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    MSE 308 Problem Set 11 Solutions

    Uploaded by

    Anshu Kumar Gupta
    This document contains the solutions to problem set 11 for the MSE 308 Thermodynamics of Materials course taught by Professor Bill Knowlton in Spring 2005. The problems involve calculating free energies and heat of mixing values for binary systems using given equations, and graphing the results. Sample graphs are provided for problems 2 and 3 showing how the free energy and heat of mixing values change with composition for different interaction parameter values. Problem 4 asks students to create their own analogous problem using the Gibbs-Duhem equation.

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    MSE 308 Problem Set 11 Solutions

    Uploaded by

    Anshu Kumar Gupta
    427 views7 pages
    This document contains the solutions to problem set 11 for the MSE 308 Thermodynamics of Materials course taught by Professor Bill Knowlton in Spring 2005. The problems involve calculating free energies and heat of mixing values for binary systems using given equations, and graphing the results. Sample graphs are provided for problems 2 and 3 showing how the free energy and heat of mixing values change with composition for different interaction parameter values. Problem 4 asks students to create their own analogous problem using the Gibbs-Duhem equation.

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    This document contains the solutions to problem set 11 for the MSE 308 Thermodynamics of Materials course taught by Professor Bill Knowlton in Spring 2005. The problems involve calculating free energies and heat of mixing values for binary systems using given equations, and graphing the results. Sample graphs are provided for problems 2 and 3 showing how the free energy and heat of mixing values change with composition for different interaction parameter values. Problem 4 asks students to create their own analogous problem using the Gibbs-Duhem equation.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    427 views7 pages

    MSE 308 Problem Set 11 Solutions

    Uploaded by

    Anshu Kumar Gupta
    This document contains the solutions to problem set 11 for the MSE 308 Thermodynamics of Materials course taught by Professor Bill Knowlton in Spring 2005. The problems involve calculating free energies and heat of mixing values for binary systems using given equations, and graphing the results. Sample graphs are provided for problems 2 and 3 showing how the free energy and heat of mixing values change with composition for different interaction parameter values. Problem 4 asks students to create their own analogous problem using the Gibbs-Duhem equation.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
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    MSE 308 Thermodynamics of Materials

    Dept. of Materials Science & Engineering Spring 2005/Bill Knowlton

    Problem Set 11 Solutions

    1. In class, you were given:


    J Fmix = cX 1 X 2 . mole

    a. Find F1 and F2 . b. Check your answers by substituting them into the relation: Fmix = X 1 F1 + X 2 F2 .

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    MSE 308 Thermodynamics of Materials

    Dept. of Materials Science & Engineering Spring 2005/Bill Knowlton

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    MSE 308 Thermodynamics of Materials

    Dept. of Materials Science & Engineering Spring 2005/Bill Knowlton

    2. Similar to problem 1, the Helmholtz free energy of mixing is given by: J Fmix = ao X 12 X 22 . mole a. Find F1 and F2 . b. Check your answers by substituting them into the relation: Fmix = X 1 F1 + X 2 F2 . c. Graph F1 and F2 and Fmix all on the same plot as a function of X2 over a range of ao from -5000 to 5000 J/mol plotted at 500 J/mol increments.

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    MSE 308 Thermodynamics of Materials

    Dept. of Materials Science & Engineering Spring 2005/Bill Knowlton

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    MSE 308 Thermodynamics of Materials

    Dept. of Materials Science & Engineering Spring 2005/Bill Knowlton

    Part c: Blue: Fmix; Red: F1; Green: F2 Note that the largest positive values correspond to ao = 5000 J/mol and the most negative values correspond to ao = -5000 J/mol.

    Fmix, F1, F2 H J L mol


    1000 500 0 -500 -1000 -1500

    ao : 5000 to 5000 plotted at 500Jmol increments 2000 1500

    0.2

    0.4

    X2

    0.6

    0.8

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    MSE 308 Thermodynamics of Materials

    Dept. of Materials Science & Engineering Spring 2005/Bill Knowlton

    3. In the following binary system, the partial molar heat of mixing of component 1 can be fitted by the expression: . J 2 H 1 = ao X 2 X 1 . mole a. Calculate the heat of mixing and the partial molar heat of mixing of component 2. b. Graph the partial molar heat of mixing for both components and the heat of mixing all on the same plot as a function of X2 over a range of ao from -10 to 10 J/mol plotted at 1 J/mol increments.

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    MSE 308 Thermodynamics of Materials

    Dept. of Materials Science & Engineering Spring 2005/Bill Knowlton

    Part c: Blue: Hmix; Red: H1; Green: H2 Note that the largest positive values correspond to ao = 10 J/mol and the most negative values correspond to ao = -10 J/mol. The fact that H2 does not go to 0 when X2 is not present suggests an unrealistic solution. ao : 10 to 10 plotted at 1 Jmol increments

    Hmix, H1, H2 H J L mol


    1 0 -1 -2 0

    0.2

    0.4 X2

    0.6

    0.8

    4. In problem 6 of the last problems set, you proved the Gibbs-Duhem equation strictly using the following form of the Gibbs-Duhem equation:

    X
    i =1

    d Bk = 0

    when given the change in volume of each component for a particular solution with two components. Make up your own problem analogous to problem 6 and provide the solution to the problem. Open ended problem.

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