU since no work is
done if there is no volume change. Therefore.
DQ = DU = 3/2nRdT
The above expression means that the internal energy of an ideal gas depends on the
absolute temperature
2.3: Reversible Process
A process is reversible if at all stages its direction can be reversed by an
infinitesimally small change in direction of the supply of energy. That is a
reversible process is one in which every state between the initial and final states is
an equilibrium state. And that can be reversed in order to be followed exactly from
the final state back to the initial state of pressure, volume and temperature.
2.4: Irreversible Process
An irreversible process is one in which every state between the initial and final
states is not in equilibrium state, and can not be reversed from the final state to the
initial state. If any of the following features are observed in a process, it is
irreversible:
i. Frictional or viscous forces which convert mechanical energy into internal energy.
ii. Spontaneous changes, which must imply non equilibrium situations; these include.
1. Any heating process, i.e energy transfer because of finite temperature
differences
2. Processes in which bodies accelerate, as a result of unbalanced forces.
2.5: Examples of Reversible Processes
An isothermal process is a reversible process. If we do work DW on some gas, and its
temperature and internal energy do not change, it heats its surroundings by an amount
DQ (= DW) at any stage this process can be reversed: If the surrounding heat the
gas, the gas does an amount of work on the surroundings.
An adiabatic process, also can be reversible. Now we need the material of the
containing cylinder to be a perfect thermal insulator: If we compress the gas, its
temperature will rise. This does not its matter, provided the temperature difference
between the gas and its surrounding does not energy to flow. If we do work DW on
the gas, its internal energy will increase by an amount DU (DU = DW), and any stage
this process can be reversed: the increased pressure of the gas can push the piston
back in the opposite direction.
So to obtain good approximations, in practice to reversibility, both isothermal and
adiabatic processes have to be performed slowly compared with the speeds of the
molecules.
2.6: Heat Engines
The term heat engine include-internal combustion engines, steam engines, the
turbines that generate electricity in power stations, refrigerators. All heat engines
have a working substance. All heat engines must perform a cyclic process, i.e, they
must be able to repeat their operation for any number of cycles. The working
substance must therefore be returned to its original state at the end of each cycle.
In all heat engines the working substance is heated usually by contact with a source
which we call the hot reservoir, but sometimes through a direct injection of energy,
an in internal combustion engine; the working substance then expands and does
work. Most heat engines therefore convert internal energy into mechanical energy
(through some, e.g the refrigerator, reverse this process). The principle of a heat
engine therefore is to extract useful mechanical work from a machine and to replace
the energy lost by heating the machine. In this way certain amount of heat can be
converted into work.
1st law of thermodynamics Q1 = W + Q2
2nd law of thermodynamics Q2 >0
Fig. 2.1: Principle of heat engine
Energy is extracted as heat from a high temperature reservoir = a source of energy
with a very thermal capacity so that a great dead of energy can be extracted without
changing the temperature noticeable – and some of it is converted into useful work.
The remaining energy is dumped into a low temperature reservoir.
The first law of thermodynamics implies that the amount of work done by the
engine cannot be greater than the heat drawn in from the hot reservoir. The second
law requires that the engines cannot be 100% efficient – which is the same as
saying that some energy must be dumped into the low – temperature reservoir.
2.7: Carnot’s Ideal Heat Engine
The French scientist Carnot took the first steps towards developing a scientific
theory heat engines. He imagined an ideal engine, not of any particular type, but
free from all imperfections such as friction, in which the working substance was
taken reversible through a cycle (called the Carnot cycle) consisting of two
Isothermal and two adiabatic processes as shown in the P-V graph Fig. 2.2.
(a) (b)
Figure 1.0 A simple electric circuit in which a straight copper wire is
placed parallel to and over a compass needle. The deflection in the
needle becomes opposite when the direction of the current is reversed.
Current carrying conductors and cardboard iron fillings
(1) Connect the copper wire vertically between the two points, as
shown in Fig. 2.0, in series with the battery, a plug and key.
(2) Sprinkle some iron filings uniformly on the cardboard. (3) Keep
the variable of the rheostat at a fixed position and note the current
through the ammeter.
(4) Close the key so that a current
flows through the wire. Ensure that
the copper wire placed between the
two points remains vertically
straight.
(5) Gently tap the cardboard a few
times. Observe the pattern of the
iron filings. You would find that the
iron filings align themselves Fig 2.0 Iron filling expt.
showing a pattern of concentric (Magnetic Effects of Currents)
circles around the copper wire.
Magnetic field flux density
Magnetic fux density, B, is the force, F, per unit length, , per unit
current, I, on a current carrying conductor at right angles to the
magnetic feld. It is otherwise known as the magnetic field strength.
The unit of measurement is the tesla (T)
……………..(1)
Therefore, force acting on a current carrying conductor in a magnetic
field is represented by eq. 1 ()
Examples
(1) Calculate the force per centimetre length of a straight wire placed
at right angles to a uniform magnetic field of magnetic flux density
0.12 T and carrying a current of 3.5 A.
Solution: According to eq.(1) F BIl
F 0.12 3.5 0.01 (length 1.0 cm)
F 4.2 10–3 N
(2) A 4.0 cm long conductor carrying a current of 3.0 A is placed
in a uniform magnetic field of flux density 50 mT. In each of a, b and
c below, determine the size of the force acting on the conductor.
Fig.3.0 (a) (b) (c)
Solution:
a F BIl sin θ
F 0.050 3.0 0.04 sin 90°
F 6.0 10–3 N
b F 0.050 3.0 0.04 sin 30°
F 3.0 10–3 N
c F 0.050 3.0 0.04 sin 65°
F 5.44 10–3 N
5.4 10–3 N
Expression for the force on a charged particle moving in a
magnetic field
When a moving charge enters a magnetic field such that field lines
are crossed, the charge finds itself under a force perpendicular to the
direction of motion that gives it a circular motion. If a charge enters
a field such that its motion direction is parallel to the field lines and
no field line is crossed, then the charge will not be affected by the
field and keeps going straight.
There is a relationship between the electric field and the force that a
charged particle felt is given in eq. 2.
F = qE …………………….(2)
Similarly, there is a relationship between a magnetic field and the
force a charged particle feels is given in eq. 3.
F= qvB ……………………(3)
where: F = force, q = charge on the particle, v = velocity, B = flux
density
If the downward field vector is (B), and the charge velocity crossing
the magnetic field to the right and at right angle is (v), the magnitude
of force (F) initially pushing the moving charge toward the board is
given by Fig.4.0 (b) : F = q v B.
Therefore: in a vacuum
in a medium
ELECTRIC FIELD INTENSITY
(Contd
Example 1; 2)
In the Bohr model of the hydrogen atom, an electron (q = -e) cicles a proton
(q1 = e) in an orbit of radius The attraction of the proton for the electron
furnishes the centripetal force needed to hold the electron in orbit. Find (a) the
force of electrical attraction between the particles and (b)) the electrons speed.
(Electron mass = )
Solution:
Where is the angle between the field lines and the perpendicular to the plane of
the coil
I is the current.
Net P.D scross armature = (Line voltage) – (back emf)
Armature current =
𝐹𝑖𝑔𝑢𝑟𝑒(𝑐 )
APPLICATION OF
ELECTROMAGNETIC INDUCTION
(Contd
Example:
2)
How fast must a 1000 loop coil (each with 20cm2 area) turn in the earths
magnetic field of 0.70G to generate a voltage that has a maximum
value(i.e an amplitude) of 0.50V? Assuming T.
Solution;
The mutual induction of current between two circuits will occur in all cases
where the current in any coil or even single wire is changed and a
secondary coil or closed single wire is always present in the neighbourhood.
The effect is always present though it will only be significant if coils of
several turns which are close together are used especially if they are linked
by ferromagnetic core.
MUTUAL INDUCTANCE (Contd 1)
If IA is the current flowing in the primary circuit, the number of magnetic
flux lines linked with the secondary is mean, where M depends on the
geometry of the system.
If any ferromagnetic material is used, the latter greatly increase M an then
the flux linkage is not necessarily proportional to the current IA
M is the same irrespective of which of the two coils is considered to be
primary, i.e flux linkage in coil B due to current IA in coil A is the same as
the flux linkage in A due to the same current in coil B.
M is called mutual inductance or coefficient of mutual inductance.
Mutual inductance is defined as the ration of induced emf to the time rate
of change of current in a coil.
MUTUAL INDUCTANCE (Contd 2)
However, the all general expression for alternating current and voltage are;
𝐹𝑖𝑔𝑢𝑟𝑒( 𝑔)
RESONANCE and POWERLOSS
It occurs in a series R-L-C circuit when XL = XC. Under this condition Z = R
is minimum so that I is maximum for a given value of V. Equating XL to XC,
we find for the resonant (or natural) frequency of the circuit.
Where quantity cos is called the power factor. It is unity for a pure resistor.
But it is zero for a pure inductor or capacitor (no power loss occurs in a
pure inductor or capacitor).
EXAMPLES AND SOLUTIONS
1
2
THANK YOU