Uranium in Carbonate Rock

/,'7 -
Uranium in
Carbonate Rocks
GEOLOGICAL SURVEY PROFESSIONAL PAPER 474-A
Prepared on behalf of the

U.S. Atomic Energy Commission
Uranium in
Carbonate Rocks
By KENNETH G. BELL
SHORTER CONTRIBUTIONS TO GENERAL GEOLOGY
GEOLOGICAL
SURVEY PROFESSIONAL PAPER 474-A
Prepared on behalf of the

U.S. Atomic Energy Commission
A study of ore deposition and occurrence of uranium
in carbonate environments, including analyses
of
70 samples
UNITED
STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1963
UNITED STATES DEPARTMENT OF THE INTERIOR

STEWART L. UDALL, Secretary
GEOLOGICAL SURVEY
Thomas B. Nolan, Director
For sale by the Superintendent of Documents, U.S. Government Printing Office

Washington, D.C., 20402
CONTENTS
Abstract __________________________________________ _
Introduction ______________________________________ _
Objectives of the investigation _______________________ _
Previous investigations _____________________________ _
Theoretical considerations __________________________ _
Selection of sample materiaL ________________________ _
Analytical procedures ______________________________ _
Classification of carbonate rocks _____________________ _
Syngenetic uranium in carbonate rocks _______________ _
Epigenetic uranium deposits in carbonate rocks ________ _
Uranium in hydrothermal veins __________________ _
Efflorescent deposits of uranium minerals _________ _
Page
Page
A1
1
1
1
2
4
4
5
5
8
8
Epigenetic uranium deposits in carbonate rocks-Con.

Uranium deposits in karst terrains________________
Tyuya-Muyun, Fergana district, Uzbek S.S.R__
Bighorn-Pryor Mountains, Wyoming and
Montana________________________________
Peneconcordant uranium deposits in carbonate rocks_
Uranium deposits in the Todilto Limestone, New
Mexico__________________________________
Uranium deposits in the Sundance Formation,
Wyoming________________________________
Summary__________________________________________
Literature cited____________________________________
All
11
11
12
13
17
18
18
TABLES
Page
TABLE 1. Uranium content of dolomite from the Hermosa Formation, Paradox Basin, San Juan County, Utah____________
2. Analyses of some carbonate rocks and source materials____________________________________________________
AS
21

URANIUM IN CARBONATE ROCKS
By KENNETH
ABSTRACT
Carbonate rocks generally have been considered to be among

the least uraniferous substances of the earth's crust. This
conclusion has been based on analyses of a few samples. An
investigation of the association of uranium with several types
of carbonate rocks indicates that some revisions of the previous
conclusion are necessary. Rocks that are composed almost
wholly of carbonate minerals and that include only minute
traces of other constituents generally contain about 0.0001
percent (1 gram per ton), or less, of syngenetically deposited
uranium ; they are among the least uraniferous rocks. The
impure carbonate rocks, which form gradational series with
many other kinds of sediments, may contain readily measurable
quantities of syngenetically deposited uranium that is associated with the noncarbonate constituents. The quantities of
such uranium may range from about O.OOOX to O.OOX percent
and reach a maximum of a few tens of grams per ton. The
phosphatic constituent in some appreciably uraniferous limestones and dolomites is thought to hold the uranium; detrital
constituents and possibly organic matter may hold uranium in
other carbonate rocks. Uranium is deposited epigenetically in
carbonate rocks under a variety of circumstances, and some of
these deposits provide rich ores. Epigenetically deposited
uranium minerals in carbonate host rocks are found in hydrothermal veins, in efflorescent depos.its, in cavities of karst
terrains, and as peneconcordant deposits in stratified carbonate
rocks. The geochemical conditions that caus.e epigenetic deposition of uranium in carbona te rock environments, with the
exception of those causing some efflorescent deposits, have not
been determined.
1
INTRODUCTION
Limestones, dolomites, and other sedimentary carbonate rocks generally have been considered to be among
the least uraniferous of all the rocks of the earth's crust,
containing from almost none to about 4 parts per million uranium. This conclusion has been based on theoretical considerations and a few analyses of limestones
and dolomites predominantly of marine origin. Recent
investigations of carbonate rocks, both in the field and
in the laboratory, have shown that, whereas most rocks
that have carbonate minerals as major primary constituents have very little or possibly no uranium, nevertheless certain classes of these rocks may contain aboveaverage quantities of uranium. The earlier conclusion
G.
BELL
has been revised, and some qualifying amendments have

been made. The investigations described below have
not been accomplished in sufficient detail to permit complete recognition of all the geochemical relations involved, but some valid relationships have been established.
OBJECTIVES OF THE INVESTIGATION
The principal objectives of this investigation were to

determine ( 1) to what extent uranimn is deposited
syngenetically with carbonate sediments and what goochemical environments are essential for the inclusion
or uraniferous substances with carbonate sediments and
(2) some of the conditions under which uranium may
be deposited epigenetically in carbonate rocks. Information leading toward attainment of these objectives
was acquired by field examination of many carbonate
rocks and by chemical analysis of a representative collection of these rocks and of carbonate source materials.
PREVIOUS INVESTIGATIONS
It was discovered during early investigations of the

radioactivity of rocks and other terrestrial materials
that carbonate rocks in general have very low levels of
radioactivity. Consequently, little study has been made
of radioactive constituents in carbonate rocks as compared with the amount of study of these constituents
in other terrestrial materials. Because the uranium
contents of many carbonate rocks are close to, or below,
the threshold of analytical chemical procedures, many
determinations by such methods are inconclusive. The
results of some investigations have been reported in
terms of radium contents, others as equivalent uranium
contents-that is, actual uranium determinations were
not accomplished.
There are few published data pertaining to the
uranium contents of carbonate rocks. These data are
not accompanied by detailed descriptions or even
descriptions of the principal characteristics of the rocks
that were tested. Evans and Goodman (1941, table 9)
Al
A2
have reported uranium contents ranging from 0.30

X 10-6 to 2.6 X 10-6 g per g of rock ( 0.00003 to 0.00026
percent) for five samples of limestones from four
localities. Lahner ( 1939) reported uranium contents
ranging from 0.12 X 10-7 to 10.1 X 10-7 g per g of rock
( 0.000012 to 0.0001 percent) for 12 carbonate rocks of
various kinds; the sample materials were taken from
museum specimens. Bell (1956, p. 521) reported uranium contents ranging from 0. 7 to 3.8 ppm (parts per
million) ( 0.00007 to 0.00038 percent) for 11 typical
marine limestones and dolomites. Baronov and others
(EapoHoB, PoHOB, n RyHamoBa, 1956) determined
the uranium contents of 128 composites of carbonate
rocks made up from 5,475 samples collected from the
Russian platform; each composite represented a tier,
division, or system of the stratigraphic scale; ages
ranged from the late Precambrian to Quaternary.
The uranium contents of the composites ranged from
1.2 to 5.4 ppm. Distinguishing cha.racteristics of the
carbonate rocks represented in each composite are not
given. Inasmuch as the range of values is rather high
it is suspected that a substantial number of more or less
phosphatic carbonate rocks were represented in the
sample material. (See p. A5.) Some d~rminations
of uranium contents of carbonate rocks containing
epigenetically deposited minerals have been published,
but inasmuch as the investigations dealt with uranium
ores or potential ores of variable grade, the analytical
data are not considered to be characteristic of carbonate
rocks as a group.
This rather meager collection of uranium determinations made on carbonate rocks indicates that, in general,
uranium contents range from small fractions of a part
per million to a few parts per million (probably in the
range of <O.OOOOx to O.OOOx percent). Probably only
syngenetically deposited uranium was present in the
samples analyzed, but this condition cannot be taken
for granted. The reports do not indicate whether variations in uranium contents can be attributed to depositional environments or to the kinds and amounts of
noncarbonate constituents in these rocks.
THEORETICAL CONSIDERATIONS
The terms "limestone" and "dolomite" by definition

designate sedimentary rocks composed predominantly
of the carbonate minerals calcite and dolomite. The
terms commonly are used to designate rocks containing
roughly 50 percent or more by volume of carbonate
minerals, and sometimes they are used questionably to
designate rocks of which carbonate minerals are important constituents but constitute less than 50 percent
of the volume. The noncarbonate constituents of different limestones and dolomites may consist of clastic
detritus, clay minerals, iron oxides, manganese oxides,
calcium phosphate minerals, calcium sulfate minerals,

organic detritus, bitumens, various other organic derivatives of former plant and animal life, and many other
substances. The carbonate-rich rocks therefore are
parts of gradational series of which the end members
are pure limestone or dolomite on the one hand and
shales, siltstones, saline evaporites, and different varieties of organic-rich sedimentary rocks on the other
hand.
The sedimentary carbonate rocks are deposited in
aqueous environments. The chemical conditions may
be either oxidizing or reducing, but a much larger
volume of carbonate sediments prdbably is deposited
under oxidizing or slightly reducing conditions than
under strong reducing conditions. The oxidation-reduction potential of the medium from which carbonate
sediments are deposited has no bearing upon the deposition of alkaline-earth carbonates that constitute the bulk
of the carbonate rocks, but it does play a major role in
the kind and amount of syngenetically deposited chemical impurities.
Carbonate sediments are formed by biogenic and
chemical processes. Some reef limestones and coquinas
are formed almost entirely of skeletal parts and shells
of organisms; other limestones are composed almost
wholly of precipitated calcium carbonate; many carbonate rocks are composed of a mixture of bioclastic
and chemically precipitated components. The noncarbonate constituents in carbonate rocks may be deposited by any one of the sedimentary processes.
It has been known for a long time that uranium in
the oxidized, hexavalent or uranyl, state is highly soluble in the presence of substantial concentrations of
carbonate or bicarbonate ions, and this property is utilized by analytical chemists in making quantitative separations of uranium from several other metallic elements
(Fresenius and Hintz, 1895; Rodden and War, 1950,
p. 16, 31). It follows that in natural environments
where the carbonate or bicarbonate ion concentration
is high with respect to that of the uranyl ion, uranium
should not be precipitated along with carbonate sediments. Nearly pure carbonate rocks that were deposited
in oxidizing environments cannot be expected to contain
appreciable quantities of syngenetically deposited
uranium.
Uranium in the tetravalent, or uranous, state is
thought to form a soluble complex with the carbonate
ion. This conclusion is based on the fact that uraninites, or pitchblendes, which contain a mixture of hexavalent and tetravalent uranium, will dissolve completely
in some carbonate solutions, and uranium oxide (presumably uraninite) does not precipitate from all uraniferous carbonate solutions that are subjected to the
reducing action of hydrogen sulfide. The behavior of
the uranous ion in the presence of high concentrations

of the bicarbonate and carbonate ions apparently has
not been fully investigatE~d.
Theoretical considerations indicate that uranium
should not be deposited s:yngenetically with nearly pure
carbonate rocks laid down in reducing environments.
For example, a nearly pure limestone, even though
characterized by a fetid odor due to hydrogen sulfide
or sulfurous organic substances, normally cannot be
expected to be appreciably uraniferous.
Inasmuch as uranium has a strong tendency to remain
in solution in the presence of high carbonate-ion concentrations and is not eoprecipitated with carbonate
minerals, that uranium which is a syngenetic constituent of carbonate rocks must be intimately associated
with the impurities or noncarbonate constituents of
these rocks. Common constituents, or impurities, that
occur in various carbonate rocks, and which are capable
of holding small amounts of uranium, are certain heavy
mineral resistates, sedimentary or marine apatite,
fluorite, some kinds of organic matter, and possibly
other less-abundant substances.
Heavy mineral resistates may be present in impure
carbonate rocks, especially those that contain clastic
sediments. Zircon, sphene, igneous apatite, monazite,
and other resistates commonly contain small amounts
of uranium. Although these minerals contribute to the
total uranium content of the host rock, the amount of
the contribution generally is very small.
Marine apatite is an important constituent of many
marine limestones and dolomites, in fact, a completely
gradational series exists between nearly pure carbonate
rocks at one end and nearly pure phosphate rocks at
the other end. The uranium content of primary marine apatite characteristically ranges from 0.005 to 0.02
percent; phosphatic sediments that have been reworked
in marine environments may have uranium contents
ranging from 0.005 to 0.1 percent; it is thought that
this uranium substitutes for calcium in the apatite
structure, and it has been shown that uranium can be
secondarily leached from or introduced into the apatite
structure (Altschuler and others, 1958). If it is assumed that all the phosphate content of carbonate rocks
is in the form of apatite, then the quantity of this
mineral commonly is more than adequate to account
for all the uranium. Some carbonate rocks contain
substantial amounts of phosphatic fossils that hold
small quantities of uranium. This uranium probably
was introduced into the shells and skeletons after death
of the organisms and is not strictly syngenetic, but for
the purpose of this discussion it is considered to be so.
Some fluorite, particularly the purple varieties, may
contain small quantities of uranium. Most fluorite in
sedimentary carbonate rocks probably is an epigenetic
A3
constituent, but small grains of this mineral are found

in some limestones that are not metamorphosed and
show no evidence of alteration or introduction of material by hydrothermal or other solutions.
Organic matter is an important constituent of many
sedimentary carbonate rocks. Again there are gradational series ranging from nearly pure carbonate rocks
to nearly pure organic rocks. The hexavalent uranyl
ion and the tetravalent uranous ion are known to form
complexes with many organic substances, and several
such combinations are utilized in analytical chemistry
(Rodden and Warf, 1950, p. 11, 13). Undoubtedly
many other organo-uranium combinations exist that
have not been fully investigated or that are unrecognized. A part of the syngenetic uranium in some carbonate rocks probably is attached to organic matter.
Inasmuch as the precise composition and identity of
organic matter in sedimentary rocks are little-investigated subjects, only general statements can be mltde
about the association of uranium with organic matter.
Some forms of humic matter have a high capacity for
taking up uranium (Szalay, 1957; Manskaya and others
(MaHcRaH, .I(p03AOBa, n EMeJI:bHHOBa, 1956) ; Vine
and others, 1958), but the precise composition and character of the organo-uranium combination are unknown.
Many organic acids, some of which occur in nature in
small or minute quantities, can form uranium salts.
Hydrocarbons that are major constitutents of petroleums, asphalts, and most native bitumens apparently
have no capacity for taking up uranium (Bell, 1960b),
but some of the organic acids that are very minor constituents of petroliferous substances may readily form
uranium salts. Some organic-rich carbonate rocks contain above-average quantities of uranium.
This discussion of theoretical considerations so far
has dealt primarily with syngenetic deposition of
uranium in carbonate rocks. Epigenetic deposition of
uranium in carbonate rocks is known to occur under a
variety of widely differing conditions, hut no complete
explanation for the origin of some epigenetic uranium
deposits in carbonate rocks can ibe provided at this time.
Solutions that transport uranium are likely to be
either appreciably acid or alkaline rather than neutral.
Uraniferous acid solutions can be of hydrothermal
origin or can form from ground water in the zone of
oxidation where sulfide minerals become oxidized.
Acid solutions that flow through substantial amounts of
carbonate rocks become neutralized, or they even may
become slightly alkaline. Some uranium may be deposited as the pH changes. Alkaline carbonate-rich
solutions readily transport uranium, and it is evident
that the minerals of many uraniferous hydrothermal
veins were deposited from such solutions. Some of
these veins are found in carbonate rocks. The condi-
A4
tions that cause deposition of both uranium and carbonate minerals are not fully understood. Very few
paragenetic studies of such deposits have been made;
additional thorough studies are needed to provide more
information on the order of deposition and the influence of wallrock and to furnish clues concerning the
precise chemical and physical conditions that existed
at time of deposition.
The conditions that cause deposition of uranium in
hydrothermal deposits undoubtedly are physically and
chemically complex. It is possible to write chemical
equations, based on experiments made at room temperature and approximately atmospheric pressure,
that might represent reactions occurring during the
depositional processes, but one does not have complete
assurance that these reactions always occur in the range
of physical and chemical environments that exist
during genesis of hydrothermal deposits. The effects
of temperature and pressure on the solubility relations
between various ions in the ore-forming fluids, and
on phase relations of the solid and dissolved portions
of the reacting constituents are virtually unknown to
the geologist. The same statement can be made concerning most epigenetic deposition of uranium in sedimentary rocks under conditions other than
hydrothermal.
SELECTION OF SAMPLE MATERIAL
During this investigation, 70 samples of sedimentary

carbonate rocks and carbonate source materials were
collected and analyzed to determine their contents of
uranium and principal constituents. In addition,
eight samples obtained from well cuttings were checked
for uranium contents only; the small size of these samples precluded determinations of other constituents.
Most of the samples that were collected and analyzed
represent carbonate rocks in which the uranium contents are probably wholly syngenetic. These rocks
contain very small quantities of uranium and no visible
or identifiable uranium-bearing minerals except possibly some clastic resistates and sedimentary marine
apatite. A few carbonate rocks containing uranium
minerals of undoubted epigenetic origin were sampled
primarily for determination of their phosphate and
fluoride contents; samples of such rocks having wide
ranges of uranium contents can be selected at will because the epigenetic minerals usually are readily visible
and identifiable, and it was thought that the possible
presence of fluorides and phosphates that might have
been associated with the uranium mineralization would
be of greater interest.
The number of samples analyzed was limited by the
available capacity of the laboratory for this work.
The sampling seems very sparse in relation to the al
most infinite variety of carbonate rocks. An attempt

was made to get a wide coverage of carbonate rocks of
varying compositions that were deposited in different
environments. The collection includes marine and nonmarine rocks, calcitic and magnesian limestones, dolomites, marls, marlstones, fetid and nonfetid rocks,
calcareous shells, and predominantly carbonate rocks
having as impurities substantial amounts of phosphate
minerals, clastic detritus, clays, iron oxides, and organic
matter.
The rock samples were taken from individual beds
or from vertical sections a few inches thick because
the character and composition of sedimentary carbonate rocks commonly change abruptly within short vertical distances, even from stratum to stratum within
some thinly bedded series. The purpose of this selectivity was to limit each sample, insofar as practicable,
to a unit representing a single depositional environment. About 50 pounds of rock was taken from most
of rf:Jhe units sampled; the original sample was broken
into small fragments and by successive quartering was
reduced to approximately a 2-pound sample. The latter was pulverized in a grinder equipped with ceramic
plates and then was further reduced by quartering to
about 100 grams of material which was sent to the
laboratory for analysis.
ANALYTICAL PROCEDURES
All the sample material collected during this investigation was analyzed in the Geological Survey Laboratory at Denver, Colo. The constituents th81t were determined are: uranium, acid-insoluble matter, calcium as
calcium oxide, magnesium as magnesium oxide, total
R 2 0 8 , iron as ferric oxide, phosphorous as phosphoric
pentoxide, and fluorine. The results of the analyses
are tabulated in ta;ble 2.
Total uranium in the samples was determined by the
ethyl acetate extraction-fluorimetric method. Details
of the procedure are described by Grimaldi and others
(1954).
Acid-insoluble matter was determined as follows :
To 2 g of the sample was added 50 ml of 1 : 1 hydrochloric acid; and the mixture was heated to a boil on a hot
plate. The sample was then digested 1 hour on a steam
bath, 50 ml of hot water was added, and the sample
was filtered through tared sintered glass crucibles and
washed with 1-percent hydrochloric acid. The crucibles and insoluble matter were dried at 1050 and
weighed.
Acid-soluble calcium oxide and magnesium oxide
were determined by titration with versene (Shapiro
and Brannock, 1956).
R 20 8 was determined by ammonium hydroxide precipitation from an aqua regia solution.
UR~ ~
CARBONATE ROCKS
Total iron was determined colorimetr~cally with

o-phenanthroline ( Cuttitta, 1952).
Total phosphate was determined by the volumetric
method of the Association of Official Agricultural
Chemists (1950, p. 8-10).
Total fluorine was determined colorimetrically by the
method of Icken and Blank (1953) :following distillation by the method of vVillard and Winter ( 1933).
An approximate mineral composition was calculated
:for all samples in order to make a rough check of material balances and to assure that no important constituent was overlooked. All phosphate was assumed to
be in the :form of apatite, (CaF)Ca4 (P0 4 }s; all fluorine not accounted :for in apatite was assumed to be in
fluorite (CaF2); all calcium in excess of that assumed
to be in apatite and fluorite was assumed to be in calcium carbonate ( CaC03) ; all magnesium was considered to be in magnesium carbonate (MgC03) ; uranium was assumed to be in the :form of the oxide, U30s;
the percentages of insoluble matter and R 2 0 3 were used
as determined. The sun1mation of these assumed constituents is 100 3 percent :for most of the samples.
Deficiencies greater than 3 percent :for a :few samples
reasonably can be accounted :for by constituents such
as manganese oxides or earbonate, sulfide minerals, organic matter, silicate minerals, and other minor constituents known to be in the rocks.
A petrographic examination of the rocks was made
:for the purpose of observing textural features and
identifying the principal noncarbonate constituents.
The observations are included in table 2.
CLASSIFICATION OF CARBONATE ROCKS
The carbonate rocks and source materials sampled

and analyzed during this investigation are divided into
18 categories. The division is based in part upon welldefined characteristics and in part is arbitrary. This
classification, used in the discussion and in presenting
analytical data in table 2, is simply one possible method
of classifying these rocks; obviously many classification schemes can be devised.
The principal point of interest in this discussion is
tJhe uranium content of carbonate rocks; 'therefore, they
are divided into two ma;jor categories, those containing
only syngenetically deposited uranium, and those containing epigenetically deposited uranium. Further
subdivisions are based on combinations of the :following :features : ( 1) marine versus nonmarine origin, ( 2)
unmetamorphosed versus metamorphosed rocks, ( 3)
principal carbonate constituent, that is, calcitic limestones composed predominantly of calcite and containing less than 4 percent magnesium carbonate, magnesian limestones containing more than 4 percent and less
686494-63-2
A5
than 30 percent magnesium carbonate, and dolomite

which is arbitrarily considered to include all the rocks
containing more than 30 percent magnesium carbonate,
and ( 4) :fetid versus non:fetid rocks. Carbonate-bearing concretions, tufas, and shells of organisms are
placed in separate categories. . The separation of fetid
:from non:fetid rocks was made because some of the :fetid
rocks may have been deposited in reducing environments that commonly are thought to be conducive to the
precipitation of uranium.
SYNGENETIC URANIUM IN CARBONATE ROCKS
Minute quantities of uranium can be deposited syngenetically with carbonate sediments by at least :four
mechanisms:
1. Uranium can be a minor constituent of some substances that may be coprecipitated with carbonate
sediments; an example is calcium fluophosphate, or
marine apatite, in which a small quantity of uranium can substitute :for calcium.
2. Uranium may be adsorbed on clay, gelatinous silica,
and some :forms of organic matter that are deposited simultaneously with the ca,rbonate sediments.
3. Uranium may become incorporated in the sediments
shortly after deposition and, while the sediments
still are in contact with the aqueous medium :from
which deposition occurred, by base, exchange; an
example of this mechanism is the increase of uranium in marine apatites that remain in contact
with ocean water (Altschuler and others, 1958).
4. Uranium can be a minor constituent of some heavy
mineral resistates that are present in clastic detritus deposited with some impure carbonate sediments.
It is essential to notice that uranium deposited by these
mechanisms is contained in impurities adventitiously
deposited with carbonate sediments. No primary uranium carbonate minerals are known to be deposited
syngenetically with carbonate sediments.
The analytical data presented in table 2 indicate
that the most characteristic :feature of carbonate rocks
containing only syngenetic uranium is the generally
very low content of this element, which in most of the
samples ranges from less than 1 ppm ( <0.0001 percent) to about 4 ppm ( 0.0004 percent). Among 51
samples of carbonate rocks in which the uranium content is thought to be wholly syngenetic, 15 samples had
uranium contents of less than 1 ppm, and 10 samples
had uranium contents of 1 ppm. These 25 samples include marine and nonmarine rocks, calcitic limestones,
magnesian limestones, dolomites, :fetid and non:fetid
rocks, and metamorphosed and unmetamorphosed
A6
rocks. The rocks in this group were deposited under a

wide variety of sedimentary conditions.
The most significant feature of this group of samples
is that it includes most of the nearly pure carbonate
rocks that were analyzed (examples: Upper part of the
Burlington Limestone, I-A, No. 260486; upper part of
the Madison Limestone, I-A, Nos. 260492 and 260493;
Franklin Limestone, I-E, No. 249713, and I-B,
No. 249714; Niagara Group, I-G, Nos. 249702 and
249703; dolomites from the Stockbridge Limestone,
I-I, Nos. 249704 and 260487). The group includes
several fetid rocks (examples: Pinery Limestone
Member of the Bell Canyon Formation, I -C,
No. 260483; Edwards Limestone, I-D, No. 260448;
Hueco Limestone, I-D, No. 260488; limestone bed in
Pierre Shale, I-D, No. 249717). The group also includes some carbonate rocks that contain a few percent
of impurities in the form of acid insoluble matter, iron
and aluminum oxides, and probably other minor constituents (examples: St. Louis Limestone, I-A,
No. 249711; Sinbad Limestone Member of Moenkopi
Formation, I-A, No. 260542; limestone from Maysville Group, I-A, No. 249710; limestone from Chaffee
Formation, I-D, No. 260457; Pony Express Limestone
Member of \Vanakah Formation, I-J, No. 260479).
Only one conclusion can be drawn from this assemblage
of data, that is, uranium is not syngenetically deposited
in significant quantities with most carbonate rocks.
This conclusion is in accordance with the theoretical
consideration that uranium compounds, under most
circumstances, are not deposited from solutions in
which carbonate, or bicarbonate, or carbonate and bicarbonate ion concentrations are high with respect to those
of various uranium ions.
The fact that the fetid rocks do not contain significant quantities of uranium merits a brief comment. If
the sediments that constitute these rocks had been deposited from sulfurous waters where reducing conditions prevailed, they might be expected to contain
greater quantities of uranium than nonfetid rocks
having otherwise identical compositions. The quantities of uranium would be dependent upon rates
of sedimentation and availability of uranium in
the aqueous medium. Rapid sedimentation generally
would result in low uranium contents. Sediments
oftentimes may be deposited on the ocean bottom or a
lake bottom under oxidizing conditions and, after a
particular layer becomes buried at a slight depth,
putrefaction of a small content of organic matter
creates a sulfurous reducing environment. The available uranium is limited to the minute quantity present
in the connate water and, consequently, the sediment
cannot become appreciably enriched with the element.
No attempt was 1nade during this study to determine
whether the fetid character of the rocks was acquired

contemporaneously with deposition or by subsequent
alteration of primary sediments.
The trubulated data indicate that, when substantial
quantities of phosphate are present in carbonate rocks
as an impurity, the uranium contents may be considerably increased. For example, the limestone sample
from the Uinta Formation (I-F, No. 260490) contained
0.28 percent P 20 5 and 0.021 percent uranium, a dolomite
sample from the IGttatinny Limestone (I-I, No.
249706) contained 0.40 percent P20 5 and 0.0020 percent
uranium, and a sample from the !iilton Dolomite (I-I,
No. 249708) contained 3.06 percent P205 and 0.0030
percent uranium. The sample of limestone from the
Uinta Formation, which is of nonmarine origin, was
taken from a bed about 4 inches thick; this sample contained a small quantity of organic matter of undetermined character that probably holds some of the
uranium. The IGttatinny Limestone and Milton
Dolomite are of marine origin and have thick, slightly
phosphatic beds that can be traced for considerable
distances. There is no constant ratio between the
phosphate and uranium contents of carbonate rocks.
Some of the most phosphatic samples collected during
this investigation, such as one from the Bigby Limestone (I-A, No. 260445) that contained 2.85 percent
P 20 5 and one from the Hermitage Limestone (I-B,
No. 260446) that contained 6.87 percent P20 5, contained
only slightly more uranium than the general run of
nonphosphatic rocks, that is, 0.0002 and 0.0004 percent
respectively.
Four samples of slightly phosphatic and uraniferous
limestone containing a substantial amount of organic
matter (III-A, Nos. W66873, W67241, W67247, and
W90218) from the Bear River Formation of Cretaceous
age, Fall River area, Bonneville County, Idaho, (collected by J. D. Vine of the Geological Survey) have
been analyzed, and the results are included in table 2.
These limestone samples contained about 1 percent P205
and 0.01 to 0.024 percent uranium. The phosphateuranium ratios are unusually high, and some of the
uranium probably is associated with the organic
matter. The Fall River locality has not been examined
by the author, and it cannot be stated definitely whether
all the uranium in this limestone is syngenetic or
whether some of it may represent a late enrichment.
For this reason these samples are not listed with those
believed to contain only syngenetic urani urn.
A lack of correlation between phosphate and uranium
in apatites and phosphorites has been noted by several
investigators (Hebert, 1947; Davidson and Atkin,
1953; Altschuler and others, 1958). Recent investigations by Altschuler and others (1958) indicate that
uranium probably enters the apatite structure in iso-
morphous substitution for calcium, and the substitution

can take place as the mineral is formed and at any time
thereafter when ocean water, ground waters, or other
aqueous solutions make uranium available. The phosphatic constituents of carbonate rocks probably are
predominantly forms of apatite, fluorapatite, and carbonate-apatite. The introduction of uranium into
lacustrine and marine limestones and dolomites most
likely occurs between the time the sediment is deposited
on the bottom and its burial by the next suceeding layer.
The quantity of uranium that can be introduced is dependent upon its concentration in the water and the
length of time the sediment remains unburied. These
conditions are conducive to highly variable
uranium-phosphate ratios, particularly when the rate
of sedimentation fluctuates.
None of the samples listed in table 2 as containing
only syngenetically deposited uranium contained megascopically visible fluorite although a few of them contained a few hundredths of a' percent of fluorine in
excess of that which would be held in fluorapatite if all
the phosphate constituent exists in this mineral. (Examples: Bigby Limestone, I-A, No. 260445; Hermitage
Limestone, I-A, No. 260446; Mahogany oil shale bed
(of economic usage) in the Parachute Creek Member
of the Green River Formation, I-F, No. 260464; marlstone from the Green River Formation, I-K, No.
260485). The maximurn uranium content of these
samples was 0.0004 percent, and it cannot definitely be
associated with any particular constituent. The Salem
Limestone ( Spergen Limestone of former usage) locally
contains scattered small crystals of purple fluorite. The
two samples of this rock, I-A, No. 249720, and I-D, No.
260463, that were selected for analyses did not contain
any visible fluorite and contained only 0.0004 and
0.0003 percent uranium respectively. During wet
periods, thin effiorescent films of a carnotite-type mineral, which apparently is a transient substance here,
appear on some joint surfaces and parts of quarry faces
in this rock (J\fuilenburg and Keller, 1950; Gott and
others, 1952, p. 34).
Uranium, in many places, is associated with various
native organic substances that, in general, have not been
precisely identified. There is substantial evidence that
uranium tends to associate with humic-type organic
substances (Vine and others, 1958; Manskaya and
others (MancEaa, Jipos.n;oBa, :n: EMeJibaHoBa, 1956))
and shuns sapropelic-type organic substances, including
petroleum hydrocarbons (Bell, 1960b) and sapropelic
solids. Different carbonate rocks contain a wide variety
of native organic substances as impurities.
Several of the samples of carbonate rocks analyzed
during this investigation contained readily noticeable
quantities of organic matter. A sample of dark-gray
A7
fetid Madison Limestone (I-C, No. 260450) that contained many fossil brachiopods contained 0.0004 percent uranium. A sample from the Sinbad Limestone
Member of the Moenkopi Formation (I-A, No. 260452)
that contained about 2 or 3 percent of heavy petroliferous residue and a sample of dolomite from the Niagara
(I-G, No. 249703) that contained enough residual
petroliferous matter to give the rock a dark brown color
contained 0.0001 and less than 0.0001 percent uranium,
respectively. These determinations confirm the earlier
observations that petroliferous substances are not carriers of significant quantities of uranium (Unkovskaya,
1940; Bell, 1960b). Two samples of metamorphosed
Franklin Limestone (I-E, No. 249713, and I-B, No.
249714) that contained abundant flakes of graphite both
contained less than 0.0001 percent uranium. A sample
of madstone from the Mahogany oil shale bed in the
Parachute Creek Member of the Green River Formation
(I-F, No. 260464) that contained at least 25 percent
kerogen contained only 0.0004 percent uranium. This
determination supports the observation that sapropelic
substances are not carriers of significant quantities of
uranium. The samples that were analyzed did not indicate any tendency for uranium to concentrate in the
organic-rich carbonate rocks.
During the course of investigating the distribution of
uranium in salt-pan deposits (Bell, 1960a), several samples of drill cuttings from the Hermosa Formation of
the Paradox basin, southeastern Utah, were checked
for uranium contents. This collection included seven
samples of dolomite. The small amounts of material
that were available permitted only uranium determinations to be made. A few thin beds of slightly uraniferous black shale (maximum uranium content was 0.0057
percent) are interspersed in the dolomite. The dolomite
samples contained no megascopically visible shaly
material. All the samples were oil stained and emitted
an odor of crude petroleum when crushed. The analytical data are listed in table 1. No unusual concentrations of uranium are indicated, and it is thought
that the slight traces of uranium were deposited syngenetically with the carbonate sediments.
A few conclusions can be drawn from the preceding
discussion and from the analytical data presented in
table 2: Uranium is an insignificant syngenetic constituent of rocks composed almost wholly of carbonate
minerals and of only traces of phosphates, fluorides,
and organic substances of humic origin. The uranium
contents of these rocks reasonably can be considered to
range from 0 to 0.0001 percent ( 1 gram per ton).
The almost pure carbonate rocks are end members
of gradational series with many other kinds of sedimentary rocks. As the proportions of noncarbonate
constituents increase, the uranium contents likewise
A8
TABLE
1.-Uraniumcontent of dolomite/rom the Hermosa Formation, Paradox basin, San Juan County, Utah
[Analysts: C. G. Angelo, J.P. Schuch, and E. J. Fennelly]
Sample
Description
252225
----- Dolomite
___ --- __ ---------------_
252226 ____
______________
do ________________________
252227 ______________ do ________________________ _
252228 _ _ _ _ __ _ __ Dolomite and anhydrite ____ ---- __
252248_ _ _ _ __ _ __ Dolomite ________ ---- ___ -------252253 ______________ do ________________________ _
252256 ______________ do ________________________ _
Uranium
(percent)
0.0004
0011
. 0003
. 0003
. 0002
. 0001
. 0005
Source of samples:
Nos. 252225, 252226, 252227, 252228 from Shell Oil Co. 1 North Boundary Butte
well, CSW~NE~ sec. 33, T. 42 S., R. 22 E., San Juan County, Utah, at
depths of 4,221 ft 6 in, 4,622 ft, 4,623 ft, and 4,625 ft, respectively.
No. 252248 from Superior Oil Co. 1-28 Navajo well, CNW~NW~ sec. 28, T.
41 S., R. 26 E., San Juan County, Utah, at depth of 6,073 to 6,074 ft.
No 252253 from Shell Oil Co. 1 Desert Creek well, SW+4SE~NW34 sec. 2, T.
42 S., R. 23 E., San Juan County, Utah, at depth of 5,128 ft 6 in.
No. 252256 from Reynolds Metal Co. 1 Hatch well, sec. 4, T. 39 S., R. 24 E.,
San Juan County, Utah, at depth of 5,799 to 5,800 ft.
may increase appreciably. The presence of phosphate,

presumably as calcium phosphate in some form of
apatite, commonly has a significant effect on uranium
content. Many phosphatic carbonate rocks contain
quantities of uranium that are n1easurable by routine
chemical methods (in excess of 0.0001 percent or 1 gram
per ton). This uranium probably substitutes for calcium in the apatite structure, and the quantities of
uranium in such rocks are dependent upon environments existing at times of sedimentation and upon subsequent geological histories. There is no consistent
ratio between the uranium and the phosphate contents
in these rocks; in fact, some phosphatic limestones are
almost devoid of uranium, and the quantities of uranium
in other phosphatic limestones may reach a few tens of
grams per ton. The uranium in carbonate rocks containing substantial amounts of detrital sediments is
most likely to be in uraniferous heavy mineral
resistates. The association of uranium with organicrich carbonate rocks has not been thoroughly investigated. Available data indicate that carbonate rocks
containing sapropelic derivatives such as kerogen and
petroleum hydrocarbons are not enriched in uranium.
It is pointed out in the discussion of epigenetic uranium
deposits in carbonate rocks that some of these rocks
which contain rich uranium deposits are strongly fetid.
Analyses of several fetid limestone and dolomite
samples show that these rocks, as a group, are not at
all enriched with syngenetically deposited uranium.
Finally, no useful result can come from any attempt
to establish average uranium contents of comparatively
impure carbonate rocks on the basis of available data.
The uranium contents of these rocks are associated with
the noncarbonate constituents rather than the carbonates, and, to have any meaning at all, average uranium
contents should be expressed in relation to quantities
of specific impurities in the carbonate rocks; sufficient
analytical data to justify such expressions have not

been assembled.
EPIGENETIC URANIUM DEPOSITS IN
CARBONATE ROCKS
Uranium is deposited epigenetically in carbonate

rocks under a wide variety of circumstances. In the
discussion that follows these deposits are divided into
four types : ( 1) hydrothermal veins, ( 2) effiorescent deposits, ( 3) deposits in karst terrains, and ( 4) peneconcordant deposits. The term hydrothermal vein should
need no explanation. The effiorescent deposits form
at or near the earth's surface by evaporation of uraniferous solutions. Many minerals can be deposited in
caves, solution channels, and other cavities in the carbonate rocks of karst terrains; uranium minerals are
included in this group. The peneconcordant deposits
are formed in permeable sedimentary rocks. Epigenetic uranium deposits may originate from hydrothermal processes, from supergene enrichment processes,
may be effiorescent, or even may form as results of combinations of these processes.
URANIUM IN HYDROTHERMAL VEINS
Large uraninite-bearing veins of hydrothermal origin cut across sedimentary carbonate rocks in the Shinkolobwe district, Republic of Congo (Thoreau and du
Trieu de Terdonck, 1933, 1936; Bain, 1950; Derriks
and Vaes, 1956), and in the Lake Athabaska region,
Saskatchewan, Canada (Alcock, 1936, p. 36; Christie
and Kesten, 1949; Bowie, 1955; Robinson, 1955). Uranium-bearing veins have been discovered in carbonate
rocks at several localities in Central Asia; the uranium
minerals near the surface are mainly carnotite and
tyuyamunite and are accompanied in different deposits
by barite, sulfide minerals, and secondary copper minerals. Available descriptions hint that the primary
mineralization in some of these deposits may have been
hydrothermal. Such deposits at Kan-sai in the
Tadzhik S.S.R. are described by Arapov (ApanoB,
1936); deposits at Tyuya-Muyun in the Uzbek
S.S.R. are described by Alexandrov (AJieRcaH;o;poB,
1922), Pavlenko (IIaBJieHKO, 1933), and Betekhtin
(BeTexTHH, 1946); deposits at Agalyk in the Uzbek
S.S.R. are described by Gorbunov (rop6yHoB, 1935)
and Gotman croTlvraH, 1937); and deposits at Taboshar in the Tadzhik S.S.R. are described by Vol'fson
(BoJin<f>coH, 1940).
The uraninite-bearing hydrothermal veins at Shinkolobwe are enclosed by dolomite in which there are
some schist, sandstone, and siliceous beds. The structure, mineralogy, and geological history of these deposits are complex. The deposits have been deeply
weathered, and above the present ground-water table
URANITUl4
CARBONATE ROCKS
the secondary ores, which have been largely mined out,

consist of a great variety of secondary uranium minerals and oxidation products of primary sulfide and
selenide minerals. Descriptions of the deposits by
Thoreau and du Trieu de Terdonck (1933) and Derriks and Vaes (1956) indicate that a large proportion
of the carbonate constituents in the oxidized zone has
been removed, apparently by weathering processes.
Below the water table, in the unoxidized zone, uraninite is the only uranium mineral, and carbonate minerals, both in the veins and in the wallrock, are intact.
The mineralization process apparently included at
least two phases of vein carbonate mineral deposition,
one preceding and one following uraninite deposition
(Derriks and Vaes, 1956, p. 127). Several sulfide minerals, those of nickel and cobalt being most abundant
and including iron, molybdenum, and copper sulfides,
were deposited after the uraninite. Descriptions of
the deposits indicate that uraninite replaces some of
the earlier carbonate minerals, and, in turn, is replaced
by later carbonate minerals; uraninite and sulfide minerals tend to be concentrated in separate veins.
Uraninite-bearing veins in the Lake Athabaska region, Saskatchewan, Canada, are enclosed in a sequence
of Precambrian rocks that includes gneisses, chlorite
schists, diabases, basalts, quartzites, conglomerates, and
dolomites. The vein materials consist principally of
carbonate and sulfide rninerals and lesser amounts of
uraninite and other minerals. Uraninite-bearing parts
of the veins occur within all the rocks of the region, but
published descriptions soem to indicate that the quantities of uraninite are least where dolomite forms the
wallrock. About 40 percent of the uraninite occurs as
colloform masses, 5 percent as dusty or sooty powder,
and most of the remainder as massive pitchblende or
uraninite (Robinson, 1955, p. 61).
There is little inforn1ation available to the author
about the uraniferous veins of Central Asia. The obtainable literature reports only the presence of secondary uranium minerals in these deposits; this indicates that the descriptions probably apply to oxidized
zones. Some of the veins in the Tyuya-Muyun locality
originally may have consisted of minerals of hydrothermal origin. The hydrothermal activity could have
been associated with nearby igneous intrusions according to Pavlenko (IIaBJieHRo, 1933) and S'himkin
(1949). Arapov (Apa1roB, 1936) has described uraniferous deposits within limestone, which in places has
been converted to skarn, along the contact with a
granodiorite batholith in the vicinity of Kan-sai.
Other uranium deposits within limestones and near
contacts with igneous intrusive rocks that are situated
near Agalyk in the Uzbek S.S.R. have been described by Gorbunov crop6yHOB, 1934)' Zil'bermintz
A9
(3nJII>6epMHHD;, 1935), and Zil'bermintz and Samoilo

(3HJII>6epMHHD; H CaMOti:Jio, 1935).
Slightly uraniferous apatite and traces of a powdery
yellow uranium mineral have been found in a fault
zone in the Kittatinny Limestone at the Mulligan
quarry, Clinton, N.J. The traces of secondary yellow
uranium mineral may have been derived from the apatite or may be a slight supergene enrichment of uranium
leached from the carbonate rock itself or from formations that formerly overlay the Kittatinny hut have
been eroded from the locality. The rock exposed in the
Mulligan quarry is dolomite or has the chemical composition of dolomite. Two samples (I-I, Nos. 249706
and 249707) taken from the quarry contained 0.0020
and 0.0006 percent uranium respectively; sample
249706 was taken from a bed of slightly phosphatic rock
approximately 10 feet thick.
In summary, it is pointed out that, although carbonate rocks would seem on the basis of theoretical considerations to provide unfavorable environments for
the deposition of uranium minerals from hydrothermal
solutions, such deposits do exist and some furnish rich
ores. This situation indicates a gap in our knowledge
of the chemical behavior of uranium. Carbonate gangue
minerals are abundant in the known deposits.
At Shinkolobwe, uraninite veins are enclosed in predominantly carbonate rocks; on the other hand, in the
Lake Athabaska region carbonate rocks form a small
part of the stratified sequence, and the richest parts of
the uraninite-bearing veins are adjacent to siliceous
rocks. An interesting observation has been made by
Derriks and Vaes (1956, p. 106) in describing the Shinkolobwe deposits. They state, "The uraninite is always
crystalline. We have never observed at Shinkolobwe
the colloform type which occurs at Great Bear Lake and
St. J oachimstal." The following question arises: Is
uraninite deposited in a carbonate rock environment
likely to be crystalline and that deposited in a silicate
rock environment likely to be colloform ~
EFFLORESCENT DEPOSITS OF URANIUM MINERALS
Superficial deposits of efflorescent epigenetic uranium

minerals are found in some places on walls of solution
cavities 'and open fractures and even on surfaces of outcrops of all kinds of rocks. Tyuyamunite, carnotite,
uranophane, bayleyite, and schroeckingerite are the
most common constituents of such deposits, but other
secondary uranium minerals may be deposited. The
distribution of uranium minerals is generally erratic
and commonly is so sparse that the minerals are barely
visible. Such deposits are fairly common in semiarid
regions and are rather uncommon elsewhere. The
uranium minerals in some deposits are associated with
substantial amounts of chalcedony and (or) opal and
AlO
in other deposits with secondary calcite or with nonuraniferous efflorescent minerals. All these substances
are deposited because the solutions that transport them
evaporate. A change of pH as the solutions enter a
carbonate rock environment probably is a secondary
factor causing deposition.
The largest efflorescent deposits that have been found
in carbonate rocks in the United States are in the Miller
Hill area of Carbon County, Wyo. Here they are small
uranium deposits on and within a few feet of outcrops
of a thin lenticular lacustrine algal limestone bed in
theNorth Park ( ~) Formation of Pliocene ( ~) age. The
limestone is more resistant to erosion than the so.ft sandstone above it. The limestone is exposed in small cliffs
and on benches ranging from a few feet to a few hundred feet in width behind the cliff's. The only visible
uranium mineral is uranophane that is spottily distributed in fractured and brecciated parts of the limestone.
This mineral apparently does not occur in the rock along
the cliff faces; it is most abundant in a zone of variable
width on the benches extending from the margin of the
overlying sandy sediments towards the cliff's.
Slightly uraniferous chalcedony and opal, mostly
dark gray to black, have been deposited in fractures,
vugs, and solution cavities in the limestone. These minerals, which have a greater distribution than the uranophane, definitely are epigenetic constituents of the
rock. The chalcedony and opal were deposited from
ground-water solutions carrying both silica and uranium. A part of the silica seems to have been deposited
as a result of evaporation, but reactions between silicarich solutions and the carbonate rock may have caused
a substantial part of the deposition of silica.
The uranophane in this limestone seems to be a strictly
efflorescent mineral. It has been found only in the
upper part of the limestone bed where it crops out or
is covered with a thin soil mantle; it has not been found
on cliff faces because it can be readily leached in such
places. U ranophane evidently is being formed by
evaporation of uraniferous ground-water solutions, and
capillary action is instrumental in bringing the solutions toward ground surface. U ranophane is a rather
soluble uranium mineral; it is more soluble than carnotite and tyuyamunite. There is probably a slow, but
continuous, movement of uranium across the limestone
benches; uraniferous ground water draining from the
more elevated terrain behind the benches evaporates
from the porous limestone exposed along the benches;
through the medium of successive resolution and redeposition, the uranium moves toward the cliff faces and
finally is carried a way in the surface drainage. U ranium that becomes incorporated in uranophane is not
leached from chalcedony and opal.
Uranium deposits in the Miller Hill area also have

been described briefly by Love ( 1953) and by Vine and
Prichard (1959) who suggest that the uranium was
leached from tuffaceous beds in the upper part of the
North Park ( ~) Formation and transported to sites of
deposition by ground water.
Small pockets of ore-grade material are found in the
Miller Hill area. The deposits discovered up to 1958
ranged from a few hundred pounds to possibly a ton
of ore-grade rock. The small size of these deposits,
and an erratic distribution of the uranium mineral make
them unfa.vorable for profitable exploitation.
U ranophane is locally rather abundant in the uppermost part of the Todilto Limestone, Grants district,
McKinley County, N.Mex., but not in sufficient quantity to constitute ore. It has been deposited in vugs,
solution cavities, and along open fractures. This
uranophane seems to be in the form of efflorescent
deposits.
Similar deposits found in carbonate rocks elsewhere
in the United States produce interesting specimens but
not ores. Such minor deposits in the Hueco and
Edwards Limestones of west Texas are described by
Eargle (1956). Carnotite and tyuyamunite form thin
films on fracture surfaces and walls of cavities in these
limestones and on surfaces of boulders and pebbles in
the alluvial mantle. The uranium probably has been
leached from thin clay and shale beds in the limestone
formations by ground and surface waters. Yellow
secondary uranium minerals occur in cavities and fractures in limestone beds of Mississippian and Pliocene( ~)
age in the vicinity of Clarkdale and Jerome, Ariz.
Minor deposits of uranium minerals occur in the limestone facies of the Hermosa Formation, Gypsum Valley
area, San Miguel County, Colo. Stephens (1954) has
described briefly minor deposits of secondary uranium
minerals in cherty limestone of the Browns Park ( ~)
Formation of Miocene(~) age in the Saratoga area,
Carbon County, Wyo.; these deposits are similar to
those in the Miller Hill area. Isachsen and others (1955,
p. 129) mention the presence of copper-uranium mineral
concentrations in the uppermost parts of the Kaibab
Limestone of Permian age near Williams, Ariz.
Thin films of carnotite coat fracture surfaces and
cavities in dolomite wallrock of hydrothermal fluorspar
pipes in the Thomas Range district, Utah (Thurston
and others, 1954, p. 5 and 29') . The fluorite in these
deposits is slightly uraniferous, and near-surface weathering probably has released some uranium that has been
redeposited in carnotite.
Yellow coatings of carnotite, or a carnotite-type
mineral sporadically appear on rock faces of quarries
in the Salem Limestone ( Spergen Limestone of former
usage) near Ste. Genevieve, Mo. The limestone itself
does not seem to contain unusually large amounts of
All
Rich deposits of secondary uranium minerals are

found in caves, solution channels, and fractures in
carbonate rocks of karst terrains at Tyuya-Muyun,
Fergana district, Uzbek S.S.R., U.S.S.R., and in the
Pryor Mountains-Bighorn Mountains area of Montana
and Wyoming. According to Alexandrov (AJieRca-H
m>OB, 1922), the Tyuya-Muyun deposits have been
known for several centuries and were worked sporadically by the Chinese for the copper minerals that they
also contain. The deposits in the Pryor and Bighorn
Mountains were discovered in 1955.
containing uranium, vanadium, and copper minerals,

and at least 30 pure barite veins are known in the
locality. No report that describes completely the
possible origin and emplacement of the uraniferous
ores has been available to the author. No direct association between the uraniferous barite veins and the
fillings of the karst cavities has been demonstrated.
Pavlenko (llaBJieHRo, 1933) has proposed the following general sequence of mineral deposition within
the cavities: (1) a thermal ore process which was
dependent upon solidification of diabase rocks and
during which calcite and then calcite and ore minerals
were deposited, ( 2) a thermal barite process during
which barite was deposited, (3) a typical first "karst"
process during which banded crusts were deposited, and
( 4) a second "karst" process during which previously
deposited barite was reworked and quartz and then
aluminous sediments were deposited. Pavlenko's conclusions and the presence of many barite veins containing metallic constituents suggest that the uranium may
be of hydrothermal origin. No published reports
available to the author stated that primary uranium
minerals, such as uraninite, have been found in the
locality. Unsubstantiated reports indicate that uraninita has been found in deep mines of the locality.
TYUYAMUYUN, FERGANA DISTRICT, UZBEK S.S.R.
BIGHORN-PRYOR MOUNTAINS, WYOMING AND MONTANA
The ore deposits for which the Tyuya-Muyun

locality is especially noted consist mainly of incrustations of calcite, barite, and several secondary uranium,
vanadium, and copper minerals that partly or wholly
fill a series of caves, solution channels, and fractures
in metamorphosed limestones of Paleozoic age. The
deposits are in the northern foothills of the Alai Range,
and according to Pavlenko ( llaBJieHRO, 1933) they are
close to an area where a series of younger volcanic rocks
have been erupted upon a sedimentary terrain. The
-ores have been mined to depths exceeding 175 meters.
The incrustations locally reach a thickness of 1.5 meters
and consist of successive layers that vary in number,
thickness, and to some extent in order of deposition
from one cavity to another; the general sequence of
mineral layers, in order of deposition as stated by
Betekhtin (BeTexTHH, 1946) , is as follows : ( 1) calcite interspersed with thin argillaceous-carbonaceous
bands, (2) coarse-grained calcite with tyuyamunite,
turanite (5 CuO .v, 0 5 2H20), and other minerals, (3)
barite, both red and honey yellow and red quartz, ( 4)
barite breccia cemented with younger barite and carbonate minerals, and ( 5) dense calcite and earthy red
clays.
The Tyuya-Muyan deposit, as described by Fersman
(<DepcMaH, 1928), is in the midst of a vein field. According to Shimkin ( 1949), at least 5 barite veins
A karst terrain that was formed in the upper part of

the Madison Limestone of Mississippian age during
Late Mississippian or Early Pennsylvanian time is now
exposed on the westward-facing slopes of the Pryor
Mountains of south-central Montana and the northern
part of the Bighorn Range of north-central Wyoming.
Some of the caves and solution channels formed during
the main karst-forming stage subsequently have become partly or wholly filled with an assortment of
debris, and some of this debris is mineralized with
tyuyamunite.
The materials within individual caves and solution
channels may include blocks of limestone that have
fallen from the backs and walls, chert nodules and
other insoluble residue from the limestone, clay, silt,
and sand washed in from the surface of the ground or
from rocks that formerly overlay the Madison, and in
some caves large quantities of siliceous sinter. Some
of the fine-grained sediments are stratified and indurated and form masses of siltstone or sandstone.
The rubble in some of the caves is unconsolidated, and
in other caves it is cemented by siliceous sinter or by
secondary calcite.
The uranium deposits are restricted to the rubble,
sinter, and sediments within the caves and to scaly
crusts on the walls of caves, solution channels, and
fractures. Tyuyamunite is the only uranium mineral
uranium; the two samples (I-A, No. 249720 and I-D,

No. 260463) analyzed during this investigation contained 0.0004 and 0.0003 percent uranium, respectively.
A few thin seams of dark-gray to black clays and shales
are interspersed among the limestone strata. A sample
of shale collected by G. B. Gott, U.S. Geological Survey,
contained 0.48 percent uranium oxide as U 3 0 8 Ura-
nium probably is being leached from the clays and
shales by ground waters and is being deposited in
carnotite where these waters evaporate from rock
surfaces.
URANIUM DEPOSITS IN KARST TERRAINS
A12
that has been identified from these deposits. Tyuyamunite occurs in powdery form dispersed in silt and
siliceous sinter, as powdery films on secondary calcite,
as scaly crusts on walls of cavities and caverns, and as
films and scaly crusts on limestone rubble and chert
nodules. Some caves in the area have not been mineralized. The controlling factors of the mineralization
process have not been determined. The deposits range
from insignificant accumulations of tyuyamunite within
a single small opening to those occupying series of connected caves, channels, and fractures extending over
distances of several hundred feet horizontally and to a
known depth of 175 feet. The quantity of uranium in
the mineralized material ranges from mere traces to
several percent and tends to be erratically distributed.
The uranium was introduced into the cave fillings
from some source outside of the limestone. Although
cave walls may be coated with highly uraniferous incrustations, limestone an inch or so back from the incrustations generally is nonuraniferous except along
surfaces of connected fractures and solution cavities.
This observation was checked by uranium determinations on two samples of limestone broken from the walls
of heavily mineralized caves, one at Big Pryor Mountain in Montana and the other at the Little Mountain
locality near the north end of the Bighorn Mountains
in Wyoming. The two samples (I-A, Nos. 260492 and
260493) contained less than 0.0001 percent uranium.
The source of the uranium has not been determined.
The two most likely methods of emplacement seem to
be: (1) the deposits are supergene enrichments of
uranium leached from formations that are younger than
the Madison Limestone and which formerly covered
the area, and (2) the tyuyamunite is the oxidized
residue of hydrothermal deposits.
The principal point in favor of the supergene enrichment hypothesis is the presence, in the Mesozoic and
Tertiary rocks of the region, of several formations containing an abundance of arkosic and tuffaceous material. The most uraniferous of these sediments are in
the Tertiary section. An obstacle to strict supergene
enrichment is the presence of several more or less impervious mudstone, clay, and shale formations and
strata distributed throughout the sedimentary sequence.
Shale and clay beds in the Amsden Formation of Pennsylvanian age that directly overlies the Madison would
seem to prevent a normal type of supergene enrichment. It is possible that as the present Madison surface was exposed through erosion, surface and ground
waters carrying uranium leached from surrounding
terrain may have deposited it in the cave and solution
channels in the limestone.
Evidence supporting a possible hydrothermal origin
for the uranium likewise is meager. Very few features
that might be attributed to hydrothermal activity

were seen by the author while examining several dozen
prospects. Fluorite and barite are common, although
minor, constituents of the material filling fractures and
caves of the Big Pryor Mountain locality; these minerals were not observed in the limestone wallrock.
Several hundred pounds of massive pyrite within a
fracture zone was exposed in a prospect in the Little
Mountain locality. Secondary calcite, commonly in
the form of dog-tooth spar, occurs in many of the deposits and is very abundant in the Little Mountain locality. Siliceous sinter partly fills some caves and has
been deposited in large quantities along some fracture
zones in the Big Pryor Mountain locality ; it is either
a minor constituent or does not occur in deposits of the
Little Mountain locality. Most of the limestone in the
upper part of the Madison is very pure, and the effects
of hydrothermal solutions upon it would be mainly
solution and redeposition of calcite. No sulfide minerals or oxidation products of sulfide minerals except
pyrite, limonite, and possibly other iron oxides have
been observed.
The problem of the genesis of uranium ores in karst
terrains of the Madison Limestone probably cannot be
solved until exploration has progressed to depths below
the zone of oxidation. Disappearance of the uranium
mineral with increasing depth will be a point in favor
of supergene enrichment. The presence of primary
uranium and sulfide minerals at deeper levels will favor
the hydrothermal hypothesis. The physical characteristics of some of these ores, especially those occurring
in silt-filled caves, are, in general, similar to many sandstone uranium ores from the Colorado Plateau region.
The bulk of the tyuyamunite in all the deposits is within
siliceous cave and fracture fillings, and the mineralized
zones tend to end abruptly on or very close to the limestone walls. Uraniferous solutions prdbably entered
the channels and caves where a slight reaction with the
carbonate wallrocks changed the pH enough to cause
precipitation of a uranium mineral.
PENECONCORDANT URANIUM DEPOSITS IN
CARBONATE ROCKS
The largest and richest uranium deposits in carbonate

rocks within the United States are of the type called
peneconcordant by Finch (1959). These deposits are
"tabular, lenticular, or irregularly shaped masses of
widely differing size that are, in general, concordant to
the gross sedimentary structures of the enclosing rock
burt th'3Jt, in detail, cut across sedimentary structures.
This local discordance is a diagnostic characteristic
indicating that the deposits are epigenetic rather than
syngenetic." The uranium deposits in limestone beds
of the Todilto Limestone of Late Jurassic age in north-
western New Mexico definitely can be placed in this

category. Some small uranium deposits in limestone
lenses at the base of the Sundance Formation of Late
Jurassic age in Wyoming have similar characteristics.
All these deposits in limestones have physical features
like those of most uranium deposits in sandstones of
the Colorado Plateau region.
URANIUM DEPOSITS IN THE TODILTO LIMESTONE,
NEW MEXICO
A few large and several small uraniun1 deposits have

been discovered in limestone beds of the nonmarine
Todilto Limestone in the Grants district, Mcl{inley and
Valencia Counties, N. Mex. Other small deposits in
this formation have been discovered in the Laguna district, Valencia County; in the Sanostee area, Apache
and San Juan Counties; and in the Rio Cebolla and
Arroyo del Agua areas, Rio Arriba County. Only the
Grants district has produced a substantial amount of
ore.
The Todilto was deposited in a nearly elliptical basin
about 300 miles long in an east-west direction and 100
miles wide (Rapaport and others, 1952, p. 23). The
formation consists of two members. The lower Inember is a sequence of supposedly fresh- to brackish-water
beds of limy shale, silty limestone, and lilnestone that
reaches a maximum thickness of about 40 feet. The
upper member, of considerably smaller areal extent
.
.
'
consists mainly of gypsum and anhydrite that was deposited in the basin sink; it attains a thickness of at
least 95 feet in the northern part of the Lucero uplift
near Laguna (Rapaport and others, 1952, p. '23). The
Todilto rests upon the nonuraniferous Entrada
Sandstone.
The Summerville Formation, Bluff Sandstone 1\lor. Formation, all of Late Jurassic age, and
' the
r1son
Dakota Sandstone of Early ( ?) and Late Cretaceous
age overlie the Todilto in the order given in the Grants
di~trict.. The . Summerville and Dakota are weakly
m1nerahzed with uranium in a few places. Some of
the largest known uranium deposits in the United
States are in the Morrison Formation of the Ambrosia
Lake district a few miles northwest of the Grants district; a large ore body has been mined out of the Morrison Formation at Poison Canyon on the north edge
of the Grants district.
It is desirable to point out some features that characterize the limestone member of the Todilto and which
possibly influenced the deposition of uranium because
substantial uranium deposits are uncommon in limestones. The Grants district is described in some detail
because the largest known deposits are in this district
and because outcrops and mining operations have provided excellent exposures.
686494-63-3
A13
The limestone member of the Todilto in the Grants

district is a part of the southern rim of the San Juan
Basin and is on the north flank of the Zuni uplift.
The upper gypsiferous member is absent in this locality.
The limestone is underlain, apparently conformably, by
the Entrada Sandstone, and these formations are exposed on low southward-facing cliffs that form the
steep slope of a dissected cuesta about 15 miles long
and a half a mile to about 2 miles wide. The back
slope of the cuesta is a gentle dip slope formed on the
upper part of the Todilto; its surface is made somewhat
irregular by minor structural features and variable
thicknesses of residual soil and alluvium. The Todilto
passes under younger formations that are exposed on
southward-facing cliffs several hundred feet high and
which form the main part of the southern rim of the
San Juan Basin.
The limestone ranges in thickness from about 18 to
about 30 feet. Much of it is thinly bedded and tends
to split along bedding planes. Several thin units can
be recognized, but only three persist throughout most
of the district. These are a basal, or near basal, very
fine grained dense limestone; a middle unit of very
thinly bedded fine-grained crinkly lin1estone; and an
upper unit of coarse-grained recrystallized limestone,
which in most places is rather coarsely crinkled.
These three principal units are separated locally from
one another and fron1 the underlying Entrada Sandstone and the overlying Summerville Formation by lenticular, thinly laminated shaly and silty beds that range
fron1 a feather edge to about a foot in thickness other
lenticular shaly and silty beds are interspersed ~ithin
the 1nain lin1estone units. These partings vary in
thickness and number from place to place.
The Grants district probably lies along, or close to,
the strand line of the upper gypsiferous member of the
Todilto where thin layers of gypsum or anhydrite formerly were interspersed with limestone beds or where
a 1nixture of calcium sulfate and calcium carbonate
was deposited. Subsequently, anhydrite, where that
was the primary sulfate mineral, was hydrated to
gypsum, and the attendant swelling helped produce the
crinkly features of the upper unit of the limestone
member. The gypsum along the strand line eventually
was leached .from the rock. Results of the leaching
were formatiOn of a porous texture, completion of
crinkling of the thinly laminated limestone, and erratic
recrystallization of the calcite constituent.
The limestone is strongly fetid. It has a brownish
color except in places where it has been recrystallized,
and there the colors are usually white and light shades
of pink, yellow, and gray; locally the presence of hematite is the cause of a red color. It generally has been
A14
assumed that the odor and brown color are due priInarily to a small amount of petroliferous substance.
Attempts to extract organic matter from several
samples of limestone collected in the Grants district
have been unsuccessful. Several kinds of organic solvents were used in the experiments. It is concluded
that this rock is not now petroliferous, and that it probably never has been petroliferous. The limy sediments
undoubtedly contained significant amounts of organic
matter as they were being deposited, and the traces
that remain give the rock its brown color. The exact
nature of the organic matter cannot be stated. The
only fossils that have been recognized in the Todilto
are remains of ostracodes (Swain, 1946), and the author has found remains of small fishes. The scarcity
of readily recognizable fossil forms suggests that most
of the organic matter likely was derived from minute
organisms of which plankton might have been the principal members. The organic matter, brown color, and
fetid odor have been eliminated from some of the
thoroughly recrystallized rock.
The sediments that formed the limestone member of
the Todilto were composed principally of chemically
precipitated carbonates, 1ninor amounts of clay- and
silt-size detritus, and traces of organic matter. The
analyses reported in table 2 (II-C, Nos. 260469-260477)
show that the rock is a normal high-calcium limestone
containing approximately 1 percent of magnesium carbonate. It contains less than 0.01 percent P 20 5 and
variable a1nounts of acid-soluble R20s ranging from
about 0.8 to about 3.8 percent. Most of the limestone
contains less than 10 percent of clastic sediments, but
some lenses are marlstone and calcareous siltstone, and
some thin stringers are composed almost wholly of detrital quartz and feldspars.
The limestone is mostly very thinly stratified and
consists of alternating layers of dense finely crystalline
calcite and calcite mixed with silt. The silty layers generally are thinner than the dense calcite layers, but they
evidently have been quite permeable because epigenetic
minerals locally have been deposited in them and have
given the rock a banded appearance.
The calcareous sediments consisted of very fine
grained material that was deposited in an aqueous environment, and they probably were subjected to considerable compaction before lithification occurred.
Layers of dense material inhibited vertical movement
of water and solutions; hence, the main flow was laterally along bedding planes and through relatively
more permeable silty lenses. This condition has had
a readily noticeable effect on the deposition of epigenetic minerals. Secondarily induced permeability in the
limestone resulting from leaching of calcium sulfate
minerals and development of vertical fractures has
been an important factor in redistribution of secondary

uranium minerals.
Four types of deformation have affected the Todilto
Limestone in the Grants district. The first is tectonic
folding that has produced broad, slightly undulating
structures in all the formations of the area ; these folds
are a mile or more wide and have closures of only a
few tens of feet and axes that trend approximately
northward. The second type of deformation is smallscale folding that is almost wholly confined within the
limestone beds and has affected adjacent formations in
only a few scattered places; these folds probably were
caused by hydration of calcium sulfate and su~sequent
leaching of this material. These folds range from a
few inches to some 30 or 40 feet in width, but most are
less than 10 feet in width; they range from a few feet
to a few hundred feet in length and have closures of
a few inches up to 5 or 6 feet; the numbers of these folds
vary greatly from place to place, the limestone in some
localities being almost devoid of them and in other
localities being tightly crumpled by closely spaced series of such folds. The third type of deformation consists of northward- and northeastward-trending fault
zones that cross the district; there is but little vertical
displacement along these faults; the amount of horizontal displacement has not been determined. Finally,
the entire section was tilted as the present regional
structures of the San Juan Basin and Zuni uplift
formed.
An interesting feature of the Grants district is the
recrystallized character of much of the uppermost few
feet of the limestone. The results of this alteration
vary considerably from place to place. The limestone,
where altered, generally has been more or less recrystallized to depths of about 5 feet below its upper surface, but locally it is recrystallized to depths of as much
as 10 to 12 feet below the upper surface. The rock in
the latter places is coarsely crystalline, vuggy, and is
streaked with hematite stain. The cause of this recrystallization has not been determined. It may have been
caused by warm water, of undetermined origin, moving
through porous strata and along fractures. Recrystallized limestone has considerably greater areal distribution than rock enriched with uranium minerals
and fluorite.
Ore bodies mined or discovered in the Grants district
up to 1960 tend to be clustered along zones of major
faults. These fractures are unmineralized except for
minor amounts of secondarily redistributed uranium
minerals. The primary uranium mineralization occurred mainly in the small anticlinal structures within
the limestone adjacent to fault zones; this feature suggests a structural control. What role, if any, was
played by the major fractures is not clear. The masses
of primary or "black" ore, of which uraninite is the

important constituent, are mostly small and range from
insignificant pods to bodies about 30 feet wide, 200 x 300
feet long, and about 3 feet thick. At some places two
or more bodies of primary ore, in adjacent small anticlines, can be mined from the same pit, particularly if
the intervening rock has been heavily mineralized with
secondary uranium minerals. The uraninite in some
ore bodies has been altered almost completely to secondary uranium minerals. Secondary minerals are
likely to be redistributed along fracture surfaces, in
vugs, and in solution cavities for substantial distances
from sites of the primary deposition. The redistributed yellow secondary minerals are especially conspicuous in the upper, crinkly layers of the limestone. Ore
bodies of predominantly secondary uranium minerals
tend to be irregulary rounded rather than elongate.
Several epigenetic minerals, and some that possibly
are authigenic, occur in the mineralized parts of the
limestone. There are two categories of these minerals,
those that are primary, and those that are alteration
products of the primary minerals. In the primary category are pyrite, fluorite, uraninite, barite, some calcite,
and probably hematite. It seems unlikely that all these
minerals were deposited during the same phase of mineralization. The alteration products of the primary
epigenetic minerals include carnotite, tyuyamunite,
uranophane, and limonite. Redistributed calcite is
abundant. Small, probably authigenetic manganesebearing nodules, possibly composed predominantly of
psilomelane ( ~), are widely, though not abundantly,
distributed in the limestone. These nodular masses
rarely exceed an eighth of an inch in diameter. There
is no evidence to indicate that any of these minerals
are mainly syngenetic except for some fine-grained
pyrite in parts of the limestone that are otherwise unmineralized. None of the minerals listed above is confined to any particular stratum, and none is even
approximately uniformly distributed within a particular stratum. The bulk of the primary minerals are
concentrated in zones of former bedding-plane porosity
and generally are further controlled by the small anti clinal structures; the banded appearance of rock so
mineralized commonly does not extend more than a few
feet from the flanks of the folds. The secondary minerals, particularly those of uranium, in most places
have been redistributed beyond the limits of the primary deposits and are concentrated mainly in fractures.
The primary uranium mineral, uraninite, is preserved
mainly in the fine-grained dense limestone of the lower
units. Ore in lots of a few tons containing several
percent uranium can be handpicked from places where
uraninite is especially abundant. The limestone generally has been recrystallized to the point where stratifi-
A15
cation features are obscure or eliminated; the uraninite

occurs as small grains, irregular masses, and small
stringers that show some indication of following the
former stratification but also in many places cut across
it; lenticular masses of nearly pure uraninite about half
an inch thick and a few inches long that obviously _replace the limestone are found in this rich ore. Small
grains and nodular masses of uraninite definitely follow
bedding planes and give the rock a somewhat discontinuous banded appearance around the flanks of rich
ore bodies and in places where there has been relatively
little primary uranium mineralization as well as little
or no recrystallization of the limestone. This feature
indicates that bedding plane permeability exerted considerable control over localization of uraniferous solutions. No direct association between uraninite and
organic matter has been observed.
Fluorite is rather widespread in the Grants district
and locally attains concentrations ranging from a trace
to possibly 5 percent. It occurs as minute grains and
as aggregates of microscopic grains. Some of the
fluorite is purple, some is colorless, and some of the
aggregates consist of mixtures of purple and colorless
grains. Although some of the fluorite is uraniferous, it
does not seem to be associated directly with uraninite.
Some aggregates of fluorite grains have cores of uranophane, a peculiar feruture that cannot now be explained.
Fluorite-rich parts of the limestone are not characteristically mineralized with uraninite, in fact, some fluorite-rich rock seems to be devoid of uraninite. Some
of the richest concentrations of fluorite occur in the
small anticlinal structures, particularly those adjacent
to major fractures. In those parts of the limestone that
are not extensively recrystallized, fluorite, like uraninite, follows the stratification, and some of the rock is
conspicuously banded. No conclusive evidence has been
found indicating that fluorite and uraninite belong to
the same period of mineralization. It is possible that
the two minerals were deposited at different times from
unrelated solutions.
Hematite, or some other reddish iron oxide, is a conspicuous constituent of some of the mineralized limestone. Most of this mineral is extremely fine grained
and tends to color the rock a dull red. It probably does
not amount, at the most, to more than 1 percent of the
rock. Hematite also has a tendency to follow bedding
planes and is more likely to accompany uraninite than
is fluorite, but hematite and fluorite are not always
found together in mineralized zones devoid of uraninite.
Known uranium deposits in the Todilto Limestone
outside of the Grants district are small and are distributed along the margins of the San Juan Basin or
at points within the basin sink where the upper gyp-
A16
siferous member is missing. Only secondary uranimn

minerals have been found in these deposits.
Although the source of the uranium in the Todilto
Limestone has been a subject of much speculation by
many geologists, no completely satisfactory answer has
been found. The author believes that the uranium in
the limestone was derived from the same source as that
which furnished the uranium in the overlying sandstone
formations and that it was deposited at the same time.
When the origin of uranium deposits in sandstones is
determined, it is expected that the deposits in the
Todilto Limestone also will be explained.
Limestones generally are not favorable host rocks
for uranium deposits; therefore, some unusual conditions had to exist to cause deposition of uraninite in the
Todilto. This limestone probably contains no significant amount of syngenetic uranium. The validity of
this statement cannot be established completely on the
basis of analyses of samples collected in the Grants
district. All the rock seems to contain redistributed
uranium in the form of secondary minerals. All the
samples collected by the author contained visible traces
of yellow minerals even though considerable effort was
expended to obtain rock free from such constituents.
Even so, it should be noted that samples 260469 and
260471 contained only 0.0005 and 0.0006 percent uranium, respectively (table 1, II-C). The analyses of
nine samples also show that the Todilto is almost nonphosphatic, the maximum quantity of P 2 0 5 being only
0.08 percent. It already has been pointed out in the
discussion of syngenetic uranium in carbonate rocks
that only those carbonate rocks that have a few tenths
of 1 percent or more of P 2 0 5 are likely to contain syngenetic uranium in quantities exceeding about 0.0004
percent. It is concluded that the possibility that a
minor amount of syngenetic uranium in the Todilto
could have been concentrated and redeposited is nil.
The uraninite, as well as fluorite, hematite, and some
other less abundant minerals, are distributed in the
limestone in a manner indicative of epigenetic
deposition.
The ore-forming solutions responsible for deposition
of uranium in the sandstone units overlying the Todilto
fluids, structural features for entrapment of the fluids,
and chemical environments causing precipitation of ore
minerals. Within the Todilto, structural features are
readily visible, and the availability of ore-forming
fluids can be easily explained, but the precise nature
of the chemical environment in which the uranium
was precipitated cannot be fully explained.
The ore-forming solutions responsible for deposition
of uranium in the sandstone units overlying the Todilto
Limestone in the area also must have deposited the
uranium in the Todilto; no evidence has been uncovered
to the contrary, and there is no evidence of more than

one period of primary uranium mineralization in the
area. It is reasonable to assume that uraniferous solutions migrated through several permeable strata of the
local section and that, wherever structural and chemical conditions were favorable uranium was deposited.
Structural features in the Todilto that trapped oreforming fluids were mainly the small folds that are
confined to the limestone itself. Generally the overlying Summerville Formation, composed mostly of
shales and mudstones, had formed an impervious ca.p
over the limestone. Ore-forming solutions may have
flowed along fractures in the limestone to some extent,
but the major movement was controlled by stratification
features and was along thin permeable beds that average only a small fraction of an inch in thickness. This
circumstance is indicated by the predominant deposition of uraninite, fluorite, and hematite along bedding
planes. Bedding-plane permeability seems to have been
an inherent feature of the lower units of the Todilto
in the Grants district.
The geochemical environment that existed as the
uraninite was deposited is not fully understood. The
pH of the mineralizing solutions must have been nearly
neutral or slightly alkaline. Large masses of the liinestone have been almost completely recrystallized, but
are not characteristically mineralized with uraninite.
Those parts of the limestone that contain the uraninite
show relatively little recrystallization and only minor
extraction of the carbonate constituent; this condition
would not exist if the mineralizing solutions had been
acid. Even moderately acid mineralizing solutions
would have dissolved substantial amounts of the limestone; conversely, strongly alkaline solutions, or solutions nearly saturated with carbonate ions, probably
would not have permitted replacement of calcite
by uraninite. It is concluded that recrystallization of
the limestone was not an essential feature of the mineralizing process and that the fact that uraninite occurs
in some of the least recrystallized parts of the limestone is indicative of nearly neutral or moderately alkaline solutions.
The environment was undoubtedly reducing and sul-furous as uraninite was being deposited. The uranium
ores of the Ambrosia Lake district are characterized
by an abundance of very fine grained iron sulfides that
are dispersed throughout the mineralized parts of the
rock. Iron sulfides also are present in ores of the
Todilto Limestone, althought not so abundantly. The
limestone itself is a fetid rock.
The state of the uranium as it was introduced into
the limestone is a subject that can only be speculated
upon. Some, and possibly all, of the uranium may
have existed in the uranyl form, most likely as a uranyl
URANIT~ ~
CARBONATE ROCKS
carbonate complex. The sulfide ion readily reduces the

uranyl ion under some conditions, and it probably was
the reducing agent in the Todilto Limestone.
Phase relations that exist with varying temperatures
and pressures in complex solutions containing uranyl,
uranous, sulfide, and carbonate ions, and which may
be in contact with solid phases of uranium oxides, are
virtually unknown. The presence of uraninite in the
Todilto Limestone seems to indicate that reduction of
uranyl uranium by sulfide ions may occur in a carbonate environment, but the concentrations of reacting
constituents, and the Eh and pH of the solutions, cannot be stated from present knowledge. The only alternative is that uranium might be transported in the
uranous state and be deposited by some process that
cannot be explained on the basis of present knowledge.
URANIUM
DEPOSITS IN THE SUNDANCE

WYOMING
FORMATION,
Some small, low-grade uranium deposits are found

in lenticular limestone beds at the base of the Sundance
Formation in Wyoming. These deposits have some
features similar to those of deposits in the Todilto
Limestone and therefore are classed as peneconcordant.
The largest known deposits in the Sundance Formation are in sec. 3, T. 44 N., R. 83 W., in Johnson
County. This locality is on the east flank of the Bighorn Mountains and 3!bout 2 miles southwest of the
abandoned Mayoworth post office. The formations exposed in the vicinity of the uranium deposits are the
Chugwater, Sundance, and Morrison. The upper part
of the Chugwater, of Triassic and Permian age, consists
of a thick section of massive to crossbedded fine-grained
red sandstone. The Sundance Formation, of Jurassic
age, consists of a hasal lenticular limestone having a
maximum thickness of about 20 feet that is overlain
by beds of nonglauconitic sandstone and shale approximately 200 feet thick and an upper sequence of glauconitic shale and sandstone about 150 feet thick; all
these units contain marine fossils. The Morrison
Formation, of Jurassic age, consists of shale and sandstone. The only uraniferous material that has been
found in these formations in this locality, other than
the deposits in the limestone, is fossil dinosaur bone in
the Morrison Formation (Love, 1954, p. 3) .
The formations at the Mayoworth locality strike approximately N. 30 W. and dip 12 to 15 NE. The
largest exposure of the limestone at the base of the Sundance Formation is within an area of several acres on a
northeastward-facing dip slope in the SW% sec. 3.
This limestone bed feathers out within distances of
about a mile to the northwest and southeast.
The limestone consists predominantly of calcitic
oolites cemented with calcite. It is mostly dull grayish
A17
brown, hut in places it is reddish because of local abundance of iron oxides. The freshly broken rock is
strongly fetid. The limestone contains no recognizable
organic matter, and organic solvents extract no material from it. Chemically the rock is a calcitic
nonphosphatic limestone (table 2, II-B, No. 249721).
Metatyuyamunite is irregularly distributed within
the limestone, some forming coatings on fracture surfaces and some replacing, or partly replacing, oolites
and calcite cement. These two modes of deposition do
not everywhere occur together; consequently, the most
richly mineralized parts of the limestone are small
pockets where the two occur together. The uranium
content of the rock generally is substantially less than
0.1 percent except for a few small pockets. A petrographic description of the rock has been presented by
Guilinger and Theobald (1957).
Inasmuch as most of the metatyuyamunite on fracture surfaces obviously is redistributed, it seems that
the primary uranium deposition involved replacement
of the oolites and calcite cement. Whether metatyuyamunite is the primary uranium mineral or an alteration product of some previously existing mineral is
unknown. No structural control of deposition has 'been
observed, perhaps because observations have been restricted to the upper surface of the limestone and to a
few prospect pits not exceeding 5 feet in depth.
The source of the uranium in the limestone is a subject for speculation. The author has observed no features that indicate syngenetic deposition of the uranium.
The limestone can be considered to be nonphosphatic
(table 2, II-B, No. 249721 contained less than 0.05
percent P 2 0 5 ) and is a type not likely to contain aboveaverage quantities of syngenetic uranium. The uranium probably was carried into an originally porous
limestone by ground-water solutions and was precipitated in the reducing environment of the fetid rock.
There is no apparent source of uraniferous solutions in
the immediate vicinity. No other appreciable concentrations of uranium minerals are known to exist for
considerable distances around the Mayoworth locality.
There are no intrusive igneous rocks or hot-spring deposits nearby that could point to possible hydrothermal
solutions. The uranium may have been leached from
other rocks of the region and concentrated in the limestone. Love (1954) has suggested that it might have
been leached from volcanic ash in the White River
Formation of Oligocene age, which was deposited unconformably upon the upturned edges of the Jurassic
formaJtions but which subsequently was eroded from the
area.
The uranium probably was deposited epigenetically
in the limestone. If uraniferous solutions entered the
limestone and a reducing environment was encountered,
A18
it is reasonable to assume that the primary mineral was

uraninite; because the known deposits are within 5
feet of the surface of the ground where oxidation is
complete, no trace of uraninite has been found.
criterion is the presence, or former presence, of tuffaceous or arkosic sediments that could have furnished
uranium for supergene enrichment. The only known
peneconcordant deposits are in fetid limestones.
SUMMARY
LITERATURE CITED
Uranium deposits can be formed epigenetically in

carbonate rocks by several mechanisms. Some of these
mechanisms produce deposits that furnish interesting
mineralogical specimens but generally do not provide
ores; most of the effiorescent deposits belong in this
category. Other mechanisms have produced a few deposits that have been mined profitably primarily for
their uranium contents alone; examples of these deposits are the hydrothermal veins at Shinkolobwe, Republic of Congo, the peneconcordant deposits in the
Todilto Limestone in New Mexico, and deposits in the
karst terrains of the Pryor Mountains in Montana and
the Bighorn Range in Wyoming.
Carbonate rocks are less favorable host rocks for
epigenetic uranium deposits than are clastic sedimentary rocks, metamorphosed clastic sedimentary rocks,
and igneous rocks. Carbonate rocks that contain significant epigenetic uranium deposits are in the so-called
uranium provinces of the earth, and even in these
regions the deposits generally seem to be restricted to a
single carbonate rock formation.
The exact physical and chemical conditions that
cause primary deposition of uranium in carbonate rocks
are virtually unknown. U raninite seems to be the only
primary uranium mineral deposited in the hydrothermal veins. TyuJ.amunite, uranophane, uraniferous
fluorite, and possibly other minerals may be deposited
as primary constituents in some of the other types of
deposits, but this point has not been established
definitely. It cannot be stated that the same chemical
conditions existed during mineralization of deposits
having different physical characteristics. The fact
that uraninite can be deposited in carbonate rocks, and
apparently from solutions rich in carbonate, or bicarbonate, or carbonate and bicarbonate ions, seems to be
puzzling, but this circumstance merely points out a gap
in our knowledge of the chemical behavior of uranium.
Only a few favorability criteria can be suggested that
might aid in the discovery of epigenetic uranium deposits in carbonate rocks. The known significant deposits are in uranium provinces, and this circumstance
would seem to define favorable regions. Uraniferous
hydrothermal veins in carbonate rocks are most likely
to be found in districts where similar veins occur in
other types of rocks. Uranium deposits in karst terrains are most likely to exist where there has been
deep-seated hydrothermal activity; a less favorwble
Alcock, F. J., 1936, Geology of the Lake Athabaska region,

Saskatchewan: Canada Geol. Survey Mem. 196, 41 p.
Alexandrov, S., 1922, Tyuya Muyun Radium expedition of
1922: Mining Journal [Moscow] no. 10-12, p. 415-416.
(AJieRCaH;o;poB, C., 1922, TroH-MyroHcRaH pa;o;HeBaJI :mcne;IJ;HIJ;HH 1922. r.: I'opHI:.I:H: jKypHaJI, I'o;o; 98, BLinycR 10-12,
CTp. 415-416.)
Altschuler, Z. S., Clarke, R. S., Jr., and Young, E. S., 1958,
The geochemistry of uranium in apatite and phosphorite:
U.S. Geol. Survey Prof. Paper 314-D, p. 45-90.
Arapov, Yu. A., 1936, Mineralogy and geochemistry of the Kansai
ore deposit, in Tadjik-Pamir expedition of 1934, Reports
of the expedition, No. 49: Acad. Sci. (U.S.S.R.), 104 p.
(AparroB, IO. A., 1936, MHHepaJiorHJI H reOXHMHH RaHca:H:Koro MecTopom;o;eHHH: Ta;o;mHRCRo-IIaMHpcRaH 9Rcne;IJ;HD;HH 1934 r., Tpy;o;LI 9Rcrre;o;Hn;HH, BLirrycR 49, ARa;o;eMHH
HayR C.C.C.P.)
Association of Official Agricultural Chemists, 1950, Official
methods of analysis, 7th ed., 910 p.
Bain, G. W., 1950, Geology of the fissionable materials: Econ.
Geology, v. 45, p. 273-323.
Baronov, D. I., Ronov, A. B., and Kunashova, K. G., 1956,
On the geochemistry of dispersed thorium and uranium in
clays and carbonate rocks of the Russian Platform: Geochemistry [Moscow] 1956, no. 3, p. 3-8. (BapoHOB, B. n.,
PoHoB, A. B., H RyHamoBa, R. I'., 1956, R reoXHMHH
pacceRHHOrO TOpHH H ypaHa B rJIHHaX H Rap60HaTHhlX
nopo;o;ax pyccRo:H: nJiaTcilopMLI: I'eoxHMHH 1956, BLinyCR
3, CTp. 3-8.)
Bell, K. G., 1956, Uranium in precipitates and evaporites, in
United Nations, Geology of uranium and thorium: Internat.
Conf. on the Peaceful Uses of Atomic Energy Proc., Geneva
1955, v. 6, p. 520-524.
---1960a, Deposition of uranium in salt-pan basins: U.S.
Geol. Survey Prof. Paper 354-G, p. 161-169.
---1960b, Uranium in petroleum and rock asphalt: U.S.
Geol. Survey Prof. Paper 356-B, p. 45-65.
Betekhtin, A. G., 1946, Deposits of radioactive metals; Uranium
and radium, in Tatarinova, P. M., and Betekhtin, A. G.,
eds., Course in useful mineral deposits: Moscow-Leningrad,
p. 233-238. (BeTeXTHH, A. I'., 1946, MecTopom;o;eHHH
pa;o;HoaRTHBHLIX MeTaJioB; YpaH n pa;o;H:H:: B Rypc MecTopom;o;eHHii noJieBHDIX HCROnaeMLix; IIo;o; pe;o;aRn;ne:H: II. M.
TaTapHHoBa H A. I'. BeTeXTHHa, CTp. 233-238.)
Bowie, S. H. U., 1955, Thucholite and hisingerite-pitchblende
complexes from Nicholson mine, Saskatchewan, Canada:
Great Britain Geol. Survey Bull. 10, p. 45-55.
Christie, A. M., and Kesten, S. N., 1949, Goldfields and Martin
Lake map areas, Saskatchewan (Preliminary account) :
Canada Geol. Survey Paper 49-17.
Cuttitta, Frank, 1952, The colorimetric determination of total
iron with o-phenanthroline: A spectrophotometric study:
U.S. Geol. Survey TEI-223, issued by U.S. Atomic Energy
Comm. Tech. Inf. Service, Oak Ridge, Tenn., 25 p.
Davidson, C. F., and Atkin, D., 1953, On the occurrence of
uranium in phosphate rock: Internat. Geol. Cong., 19th,
Algiers 1952, Comptes rendus, sec. 11, p. 13-31.
Derriks, J. J., and Vaes, J. F., 1956, The Shinkolobwe uranium

deposit: Current status of our geological and metallogenic
knowledge, in United Nations, Geology of uranium and
thorium: Internat. Conf. on the Peaceful Uses of Atomic
Energy Proc., Geneva 1955, v. 6, p. 94-128.
Eargle, D. H., 1956, Some uranium occurrences in West Texas:
Texas Univ., Bur. Econ. Geology, Rept. Inv. 27, 23 p.
Evans, R. D., and Goodman, Clark, 1941, Radioactivity of
rocks: Geol. Soc. America Bull., v. 52, p. 459-490.
Fersman, A. E., 1928, The uranium-vanadium mine in Turkestan,
in All Union Geol. Cong., 3d, Tashkent 1928, Guidebook of
the excursions: no. 1, Paper 22, Geol. Comm. Publication,
Leningrad. (<DepcMaH, A. E., 1928, 'YpaHo BaHap;n:eBI:.Iit
pyp;HHR TroH-MyroH B TypReCTaHe: BcecoiOSHhlfi reoJiorn:qeCimit C:&eap;, m TamReHT 1928, IlyTeBO)l;HMeJIL
eRCRypcn:it: BI:.IrrycR 1, No. 22, llap;aHHe reoJiorn:qecRoro
RoMn:TeTa, JleHn:Hrpap;, 1928.)
Finch, W. 1., 1959, Peneconcordant uranium deposit-a proposed term: Econ. Geology, v. 54, p. 944-946.
Fresenius, R., and Hintz, E., 1895, Bestimmung des Urans in
Phosphorsaure und Arsensaure enthaltenden Erzen:
Zeitschr. Anal. Chemie, v. 34, p. 437-439.
Gorbunov, N. P., 1935, Tadjik-Pamir Expedition of 1934, in
Tadjik-Pamir Expedition of 1934: Acad. Sci. (U.S.S.R.),
p. 5-36. (rop6yHoB, H. II., 1935, Tap;mn:cRcRo IlaMn:pcRaH
aRcrrep;n:~n:H 1934 r. : B Tap;mn:RCRO IlaMn:pcRa.JI e~tcrrep;n:~n:H
1934 r., CTp. 5-36, ARap;eMn:H HayR C.C.C.P.)
Gotman, Ya. D., 1937, Petrography and mineralogy of the
Agalyk uranium and vanadium deposit (Middle Asia):
Acad. Sci. (U.S.S.R.) Bull., Geol. Ser. 1937, p. 291-311.
(roTMaH, JI. ,I(., 1937, IleTporpaqmH n MHHepaJiorn:H
AraJII:.IRCRoro ypaHo-BaHap;n:eBoro MecTopomp;eHHH (CpeAHHH Aan:H): llaBeCTHSI A~tap;eMn:H HayR C.C.C.P., 1937,
CepnH reoJiorn:qecRaH, CTp. 291-311.)
Gott, G. B., Wyant, D. G., and Beroni, E. P., 1952, Uranium in
black shales, lignites, and limestones in the United States,
in Selected papers on uranium deposits in the United States:
U.S. Geol. Survey Circ. 220, p. 31-35.
Grimaldi, F. S., May, 1., Fletcher, M. H., and Titcomb, J.,
compilers, 1954, Collected papers on methods of analysis
for uranium and thorium: U.S. Geol. Survey Bull. 1006,
184 p.
Guilinger, R. R., and Theobald, P. K., 1957, Uranium deposits in oolitic limestone near Mayoworth, Johnson
County, Wyoming: U.S. Geol. Survey BulL 1030-K, p.
335-342.
Hebert, Claude, 1947, Contribution a l'etude de la chimie des
phosphates de calcium: Annales des Mines Mem., v. 136,
no. 4, 93 p.
Icken, J. M., and Blank, B. M., 1953, Determination of fluorides.
Spectrophotometric adaption of method of Association of
Official Agricultural Chemists: Anal. Chemistry, v. 25, p.
1741-1742.
Isachsen, Y. W., Mitcham, T. W., and Wood, H. B., 1955, Age
and sedimentary environments of uranium host rocks,
Colorado Plateau: Econ. Geology, v. 50, p. 127-134.
Lahner, llse, 1939, Uran- und Thoriumbestimmungen an Kalken
und Dolomiten und die Frage des radioaktiven Gleichgewichtes in diesen Gesteinen: Akad. Wiss. Wien, Math.Naturwiss. Kl., Sitzungsber., sec. 2, v. 148, p. 149-162.
Love, J. D., 1953, Preliminary report on uranium deposits in the
Miller Hill area, Carbon County, Wyoming: U.S. Geol.
Survey Circ. 278, 10 p.
A19
Love, J. D., 1954, Uranium in the Mayoworth area, Johnson

County, Wyoming-A preliminary report: U.S. Geol. Survey
Circ. 358, 7 p.
Manskaya, S. M., Drozdova, T. V., and Emel'ianova, M. P.,
1956, Uranium binding by humic acids and melanoidines:
Geochemistry (Moscow), 1956, no. 4, p. 10-23. (MaHCRaH,
C. M., ,I(poap;oBa, T. B., H EMeJI:&HHOBa, M. II., 1956,
CBHSI:.IBaHn:e ypaHa ryMHHOBLIMH RHCJIOTaMH u MeJiaHonp;n:HaMn:: reoxn:MHH 1956, BI:.IrrycR 4, CTp. 10-23.)
Muilenburg, G. A., and Keller, W. D., 1950, Carnotite and
radioactive shale in Missouri: Am. Mineralogist, v. 35,
p. 323-324.
Pavlenko, D. M., 1933, New data on the geology and genesis of
the Tyuya-Muyun deposits in Uzbekistan: Problems of
Soviet Geology, v. 4, no. 10, p. 123-142. (IIaBJieHRo,
,I(. M., 1933, HoB:&Ie p;aHHI:.Ie o reoJiornn: n: reHeance MecTopomp;eHHH TroH MyroH B a6e~tn:cTaHe: Ilpo6JieMI:.I.
CoBeTcRoit reoJiorn:n:, ToM 4, BI:.IrrycR 10, CTp. 123-142.)
Rapaport, 1., Hadfield, J. P., and Olson, R. H., 1952, Jurassic
rocks of the Zuni uplift, New Mexico: U.S. Atomic Energy
Comm. RM0-642, issued by U.S. Atomic Energy Comm.
Tech. Inf. Service, Oak Ridge, Tenn., 47 p.
Robinson, S. C., 1955, Mineralogy of uranium deposits, Goldfields, Saskatchewan: Canada Geol. Survey Bull. 31, 128 p.
Rodden, C. J., and Warf, J. C., 1950, Uranium, in Rodden, C. J.,
ed., Analytical chemistry of the Manhattan Project: Nat.
Nuclear Energy Ser., div. 8, v. 1, p. 3-159, McGraw-Hill
Book Co., Inc., New York.
Shapiro, Leonard, and Brannock, W. W., 1956, Rapid analysis
of silicate rocks: U.S. Geol. Survey Bull. 1036-C, p. 19-56.
Shimkin, D. B., 1949, Uranium deposits in the U.S.S.R.: Science,
v. 109, p. 58-60.
Stephens, J. G., 1954, Uranium in limestone: Saratoga area,
Carbon County, Wyoming, in Geologic investigations of
radioactive deposits-Semiannual progress report, June 1
to Nov. 30, 1954: U.S. Geol. Survey TEI-490, p. 131-132,
issued by U.S. Atomic Energy Comm. Tech. Inf. Service,
Oak Ridge, Tenn.
Swain, Fredrick, 1946, Middle Mesozoic nonmarine ostracoda
from Brazil and New Mexico: Jour. Paleontology, v. 20,
p. 543-555.
Szalay, A., 1957, The role of humus in the geochemical enrichment of U in coal and other bioliths: Acta Phys. Acad. Sci.
Hungaricae, v. 8, pts. 1-2, p. 25-36.
Thoreau, J., and du Trieu de Terdonck, R., 1933, Le gite d'uranium de Shinkolobwe-Kasola (Katanga) : Memoires de
l'lnstitut Colonial Beige, v. 1, pt. 8.
---1936, Concentrations uraniferes du Katanga (Congo
Belge): Internat. Geol. Cong., 16th, Washington 1933,
v. 2, p. 1099-1101.
Thurston, W. R., Staatz, M. H., Cox, D. C., and others, 1954,
Fluorspar deposits of Utah: U.S. Geol. Survey Bull. 1005,
53 p.
Unkovskaya, V., 1940, Determination de faibles quantities
d'uranium par le procede de fluorescence: Acad. Sci.
(U.S.S.R.), Comptes rendus, v. 29, p. 380-383.
Vine, J. D., and Prichard, G. E., 1959, Geology and uranium
occurrences in the Miller Hill area, Carbon County,
Wyoming: U.S. Geol. Survey Bull. 1074-F, p. 201-238.
Vine, J. D., Swanson, V. E., and Bell, K. G., 1958, The role of
humic acids in the geochemistry of uranium, in United
Nations, Survey of raw material resources: Internat. Conf.
on Peaceful Uses of Atomic Energy Proc., Geneva 1958,
v. 2, p. 187-191.
A20
Vol'fson, F. I., 1940, The principal features of the metallogeny

in the West Tian-Shan: Acad. Sci (U.S.S.R.) Bull., Geol.
Ser., no. 3, p. 65-83. (BoJIL!f>coH, <D. H., 1940, OcHOBHLie
't!epTLI MeTaJIJioreHHH saHa;n;Horo THH-illaHH: HsBeCTHH
ARa;n;eMHH HayR C.C.C.P., CepHH reoJIOrH't!eCRaH, BLmycR
3, CTp. 65-83.)
Willard, H. H., and Winter, 0. B., 1933, Volumetric method for
determination of fluorine: Indus. and Eng. Chemistry, Anal.
Ed., v. 5, p. 7-10.
Zil'bermintz, V. A., 1935, The uranium-vanadium deposit near
Samarkand, in Tadjik-Pamir Expedition of 1934: Acad.
Sci. (U.S.S.R.), p. 197-205. (3HJIL6epMnHn;, B. A., 1935,
YpaHo-BaHa;n;HeBoe MecTopom;n;eHne 6JIH3 CaMapRaH;o;a:
B
Ta)l;mHRCRo-llaMnpcRaH ::mcrre;n;nn;nH 1934 r., CTp.
197-205, ARa)l;eMBH HayR C.C.C.P.)
Zil'bermintz, V. A., and Samoilo, M. V., 1935, Material on the

mineralogy of Karatyube Mountain (Zerayshan Range),
in Geology of the Zeravshan-Gissar system; Petrography
and Mineralogy: Acad. Sci. (U.S.S.R.), p. 217-242.
(3nJIL6epMHHn;, B. A., H CaMo:iiJio, M. B., 1935, MaTepnaJII>I
R MBHepaJiornu rop RapaTio6e (3epaBmaHCRHH Xpe6eT):
B R reOJIOrHB 3epaBmaHCRO rnccapCROH CHCTeMLI; lleTporpa!f>HH H MHHepaJiorHH: Ta;n;muRCRo-IlaMHpcRaH sRcrre;n;nn;nH 1933, Tpy;n;LI ::mcrre;n;Hn;Hu, BLirrycR 29, CTp. 217-242,
ARa)l;eMHH HayR, C.C.C.P.)
TABLE
2.-Analyses in percent of some carbonate rocks and source materials
[Analysts: R. P. Cox, E. J. Fennelly, D. L. Ferguson, W. D. Goss, Claude Huffman, H. H. Lipp, E. C. Mallory, Wayne Mountjoy, W. W. Niles, L. F. Rader, D. L. Schafer, J.P. Schuch, and D. L. Skinner]
Chemical composition
Laboratory
sample
Approximate mineral composition
Source
Age
Locality
.s
-<
.c
9:
&}~
l~
'Cj s
.c
Ql
l'<i
0
0
bl)
"'
"'"'
Ql
1'r;
&
.:g
p:;
l'<i
"'...,
~E
~~
-<
0
0:1
0
0
0
bl)
Remarks
r;;
s"'
0:1
I. ROCKS AND SOURCE MATERIALS CONTAINING ONLY SYNGENETIC URANIUM

A. Marine limestones-no significant metamorphism, nonfetid
2
. Burlington
Limestone.
Madison Limestone,
Early Mississip pian.
Road cut, U.S.

Highway 60,
east bank
James River,
Galloway,
Mo.
Mississippian. Open pit, Tripacer claims,
T. 58N., R.
94 W. Bighorn County,
Wyo.
. Washita Group_ Cretaceous ____ Top of Kings
:y~~~~~h~
0.1
55.4 <0.5
<.1
55.3
1.2
54.1
<.5
.6
0.15
0.030
0.02
-------
<0.0001
0.1
98.87 <1.05
0.05
-------
0.15
.13
.020
<.01
-------
<.0001
<.1
98.75 <1.05
<.02
-------
.13
-------
.0003
-------
.42
.42
.121
<.01
1.2
96.60
1.26
<.02
east of
McCamey,
Tex.
. Madison Limestone.
Salem Limestone.
. St. Louis Limestone,
Mississippian. Sec. 4, T. 9 S.,

R. 27 E., Carbon County,
Mont.
2.5
Late Mississip pian.
Upper bench
Busson's
~uarry, Ste.
enevieve,
Mo.
1. 75
Abandoned
quarry, N~
sec. 34, T. 3 S.,
R. 4 E., near
Corydon, Ind.
3.47
53.2 <1.0
1. 30
.82
.05
-------
sw~~
4.1
52.7
.8
1.4
.81
.12
0.005
,0001
Road cut, U.S.

Highway60,
5 miles west of
Frankfort,
Ky.
4.55
52.1
1.1
2.11
.88
.13
.021
<.0001
Late Mississip pian.
Sinbad LimeEarly Triassic.

stone Member
of Moenkopi
Formation.
. Maysville
Group,
Late Ordovician.
sec. 6, T.
21 S., R. 13 E.,
Grand Connty, Utah.
53.4
.6
53.2 <1.0
.02
.20
.020
.11
<.01
<.05
-------
-------
<.0001
.0004
<.0001
2.5
1. 75
95.36
1.26
95.00 <2.09
<.02
<.12
-------
-------
.02
.20
3.47
94.89 <2.09
.12
-------
1.30
4.1
93.84
1.67
.28
-------
1.4
4.55
92.71
2.30
.31
0.02
2.11
99.1+ Light-gray medium-grained limestone. Contains a few fossil

brachiopods and fragments of
crinoid stems. Composed of
calcite and traces of very fine
grained clay-size material.
98.9+ Buff fine-grained dense limestone.
Contains poorly preserved microfossils. Composed of minute
calcite grains (about 35 percent)
in a matrix of extremely fine
grained calcite. Calcite is the
only mineral that can be identified under the microscope
99.5
Buff fine-grained dense limestone,
Contains some small macrofossils and many microfossils.
Composed of an extremely fine
grained matrix of calcite in which
there are scattered small grains
and stringers of clear colorless
secondary calcite, some replacing
fossils, and a few minute quartz
grains.
99.1+ Buff fine-grained dense limestone.
Composed of an extremely finegrained calcite matrix in which
there are small grains of calcite
and minute grains of quartz.
97.0+ Gray medium-grained oolitic limestone cemented with calcite.
Microfossils are abundant, many
with aggregates of minute quartz
grains or cryptocrystalline silica
in the interior parts. There are
a few minute grains of detrital
quartz.
99.8+ Dark-gray fine-grained fossiliferous
limestone. Composed of calcite
grains, macrofossils, microfossils,
and oolites(?). Many of the
fossils are composed of cryptocrystalline silica. There are some
small aggregates of fine-grained
clay-size material and many
minute pyrite granules.
101.3
Dark-gray fine-grained dense limestone,
Composed chiefly of
extremely fine grained calcite;
minor constituents are finegrained detrital quartz (about 2
percent), pyrite and other opaque
minerals, and traces of petroliferous residue
102.0
Gray medium-grained fossiliferous
limestone, Rock is about 25
percent fossils. Composed of
fine-grained calcite, minor quantitles of detrital quartz, clay,
phosphatic material, and a very
minute auantitv of nvrite.
i
!21
~
~
~
~
!;:d
'(Jl
~
..-
TABLE
Laboratory
sample
Age
Locality
,.Q
.s
-~~
~s
...::
f;:<;
~~
bll
::;?1
"'
03
Q)
f;:<;
..9:l
-g
::l
,.Q
~~
31
0
03
0
-~5
..9:l
Source
>
2.-A.nalyses, in percent, of some carbonate rocks and source materials-Continued
f;:<;
~~
...::
0
03
0
0
0
bll
::;?1
Remarks
~
03
r::
03
.05
E-t
I. ROCKS AND SOURCE MATERIALS CONTAINING ONLY SYNGENETIC URANIUM-Continued

A. Marine limestones-no significant metamorphism, nonfetid-Continued
2 60444
Nicholas Limestone. Member of Cynthiana Formation.
30447---- Catheys Limestone.
2 30445 ____
Bigby Limestone.
2' 30451. ___ Belden Forma-
tion.
2 30446 --
2 30480.---
Hermitage Formation.
Twin Creek
Limestone.
Middle Ordoviclan.
_____ do _________
5.6
51. 1
<.5
2. 3
0.90
0.07
0.007
0.0002
5. 6
91.09 <1.05
0.16
Road cut, U.S.

Highway31,
2 miles north
of Columbia,
Tenn.
4. 9
50.3
1.5
2.2
.54
.59
.064
.0002
4. 9
88.41
1. 40 0.02
_____ do _________ ___ do ___________
Pennsylvanian.
Middle Ordovician.
Middle and
Late Jurassic.
-------
Abandoned
quarry 2 miles
east of Carlisle, Ky.
West slope of
Vail Pass,
Eagle
County,
Colo.
3.14
2.3
2.2
2.2
52.3
.7
5.2
.20
2.85
.39
.0002
2.2
86.32
1. 46
6. 75
. 29
5.2
11.9
47.0
.6
4.0
. 74
.13
.016
.0006
11.9
83.62
1. 25
. 31
.01
4.0
Road cut, U.S.

Highway31,
2 miles north
of Columbia,
Tenn.
24.3
Road cut, U.s.

Highway 40,
Parleys Canyon, Utah.
32.2
34.0
33.6
1.2 13.7
1.2
8.3
.50
.19
6.87
.12
.71
.056
.0004
.0004
24.3
32.2
44.35
59.62
2. 51
2.51
16.26
.28
.20
13.7
99.2+ Gray fine-grained fossiliferous limestone. Rock is about 5 percent

fossils. Composed of finegrained calcite, minor quantities
of detrital quartz, clay, phosphatic material, and a very minute
quantity of pyrite.
Fine-grained, mottled gray and
100.1
brown, fossiliferous limestone.
Composed chiefly of irregularsized calcite grains, phosphatized
microfossils (2 to 3 percent),
small quantities of detrital quartz
and clay, and scattered minute
granules of pyrite. Macrofossils
are composed of calcite.
102.2
Medium-grained mottled gray and
brown limestone.
Composed
chiefly of calcite. Many phosphatized microfossils (3 to 4 percent), detrital quartz (about 1
percent), a few minute pyrite
granules, and specks of iron oxide.
101.1
Dark-gray fine-grained fossiliferous
limestone. Composed chiefly of
calcite. Many microfossilsf some
phosphatized. Some smal granules of phosphatic material are
interstitial to calcite grains.
There are very small quantities
of detrital quartz, minute pyrite
granules, and a black opaque
mineral. Bulk of insoluble matter seems to be finely divided
clay.
101.3
Dark-gray fine-grained arenaceous
limestone. A few fossil brachiopods; many microfossils, most of
which are phosphatized. Composed of calcite matrix, about 15
percent recognizable phosphatic
material, 10 percent detrital
quartz, 2 percent detrital feldspar, come clay, and a few
103.0
Gray fine-grained argillaceous lime
stone. Slaty cleavage. Only
recognizable constituents are
minute grains of quartz, muscovite(?), and pyrite. Almost
opaque in thin section.
.09
8.3
100.17 <2.09 <0.12
-------
0.18
100.4+
100.00 <2.09
-------
.30
101.1+
B. Marine Limestone-metamorphosed, completely recrystallized, nonfetid
249718.- - Leadville
Limestone.
Mississippian. Abandoned
Strauss
quarry, Marble, Colo.
249705. Stockbridge _____ Cambrian and Quarry at FarLimestone
Ordovician.
nams, Mass.
0.03
56.1 <1.0
0.18
0.08
<0.05
-------
0.0003
0.03
. 75
56.0 <I.O
.30
.11
<.05
-------
.0002
. 75
<.12
arof
an-
~
~t:rJ
(")
~
~
1-4
t:C
I
00
G')
t:rJ
~
G')
t:rJ
0
1:"1
0
249714 Franklin Limestone.
Precambrian __ Abandoned
quarry at
McAfee, N.J.
26049L Leadville Limestone.
Mississippian
Quarry at
Garfield, Colo.
.3
53.5
1.7
249716__ __ Hermosa Forma- Middle Penntion.

sylvanian.
Bank of Yule
Creek, Marble,
Colo.
4.07
53.4
1.0
1.59
54.5 <1.0
.22
.16
------ ------.23
.55
<.05
-------
<.0001
<.Ol
-------
.0003
0.017
.0004
.06
1. 59
97.32 <2.09
<.12
-------
.3
95.53
3. 55
<.02
------- -------
4.07
95.19
2.09
.14
.22
0.02
.55
99. 1+
White very coarse-grained limestone. Composed of coarse calcite crystals, a few grains of
quartz and graphite, aggregates
of epidote, and pyrite granules.
99.4+ Gray medium-grained limestone.
Contains traces of graphitic
carbon, minute pyrite granules,
and granules of colorless zoisite(?)
or epidote(?).
102.0
Gray fine-grained limestone. Contains minute grains of quartz,
colorless zoisite(?) or epidote(?),
and tiny granules of pyrite and
graphitic carbon.
C. Marine Limestone-no significant metamorphism, fetid

260450 Hueco Lime
Permian ______ Abandoned road

cut, U.S. Highway 62, 1 mile
west of Hueco
Inn, Hudspeth
County, Tex.
1.5
54.3
0.5
0.29
260478 . Madison Limestone.
Mississippian. Center Ell.! sec.

14, T. 3 S., R.
7 E., Wasatch
County, Utah.
.5
53.2
1. 7
.14
stone.
26048L Unknown _______
260483 ____ Pinery Limestone Member of Bell

Canyon Formation.
----------------
Road cut, U.S.

Highway 50,
40.2 miles east
of Eureka,
Nev.
2. 9
Permian Outcrop on south

side of U.S.
Highway 62, 1
mile east Salt
Flat, Tex.
1.5
53.4
53.4
.7
<.5
0.055 <0.01
.030
. 70
.14
.42
.18
<.01
.20
.07
-------
0. 0002
1. 5
96.96
1. 05 <0.02
-------
0.29
-------
.0004
.5
95.00
3. 56
-------
.14
0.030
.018
.0001
2. 9
.0001
94.87
1.5
1.46
95.18 <1.05
<.02
.47
.17
0.02
.02
o. 70
.42
99.8+ Light-tan fine-grained dense limestone. Contains about 45 percent

poorly preserved microfossils, a
few aggregates of cryptocrystalline silica, and specks of powdery
iron oxide probably formed by
alteration of pyrite.
98.7+ Dark grayish-brown fine-graine
limestone. Composed chiefly of
very fine grained calcite enclosing
scattered large crystals of calcite,
a few small aggregates of cryptocrystalline silica, and traces of
clay. Rock contains scattered
macrofossils and microfossils~
Color probably is due to organic
matter.
100.4
Light-brown fine-grained dense
limestone containing small chert
nodules. Sample analyzed contained no chert nodules. Composed chiefly of fine-grained calcite and a small amount of detrital
quartz and feldspar, and scattered
tiny specks of iron oxide probably
formed by alteration of piirite.
Brown
fine-grained dense ime97.3+
stone. Composed chiefly of very
fine grained calcite and scattered
small grains of colorless calcite,
a few tiny grains of detrital
quartz, small aggregates of cryptocrystalline silica, and minute
~fi~~J:'t~nules; microfossils are
~
~
z
&;
~
ttl
0
tz:j
!;)j
p:j
Ul
D. Marine magnesian limestone-no significant metamorphism, fetid

260448 __ __1 Edwards Limestone.
~60488 __ __1 Hueco

Limestone.
I Early
Creta- I South slope
I 1.8
ceous.
King Moun-
148.sl 4.511.1
Io. 54 I o. 02 '-------1
o. 0001
I 1.8 I 87.09 I
9.41 I 0. 05 ,_______ , 1.1 I 99.50
tain, 2 miles
northeast of
McCamey,
Tex.
Permian ______ Road cut, U.S.

Highway62,
Hueco Gap.
Hudspeth
County, Tex.
4.0 1 49.4 1 3.1 1 .42
.030
I <.01 1-------1
<.0001
4.0
88.21
1 6.48 I <.o2 1-------1
Light-tan fine-grained dense limestone containing small chert

nodules. Composed chiefly of
very fine grained calcite and tiny
grains of detrital quartz, aggregates of cryptocrystalline silica,
and specks of iron oxide. Rock
is partly stained brownish, possibly by organic matter. There
are a few microfossils.
.42 I 99.1+ Light-brown fine-grained limestone. Composed chiefly of finegrained calcite and scattered
larger grains; microfossils are
abundant; some seem to be
phosphatized and others are
composed partly of cryptocrystalline silica. Specks of iron oxide,
probably formed from pyrite,
1
I are abundant.
>
~
~
T.A.BLE
C!)
Source
Age
.ag~
:a
Locality
~~
sa
Laboratory
sample
>
2.-A.nalyses, in percent, of some ca.rbonate rocks and source materials-Continued
.g
.s~
0
Qil
0
bO
"'
Qil
C!)
'6~
0
p::
~~
~
0
o3
0
0
0
r;:;-
bO
Remarks
<e
Qil
o3
'd
2.1
100.4

D. Marine magnesian limestone-no significant metamorphism, fetid-Continued
260452 Sinbad Limestone MemberofMoenkopi Formation.
260457---- Chaffee Formation.
260463 Salem Limestone.
Early Triassic. SWH sec. 6, T.

21 S., R. 13 E.,
Grand Connty, Utah.
Late
Devonian.
Late Mississippian.
249718 ____ Pierre Shale _____ Late Cretaceous.
260458 ____ Carmel Formation.
Middle and
Late Jurassic.
Road cut, U.S.

Highway624, east end of
Glenwood
Canyon, Garfield County,
Colo.
Middle bench,
Busson's
~uarry, Ste.
enevieve,
Mo.
Road cut U.S.

Highway40,
5 miles west of
Kremmling,
Colo.
Northeast end
ot San Rafael
Swell, Emery
County,
Utah.
6.2
11.4
18.1
17.8
27.6
49.0
38.2
33.2
38.9
35.8
2.2
9.0
8.8
3.5
2.5
2.1
2.3
4.3
5.59
4. 7
0.84
0.04
.06
.44
.05
1.24
2.45
. 75
.65
.12
--
0.011
.025
.048
.037
.025
0.0002
.0001
.0003
.0001
.0002
-----------------------
6.2
11.4
18.1
17.8
27.6
87.39
68.05
59.05
67.95
63.62
4.60
18.83
18.41
7.32
5.23
0.09
.14
.12
1. 54
.28
0.02
.04
.09
-------
.03
2.3
4.3
5.59
100.7
100.1
100.2
Gray medium-grained asphaltic

limestone having many small
cavities; petroleum stained.
Composed of fine-grained calcite
and coarser grained secondary
calcite lining cavities. Small
detrital quartz grains are abundant. Rock contains about 0.3
percent pyrite and many microfossils, a few of which are phosphatized.
Dark-gray fine-grained dense limestone. Composed of an extremely fine grained matrix in
which there are many small
calcite grains and detrital quartz
grains. Scattered granules and
small stringers of pyrite constitute about 0.1 percent of the
rock. There are a few macrofossils.
Gray fine-grained argillaceous limestone. Composed chiefly of very
fine grained carbonate minerals
and substantial amounts of
detrital quartz and clay; small
blebs and stringers of an opaque
black substance probably are
carbonized organic residue.
Rock contains a few tiny granules
of pyrite.
Gray fine-grained argillaceous limestone. Composed of an extremely fine grained, almost
opaque matrix, 2 to 3 percent
detrital quartz and feldspar, 2
to 3 percent phosphatic material,
abundant shreds and blebs of
black opaque material that is
probably an organic residue, and
many granules and tiny veinlets
of pyrite.
Grayish-brown fine-grained dense
limestone. Contains about li
percent detrital quartz and feld
spar and a considerable amount
of clay and iron oxide.
4. 7
101.5
0.45
100.0+ White, very coarse grained limestone. Composed of large grains

of carbonate minerals and a few
:flakes of graphite and phlogopite
------
E. Marine magnesian limestone-metamorphosed, completely recrystallized, nonfetid
149713 Franklin
Limestone.
Precambrian
Abandoned
quarry at
Franklin,
N.J.
0.17
--
51.8
3.3
0.45
- - - - - - -
0.26
<0.05
-------
<o. ooo1
0.17
92.50
6.90 <0.12
-------
-------------
----
~
~
~
~
1-4
U2
1-3
C)
l?=.l
~
C)
l?=.l
0
t"4
0
F. Nonmarine magnesium limestone-no significant metamorphism, nonfetid

2 60490 1___ Uinta Forma-
Eocene ________ Near Parlette

gilsonite
mine, Uintah
County,
Utah.
. ____ do _________ NW~
sec.20,
T.10 S., R.
25 E., Uintah
County,
Utah.
tion.
2 50464.---
Mahogany oil
shale bed of
Parachute
Creek.
Member of
Green River
Formation.
~-------
9.4
40.2
3.6
3. 5
1. 90
0.28
0.054
55.0
14.8
6. 7
7. 6
2.41
.09
.11
--
-~
0.021
.0004
9.4
71.07
7. 53
0.66
0.04
3. 5
92.20
55.0
25.89
14.01
.21
.25
7. 6
103.0
--
-----
---- --
-~-
--
Brown, extremely fine grained

limestone containing small quantitles of organic matter{ manganese oxide(?), detrlta quartz
and feldspar, and analcite(?).
Dark-brown madstone containing
at least 25 percent kerogenous
organic matter. Rock is mostly
too fine grained and opaque to
permit identification of constituents. It contains at least 5 percent analcite in visible grains, 1
to 2 percent pyrite, and scattered
small grains of detrital quartz.
--
G. Dolomite-no significant metamorphism, nonfetid

2 i9702 ____
Niagara Group .. Middle Silur- Quarry at

Genoa, Ohio.
ian.
_____ do ___________ _____ dO------- _____ do ________ _
2 <19703. ___
0.23
31.1
22.3
0.21
0.10
<0.05
-------
0. 0001
0.23
55.54
46.65 <0.12
-------
0.21
.45
31.0
21.1
.19
.07
<.05
-------
<.0001
.45
55.36
44.14
<.12
------
.19
2 <19712._ ..
5. 72
29.5
19.8
1.43
.69
<.05
-------
<.0001
5. 72
52.68
41.42
<.12
-------
1.43
Little Falls
Dolomite.
Late Cambrian.
Abandoned
quarry at
Canajoharie,
N.Y.
~-
----------
102.6+ White medium-grained dolomite.

No recognizable constituent
other than dolomite.
100.1+ Brown fine-grained dolomite. No
recognizable constituent other
than dolomite. Rock is petroleum stained.
101.3+ Grayish-brown fine-grained dolo
mite. Contains a small quantity
of detrital quartz, small aggregates of cryptocrystalline silica,
and minute granules of a pyrobitumen
generally
called
anthraxolite.
--
------
stone.
Late Ordovi
cian.
Sec. 24 and 25,

T.48N., R.
5 E., Saguache
County, Colo.
0.43
30.6
22.4
0.33
0.20
<0.05
-------
0.0004
0.43
54.64
46.86 <0.12
-------
0.33
102.3+ Grayish-brown fine-grained dolomite. No recognizable constituent other than dolomite. Rock
is slightly stained by a brown
substance.
------- <0.0001
0.56
55.54
43.09 <0.12
-------
<.05
-------
<.0001
2.05
54.82
42.25
<.12
-------
.48
.18
.02
-------
<.0001
3.5
58.34
36.40
.05
-------
.93
2.64
.36
.40
0.05
.0020
8.59
49.72
40.58
.95
0.03
2.64
2.69
.67
.05
-------
.0006
9.85
49.34
39.54
.12
-------
2.69
Mississippian_ Strauss quarr~,

Marble, Coo.
0.56
31.1
20.6
0.82
0. 72
<0.05
2 i9704 ____
Cambrian and Quarry at

Farnams,
Ordovician.
Mass.
2.05
30.7
20.2
.48
.28
3.5
32.7
17.4
.93
8.59
28.4
19.4
9.85
27.7
18.9
2 <10487 ----
Stockbridge
Limestone.
__ ...do._------- _____ do.------- Abandoned

quarry at
Ashley Falls,
Mass.
69706..-- Kittatinny
Limestone.
Late Cambrian and

Ordovician.
Mulligan
quarry, Clinton, N.J.
29707.. __ _____ do __ ------- _____ do. _______ _____ do __ ------
See footnote at end of table.
!2l
t:J:j
I. Dolomite-metamorphosed, completely recrystallized, nonfetid

2 l9717 ---- Leadville Limestone.
~
~
~
H. Dolomite-no significant metamorphism, fetid

2 <19715 ____ Fremont Lime-
c::f
0.82
100.0+ Light-gray fine-grained dolomite.

Contains a few tiny aggregates
and stringers of cryptocrystalline
silica and minute pyrite grains.
99.6+ Light-gray fine-grained dolomite.
Contains about 1 to 13-i percent
quartz and a few minute muscovite$ains.
99.2
White medium-grained dolomite.
Contains about 1 to 13-i percent
tremolite, a few small quartz
grains, and some minute muscovite fiakes.
102.5
Gray fine-grained dense dolomite.
Contains a few small quartz
grains and tiny quartz veinlets
and minute granules of an iron
mineral.
Dark-gray fine-grained dense dolo101.5
mite. Contains a few small
quartz grains and tiny veinlets
filled with c;g-artz pyrite, and
graphitic car on(?). There are
many ver~ minute pyrite granules distri uted throughout the
rock.
TABLE
>
t..:>
2.-A.nalyses, in percent, of some carbonate rocks and source materials-Continued
Oo)
.s:l
Laboratory
sample
Age
Source
Locality
.s!
~Ill
as
-<
-
---
d
il-l
.s:l
.0
.0
.El
OJ.<
.El<ll
~~
~.!3
0
Ill
0
bO
<ll
Ill
<D
0
Ill
0
"'<D
'C)'d
Remarks
o;
~~
-<
0
~
0
bO
Ill
r::
'i0
Ill
-----

I. Dolomite-metamorphosed, completely recrystallized, nonfetid-Continued
Late Cambrian.
249708.. Milton Dolomite.
Outcrop on east
side of U.S.
Highway7,
south of
Milton, Vt.
13.80
17.1
4.80
1. 06
3.06
.29
.0030
13.80
43.50
35.77
7.24
.04
4.80
105.13
Gray tine-grained siliceous dolomite. Contains about 10 per-
101.8
that seems to be an organicresidue; phosphatic constituent

probably is mixed with this residual substance. Extremely tine
grained pyrite is dispersed
throughout the rock. (R20s
probably includes some (P04)-B,)
Gray tine-grained siliceous dolomite. Composed chiefly of
cloudy carbonate mineral and
about 10 percent quartz and
cryptocrystalline silica. Some of
the cloudiness seems to be due to
clay-size detritus. Contains a
few minute pyrite granules.
~1n: %~~~ a~d 6l~~~t s~E:r:~!
249709 -- _____ do._-------- do._------ _____ do._-------- 22.45
28.4
24.0
15.8
3.46
1.16
. 70
.078
.0014
22.45
41.18
33.05
1. 66
.03
3.46
~
~
t_:fj
l;:lj
~
~
1-4
~
UJ
---
1. Nonmarine limestone-not metamorPhosed, nonfetid
260482---- Flagstaff Limestone.
260465 ____ Fresh-water

marl.
260479 ____ Pony Express
Limestone
Member of
Wanakah
formation.
--
Abandoned
Bird's Eye
quarry, sec. 30,
T.10 S.bR. 4
E., Uta
County,
Utah.
Modem _______ Lake bottom, 1~
miles south
of Charlo,
New Brunswick, Canada.
Late Jurassic .. Abandoned
quarryl Sawpit, Coo.
Late Paleocene and

early
Eocene(?).
- -
53.9 <0.5
1.4
0. 62
0.16
0.05
0.008
0. 0001
1.4
96.12 <1.05
0.12
0.008
0. 62
98.3+ Light-brown, extremely tine

grained dense limestone. Only
constituent that can be identifled is calcite.
52.2
.5
5.0
51.1
.5
1.0
.91
.11
.03
.005
.19
.02
-------
<.0001
2. 8
93.11
1. 05
.07
.004
.0001
5.0
91.20
1.05
.05
-------
--------~---
1. 0
.91
98.0
98.2
Buff unconsolidated marl currently

Composed
being deposited.
chiefly of extremely fine grained
calcium carbonate and a small
quantity of clay and silt.
Very dark gray, extremely tine
grained dense limestone; contains about 3 percent detrital
quartz, some detrital feldspar,
and minute granules of pyrite.
------
K. Nonmarine magnesian limestone-not metamorPhosed, nonfetid
260485 ____ Green River

Formation.
SW!4 sec. 14Er

lOS., R.6 .,
Utah County,
Utah.
16.8
29.1
10.8
3. 7
1.00
0.17
0.085 <0.0001
16.8
51.37
22.59
0. 40
0.15
3. 7
95.0
-~-----
Buff, extremely fine grained marl

stone. Mostly too fine grained
for identification of constituents.
Contains a tew tiny grains of a
carbonate mineral, quartz, and
pyrite.
---
L. Calcareous tufa from uraniferous district-not metamorPhosed, nonfetid
260456 ____ Tufa ____________ Recent ________
---
S~i sec. 24,
T. 30
N.,R.90W.
Fremont
County, Wyo.
~
t_:fj
2.8
Eocene ________
7.2
49.7
1.6
0.68
0.03
0.12
0.050
7.2
0.0004
88.36
3.35
0.28
0.08
0. 68
100.0
Buff fine-grained deposit of extinc1

spring. Composed chiefly o
calcite and contains about 3 per
cent quartz and cryptocrystallinE
silica, traces of organic matter,
limonite, and some clay.
~
~
0
tot
0
M. Shells ot Modern organisms

260489 ____ Land snail. _____ Modem _______ Sec. 29, T. 6 S.,
R.4 E., Utah
County,
Utah.
_____
do.
________
Barnacle ________
Falmouth,
260468---Mass.
_____ do _________ Lions
Head,
260467---- Clam, tivela
Santa Baratultorum.
bara County,
Calif.
260489 ____ Blue mussel,
Modern _______ Hull, Mass ..
0.1
55.0 <0.5
0.09
------
96.43 <1.05
>.02
>.02
-------------
.11
95.00 <1.05
.11
96.5+ Shells contained small amount of

organic matter.
95.1+ Includes a small quantity of chitin
and other organic matter.
.002
.42
89.7+ Includes some chitin and other

organic matter.
0.34
99.1+ Brownish-gray fine-grained vnggy

limestone. Vugs are lined with
secondary calcite. Small specks
and stains of reddish-brown iron
oxide are distributed throughout
the rock. Traces of a powdery
yellow mineral, probably tyuyamunite, occur on some vug walls.
0.02
-------
<.0001
0.1
--------------
<.0001
<.1
<.0001
<.1
.006
<.0001
.2
89.12 <1.05
.14
<.1
54.0
<.5
.11
.020
<.01
<.1
53.2
<.5
.11
.013
<.o1
.2
50.0
<.5
.42
.020
.06
mytilua edulia.
0.05
0.011
98.16 <1.05
0.09
98.4+ Includes small amount of chitin.

Snails lived on a terrain of Flagstaff Limestone.
D. ROCKS CONTAINING EPIGENETIC URANIUM

A. Marine limestone-not metamorphosed, nonfetid
260484 2___ Tansill Formation.
Permian.-----
SE~
sec. 21, T.
22 S., R. 25
E., Eddy
County,
N.Mex.
0.05
55.0 <0.5
0.34
0.14
0.05
0.010
0.0054
0.5
98.09 <1.05
0.12
0.01
-~-
B. Marine limestone-not metamorphosed, fetid

24g721 ____ Sundance Formation.
Late Jurassic . Sec.3, T. 44

N., R.83W.,
Johnson
County,
Wyo.
5.11
52.8 <1.0
0.86
0.44
<0.05
-------
0.055
5.11
94.28 <2.09 <0.12
-------
0.86
100.2+ Mottled reddish-brown and gray

oolitic limestone
containing
about 0.2 percent metatyuyamunita on fracture surfaces and
irregularly distributed throughout the rock, about 4 percent
detrital quartz and feldspar, 1
percent cryptocrystalline silica,
and stains of reddish-brown iron
oxide.
C. Nonmarine limestone-not metamorphosed, fetid
iz
f;
~
~
~
0
260469 ____ Todilto Limestone.
Late Jurassic.
NW~
4.7
53.2
0.5
0.89
0.13
0.04
0.020
0.0005
4. 7
94.87
1. 05
0.09
0.03
0.89
101.6
2. 7
52.7
<.5
. 78
.16
.02
-------
.031
2.7
94.05 <1.05
.05
-------
. 78
97.6
260471 ____ _____ do ___________ do _________ do ________ --- 10.6
46.9
.8
2.8
.35
.06
.024
,0006
10.6
83.55
1.67
.14
.04
2.8
98.8
260472 ____ _____ do ___________ _____ do _________ _____ do ___________
49.1
.5
1.3
.25
.08
.018
.0032
8.2
87.46
1.05
.18
.02
1. 3
98.2
sec. 31,
T.13 N., R.9
W., McKinley County,
N.Mex.
260470 _____ do ______ ----- . do _________ . dO-----------
8.2
Brownish-gray fine-grained dense

limestone. Contains about 3.5
percent detrital quartz and feldspar, a few minute specks of iron
oxide, and traces of tyuyamunite
on fracture surfaces.
limestone. Contains about 2
percent detrital q.uartz and feldspar, traces of rron oxide and
tyuyamunite.
Light brownish-gray fine-grained
thin-bedded silty limestone.
Contains about 10 percent
detrital quartz and feldspar, a
few minute granules of iron oxide
and pyrite, and thin films of
tyuyamunite.
percent detrital quartz and feldspar, and a few specks of reddishbrown iron oxide. There are
traces of tyuyamunite on fracture
surfaces.
See footnote at end of table.
>
1::..:>
-.J
TABLE
Source
Age
Locality
~5l~
.c,~
s S
-<
:::l
'"'
.,:::l
~E
1":>:1
0
l
0
bO
,Q
.S-<->
"'lct>
1":>:1
00
Laboratory
sample
>
tV
2.-.A.nalyses, in percent, ot some carbonate rocks and source materials-Continued
~.
1":>:1
-<
0
l
0
bO
Remarks
~
l
r;:
"'
<d
98.8
II. ROCKS CONTAINING EPIGENETIC URANIUM-Continued

C. Nonmarine limestone-not metamorphosed, fetid-Continued
260473 ____ Todilto Formation.
15.5
44.9
0.5
2.1
0.22
0.07
0.025
260474 ____ _____ do _ _____ _____ do _________ _____ do ___________ 16.1
45.4
.4
1.9
.14
.04
.009
Late Jurassic. NW}-4 sec. 31,

T.13N.KR.9
W.,Mc inley County,
N.Mex.
0.023
.0039
15.5
79.98
1.05
.16
0.04
2.1
16.1
80.98
.84
.09
.01
1.9
___ do ___________ _____ do _________ ____ .do ___________
1. 5
56.1
<.5
.88
.10
.08
.85
.45
1.5
97.78 <1.05
.18
1. 73
.88
260475 ____ _____ do ___________ _____ do _________ __ do _______ ----
1.5
53.7
<.5
.93
.45
.04
.048
.033
1.5
95.70 <1.05
.09
.09
.93
260476.---
260477----
_____ do ___________ _____ do _________
Sec. 2\i T. 13
N., .9W.,
McKinley
County,
N.Mex.
10.2
46.6
<.5
3.8
. 51
.06
.067
1.19
------------
..
--
10.2
82.91 <1.05
.14
.13
3. 8

percent detrital quartz and feldspar, a few specks of reddishbrown iron oxide and pyrite
granules. There are traces of
tyuyamunite on fracture surfaces.
99.9
percent detrital quartz and feldspar and a few specks of iron
oxides. There is tyuyamunite
on fracture surfaces.
102.0+ Light brownish-gray fine-grained
dense limestone. Contains about
1 percent detrital quartz, many
tiny fluorite grains, and traces of
tyuyamunite.
98.3+ Recrystallized limestone that is
bleached and partly stained by
iron oxides. The altered equtva
lent of sample 260469. Contains
about 1 percent quartz in rounded
and corroded reams, small aggregates of pow ery tyuyamunite,
and iron oxide stains.
97.2+ Brownish-gray fine-grained dense
limestone spotted and streaked
with red iron oxide and uranlnite.
Contains about 8 percent detrital
quartz and feldspar. Mineral
ized parts consist of a mixture of
extremely fine grained reddishbrown substance (hematite?)
and uraninite interstitial to, and
replacing, calcite, and abundant
--~~----------------~~--~-----------
III. ROCKS IN WHICH THE GENETIC CHARACTER OF THE URANIUM WAS NOT DETERMINED
A.
W668733 __ Bear River

Formation.
Early Cretaceo us.
Brackish water limestone-not metamorphosed, fetid
0. 7 3.1
Sec. 4, T. 1 S.,
10.9
R.42 E.,
Bonneville
County,
Idaho.
W902183 __ _____ do.------- _ do ________ ______ do __________ 11.0
46.5
46.5
.6
4.1
W672473 __ _____ do _____ ------ do _________ _____ do ___________ 12.6
45.8
.5
4.8
0. 93
0.86
0.15
0.024
10.9
80.80
1. 46
2.04
0.15
3.1
98.5
Gray fine-grained limestone containing a substantial quantity

of organic matter.
.86
1.35
.17
.012
11.0
79.73
1.26
3.20
.10
4.1
99.4
. 91
.12
.011
12.6
79.55
1.05
2.15
.08
4.8
100.2
Dark-gray thinly laminated lime

stone with thin coaly partings.
Contains about 10 percent or
ganic matter, 0.5 percent pyrite,
and a few quartz grains. Phos
phatic constituent probably is
mixed with the dark coaly substance.
Gray fine-grained limestone containing a substantial quantity
of organic matter.
1.1
~
~
~
~
~
I
Ul
1-3
0
t:z:.l
s
~
W67241 a__ Bear River

Formation.
Early Cretaceous.
Sec. 4, T.1 S.,

R.42E.,
BonnevUle
County,
Idaho.
36.7
30.9
.9
9.4
4.0
.34
.08
.022
36.7
54.26
1. 88
.80
.10
9.4
103.1
Gray fine-grained argillaceous limestone with a substantial quantity

of organic matter.
Gray fine-grained concretion in

shale. Consists chiefly of very
fine grained calcite, about 15
percent clay, 5 percent detrital
quartz, a small quantity of organic matter, and a few pyrite
granules.
Brownish-gray fine-grained concretion in shale. Consists chiefly
of extremely fine grained material
in which no minerals can be
recognized, and contains about
15 percent detrital quartz and
feldspars, a few granules of
pyrite, and a trace of organic
matter.
B. Carbonate concretions in marine shales-not metamorphosed, nonfetid
20.6
41.0
1.1
5. 8
1. 66
0.10
o. 016
0. 0001
20.6
72.98
2. 30
0.24
0.01
5. 8
101.9
260455 ____ Monterey Shale_ Miocene_----- Road cut, U.S.

24.4
Highway 101,
2 miles north
of Shell
Beach, San
Luis Obispo
County, Calif.
19.5
14.2
6.2
2.25
.20
.047
.0005
24.4
43.00
29.70
.48
.06
6.2
103.8
260454 ____ Mancos Shale___ Late Cretaceous.
Road cut, U.S.

Highway40,
1 mile west of
Steamboat
Springs, Colo.
--'-1 Collected by E. P. Baroni.

a Collected by A. P. Pierce and J, W. Mytton.
a Collected by James D. Vine.
----
-------
- -
---~.
---------
---------- ----------
I
~
e
0
~
~
~
c
gj
>

Uranium in Carbonate Rock

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/,'7 -

Prepared on behalf of the

SHORTER CONTRIBUTIONS TO GENERAL GEOLOGY

SURVEY PROFESSIONAL PAPER 474-A

Prepared on behalf of the

STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1963

UNITED STATES DEPARTMENT OF THE INTERIOR

Thomas B. Nolan, Director

For sale by the Superintendent of Documents, U.S. Government Printing Office

Epigenetic uranium deposits in carbonate rocks-Con.

SHORTER CONTRIBUTIONS TO GENERAL GEOLOGY

Carbonate rocks generally have been considered to be among

has been revised, and some qualifying amendments have

The principal objectives of this investigation were to

It was discovered during early investigations of the

SHORTER CONTRIBUTIONS TO GENERAL GEOLOGY

have reported uranium contents ranging from 0.30

The terms "limestone" and "dolomite" by definition

calcium phosphate minerals, calcium sulfate minerals,