Touseef Seminor Report
Touseef Seminor Report
Touseef Seminor Report
extract just the electrons and divert them through a separate path. Thus Sony used
an electron transport mediator so that electrons could be exchanged smoothly
between the enzymes and the electrodes that are the entrance and exit to that
detour. The principles of the bio battery are based on the energy conversion
mechanism in living organisms.However, in order to create the bio battery, several
technologies needed to be developed. These include immobilization of enzymes
that are normally incompatible with carbon and metal electrodes, electrode
structures, and electrolytes. Mechanisms used in living organisms, are not only
friendly to the environment but is also likely to be of practical use as an energy
source. This prototype bio battery has achieved the worlds highest power output
of 50 mW*2.
cathode (+), and the electrolyte. The cathode and anode (the positive and negative
sides at either end of a traditional battery) are hooked up to an electrical circuit.
2.2 History
As an electrical signal can induce a biological reaction; the reverse in is also true in
most of the cases and in this way biological processes can be used to generate
electricity for powering electrical equipment. Even though the Bio fuel cells have
been known for almost a century since the first microbial BFC(Bio fuel cells) was
demonstrated in 1912,the first enzyme-based bio-fuel cell was reported only in
1964 using glucose oxidize (GOx) as the anodic catalyst and glucose as the biofuel.
2.2.1 The first Bio Battery:
The Bio Battery, based on the work of Professor Kenji Kano (Kyoto University), is
a type of battery that uses energy sources such as carbohydrates, amino acids and
enzymes from a variety of sources. anode consists of sugar-digesting enzymes and
mediator, and the cathode composes of oxygen-reducing enzymes and mediator.
The mediators in this case are Vitamin K3 for the anode and potassium
ferricyanide for the cathode. When sugar is added to the mixture, the anode garners
the electrons and hydrogen ions. When the battery generates power, the protons
travel to the cathode through the electrolyte to combine with the oxygen to produce
water. Since the biocatalysts (enzymes) are very selective catalytically, the
miniaturized bio-fuel cell could in principle be fabricated as a membrane-less fuel
cell.
2.2.2 The Micro Fluidic BFC:
Lim and Pal more at the Brown University have reported a micro fluidic BFC with
many channels connected in parallel In this configuration, the design allows
streams of fuel and oxidant to flow in parallel within a micro channel without
using a membrane as a separator and showing a power density >25 uW/sqcm.
Several potential applications of BFCs have been reported or proposed in the
literature for implantable devices, remote sensing and communication devices as a
sustainable and renewable power source. However, there are no BFC design
formats or templates that allow for theproduction of a working device with a size
on the order of 1 cc, which are needed for several real world applications.
2.2.3 Enzyme Based Bio Battery:
Enzyme based BFC is very attractive, however it has been shown that electron
flow is too slow to make a viable fuel cell. This is due to the difficulty for enzymes
to attain direct electrical contact with the electrodes of the cell and catalyze
reactions effectively.
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The principles of the bio battery are based on the energy conversion mechanism in
living organisms. However, in order to create the bio battery, several technologies
needed to be developed. These include immobilization of enzymes that are
normally incompatible with carbon and metal electrodes, electrode structures, and
electrolytes. Mechanisms used in living organisms, are not only friendly to the
environment but is also likely to be of practical use as an energy source. Sony has
focused on these advantages since 2001 and has developed an electrical power
generation device that uses mechanisms similar to those in living organisms.
2.2.4 Bio battery using Human Blood
In 2003, Japanese researchers at Panasonic's Nanotechnology Research Laboratory
announced that they were working on extracting power from blood glucose. At the
time, they were using enzymes -- a frequent component of bio-batteries due to their
catalytic properties -- to retrieve electrons from glucose. Two years later, a
different Japanese research team, this one from Tohoku University, announced that
they had succeeded in creating a small "biological fuel cell." Their cell could be
used to power small medical devices, such as an implant to measure blood sugar
levels in diabetics. Future versions of such technology could, like RPI's
nanocomposite paper, be used to power an artificial heart with the blood that flows
through and around it.
2.2.5 Bio battery using Human Urine
In August 2005, scientists in Singapore developed a battery that uses human urine
as its fuel. Despite its potentially off-putting power source, the battery has a wide
variety of applications. The researchers said that their device was the size of a
credit card and could form the basis of inexpensive, disposable disease-testing kits.
(Urine is already used to detect drugs and some diseases.) What makes the device
particularly useful is that it integrated the battery and testing device into one
disposable chip. Imagine a one-time use home-testing kit for diseases like cancer
or hepatitis. One of the researchers involved in the project said that the battery
could also be adapted to provide a brief charge to other electronic devices. A lost
hiker might use one to power a cell phone for a short emergency call.[4] electrons
will be able to get to the cathode. In the picture above, the electrons go through the
wire, lighting the light bulb along the way. This is one way of describing how
electrical potential causes electrons to flow through the circuit. [6]
However, these electrochemical processes change the chemicals in anode and
cathode to make them stop supplying electrons. So there is a limited amount of
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power available in a battery. When we recharge a battery, you change the direction
of the flow of electrons using another power source, such as solar panels. The
electrochemical processes happen in reverse, and the anode and cathode are
restored to their original state and can again provide full power.
cathode, the hydrogen ions and electrons absorb oxygen from the air to produce
O2 +4H+ +4e 2H2O
3.2 Working
A Bio-Battery battery consists of two different metals suspended in an acidic
solution. They contain an anode, cathode, separator and electrolyte, which are the
basic components to any cell battery. Each component is layered on top of another
component. Anodes and cathodes are the negative and positive areas on a battery.
The anode is located at the top of the battery and the cathode is located at the
bottom of the battery.[Anodes are components that allow electrons to flow in from
outside the battery, whereas cathodes are devices that allow current to flow out
from the battery.
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Like a conventional fuel cell battery, Bio Battery basically consists of an anode,
cathode, electrolyte and separator. However, Bio Battery has certain specific
characteristics. First, biological enzymes are used as catalysts for the anode and
cathode. Second, enzymes and electronic mediators (which transfer electrons
between enzymes, and between enzymes and electrodes) are fixed on the anode
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and cathode. Glucose is broken down on the anode side of the battery, producing
protons (H+) and electrons (e-). The protons (H+) are transferred to the cathode
side through the separator, while the electrons (e-) are transported to the cathode
side through the mediator, which transfers them to the external circuit. The cathode
uses the enzymes to drive an oxygen-reduction reaction which ultimately produces
water using both the protons (H+) and the electrons (e-) transferred from the
anode. These reactions at the anode and cathode generate electric energy by
creating proton (H+) and electron (e-) flow in the cell system.
Bio batteries are heavily based on the amount of glucose available. The
decomposition of materials to glucose (if they are not already in the proper stage)
is the main step in getting the cycle started. Materials can be converted into
glucose through the process of enzymatic hydrolysis. Enzymatic hydrolysis is the
process in which cellulose (an insoluble substance) is converted to glucose with the
addition of enzymes. After glucose exists oxygen and other enzymes can act on the
glucose to further produce hydrogen ions and electrons.
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The latest step in the quest for 'clean electricity' has shown that proteins on the
surface of bacteria can produce an electric current by simply touching a mineral
surface. It is possible for bacteria to lie directly on the surface of a metal or mineral
andtransfer electrical charge through their cell membranes. In theory, it should be
possible to 'tether' bacteria directly to electrodes. With the process, microorganisms
attached to the anode then start snatching electrons from organic compounds
dissolved in the waste water to produce carbon dioxide and clean water.
All microbe-based batteries and fuel cells need a place to send electrons, a fact that
has proved to be technically challenging. With some new research, scientists at
Stanford University have replaced bubbling oxygen with a solid silver oxide that
consumes electrons, making a more reliable, rechargeable bacterial battery. Silver
possesses the highest electrical conductivity of any element and the highest thermal
conductivity of any metal. Silver is found in native form, as an alloy with gold
(electrum), and in ores containing sulfur, arsenic, antimony or chlorine.
Another advantage with silver it has a high efficiency in terms of the amount of
power produced. The downside is that silver is relatively expensive and the cost
would be high, should this be reproduced on an industrial scale.
In general, the bio-fuel cells are classified based on the type of electron transfer;
mediated electron transfer and direct electron transfer or electronic charge transfer
(ECT). The ECT of the bio-fuel cells is critically reviewed and a variety of
possible applications is considered. The technical challenges of the bio-fuel cells,
like bioelectrocatalysis, immobilization of bioelectrocatalysts, protein denaturation
etc
For the electron transfer the Carbone nano tubes are used which is a tube-shaped
material, made of carbon, having a diameter measuring on the nanometer scale. A
nanometer is one-billionth of a meter, or about one ten-thousandth of the thickness
of a human hair. The graphite layer appears somewhat like a rolled-up chicken
wire with a continuous unbroken hexagonal mesh and carbon molecules at the
apexes of the hexagons. Carbon Nanotubes have many structures, differing in
length, thickness, and in the type of helicity and number of layers.
Although they are formed from essentially the same graphite sheet, their electrical
characteristics differ depending on these variations, acting either as metals or as
semiconductors. As a group, Carbon Nanotubes typically have diameters ranging
from <1 nm up to 50 nm. Their lengths are typically several microns, but recent
advancements have made the nanotubes much longer, and measured in centimeters
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\CNTs have unique electronic properties, high mechanical strength and chemical
stability, making them attractive for fabricating of GOx coupled CNT based device
elements for use in bio fuel cells. For chemically coupling the CNTs with
biomolecules, it is critical to functionalize CNT surfaces,which are very inert.
Several strategies have been develop for functionalizing CNTs for sensing via
electrical, electrochemical, and electro-optical means. In all the cases, however, the
CNTs are functionalized wet-chemically in a spatially random fashion where
molecular bonding is mediated by defect creation, or hydrophobic adsorption.
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Fig -16: Microprocessor and LCD powered by bio battery The open circuit
voltage here is > 4.0V, Short-Circuit Current is > 125mA .The load voltage is V
>2.0V and current is approximately0.5mA while the power is 1mW .This
application needs 5mL of glucose fuel is sufficient for >100 hrs operation Another
example shows Sensor and Wireless Transmitter running on a bio battery.
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This 5W Prototype with 15-Cell Graphite Stack Designed and fabricated with
graphite bipolar plate configuration . This Stack provides 5V at 1A (5W).It is
Fitted with USB connector and demonstrated powering electronic devices and
recharging an iPhone.
Advantages
A significant advantage that bio-batteries have in comparison to other batteries is
their ability to allow an instant recharge.In other words through a constant supply
of sugar, or glucose, bio batteries are able to continuously keep themselves charged
without an external power supply with high fuel flexibility like sugar, alcohol,
diesel, ethanol,blood etc. Other advantages include high energy density,
size/weight, instant recharge, flexible shape, renewable biocatalysts, room
temperature operation, readily available fuel source.It can be an implantable
power source with flexible paper based prototypes. This is an Government and
IR&D funded research Since 2004 . Bio batteries are also a source of nonflammable, and non-toxic fuel. This provides a clean alternative renewable power
source.[9]
Future Scope
Improved design and performance leads to 50X higher volumetric power density
over existing prototype .The longer-term goal in this area is to further enhance
performance to ultimately develop batteries suitable for notebook computers and
other mobile devices. While many technological challenges still remain, Bio
Battery has great potential as a next-generation energy device. Advantages include
its excellent harmony with the environment as a product fueled by a carbohydrate
(glucose) having high energy density. Sony will continue to work toward the
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commercialization of this technology in the near future, initially for use in toys and
other low-power products.
Bio-batteries have a very bright future ahead of them as test productions and
research have been increasing over recent years. They serve as a new form of
energy that is proving to be environmentally friendly, as well as successful, in
producing and reserving energy. Fully-integrated demonstrations are to be
executed in close collaboration with customer, for relevant applications.
Applicatications
Bio batteries find applications in various fields like Miltary and commercial
applications,Medicalfield,ConsumerElectronics.InMiltary applications it is used
for Soldier portable power, unmanned chem/bio detection (large insects), MAVs,
remote surveillance (tree-sap),etc.
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