Caramelization - The Untold Story
Caramelization - The Untold Story
Caramelization - The Untold Story
Food Science
Caramelization
Caramelization is defined as the chemical reactions that occur when any sugar is
heated to the point that its molecules begin to break apart.
The greater the quantity of sugar that is heated, the less sugar and sweetness remain,
and the darker more bitter it gets.
It is a type of non-enzymatic browning reaction
Differs from other browning reactions (namely the Maillard) reaction as it is an example
of a pyrolytic reaction.
Caramelizing sugar results in different flavors, such as buttery and milky notes (from
diacetyl), fruity notes (from esters and lactones), flowery notes, sweet notes, rum-like
notes and roasted notes.
When sugars are cooked with amino acids or proteins (like in milk) then some of the
sugars participate with the proteins in the Maillard Reaction, and produce a larger range
of compounds and a rich aroma.
Chemistry of Caramelization
The Science
Caramelization of sucrose starts with the melting of the sugar at high
temperatures (see below) followed by foaming (boiling). Sucrose first decomposes
into glucose and fructose. This is followed by a condensation step, in which the
individual sugars lose water and react with each other. Hundreds of new aromatic
compounds are formed having a range of complex flavors.
In the case of the caramelization of sucrose three main product groups are
formed: a dehydration product, caramelan C12H18O9; and two polymers, carmelen
C36H50O25 and caramelin. The average molecular formula for caramelin
C125H188O80.
More Science
Sugar
Temperature
Fructose
110 C
Galactose
160 C
Glucose
160 C
Maltose
180 C
Sucrose
160 C
Caramelization in Action
Caramelized Onions
recipe:http://www.foodnetwork.com/recipes/ina-garten/caramelized-butternut-squash-recipe.
html
Caramelized Apples
recipe: http://www.foodnetwork.com/recipes/ina-garten/caramelized-shallots-recipe.html
Caramelized Squash
Caramelized Shallots
the system of dessert wine offers the opportunity to study caramelization in a simple food
situation
recipe: http://www.epicurious.com/recipes/food/views/caramelized-apples-234164
Crme Brle
Caramelization As Used By Us
Acknowledgements
Thank you first and foremost to Jennifer for an engaging class, we couldnt
have done this without you. Definitely the best intersession class either of us
have taken
Thank you to Dans grandma, she helped out with refining the recipe.
Thank you to Victorias mom- she paid for the sugar and milk- integral to the
process.
References
1.
2.
3.
McGee, Harold. "Chapter 12." On Food and Cooking: The Science and Lore of
the Kitchen. New York: Scribner, 2004. 656-57. Print.
Kroh, L.W. Caramelization in food and beverages. Food Chemistry 51 (1994):
373-79
http://www.scienceofcooking.com/caramelization.htm