Tarea Semana 8 Termo
Tarea Semana 8 Termo
Tarea Semana 8 Termo
Evelyn Ibaceta
TERMODINÁMICA
Instituto IACC
30/12/19
Desarrollo
Se quema metano (CH4) con aire seco. El análisis de los productos en base seca es de
a) La relación aire-combustible y
Desarrollo:
Base
a) La relación aire-combustible
- Desarrollo:
Nteorico = 2Kmol.
Balance de energía:
Trabajo de frontera = W = O.
Adiabático = Q = O.
HP = Hr
Reemplazamos:
(-395520+HCO2-9364-8,314T)+2(-241820+HH2o-9904-8,314T)+6(0+HO2-8682-
8,314T)+30,095(0+HN2-8669-8,314T)=
(-7485+H-H298-8,314(298))+8(0+H-H298-8,314(298))+30,095(0+H-H298-8,314(298))=
kJ/Kmol.
Tabla N2
T= 1200K.
T = 1100K.
Interpolación:
1200 = 1090051,815.
T2 = 1047606,878.
1100 = 986210,97.
T2 = 1160K.
V = const.
P1/T1 = P2/T2.
1/298 = P2/1160.
P2 = 3,89 atm.
constante a 100 kPa, con 200% de aire teórico. Durante el proceso de combustión,
Determine:
Desarrollo :
90% 𝑑𝑒 𝐶3 𝐻8 → 𝐶𝑂2
10% 𝑑𝑒 𝐶3 𝐻8 → 𝐶𝑂
3 3,5
(𝑛𝑂2 )𝑢𝑠𝑎𝑑𝑜 = 𝑛𝐶𝑂2 + 𝑛
5 5 𝐶𝑂
3 3,5
= (2,7) + (0,3) = 4,85𝑚𝑜𝑙𝑒𝑠
5 5
= 200%(4,85) = 9,7𝑚𝑜𝑙𝑒𝑠
79 79
(𝑛𝑁2 )𝑖𝑛𝑔𝑟𝑒𝑠𝑎 = (𝑛𝑂2 )𝑖𝑛𝑔𝑟𝑒𝑠𝑎 = (9,7) = 36,49𝑚𝑜𝑙𝑒𝑠
21 21
4 4
𝑛𝐻2 𝑂 = 𝑛𝐶𝑂2 + 𝑛𝐶𝑂
3 3
4 4
= (2,7) + (0,3) = 4𝑚𝑜𝑙𝑒𝑠
3 3
𝐶3 𝐻8 (𝑔) + 9,7𝑂2 (𝑔) → 2,7𝐶𝑂2 (𝑔) + 0,3𝐶𝑂 (𝑔) + 4,85𝑂2 (𝑔) + 4𝐻2 𝑂(𝑙)
𝑛𝑇 = 48,34𝑚𝑜𝑙𝑒𝑠
𝑛𝐻2 𝑂
𝑃𝑣 = ∙𝑃
𝑛𝑡𝑜𝑡𝑎𝑙
4
𝑃𝑣 = ∙ 100
48,34
𝑃𝑣 = 8,27𝐾𝑃𝑎
Cuando esta presión llega a su equilibrio su temperatura es la del rocío
Tabla A-5
P(KPa) T(°C)
7,5 40,29
10 45,81
Tpr = 42,0°C
c) Q = ? KJ
Q = entalpia de la reacción
𝐾𝐽
𝐶3 𝐻8 (𝑔) + 5𝑂2 (𝑔) → 3𝐶𝑂2 (𝑔) + 4𝐻2 𝑂(𝑙) − 103,85 0 − 393,52 − 285,83 𝑒𝑛
𝑚𝑜𝑙
𝐾𝐽
∆𝐻𝑅𝑒𝑎𝑐𝑐𝑖ó𝑛 = 4(−285,83) + 3(−393,52) + 103,85 = −2220,03
𝑚𝑜𝑙
𝐾𝐽
𝐶3 𝐻8 (𝑔) + 3,5𝑂2 (𝑔) → 3𝐶𝑂 (𝑔) + 4𝐻2 𝑂(𝑙) − 103,85 0,0 − 110,53 − 285,83 𝑒𝑛
𝑚𝑜𝑙
𝐾𝐽
∆𝐻𝑅𝑒𝑎𝑐𝑐𝑖ó𝑛 = 3(−110,53) + 4(−285,83) + 103,85 = −1371,06
𝑚𝑜𝑙
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