Grand Assignment

CHEMISTRY

Classification and Nomenclature of Organic

Compound
1. The IUPAC name of the compound

CH 2 CH 2 CH 2
|
|
|
CN

CN

CN

is

(a) 1, 2, 3-Tricyanopropane

(b) 3-Cyanopentane-1, 5-dinitrile

(c) 3-Cyanopentane-1, 5-dinitirle

(d) Propane-1, 2, 3-tricarbonitrilie

CH3 - CH - CH2 - CH3

2. IUPAC name of the following compound

is

(a) 1-(2-Butyl) cyclohexane

(b) 1-(3-Butyl)cyclochexane

(c) 2-Cyclohexylbutane

(d) 3-Cyclohexylbutane.

3. The structure of 4-methylpentene-2 is

(a) (CH 3 ) 2 CH CH 2 CH CH 2

(b) (CH 3 ) 2 CH CH CH CH 3

(c) (CH 3 ) 2 CH CH 2 CH CHCH 3

(d) (CH 3 ) 2 CHCH 2 CH 3 .

4. The IUPAC name of the compound,

CH 3
|
CH 3 CH 2 CH CH 2 COCl

is

(a) 3-Methylpentanoyl chloride

(b) 3-Methylbutanoyl chloride

(c) 1-Chloro-3-ethylbutanone

(d) 1-Chloro-3-methylpentanone.

5. IUPAC name of (C 2 H 5 ) 2 CHCH 2 OH is

(a) 2-Ethylbutanol-1

(b) 2-Methylpentanol-1

(c) 2-Ethylpentanol-1

(d) 3-Ethylbutanol-1.

6. An organic compound X (molecular formula C 6 H 7 O 2 N ) has six carbon atoms in a ring

system, two double bonds and a nitro group as substituent, X is
(a) Homocyclic but nor aromatic

(b) Aromatic but not homocyclic

(c) Aromatic but not heterocyclic

(d) Heterocyclic and aromatic

7. 2-Methyl-2-butene is represented as
(a)

(c)

CH 3
|
CH 3 CH CH 2 CH 3
CH 3 CH 2

C
CH 2
|
CH 3

8. The IUPAC name of

(b)

(d)

CH 3 CH CH
|
OH

(a) 4-Hydroxy-1-methylpentanal

CH 3

C
CH CH 3
|
CH 3

CH 3 CH CH CH 2
|
CH 3

C CHO
|
CH 3

is

(b) 4-Hydroxy-2-methylpent-2-en-1al
1

(c) 2-Hydroxy-4-methylpent-3-en-5-al
9. The IUPAC name for the compound,

(d) 2-Hydroxy-3-methylpent-2-en-5-al

CH 3 CH
|
CH 3

C CH 2 CH 3
||
CH 2

is

(a) 2-Ethyl-3-methylbut-1-ene

(b) 2-Isopropylbut-1-ene

(c) 2-Methyl-3-ethyl-3-butene

(d) 2-(1-Methylethyl)but-1-ene.

10. The IUPAC name of CH 3 C C CH(CH 3 ) 2 is

(a) 4-Methyl-2-pentyne

(b) 4, 4-Dimethyl-2-butyne

(c) Isopropylemethylacetylene

(d) 2-Methyl-4-pentyne

11. The kind of valency that exists in CaH 2 and C 2 H 2 is ?

(a) Electrovalency in CaH 2 and covalency in C 2 H 2

(b) Electrovalency in both

(c) Covalency in CaH 2 and electrovalency in C 2 H 2

(d) Covalency in both

12. When a mixture of potassium cyanate and ammonium chloride is heated, it gives
(a) Urea

(b) Methanamide

(c) Ethanamide

(d) Ethanamine

13. Which of the following IUPAC names is correct ?

(a) 2-Methyl-3-ethylpentane

(b) 3-Ethyl-2-methylpentane

(c) 2-Ethyl-3-methylpentane

(d) 3-Methyl-2-ethylpentane

14. The IUPAC name of

OHC CH CH CH CH CH 2
|
CH 2 CH 2 CH 2 CH 3

is

(a) 5-Vinyloct-3-en-1-al

(b) 4-Butyl-2, 5-hexadien-1-al

(c) 5-Vinyloct-5-en-8-al

(d) 3-Butyl-1, 4-hexadien-8-al.

15. The IUPAC name of the compound

CH 3 CH CHCH 2 CHCH 2 COOH

|
NH 2

is

(a) 5-Amino-2-heptenoid acid

(b) -Amino--heptanoic acid

(c) 5-Aminohex-2-enecarboxylic acid

(d) 3-Amino-5-heptenoic acid.

16. Which of the following represents the correct IUPAC name of the compound
CH 2 CH CH 2 Cl ?

(a) Allyl chloride

(b) 1-Chloro-3-propene (c) 3-Chloro-1-propene (d) Vinyl chloride

17. The structure formula of chclohexyl alcohol is

OH

(a)

OH

(b)

CH2OH

(c)

(d) none of these

18. The IUPAC of

CH 3 O
|
||
CH 3 CH C CH 2 CH 2 OH

is

(a) 1-Hydroxy-4-methyl-3-pentanone

(b) 2-Methyl-3-oxo-1-pentanone
2

(c) 4-Methyl-3-oxo-1-pentanol

(d) Hexanol-1-one-3.

19. Which of the following statements is false for isopentane ?

(a) It has three CH 3 groups

(b) It has one CH 2 group

(c) It has one CH group

(d) It has a carbon which is not bonded to hydrogen.

20. IUPAC name of (CH 3 ) 2 CH CH 2 CH 2 Br is

(a) 1-Bromopentane

(b) 2-Methyl-4-bromobutane

(c) 1-Bromo-3-metylbutane

(d) 2-Methyl-3-bromopropane

21. The IUPAC name of the compound

CH 3 CH CH 2
|
OH

CH 3
|
C CH 3
|
OH

is

(a) 1, 1-Dimethylbutane-1, 3-diol

(b) 1, 3, 3-Trimethylpropane-1, 3-diol

(c) 2-Methylpentane-2, 4-diol

(d) 1, 3, 3-Trimethyl-1, 3-propanediol

22. IUPAC name of the compound

CH 3 CH CH 2 CHOH CH 3
|
CH 2 CH 3

(a) 4-Methyl-3-hexanol

(b) Heptanol

(c) 4-Methyl-2-hexanol

(d) none of these

23. The IUPAC name of the compound,

CH 2 CH COOH
|
|
OH
NH 2

is

(a) 2-Amino-3-hydroxypropanoic acid

(b) 1-Hydroxy-2-aminopropan-3-oic acid

(c) 1-Amino-2-hydroxypropanoic acid

(d) 3-Hydroxy-2-aminopropanoic acid.

Cl

CH2CH3
C=C
I

24. IUPAC name for the compound H3C

is

(a) trans-2-Chloro-3-iodopentene-2

(b) cis-2-Chloro-3-iodo-2-pentene

(c) trans-3-Iodo-4-chloro-3-pentene

(d) cis-3-Iodo-4-chloro-3-pentene.

25. The compound,

is known by which of the following names ?

(a) Bicycol [2.2.2]octane

(b) Bicyclo [2.2.1] octane

(c) Bicyclo [1.2.1] octane

(d) Bicyclo [1.1.1] octane

26. The IUPAC name for the formula,

CH 3 H
|
|
CH 3 C C COOH

is

(a) 2-Methyl-2-butenoic acid

(b) 3-Methyl-3-butenoic acid

(c) 3-Methyl-2-butenoic acid

(d) 2-Methyl-3-butenoic acid

27. The correct IUPAC name of the compound with molecular formula, (CH 3 ) 3 C CH 3 is
3

(a) Pentane

(b) 1, 1, 1-Trimethylethane

(c) 2, 2-Dimethylpropane

(d) Neopentane.

28. The IUPAC name of

CH 3 C C C
CH 2 C CH
|
|
|
Cl CH 3 C 2 H 5

(a) 6-Chloro-4-ethyl-5-methylphept-5-en-1-yne
(b) 6-Chloro-4-ethyl-5-methylhept-1-yn-5-ene
(c) 2-Chloro-4-ethyl-3-methylhept-2-en-6-yne
(d) 2-Chloro-4-ethyl-3-methylhept-6-yn-2-ene.
29. The IUPAC name of the compound having the molecular formula Cl 3 C CH 2 CHO is
(a) 3, 3, 3-Trichloropropanal

(b) 1, 1, 1-Trichloropropanal

(c) 2, 2, 2-Trichlorop;ropanal

(d) Chloral

30. The IUPAC name of

O

OH

CH3 C CH2 CH CHO

is

(a) 5-Oxo-4-hydroxy-2-pentanone

(b) 4-Hydroxy-5-al-2-pentanone

(c) 2-Hydroxy-4-oxopentanal

(d) 1-Al-4-oxo-2-pentanol

31. IUPAC name of the following compound will be

CH 3 CH C CH 2 CH 3
|
CH 2 CH 2 CH 3

(a) 3-Propyl-3-hexene

(b) 3-Propyl-3-hexene

(c) 3-Ethyl-2-hexene

(d) 4-Ethyl-4-hexene

32. CH 3 CH 2 CH(CH CH 2 )CH 2 CH 2 CH 3 is

(a) 4-Ethenylheptane

(b) 3-n-Propyl-1-hexene

(c) 4-Ethenylhexane

(d) 3-Ethenylhexene

33. The IUPAC name of acraldehyde is

(a) Prop-2-en-1-al

(b) Propenyaldehyde

(c) But-2-en-1-al

(d) Propenal

34. The IUPAC name of

H

C4 H9

CH 3 C CH 2 CH C HO
H3 C

CH3

(a) 3, 4, 4-Trimethylheptane

(b) 3, 4, 4-Trimethylcotane

(c) 2-Butyl-2-methyl-3-ethylbutane

(d) 3-methyl-3-(2-propyl)heptanal.

35. The IUPAC name of CH 3 CH CHCOOC 2 H 5 is

(a) Ethyl but-1-enoate

(b) Ethyl but-2-enoate

(c) Ethyl prop-2-enoate

(d) none of these

4

36. The IUPAC name of

C=O

is

(a) Cyclohexanone

(b) Cyclohexylemethanone

(c) Oxyclocohexene

(d) Cyclohexylidenemethanone

37. IUPAC name of CH 2 CHCN is

(a) Ethenenitrilie

(b) Vinyl cyanide

(c) Cyanoethene

(d) 2-Propenentriile

38. Vinylcarbinol is
(a) HO CH 2 CH CH 2

(b) CH 3 CH(OH) CH 2

(c) CH 3 CH CH OH

(d) CH 3 C(CH 2 OH) CH 2

39. The IUPAC name of

CH 3

H
Br
|
|
C CH 2 CH 2 CH 2 C CH 3
|
|
OH
Br

is

(a) 6, 6-Dibromoheptan-2-ol

(b) 2, 2-Dibromoheptan-6-ol

(c) 6, 6-Dibromoheptan-6-ol

(d) none of these

40. The correct IUPAC name of

O
||
H C CHO

is

(a) Formylmethanal

(b) 1, 2-Ethanedione (c) 2-Oxoethanal

(d) 1, 2-Ethanedial.

41. The IUPAC name of the following CH 3 C(CH 3 ) 2 CH 2 CH CH 2 is

(a) 2, 2-Dimethyl-4-pentene

(b) 4, 4-Dimethyl-1-pentne

(c) 1, 1, 1-Trimethyl-3-butene

(d) 4, 4, 4-Trimethyl-1-butene

42. IUPAC name of 4-isopropyl-m-xylene is

(a) 1-(2-propyl)-2, 4-dimethylbenzene

(b) 4-Isopropyl-m-xylene

(c) 1-isopropyl-3, 5-dimethylbenzene

(d) 4-(2-propyl)-3, 5-dimethylbenzene

43. IUPAC

nomenclature

of

the

given

organic

compound

will

be

(CH 3 ) 2 C(CH 2 CH 3 )CH 2 CH(Cl)CH 3

(a) 5-Chloro-3, 3-dimethylhexane

(b) 4-Chloro-2-ethyl-2-methylpentane

(c) 2-Chloro-4-ethyl-4-methylpentane

(d) 2-Chloro-4, 4-dimethylhexane

44. The name of

ClCH 2 C C CH 2 Cl
|
|
Br

Br

according to IUPAC nomenclature system is

(a) 2, 3-Dibromo-1, 4-dichlorobutene-2

(b) 1, 4-Dichloro-2, 3-dibromobutene-2

(c) Dichlorodibromobutene

(d) Dichlorodibromobutane

45. Which of the following compound has wrong IUPAC name ?

(a)

CH 3 CH 2 CH 2 COO CH 2 CH 3
ethyl butanoate

(b)

CH 3 CH CH 2 CHO
|
3 methylbutanal
CH 3

(c)

CH 3 CH CH CH 3
|
|
OH CH 3

(d)

CH 3 CH C CH 2 CH 3
|
||
CH 3 O

2-methyl-3-butanol
2-methyl-3-pentanone

46. The correct nomenclature (IUPAC) for the following alcohol is

CH 3 CH 2

CH 3
C

CH 3 CH 2

OH

(a) 2-Ethyl-2-butanol

(b) 3-Methyl-3-pentanol

(c) 3-Ethyl-3-methyl-3-pentanol

(d) 1, 1-Diethylanol

47. IUPAC name of CH 3 CH 2 CH 2 CH(CH 3 )COCH 3 is

(a) Isohexanone

(b) Heptanone

(c) Hexanone-5

(d)

3-

Methylhexanone-2
48. The IUPAC name of CH 3 COCH(CH 3 ) 2 is
(a) 2-methyl-3-butanone

(b) 4-methylisopropopyl ketone

(c) 3-methyl-2-butanone

(d) Isopropyl methyl ketone

49. Name of the compound given below is

CH3
H3 C

CH3
CH3

(a) 4-ethyl-3-methyloctane

(b) 3-methyl-4-ethyloctane

(c) 2, 3-diethylheptane

(d) 5-ethyl-6-methyloctane

50. The IUPAC name of

CH3

is
(a) 3-Methylcyclohexane

(b) 1-Methylcyclohex-2-ene

(c) 6-Methylcyclohexane

(d) 1-Methylcyclohex-5-ene

51. The compound which has one isopropyl group is

(a) 2, 2, 3, 3-Tetramethylpentane

(b) 2, 2-Dimenthylpentane

(c 2, 2, 3-Trimethylpentane

(d) 2-Methylpentane.

52. The correct IUPAC name of the compound,

is
(a) 5, 6-Diethyl-8-methyldec-6-ene (b) 6-Butyl-5-ethyl-3-methylcot-4-ene
(c) 5, 6-Diethyl-3-methyldec-4-ene (d) 2, 4, 5-Triethylnon-3-ene.
6

CH 3 CH CHO

53. Choose the correct IUPAC name for

|
CH 2 CH 3

(a) Butan-2-aldehyde

(b) 2-Methylbutanal

(c) 3-Methylisobutyraldehyde

(d) 2-Ethylpropanal.

54. The IUPAC name of (CH 3 ) 3 C CH CH 2 is

(a) 2, 2-Dimethylbut-3-ene

(b) 2, 2-Dimethylpent-4-ene

(c) 3, 3-Dimethylbut-1-ene

(d) Hex-1-ene

Key
1.d

2.a

3.b

4.a

5.d

6.a

7.b

8.b

9.a

10.a

11.a

12.a

13.b

14.b

15.d

16.c

17.a

18.a

19.d

20.b

21.c

22.c

23.a

24.a

25.a

26.c

27.c

28.a

29.a

30.c

31.c

32.d

33.

34.d

35.a

36.d

37.d

38.a

39.a

40.d

41.b

42.a

43.a

44.b

45.c

46.b

47.d

48.c

49.a

50.b

51.d

52.c

53.b

54.c