PVT Keyword

DESKTOP-PVTKeyword
Reference Manual
2001, 2002 Landmark Graphics Corporation
Part No. 159678 R2003.4
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Table of Contents
About This Manual
Purpose . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii
Audience . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii
Organization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii
Related Documentation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . viii
Chapter 1
Introduction
1.1 Overview of the Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-1
1.2 Free Field Input . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-2
1.3 FORTRAN File Assignments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-3
Chapter 2
Equation-of-State Properties
2.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-5
2.2 Equation of State (EOS) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-6
2.3 Component Names (Components) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-8
2.4 Component Characteristics (PROPERTIES) . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-9
2.5 Binary Interaction Coefficients (DJK and DJKCOR) . . . . . . . . . . . . . . . . . . . 2-12
2.6 Lohrenz-Bray-Clark Viscosity Correlation . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-14
2.7 Pedersen et al. Viscosity Correlation (VISPE, VISK and VISKJ) . . . . . . . . . 2-15
2.8 Component K-Value Correlation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-17
2.9 Correlation of CO2 Saturated Water Properties . . . . . . . . . . . . . . . . . . . . . . 2-18
2.10 Ideal Gas State Enthalpy Coefficients (HIDEAL) . . . . . . . . . . . . . . . . . . . . 2-22
2.11 End of EOS Data (ENDEOS) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-23
2.12 Output File for PVT Properties (PVTFILE) . . . . . . . . . . . . . . . . . . . . . . . . . 2-24
2.13 Output File for K-values (KVFILE) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-25
2.14 Selection of Water in Oil Option (WINOIL) . . . . . . . . . . . . . . . . . . . . . . . . . 2-25
R2003.4 - Landmark
iii
DESKTOP-PVT KEYWORD REFERENCE MANUAL
2.15 Thermal Option (THERMAL) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-26

Chapter 3
Simulating Laboratory Measurements

3.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-33
3.2 Gas Z-Factor (Z-FACTOR) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-33
3.3 Liquid Density (LIQDEN) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-36
3.4 Vapor Pressure (VP) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-38
3.5 Saturation Pressure (PSAT) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-40
3.6 Liquid and Vapor Viscosity (VISC) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-42
3.7 Constant Composition Expansion (CCEXP) . . . . . . . . . . . . . . . . . . . . . . . . . 3-43
3.8 Constant Volume Depletion (CVDEP) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-48
3.9 Swelling Test (SWELL) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-54
3.10 Differential Expansion (DIFF) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-55
3.11 Multiple Contact Vaporization Test (MCVAP) . . . . . . . . . . . . . . . . . . . . . . 3-59
3.12 Phase Envelope Calculation (ENVELOPE) . . . . . . . . . . . . . . . . . . . . . . . . . 3-62
3.13 Enthalpy Calculation (ENTHV or ENTHL) . . . . . . . . . . . . . . . . . . . . . . . . . 3-64
3.14 Liquid Water Properties (WATPRP) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-66
3.15 Saturation Pressure with Water (PSATW) . . . . . . . . . . . . . . . . . . . . . . . . . . 3-67
3.16 Distillation Test (DISTIL) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-69
3.17 Complete Phase Envelope Calculation (ENVPT) . . . . . . . . . . . . . . . . . . . . 3-77
3.18 Composition Variations with Depth (ZGRAD) . . . . . . . . . . . . . . . . . . . . . . 3-79
3.19 Properties of Carbon Dioxide Saturated Water (CO2TAB) . . . . . . . . . . . . 3-84
3.20 Multiple Contact Steam Vaporization Test (MCSVAP) . . . . . . . . . . . . . . . 3-86
3.21 Two Phase Isothermal Flash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-91
Chapter 4
Simulating Multistage Separators

4.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-95
4.2 Separator Conditions Data (SEPARATOR) . . . . . . . . . . . . . . . . . . . . . . . . . . 4-95
4.3 Separator Test with Regression (SEP) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-97
Chapter 5
Automatic Parameter Adjustment

5.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-103
iv
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5.2 EOS Property Adjustment (REGRESS) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-105

5.3 Regression Variable Data (VARIABLE) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-105
5.4 Nonlinear Regression Process (IMAX) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-106
5.5 Assignment of Regression Variables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-107
5.6 End of Regression Data (ENDREG) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-111
Chapter 6
Pseudoization
Chapter 7
Heavy Fraction Characterization

Chapter 8
Calculation Controls
8.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-125
8.2 Selection of Flash Method . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-125
8.3 Saturation Pressure Tolerance Card . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-126
8.4 Flash Calculation Tolerance Card . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-128
8.5 Expansion Tolerance Card . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-129
8.6 Saturation Pressure and Flash Calculations Output
(DBUGS and DEBUGF) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-130
8.7 Selection of Viscosity Calculation Method . . . . . . . . . . . . . . . . . . . . . . . . . . 8-131
Chapter 9
Composition Specification
Appendix A
Unconstrained Minimization of
Least-Squares Functions
A.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-137
A.2 Gauss-Newton Method . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-139
A.3 Advantages of the Gauss-Newton Method . . . . . . . . . . . . . . . . . . . . . . . . A-140
A.4 Defects in the Gauss-Newton Method . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-141
A.5 Method of Rotational Discrimination . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-142
A.6 The Rotational Discrimination Algorithm . . . . . . . . . . . . . . . . . . . . . . . . A-144
R2003.4 - Landmark
Appendix B
The Establishment of Bounds on Variables

B.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . B-149
B.2 Our Treatment of Bounded Variables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . B-149
Appendix C
One-Dimensional Search Procedure

C.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . C-151
C.2 Assumptions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . C-151
C.3 Operating Characteristics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . C-152
C.4 Description of the Search Procedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . C-152
Appendix D
Example Problems
D.1 Example 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-155
D.1.1 Lab Report . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-156
D.1.2 Sample Files . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-174
D.2 Example 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-222
D.2.1 Lab Report . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-222
D.2.2 Sample File . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-236
Appendix E
References
Keyword Index
Subject Index
vi
Landmark - R2003.4
Preface
About This Manual

Purpose
This manual describes the functions of DESKTOP-PVT, a program
designed to simulate the behavior of hydrocarbon fluid mixtures.
DESKTOP-PVTs purpose is to generate PVT properties or develop a
mathematical model which can be used in a compositional reservoir
simulator such as VIP-COMP to analyze oil and gas production
characteristics.
Audience
This manual is intended to assist new and experienced users of
DESKTOP-PVT in the generation of PVT properties where laboratory data
is limited, or the development of a mathematical model that agrees with
experimental data.
Organization
The information in this manual is arranged in a logical manner for
maximum ease-of-use. The following chapters are included:
R2003.4 - Landmark
Introduction.
Equation-of-State Properties.
Simulating Laboratory Measurement.
Simulating Multistage Separators.
Automatic Parameter Adjustment.
Pseudoization.
Heavy Fraction Characterization.
Calculation Controls.
Composition Specification.
vii
About This Manual
Related Documentation
The following manuals provide more information related to the material
in this manual. For more information, please consult the appropriate
manual listed below.
DESKTOP-PVT Users Manual. Characterizing equations of state for

compositional simulation.
viii
Landmark - R2003.4
Chapter
1
Introduction
DESKTOP-PVT is used to simulate the behavior of fluid mixtures when
they are subjected to any of a variety of laboratory procedures. The fluids
may be either liquid or vapor and may undergo phase changes during the
simulated experiments.
The program can be used in a purely predictive mode to generate PVT
properties where laboratory data is limited, or it can be used to develop a
mathematical model that agrees with experimental data. In the latter case,
the mathematical model of the fluid system can then be used in a
compositional simulator such as VIP-COMP to analyze oil and gas
production characteristics. In addition, the tabular data necessary to
define fluid behavior in VIP-ENCORE may also be generated by
DESKTOP-PVT.
To aid in development of a fluid model that matches experimental data, a
nonlinear regression package is provided as an integral part of DESKTOPPVT. This facilitates the adjustment of unknown or uncertain parameters
that affect fluid behavior.
1.1 Overview of the Data

The data for DESKTOP-PVT is divided into six major parts:
1. Equation-of-state properties
2. Laboratory procedures
3. Surface separation
4. Automatic parameter adjustment
5. Pseudoization
6. Heavy fraction characterization
R2003.4 - Landmark
1-1
Introduction
DESKTOP-PVT Keyword Reference Manual
1.2 Free Field Input

All data is read in "free field" format. Simply stated, this means that it is
not necessary to type numbers in specific columns. DESKTOP-PVT reads
each item of data or "word" by finding the leftmost character and then
decoding each successive character until a blank column or a comma
signifies the end of the word.
The data stream contains both numbers and alpha code words, the latter
used to identify subsequent numbers or to select program options. It is a
general rule that each new type of data is introduced by an alpha code
word.
In the data descriptions that follow, code words are identified by being
typed in upper case letters. They must appear in the data stream exactly as
typed in this manual. The names of variables whose values must be
supplied are typed in lower case letters. Appropriate numbers or names
must be entered in their proper place.
1-2
Landmark - R2003.4
Introduction
1.3 FORTRAN File Assignments

DESKTOP-PVT makes use of several different FORTRAN units for scratch
files for input and output. Figure 1-1 illustrates schematically the
DESKTOP-PVT I/O structure.
Figure 1-1: DESKTOP-PVT I/O Structure
R2003.4 - Landmark
1-3
Introduction
1-4
Landmark - R2003.4
Chapter
2
2.1 Introduction
The PVT properties of both vapors and liquids are predicted by
DESKTOP-PVT by means of a cubic equation of state. Available equations
of state include Redlich-Kwong (RK), Soave-Redlich-Kwong (SRK),
Zudkevitch-Joffe-Redlich-Kwong (ZJRK), Peng-Robinson (PR), and the
three-parameter versions of PR, SRK, and RK.
In order to completely define fluid properties it is necessary only to define
fluid composition and various properties of individual components. The
individual components may be pure components, but frequently they are
themselves mixtures. For example, isobutane (i-C4) and normal butane (nC4) may be treated together simply as C4.
Heavy fractions are normally grouped together over a reasonably wide
range of molecular weights. For example, C16 - C20 may be grouped
together as a single component that is designated as C18.
The properties of a large number of components have been internally
coded, so they are automatically assigned unless the user elects to
override the default. For light components the internal values usually
represent pure component properties, but for heavier fractions the internal
values have been adjusted to produce improved results for naturally
occurring oils and gases at reservoir conditions.
Table 2-1 and Table 2-2 summarize the internally coded properties for all
components that can be automatically determined. Using one of the
component identification codes contained in these tables as data in the
COMPONENTS input data will cause the tabulated values to be loaded.
Unless these values are overridden by the user in the PROPERTIES data
section, they will be used by default.
R2003.4 - Landmark
2-5
2.2 Equation of State (EOS)

The equation of state to be used for PVT properties is specified on the EOS
data card.
RK
PR
PRORIG
SRK
EOS
ZJRK
RK3P
PR3P
PROR3P
SRK3P
Definitions:
RK
Redlich-Kwong equation-of-state.
PR
Peng-Robinson equation-of-state.
PRORIG
Original Peng-Robinson equation-of-state.
SRK
Soave Redlich-Kwong equation-of-state.
ZJRK
Zudkevitch-Joffe-Redlich-Kwong equation-ofstate.
RK3P, PR3P,
PROR3P, SRK3
Three-parameter version of RK, PR, PRORIG and

SRK respectively
Example:
To specify the Peng-Robinson equation-of-state, the following data card is
required:
EOS
NOTE:
2-6
PR
1.
The original Peng-Robinson equation of state uses the same

equation to calculate the temperature dependent term of "a" for
all ranges of acentric factor. The default version of the PengRobinson equation of state used in DESKTOP-PVT employs a
different equation to calculate the temperature dependent term of
"a" when the acentric factor is greater than 0.49.
Landmark - R2003.4
2.
For compatibility with VIP-CORE, the user does not have to use a
different keyword to specify the three parameter version of an
equation of state. The program recognizes that the volume shift
parameter should be used if the keyword VSHFT is included on
the second line of the PROPERTIES data card. For example, the
three parameter version of the Seave-Redlich Kwong EOS can be
spedifed by
EOS
SRK
if VSHFT is also included on the PROPERTIES card.
R2003.4 - Landmark
2-7
2.3 Component Names (Components)

The alphameric labels that will be used to identify the components are
defined here. If any of the component names contained in Table 2-1 or
Table 2-2 is used, the properties data will be picked from the table, subject
to user override. If unrecognized labels are used, the user must directly
specify at least molecular weight data.
COMPONENTS
cmp1 cmp2. . . cmpn
(NCV
ncv)
Definitions:
cmpn
Component name. An alphameric label containing up to 6 characters. Using a name contained in

either Table 2-1 or Table 2-2 will cause the tabulated properties to be automatically loaded.
ncv
Number of volatile components. Use only in

experiments associated with VIP-THERM (STMDIS, PSATW).
Define the components in a fluid system that contains carbon dioxide,

nitrogen, methane through hexane, and heptanes plus. Either of the
following is acceptable:
(1) COMPONENTS
CO2 N2 C1 C2 C3 IC4 NC4 IC5 NC5 NC6 C7+
(2) COMPONENTS
CO2 N2 C1 C2 C3 NC4 NC5 NC6 C7+
In both components definitions, all components except C7+ will have
default properties. The user must enter properties data for C7+.
2-8
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2.4 Component Characteristics (PROPERTIES)

Properties data are entered to define the PVT characteristics of individual
components. These are combined by appropriate mixing rules and used
with the equation of state to determine the properties of mixtures.
Default properties for internally defined components are given in Table 21 and Table 2-2. Omitting the properties data card for these components
results in the use of the default properties.
For non-internally defined components, a minimum of molecular weight
data must be entered on the properties data card. Default properties for
these components are determined by table lookup on the internally
defined hydrocarbon component properties based on molecular weight.
All properties for internally-defined components and all except molecular
weight for non-internally defined components may be defaulted by
entering the alpha label X on the properties data card where the default
value is desired. The properties table may be truncated at any point after
molecular weight. All unread data is defaulted. The number of entries on
the table title and properties data must be the same.
F PSIA
PROPERTIES
C PSIG
K KPA
R KGCM2
COMP MW
ACENTRIC OMEGAA
OMEGAB
cmpi mwi tci pci zci wi
o
al
o
bl
TC PC
ZC
VSHFTD VSHFTE
d
PCHOR
pchor
VSHFT
s
NBP
nbp
GRVL
grvl
TREF
tref
Definitions:
F, C, K, R
R2003.4 - Landmark
Alpha label indicating that the units of all temperature

values are:
F
Degrees Fahrenheit, F. This is the

default.
Degrees Centigrade, C.
Degrees Kelvin, K.
2-9
Degrees Rankin, R.
(input optional)
PSIA, KPA, PSIG,
KGCM2
Alpha label indicating that the units of the critical

pressure values (PC) are:
PSIA
Psia. This the default.
KPA
KPa.
PSIG
Psig.
KGCM2
Kg/cm2.
(input optional)
2-10
cmpi
Component name for component i. Must be identical

to one of the names included in the COMPONENTS
data.
mwi
The molecular weight of component i.
tci
Critical temperature of component i.
pci
Critical pressure of component i.
zci
Critical z-factor of component i. (This property

affects only viscosity calculations.)
wi
o
ai
Acentric factor of component i.

o
ai for component i. This is treated as a universal
o
bi
o
bi for component i. This is treated as a universal
constant in the original formulations of the equations

of state (0.4274802 for RK, SRK, and ZJRK; 0.457235529
for PR). Additional flexibility in fitting data is gained
by allowing it to vary by component.
constant in the original formulation of the equations of
state (0.08664035 for RK, SRK and ZJRK; 0.077796074
for PR). Additional flexibility in fitting data is gained
by allowing it to vary by component.
14
12
pchori
Parachor for component i, g

-cm ( s
mole ) .
(This property affects only interfacial tension calculations.)
si
Dimensionless volume shift parameter. (This property

is used only if molar volume is corrected using the
three-parameter EOS option.)
nbpi
Normal boiling point temperature for component i.

(This property is used in ZJRK only.)
grvli
Specific gravity of component i at temperature trefi

relative to water at 60F. (This is used in ZJRK only.)
Landmark - R2003.4
trefi
Reference temperature for component i specific gravity. Default is 60F. (This is used in ZJRK only.)
d, e
Parameters d and e for computing volume shift

parameter s,
s = 1 - d M-e
where M is the molecular weight of a component.
The default value for d is 1.74 and is 0.133 for e.
NOTE:
l.
If either of the temperature or pressure unit flags is specified,

then both must be specified.
2. Repeat the data card containing cmpi, mwi, etc. as necessary to

specify all properties correctly.
3.
Only 80 columns are allowed for each card. By entering the alpha
label > at the end of a card, the data at the next card will be
treated as a continuation of this card.
4.
For the non-internally defined components, the volume shift

parameters are calculated using d and e only if they are input,
otherwise, they are determined by table lookup on the internally
defined hydrocarbon component properties based on molecular
weight.
Example:
PROPERTIES
COMP
MW
C7+
206.
C1
X
R2003.4 - Landmark
TC
895.1
X
PC
302.6
X
ZC
.3121
X
ACENTRIC
.8643
X
OMEGAA
X
.48521
OMEGAB
X
.08261
2-11
2.5 Binary Interaction Coefficients (DJK and DJKCOR)

DJK and DJKCOR data are used to define binary interaction coefficients
(djk). The binary interaction coefficients are used in the mixing rules that
determine for mixtures the A parameter of the EOS. The binary interaction
coefficients are read in if the DJK card is specified, and are computed from
a correlation [4] if the DJKCOR card is specified.
Table 2-3 summarizes non-zero values of djk that have been internally
coded for various combinations of components. These values will be
automatically loaded as data when the corresponding component names
are entered in the COMPONENTS data. In addition, default values for the
interaction coefficients between methane and heavy fractions from C6
through C45 are given in Table 2-2. Interaction parameters between any of
the heavy fractions in Table 2-2 and CO2, N2, C2, and C3 are the same as
given for NC18 in Table 2-3. All binary combinations that involve an
unrecognized component name will be assigned default values of zero.
Any of the default values for binary interaction coefficients can be
overridden by means of the DJK or DJKCOR data.
DJK
cmpk
cmpj
djk
Definitions:
cmpj
Component name of one component in a binary

mixture.
cmpk
Component name of the second component in a

binary mixture.
djk
The binary interaction coefficient for mixtures of

component j and component k.
NOTE:
2-12
1.
Enter one data card for each component k that interacts with
component j.
2.
Enter an entire set of data including the DJK card and cmpk cards
for each component j that requires djk specifications.
3.
Remember that djk = dkj. It is not necessary to define both.
4.
In some experiments associated with VIP-THERM, water appears

implicitly as a component. Binary interaction coefficients for
water may be input by replacing cmpj or cmpk with the alpha
label H2O.
Landmark - R2003.4
DJKCOR
djkcor
Definition:
djkcor
The exponent of the binary interaction coefficients as

[4]:
d jk
= 1
1 6 1 6 djkcor
2V c V c
j
k
-----------------------------13
13
Vc + Vc
j
k
where V c and V c are the critical volumes for comj

k
ponent j and k, respectively. Default is 1.
Example:
Specify the interaction parameters between heavy component C7+ and
CO2, N2, C2, and C3:
DJK C7+
CO2 .15
N2 .12
C2 .01
C3 .01
Example:
DJKCOR
R2003.4 - Landmark
1.2
2-13
2.6 Lohrenz-Bray-Clark Viscosity Correlation

00
The Lohrenz-Bray-Clark viscosity calculation is as follows:

2
00
00
00
00
00
4 4
= b + ( [ C 1 + C 2 r + C 3 r + C 4 r + C 5 r ] 10 )
where is the phase viscosity, b is a base viscosity, is a function of
pseudo critical pressures, pseudo critical temperatures, and mixture
molecular weight, and r is a pseudo reduced phase density.
By default, the coefficients C1, C2, C3, C4, and C5 are equal to 0.1023,
0.023364, 0.058533,-0.040758, and 0.0093324, respectively. Use of the LBC
keyword allows the user to modify these default coefficients to obtain a
better match with experimental viscosities.
The LBC keyword is not required if the user wishes to retain the default
coefficients.
The LBC keyword can appear anywhere after the PROPERTIES keyword
and data and before the end of the ENDEOS keyword. The modified
coefficients will only apply for the current EOS table being defined.
LBC
C1 C2 C3 C4 C5
2-14
Landmark - R2003.4
2.7 Pedersen et al. Viscosity Correlation (VISPE, VISK and

VISKJ)
The Pedersen et al. viscosity correlation is based on the corresponding
states principle [10,11]. A group of substances obeys the corresponding
states principle if these substances have the same reduced viscosity at the
same reduced density and reduced temperature. In such case, only
comprehensive viscosity data for one component (the reference
component) in the group are needed. Others can be calculated from the
reduced viscosity. The Pedersen et al. viscosity correlation uses methane as
a reference substance.
This correlation is useful for heavy oils where the Lohrenz-Bray-Clark
correlation [2] fails to give a proper viscosity prediction for some cases. To
invoke the Pedersen et al. viscosity option, a keyword "VISPE" should be
entered before the laboratory test data (see Section 8.7). The user has the
option of specifying k1 to k7 (VISK card) for calculating the viscosity of the
reference component and binary interacting coefficients Xkj (VISKJ card)
for calculating the mixture pseudo-critical temperature used in the
viscosity correlation. VISK and VISKJ cards are optional. Default values
will be used if they are not entered. The default values are zero for all the
interacting coefficients Xkj and the following values for the coefficients kj.
k1 = 9.74602
k2 = 18.0834
k3 = 4126.66
k4 = 44.6055
k5 = 0.976544
k6 = 81.8134
k7 = 15649.9
Only those data overwriting the default values need to be entered.
VISK
j
.
.
.
VISKJ
k
.
.
.
ENDVIS
kj
.
.
.
j
.
.
.
xk,j or cmpk cmpj xk,j

.
.
.
.
.
.
.
.
.
.
.
.
Definitions:
VISK
R2003.4 - Landmark
The keyword for inputting kj values. Optional.
2-15
Index for kj.
kj
The kj values for calculating the viscosity of the

reference component.
VISKJ
The keyword for inputting binary interaction

coefficients xkj. Optional.
Component number k.
Component number j.
cmpk
Component name of component k
cmpj
Component name of component j
xkj
Binary interaction coefficient for components k

and j for calculating critical temperature used in
the viscosity correlation. Default is 0.0
ENDVIS
The keyword marks the end of Pedersen et al.

viscosity data input.
Example:
VISK
1
42.5
2
0.0002279
3
11770.0
4
600.3
5
16.49
6
0.0552
VISKJ
3 5
-0.36409
3 6
-0.38517
3 7
-0.8
3 8
-0.62763
ENDVIS
2-16
Landmark - R2003.4
2.8 Component K-Value Correlation

In DESKTOP-PVT the component K-values are usually computed using
an equation of state. For distillation test, a correlation is available to
computed compute K-values of distillates. The component K-value is
expressed as
Ki =
Di
B
A i + -----i + C i P exp ---------------
T E i
P
(2-1)
where Ai to Ei are constant coefficients for component i, P is pressure in

psia and T is temperature in Rankin.
KVCOR
COMP
k
.
.
A
ak
.
.
B
bk
.
.
C
ck
.
.
D
dk
.
.
E
ek
.
.
Definitions:
KVCOR
Alpha label indicating the coefficients of component

K-values correlation are to follow. (Input Optional)
Component number k.
ak to ek
Coefficients A to E of component K-value

correlation. (Input Optional)
Example:
KVCOR
COMP
1
2
3
4
R2003.4 - Landmark
A
-1.0
-1.0
-1.0
-1.0
B
0.1531431E+06
0.9296972E+06
0.3488022E+08
0.2121159E+12
C
0.3614000E-02
0.4227000E-02
0.5141000E-02
0.1246900E-01
D
0.7275900E+04
0.1214770E+05
0.2085317E+05
0.4656781E+05
E
0.0
0.0
0.0
0.0
2-17
2.9 Correlation of CO2 Saturated Water Properties

Correlations were developed to calculate properties of carbon dioxide
saturated water as functions of temperature, pressure and salinity. These
properties include carbon dioxide solubility, formation volume factor,
compressibility and viscosity.
The solubility of carbon dioxide in pure water is calculated as a function of
temperature and pressure.
c P
R sw = a P 1 b sin --- --------------------
2 c P + 1
if P < P
and
o
R sw = R sw + m ( P P )
if P P
where
4
a =
ai ( 10 3 T )
i=0
4
b =
bi ( 10 3 T )
and
0<b<1
i=0
4
c =
10 3
ci ( 10 3 T )
i=0
2
2
sin1 ( b )
o
P = --- -------------------------------------------
2
2
c 1 --- sin1 ( b )
R sw = a P ( 1 b )
o
c Po
c Po
cP
---------------------
-m = a 1 b sin --- --------------------+
cos
--- --------------------2 c Po + 1
2 c P o + 1
2 c P o + 1
2-18
Landmark - R2003.4
with Rsw in scf of carbon dioxide per stb water, temperature (T) in degree
Fahrenheit, pressure (P) in psia and
a0 =1.16306, a1 =-16.6304, a2 =111.07305, a3 =-376.85925, a4 =524.88916
b0 =0.96509, b1 = -0.27255, b2 = 0.09234, b3 = -0.10083, b4 = 0.09979
c0 =1.28030, c1 =-10.75660, c2 = 52.69622, c3 =-222.39488, c4 =462.67255
This correlation matches the solubility data of Wiebe [22] for liquid and
supercritical carbon dioxide in water within 10 scf/stb for temperatures
between 54 and 212 degrees Fahrenheit and pressures up to 10,000 psia.
The calculated solubility in pure water is further adjusted for the effects of
salinity to obtain the solubility of carbon dioxide in brine
R sb
log -------- = s o S T s1
R sw
where S is salinity of brine in weight percent of solid, T is temperature in
degree Fahrenheit and
s0 = -0.028037
s1 = -0.12039
The measured data in NaCl Solutions from Malinin and Savelyeva [14],
Malinin and Kurovskaya [15], and McRee [16] were used to obtain
parameters s0 and s1.
The formation volume factor of carbon dioxide saturated water (or brine)
is calculated using
1
B w = ------ [ w, sc + 0.02066 R sb ]
w
w = w, atm + 10 3 d 1 R sb
where d1 = 5.8, Bw is in rb/stb, w,sc is water density at standard
temperature and pressure in lb/cu ft and w,atm is water density at
temperature and 14.7 psia in lb/cu ft. Both w,sc and w,atm are calculated
using the correlation from Rowe and Chou [17].
The correlation of carbon dioxide saturated water density is developed
using the data of Parkinson and De Nevers [18], and Sayegh and Najman
[19].
R2003.4 - Landmark
2-19
For pressures less than 5000 psia the water compressibility is calculated
using the correlation from Rowe and Chou [17]. For pressures greater than
5000 psia,
1
1
------- = ------------------ + 7.033 ( P 5000 )
Cw
C w, 5000
where Cw,5000 is water compressibility at temperature and 5000 psia from
Rowe and Chou correlation in 1/psia. The above correlation is derived
from the water compressibility correlation by Osif [20].
Water viscosity is calculated from Kestin et al. correlation [21]. The effects
of carbon dioxide solubility are ignored in both compressibility and
viscosity calculations.
Default values of a0 to a4, b0 to b4, c0 to c4, s0, s1, and d1 as shown above
are given in the program. The default values may be overwritten by means
of CO2COR data. Only those data overwriting the default values need to
be entered.
CO2COR
ACOEF
BCOEF
CCOEF
SCOEF
DCOEF
ENDCO2
a0
b0
c0
s0
d1
a1
b1
c1
s1
a2
b2
c2
a3
b3
c3
a4
b4
c4
Definitions:
2-20
CO2COR
The keyword for inputting correlation coefficients

for properties of carbon dioxide saturated water.
ACOEF
The keyword for inputting coefficients a0 to a4 for

computing solubility of carbon dioxide in water.
Five numbers corresponding to a0 to a4 must be
entered following the keyword.
BCOEF
The keyword for inputting coefficients b0 to b4 for

Five numbers corresponding to b0 to b4 must be
CCOEF
The keyword for inputting coefficients c0 to c4 for

Five numbers corresponding to c0 to c4 must be
Landmark - R2003.4
SCOEF
The keyword for inputting coefficients s0 and s1 for

adjusting the salinity effects in computing solubility
of carbon dioxide in water. Two numbers
corresponding to s0 and s1 must be entered
following the keyword.
DCOEF
The keyword for inputing coefficient d1 for

computing density of carbon dioxide saturated
water. Only one number corresponding to d1 need
to be entered following the keyword.
ENDCO2
The keyword indicates the end of inputting

correlation coefficients for properties of carbon
dioxide saturated water.
Example:
EOS PR
COMPONENTS
.
.
.
c
c -----------------------------------------------c correlation of properties of co2 saturated water
c -----------------------------------------------c
CO2COR
ACOEF 1.16306
-16.6304
111.07305
-376.85925
BCOEF 0.96509
-0.27255
0.09234
-0.10083
CCOEF 1.28030
-10.75660
52.69622
-222.39488
SCOEF
-0.028037
-0.12039
DCOEF
5.8000
ENDCO2
.
.
.
ENDEOS
R2003.4 - Landmark
524.88916
0.09979
462.67255
2-21
2.10 Ideal Gas State Enthalpy Coefficients (HIDEAL)

The HIDEAL card is used to define component ideal gas state enthalpy
coefficients. The ideal gas state enthalpy for each component is given by
the fifth degree polynomial
*
Hi
= h i0 + h i1 T + h i2 T + h i3 T + h i4 T + h i5 T
where H i is the ideal gas state enthalpy of component i in Btu/lb-mole, T

*
is the temperature in degrees Rankin and h in are the ideal gas state
enthalpy coefficients of component i in Btu/lb-mole-(R)n.
Table 2-4 gives component Passut-Danner ideal gas state enthalpy
coefficients for pure components [6, 7] which have been internally coded.
Note that these coefficients are given on a mass rather than a molar basis.
These values will be automatically loaded when the corresponding
component names are entered in the COMPONENTS data.
For components not listed in Table 2-4, default ideal gas state enthalpy
coefficients are calculated using the Kesler and Lee correlation [8, 9, 10].
This correlation is not always applicable. It fails if the component critical
temperature is less than 60 F. The correlation requires component specific
gravity. If the component is a gas at standard conditions, then we use the
density at the vapor pressure at standard temperature. For the relatively
heavy components commonly used in thermal reservoir simulation, these
shortcomings are not a problem.
Any of the default values for ideal gas state enthalpy coefficients may be
overridden by means of HIDEAL data.
HIDEAL
cmpi
*
*
*
*
*
*
h i0 h i1 h i2 h i3 h i4 h i5
Definitions:
cmpi
*
h in
Component name for component i. Must be identical to one of the components included in the
COMPONENTS data.
Ideal gas state enthalpy coefficients for component i, Btu/lb-mole-(R)n.
Example:
C7+ 26.6 -0.023 4.59E-04 -0.998E-07 1.085E-11 -0.33E-15
2-22
Landmark - R2003.4
2.11 End of EOS Data (ENDEOS)

The ENDEOS card terminates the reading of the equation-of-state
properties for the components whose mixture characteristics are to be
simulated. Data describing various laboratory procedures follow.
ENDEOS
Example:
EOS
PR
COMPONENTS
CO2 N2 C1 C2 C3 NC4 NC5 NC6 C7+
PROPERTIES
COMP
MW
TC
PC
ZC
C7+
206.
895.1
302.6
.3121
C1
X
X
X
X
DJK
C7+
CO2
.15
N2
.12
C2
.01
C3
.01
ENDEOS
ACENTRIC
.8643
X
OMEGAA
X
.48521
OMEGAB
X
.08261
ACENTRIC
.8643
X
OMEGAA
X
.48521
OMEGAB
X
.08261
An equivalent set of data is as follows:

EOS
PR
COMPONENTS
CO2 N2 C1 C2 C3 NC4 NC5 NC6 C15
PROPERTIES
COMP
MW
TC
PC
ZC
C15
206.
895.1
302.6
.3121
C1
X
X
X
X
ENDEOS
R2003.4 - Landmark
2-23
2.12 Output File for PVT Properties (PVTFILE)

The user may direct DESKTOP-PVT to write a disk file which contains all
information necessary for PVT calculations in VIP-EXECUTIVE. This
information consists of component names, component critical properties,
and equation-of-state parameters. The data is written in a form that is
syntactically correct for use in VIP-ENCORE. The keyword PVTFILE must
be included following the ENDEOS card to invoke the writing of this PVT
information.
PVTFILE
Example:
To specify the writing of PVT information, enter the following sequence of
data:
EOS
PR
.
.
.
ENDEOS
PVTFILE
2-24
Landmark - R2003.4
2.13 Output File for K-values (KVFILE)

The user may direct DESKTOP-PVT to write a disk file which contains Kvalue tables for use in VIP-ENCORE. The keyword KVFILE must be
included following the ENDEOS card and before the first laboratory data
to invoke the writing of K-value tables. Data written to this file will be
syntactically correct for input into VIP-ENCORE from isothermal tests and
into VIP-THERM from thermal tests. Only one occurrence of KVFILE is
required to produce this file for all constant volume expansion tests,
differential expansion tests, separator tests and distillation tests.
KVFILE
Example:
To specify the writing of K-value tables, enter the following sequence of
data:
EOS
PR
.
.
.
ENDEOS
KVFILE
2.14 Selection of Water in Oil Option (WINOIL)

Water may be allowed to partition into the oil phase in the Multiple
Contact Steam Vaporization Test (MCSVAP), Steam Distillation Test
(STMDIS), and the Saturation Pressure with Water Calculation (PSATW).
In all of these tests, water is an implicitly defined component and, for VIPTHERM applications, should not be defined as a component by the user in
the component properties data. Other tests are not affected by the selection
of this option.
WINOIL
R2003.4 - Landmark
2-25
2.15 Thermal Option (THERMAL)

This option allows user input of binary interaction coefficients DJK
between implicitly defined component H2O and user-defined
components. These interaction coefficients are pertinent only to the Steam
Distillation Test (STMDIS), Multiple Contact Steam Vaporization Test
(MCSVAP), and Saturation Pressure with Water Calculation (PSATW).
This option also causes the PVTFILE option to write EOS data in the
format required for direct input into VIP-THERM.
THERMAL
NOTE:
2-26
Only PR equation of state is allowed with THERMAL option.
Landmark - R2003.4
Table 2-1: Component Properties Data - Pure Compounds

Critical Properties
Tc, F
Pc, psia
Zc
1 4. 3
cm
g
P , ------------------------1 2.
s
mol
Tb, F
Component
M. W.
H2O
18.015
705.2
3198.8
.2295
.3210
0.0
212.0
CO2
44.010
87.9
1070.9
.2742
.2225
49.6
-109.3
0.815
-0.1009
H2S
34.076
212.7
1036.0
.2660
.0920
80.1
-76.6
0.801
-0.1141
N2
28.013
-232.4
493.0
.2910
.0372
35.0
-320.4
0.300
-0.1740
C1
16.043
-116.6
667.8
.2890
.0126
71.0
-258.7
0.300
-0.1546
C2
30.070
90.1
707.8
.2850
.0978
111.0
-127.5
0.356
-0.0740
C3
44.097
206.0
616.3
.2810
.1541
151.0
-43.7
0.508
-0.0603
NC4
58.124
305.7
550.7
.2740
.2015
191.
31.1
0.584
-0.0675
IC4
58.124
275.0
529.1
.2830
.1840
191.0
10.9
0.563
-0.0798
NC5
72.151
385.7
488.6
.2620
.2524
231.0
96.9
0.631
-0.0369
IC5
72.151
369.1
490.4
.2730
.2286
231.0
82.1
0.625
-0.0640
NC6
86.178
453.7
436.9
.2640
.2998
271.0
155.7
0.664
-0.0036
NC7
100.210
512.8
396.8
.2630
.3498
321.6
209.2
0.688
0.0178
NC8
114.230
564.2
360.6
.2590
.3981
362.3
258.2
0.707
0.0455
NC9
128.260
610.7
332.0
.2510
.4452
403.0
303.5
0.722
0.0642
NC10
142.290
652.1
304.0
.2470
.4904
443.6
345.5
0.734
0.0919
NC11
156.300
690.0
285.0
.2410
.5349
484.3
384.6
0.744
0.0996
NC12
170.330
725.2
264.0
.2360
.5622
525.0
421.3
0.753
0.1245
NC13
184.350
756.7
250.0
.2390
.6231
565.6
455.8
0.760
0.1268
NC14
198.380
785.7
235.0
.2330
.6797
606.3
488.3
0.767
0.1402
NC15
212.410
812.5
220.0
.2290
.7060
647.0
519.1
0.772
0.1594
NC16
226.430
837.3
206.0
.2260
.7418
687.0
548.2
0.777
0.1801
NC17
240.460
860.4
191.0
.2160
.7699
728.3
575.9
0.782
0.2111
NC18
254.480
881.8
176.0
.2200
.7895
767.0
602.1
0.786
0.2471
1.0
0.0
* Adjusted to fit the vapor pressure curve using the P-R equation.
R2003.4 - Landmark
2-27
Table 2-2: Component Properties - Heavy Fractions*

1 4. 3
cm
g
P , ------------------------1 2.
s
mol
Tb, F
.0298
271.0
147.0
0.685
-0.02197
.2718
.0350
311.0
197.5
0.722
0.00512
429.8
.3151
.0381
351.0
242.0
0.745
0.04473
625
402.0
.3636
.0407
391.0
288.0
0.764
0.06807
134
668
379.6
.4176
.0427
431.0
330.5
0.778
0.09752
C11
147
706
359.3
.4680
.0442
471.0
369.0
0.789
0.11954
C12
161
743
340.2
.5147
.0458
511.3
407.0
0.800
0.13568
C13
175
776
323.9
.5575
.0473
551.6
441.0
0.811
0.14247
C14
190
810
308.8
.5982
.0488
591.9
475.5
0.822
0.14923
C15
206
844
294.3
.6445
.0502
632.2
511.0
0.832
0.15776
C16
222
872
280.0
.6889
.0512
672.5
542.0
0.839
0.16026
C17
237
900
269.3
.7315
.0523
712.8
572.0
0.847
0.16594
C18
251
920
258.7
.7664
.0530
753.1
595.0
0.852
0.16303
C19
263
940
251.3
.8002
.0537
793.4
617.0
0.857
0.16712
C20
275
961
244.7
.8415
.0544
833.7
640.5
0.862
0.17537
C21
291
982
235.4
.8750
.0551
874.0
664.0
0.867
0.17208
C22
300
1001
232.1
.9261
.0558
914.3
686.0
0.872
0.18694
C23
312
1020
226.9
.9629
.0565
954.6
707.0
0.877
0.19180
C24
324
1037
221.6
1.0045
.0571
994.9
727.0
0.881
0.19568
C25
337
1055
216.2
1.0382
.0575
1035.2
747.0
0.885
0.19833
C26
349
1071
211.5
1.0804
.0581
1075.5
766.0
0.889
0.20126
C27
360
1087
207.8
1.1167
.0586
1115.8
784.0
0.893
0.20571
C28
372
1102
203.4
1.1583
.0591
1156.1
802.0
0.896
0.20884
C29
382
1114
200.0
1.1987
.0595
1196.4
817.0
0.899
0.21080
C30
394
1129
196.2
1.2325
.0599
1236.7
834.0
0.902
0.21344
C31
404
1143
193.7
1.2706
.0605
1277.0
850.0
0.906
0.21737
Component
M. W.
Critical Properties
Tc, F
Pc, psia
C6
84
463
C7
96
C8
djk
468.3
.2313
525
449.4
107
576
C9
121
C10
2-28
Landmark - R2003.4
Table 2-2: Component Properties - Heavy Fractions*

1 4. 3
g
cm
P , ------------------------1 2.
s
mol
Tb, F
.0609
1317.3
866.0
0.909
0.22009
1.3494
.0613
1357.6
881.0
0.912
0.22189
184.2
1.3901
.0616
1397.9
895.0
0.914
0.22272
1191
182.5
1.4284
.0620
1438.2
908.0
0.917
0.22689
456
1202
179.5
1.4718
.0623
1478.5
922.0
0.919
0.22819
C37
464
1213
178.1
1.4993
.0627
1518.8
934.0
0.922
0.23141
C38
475
1223
175.2
1.5423
.0630
1559.1
947.0
0.924
0.23137
C39
484
1233
173.2
1.5781
.0633
1599.4
959.0
0.926
0.23376
C40
495
1243
170.6
1.6237
.0635
1639.7
972.0
0.928
0.23418
C41
502
1252
169.4
1.6494
.0638
1680.0
982.0
0.930
0.23721
C42
512
1260
166.9
1.6927
.0640
1720.3
993.0
0.931
0.23732
C43
521
1269
165.2
1.7294
.0642
1760.6
1004.0
0.933
0.23856
C44
531
1279
163.2
1.7829
.0645
1800.9
1017.0
0.935
0.24117
C45
539
1287
161.8
1.8213
.0648
1841.2
1027.0
0.937
0.24247
Component
M. W.
Critical Properties
Tc, F
Pc, psia
C32
415
1156
190.5
1.3151
C33
426
1169
187.5
C34
437
1180
C35
445
C36
djk
* Pc, and acentric factor have been adjusted to fit the liquid density and boiling point data of Katz and Firoozabadi.[1]
R2003.4 - Landmark
2-29
Table 2-3: Binary Interaction Coefficients

H2O
CO2
H2S
N2
C1
C2
C3
H2O
.0
CO2
.0
.0
H2S
.0
.0
.0
N2
.0
.0
.0
.0
C1
.500
.150
.0
.120
.0
C2
.500
.150
.0
.120
.0
.0
C3
.480
.150
.0
.120
.0
.0
.0
NC4
.480
.150
.0
.120
.020
.010
.010
IC4
.480
.150
.0
.120
.020
.010
.010
NC5
.480
.150
.0
.120
.020
.010
.010
IC5
.480
.150
.0
.120
.020
.010
.010
NC6
.480
.150
.0
.120
.025
.010
.010
NC7
.480
.150
.0
.120
.025
.010
.010
NC8
.480
.150
.0
.120
.035
.010
.010
NC9
.480
.150
.0
.120
.035
.010
.010
NC10
.480
.150
.0
.120
.035
.010
.010
NC11
.480
.150
.0
.120
.0374
.010
.010
NC12
.480
.150
.0
.120
.0386
.010
.010
NC13
.480
.150
.0
.120
.0396
.010
.010
NC14
.480
.150
.0
.120
.0406
.010
.010
NC15
.480
.150
.0
.120
.0413
.010
.010
NC16
.480
.150
.0
.120
.0420
.010
.010
NC17
.480
.150
.0
.120
.0427
.010
.010
NC18
.480
.150
.0
.120
.0432
.010
.010
Note: All other binary interaction coefficients are zero, and djk = dkj.
2-30
Landmark - R2003.4
Table 2-4: Passut-Danner Ideal Gas State Enthalpy Coefficients BTU/LB-(R)n

COMPONENT
HO2
h i2 ( *10 )
h i3 ( *10 )
11
h i4 ( *10 )
h i1
854.01
0.45739
-0.52512
0.64594
-2.02760
2.36310
CO2
4.778
0.11443
1.01130
-0.26490
0.34706
-0.13140
H2S
-0.617
0.23858
-0.24460
0.41070
-1.30126
1.44852
N2
-0.934
0.25520
-0.17790
0.15890
-0.32203
0.15893
C1
-6.977
0.57170
-2.94312
4.23157
-15.26740
19.45261
C2
-0.021
0.26488
-0.25014
2.92334
-12.86050
18.22060
C3
-0.738
0.17260
0.94041
2.15543
-10.70986
15.92794
NC4
7.430
0.09857
2.69180
0.51820
-4.20139
6.56042
IC4
11.498
0.04668
3.34801
0.14423
-3.16420
5.42893
NC5
27.172
-0.00280
4.40073
-0.86287
0.81764
-0.19715
IC5
27.623
-0.03150
4.69884
-0.98282
1.02985
-0.29485
NC6
-7.391
0.22911
-0.81569
4.52784
-25.23180
47.48019
NC7
-0.066
0.18021
0.34729
3.21879
-18.36600
33.76939
NC8
1.120
0.17308
0.48810
3.05401
-17.36459
31.24831
NC9
1.720
0.16906
0.58126
2.92611
-16.55850
29.29610
NC10
-2.993
0.20335
-0.34904
4.07057
-23.06441
42.96899
NC11
28.070
-0.02384
4.60773
-0.99839
1.08415
-0.33120
NC12
26.211
-0.01852
4.53893
-0.96464
1.01393
-0.29660
NC13
26.977
-0.02293
4.59517
-0.99758
1.08351
-0.33090
NC14
26.507
-0.02205
4.58079
-0.99164
1.07126
-0.32540
NC15
26.748
-0.02411
4.60717
-1.00768
1.10447
-0.34150
NC16
26.194
-0.02282
4.59024
-1.00021
1.08912
-0.33390
NC17
26.162
-0.02356
4.59907
-1.00665
1.10307
-0.34076
NC18
25.976
-0.02362
4.59950
-1.00804
1.10587
-0.34205
R2003.4 - Landmark
15
h i5 ( *10 )
h i0
2-31
2-32
Landmark - R2003.4
Chapter
3
3.1 Introduction
DESKTOP-PVT can be used to simulate a variety of laboratory
procedures. The calculations can be entirely predictive or they can be
compared to experimental data. Any or all of the various laboratory
procedures can be simulated in an arbitrary sequence.
Fluid samples can vary in composition from one procedure to another,
and operating temperature can change. Multiple fluid samples can be
analyzed with a single laboratory procedure by sequentially simulating
the same procedure for each different sample.
The data set for each laboratory procedure is introduced by a unique code
word. Each data set follows its predecessor without any intervening data
cards. A card containing the code word END terminates data processing.
For each laboratory test in this section, the unit of measurement for
pressure and temperature may be optionally specified. The default
pressure unit is psia. The default temperature unit is degree Fahrenheit.
3.2 Gas Z-Factor (Z-FACTOR)

The z-factor for a mixture of gases is defined by the real gas law:
Z = PV
--------RT
where
Z is the gas compressibility factor, dimensionless,
P is pressure,
V is molar volume,
R is the gas law constant,
T is absolute temperature.
R2003.4 - Landmark
3-33
Any consistent set of units can be used for P, V, R, and T.

Z-FACTOR
COMPOSITION
y1 y2 . . .yn
F
C
TEMP t
repeat
R
K
PSIA
PSIG
KPA
KG C2
PRES
LB FT3
GM CC
(DEXP
p1 p2
. . .
pk
d1 d2
. . .
dk)
(WT
w1 w2 ... wk)
(WT
zf1 zf2 . . .
w1 w2 . . .
(WT
v1 v2
w1 w2
ZEXP
(VEXP
as
necessary
zfk)
wk)
. . . vk)
. . . wk)
Definitions:
3-34
yi
Mole fraction of component i. The number of values must equal the number of components
defined in the component properties data (Chapter 2).
A value of temperature in units specified by one

of the labels F, C, R, or K.
pk
A value of pressure in the units specified by one

of the labels PSIA, PSIG, KPA, or KG/C2.
zfk
The z-factor measured at a pressure of pk and a

temperature of t. Enter the alpha character X, if no
data is available. (Input optional.)
Landmark - R2003.4
dk
The gas density measured at a pressure of pk and

a temperature of t. The units are specified by one
of the labels LB/FT3 or GM/CC. Default is LB/
FT3. Enter the alpha character X if no data is
available. (Input optional.)
vk
The gas viscosity measured at a pressure of pk

and a temperature of t in the units of cp. Enter the
alpha character X if no data is available. (Input
optional)
wk
Weight factor for measured zfk, dk and vk. (Input

optional)
NOTE:
1.
If the number of values required on the COMPOSITION, PRES,

ZEXP, DEXP, or VEXP cards is too large to fit on one card,
additional cards may be used as necessary.
2. Assignment of Weight Factors for Nonlinear Regression:

Weight factors can be assigned to the z-factor, density and/or
viscosity measurements by inserting a card entry with the
keyword WT followed by a string of weights wk corresponding
to the number of measurements. The WT card should
immediately follow the ZEXP, DEXP, and/or VEXP entries.
By defaults, the weight factors for z-factor, density, and viscosity
are 1.
Example:
C --------------------------------------------------------------C CALCULATE Z-FACTOR OF ENRICHED METHANE
C --------------------------------------------------------------Z-FACTOR
COMPOSITION
.0047 .0070 .9363 .0358 .0102 .0021 .0019 .0006 .0006 .0008 0. 0.
TEMP 144 F
PRES PSIA 200
R2003.4 - Landmark
3-35
3.3 Liquid Density (LIQDEN)

The density of a liquid mixture is calculated as a function of its
LIQDEN
COMPOSITION
F
C
R
K
PRES
x1 x2 . . . xn
repeat
p1 p2 . . . pk
as
LB FT3
DEXP
GM CC
d 1 d 2 ...d k
(WT
w1 w2 . . . wk)
(WT
zf1 zf2 . . . zfk)

w1 w2 . . . wk)
(WT
v1 v2 . . . vk)
w1 w2 . . . wk)
(ZEXP
(VEXP
necessary
Definitions:
3-36
xi
Mole fraction of component i in the liquid. The

number of values must equal the total number of
components defined in the component properties
data (Chapter 2).

pk

dk
The liquid density measured at a pressure of pk

and a temperature of t. The units are specified by
one of the labels LB/FT3 or GM/CC. (Default is
LB/FT3). Enter the alpha character X, if no data is
available. (Input optional.)
zfk
The Z-factor measured at a pressure pk and a

temperature of t. Enter the alpha character X, if
no data is available. (Input optional.)
vk
The liquid viscosity measured at a pressure of pk

and a temperature of t in the units of cp. Enter the
alpha character X, if no data is available. (Input
optional)
Landmark - R2003.4
wk
NOTE:
Weight factor for measured dk, zfk, and vk.

(Input optional.)
1.

DEXP, ZEXP, and VEXP cards is to large to fit on one card,
additional cards may be added as necessary.
2.
Assignment of Weight Factors for Nonlinear Regression:

Weight factors can be assigned to the density, z-factor and/or
viscosity measurements by inserting a card entry with the
immediately follow the DEXP, ZEXP and/or VEXP entries.
By defaults, the weight factors for density, z-factor and viscosity
are 1.
Example:
C -----------------------C LIQUID DENSITY
C -----------------------LIQDEN
COMPOSITION .0584 .5043 .0965 .0875 .0589 .0295 .0229
0.044472 0.082646 0.014882
TEMP 276 F
PRES PSIG 6000 4375
DEXP .4924 .4530
R2003.4 - Landmark
3-37
3.4 Vapor Pressure (VP)

The vapor pressure of a pure component can be calculated as a function of
temperature. The component must be one of those defined in the
component properties data described in Chapter 2.
VP
COMPOSITION
x1 x2 . . . xn
TEMP
F
C
R
K
t1 t2 . . . tk
PEXP
PSIA
PSIG
KPA
KG C2
p1 p2
. . . pk
(WT
w1 w2
. . . wk)
w1 w2
. . . wk)
DNSAT
ZSAT
LB FT3 d d d
k
1 2
GM CC
z1 z2 zk
(WT
Definitions:
3-38
xi
Mole fraction of component i in the fluid. The

data (Chapter 2), but only one value can be nonzero.
tk

pk
The value of vapor pressure measured at a temperature tk. The units for pk are specified by one
of the labels PSIA, PSIG, KPA, or KG/C2. Enter
the alpha character X, if no data is available.
dk
Oil densities at tk and pk (lb/cu ft, LB/FT3) or

(gm/cc, GM/CC) if DNSAT is specified. This
option should be used for oil samples. (Input
optional)
Landmark - R2003.4
zk
Gas z-factor at tk and pk if ZSAT is specified. This

option should be used for gas samples. (Input
optional)
wk
Weight factors for measured pk and dk (or zk).

(Input optional)
NOTE:
1.
The vapor pressure calculation is not applicable to mixtures.
2.

Weight factors can be assigned to the saturation pressure and/or
density/z-factor measurements by inserting a card entry with the
immediately follow the PEXP and/or DNSAT/ZSAT entries.
By default, the weight factor for saturation pressures is 10 and for
density, z-factors the weight is 5.
Example:
C ------------------------------------------------------------C VAPOR PRESSURE CURVE FOR ETHANE
C ------------------------------------------------------------VP
COMPOSITION 1. 0.
TEMP F -70. -50. 000.
025.
050.
075.
100.
PEXP PSIA 20.
100.
250.
325.
450.
550. 700.
R2003.4 - Landmark
3-39
3.5 Saturation Pressure (PSAT)

The dewpoint or bubblepoint of a mixture is calculated as a function of
temperature.
PSAT
COMPOSITION
z1 z2 . . . zn
F
C
R
K
TEMP
BPEXP
DPEXP
t1 t2 . . . tk
PSIA
PSIG
KPA
KG C2
p1 p2 . . . pk
w 1 w 2 w k )
(WT
DNSAT
ZSAT
LB FT3
GM CC
d 1 d 2 ...d k
z 1 z ...z k
2
w 1 w 2 w k )
(WT
Definitions:
3-40
zi
Mole fraction of component i in the liquid. The

data (Chapter 2).
tk

BPEXP
The pressure values are bubble points.
DPEXP
The pressure values are dewpoints.
pk
The saturation pressure measured at a temperature of tk. The units for pk are specified by one of
the labels PSIA, PSIG, KPA, or KG/C2. A realistic
value should be entered even if no data is available, since it will be used as the starting value for
the saturation pressure iteration. A poor estimate
can cause convergence failure.
Landmark - R2003.4
dk

optional)
zk
Gas z-factors at tk and pk if ZSAT is specified.

This option should be used for gas samples.
(Input optional)
wk

(Input optional)
NOTE:

keyword WT followed by a string of weights wk corresponding to the
number of measurements. The WT card should immediately follow
the BPEXP/DPEXP and/or DNSAT/ZSAT entries.
Example:
C ------------------------------------------------------------C SATURATION PRESSURE CALCULATION
C ------------------------------------------------------------PSAT
COMPOSITION .0584 .5043 .0965 .0875 .0589 .0295 .0229
.109376 .020830 .011794
TEMP F 276
BPEXP PSIG 4375
WT 50
DNSAT GM/CC .453
R2003.4 - Landmark
3-41
3.6 Liquid and Vapor Viscosity (VISC)

Viscosities of either a liquid or a vapor are calculated as functions of
temperature and pressure, by default using the Lohrenz, Bray, and Clark
correlation [2]. This correlation was originally developed for use in
calculating liquid viscosities only, but it is extended to vapors for purposes
of consistency in compositional reservoir simulation. Fluid density and
critical volume are important parameters in this method.
VISC
(GAS)
COMPOSITION
TEMP t
F
C
R
K
PSIA
PSIG
KPA
KG C2
PRES
DEXP
z1 z2 . . . zn
p1 p2
. . . pk
LB FT3
GM CC
p 1 p 2 ...p k
(WT
w1
(WT
zf1 zf2 . . .zfk)

w1 w2 . . . wk)
(WT
v1
w1
(ZEXP
(VEXP
w2
v2
w2
. . . wk)
. . . vk)
. . . wk)
Definitions:
3-42
zi

data (Chapter 2).

pk

vk
The viscosity of the fluid measured at a pressure

of pk and a temperature of t in the unit of cp.
Enter the alpha character X, if no data is available.
Landmark - R2003.4
dk
The density of the fluid measured at a pressure of

pk and a temperature of t. The units are specified
by one of the labels LB/FT3 or GM/CC. Default
is LB/FT3. Enter the alpha character X, if no data
is available. (Input optional)
zfk
The z-factor if the fluid measured at a pressure of

pk and a temperature of t. Enter the alpha character X, if no data is available. (Input optional)
wk
Weight Factor for measured vk, dk and zfk.
GAS
Indicates that the fluid is a vapor rather than a

liquid. (This selection can affect the root selected
when the cubic equation of state is solved for
density).
NOTE:
1.

DEXP, ZEXP, or VEXP cards is too large to fit on one card,
additional cards may be added as necessary.
2.

Weight factors can be assigned to the viscosity, density and/or zfactor measurements by inserting a card entry with the keyword
WT followed by a string of weights wk corresponding to the
number of measurements. The WT card should immediately
follow the VEXP, DEXP and/or ZEXP entries.
By default, the weight factors for viscosity, density and/or zfactor are 1.
Example:
C ---------------------------------------------C OIL VISCOSITY CALCULATION
C ---------------------------------------------VISC
COMPOSITION .0091 .0016 .3647 .0967 .0695 .0144 .0393 .0144 .0141
.0433 .156876 .111391 .064633
TEMP 220 F
PRES PSIA 2620. 3000. 4000. 5000.
DEXP
.5986 .6035 .6155 .6268
VEXP
.1580 .1620 .1755 .1881
3.7 Constant Composition Expansion (CCEXP)

The constant composition expansion procedure starts with a fluid sample
at a pressure above the saturation pressure. Pressure is reduced in a
sequence of discrete steps until the saturation pressure is reached. After
each pressure reduction, the volume is measured and normalized relative
to the volume at the saturation pressure.
R2003.4 - Landmark
3-43
Pressure is then reduced below the saturation pressure in a further

sequence of discrete steps. After each pressure reduction the vapor-liquid
mixture is equilibrated. The total volume of the mixture is normalized
relative to the volume at the saturation pressure, and sometimes the
volume fraction of liquid is measured.
CCEXP
COMPOSITION
TEMP t
BUBPT
DEWPT
z1 z2 . . . zn
F
C
R
K
psat
PSIA
PSIG
KPA
KG C2
(WT w)
(ZPSAT zpsat
PRES
VREL
p1
p2
(WT
.
.
.
pk
v1
v2
w1
.
.
.
vk
(WT w))
SLIQ
XLIQ
s1
s2
w2
.
.
.
sk
ZG
(ZL)
(VISO) (VISG)
(DENO)
(DENG)
zg1
zg2
w3
.
.
.
zgk
(zl1)
(zk2)
(w4)
.
.
.
(zlk)
(viso1)
(viso2)
(w5)
.
.
.
(visok)
(deno1)
(deno2
(w7)
.
.
.
(denok)
(deng1)
(deng2)
(w8))
.
.
.
(dengk)
XCOMP
CMP 1 CMP 2 CMP i
x
x i1
11 x 21
( WT
w1 w2 wi )
x
x
x
1k
2k
ik
(visg1)
(visg2)
(w6)
.
.
.
(visgk)
YCOMP
CMP CMP CMP

1
2
i
y
y 21
y i1
11
y
y ik
1k y 2k
3-44
Landmark - R2003.4
Definitions:
R2003.4 - Landmark
zi
Mole fraction of component i in the mixture. The

data (Chapter 2).
The temperature of the fluid in units specified by

one of the labels F, C, R, or K.
psat
The saturation pressure of the fluid at temperature t. The label BUBPT or DEWPT indicates
whether the fluid has a bubblepoint or a dewpoint, and the pressure units are specified by one
pk
A pressure level at which the total volume of the

fluid was measured. Units are specified by the
units label on the BUBPT or DEWPT card.
vk
The total volume of the fluid mixture at pressure

pk divided by the volume measured at the saturation pressure. Enter the alpha label X if no data
is available at this pressure.
sk
The liquid volume measured at pressure pk,

divided by the total volume at the same pressure
if SLIQ is specified. If XLIQ is specified, sk is the
liquid volume measured at pressure pk, divided
by the total volume at saturation pressure. Enter
the alpha X if no data is available at this pressure.
zgk
The gas z-factor measured at pressure pk. Enter

the alpha label X if no data is available at this
pressure.
zlk
The oil z-factor measured at pressure pk. Enter

the alpha label X if no data is available at this
pressure.
visok
Oil viscosity (cp) measured at pk if VISO is specified. (Input optional)
visgk
Gas viscosity (cp) measured at pk if VISG is specified. (Input optional)
denok
Oil density (gm/cc) measured at pk if DENO is

specified. (Input optional)
dengk
Gas density (gm/cc) measured at pk if DENG is

Weight factors for psat and measured quantities

at each pressure entry pk. (Input optional)
3-45
CMPi
The alphametric label that identifies component

i. This must agree with the component names
defined in the component properties data.
xik
Mole fraction of component i in the oleic phase at

the expansion pressure pk. The number and
order of pressure steps must be the same as those
under the PRES keyword.
yik
Mole fraction of component i in the gaseous

phase at the expansion pressure pk. The number
and order of pressure steps must be the same as
those under the PRES keyword.
zpsat
Z-factor measured at psat.
NOTE:

A weight factor for psat can be specified by including the keyword
WT followed by the psat weight in the BUBPT/DEWPT entry.
Weight factors for the individual measured quantities at each
pressure entry pk can be specified by inserting a card following a
pressure entry, with the keyword WT followed by a string of weights
corresponding to the number of measurements.
By default, the weight factor for psat is 10 and for the measured
quantities at pk the weight is 1.
Example:
C ----------------------------------------------------------C CONSTANT COMPOSITION EXPANSION
C ----------------------------------------------------------CCEXP
COMPOS .5832 .1428 .0761 .0834 .0573 .0433 .0139
TEMP 190 F
DEWPT 4450 PSIG
PRES VREL SLIQ
ZG
5580
.9525
X
1.1899
5400
.9589
X
X
5000
.9737
X
X
4800
.9819
X
X
4600
.9916
X
X
4500
.9972
X
X
4420
1.0018
.4738
X
4388
1.0037
.5082
X
4339
1.0068
.5164
X
4300
1.0093
.5194
X
4180
1.0181
.5195
X
3993
1.0372
.5132
X
3780
1.0605
.5007
X
3490
1.1032
.4786
X
2998
1.2053
.4296
X
2505
1.3722
.3675
X
2000
1.6683
.2888
X
1485
2.2378
.2020
X
1058
3.1813
.1306
X
3-46
Landmark - R2003.4
3.8 Constant Volume Depletion (CVDEP)

The constant volume depletion begins with a fluid sample, usually a
condensate, at its saturation pressure at the temperature of interest. The
pressure is then reduced in a series of discrete steps by allowing the fluid
to expand. After each expansion, the PVT cell is equilibrated and then
returned to its original volume by withdrawing vapor at constant
pressure.
Data measured and reported at each pressure level usually includes the
+
composition of the produced gas, the molecular weight of the C 7 fraction,
the gas z-factor, the cumulative production of gas as a fraction of the gas
originally in place, and the fraction of the cell volume occupied by liquid
after returning to the original volume.
Black oil table data may be generated from a CVDEP test.
CVDEP
COMPOSITION
z1 z2 . . . zn
F
C
R
K
TEMP t
PSIA
PSIG
KPA
KG C2
BUBPT psat
DEWPT
(ZPSAT
PRES
CMP1
CMP2
.
(WT
.
CMPn
MW
R2003.4 - Landmark
zpsat
p1
y11
y21
.
w1
.
yn1
(WT
p2
y12
y22
.
w2
.
ya2
XCOMP
CMP 1 x 11 y 12
CMP 2 x 21 y 22
( WT
w1
w2
CMP n y n1 y n2
CMPm1
(WT w)
w))
. .
. .
. .
.
. .
.
. .
.
.
.
.
.
pk
y1k
y2k
.
wk)
.
yak
x 1k
x 2k
wk )
x nk
CMPm2 mw1
mw2 . . . mwk
3-47
ZS
zf1
zf2
. . .
zfk
(ZL
zl1
zl2
. . .
zlk)
VPROD
q1
q2
. . .
qk
SLIQ
s1
s2
. . .
sk
(VISO
viso1
viso2 . . . visok)
(VISG
visg1
visg2 . . . visgk)
(DENO
deno1
deno2 . . .
denok)
(WT
w1
w2
wk)
. . .
(
BOETAB
WHITSON
COATS
FIELD
BOUNIT METRIC
LAB
BOVISC
EXPERIMENTAL
CALCULATED
BOPSAT
bopsat1
bopsat2 .........bopsatk
BODP
bodp1
bodp2 ............bodpk
BOSEP
STAGE
TEMP PRES
VFRAC VDEST LFRAC LDEST
1
X
.
.
.
X
.
.
.
t1
X
.
.
.
X
.
.
.
p1
X
.
.
.
X
.
.
.
vf11
vf12
.
.
.
vf1m
.
.
.
vd11
vd12
.
.
.
vd1m
.
.
.
lf11 ld11
lf12 ld12
.
.
.
.
.
.
lf1m ld1m
.
.
.
.
.
.
n
X
.
.
.
X
tn
X
.
.
.
X
pn
X
.
.
.
X
vfn1
vfn2
.
.
.
vfnm
vdn1
vdn2
.
.
.
vdnm
lfn1 ldn1
lfn2 ldn2
.
.
.
.
.
.
lfnm ldnm
3-48
Landmark - R2003.4
Definitions:
R2003.4 - Landmark
zi

data (Chapter 2).

psat
whether the fluid has a bubblepoint or a dewpoint, and the pressure units are specified by one
pk
A pressure level at which the fluids were equilibrated and gas was withdrawn to maintain constant volume.
CMPn
The alphameric label that identifies component n.

This must agree with the component names
ynk
The mole fraction of component n in the gas mixture withdrawn from the PVT cell at pressure pk.
visok
Oil viscosity measured at pk if VISO is specified.

(Input optional)
visgk
Gas viscosity measured at pk if VISG is specified.

(Input optional)
denok
Oil density (gm/cc) at pk if DENO is specified.

(Input optional)

CMPm1
CMPm2
The component labels for the highest and lowest

molecular weight components in a group of components for which molecular weight is being
reported. Typically the molecular weight of the
fraction is reported. In this case CMPm1 would be
the name of the lowest molecular weight component in the heavy fraction, and CMPm2 would be
the name of the heaviest component in the mixture. If the heavy fraction is not split, enter the
same name for CMPm1 and CMPm2.
mwk
The average molecular weight for the group of

components CMPm1 - CMPm2, measured at a
pressure of pk.
3-49
3-50
zfk
The z-factor of the gas produced at a pressure of

pk.
qk
The cumulative gas produced after returning the

PVT cell to its original volume at a pressure of pk.
This is expressed as a mole fraction of the original
gas in the cell.
sk
The fraction of the PVT cell occupied by liquid

after returning it to its original volume at a pressure of pk.
zlk
The z-factor of liquid at a pressure of pk.
xnk
The mole fraction of component n in the liquid

mixture at a pressure of pk.
zpsat
BOETAB
Optional keyword indicating that black oil data

are to be generated.
WHITSON
Calculation algorithm selection. Either

WHITSON or COATS must be specified.
COATS
Calculation algorithm selection. Either

WHITSON or COATS must be specified.
FIELD
Output of black oil data in oilfield units.
METRIC
Output of black oil data in metric units.
LAB
Output of black oil data in laboratory units.
bopsatk
Saturation pressures at which black oil data are

generated.
bodpk
Pressure levels above saturation pressure at

which black oil data are generated
Temperature of separator stage n.
tn
Pressure of separator stage n.
pn
Separator stage pressure.
vfnm
Vapor fraction sent to output stream m of separator stage n.
vdnm
Destination of output stream m of separator stage

n. The destination can be either the number of a
later stage, or the GAS production line.
lfnm
Liquid fraction sent to output stream m of separator stage n.
Landmark - R2003.4
ldnm
Destination of output stream m of separator stage

n. The destination can be either the number of a
later stage, or the OIL production line.
A symbol indicating that the same stage number,

or pressure, or temperature is to be used from the
data of the preceding input line.
NOTE:
1.

A weight factor for psat can be specified by including the
keyword WT followed by the psat weight in the BUBPT/DEWPT
entry.
pressure pk can be specified by inserting a card following the
card for a measured quantity with the keyword WT followed by
a string of weights corresponding to the number of pressures.
2.
The keyword KILE may be entered to instruct the program to

write a table of K-values for use in VIP-ENCORE. KVFILE should
be entered after the EOS data and before the first laboratory data.
Only one occurrence of KVFILE is required to produce a file with
K-value tables for all constant volume expansion tests,
3.
The entire collection of BOETAB input data must either all be

present or all be absent.
4.
Each separator stage can have as many destinations as required

to define the stage, as long as the liquid fractions sum to 1, and
the vapor fractions sum to 1.
5.
The separator battery can have as many stages as desired.
6.
The keyword KVFILE may be entered to instruct the program to

differential expansion tests, separator tests, and distillation tests.
Data written to this file from constant volume depletion tests will
be syntactically correct for input into VIP-ENCORE.
Example:
C
C -------------------------------------------------C CONSTANT VOLUME DEPLETION
C -------------------------------------------------CVDEP
R2003.4 - Landmark
3-51
COMPOSITION .0011 .6893 .0864 .0534 .0348 .0178 .0173

0.064447 0.020473 0.010029 0.004951
TEMP 256 F
DEWPT 6010 PSIG
PRES
.6010 .5000 4000
.3000 .2100 .1200 .0700
C1
.6893 .7069 .7360 .7660 .7777 .7704 .7513
C2
.0864 .0868 .0873 .0883 .0897 .0938 .0983
C3
.0534 .0526 .0520 .0516 .0516 .0544 .0590
C6
.0173 .0148 .0125 .0108 .0101 .0107 .0125
MW C8 C34
158
146
134
123
115
110
109
ZGAS
1.1401 .015
.897
.853
.865
.902
.938
VPROD
0.
.06624 .17478 .32927 .49901 .68146 .77902
SLIQ
0.
.0780 .2130 .2500 .2440 .2250 .2100
C----------------------------------------------------------C Black oil table generation
C----------------------------------------------------------BOETAB WHITSON
BOUNIT FIELD
BOVISC EXPERIMENTAL
BOPSAT 500. 1000. 2000. 2200. 3000. 4000.
BODP 0. 500.
BOSEP
STAGE TEMPPRES VFRAC VDEST LFRACLDEST
1
100. 500. 1. GAS
1.
2
2
60. 100. 0.5 GAS
1.
3
X
X
X 0.5 3
0.
OIL
3
60. 0. 1.0 GAS
1.
OIL
3-52
Landmark - R2003.4
3.9 Swelling Test (SWELL)

The swelling test begins with a fluid sample, usually a liquid, at its
saturation pressure at the temperature of interest. A lean vapor is then
injected into the fluid sample in a series of discrete stages, causing an
elevation of saturation pressure. In the case of a liquid sample the fluid
may switch from a bubblepoint to a dewpoint between two stages,
spanning a critical mixture.
Data measured and reported at the end of each stage includes the
saturation pressure of the new mixture, the type of fluid (dewpoint or
bubblepoint), and the volume of the saturated mixture relative to the
saturated volume of the original sample.
SWELL
COMPOSITION
YINJ
TEMP
z1 z2 . . . zn
y1 y2 . . . yn
F
C
R
K
PSIA
PSIG
KPA
KG C2
ZINJ
zz1
zz2
.
(WT
.
.
zzk
VREL
v1
v2
.
w1
.
.
vk
PSAT
TYPE
p1 DEWPT or BUBPT
p2 DEWPT or BUBPT
.
.
w2)
.
.
.
.
pk DEWPT or BUBPT
Definitions:
R2003.4 - Landmark
zi

data (Chapter 2).
yi
Mole fraction of component i in the injection gas.

The number of values must equal the total number of components.

3-53
zzk
Moles of injection gas in the mixture divided by

the total number of moles in the mixture at the
end of any stage.
vk
The volume of the saturated mixture at the end of

any stage divided by the saturated volume of the
original mixture.
pk
The saturation pressure of the mixture at the end

of any stage. The units of pressure we specified
by one of the labels PSIA, PSIG, KPA, or KG/C2.
DEWPT
Indicates that the saturation pressure reported is

a dewpoint.
BUBPT
Indicates that the saturation pressure reported is

a bubblepoint.
Weight factors for vk and pk. (Input optional)
NOTE:

Weight factors for vk and pk of a swollen mixture can be specified by
inserting a card following a mixture input, with the keyword WT
followed by a string of weights corresponding to the number of
measurements.
By default, the weight factor for pk is 1.5 and for vk the weight is 1.
Example:
C ------------------------C SWELLING TEST
C ------------------------SWELL
COMPOSITION .679300.099000 .110800 .045000 .052966 .011941 .000993
YINJ .9468.0527.00050 0 0 0
TEMP 200 F
PSIG
ZINJ
VREL
PSAT
TYPE
0
1.0
3428
DEWPT
.1271 1.1224 3635
DEWPT
.3046 1.3542 4015
DEWPT
.5384 1.9248 4610
DEWPT
.6538 2.5043 4880
DEWPT
3.10 Differential Expansion (DIFF)

The differential expansion begins with an oil sample at its saturation
pressure at the temperature of interest. The pressure is then reduced in a
series of discrete steps by allowing the fluid to expand. After each
expansion, the PVT cell is allowed to equilibrate and then all evolved gas
is removed from the cell at constant pressure.
3-54
Landmark - R2003.4
It is recommended that all differential liberation test data be entered into

the programs up to and including the flash at standard pressure and
reservoir temperature, and the flash to standard temperature and
pressure. If these data are not input, the program will perform a flash at
these last two conditions anyways.
Data measured and reported at each pressure level usually includes the
solution gas-oil ratio, relative oil volume, oil density, z-factor of the
withdrawn gas, and gravity of the withdrawn gas.
DIFF
COMPOSITION
TEMP t
z1 z2 . . . zn
F
C
R
K
BUBPT psat
PSIA
PSIG
KPA
KG C2
(WT
w)
(ZPSAT zpsat
(WT w))
(BOPSAT bopsat (WT w))
(RSPSAT rspsat (WT w))
(TSTD
tstd)
(PSTD
pstd)
(METRIC)
PRES
BO
pk
.
(WT
.
.
pn
bok
.
w1
.
.
bon
RESV
RESSOL
rsk
.
w2
.
.
rsn
ZG
zgk
.
w3
.
.
zgn
VISO
VISG
DENO
GRVG
vok
.
w4
.
.
von
vgk
.
w5
.
.
vgn
dok
.
w6
.
.
don
gk
.
w7)
.
.
gn
Definitions:
R2003.4 - Landmark
zi
The mole fraction of component i in the oil sample.

3-55
3-56
psat
The saturation pressure of the fluid at temperature t. The label BUBPT indicates the fluid must
be a liquid at reservoir conditions. The pressure
units are specified by one of the labels PSIA,
PSIG, KPA, or KG/C2.
tstd
Standard temperature in units specified on TEMP

entry. Default is 60 F. (Input optional)
pstd
Standard pressure in units specified on BUBPT

entry. Default is 14.7 psia. (Input optional)
METRIC
The METRIC keyword causes gas-oil ratio values

to be printed in metric units of SCM/STCM
rather than the (default) English units of SCF/
STB. (Input optional)
pk
A pressure level at which the fluids were equilibrated and gas withdrawn, in same units as psat.
bok
Relative oil volume, barrels of oil at indicated

pressure, pk, per barrel of residual oil at 60 F.
rsk
Gas-oil ratio, cubic feet of gas at standard pressure and 60 F per barrel of residual oil at 60 F. If
RSEV is entered, rsk refers to cumulative gas that
has evolved. If RSSOL is entered, rsk refers to gas
that is still in solution.
zgk
The z-factor of the gas produced at pressure pk.
vok
The oil phase viscosity (cp) measured at pressure

pk.
vgk
The gas phase viscosity (cp) measured at pressure pk.
dok
The oil phase density (gm/cc) at pressure pk.
gk
The gravity of gas withdrawn at pressure pk.

zpsat
bopsat
Relative oil volume at psat, barrels of oil at psat

per barrel of residual oil at 60 F.
rspsat
Gas-oil ratio, cubic feet of gas in solution (corrected to standard conditions) at the begining of
differential expansion per barrel of residual oil at
60 F.
Landmark - R2003.4
NOTE:
1.

A weight factor for psat can be specified by including the
keyword WT followed by the psat weight in the BUBPT entry.
pressure pk can be specified by inserting a card following a
pressure entry, with the keyword WT followed by a string of
weights corresponding to the number of measurements.
2.

Data written to this file from differential expansion test will be
syntactically correct for input into VIP-ENCORE.
Example:
C ----------------------------------------C DIFFERENTIAL EXPANSION
C ----------------------------------------DIFF
COMPOSITION .0091 .0016 .3647 .0967 .0695 .0144 .0393 .0144 .0141
.0433 .156876 .111391 .064633
TEMP 220 F
BUBPT 2620 PSIG
PRES
BO
RSSOL ZG
VISO
VISG
DENO
GRVG
2620
1.600 854
0.00X .373
X
.6562 .00X
2350
1.554 763
0.846 .396
X
.6655 .825
2100
1.515 684
0.851 .417
X
.6731 .818
1850
1.479 612
0.859 .442
X
.6808 .797
1600
1.445 544
0.872 .469
X
.6889 .791
1350
1.412 479
0.887 .502
X
.6969 .794
1100
1.382 416
0.903 .542
X
.7044 .809
850
1.351 354
0.922 .592
X
.7121 .831
600
1.320 292
0.941 .654
X
.7198 .881
350
1.283 223
0.965 .738
X
.7291 .988
159
1.244 157
0.984 .855
X
.7382 1.231
000
1.075
0
X 1.286
X
.7892 2.039
R2003.4 - Landmark
3-57
3.11 Multiple Contact Vaporization Test (MCVAP)

The multiple contact vaporization test begins with an oil sample at a given
pressure and temperature. The multiple contact vaporization test can
perform either a gas-cycling process (default) or an oil-cycling process. In
a gas-cycling process, gas will be injected into oil in a series of steps at
constant pressure. By default, this process is differential, in that all gas is
removed at the end of each contact step. The user may choose not to
remove any gas by entering CCOMP, indicating a constant composition
process. An oil-cycling process is selected with the keyword OILCYCLE.
In an oil-cycling process, after an initial contact of injected gas with oil, the
remaining oil is removed from the cell. For subsequent steps, the original
oil is added to the gas phase left from the previous step. The user may
request additional composition output for each step in either process by
defining three pseudo components, typically light components,
intermediate components, and heavy components. In this way, ternary
diagrams can easily be constructed to follow the mechanism of miscible
processes. The definition of the pseudo components is identical to the
definition of pseudo components in the PSEUDO function.
Data which is calculated at each step of the test include moles of gas (or
oil) removed, gas (or oil) z-factor, and liquid fraction. Required user input
includes the saturation pressure and composition of the fluid sample, the
composition of the injected gas (or oil), and the number of moles of gas (or
oil) added at each contact step.
MCVAP
COMPOSITION
z1
z2 . . . zn
YINJ
y1
y2 . . .yn
(OILCYCLE)
(CCOMP)
F
C
R
K
TEMP t
BUBPT psat
PRES
3-58
PSIA
PSIG
KPA
KG C2
(WT
w)
Landmark - R2003.4
PSEUDO
PCMP 1 one or more of CMP i
ENDCMP
ADD
ak
.
(WT
.
.
.
an
REM
rk
.
w1
.
.
.
rn
ZG
zgk
.
w2
.
.
.
zgn
SLIQ
sk
.
w3)
.
.
.
sn
Definitions:
R2003.4 - Landmark
zi
The mole fraction of component i in the oil sample.
yi
The mole fraction of component i in the injection

gas fluid.
OILCYCLE
Keyword that indicates oil cycling process.
CCOMP
Keyword that indicates constant composition

process.

psat
The saturation pressure of the fluid at temperature t. The fluid must be a liquid at reservoir conditions. The pressure units are specified by one of
the labels PSIA, PSIG, KPA, or KG/C2.
The pressure level of the multiple contact vaporization test in the same units as psat.
PSEUDO
Keyword that indicates pseudo components are

specified.
PCMPi
An alphanumeric label that identifies pseudo

component i. (Exactly three components are
required.)
CMPi
An alphanumeric label that identifies component

i of the original fluid system. This must agree
with one of the component names defined in the
component properties data.
3-59
ENDCMP
Keyword that terminates the reading of the

pseudo components.
ak
The moles of gas (or oil) added at contact step k.
rk
The moles of gas (or oil) removed after equilibration at contact step k.
zgk
The z-factor of the gas removed at contact step k.
sk
The liquid volume fraction before gas removed at

contact step k.

at each contact step. (Optional)
NOTE:

A weight factor for psat can be specified by including the keyword
WT followed by the psat weight in the BUBPT entry.
Weight factors for the individual measured quantities at each contact
step can be specified by inserting a card following the contact entry,
with the keyword WT followed by a string of weights corresponding
to the number of measurements.
quantities at each contact step the weight is 1.
Example:
C ------------------------------------------------------C MULTIPLE CONTACT VAPORIZATION
C ------------------------------------------------------MCVAP
COMPOSITION
.0022.0266.3324.0678.0643.0574.0430.0453.0538.0336.0378.1296.1062
YINJ
.0104.0014.6900.1219.0875.0495.0209.0000.0184 4*0.000
TEMP 256
BUBPT 2514.7
PRES 4514.7
ADD
REM ZG SLIQ
.5
X X X
.5
X X X
.5
X X X
.5
X X X
.5
X X X
.5
X X X
.5
X X X
3-60
Landmark - R2003.4
3.12 Phase Envelope Calculation (ENVELOPE)

The phase envelope calculation consists of a series of bubblepoint and
dewpoint calculations to delineate the boundary of the two-phase region.
The calculation may be performed for both oil and gas fluid systems and
requires minimal user data input.
The convergence of the saturation pressure calculations using an equation
of state is dependent upon the starting value of pressure at a given
temperature. As a result, data which define starting values for pressure
and temperature must be specified. These starting values are defined by
specifying a range of pressure and temperature for both the upper and
lower portions of the phase envelope. The program will perform a
saturation pressure calculation for each of the temperatures specified in
this range, trying specified starting values for pressure until a calculation
converges. The critical point of the fluid system can easily be estimated by
noting the change in saturation pressure type from bubblepoint to
dewpoint.
ENVELOPE
COMPOSITION
z1 z2 . . . zn
TEMP
F
C
R
K
tu1 tu2 tuinc tl1 tl2 tlinc
PSAT
PSIA
PSIG
KPA
KG C2
pu1 pu2 puinc pl1 pl2 plinc
Definitions:
R2003.4 - Landmark
zi
The mole fraction of component i in the oil or gas

sample.
tu1
The lowest temperature to calculate saturation

pressure for the upper portion of the phase envelope. The temperature units are specified by one
tu2
The highest temperature to calculate saturation

pressure for the upper portion of the phase envelope. The temperature units are specified by one
3-61
tuinc
The increment to use in selecting temperature

values from tu1 to tu2 for the upper phase boundary.
pu1
The lowest pressure to initialize the saturation

pressure calculation for the upper portion of the
phase envelope. The pressure units are specified
pu2
The highest pressure to initialize the saturation

pressure calculation for the upper portion of the
puinc
The increment to use in selecting pressure values

from pu1 to pu2 for the upper phase boundary.
tl1
The lowest temperature to calculate saturation

pressure for the lower portion of the phase envelope. The temperature units are specified by one
tl2
The highest temperature to calculate saturation

pressure for the lower portion of the phase envelope. The temperature units are specified by one
tlinc
The increment to use in selecting temperature

values from tl1 to tl2 for the lower phase boundary.
pl1
The lowest pressure to initialize the saturation

pressure calculation for the lower portion of the
pl2
The highest pressure to initialize the saturation

pressure calculation for the lower portion of the
plinc
The increment to use in selecting pressure values

from pl1 to pl2 for the lower phase boundary.
Example:
The data which follows instructs the program to build a phase envelope
for an oil system. The upper portion of the envelope will be found by
using temperatures every 20 degrees from -100 to 800F, and starting initial
3-62
Landmark - R2003.4
pressure values of 2000, 4000, and 6000 psig. The lower portion of the
envelope will be found by using temperatures every 20 degrees from 600
to 800F, and starting initial pressure values of 100, 200, and 300 psig.
C ---------------------------C PHASE ENVELOPE
C ---------------------------ENVELOPE
COMPOSITION .0584 .5043 .0965 .0875
.0445 .0826 .0149
TEMP F
-100
0800
020
600
PSAT PSIG
2000
6000
2000
100
.0589
.0295
800
300
020
100
.0229
3.13 Enthalpy Calculation (ENTHV or ENTHL)

The enthalpy of a gas or liquid mixture is calculated as a function of its
ENTHV (or ENTHL)
z1 z2 ... zn
COMPOSITION
TEMP
F
C
R
K
PSIA
PSIG
KPA
KG C2
PRES
HEXP
KBTU LBMOLE
J GMOLE
(WT
DEXP
ZEXP
LB FT3
GM CC
(WT
repeat
p1 p2 ... pk
h 1 h 2 h k
as
necessary
w1 w2 ... wk)
d 1 d 2 d k
w1 w2 ... wk)
Definitions:
R2003.4 - Landmark
ENTHV
Calculate gas enthalpy.
ENTHL
Calculate liquid enthalpy.
3-63
zi

data (Chapter 2).
A value of temperature in the units specified by

one of the labels F, C, R or K.
pk

of the labels PSIA, PSIG, KPA and KG/C2.
hk
The enthalpy of the fluid measured at a pressure

of pk and a temperature of t in the units specified
by one of the labels KBTU/LBMOLE or J/
KGMOLE. Enter the alpha character X, if no data
is available. (Input optional)
dk
The liquid density, if DEXP is specified, or z-factor, if ZEXP is specified, of the fluid measured at
a pressure of pk and a temperature of t. The units
for density are specified by one of the labels LB/
FT3 or GM/CC. Enter the alpha character X, if no
data is available. (Input optional)
wk
Weight factors for measured hk and dk. (Input

optional)
NOTE:

Weight factors can be assigned to the enthalpy and/or density/zfactor measurements by inserting a card entry with the keyword WT
followed by a string of weights wk corresponding to the number of
measurements. The WT card should immediately follow the HEXP
and/or DEXP/ZEXP entries.
By defaults, the weight factors for both enthalpy and density/z-factor
are 1.
Example:
C ----------------------------------------------C GAS ENTHALPY CALCULATION
C ----------------------------------------------C
ENTHV
COMPOSITION
1.0
0.0
C
TEMP 450F
PRES PSIA
10.0
110.0
210.0
310.0 410.0 422.17
HEXP KBTU/L
22.750
22.538 22.303 22.037 21.733 21.693
ZEXP
0.9960 0.9671
0.9356 0.9007 0.8615 0.8564
3-64
Landmark - R2003.4
3.14 Liquid Water Properties (WATPRP)

The liquid water properties of density, enthalpy, viscosity and fugacity
coefficient are calculated as a function of pressure and temperature.
WATPRP
PRES
p1
p2
.
.
.
pk
TEMP
t1
t2
.
.
.
tk
Definitions:
pk
A value of pressure in the units of PSIA.
tk
A value of temperature in the units of F.
Example:
C ------------------------------------------C LIQUID WATER PROPERTIES
C ------------------------------------------C
WATPRP
PRES
TEMP
0029.82
250.
0066.97
300.
0422.20
450.
1541.80
600.
0460.00
450.
0610.00
450.
1510.00
450.
1535.00
450.
1510.00
455.
R2003.4 - Landmark
3-65
3.15 Saturation Pressure with Water (PSATW)

The bubble point pressure of oil in the presence of water is calculated as a
function of temperature.
If the water in oil option (Section 2.14) has been selected, then the bubble
point pressure may also be a function of the amount of water present (only
if the oil is undersaturated with water). For this option, the composition
card specifies the water-free oil composition. The ZWAT card specifies the
overall water mole fraction in the water/oil system.
Water is an implicitly defined component and should not be defined as a
component in the component properties data (Chapter 2). The only water
properties which may be adjusted by the user are the H2O/component
binary interaction coefficients (DJK).
PSATW
COMPOSITION
TEMP
z1 z2 ... zn
F
C
R
K
t1 t2 ... tk
ZWAT
zw1 zw2 ... zwk
BPEXP
DNSAT
ZSAT
PSIA
PSIG
KPA
KG C2
p1 p2 ... pk
(WT
w1 w2 ... wk)
LB FT3
GM CC
d1 d2
z1 z2
(WT
d k
z k
w1 w2 ... wk)
Definitions:
zi
3-66
Water-free mole fraction of component i in the

oil. The number of values must equal the total
number of components defined in the component
properties data (Chapter 2).
Landmark - R2003.4
zwk
Overall water mole fraction in the water/oil system for measurment k.
tk

zwk
The overall water mole fraction in the water/oil

system fraction. Ignored if water in oil option is
not selected.
pk
The saturation pressure measured at a temperature of tk. The units for pk are specified by one of
the labels PSIA, PSIG, KPA, or KG/C2. A realistic
value should be entered even if no data is available, since it will be used as the starting value for
the saturation pressure iteration. A poor estimate
can cause convergence failure.
dk

optional)
zk
Gas z-factors at tk and pk if ZSAT is specified.

This option should be used for gas samples.
(Input optional)
wk

(Input optional)
NOTE:

keyword WT followed by a string of weights wk corresponding to the
number of measurements. The WT card should immediately follow
the BPEXP and/or DNSAT/ZSAT entries.
Example:
PSATW
COMPOSITION
TEMP
ZWAT
BPEXP
WT
DNSAT
R2003.4 - Landmark
F
PSIG
GM/CC
.0584
.0229
276
0.0
4375
50
0.453
.5043
.109376
.0965
.0875
.0489 .0295
.020830 .011794 .01
3-67
3.16 Distillation Test (DISTIL)

A laboratory distillation test can be calculated as a prediction or through
regression where experimental data is matched. The data required to
define this procedure is described as follows.
DISTIL
COMPOSITION
PRES
pres
TZERO tzero
TS
ts
F
C
R
K
z2
PSIA
PSIG
KPA
KG C2
(WT
TEMP
WFRAC
VFRAC
n1(=1)
t1
(WT
t2
(WT
.
.
.
ti
vfrac1
w1)
vfrac2
w2)
.
.
.
vfraci
.
.
.
ni
(TINC
MW
(WT
MW
(WT
...
zn
w)
PS
ps
n2(=2)
3-68
z1
tinc)
CRUDE CMP1
CMP2
mwc
cmp1
cmp2
w)
RESID CMP1
CMP2
N
mwr n1 cmp1 n cmp2 n
n1
1
1
w2)
.
.
.
.
.
.
.
.
.
.
.
.
mwr n2 cmp1 n cmp2 n
n2
2
2
Landmark - R2003.4
WFRAC CRUDE CMP1 CMP2
wfrac cmp1 cmp2
w)
( WT
API CRUDE
apic
w)
( WT
API RESID N
apir 1 n 1
( WT w 1 )
apir 2 n 2
( WT w 2 )
.
.
.
.
.
.
apir i n i
API DIST NDFRAC N1 N2
apid
ndfrac 1 n1 1 n2 1
1
( WT w 1 )
apid
ndfrac 2 n1 2 n2 2
2
( WT w 2 )
.
.
.
.
.
.
.
.
.
.
.
.
apid
ndfrac k n1 k n2 k
k
KVTBS
NDFRAC KVALUE
.
.
.
.
.
.
ndfrac
K
K
K
k
1, k
2, k
n, k
(WT
wt
wt
wt
1, k
2, k
n, k )
(WTC wtc 1, k wtc 2, k wtc n, k
.
.
.
.
.
.
R2003.4 - Landmark
3-69
BLEND
WFRAC
CRUDE
RESID
WFRAC
VFRAC
nblend
vfcrude
DIST
NDFRAC
VFRAC
n
i1
vfres
WFRAC
ndfrac
k1
vfdis
( WT
nblend
vfcrude
i2
vfres
ndfrac
k2
vfdis
nblend
vfcrude
VMIN
vmin
VCRUDE
TEMP
VDIST
t1
p1
visc 1
( WT )
( w1 )
t2
p2
visc 2
( w2 )
PRES VISC
tm
pm
visc m
(wm )
.
VRESID
ij
t1
p1
visc 1
( WT )
( w2 )
n1
t2
p2
visc 2
( w2 )
n1
tm
visc m
(wm)
TEMP PRES
VISC
ndfrac k
t1
p1
( WT )
visc 1 ( w 1 )
ndfrac k
t2
p2
visc 2
NDFRAC TEMP PRES
vfres
ndfrac
kj
vfdis
tm
pm
visc m
(wm)
nblend j
t1
p1
( WT )
visc 1 ( w 1 )
nblend j
t2
p2
visc 2
VISC
( w2 )
nblend j
tm
pm
visc m
(wm)
apib
( w2 )
VISC
ndfrac k
apib
w
n1
VBLEND NBLEND TEMP PRES
3-70
apib
w
( WT
API
VFRAC
Landmark - R2003.4
Definitions:
R2003.4 - Landmark
zi

data (Chapter 2).
pres
The operating pressure in the units specified by

one of the labels PSIA, PSIG, KPA, and KG/CM2.
Default is 14.7 psia. (Input optional)
tzero
The boiling point temperature (temperature at

zero volume fraction distillate) in the units specified by one of the labels F, C, R, and K.
ts
Standard temperature in the units specified on

TZERO entry. Default is 60 F. (Input optional)
ps
Standard pressure in the units specified on PRES

entry. Default is 14.7 psia. (Input optional.)
ni
Data entry number for distillation curve, must

increase consecutively in VFRAC data.
ti
The temperature at point ni on distillation curve

with the units specified on TZERO entry.
vfraci
The volume fraction distillate at point ni on distillation curve if VFRAC is specified (equal to volume distilled divided by initial oil volume, all
volumes measured at standard conditions). If
WFRAC is specified, vfraci is the distillate weight
fraction at point ni on distillation curve (equal to
weight distilled divided by initial oil weight).
tinc
The temperature increment used in stepping

through distillation curve, in the units specified
on TZERO entry. Default is 5 F. (Input optional)
cmp1, cmp2
The component labels for the highest and lowest

molecular weight components in a group of components for which molecular weight is being
reported.
wfrac
The weight fraction for the group of components

cmp1 - cmp2 in the original crude. (Input
optional)
mwc

components cmp1 - cmp2 in the original crude.
(Input optional)
3-71
3-72
mwrn1

components cmp1 - cmp2 at point ni on distillation curve. (Input optional)
apic
API gravity of original crude. (Input optional)
apiri
API gravity of residue at point ni on distillation

curve. (Input optional)
apidk
API gravity of distillate fraction ndfrack. (Input

optional)
ndfrack
Distillate fraction number. (Input optional)
n1k, n2k
Data point numbers on distillate curve which

define distillate fraction number ndfrack. The
distillate fraction defined by n1k, n2k is the distillate obtained from temperature tn1kto temperature tn2k. If n1k is set to 0, the distillate is
obtained from tzero to tn2k. If n1k is set to -1, the
distillate includes all distillate fractions at temperatures less than tn2k. (Input optional)
KVTBS
Alpha label indicating the measured component

K-values are to follow. (Input optional)
NDFRAC
KVALUE
Alpha label indicating the following is for distillate component K-value. (Input optional)
Kn,k
Distillate K-value for component n and distillate

fraction number ndfrack. (Input optional)
wtn,k
Weight factor for the measured K-value, Kn,k.

(Input optional) This weight factor is applied to
the residual of equation-of-state computed kvalue and measured k-value. To accomodate the
large variation in component K-values, the logarithm of the K-values are used in computing the
residual.
wtcn,k
Weight factor for the measured K-value, Kn,k.

(Input optional) This weight factor is applied
only to the residual of correlation computed Kvalue and measured K-value. To accomodate the
large variation in component K-values, the logarithm of the K-values are used in computing the
residual.
nblendj
Blend number. (Input optional)
Landmark - R2003.4
vfcrudej
Volume fraction of original crude in nblendj, if

VFRAC is specified. If WFRAC is specified,
vfcrudej is the weight fraction of the original
crude in nblendj. (Input optional)
vfresj
Volume fraction of residue from point ni on distillation curve in nblendj, if VFRAC is specified.
If WFRAC is specified, vfresj is the weight fraction of the residue from point ni on distillation
curve in nblendj. (Input optional)
vfdisj
Volume fraction of distillate fraction ndfrack in

nblendj if VFRAC is specified. If WFRAC is specified, vfdisj is the weight fraction of the distillate
fraction ndfrack in nblendj. (Input optional)
apibj
API gravity of nblendj. (Input optional)
Weight factor for the measured data. (Input

optional)
vmin
The limiting viscosity (cp) as temperature

approaches infinity. The default value is 0.2.
This value is used only in plotting the viscosity
data in the form of
ln ( ln ( + 1 vmin ) ) = A + B ln ( T )
where T is absolute temperature.
R2003.4 - Landmark
VCRUDE
Alpha label indicating the measured viscosities

(cp) of original crude are to follow. (Input
optional) If one of the Twu viscosity correlations
is selected, a viscosity data file named "visc.log"
will be generated. This file will contain computed component viscosities at the temperatures
specified in the crude viscosity table. The format
of the voscosity data in the file is syntactically
correct for input into VIP-THERM.
VRESID

(cp) of residue are to follow. (Input Optional)
VDIST

(cp) of distillate are to follow. (Input Optional)
VBLEND

(cp) of blend are to follow. (Input Optional)
tm
Temperature of the measured viscosity. The units

are the same as those specified in the TZERO
entry.
3-73
pm
Pressure of the measured viscosity. The units are

the same as those specified in the PRES entry.
viscm
Measured viscosity (cp) at tm and pm.
NOTE:
1.
A weight factor for tzero can be specified by including the

keyword WT followed by the tzero weight in the TZERO
entry.
Weight factors for all other measured quantities can be
specified by inserting a card following the measured data
input, with the keyword WT followed by a weight.
By default, the weight factor for tzero is 2 and for all other
measured quantities is 1.
2. The keyword KVFILE may be entered to instruct the
program to write a table of K-value for use in VIP-THERM.
KVFILE should be entered after the EOS data and before
the first laboratory data.
Only on occurrence of KVFILE is required to produce a file
with K-value tables for all constant volume expansion tests,
differential expansion tests, separator test, and distillation
tests.
The format of the K-value table from distillation tests is
syntactically correct for input into VIP-THERM. The table
of K-value generated from distillation tests is the distillate
K-values.
The user must enter the keyword KVFILE as described
previously, and specify the distillate number in order to generate
the K-value table file.
Example:
C -----------------------------C DISTILLATION TEST
C -----------------------------C
DISTIL
COMPOSITION .19927.61835.18238
TZERO
515.
F
N
TEMP
VFRAC
1
548
.021
2
564
.035
3
581
.056
4
586
.066
5
602
.075
6
612
.093
7
631
.111
8
650
.136
3-74
Landmark - R2003.4
9
668
10
696
11
708
API CRUDE
11.5
API RESID
10.58
9.80
8.50
API DIST NDFRAC
27.83
1
24.63
2
21.27
3
BLEND CRUDE
1
2
.162
.188
.213
N
3
7
11
N1
N2
1
3
4
7
8
11
VFRAC RESIDN
.98
0
.96
0
VFRAC DIST NDFRAC VFRAC API

0.
1
.02
11.80
0.
1
.04
12.12
Example:
DISTIL
COMPOSITION
0.234391 0.444724 0.250463 0.070421
PRES
0.0
PSIG
TZERO
299.9
F
C
N
TEMP
WFRAC
1
300.0
0.0000
2
400.0
0.0081
3
500.0
0.0394
4
600.0
0.1190
5
700.0
0.2197
6
800.0
0.3862
7
900.0
0.4688
8 1027.0
0.6511
C
API CRUDE
12.6
API RESID
N
3.9
8
API DIST NDFRAC
N1
N2
36.0
1
1
2
30.7
2
2
3
25.6
3
3
4
20.5
4
4
5
15.6
5
5
6
14.4
6
6
7
12.3
7
7
8
C
C -----------------C DISTILLATE K-VALUE
C -----------------C
KVTBS
NDFRAC
KVALUE
3
0.1437896E+02 0.3973139E+00 0.1687528E-02 0.4442320E-12
4
0.6741022E+02 0.1413388E+01 0.1898595E-01 0.4679788E-09
C
C -------------C VISCOSITY DATA
C -------------C
VMIN
0.2
VCRUDE
TEMP
PRES
VISC
102.63
0.0
2446.00
334.70
0.0
14.96
540.30
0.0
2.26
VRESID
N
TEMP
PRES
VISC
8
334.7
0.0
491.5
8
540.3
0.0
31.3
VDIST
NDFRAC
TEMP
PRES
VISC
3
102.63
0.0
6.50
3
334.70
0.0
1.55
3
540.30
0.0
1.18
R2003.4 - Landmark
3-75
4
4
4
102.63
334.70
540.30
0.0
0.0
0.0
18.77
1.81
1.23
3.17 Complete Phase Envelope Calculation (ENVPT)

The boundary of the two-phase region and the quality lines inside the
two-phase region are calculated in a complete phase envelope. The quality
lines can be specified as either liquid mole fraction or liquid volume
fraction. The step-size for temperature and pressure are adjusted
automatically so the computation can be performed in an efficient manner
while giving a clear picture of the phase envelope.
ENVPT
COMPOSITION
z1 z2 . . . zn
TEMP
F
C
R
K
TEMP
PSIA
PSIG
KPA
KG C2
LIQMF
LIQSAT
t min
l1
t inc
t max
P min
l2
P max
P inc
l k
Definitions:
3-76
zi
The mole fraction of component i in the oil or gas

sample.
tmin
The lowest temperature to calculate equilibrium

pressure. The units are specified by one of the
labels F, C, R, or K. (Input optional, default is 0
F.)
tmax
The highest temperature to calculate equilibrium

pressure. (Input optional, default is 800 F.)
tinc
The maximum temperature increment allowed.

(Input optional, default is 25 F.)
Landmark - R2003.4
pmin
The lowest pressure to calculate equilibrium temperature, and to initialize equilibrium pressure
calculation. The units are specified by one of the
labels PSIA, PSIG, KPA, or KG/C2. (Input
optional, default is 14.7 psia.)
pmax
The highest pressure to calculate equilibrium

temperature, and to initialize equilibrium pressure calculation. (Input optional, default is 8014.7
psia.)
pinc
The maximum pressure increment allowed.

(Input optional, default is 250 psia.)
lk
Liquid mole fraction if LIQMF is specified, or liquid volume fraction if LIQSAT is specified. (Input
optional, defaults are 0.0, 0.25, 0.5, 0.75, and 1.0.)
Example:
C
---------------------------C
PHASE ENVELOPE
C
---------------------------C
ENVPT
COMPOSITION 0.0618
0.0541 0.8170
0.0066 0.0030
C
TEMP
F
-200
0200
020
PRES PSIA
0014.7
3014.7 200
LIQSAT
0000.0
0000.01 001.0
C
R2003.4 - Landmark
0.0375
0.0023
0.0094
0.0083
3-77
3.18 Composition Variations with Depth (ZGRAD)

Considerable variations of hydrocarbon composition with depth have
been observed in several near critical reservoirs. In the top part of the
reservoir, the compositions are such that the fluid is classified as a gas
condensate. The heavy component composition increases as a function of
depth so that the fluid would be classified as a volatile oil at the bottom of
the reservoir. At some depth in the reservoir, the fluid would change
classification from gas to oil, but there is no classical gas-oil contact and no
two-phase region. This is because the hydrocarbon compositions are
always at temperatures and pressures that do not cross the equilibrium
two-phase envelope.
The composition variations of hydrocarbon fluids in an isothermal
reservoir are predicted in this test. We assume that the fluid has reached
the stationary state and no two-phase region exists in the reservoir. Only
the fluid component fugacities and gravity forces are considered in
calculating the composition variations. In addition to the tabular report, a
file named "zgrad.log" is written at the end of calculation. This file
contains the composition information that can be exported directly to VIPCOMP.
3-78
Landmark - R2003.4
ZGRAD
COMPOSITION
TEMPI
PRESI
z1 z2 . . . zn
tref
F
C
R
K
perf
PSIA
PSIG
KPA
KG C2
BUBPT
DEWPT
psat
FT
M
DEPTHI dref
DEPTH
DEPMIN
dmin
d1
DEPMAX
dmax
ZCOMP
d1
cm p 1
z 11
z 12 z 1n
cm p 2
z 21
z 22 z 2n
(WT
w1
w2
wn)
cm p m
d2
d2
dn
DEPINC
dinc
dn
z m1 z m2 z mn
NEWTON
SS
(KNTMXZ
(kntmx
DPMXZ
dpmx
(DSTMIN
(dstmn
DSTMAX
dstep
DBUGZ
R2003.4 - Landmark
DXMXZ
dxmx
TOLPZ
tolp
TOLXZ
tolx
TOLZ)
told)
DSTFAC)
dcut)
ON
OFF
3-79
Definitions:
zi
The hydrocarbon composition at the reference

depth in mole fraction. The number of values
must equal the total number of components
defined in the component properties data (Chapter 2).
tref
The reservoir temperature in units specified by

pref
The reservoir pressure at the reference depth. The

pressure units are specified by one of the labels
PSIA, PSIG, KPA, or KG/C2.
psat
The measured saturation pressure at the reference depth. The label BUBPT or DEWPT indicates whether the fluid has a bubblepoint or a
dewpoint. The units are the same as those specified in pref.
dref
The reference depth where composition, temperature, pressure and saturation pressure are measured. The depth units are specified by one of the
labels FT or M.
dn or dmin,
dmax, dinc
Two options are available to specify the depths

where compositions are calculated. If the keyword DEPTH is entered, then the numerical values of depth are entered directly. If the keyword
DEPMIN, DEPMAX and DEPINC are entered,
the depths are computed by specifying the minimum (dmin), the maximum (dmax) and the increment (dinc) of depth. the depths are positive
downward.
cmpm

defined in the component properties data. (Input
optional)
zmn
Overall mole fraction of component m at the

depth entry dn. (Input optional)
wn
Weight factors for the measured overall mole

fractions. The default value is 1. (Input optional)
NEWTON
SS
Two calculation methods are available. (Input

optional)
NEWTON Newton-Raphson method (Default)
SS
3-80
Successive-substitution method
Landmark - R2003.4
R2003.4 - Landmark
kntmx
The maximum number of iterations allowed to

compute composition at a depth. Default is 40.
(Input optional)
dpmx
The maximum change in pressure for an iteration. Default is 10. (Input optional)
dxmx
The maximum change in composition for an iteration. Default is 0.01. (Input optional)
tolp
Convergence tolerance for pressure change

between iterations. Default is 0.01. (Input
optional)
tolx
Convergence tolerance for compositional change

between iterations. Default is 0.00001. (Input
optional)
told
Convergence tolerance for the damping factor of

the pressure and composition changes between
iterations. The composition calculation will fail if
the computed damping factor is less than the tolerance. Default is 0.001. (Input optional)
dstmn
The minimum depth interval allowed in the composition calculation. If the computed depth interval is less than this minimum value, the
calculation will be reported as a failure. Default is
1. (Input optional)
dstep
The maximum depth interval allowed in the

composition calculation. If the user specified
depth interval is greater than this value, the compositions at additional intermediate depth interval between the user specified depths. Default is
100. (Input optional)
dcut
The factor for reducing the size of depth interval

when a composition calculation fails. If the composition calculation which failed was of size of
D, the next intermediate composition calculation will be of size D times this factor. Default is
0.2. (Input optional)
DBUGZ
The user may request additional output of composition calculation by turning on the debug output option. (Input optional)
ON
Activate printing of detailed calculation output.
OFF
Deactivate printing of detailed calculation output. (Default)
3-81
Example:
ZGRAD
COMPOSITION
TEMPI
PRESI
DEWPT
DEPTHI
DEPMIN
8000.0
3-82
0.780000
150.0
3400.0
3150.0
10300.0
DEPMAX
13000.0
0.140000
F
PSIA
0.080000
FT
DEPINC
200.0
Landmark - R2003.4
3.19 Properties of Carbon Dioxide Saturated Water (CO2TAB)

Properties of carbon dioxide saturated water are calculated using
correlations in this test. The correlations are shown in Section 2.9. These
properties include carbon dioxide solubility, formation volume factor,
compressibility and viscosity.
In addition to the tabular report, a file named "co2tab.log" is written at the
end of calculation. This file contains the properties of carbon dioxide
saturated water that can be exported directly to VIP-COMP.
CO2TAB
SALINITY
WT%
PPM
F
TEMP
C
R
K
PSIA
PRES
KPA
PSAT
p1
p2
.
.
(WT
.
.
pk
RSWCO2
rsw1
rsw2
.
.
w1
.
.
rswk
BWCO2
bw1
bw2
.
.
w2
.
.
bwk
CWCO2
cw1
cw2
.
.
w3
.
.
cwk
VWCO2
vw1
vw2
.
.
w4)
.
.
vwk
Definitions:
R2003.4 - Landmark
Salinity of brine in the units specified by the one of

the label WT% (weight percent of solid) or PPM
(part per million of solid).
The temperature at which all data were measured.

The units of temperature is specified by one of the
labels F, C, R, or K.
PRES
A keyword for specifying pressure units in PSIA or

KPA.
pk
A pressure stage at which water properties are

measured. The pressures must be entered in
decreasing order.
3-83
rswk
Solubility of carbon dioxide in water. The units are

scf/stb if the pressure units are PSIA and are scm/
stcm if the pressure units are KPA.
bwk
Formation volume factor of carbon dioxide

saturated water. The units are rb/stb if the pressure
units are PSIA and are cm/stcm if the pressure
units are KPA.
cwk
Compressibility of carbon dioxide saturated water.

The units are inverse of pressure units.
vwk
Viscosity of carbon dioxide saturated water in cp.
Weight factor for the measured data. Default is 1.
Example:
CO2TAB
SALINITY
TEMP
PRES
PSAT
6000.0
5000.0
4500.0
4000.0
3500.0
3000.0
2500.0
2000.0
1500.0
1000.0
500.0
14.7
3-84
7.5 WT%
121
F
PSIA
RSWCO2
150.1
145.2
142.8
140.4
137.6
134.3
129.9
123.3
112.7
94.5
61.8
0.0
BWCO2
1.046
1.045
1.045
1.044
1.044
1.043
1.042
1.040
1.038
1.034
1.027
1.013
CWCO2
0.232E-05
0.236E-05
0.240E-05
0.245E-05
0.249E-05
0.253E-05
0.257E-05
0.262E-05
0.266E-05
0.270E-05
0.274E-05
0.278E-05
VWCO2
0.650
0.647
0.646
0.645
0.644
0.643
0.642
0.641
0.640
0.639
0.638
0.637
Landmark - R2003.4
3.20 Multiple Contact Steam Vaporization Test (MCSVAP)

NOTE:
The Steam Distillation Test (STMDIS) is no longer updated, since for

heavy oils it is not an equilibrium process and should not be used to
characterize fluids for use in VIP-THERM, which assumes
equilibrium (a good assumption on the pore scale). However,
STMDIS simulation capability has not been removed from
DESKTOP-PVT.
A multiple contact steam vaporization test can be calculated as a

prediction or through regression where experimental data is matched.
This stepwise batch experiment is shown schematically below.
PGk
Vk
POk
PWk
Fk
Separator @ Ts, Ps
Vk,SGk
Lk,SOk
Wk,SWk
PVT Cell @ Tk, Pk
with volume VOLk
A specified initial amount of oil, LI, and optionally a specified initial

amount of water, WI, are charged to the PVT cell. For each contact k, a
specified amount of water (or steam), Fk is injected into the PVT cell and
the fluids are brought to equlibrium at temperature Tk and pressure Pk
with total cell volume VOLk such that a vapor phase is formed. A liquid
water phase may or may not be formed. The amount of vapor phase
formed at equilibrium, Vk, and the equilibrium phase saturations SGk,
SOk, and SWk are measured. Then, the vapor phase is completely
displaced from the PVT cell and is flashed to standard conditions, and
produced amounts of gas, oil and water phases (PGk, POk, and PWk,
respectively) are measured. The initial amounts of oil (LI), water (WI) and
the amounts of streams Fk, Vk, PGk, POk and PWk may be expressed in
mass (default), volumetric, or molar units. For the volumetric unit option,
LI is defined as ccs oil at standard conditions, WI and Fk are defined as ccs
H2O cwe (cold water equivalent), Vk is defined as ccs vapor phase at PVT
cell conditions, and PGk, POk, and PWk are defiend as ccs of gas, oil and
water, respectively, at standard conditions. For cases in which the initial
oil is saturated at standard conditions, the volumetric unit option should
not be used. This condition is not checked by the program.
R2003.4 - Landmark
3-85
Optionally, oil viscosities of the initial oil (crude) and of the PVT cell oil
and the produced oil for any contact may also be calculated as predictions
or through regression to match experimental data. Care should be taken
to insure that the specified temperatures and pressures at which
viscosities are to be calculated correspond to undersaturated conditions
for the relevant fluid composition. This is not checked by the program.
The program utilizes rigorous three phase flash algorithms for equilbrium
calculations both in the PVT cell and the separator. For most heavy oils,
the fluid in separator will be an undersaturated oil/water mixture (no
produced gas). If this condition is detected by calculation of the bubble
point, the separator flash calculation is of course bypassed. Water is
allowed to partition into the oil phase in all equilibrium/bubble point
calculations if the WINOIL option has been selected (Section 2.14).
Normally, H2O should not be defined as a component by the user. H2O is
defined implicitly and is treated by the equation of state as a component in
the gas and (optionally) oil phases with fixed properties which are
consistent with those used in VIP-THERM. The only properties associated
with H2O which may be modified by the user are the DKJ binaries.
MCSVAP
COMPOSITION z1 z2 ... zn
TUNIT
PUNIT
SUNIT
TS PS
API
(LI
(WI
ts ps
C
R
K
C2
MOLES
PSIA
PSIA
KPA
KG
G
CC
api
li)
wi)
TEMP PRES F VOL

p1
f1 vol1
t1
(WT
wtvol1
wtapi1)
t2
...
(WT ...)
.
3-86
V
ZG
ZO
SO
SW
XW
YW
PO
PG PW
API
v1
zg1
zo1
so1
sw1
xw1
yw1 po1 pg1 pw1 api1
wtv1 wtzq1 wtzo1 wtso1 wtsw1 wtxw1 wtyw1 wtpo1 wtpg1wtpw1
Landmark - R2003.4
.
.
tn
(WT
...
...)
(VMIN
vmin)
VCRUDE TEMP PRES VISC
VOC
VOP
visc
( WT )
( wt )
TEMP PRES VISC
visc
TEMP PRES VISC
visc
( WT )
( wt )
( WT )
( wt )
Definitions:
zi
Mole fraction of component i in the initial fluid LI.

The number of values must equal the total number of
components defined in the component properties data
(Chapter 2).
TUNIT
Alpha label indicating that the following alpha string

defines the temperature unit. Optional, default unit is
degress F.
PUNIT

defines the pressure unit. Optional, default unit is
psia.
SUNIT

defines the stream unit (G, CC, or MOLES). Optional,
default unit is G (grams). For CC unit, stream units
are:
LI
R2003.4 - Landmark
- ccs initial oil at Ts Ps.
3-87
WI
- ccs initial H2O cwe (cold water

equivalent).
Fk
- ccs H2O cwe.
Vk
- ccs vapor at Tk, Pk.
PO, PG, PW
- ccs produced phase at Ts, Ps.
The MOLES unit is LB moles.
3-88
ts
Standard temperature in the units specified on the

TUNIT card. Optional, default is 60F.
ps
Standard pressure in the units specified on the PUNIT

card. Optional, default is 14.7 psia.
api
API gravity of the initial oil. Use only if initial oil is

undersaturated.
li
Initial amount of oil in PVT cell in units specified on

SUNIT card. Optional, default is 100g, 100ccs, or 0.001
LB moles.
wi
Initial amount of water in PVT cell in units specified

on SUNIT card (grams, ccs cwe, or moles). Optional,
default is 0.
Temperature for contact k or for visocisty measurement in units specified on TUNIT card. Required.
Pressure for contact k or for viscosity measurement in

units specified on PUNIT card. Required.
fk
Amount of H2O injected into cell on contact k in units

specified by SUNIT card (for CC, ccs cold water equilvalent). Required.
volk
Total cell volume for contact k at equilbrium after

injection of H2O, ccs. Input optional.
vk
Amount of equilibrium vapor formed on contact k

and then withdrawn in units specified on SUNIT card
(for CC, ccs vapor at tk, pk). Input optional.
zgk
Z-factor of equilibrium vapor formed on contact k.

Input optional.
zok
Z-factor of equilibrium cell oil for contact k. Input

optional.
sok
PVT cell oil saturation at equilibrium on contact k

(before withdrawal of vapor), fraction. Input optional.
swk
PVT cell liquid water saturation at equilibrium on

contact k (before withdrawal of vapor), fraction. Input
optional.
Landmark - R2003.4
xwk
Mole fraction H2O in the PVT cell oil. Ignored if water

in oil option is not selected. Input optional.
ywk
Mole fraction H2O in the PVT cell vapor. Input

optional.
pok
Amount of produced oil at ts, ps in units specified on

SUNIT card (grams, LB moles, or ccs). Input optional.
pgk
Amount of produced gas at ts, ps for contact k in units

specified on SUNIT card (grams, LB moles, or ccs).
Input optional.
pwk
Amount of liquid water produced at ts, ps for contact

k in units specified on SUNIT card (grams, LB moles,
or ccs). Input optional.
apik
API gravity of produced oil for contact k. Input

optional.
vmin
Minimum value of viscosity used for plotting viscosity vs. temperature data on logarithmic scale:
ln ( ln ( + 1 min ) ) = F ( ln ( T ) )
Optional, default is 0.2. Internally reset to 0 if any
input or calculated viscosity value is less than vmin.
VCRUDE
Alpha label designating viscosity table for initial oil.
VOC
Alpha label designating viscosity table for PVT cell oil.
VOP
Alpha label designating viscosity table for produced

oil.
Contact number for cell oil and produced oil viscosity

data.
visc
Measured viscosity values in viscosity tables, cp.
wt
Weight factors for measured values used in regression.
NOTE:
R2003.4 - Landmark
Optional data items in the table must be specified as a number,

specified as zero, or specified with the alpha label X. The table
header must appear as shown (do not eliminate columns for data not
specified.)
3-89
3.21 Two Phase Isothermal Flash

FL2I
COMPOSITION
z1 z2 . . . zn
TEMP t
F
C
R
K
PRES
PSIA
PSIG
KPA
KG C2
PRES
p1
p2
(WT
.
.
.
pk
(MLIQ) (ZG)
XLIQ
(l1)
(zg1)
(l2)
(zg2)
(w1)
(w2)
.
.
.
.
.
.
(lk)
(zgk)
(ZL)
(VISO)
(VISG)
(zl1)
(zl2)
(w3)
.
.
.
(zlk)
(viso1)
(viso2)
(w4)
.
.
.
(visok)
(visg1)
(visg2)
(w5)
.
.
.
.
.
.
(visgk)
XCOMP
CMP 1 CMP 2 CMP i
x
x i1
11 x 21
( WT
w1 w2 wi )
x
x
x
1k
2k
ik
(DENO)
(DENG)
(deno1) (deng1)
(deno2) (deng2)
(w6)
(w7)
)
.
.
.
.
.
.
(denok) (dengk)
YCOMP
CMP CMP CMP

1
2
i
y
y i1
11 y 21
y
y ik
1k y 2k
3-90
Landmark - R2003.4
Definitions:
R2003.4 - Landmark
zi

data (Chapter 2).

pk
A pressure level at which the flash is to be performed. Units are set with the PRES keyword.
MLIQk
The liquid volume fraction measured of the fluid

mixture at pressure pk. (Input optional)
zgk
The gas z-factor measured at pressure pk. (Input

optional)
zlk
The oil z-factor measured at pressure pk. (Input

optional)
visok
Oil viscosity (cp) measured at pk if VISO is specified. (Input optional)
visgk
Gas viscosity (cp) measured at pk if VISG is specified. (Input optional)
denok
Oil density (gm/cc) measured at pk if DENO is

dengk
Gas density (gm/cc) measured at pk if DENG is


CMPi

xik
Mole fraction of component i in the oleic phase at

the expansion pressure pk. The number and
order of pressure steps must be the same as those
under the PRES keyword.
yik
Mole fraction of component i in the gaseous

phase at the expansion pressure pk. The number
and order of pressure steps must be the same as
those under the PRES keyword.
3-91
NOTE:

pressure entry pk can be specified by inserting a card following a
pressure entry, with the keyword WT followed by a string of weights
corresponding to the number of measurements.
By default, the weight factor for the measured quantities at pk is 1.
Example:
C ----------------------------------------------------------C TWO PHASE ISOTHERMAL FLASH
C ----------------------------------------------------------FL2I RUN1
COMPOSITION
.5832 .1428 .0761 .0834 .0573 .0433 .0139
TEMP 190 F
PRES PSIG
PRES
5580
5400
5000
3-92
Landmark - R2003.4
Chapter
4
4.1 Introduction
DESKTOP-PVT can be used to model the behavior of multistage surface
separation facilities. The calculations can be entirely predictive, or they
can be compared to experimental data. For any specified separator
configuration it is possible to predict behavior for a variety of feed
streams.
4.2 Separator Conditions Data (SEPARATOR)

Each separator battery may contain an arbitrary number of stages. Each
stage contains one feed stream and two output streams, one vapor and one
liquid. Each of the two output streams can itself be split into two streams,
each of which may be fed to (1) any downstream separator stage, (2) the
gas sales line or (3) the oil sales line.
SEPARATOR
ibat
F
C
R
K
PSIA
PSIG
KPA
KG C2
(label card)
STAGE
TEMP
(type 1 data)
n
tn
(type 2 data)
X
X
COMPOSITION z1 z2 . . . zk
PRES
pn
X
VFRAC VDEST LFRAC LDEST

vfn1
vdn1
lfn1
ldn1
vfn2
vdn2
lfn2
ldn2
(METRIC)
Definitions:
R2003.4 - Landmark
ibat
The separator battery number.
The separator stage number. Values range

from 1 to the total number of stages.
tn
The operating temperature of separator stage

n in units indicated by one of the labels F, C,
R, or K.
4-95
pn
The operating pressure of separator stage n in

units indicated by one of the labels PSIA,
PSIG, KPA, or KG/CM2.
vfni
This fraction of the vapor stream leaving separator stage n will be sent to the destination
indicated by vdn1. Values must lie in the
range of 0-1. If vfn1 is less than 1.0, then a
type 2 data card must be provided for this
stage.
vdn1
Defines the destination of the first vapor

stream leaving stage n. Alternatives include a
downstream separator stage and the gas sales
line.
vdn1
m (m is a stage number)
GAS (alpha label)
lfn1
This fraction of the liquid stream leaving separator stage n will be sent to the destination
indicated by ldn1. Values must lie in the range
0-1. If lfn1 is less than 1.0, then a type 2 data
card must be provided for this stage.
ldn1
Defines the destination of the first liquid

downstream separator stage and the oil sales
line.
ldn1
4-96
m (m is a stage number)
OIL (alpha label)
An alpha label that must be entered in the

first three locations on a type 2 data card.
vfn2
This fraction of the vapor stream leaving separator stage n will be sent to the destination
indicated by vdn2. The values of vfn1 and vfn2
must sum to exactly 1.0.
vdn2
Defines the destination of the second vapor

downstream separator stage and the gas sales
line.
lfn2
This fraction of the liquid stream leaving separator stage n will be sent to the destination
indicated by ldn2. The values of lfn1 and lfn2
must sum exactly to 1.0.
Landmark - R2003.4
ldn2
Defines the destination of the second liquid

downstream separator stage and the oil sales
line.
zi
The mole fraction of component i in the feed

to the first stage of the separator battery.
METRIC
The METRIC keyword causes output units to

be printed in metric units instead of English
units (optional).
NOTE:
1.
If all values necessary to define a single feed composition will not

fit on one card, an additional card(s) may be used. Multiple feed
compositions can be modeled by entering additional
COMPOSITION data cards without redefining the separator
conditions.
2. Stock tank conditions should be entered as the last stage of

separation in order to obtain the stock tank liquid volume.
3.
If no units are specified, pressure is in psia and temperature is in

degree Fahrenheit. If a unit specification is made, it must be made
for both pressure and temperature.
Example:
C -------------------------------------------------------C SEPARATOR TEST (NO REGRESSION)
C -------------------------------------------------------SEPARATOR 1 F PSIG
STAGE TEMP
PRES
VFRAC
VDEST
LFRAC
LDEST
1
75.
450.
1.
GAS
1.
2
2
75.
100.
1.
GAS
1.
3
3
75.
0.
1.
GAS
1.
OIL
COMPOSITION .0011 .6893 .0864 .0534 .0348 .0178 .0173
0.064447 0.020473 0.010029 0.004951
4.3 Separator Test with Regression (SEP)

A laboratory separator test may be calculated by DESKTOP-PVT as a
prediction, or through regression where experimental data is matched.
Optionally, the user may enter equation-of-state parameters for either
reservoir calculations or surface calculations, or both. The data must be
entered immediately following the composition data. If reservoir
parameters are entered, calculations of saturation pressure and oil volume
at reservoir conditions will be performed using these parameters, even in
a regression run that modifies these parameters. Therefore, a regression to
match surface separation data may be performed honoring the reservoir
data. Likewise, entering surface equation-of-state parameters will force all
surface calculations to use the input parameters.
R2003.4 - Landmark
4-97
The data required to define this procedure is described as follows.
4-98
Landmark - R2003.4
SEP
COMPOSITION
z1 z2 . . . znc
OMEGA
a 1 a 2 a nc
OMEGB
b
b
1
2
nc
OMEGAS 1
a1
a 2 a nc
OMEGAS 2
a1
a 2 a nc
OMEGAS n
a1
a 2 a nc
OMEGBS 1
b1
b 2 b nc
OMEGBS 2
b1
b 2 b nc
OMEGBS n
b1
b 2 b nc
TEMP
F
C
R
K
BUBPT
DEWPT
PSIA
PSIG
KPA
KG C2
psat
(METRIC)
DNSAT d
ZSAT z
LB FT3
GM CC
(TSTD tstd)
(PSTD pstd)
BO
BG
bo
b g
(WT
w)
(API api) (WT w)

(GORT gort) (WT w)
R2003.4 - Landmark
4-99
PRES
pk
.
(WT
.
.
pn
TEMP
tk
.
.
.
.
tn
GORSP
gspk
.
w1
.
.
gspn
GORST
gstk
.
w2
.
.
gstn
SVF
svfk
.
w3
.
.
svfn
GRVG
gk
.
w4)
.
.
gn
Definitions:
zi
ai
bi
4-100
The mole fraction of component i in the feed to

the first stage of the separator battery.
o
a for component i either at reservoir conditions
if it is entered after the keyword OMEGA, or at

surface conditions if it is entered after the keyword OMEGAS.
o
b for component i either at reservoir conditions
if it is entered after the keyword OMEGB, or at

surface conditions if it is entered after the keyword OMEGBS.

psat
whether the fluid has a bubblepoint or a dewpoint. The pressure units are specified by one of
the labels PSIA, PSIG, KPA, or KG/C2.
METRIC
The METRIC keyword causes gas-oil ratio values

to be printed in metric units of SCM/STCM
rather than the (default) English units of SCF/
STB. (Input optional.)
bo
Oil formation volume factor, barrels of saturated

oil at bubblepoint pressure and reservoir temperature per barrel of stock tank oil at standard conditions. (Optional).
api
API gravity of stock tank oil at standard conditions. (Optional).
gort
The total gas-oil ratio calculated by separation

through all stages to surface conditions. Units are
standard cubic feet of gas per stock tank barrel of
oil.
pk
The operating pressure of separator stage k, in

same units as for psat.
Landmark - R2003.4
tk
The operating temperature of separator stage k,

in same units as for t.
gspk
Gas-oil ratio in cubic feet of gas at standard conditions per barrel of oil at pressure and temperature for stage k.
gstk
Gas-oil ratio in cubic feet of gas at standard conditions per barrel of stock tank oil at standard
conditions for stage k.
svfk
Separator volume factor, barrels of oil at temperature and pressure of stage k per barrel of stock
tank oil at standard conditions.
gk
Specific gravity of flashed gas from stage k.
Oil density at t and psat (lb/cu ft, LB/FT3) or

(gm/cc, GM/CC). This option should be used for
oil samples. (Optional)
Gas z-factor at t and psat. This option should be

used for gas samples. (Optional)
tstd
Standard temperature in units specified on TEMP

entry. Default is 60 F. (Optional)
pstd
Standard pressure in units specified on BUBPT/

DEWPT entry. Default is 14.7 psia. (Optional)
bg
Gas formation volume factor, barrels of gas at t

and psat per thousand standard cubic feet of gas.
(Optional)
Weight factors for bo, bg, api and measured

quantities at each separation stage. (Optional)
NOTE:
1.

Weight factors for bo, bg and/or api can be specified by including
the keyword WT followed by a weight factor in the respective
BO/BG and/or API entries.
separation stage can be specified by inserting a card following a
stage input, with the keyword WT followed by a string of
weights corresponding to the number of measurements.
By default, weight factor for all measured quantities is 1.
2.
R2003.4 - Landmark
Calculation of Formation Volume Factors:
4-101
The entries, TEMP, BUBPT/DEWPT and DNSAT/ZSAT must be

entered for calculating bo/bg. Formation volume factors are
calculated as,
Vsat/Vst
Vsat
=
=
(Molecular Weight)/d
zRT/psat
for oils
for gases
Vst is oil or gas volume at standard conditions after separation.

3.

Data written to this file from separator tests will be syntactically
correct for input into VIP-ENCORE.
Example:
C -------------------------------------------------C SEPARATOR TEST (REGRESSION)
C -------------------------------------------------SEP
COMPOSITION .0011 .6893 .0864 .0534 .0348 .0178 .0173
0.064447 0.020473 0.010029 0.004951
TEMP 256 F
DEWPT 6010 PSIG
TSTD 75.
PSTD 0.
API 49.3
GORT 4699.7
PRES
TEMP
GORSP
GORST
SVF
GRVG
450.
75.
X
4276.1
X
X
100.
75.
X
0212.
X
X
0.
75.
X
0211.6
X
X
4-102
Landmark - R2003.4
Chapter
5
5.1 Introduction
A nonlinear regression package built into DESKTOP-PVT allows
automatic adjustment of the EOS properties of individual components. An
objective function measures the quality of the match between
experimental data and simulated phase behavior. The objective function is
defined as the sum of the squares of the weighted residuals. For example,
n
Q=
w i res i
(5-1)
i=1
where
Q
The objective function.
The total number of observations.
wi
Weight factor for observation i.
resi
Residual for observation i:

For each physical quantity, the residual is defined
as
resi =
(icalc - iobs)/iobs
except for liquid fractions and mole fractions, in

which case the residual is defined as
resi = icalc - iobs
where
icalc
A calculated physical quantity.
iobs
The measured physical quantity.
Weight factors have default values which can be replaced by using the
keyword WT.
Regression variables are used to alter the initial values of various EOS
R2003.4 - Landmark
5-103
properties, usually by multiplying the initial value. For example:

init
T ci = X j T ci
(5-2)
where
Xj
Regression variable j.
Tci
The current critical temperature of component i,

R, (K).
init
T ci
The initial critical temperature of component i, R,

(K).
The lone exception to this method of modifying parameters is the

treatment of binary interaction coefficients:
init
d ik = d ik + ( X j 1 )
(5-3)
where
Xj
Regression variable j.
dik
The binary interaction coefficient between components i and k.
The initial binary interaction coefficient between

components i and k.
init
d ik
With this treatment of the regression variables, using values equal to 1.0
for all variables is equivalent to using the unaltered EOS properties.
Furthermore, there is no limitation on the use of single regression variable
to modify multiple EOS properties. For example, a single variable might
o
+
frequently be used to modify the a parameter of all of the C 7
components. This lends certain consistency to the parameter modification.
The regression data appears as a block of data beginning with a REGRESS
card and ending with an ENDREG card. This block of data is placed at the
beginning of the data deck, preceding the EOS card. If you do not want to
modify any of the EOS parameters, simply omit the entire block of data.
5-104
Landmark - R2003.4
5.2 EOS Property Adjustment (REGRESS)

This keyword tells the program that EOS properties are to be adjusted.
REGRESS
(COMP)
Definition:
COMP
Only compositional data will be used to adjust EOS

properties. Default is to use all data. (Input
optional)
5.3 Regression Variable Data (VARIABLE)

The following data sets the initial value of each regression variable and
establishes upper and lower bounds on each variable.
VARIABLE
i
.
.
.
MIN
xmini
.
.
.
INIT
xi
.
.
.
MAX
xmaxi
.
.
.
Definitions:
R2003.4 - Landmark
The number of regression variable. These should

range from 1 to the total number of variables.
Order is not important.
xmini
The smallest value allowed for variable i. A value

of 0.8 is suggested.
xi
The initial value for variable i. This is normally

1.0 on the first attempt. If additional runs are
made, the last set of values from a previous run
may be used.
xmaxi
The largest value allowed for variable i. A value

of 1.2 is suggested.
5-105
5.4 Nonlinear Regression Process (IMAX)

This data controls the operation of the nonlinear regression process. In
most cases the default values should be used, allowing this data to be omitted.
The use of this data is described in the Users Reference Manual for
ROTDIS, included as an appendix.
IMAX
imax
IPRINT
iprint
H
h
TOL1
tol1
TOL2
tol2
TOL3
tol3
Definitions:
imax
The maximum number of iterations allowed.

Default is 5.
iprint
Controls the quantity of output. Allowed values

are 0, 1, and 2. A value of 0 provides only the values of the objective function and the regression
variables at each regression iteration. A value of 1
also includes a table of calculated and observed
values. A value of 2 also includes details of the
internal regression calculation. Default is 1.
Controls the length of the search vector. Default

is 0.2.
tol1
A tolerance used as a convergence criterion. (The

required length of the X vector.) Default is 0.001.
tol2
An increment used to perturb variables in order

to compute numerical derivatives. Default is
0.001.
tol3
A tolerance used as a convergence criterion. (The

required reduction in the sum-of-squares from
one iteration to the next.) Default is 0.01.
NOTE:
5-106
Enter the alpha label X to obtain the default value for any parameter.
Landmark - R2003.4
5.5 Assignment of Regression Variables

The regression variables are assigned in much the same way that the EOS
properties are defined. Regression variable numbers are simply entered in
the places where data would appear in the PROPERTIES data (Section 2.4)
and DJK data (Section ).
COMP
cmpi
MW
TC
PC
ZC
ACENTRIC
xmwi xtci xpci xzci xwi
OMEGAA OMEGAB
xai
xbi
PCHOR
xpchori
VSHFT
xsi
VSHFTD VSHFTE
xd
xe
DJK
cmpk
cmpj
xdjk
REGZ
COMP
cmpn
Z
xzn
LBC
l
xl
.
.
ENDLBC
VISK
l
.
.
VISKJ
k
.
.
.
ENDVIS
KVCOR
COMP
cmpi
.
.
CO2COR
ACOEF
BCOEF
CCOEF
SCOEF
DCOEF
ENDCO2
R2003.4 - Landmark
xj
.
.
j
.
.
.
xxkj
or
cmpk
.
.
.
A B C D E
xai xbi xci xdi xei
.
.
.
.
xa0
xb0
xc0
xs0
xd1
xa1
xb1
xc1
xs1
xa2
xb2
xc2
cmpj
.
.
.
xxkj
.
.
.
.
.
.
.
xa3
xb3
xc3
xa4
xb4
xc4
5-107
Definitions:
5-108
cmpi
Component name for component i. Must be identical to one of the names included in the COMPONENTS data.
xmwi
The number of the regression variable that will be

used to adjust the molecular weight of the component i. Enter the alpha label X if it is not to be
regressed.
xtci
The number of the regression variables that will

be used to adjust the critical temperature of component i. Enter the alpha label X if it is not to be
modified.
xpci

be used to adjust the critical pressure of component i. Enter the alpha label X if it is not be modified.
xzci

be used to adjust the critical z-factor of component i. Enter the alpha label X if it is not to be
modified. (This affects only viscosity calculations.)
xwi

used to adjust the acentric factor of component i.
Enter the alpha label X if it is not to be modified.
xai

used to adjust the a parameter of component i.
xbi

used to adjust the b parameter of component i.
xpchori

be used to adjust the Parachor of component i.
(Input optional) Enter the alpha label X if it is not
to be modified. (This affects only interfacial tension calculations.)
xsi

be used to adjust the volume shift parameter of
component i. (Input optional) Enter the alpha
label X if it is not to be modified.
xd, xe
Parameters d and e for computing volume shift

parameter s,
Landmark - R2003.4
s = 1 - d M-e
The default value for d is 1.74 and is 0.133 for e.
(Input optional) Enter the alpha label X if it is not
to be modified. These regression parameters are
applied to the non-internally defined components only. Additionally, this option can not be
used if the xsi option has been invoked for these
components.
R2003.4 - Landmark
cmpj
Component name of one component in a binary

mixture.
cmpk
Component name of the second component in a

binary mixture.
xdjk

used to adjust the binary interaction coefficient
for component j and component k.
cmpn
Component name of component n for component

composition regression. Must be identical to one
of the names included in the COMPONENTS
data.
xzn

be used to adjust the component composition of
component n.
xl

be used to adjust the Cl values for calculation of
the phase viscosity using the Lohrenz-Bray-Clark
correlation. Here l is the index for Cl.
xj

be used to adjust the kj values for calculation of
the viscosity of the reference component in the
Pedersen et al. viscosity correlation. Here j is the
index for kj.
xxkj

be used to adjust the binary interaction coefficient xkj for calculating pseudo-critical temperature used indices in the Pedersen et al. viscosity
correlation. Here k (cmpk) and j (cmpj) are the
component indices (names).
xai to xei
The number of regression variable that will be

used to adjust the coefficients A to E of K-value
correlation of component i. The component Kvalue correlation is expressed as
5-109
Ki =
Di
B
A i + -----i + C i P exp ---------------
T E i
P
where Ai to Ei are constant coefficients for component i, P is pressure in psia and T is temperature in Rankin.
xa0 to xa4
xb0 to xb4
xc0 to xc4

be used to adjust the correlation coefficients that
are used in computing solubility of carbon
dioxide in pure water. The correlation is shown in
Section 2.9.
xs0 and xs1

are used in computing the effects of salinity on
carbon dioxide solubility in water. The correlation is shown in Section 2.9.
xd1

are used in computing density of carbon dioxide
saturated water. This density is then used in computing water formation volume factor. The correlation is shown in Section 2.9.
NOTE:
1.
Attempting to adjust too many parameters simultaneously is

likely to create an ill-conditioned problem. The result may be to
generate physically meaningless values for some parameters. It is
wise to try to limit the number of variables.
2. A single variable can be used to modify the same property of

multiple components. When this is done, the various components
using the same variable should be closely related, such as heavy
fractions. This is frequently done for binary interaction
parameters.
5-110
3.
Component cards are entered only for components that will be

adjusted. Others are simply omitted from the data.
4.
The keyword REGZ is used to indicate regression on component

composition. A maximum of NC - 1 components may be
regressed upon. A regression variable of zero must be assigned to
a component composition which is used to preserve the mole
fraction constraint.
5.
Water appears implicitly as a component in some experiments

associated with VIP-THERM (STMDIS and PSATW). Binary
interaction coefficients for water may be regressed upon by using
the alpha label H2O for cmpj or cmpk.
Landmark - R2003.4
5.6 End of Regression Data (ENDREG)

This keyword is used to terminate the regression data.
ENDREG
Example:
The data which follows defines a set of regression variables for tuning the
equation of state. The seven regression variables are the a and b of each
of three heavy fractions and the binary interaction coefficient between
methane and all the heavy fractions. Use a range of .7 to 1.25 for the
interaction coefficient variable. Use a maximum of ten regression
iterations and request maximum output.
REGRESS
VARIABLE MIN INIT MAX
1
X
X
X
2
X
X
X
3
X
X
X
4
X
X
X
5
X
X
X
6
X
X
X
7
.7
X
1.25
IMAX
IPRINT H TOL1 TOL2 TOL3
10
2
X X
X
X
COMP
MW TC PC ZC ACENTRIC
HVY1
X X X X
X
HVY2
X X X X
X
HVY3
X X X X
X
DJK
C1
HVY1
7
HVY2
7
HVY3
7
ENDREG
R2003.4 - Landmark
OMEGAA
1
3
5
OMEGAB
2
4
6
5-111
5-112
Landmark - R2003.4
Chapter
6
Pseudoization
DESKTOP-PVT provides a calculation to combine components through a
process called pseudoization. The original fluid system is reduced to a
pseudo system by specifying which of the original components will be
lumped into which pseudo component.
This procedure is consistent with both the equation-of-state and the
viscosity correlation, in that the density and viscosity of the original
system is preserved in the pseudo system. Experience has shown that the
saturation pressure of the pseudo system may be slightly in error, but can
be easily adjusted through regression.
PSEUDO
COMPOSITION
TEMP
BUBPT
DEWPT
PCMP1
PCMP2
.
.
.
PCMPm
ENDCMP
R2003.4 - Landmark
z1 z2 . . . zn
F
C
R
K
psat
PSIA
PSIG
KPA
KG C2
one or more of CMPi

one or more of CMPi
.
.
.
one or more of CMPi
6-113
Pseudoization
Definitions:
zi
Mole fraction of component i in the original fluid

system. The number of values must equal the total
number of components defined in the component data
(Section 2.3).
A value of temperature in units specified by one of

the labels F, C, R, or K. If no label is entered, the
temperature is in F.
psat
The saturation pressure of the fluid at temperature t.

The label BUBPT or DEWPT indicates whether the
fluid has a bubblepoint or a dewpoint, and the
pressure units are specified by one of the labels PSIA,
PSIG, KPA, or KG/C2.
PCMPm
An alphanumeric label that identifies pseudo

component m.
CMPi
An alphanumeric label that identifies component i of

the original fluid system. This must agree with one of
the component names defined in the component
properties data.
Example:
C
C
PSEUDOIZATION FROM 10 TO 5 COMPONENTS
C
EOS
PR
COMPONENTS
CO2 N2 C1 C2 C3 NC4 NC5 NC6 C15 C20
PROPERTIES
COMP MW TC PC ZC ACENTRIC OMEGAA OMEGAB
ENDEOS
PSEUDO
COMPOSITION .015 .006 .732 .061 .042 .038 .034 .039 .021 .012
TEMP 251 F
DEWPT PSIG 4354
P1 C1
CO2
P2 C2
N2
P3 C3
NC4 NC5 NC6
P4 C15
P5 C20
ENDCMP
END
6-114
Landmark - R2003.4
NOTE:
R2003.4 - Landmark
Pseudoization
1.
A pseudoization calculation may not be performed during a

regression run. In addition, each original component must be
included in one pseudo component.
2.
On completion of the pseudoization, EOS parameters of the

pseudo system are written to a file.
3.
DESKTOP-VIP allows the calculation of any laboratory test

following the pseudoization calculation.
6-115
Pseudoization
6-116
Landmark - R2003.4
Chapter
7
DESKTOP-PVT provides a method to calculate a heavy fraction
characterization from laboratory measured properties of the heavy
fraction. Based upon user supplied heavy fraction molecular weight and
specific gravity, the program generates an extended analysis using a
modification of Whitsons method. The extended analysis can be
pseudoized into a user specified number of components or into a program
calculated number of components.
R2003.4 - Landmark
7-117
The heavy fraction characterization procedure is a stand-alone calculation.

Only the data given below should be entered. After a fluid system has
been characterized, the user should enter the resulting component
properties in a subsequent program run to perform additional
calculations.
SPLIT
MWPLUS
mwplus
GPLUS
gplus
PROPERTY
ZPLUS (WTPLUS) (NCOMP NG ALPHA NLAST ETA WAT MAXIT MW MWGRP)

zplus (wtplus) (ncomp ng alpha nlast eta wat maxit
mwgrp1 mwgrp2 . . .mwgrpng-1)
CORRELATION
GENERALIZED
TC
RIAZI DAUBERT
KESLER LEE
CAVETT
PC
RIAZI DAUBERT
KESLER LEE
CAVETT
ZC
RIAZI DAUBERT
RIEDEL PITZER
ACENTRIC
ADJUST
EDMISTER
KESLER LEE
WHITSON
SIMULATION
EXPERIMENT
PC ACENTRIC
VSH ACENTRIC
CONMWI
( MWC6C7 mwc6c7 )
( MWINIC mwinc )
VARMWI
MWBOUND
MWBOUND
SCN
SCN ncomp MWBncomp
SCN
MWB
K
K
SCN
MWB
nlast
nlast
7-118
Landmark - R2003.4
REGRES
MAXALPHA alpha
max
MINALPHA alpha
min
scn ncomp m w ncomp z ncomp sg ncomp tb ncomp
scn k
m wk
zk
sg k
tb k
scn nlast m w nlast z nlast sg nlast tb nlast

SCN
MWSCN
ZSCN SGSCN
WTSCN
TBSCN
Definitions:
R2003.4 - Landmark
mwplus
Molecular weight of the plus fraction.
gplus
Specific gravity of the plus fraction, measured at

14.7 psia and 60 F.
zplus
The mole fraction of the total fluid sample contained in the heavy fraction.
ncomp
The carbon number of the heavy fraction, i.e., for

+
+
C 7 enter 7, for C 10 enter 10. The default value is
7. (Input optional)
ng
The number of pseudo component groups in the

final fluid system. A value of zero will instruct
the program to compute the optimal number of
components.
alpha
A parameter in the gamma distribution. The

default value is 1. See note (1) below and reference [3]. (Input optional)
nlast
The carbon number of the last component to be

considered in the extended distribution. The
default value is 45. (Input optional)
eta
The minimum molecular weight expected to

occur in the plus fraction. The default value is
calculated from 14 x ncomp -6. (Input optional)
wat
The average Watson characterization factor for

the entire plus fraction, in the range of 10 to 13. If
wat is not input, its value is calculated such that
the computed specific gravity of the plus fraction
equals the measured value, gplus. (Input
optional)
7-119
mwgrp
The bracket molecular weights for the purpose of

regrouping the extended fractions into pseudo
components. For a specified value of ng, ng-1
molecular weight values must be entered. For
example, if ng is 3, two values must be entered
for mwgrp. All extended fractions with molecular weight less than or equal to mwgrp1 will be
lumped into pseudo component 1. All extended
fractions with molecular weight less than or
equal to mwgrp2 will be lumped into pseudo
component 2. All remaining fractions will be
lumped into pseudo component 3. This data is
optional. If mwgrp is present, the value of ng
must be equal to or greater than 2, and the ng
entry must be ahead of the mwgrp entry. (Input
optional)
wtplus
The weight fraction of the plus fraction. The

WTPLUS keyword causes the component weight
fractions in the plus fraction to follow the gamma
distribution. See Note (1) below. (Input optional)
maxit
The maximum number of iterations allowed to

adjust alpha to match the measured molar or
weight distribution data. The default value is 20.
(Input optional)
PROPERTY
The PROPERTY keyword allow the user to specify the method for equation-of-state (EOS)
parameters calculation, e.g. Pc, Tc, etc. (Input
optional)
The EOS parameters are computed from correlations (default) if the CORRELATION keyword is
entered after the PROPERTY keyword. The EOS
parameters are determined by table lookup using
the internally defined data given in Table 2-2 if
the GENERALIZED keyword is entered after the
PROPERTY keyword.
The keywords SIMULATION and EXPERIMENT indicate if SIMULATION or EXPERIMENTal data of molecular weights, specific
gravities, etc. are used to calculate EOS parameters. The default is SIMULATION.
TC
7-120
The keyword TC allows the user to select a critical temperature correlation. The options are
RIAZI-DAUBERT correlation (default), KESLERLEE correlation and CAVETT correlation. (Input
optional)
Landmark - R2003.4
PC
The keyword PC allows the user to select a critical pressure correlation. The options are RIAZIDAUBERT correlation (default), KESLER-LEE
correlation and CAVETT correlation. (Input
optional)
ACENTRIC
The keyword ACENTRIC allows the user to

select an acentric factor correlation. The options
are EDMISTER correlation (default), KESLERLEE correlation and WHITSON correlation.
(Input optional)
ADJUST
The keyword ADJUST causes modifications of

the plus fraction component EOS parameters
from correlations to match the component specific gravity and normal boiling point. The
default is no adjustment. (Input optional)
The component critical pressure and acentric factor are adjusted if the keyword PC/ACENTRIC
is used, and the component volume shift parameter and acentric factor are adjusted if the keyword
VSH/ACENTRIC is used.
R2003.4 - Landmark
CONMWI
The keyword indicates a constant molecular

weight interval is used to compute the molar (or
weight) distribution. This is the default. (Input
optional)
mwc6c7
The upper molecular boundary of C6. The default

value is calculated from 84 + 0.5 x mwinc. This
input must follow the keyword CONMWI immediately. (Input optional)
mwinc
The constant molecular weight interval for computing the molar (or weight) distribution. The
default is 14. (Input optional)
VARMWI
The keyword indicates a variable molecular

weight interval is used to compute the molar (or
weight) distribution. (Input optional)
scnk
The carbon number of the heavy fraction component k. These numbers must increase consecutively from ncomp to nlast. (Input optional)
7-121
mwbk
The upper molecular weight boundary of the

heavy fraction component k. The keyword
MWBOUND, and the scnk and mwbk input must
follow the keyword VARMWI immediately. This
option is applicable only if the REGRES keyword
is not used. The defaults are the mid value of the
internally defined molecular weight data given in
Table 2-2 . (Input optional)
REGRES
The keyword REGRES causes the adjustment of

the alpha value in the gamma function to match
the measured molar or weight distribution data.
The default is no adjustment. (Input optional)
alphamax
The maximum alpha allowed during adjustment.

The default is 3. (Input optional)
alphamin
The minimum alpha allowed during adjustment.

The default is 0.5. (Input optional)
mwk
The molecular weight of the heavy fraction component k. (Input optional)
zk
The mole fraction or weight fraction of the heavy

fraction component k in the hydrocarbon mixture. If ZSCN keyword is used, zk is the mole
fraction, and if WTSCN keyword is used, zk is
treated as the weight fraction. The keyword
WTSCN must be entered, if the keyword
WTPLUS is entered. Otherwise, the keyword
ZSCN must be used and the zk value is assumed
mole fraction. (Input optional)
sgk
The specific gravity of the heavy fraction component k. the alpha label X can be entered only if
the EXPERIMENT option in the PROPERTY keyword is not used. (Input optional)
tbk
The normal boiling point temperature in degree F

of the heavy fraction component k. The alpha
label X can be entered only if the EXPERIMENT
option in the PROPERTY keyword is not used.
(Input optional)
NOTE:
1.
Extended Analysis:
An extended analysis of the plus fraction is calculated assuming
the carbon numbers in the plus fraction follow the gamma
distribution. The user is required to define the shape of the
gamma function. For example, alpha should be specified. By
default, alpha is 1 (exponential). Suggested values should lie in
the range of 0.5 (accelerated exponential) to 1.5 (skewed normal).
7-122
Landmark - R2003.4
2.
EOS Parameters:
A constant Watson factor is assumed for all carbon numbers in
the plus fraction. Gravities and boiling points of the carbon
numbers are then calculated from molecular weights and the
Watson characterization factor as proposed by Whitson.
3.
Extended Analysis Pseudoization:

Pseudoization of the calculated extended analysis is performed
using Sturges rule.
4.
Parameter Output:
On completion of the split, EOS parameters of the heavy fraction
are written to a file.
Example:
The following data is available concerning the properties of the heavy
fraction of an oil sample:
Molecular weight of the heavy fraction
Gravity of the heavy fraction
Mole fraction of the heavy fraction
Carbon number of the heavy fraction
.0218
.8515
.3329
.0007
Use a distribution parameter of .75 to generate an extended analysis for

this fluid. Group this extended analysis into four heavy pseudocomponents.
SPLIT
MWPLUS
218.
END
GPLUS
8515
ZPLUS
.3329
NCOMP
7
NG
4
ALPHA
.75
Example:
The alpha parameter of the gamma function is adjusted in this example to
match the distillation data of a gas sample:
SPLIT
MWPLUS
GPLUS ZPLUS NCOMPNG
141.28
0.79293 0.0154 7 16
C
PROPERTY CORRELATION
TC
RIAZI-DAUBERT
PC
RIAZI-DAUBERT
ACENTRIC EDMISTER
ADJUST
VSH/ACENTRIC
C
CONMWI
MWINC
14
C
REGRES
R2003.4 - Landmark
NLAST ALPHA ETA

22
1.0
93
7-123
MAXALPHA 3.0
MINALPHA 0.5
C
SCN
MWSCNZSCN SGSCN
7
100.00.003610.745
8
114.00.002850.753
9
128.00.002220.773
10
142.00.001580.779
11
156.00.001210.793
12
170.00.000970.804
13
184.00.000830.816
14
198.00.000690.836
15
212.00.000500.840
16
226.00.000340.839
17
240.00.000230.835
18
254.00.000150.850
19
268.00.000100.865
20
282.00.000060.873
21
296.00.000040.876
22
310.00.000020.878
C
END
7-124
TBSCN
209.19
258.22
303.45
345.44
384.60
421.32
455.87
488.48
519.35
548.71
576.63
603.3
628.81
653.24
674.0
695.0
Landmark - R2003.4
Chapter
8
8.1 Introduction
The default values for phase behavior calculation parameters in
DESKTOP-PVT are quite adequate for most fluid systems. However, for
some difficult near-critical fluid systems, some parameters in the
saturation pressure and flash calculations may need to be changed from
the default.
The data described in this section allows the user to select alternative flash
calculation methods, specify saturation pressure parameters, specify flash
calculation parameters, specify expansion calculation parameters, and
request debug output. This data should be entered before the keyword
that introduces the laboratory test to which the data should be applied.
8.2 Selection of Flash Method

For flash calculations in DESKTOP-PVT, the user may select the NewtonRaphson method, the method of accelerated successive-substitution or the
Gibbs energy minimization method. The Newton-Raphson method is the
default. Entry of one of the keywords described below will cause all
succeeding calculations to use that method. The data to select the flash
method should be entered before the keyword that introduces the
laboratory test to which the method should be applied.
NEWTON
SS
GIBBS
Definitions:
R2003.4 - Landmark
NEWTON
Use the Newton-Raphson flash calculation

method, which is the default method.
SS
Use the accelerated successive-substitution flash

calculation method. This method may be
required for some difficult fluids that do not converge with the Newton-Raphson method.
8-125
GIBBS
Use the Gibbs energy minimization method for

flash calculation.
Example:
Use the accelerated successive-substitution calculation method for a
constant composition expansion test and switch to the Newton-Raphson
method for a differential expansion test.
EOS PR
.
.
.
ENDEOS
C
C -------------------------------------C SELECT THE SS METHOD
C -------------------------------------SS
C
CCEXP
.
.
.
C
C---------------------------------------------------------------C SELECT THE NEWTON-RAPHSON METHOD
C --------------------------------------------------------------NEWTON
C
DIFF
.
.
.
END
8.3 Saturation Pressure Tolerance Card

The user may change any of the parameters which control the
convergence of the saturation pressure calculation in DESKTOP-PVT. Any
or all of the keywords described below may be entered in any order on the
parameter names data card. The data values which occur on the card
following the parameter names data card must be in the same order as the
parameter names.
KNTMXS DPMXS DXMXS TOLPS
knt
dp
dx
tolp
8-126
TOLXS TOLKS TOLS

tolx
tolk
tol
Landmark - R2003.4
Definitions:
knt
The maximum number of iterations in the saturation pressure calculation. Default value is 40.
dp
The maximum change in pressure for an iteration

when searching for a saturation pressure. Default
value is 500. psia.
dx
The maximum change in composition for an iteration in the saturation pressure calculation.
Default value is .05.
tolp
Convergence criterion for pressure change

between iterations of the saturation pressure calculation.
tolx
Convergence criterion for composition change

between iterations of the saturation pressure calculation. Default value is .00001.
tolk
Tolerance for the heavy component K-value during the saturation pressure calculation. The calculation will fail if the heavy component K-value is
less than 1.-tolk. Default value is .00001.
tol
Convergence tolerance for the scaled changes of

mole fraction and pressure during the saturation
pressure calculation. The calculation will fail if
the changes are less than tol. Default value is
.00001.
Example:
Change the number of saturation pressure calculation iterations to 50 and
change the maximum pressure interval to 250. psia. Also adjust the heavy
component K-value tolerance to .0001.
KNTMXS
50
R2003.4 - Landmark
TOLKS
.0001
DPMXS
250.
8-127
8.4 Flash Calculation Tolerance Card

The user may change any of the parameters which control the
convergence of the flash calculations in DESKTOP-PVT or all of the
keywords described below may be entered in any order on the parameter
names data card. The data values which occur on the card following the
parameter names data card must be in the same order as the parameter
names.
KNTMXF
knt
DXMXF DRIFT
dx
drift
TOLXF
tolx
TOLKF
tolk
TOLF
tol
Definitions:
knt
The maximum number of iterations in the flash

calculation. Default value is 20.
dx
The maximum target change in composition and

liquid/vapor fraction for an iteration in the flash
calculation. Default value is .05.
drift
The maximum amount of deviation for the target

change in liquid/vapor fraction allowed in the
flash calculation. Default value is .01.
tolx
Convergence criterion for composition and liquid/vapor fraction changes between iterations of
the flash calculation. Default value is .00001.
tolk
Tolerance for the heavy component K-value during the flash calculation. The calculation will fail
if the heavy component K-value is less than 1.tolk. Default value is .00001.
tol
Convergence tolerance for the scaled changes of

mole fraction and liquid/vapor fraction during
the flash calculation. The calculation will fail if
the changes are less than tol. Default value is
.00001.
Example:
Change the number of flash iterations to 35 and change the targeted
composition to .07 and the drift to .005.
KNTMXF
35
8-128
DXMXF
0.07
DRIFT
0.005
Landmark - R2003.4
8.5 Expansion Tolerance Card

The user may change any of the parameters which control the selection of
pressure intervals in the flash calculations of the expansion tests in
DESKTOP-PVT. Any or all of the keywords described below may be
entered in any order on the parameter names data card. The data values
which occur on the card following the parameter names data card must be
in the same order as the parameter names.
DPMAX
dpmax
DPFAC
dpfac
DPMIN
dpmin
Definitions:
dpmax
The maximum pressure interval to be used during a flash calculation in constant composition,
constant volume, and differential expansion tests.
When flashing from pressure p2 down to pressure p1, if p2-p1 is greater than dpmax, an intermediate flash will be performed at p2-dpmax.
For some difficult fluids, an adjustment of dpmax
may be required for convergence. Default value
is 500. psia.
dpfac
The factor for reduction in size of pressure interval when an intermediate flash fails. If the flash
which failed was of size dp, the next intermediate
flash calculation will be of size dp*dpfac. Default
value is .1.
dpmin
The minimum pressure interval to be used during a flash calculation in constant composition,
constant volume, and differential expansion tests.
If the pressure interval is less than dpmin, the
calculation will be reported as a failure. Default
value is .001 psia.
Example:
Specify a maximum pressure interval of 200. psia, a minimum pressure
interval of 1. psia, and a reduction factor of .25 for flash calculations.
DPMAX
200.
R2003.4 - Landmark
DPMIN
1.
DPFAC
.25
8-129
8.6 Saturation Pressure and Flash Calculations Output

(DBUGS and DEBUGF)
The user may request additional output from the program for saturation
pressure and flash calculations. This output gives detailed print of each
iteration of the calculations, with phase compositions, z-factors, residuals,
and scale factors for each sub-interval. The volume of output can be quite
large, so the user is cautioned to use this option with discretion.
DBUGS
ON
OFF
DBUGF
ON
OFF
Definitions:
DBUGS
Control switch for debug output for the saturation pressure calculation. This switch can be
turned on or off by the appropriate keyword.
Default value for this switch is off.
DEBUGF
Control switch for debug output for the flash calculations. This switch can be turned on or off by
the appropriate keyword. Default value for this
switch is off.
Example:
Request debug output for the saturation pressure and flash calculations
for a constant composition expansion, but turn off this output for a
differential expansion. Include the changes to calculation parameters used
in examples in this chapter.
EOSPR
.
.
.
ENDEOS
C
C -----------------------------C DEBUG OUTPUT ON
C -----------------------------DBUGS ON
DBUGF ON
8-130
Landmark - R2003.4
C
KNTMXS TOLK
DPMXS
50
.0001
250.
KNTMXF DXMXF
DRIFT
35
.07
.005
DPMAX
DPMIN
DPFAC
200.
1.
.25
SS
C
CCEXP
.
.
.
C
C
C -------------------------------C DEBUG OUTPUT OFF
C ------------------------------DBUGS OFF
DBUGF OFF
C
NEWTON
C
DIFF
.
.
.
END
8.7 Selection of Viscosity Calculation Method

The fluid viscosity can be calculated using either the Lohrenz, Bray, and
Clark (LBC) viscosity correlation [2] (default), the viscosity correlation
described by Reid, Prausnitz and Sherwood (RPS) [5], the Pedersen et al.
viscosity correlation [10, 11], or the cTwu viscosity correlations [12,13].
Entry of one of the keywords described below causes all succeeding
viscosity calculations to use that method.
The keyword that selects the viscosity calculation method should be
entered immediately before the keyword that introduces the laboratory
test to which the method should be applied.
LBC
RPS
VISPE
TWU1
TWU2
R2003.4 - Landmark
8-131
Definitions:
LBC
Selects the Lohrenz, Bray, and Clark viscosity correlation. Default.
RPS
Selects the viscosity correlation described by

Reid, Prausnitz, and Sherwood.
VISPE
Selects the Pedersen et al. viscosity correlation.
TWU1
Select the 1985 Twu viscosity correlation [12]. In

this option, the component viscosities at a given
temperature is first computed using the Twu viscosity correlation. Then the oil viscosity is computed from component viscosities using the
mixing rule
x
11 22 ncnc
The Twu viscosity correlation is based on perturbation theory using n-alkanes as a reference. This
correlation is intended to predict liquid viscosities of petroleum fractions.
TWU2
Select the 1986 Twu viscosity correlation [13]. In

this option, the component viscosities at a given
temperature is first computed using the Twu viscosity correlation. Then the oil viscosity is computed from component viscosities using the
mixing rule
x
11 22 ncnc
This correlation uses a corresponding states principle based on the viscosities of two reference fluids. This correlation was development to
represent the Watson (viscosity) plot.
Example:
EOS
PR
.
.
.
ENDEOS
C
C --------------------------------------------------------C SELECT THE LBC VISCOSITY METHOD
C --------------------------------------------------------LBC
CCEXP
.
.
.
C
8-132
Landmark - R2003.4
C --------------------------------------------------------C SELECT THE RPS VISCOSITY METHOD

C --------------------------------------------------------RPS
DIFF
.
.
.
END
R2003.4 - Landmark
8-133
8-134
Landmark - R2003.4
Chapter
9
Throughout this manual, fluid composition has been entered via the
COMPOSITION data card. In some cases, the composition that is needed
for a calculation is actually the composition of some intermediate step in
another laboratory test. An alternative method of composition
specification is presented here which allows the reference to compositions
from previously entered tests. The tests for which this composition
specification is available include constant composition expansion,
constant volume depletion, swelling, differential expansion, and
composition variations with depth.
The data described below allows the user to replace the COMPOSITION
data card in any of the calculations in this manual with an alternative
specification. The only restriction is that reference to the composition from
a type of test pertains to the most recently entered test of that type in the
data stream.
CCEXPX
CCEXPY
CCEXPZ
CVDEPX
CVDEPY
CVDEPZ
SWELLX
SWELLY
SWELLZ
DIFFX
DIFFY
DIFFZ
ZGRADX
ZGRADY
ZGRADZ
ccexpxi
ccexpyi
ccexpzi
cvdepxi
cvdepyi
cvdepzi
swellxi
swellyi
swellzi
diffxi
diffyi
diffzi
zgradxi
zgradyi
zgradzi
Definitions:
R2003.4 - Landmark
ccexpxi
Reference to the composition of the liquid phase

at pressure entry i in the previous constant composition expansion test.
ccexpyi
Reference to the composition of the vapor phase

at pressure entry i in the previous constant composition expansion test.
9-133
9-134
ccexpzi
Reference to the overall composition at pressure

entry i in the previous constant composition
expansion test.
cvdepxi

at pressure entry i in the previous constant volume depletion test.
cvdepyi

at pressure entry i in the previous constant volume depletion test.
cvdepzi

entry i in the previous constant volume depletion
test.
swellxi

at entry i in the previous swelling test.
swellyi

at entry i in the previous swelling test.
swellzi
Reference to the overall composition at entry i in

the previous swelling test.
diffxi

at pressure entry i in the previous differential
expansion test.
diffyi

at pressure entry i in the previous differential
expansion test.
diffzi

entry i in the previous differential expansion test.
zgradxi
Reference to the composition of the equilibrium

liquid phase at depth entry i in the previous composition variations with depth.
zgradyi
Reference to the composition of the equilibrium

vapor phase at depth entry i in the previous composition variations with depth.
zgradzi
Reference to the overall composition at depth

entry i in the previous composition variations
with depth.
Landmark - R2003.4
Example:
Perform a surface separation calculation for the vapor phase at 4000. psig
from a constant volume depletion.
C
C--------------------------------------C CONSTANT VOLUME DEPLETION
C--------------------------------------CVDEP
COMPOSITION .0011 .6893 .0864 .0534 .0348 .0178 .0173
.064447 .020473 .010029 .004951
TEMP 256 F
BUBPT 6010 PSIG
PRES
6010
5000
4000
3000
2100
1200
C1
.6893
.7069
.7360 .7660 .7777 .7704
C2
.0864
.0868
.0873 .0883 .0897 .0938
C
.0173
.0148
.0125 .0108 .0101 .0107
MW C8 C34
158
146
134
123
115
110
ZGAS
1.140 1.015
.897
.853
.865
.902
VPROD
0.
.06624 .17478 .32927 .49901 .68146
SLIQ
0.
.0780
.2130 .2500 .2440 .2250
C
C----------------------------------------C SURFACE SEPARATION
C----------------------------------------SEP
C--------------------------------------------C REFER TO CONSTANT VOLUME VAPOR AT PRESSURE 3
C--------------------------------------------CVDEPY 3
C
TEMP 256 F
BUBPT 6010 PSIG
PRES
TEMP
GORSP
GORST
SVF
GRVG
385.
100.
X
X
X
X
0.
60.
X
X
X
X
R2003.4 - Landmark
700
.7513
.0983
.0125
109
.938
.77902
.2100
9-135
9-136
Landmark - R2003.4
Appendix
A
Unconstrained Minimization of
Least-Squares Functions
A.1 Introduction
The unconstrained minimum of any function Q(x1,x2,...,xn) can occur only
at a stationary point, that is a point where
Q
-------- = 0,
x i
i = 1, , n
(A-1)
or expressed in vector notation,
Q (X) = 0
(A-2)
If Q' is expanded in a finite Taylor series about some base point Xo, where
o
x1
o
X =
o
x2
o
xn
(A-3)
the following expression is obtained:

o
Q' ( X ) = Q' ( X ) + Q'' ( X ) X + ( X X )
R2003.4 - Landmark
(A-4)
A-137
Unconstrained Minimization of Least-Squares Functions
2
-----------Q2
x 1
Q" =
2
2
Q
Q
------------------------x 1 x n
x 1 x 2
-------------------------
2
Q
2
x n
2
2
Q
Q
x n x 1 x n x 2
------------------------- -------------------------
x1
x o
1
x2
x o
2
(A-5)
---------------
(A-6)
xn
x o
n
If the remainder term is neglected, the substitution of this expression into

Equation A-2 results in:
o
Q' ( X ) + Q'' ( X ) X = 0
(A-7)
Thus X is an approximation to a vector Xs directed from the base point

to a stationary point of the function Q. If Q' is nonsingular, X can be
calculated by:
o
X = [ Q'' ( X ) ]
Q' ( X )
(A-8)
In general, the vector X does not equal Xs; however, it can be used to
update the base point Xo and establish an iterative solution technique:
o k 1
( X ) = [ Q'' ( X ) ]
o k+1
(X )
o k
o k
Q' ( X )
= ( X ) + ( X )
(A-9)
(A-10)
If the function is sufficiently well behaved, the procedure will converge

rapidly to a stationary point. Unfortunately, it has a number of serious
drawbacks:
1. The stationary point, rather than being a minimum, may actually be a
maximum or a saddle point.
A-138
Landmark -R2003.4
2. Unless Q has a simple function form, it is necessary to calculate the

elements of Q"numerically. This can require an excessive amount of
computation time.
3. Quite frequently the iterative procedure will diverge.
These problems make the method outlined above so inefficient and
unreliable that it is of little utility; however, there are variations of the
basic method that overcome its limitations. Two such techniques are the
Gauss-Newton method and the method of rotational discrimination.
A.2 Gauss-Newton Method

For the special case of sum-of-squares objective functions, it is possible to
obtain a good estimate of the second derivative terms in Q without
actually computing second differences. The approximation that makes this
possible is the distinguishing characteristic of the Gauss-Newton
minimization method.
A sum-of-squares objective function is a function that can be expressed in
the following form:
m
Q( X ) =
Ri ( X ) ,
2
(A-11)
i=1
where Ri is the ith residual of the minimization problem. Each of the

residuals may be a nonlinear function of the variables (xi,x2,...,xn).
If Equation A-11 is differentiated with respect to one of the variables, xj,
the following result is obtained:
m
R i
Q
-------- = 2 R i -------x j
x j
(A-12)
i=1
If this expression is now differentiated with respect to a second variable,

xk, the result is:
2
Q
------------------------ = 2
x k x j
2
m R R
m
Ri
i
i
- -------------- + 2 R ----------------------- ---------i x x
x k x
k
j
j
i=1
i=1
(A-13)
Let us now assume that the first sum in this expression is much larger than
the second. This is always a valid assumption if the base point is
sufficiently near the solution to the problem. (If a set of nonlinear
equations is being solved, all of the residuals, by definition, are zero at the
solution, so the second term drops out entirely. In nonlinear regression
R2003.4 - Landmark
A-139
problems, the residuals usually are rather evenly distributed between

positive and negative values, so once again the second sum should be
fairly small, and the assumption is valid.)
Once this assumption is made, Equation A-13 reduces to:
2
Q
x k x j
------------------------ =
m R R
i
i
----------- -------------- .
x
x
j
i=1 k
(A-14)
Thus, a second derivative of Q is approximated by a sum composed

entirely of products of the first derivatives of its residuals.
If each element of the matrix Q", defined in Equation A-5, is approximated
according to Equation A-14, the resulting matrix G is called a GaussNewton matrix. The Gauss-Newton minimization technique is an iterative
procedure similar to the one defined by Equation A-9, but using G in place
of Q":
k
o k 1
( X ) = [ G ( X ) ]
o k+1
(X )
o k
o k
Q' ( X )
= ( X ) + ( X )
(A-15)
(A-16)
In addition to the substitution of G for Q", this method differs from the
previous one in that the vector X is multiplied by a scalar , which may
assume a different value for each iteration. Thus we no longer think of X
as being a direct approximation to Xs, but as an estimate of the direction
in which the minimum lies. By adjusting the value of , we determine how
far along the direction we will move in picking the base point for the next
iteration.
A.3 Advantages of the Gauss-Newton Method

This method has three significant advantages over the basic iterative
procedure defined by Equation A-9.
First of all, the numerical evaluation of the matrix Q" requires at least
n(n+3)/2 evaluations of Q, assuming that the value at the base point is
already known. In contrast, the construction of G requires only n function
evaluations. Therefore, when the computational effort required to perform
a single function evaluation is significant, a Gauss-Newton iteration can
be performed much more rapidly than an iteration of the basic method.
Second, the Gauss-Newton direction X is one that, in the neighborhood
of the base point, always leads to a lower sum-of-squares. Thus, if is
sufficiently small, each iteration of the procedure must result in a reduced
objective function, assuming, of course, that the base point is not itself a
stationary point. This is known as the property of truncation convergence.
A-140
Landmark -R2003.4
The Gauss-Newton has this property because the definition of G insures

that it is either positive definite or positive semi-definite. This means that
none of its eigenvalues in the vicinity of a maximum and a mixture of
positive and negative values near a saddle. Thus G never accurately
approximates Q" near either of these types of stationary points, and the
Gauss-Newton method converges only to minima.
The final advantage of the Gauss-Newton method is that the distance
factor can be used to accelerate convergence. If a one-dimensional search
for the minimum of Q is conducted along the vector [(Xo)k + (X)k] , an
optimum value of can be determined for each iteration. This sometimes
accelerates convergence appreciably, particularly when the original base
point is a great distance from the minimum.
A.4 Defects in the Gauss-Newton Method

The primary objective to the Gauss-Newton minimization method is that
the matrix G is frequently ill-conditioned. If it ever becomes singular, its
inverse does not exist and the method fails. In this situation, G, will have
one or more zero eigenvalues.
Even when the matrix is nonsingular, one of its eigenvalues may be
sufficiently close to zero that it is approaching singularity. This leads to
serious roundoff error in the inverse of G, usually characterized by one or
more values of xi that are unusually large. Even with an optimum choice
of , there will be little or no improvement, in either the sum-of-squares or
the values of the unknowns.
This type of problem is not at all uncommon. It occurs any time that
variable has a negligible effect on the sum-of-squares relative to the
remaining variables. A variable with this characteristic is said to be nulleffect.
The most obvious source of null-effect variables is an overdefined or
unwisely formulated problem. This can be caused by attempting to regress
on a excessively large number of variables simultaneously. Even when a
problem is quite well defined near the minimum, it may be found that one
or more variables are null-effect in other regions of the n-dimensional
space. This is most likely to cause problems when the initial estimates of
the unknown parameters are poor.
R2003.4 - Landmark
A-141
A.5 Method of Rotational Discrimination

In its most general form, the method of rotational discrimination can be
applied to objective functions of arbitrary form. However, since we are
presently considering only functions of the sum-of-squares type, we will
present a specialized form of the more general method. The principal
difference is that the least-squares version employs the Gauss-Newton
matrix G, whereas the general method uses the second derivative matrix
Q".
It should be remembered from the previous discussion that the problems
with the Gauss-Newton method are caused by the matrix G being illconditioned. The method of rotational discrimination circumvents these
problems by substituting a diagonalization procedure for the matrix
inversion in calculating X.
Let us consider for the moment a rearranged version of Equation A-15,
omitting the iteration notation:
o
o
G X X = Q' X .
(A-17)
Now the elements of the matrix G are computed according to

g kj = 2
m R R
i
i
------------ -------------- .
X
X
j
i=1 k
(A-18)
where gkj is the element located in the kth row and jth column of G. It
should be obvious from this definition that G is a symmetric matrix.
For the particular case of a symmetric matrix, we can always find a matrix
S. such that
T
S G S = D,
(A-19)
where
S = [ V 1, V 2, , V n ]
(A-20)
Vi is an n-dimensional vector that is orthogonal to the remaining Vj, j

i. (The term "orthogonal" means that the dot product of Vi and Vj is zero.)
D is a matrix whose only nonzero terms appear on the principal diagonal.
The vectors Vi that satisfy these requirements are called the eigenvectors
or characteristic vectors of G. If each of these eigenvectors is normalized so
that its magnitude is one, then the diagonal elements of D are the
eigenvalues of G. These eigenvectors and eigenvalues are readily
calculated by applying an algorithm by Jacobi.
A-142
Landmark -R2003.4
Since we have defined S so that its columns are composed of mutually

orthogonal, normalized vectors, it follows that
S S
(A-21)
= I
where I is the identity matrix, a matrix having only ones on the principal
diagonal and only zeros elsewhere. Making use of this identity and
multiplying both sides of Equation A-17 by ST, we show that
T
S G S S X = S Q' .
(A-22)
This can be written in a more compact form by defining some new terms
and using Equation A-19:
Q
D Y = ------Y
(A-23)
where
T
Y = S X
(A-24)
Q
y 1
-----------
T
Q
--------- = S
Q =
Y
Q
----------y 2
(A-25)
Q
----------y n
Since D is a diagonal matrix, the solution to Equation A-23 is simply
1 Q
y i = -------- ------------- , i = 1, , n
d ii y i
(A-26)
Once the Y-vector has been calculated, it is a simple matter to convert it

back into a X-vector
.X
= SY
(A-27)
The X calculated in this manner clearly must be the same as the one
defined by Equation A-15. The net effect of this diagonalization procedure
has been to rotate the X-coordinates about the base point Xo. This
essentially creates a new coordinate system in which the Gauss-Newton
search direction is defined by Y rather than X.
R2003.4 - Landmark
A-143
The new coordinate system has a significant advantage over the original
one, however. In the neighborhood of the base point, each of the variables
yi has an effect on Q that is independent of the effects of the other
variables. In general, this is not true of the xi. Because of the local
independence of the yis, the value of each can be altered almost arbitrarily
without destroying the truncation convergence property of the search
direction Y. The only restriction is that each must have the same algebraic
sign as if it were calculated from Equation A-26.
A.6 The Rotational Discrimination Algorithm

The rotational discrimination method, or R-D method, is basically an
empirical scheme for choosing a search vector in terms of the rotated
coordinates, yi, that is either equal or superior to the one defined by
Equation A-26. The logic of the method presupposes that the variables xi
have been scaled, or normalized, in such a fashion that the following
assumptions are valid:
1. Any component of the vector Y, calculated from Equation A-26, that
exceeds some maximum value h is indicative of the matrix G being illconditioned.
2. The eigenvalues of G provide a direct measure of the importance of
the corresponding yis. Any eigenvalue that is many orders of
magnitude smaller than the largest indicates that the corresponding yi
is locally null-effect.
Thus, if yi calculated from Equation A-26 is less than h in magnitude, and
if the associated eigenvalue is sufficiently large, then yi is left unchanged.
Otherwise empirical procedures are used to alter the calculated value.
The basic instructions for the application of the R-D minimization
algorithm are as follows:
1. Select a base point, Xo, and maximum allowable distance factor h.
2. Compute Q and G from Equation A-12 and Equation A-18.
3. Find the eigenvalues and normalized eigenvectors of G. Order D and S
of Equation A-19 so that the dii are in descending algebraic order.
4. Starting with yi, compute the elements of Y according to Equation A26,
1 Qy i = ------------------d ii y i
(A-28)
until one of the following occurs:

a: i=n
A-144
(A-29)
Landmark -R2003.4
d kk
b: ----------- 10
d ii
c: yi > h
(A-30)
(A-31)
5. If step 4 is terminated at the kth parameter for reason (b), set yk and
all remaining yi equal to zero and skip to step 7. If it is terminated for
reason (c), then
Q
y k = h sign -----------
y k
(A-32)
6. If there are parameters in the list after the kth one, calculate them
according to the method of scaled steepest descent
-------------
-------------------
Q
yi
yi = yk si
Q-
------------
y k
(A-33)
where si is a scale factor defined by
si = P
(A-34)
where
d kk
0.5- ---------a = 1 exp --------- .
ln
d
l nP
ii
(A-35)
(P is a constant, usually in the range of 10-100.)

(This expression produces scale factors that vary from 1 to P as dii
varies between dkk and zero.) If |yi|>h when calculated in this
manner, it should be truncated so that |yi| = h.
7.
Convert the resulting Y-vector back into a X-vector by Equation A-27:
X = S Y
(A-36)
8. Perform a one-dimensional search for the optimum along the vector

o
X = X + X
R2003.4 - Landmark
(A-37)
A-145
9. Update the distance factor h according to

hk+1 = hk exp[0.88255 tan-1(0.56654 ln )]
This has the effect of multiplying hk by a factor between 0.25 and 4 as
varies from 0 to . For = 1, hk+1 = hk.
10. Convergence is achieved when either the change in Q over an iteration
is within a tolerance, or the magnitude of X is very small. If
convergence is not met, update Xo and return to step 2.
It is not difficult to demonstrate that the Y calculated in this manner
produces a X with the property of truncation convergence. To do this, we
expand the differential of the objective function with respect to in terms
of the yi variables.
dQ
--------- =
d
i=1
Q dy i
y i d
(A-38)
--------- -------------
The search for vector Y can be expressed as a function of in the following

manner:
For 0 < i < k,
Q
y i = -------- ------------d ii y i
(A-39)
For i = k,
Q
y i = h sign ----------y i
(A-40)
For k < i n,
yi = yk si
Q
---------
y i
---------------- =
Q
-----------
y k
h si
Q
---------
y i
--------------- Q
-----------
y k
Q
sign -----------
y k
(A-41)
Substituting these expressions into Equation A-38 we obtain

dQ
--------- =
d
A-146
k1
i=1
Q 2 1
Q
--------- -------- h ------------y k
y i d ii
Q
sign ----------y k
(A-42)
Landmark -R2003.4
i = k+1
si .
Q 2
---------
y i
------------------ Q
-----------
y k
Q
sign -----------
y k
(A-43)
Since dii, h, and si are all positive by definition, it is obvious that dQ/d is
negative at the base point, and hence truncation convergence is achieved.
This clearly remains true even if one of the yi is truncated, as described in
step 6, or if one of the yi is set to zero as in step 5.
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A-147
A-148
Landmark -R2003.4
Appendix
B
B.1 Introduction
Oftentimes physical or practical considerations dictate that the value of an
unknown parameter not exceed some upper or lower bound. Porosity, for
example, is restricted by its definition to lie between zero and one.
Similarly, negative values of permeability are physically impossible. At
other times, a reasonably good estimate of the optimum value of some
parameter may be available from previous work. Thus it is known that the
optimum should lie within some relatively narrow range of values.
In such situations, it is usually desirable to establish inequality constraints
on the parameters of a minimization problem. This often speeds
convergence to the proper solution, as well as preventing convergence to
an infeasible or unlikely solution. This is particularly valuable in solving
problems that are ill-conditioned, since it prevents excessively wide
fluctuations in parameter values.
B.2 Our Treatment of Bounded Variables

During the problem definition and initialization state of a least-squares
problem, we require that both a lower bound, ximin, and an upper bound,
ximax be specified for each minimization variable. Furthermore, we require
that the initial estimate of the value of each parameter lie within its
bounds.
Once the problem has been initialized, the base point for each succeeding
iteration is determined by a one-dimensional search for the optimum
along the vector.
X = Xo + . X.
(B-1)
If the base point for the iteration lies in the feasible region, we can always
calculate a number max such that the constraints are satisfied for all
max. This number is calculated as follows:
max = 0.999 MIN
R2003.4 - Landmark
x b x o
i
i
--------------------
x
(B-2)
B-149
where MIN is the minimum over all i,

b
max
xi = xi
if x i > 0, and
(B-3)
b
min
xi = xi
if x i < 0.
(B-4)
If the optimum for an iteration is less than max, then the constraints are
inactive and we proceed just as though the problem were unconstrained.
If, on the other hand, the optimum value exceeds the maximum we set
equal to max in computing the base point for the next iteration.
When this is done, the resulting base point will lie very close to the
boundary of the feasible region. Consequently, if the new iteration
produces a similar search direction, the distance from the base point to the
boundary will be very short, and the search direction will be unprofitable.
Therefore, when we find that
max
i=1
0.5
( x )
<
(B-5)
where is a small positive number, we modify the minimization

procedure to produce a more profitable search direction.
In calculating this new search direction, we deactivate the variable that is
attempting to violate its bounds, effectively reducing the dimensionality
of the problem. We then recalculate the incremental changes in the
remaining variables and determine a new max. This is done just as before
except that we use a Gauss-Newton matrix that has only (n-1) rows and
columns rather than n. No additional function evaluations are required,
since the necessary derivatives are always stored at the beginning of each
iteration.
If necessary, the dimensionality of the problem for a given iteration can be
reduced still further by repeated application of the above process.
However, regardless of the number of variables deactivated in the
previous iteration, each new iteration begins with the full set of n
variables. Thus a parameter constrained at an upper or lower bound for
several iterations can move back toward the middle of its permitted range
in subsequent iterations.
B-150
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Appendix
C
C.1 Introduction
Each iteration of the minimization program concludes wicne-dimensional
search for the producing the lowest sum-of-squares along the vector
X = Xo + . X
(C-1)
The search procedure employed is designed to accomplish the following

objectives:
1. Locate a point at which the sum-of-squares is lower than at the base
point.
2. Determine values of both larger and smaller than the optimum value,
and then perform a quadratic interpolation to estimate the optimum.
3. Perform the smallest number of function evaluations possible without
compromising the first two objectives. This can often mean that opt is
determined with rather low precision; however, it is considered more
productive to compute a new search direction than to further refine the
estimate of opt.
C.2 Assumptions
In order to minimize the number of function evaluations required to locate
opt, we make use of several assumptions.
1. There is only one relative minimum along any given search direction.
2. Objective function is continuous for 0 con, where con is some
positive number.
3. The optimum is always greater than or equal to zero. (This assumes
that the least-squares minimization program has the property of
truncation convergence, discussed in Appendix A.)
R2003.4 - Landmark
C-151
4. There is a high a priori probability that opt is a number close to one.

(This is generally a good assumption except on the first couple of
iterations or when the numerical derivatives used to compute the
search direction are in significant error due to roundoff or truncation
error.)
C.3 Operating Characteristics

The search routine is programmed so that it always performs at least two
function evaluations. Frequently, it will use three or four evaluations on
the first couple of searches and two thereafter. The average number
required for the entire solution will usually fall in the range of 2.3-2.7 per
iteration.
C.4 Description of the Search Procedure

In initiating the 1-D search for a given iteration, the rotational
discrimination program supplies the search routine with the equivalent of
the following information:
Xo
The location of the base point.
The search direction.
Qo
The value of the objective function at the base point.
dQ
------d
The derivative of the objective function along the

search direction,evaluated at the base point.
max
Appendix B.
The maximum permissible value of , discussed in
max
The largest change in permitted in one step of the

search procedure.
The increment used by the R-D program to

compute numerical derivatives.
The value of max is determined by the magnitude of the search vector,

the dimensionality of the problem, and the parameter h of the R-D
algorithm:
hn
max = -----------X
where
X =
i=1
C-152
0.5
(X )
(C-2)
Landmark -R2003.4
The search normally begins with a function evaluation for =1. (This is
modified when max <1.333.) Then, depending on the value of the
objective function, it follows one of two courses.
When the objective function is smaller than Qo, the search is extended to
larger values of until a point is found where the objective function
increases over the preceeding value. At this point a quadratic
interpolation is used to estimate the location of the minimum.
At the time the interpolation is applied we have saved the value of the
objective function for the three most recent points, Q1, Q2 and Q3,
corresponding to 1, 2, and 3. These points have the following
properties:
Q1 > Q2 < Q3
(C-3)
1 < 2 <3
(C-4)
The minimum of parabola fit to three such points must lie between 1 and
3, its location being given by

C
1 1
test = --- ---------2 C2
(C-5)
where
Q3 Q1 Q2 Q1
1
- ------------------------ -------------------------C 2 = ----------------------3 1 1 ( 3 2 )
Q2 Q1
- ( + ) C
C 1 = ----------------------2 1 2
2 1
(C-6)
(C-7)
The objective function at test may or may not be evaluated, depending on

its proximity to 2.
In situations where the first function evaluation, at = 1, produces an
objective function greater than at the base point, we use another quadratic
interpolation procedure to estimate the location of the minimum. In this
case = 1 serves as an upper bound on the permissible values of . This
interpolation scheme may be applied several times in succession if the
estimated minimum, test, produces an objective function, Qtest, greater
than the base value on each trial. Each time this occurs, the upper bound,
2, is reduced to test from the preceding trial.
In general, the interpolation problem becomes on the fitting a quadratic to
dQ/d, Qo, and Q2 corresponds to 2. The minimum of such parabola
occurs at
R2003.4 - Landmark
C-153
1 C1
test = --- -------2 C2
(C-8)
where
C 1 = dQ
--------d
Q2 Qo C 1 2
C 2 = ------------------------------------------------2
( )
2
(C-9)
(C-10)
In the event that 2 . Xis reduced to a value smaller than , the search
is terminated and opt is set to zero.
C-154
Landmark -R2003.4
Appendix
D
Example Problems
D.1 Example 1
The following example documents the use of DESKTOP-PVT in the
analysis of a fluid sample with an equation-of-state. Included is a standard
laboratory report for a volatile oil sample, with a constant composition
expansion test, a constant volume depletion test, and a surface separation
test. Following the laboratory report are three DESKTOP-PVT program
output listings.
The first listing shows the generation of a heavy fraction characterization
using the SPLIT feature of DESKTOP-PVT. An extended analysis to carbon
number 45 is produced with a pseudoization back to three components.
The resulting component properties are written to a disk file for use in
subsequent runs.
The second listing shows the use of non-linear regression to adjust
equation-of-state parameters to match laboratory measurements. In this
example, a, and b of each of the three heavy components and methane,
and the binary interaction parameters between methane and the heavy
components are adjusted to produce an excellent match of the observed
data.
The third listing shows the adjustment of component zc parameters to
match laboratory measured viscosity data. Note that changes of zc do not
effect the equation-of-state calculated PVT properties. The zc parameters
are used only in the viscosity correlation.
R2003.4 - Landmark
D-155
Example Problems
D.1.1 Lab Report

CORE LABORATORIES, Inc.
Reservoir Fluid Analysis
Reservoir Fluid Study
for
GOOD OIL COMPANY
Volatile Oil No. 8 Well
Good Oil Company
P.O. Box 100
Oil City, TX
Attention: Mr. John Jones
Subject:

Gentlemen:
Samples of separator liquid and vapor were collected from the subject well by a representative of Core
Laboratories, Inc. Presented in this report are the results of a reservoir fluid study performed using these
samples.
The producing gas-liquid ratio was measured to be 2527 cubic feet of separator gas at 14.696 psia and
60F per barrel of stock tank liquid at 60F. This ratio has been corrected for gas gravity and
supercompressibility. In the laboratory it was found that he ratio is equivalent to 2355 standard cubic
feet of separator gas per barrel of separator liquid. This ratio was used in conjunction with the measured
compositions of the separator products to calculate the composition of the well stream material. These
data are reported on page two.
The separator products were physically recombined to the producing ratio and examined in a visual cell
at the reservoir temperature of 276F. During a constant composition expansion a bubble point was
observed at 4375 psig. Comparison of this value to the reservoir pressure indicates that the fluid exists
in an undersaturated condition. Observation of the system at pressures immediately below the bubble
point pressure shows that the liquid exhibits a very rapid shrinkage which indicates this system to be a
volatile oil, or one which is near critical in nature.
Since a large amount of the production from this type of reservoir comes from the gaseous phase, a
constant volume depletion study was performed on a sample of the recombined fluid to enable
calculation of the production during depletion below the bubble point pressure. The depletion consisted
of a series of expansions and constant pressure displacements terminating at the original cell volume.
D-156
Landmark - R2003.4
Example Problems
This has the effect of maintaining a constant reservoir volume. The produced gas phase was charged to
low temperature, fractional distillation equipment for analysis and volume measurement. The results of
the depletion are tabulated on page five of the report.
The quantity of plant products available in the gas phases alone is shown on page six. A plant efficiency
of 100 percent has been assumed.
The well stream composition and equilibrium ratios of the literature were used to calculate the stock
tank liquid and sales gas recoveries that will be obtained as the pressure declines from reservoir
pressure to the bubble point pressure. THese recoveries are based upon one MMSCF of the fluid in
place at the bubble point pressure. One MMSCF is the gaseous equivalent of 842.8 barrels of bubble
point liquid.
R2003.4 - Landmark
D-157
Example Problems
Good Oil Company
Page Two

The viscosity of the liquid phase was measured from pressures exceeding reservoir pressure to
atmospheric pressure. These data are presented on page eight together with the calculated gas phase
viscosity.
The data concerning the shrinkage of the liquid in the reservoir are shown on page nine of this report.
Thank you for this opportunity to be of service. If you have any questions or if we may assist you
further, please do not hesitate to contact us.
Very truly yours,
CORE LABORATORIES, INC.
Manager
D-158
Landmark - R2003.4
R2003.4 - Landmark
Example Problems
D-159
Example Problems
D-160
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R2003.4 - Landmark
Example Problems
D-161
Example Problems
D-162
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R2003.4 - Landmark
Example Problems
D-163
Example Problems
D-164
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Example Problems
D-165
Example Problems
D-166
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Example Problems
D-167
Example Problems
D-168
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Example Problems
D-169
Example Problems
D-170
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Example Problems
D-171
Example Problems
D-172
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R2003.4 - Landmark
Example Problems
D-173
Example Problems
D.1.2 Sample Files

******************************************************************************
*
*
*
DDDDDD
EEEEEEE
SSSSS
KK
KK TTTTTTTT OOOOO
PPPPPP
*
*
DD
DD EE
SS
SS KK KK
TT
OO
OO PP
PP
*
*
DD
DD EE
SS
KK KK
TT
OO
OO PP
PP
*
*
DD
DD EEEEE
SSSSS
KKKK
TT
OO
OO PPPPPP
*
*
DD
DD EE
SS KK KK
TT
OO
OO PP
*
*
DD
DD EE
SS
SS KK KK
TT
OO
OO PP
*
*
DDDDDD
EEEEEEE
SSSSS
KK
KK
TT
OOOOO
PP
*
*
*
*
PPPPPP
VV
VV TTTTTTTT
*
*
PP
PP
V
V
TT
*
*
PP
PP
VV VV
TT
*
*
PPPPPP
V V
TT
*
*
PP
VVVV
TT
*
*
PP
VV
TT
*
*
PP
VV
TT
*
*
*
*
PHASE BEHAVIOUR PROGRAM
*
*
*
*
COPYRIGHT 1984, 1985, 1986, 1987, 1988
*
*
1989, 1990, 1991, 1992, 1993
*
*
1994, 1995, 1996, 1997, 1998
*
*
LANDMARK GRAPHICS CORPORATION
*
*
ALL RIGHTS RESERVED
*
*
*
*
VERSION 1998.0.0
CREATED 01 MAR 1998
*
*
*
*
LL
AAAAA
N
NN DDDDDD
M
M AAAAA
RRRRRR
KK
KK
*
*
LL
AA
AA NN
NN DD
DD MM
MM AA
AA RR
RR KK KK
*
*
LL
AA
AA NNN NN DD
DD M M M M AA
AA RR
RR KK KK
*
*
LL
AAAAAAA NN N NN DD
DD M MM M AAAAAAA RRRRRR
KKKK
*
*
LL
AA
AA NN NNN DD
DD M
M AA
AA RR RR
KK KK
*
*
LL
AA
AA NN
NN DD
DD M
M AA
AA RR RR
KK KK
*
*
LLLLLLL AA
AA NN
N DDDDDD
M
M AA
AA RR
RR KK
KK
*
*
*
*
GGGGG
RRRRRR
AAAAA
PPPPPP
HH
HH
IIII
CCCCC
SSSSS
*
*
GG
GG RR
RR AA
AA PP
PP HH
HH
II
CC
CC SS
SS
*
*
GG
RR
RR AA
AA PP
PP HH
HH
II
CC
SS
*
*
GG
RRRRRR
AAAAAAA PPPPPP
HHHHHHH
II
CC
SSSSS
*
*
GG GGG RR RR
AA
AA PP
HH
HH
II
CC
SS
*
*
GG
GG RR RR
AA
AA PP
HH
HH
II
CC
CC SS
SS
*
*
GGGGG
RR
RR AA
AA PP
HH
HH
IIII
CCCCC
SSSSS
*
*
*
***************************************************************************
1
************************************************
*
*
*
D E S K T O P - P V T
*
*
*
*
*
*
*
*
VERSION 1998.0.0
*
*
*
*
COPYRIGHT 1984, 1985, 1986, 1987, 1988
*
*
1989, 1990, 1991, 1992, 1993
*
*
1994, 1995, 1996, 1997, 1998
*
*
*
*
ALL RIGHTS RESERVED
*
*
*
************************************************
SEQUENCE
NUMBER
CARD IMAGES OF THE INPUT DATA
-------- --------------------------------------------------------------------X
C
X
C EOSPAK EXAMPLE PROBLEM #1
X
C GOOD OIL #8 - SPLIT
X
C ------------------------X
C
X
C ---------------------------------------X
C MW OF PLUS FRACTION
183
X
C GRAVITY OF PLUS FRACTION
0.8345
X
C MOLE FRACTION OF PLUS FRACTION
0.1420
X
C CARBON NUMBER OF PLUS FRACTION
7
X
C NUMBER OF GROUP
3
X
C DISTRIBUTION PATAMETER (ALPHA)
1.0
X
C GROUPING MOLECULAR WEIGHTS
125 130
D-174
Landmark - R2003.4
Example Problems
X
C ---------------------------------------X
C
1 S SPLIT
X
C
2 S MWPLUS
GPLUS
ZPLUS
NCOMP
NG
ALPHA
MWGRP
3 S 183
0.8345 0.1420 7
3
1.0
125
300
X
C
4 S END
1HEAVY FRACTION CHARACTERIZATION
-------------------------------
SPLIT ITERATION SUMMARY

----------------------ITR ALPHA M. W.+ GRAV+ NLAST N45 Z45+
MW45+ GV45+
--- ----- ------ ------ ----- --- ------ ------ ------0 1.000 183.0 0.829
45 45 0.0065 656.0 1.0017
CONTROL DATA
-----------MOLECULAR WEIGHT OF THE PLUS FRACTION ......
SPECIFIC GRAVITY OF THE PLUS FRACTION ......
MOLE FRACTION FOR THE HEAVY FRACTION .......
WEIGHT FRACTION FOR THE HEAVY FRACTION .....
CARBON NUMBER OF THE HEAVY FRACTION ........
HIGHEST CARBON NUMBER IN THE DISTRIBUTION ..
FINAL NUMBER OF PSEUDO COMPONENT GROUPS ....
BRACKET MOLECULAR WEIGHTS FOR REGROUPING ...
MWPLUS
GPLUS
ZPLUS
WTPLUS
NCOMP
NLAST
NG
MWGRP
GAMMA DISTRIBUTION ALPHA PARAMETER .........

MINIMUM MOLECULAR WEIGHT IN PLUS FRACTION ..
AVERAGE WATSON CHARACTERIZATION FACTOR .....
MAXIMUM NUMBER OF ITERATIONS ...............
ALPHA
ETA
WAT
MAXIT
CRITICAL
CRITICAL
CRITICAL
CRITICAL
ACENTRIC
SPECIFIC
CORRELATIONS
RIAZI AND DAUBERT
RIAZI AND DAUBERT
RIAZI AND DAUBERT
EDMISTER
SIMULATION
PROPERTIES COMPUTED FROM ..........

TEMPERATURE CORRELATION ...........
PRESSURE CORRELATION ..............
Z-FACTOR CORRELATION ..............
FACTOR CORRELATION ................
GRAVITY AND BOILING POINT DATA ....
R2003.4 - Landmark
MOLE FRACTION
DATA
CALC
------ -----0.0000 0.0175
0.0000 0.0154
0.0000 0.0135
0.0000 0.0118
0.0000 0.0104
0.0000 0.0091
0.0000 0.0080
0.0000 0.0070
0.0000 0.0061
0.0000 0.0054
0.0000 0.0047
0.0000 0.0041
0.0000 0.0036
0.0000 0.0032
0.0000 0.0028
0.0000 0.0024
0.0000 0.0021
0.0000 0.0019
0.0000 0.0016
0.0000 0.0014
0.0000 0.0013
0.0000 0.0011
0.0000 0.0010
0.0000 0.0008
0.0000 0.0007
0.0000 0.0006
0.0000 0.0006
0.0000 0.0005
0.0000 0.0004
WT FRACTION
DATA
CALC
------ -----0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
SPEC
DATA
----0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
300.00000
1.00000
92.00000
0.00000
20
CONSTANT MOLECULAR WEIGHT INTERVAL ......... MWINC

C6 TO C7 MOLECULAR WEIGHT BOUNDARY ......... MWC6C7
SCN MOLE WEIGHT

DATA CALC
--- ----- ----7
0.
98.
8
0. 110.
9
0. 122.
10
0. 134.
11
0. 146.
12
0. 158.
13
0. 170.
14
0. 182.
15
0. 194.
16
0. 206.
17
0. 218.
18
0. 230.
19
0. 242.
20
0. 254.
21
0. 266.
22
0. 278.
23
0. 290.
24
0. 302.
25
0. 314.
26
0. 326.
27
0. 338.
28
0. 350.
29
0. 362.
30
0. 374.
31
0. 386.
32
0. 398.
33
0. 410.
34
0. 422.
35
0. 434.
183.00000
0.83450
0.14200
0.00000
7
45
3
125.00000
12.00000
92.00000
GRAV
BOIL PT F UPPER WAT
CALC DATA CALC MW BD K-FAC
----- ----- ----- ----- ----0.740
0. 218. 104. 11.86
0.754
0. 256. 116. 11.86
0.767
0. 292. 128. 11.86
0.778
0. 327. 140. 11.86
0.789
0. 359. 152. 11.86
0.799
0. 391. 164. 11.86
0.808
0. 421. 176. 11.86
0.817
0. 450. 188. 11.86
0.825
0. 478. 200. 11.86
0.833
0. 506. 212. 11.86
0.841
0. 532. 224. 11.86
0.848
0. 558. 236. 11.86
0.855
0. 583. 248. 11.86
0.861
0. 607. 260. 11.86
0.868
0. 631. 272. 11.86
0.874
0. 654. 284. 11.86
0.880
0. 677. 296. 11.86
0.885
0. 699. 308. 11.86
0.891
0. 720. 320. 11.86
0.896
0. 742. 332. 11.86
0.901
0. 763. 344. 11.86
0.906
0. 783. 356. 11.86
0.911
0. 803. 368. 11.86
0.916
0. 823. 380. 11.86
0.921
0. 843. 392. 11.86
0.925
0. 862. 404. 11.86
0.929
0. 881. 416. 11.86
0.934
0. 899. 428. 11.86
0.938
0. 917. 440. 11.86
D-175
Example Problems
36
0. 446. 0.0000 0.0004 0.0000
37
0. 458. 0.0000 0.0003 0.0000
38
0. 470. 0.0000 0.0003 0.0000
39
0. 482. 0.0000 0.0003 0.0000
40
0. 494. 0.0000 0.0002 0.0000
41
0. 506. 0.0000 0.0002 0.0000
42
0. 518. 0.0000 0.0002 0.0000
43
0. 530. 0.0000 0.0002 0.0000
44
0. 542. 0.0000 0.0001 0.0000
45
0. 656. 0.0000 0.0009 0.0000
1PLUS FRACTION EXTENDED ANALYSIS
------------------------------SCN MOL FRAC
M. W.
NO. MOL FRAC
M. W.
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.942
0.946
0.950
0.954
0.957
0.961
0.965
0.968
0.972
1.002
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
935.
953.
971.
988.
1005.
1022.
1039.
1055.
1071.
1218.
452.
464.
476.
488.
500.
512.
524.
536.
548.
0.
11.86
11.86
11.86
11.86
11.86
11.86
11.86
11.86
11.86
11.86
TC
PC
ZC
AC
GRAV P-R DJK
(F)
(PSIA)
--- -------- ------ -------- -------- ------- ------- ------- ------7 0.01754
97.9
549.83
442.10 0.2651 0.2913 0.7403 0.0368
8 0.01538 109.9
590.04
406.13 0.2590 0.3232 0.7541 0.0388
9 0.01348 121.9
627.43
376.39 0.2536 0.3537 0.7666 0.0405
10 0.01181 133.9
662.45
351.33 0.2488 0.3832 0.7781 0.0421
11 0.01035 145.9
695.46
329.88 0.2445 0.4117 0.7888 0.0436
12 0.00907 157.9
726.71
311.29 0.2406 0.4395 0.7988 0.0450
13 0.00795 169.9
756.43
295.00 0.2371 0.4666 0.8081 0.0463
14 0.00697 181.8
784.68
280.64 0.2338 0.4932 0.8169 0.0476
15 0.00611 193.8
811.82
267.79 0.2308 0.5195 0.8252 0.0487
16 0.00536 205.8
837.86
256.25 0.2280 0.5454 0.8332 0.0498
17 0.00469 217.8
862.91
245.81 0.2254 0.5710 0.8407 0.0509
18 0.00411 229.8
887.07
236.33 0.2230 0.5965 0.8479 0.0519
19 0.00361 241.8
910.41
227.67 0.2207 0.6217 0.8548 0.0529
20 0.00316 253.8
932.99
219.73 0.2185 0.6469 0.8614 0.0538
21 0.00277 265.8
954.88
212.41 0.2165 0.6720 0.8677 0.0547
22 0.00243 277.8
976.12
205.64 0.2146 0.6970 0.8738 0.0555
23 0.00213 289.8
996.76
199.36 0.2127 0.7220 0.8797 0.0564
24 0.00187 301.8 1016.84
193.52 0.2110 0.7470 0.8854 0.0572
25 0.00163 313.8 1036.40
188.06 0.2093 0.7721 0.8909 0.0579
26 0.00143 325.8 1055.48
182.95 0.2077 0.7972 0.8962 0.0587
27 0.00126 337.8 1074.09
178.16 0.2062 0.8225 0.9014 0.0594
28 0.00110 349.7 1092.27
173.66 0.2048 0.8478 0.9064 0.0601
29 0.00096 361.7 1110.04
169.42 0.2034 0.8733 0.9113 0.0608
30 0.00085 373.7 1127.42
165.41 0.2020 0.8989 0.9160 0.0614
31 0.00074 385.7 1144.44
161.62 0.2007 0.9247 0.9206 0.0621
32 0.00065 397.7 1161.12
158.03 0.1995 0.9507 0.9251 0.0627
33 0.00057 409.7 1177.46
154.62 0.1983 0.9769 0.9295 0.0633
34 0.00050 421.7 1193.49
151.38 0.1971 1.0034 0.9338 0.0639
35 0.00044 433.7 1209.22
148.30 0.1960 1.0300 0.9379 0.0645
36 0.00038 445.7 1224.66
145.36 0.1949 1.0570 0.9420 0.0651
37 0.00034 457.7 1239.83
142.56 0.1939 1.0842 0.9460 0.0656
38 0.00029 469.7 1254.74
139.88 0.1929 1.1118 0.9499 0.0662
39 0.00026 481.7 1269.40
137.31 0.1919 1.1396 0.9537 0.0667
40 0.00023 493.7 1283.82
134.86 0.1909 1.1678 0.9574 0.0672
41 0.00020 505.7 1298.01
132.50 0.1900 1.1964 0.9611 0.0678
42 0.00017 517.7 1311.98
130.24 0.1891 1.2253 0.9647 0.0683
43 0.00015 529.7 1325.74
128.07 0.1882 1.2546 0.9682 0.0687
44 0.00013 541.7 1339.29
125.99 0.1874 1.2843 0.9716 0.0692
45 0.00092 656.0 1459.48
109.47 0.1802 1.5921 1.0017 0.0734
1PLUS FRACTION PSEUDOIZATION
--------------------------TC
PC
ZC
AC
GRAV
P-R DJK
(F)
(PSIA)
--- -------- ------ -------- -------- ------- ------- ------- ------1 0.04640 108.8
585.69
411.09 0.2609 0.3200 0.7533 0.0387
2 0.08054 187.5
790.04
283.80 0.2411 0.5033 0.8239 0.0485
3 0.01507 387.4 1138.35
165.63 0.2067 0.9360 0.9243 0.0626
--------------------------------------------------------------------AVG 0.14200 183.0
760.23
312.85 0.2643 0.4893 0.8290 0.0493
PLUS PROPERTIES WRITTEN TO UNIT
D-176
22
Landmark - R2003.4
Example Problems
1
**************************************************************************
*
*
DDDDDD
EEEEEEE
SSSSS
KK
KK TTTTTTTT OOOOO
PPPPPP
*
DD
DD EE
SS
SS KK KK
TT
OO
OO PP
PP
*
DD
DD EE
SS
KK KK
TT
OO
OO PP
PP
*
DD
DD EEEEE
SSSSS
KKKK
TT
OO
OO PPPPPP
*
DD
DD EE
SS KK KK
TT
OO
OO PP
*
DD
DD EE
SS
SS KK KK
TT
OO
OO PP
*
DDDDDD
EEEEEEE
SSSSS
KK
KK
TT
OOOOO
PP
*
*
PPPPPP
VV
VV TTTTTTTT
*
PP
PP
V
V
TT
*
PP
PP
VV VV
TT
*
PPPPPP
V V
TT
*
PP
VVVV
TT
*
PP
VV
TT
*
PP
VV
TT
*
*
*
*
COPYRIGHT 1984, 1985, 1986, 1987, 1988
*
1989, 1990, 1991, 1992, 1993
*
1994, 1995, 1996, 1997
*
*
ALL RIGHTS RESERVED
*
*
VERSION 4.0
CREATED 01 JUN 1997
*
*
LL
AAAAA
N
NN DDDDDD
M
M AAAAA
RRRRRR
KK
KK
*
LL
AA
AA NN
NN DD
DD MM
MM AA
AA RR
RR KK KK
*
LL
AA
AA NNN NN DD
DD M M M M AA
AA RR
RR KK KK
*
LL
AAAAAAA NN N NN DD
KKKK
*
LL
AA
AA NN NNN DD
DD M
M AA
AA RR RR
KK KK
*
LL
AA
AA NN
NN DD
DD M
M AA
AA RR RR
KK KK
*
LLLLLLL AA
AA NN
N DDDDDD
M
M AA
AA RR
RR KK
KK
*
*
GGGGG
RRRRRR
AAAAA
PPPPPP
HH
HH
IIII
CCCCC
SSSSS
*
GG
GG RR
RR AA
AA PP
PP HH
HH
II
CC
CC SS
SS
*
GG
RR
RR AA
AA PP
PP HH
HH
II
CC
SS
*
GG
RRRRRR
AAAAAAA PPPPPP
HHHHHHH
II
CC
SSSSS
*
GG GGG RR RR
AA
AA PP
HH
HH
II
CC
SS
*
GG
GG RR RR
AA
AA PP
HH
HH
II
CC
CC SS
SS
*
GGGGG
RR
RR AA
AA PP
HH
HH
IIII
CCCCC
SSSSS
*
***************************************************************************
1
*********************************************
*
*
*
*
*
*
*
*
*
*
*
VERSION 4.0
*
*
*
*
COPYRIGHT 1984, 1985, 1986, 1987, 1988 *
*
1989, 1990, 1991, 1992, 1993
*
*
1994, 1995, 1996, 1997
*
*
*
*
ALL RIGHTS RESERVED
*
*
*
*********************************************
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
SEQUENCE
NUMBER
-------- --------------------------------------------------------------------X
X
X
X
X
X
X
X
X
X
X
X
X
R2003.4 - Landmark
C
C
C
C
C
C
C
C
C
C
C
C
C
-----------------------------DESKTOP-PVT EXAMPLE PROBLEM #1

GOOD OIL #8 - REGRESSION
VOLATILE OIL EXAMPLE
------------------------------
------------------------REGRESSION VARIABLES ARE:

(1) OMEGA
C8
(2) OMEGB
C8
(3) OMEGA
C14
(4) OMEGB
C14
D-177
Example Problems
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
X
X
X
X
X
X
X
X
X
R
R
R
R
R
R
R
R
R
R
R
R
R
X
R
R
X
R
R
R
R
R
X
R
R
R
R
X
R
X
X
X
X
X
1
2
3
4
5
6
7
8
X
9
10
11
12
X
13
X
X
X
X
X
X
X
14
15
16
17
18
X
X
X
X
X
19
20
21
22
23
X
D-178
C
(5) OMEGA
C30
C
(6) OMEGB
C30
C
(7) DJK C1-C8
C
(8) DJK C1-C14
C
(9) DJK C1-C30
C (10) OMEGA
C1
C (11) OMEGA
C1
C ------------------------C
REGRESS
VARIABLE MIN
INIT
MAX
1
.7
1.
1.3
2
.7
1.
1.3
3
.7
1.
1.3
4
.7
1.
1.3
5
.7
1.
1.3
6
.7
1.
1.3
7
.7
1.
1.3
8
.7
1.
1.3
9
.7
1.
1.3
10
.7
1.
1.3
11
.7
1.
1.3
C
IMAX
IPRINT H
TOL1
TOL2
TOL3
20
0
X
X
X
X
C
COMP
MW
TC
PC
ZC
ACENTRIC
OMEGAA
OMEGAB
C1
X
X
X
X
X
10
11
C8
X
X
X
X
X
1
2
C14
X
X
X
X
X
3
4
C30
X
X
X
X
X
5
6
C
DJK C1
C8 7
C14 8
C30 9
C
ENDREG
C
C ---------------------------------------C INITIALIZE AFTER SPLIT OF HEAVY FRACTION
C ---------------------------------------C
EOS PR
COMPONENTS
CO2 C1 C2 C3 NC4 NC5 C6 C8 C14 C30
PROPERTIES
COMP MW
TC
PC
ZC
ACENTRIC
OMEGAA
OMEGAB
C8
108.82
585.69
411.09 0.26093 0.32000
X
X
C14
187.49
790.04
283.80 0.24105 0.50331
X
X
C30
387.42
1138.35
165.63 0.20672 0.93601
X
X
C
DJK
C1
C8
0.038665
C14
0.048547
C30
0.062598
C
ENDEOS
C
PVTFILE
C
C ------------------C SATURATION PRESSURE
C ------------------C
PSAT
COMPOSITION 0.0584
0.5043
0.0965
0.0875 0.0589 0.0295 0.0229
0.046396 0.080535 0.015069
TEMP
F
276
BPEXP PSIG 4375
C
C -------------C PHASE ENVELOPE
C -------------C
ENVELOPE
COMPOSITION 0.0584
0.5043
0.0965
0.0875 0.0589 0.0295 0.0229
0.046396 0.080535 0.015069
TEMP F
-100 800
10 600 800
10
PSAT PSIG 2000 6000 2000 100 300 100
C
Landmark - R2003.4
X
X
X
X
X
X
X
24
25
26
27
28
29
X
X
X
X
X
X
X
X
X
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
X
X
X
X
X
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
X
X
X
X
X
68
69
70
71
72
73
74
75
76
77
78
R2003.4 - Landmark
C -------------C LIQUID DENSITY

C -------------C
C NOTE: LIQUID DENSITY DATA IS GIVEN IN THE REPORT
C
IN THE CONSTANT COMPOSITION EXPANSION TEST.
C
LIQDEN
COMPOSITION 0.0584
0.5043
0.0965
0.0875 0.0589 0.0295
0.046396 0.080535 0.015069
TEMP 276
F
PRES PSIG 6000 4375
DEXP GM/CC .4924 .4530
C
C -----------------------------C CONSTANT COMPOSITION EXPANSION
C -----------------------------C
C NOTE: XLIQ IS USED BECAUSE DATA IS DEFINED AS
C
LIQUID VOLUME AT PRESSURE RELATIVE TO
C
VOLUME AT SATURATION PRESSURE.
C
CCEXP
COMPOSITION 0.0584
0.5043
0.0965
0.0875 0.0589 0.0295
0.046396 0.080535 0.015069
TEMP 276
F
BUBPT 4375 PSIG
PRES
VREL
XLIQ
ZG
6000
0.9200
X
X
5000
0.9613
X
X
4500
0.9909
X
X
4375
1.0000
1.000
X
4328
1.0052
X
X
4300
X
.651
X
4267
1.0117
X
X
4230
1.0158
X
X
4150
X
.570
X
4059
1.0368
X
X
3960
X
.530
X
3709
1.0883
X
X
3408
1.1472
X
X
2688
1.3595
X
X
1962
1.7834
X
X
1271
2.7310
X
X
951
3.6866
X
X
C
C ------------------------C CONSTANT VOLUME DEPLETION
C ------------------------C
CVDEP
COMPOSITION 0.0584
0.5043
0.0965
0.0875 0.0589 0.0295
0.046396 0.080535 0.015069
TEMP 276
F
BUBPT 4375 PSIG
PRES
4375
3700
3000
2200
1400
700
CO2
.0584 .0632
.0661
.0686
.0695
.0696
C1
.5043 .6053
.6226
.6337
.6263
.5813
C2
.0965 .0996
.1011
.1043
.1089
.1154
C3
.0875 .0827
.0824
.0836
.0883
.1024
C6
.0229 .0142
.0121
.0128
.0107
.0130
MW C8 C30
183
138
129
120
115
116
ZGAS
X
.893
.858
.860
.892
.939
VPROD
X
.08753 .19629 .35179 .52727 .69232
SLIQ
X
.501
.450
.414
.376
.333
C
C -----------------C SURFACE SEPARATION
C -----------------C
SEP
COMPOSITION 0.0584
0.5043
0.0965
0.0875 0.0589 0.0295
0.046396 0.080535 0.015069
TEMP 276
F
BUBPT 4375 PSIG
DNSAT .4530 GM/CC
TSTD 80.
PSTD
0.
BO
2.852
PRES TEMP GORSP GORST SVF GRVG
385.
80.
X
2187.
X
X
Example Problems
0.0229
0.0229
0.0229
0.0229
D-179
Example Problems
79
80
50.
80.
X
0.
80.
X
C
81
END
1NONLINEAR REGRESSION DATA
-------------------------
294.
173.
X
X
X
X
CONTROL VARIABLES
----------------IMAX
---20
IPRINT
-----0
H
------0.2000
TOL1
------0.0010
TOL2
------0.0010
TOL3
------0.0100
INITIAL VALUES OF REGRESSION VARIABLES

----------------------------------------VARIABLE
-------1
2
3
4
5
6
7
8
9
10
11
MINIMUM
------0.7000
0.7000
0.7000
0.7000
0.7000
0.7000
0.7000
0.7000
0.7000
0.7000
0.7000
INITIAL
------1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
MAXIMUM
------1.3000
1.3000
1.3000
1.3000
1.3000
1.3000
1.3000
1.3000
1.3000
1.3000
1.3000
REGRESSION VARIABLE ASSIGNMENTS

------------------------------COMPONENT
NO. NAME
--- -----1
CO2
2
C1
3
C2
4
C3
5
NC4
6
NC5
7
C6
8
C8
9
C14
10
C30
MW
---0
0
0
0
0
0
0
0
0
0
TC
---0
0
0
0
0
0
0
0
0
0
PC
---0
0
0
0
0
0
0
0
0
0
ACENTRIC
FACTOR
-------0
0
0
0
0
0
0
0
0
0
ZC
---0
0
0
0
0
0
0
0
0
0
OMEGA
A
----0
10
0
0
0
0
0
1
3
5
OMEGA
B
----0
11
0
0
0
0
0
2
4
6
PCHOR
----0
0
0
0
0
0
0
0
0
0
VSHFT
-----0
0
0
0
0
0
0
0
0
0
THERE ARE NO REGRESSION VARIABLES CORRESPONDING TO MOLE FRACTIONS.
BINARY INTERACTION COEFFICIENTS

-------------------------------
1
2
3
4
5
6
7
8
9
10
9 10
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7
8
9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
PARAMETERS D AND E FOR VOLUME SHIFT PARAMETER CALCULATION

D
E
0
0
D-180
Landmark - R2003.4
Example Problems
K-COEFFICIENT OF PEDERSEN ET AL. VISCOSITY CORRELATION

K-COEFFICIENT
REGRESSION VARIABLE
------------------------------k(1)
0
k(2)
0
k(3)
0
k(4)
0
k(5)
0
k(6)
0
k(7)
0
BINARY INTERACTION COEFFICIENTS FOR COMPUTING PSEUDOCRITICAL TEMPERATURE OF PEDERSEN ET AL. VISCOSITY CORRELATION
-----------------------------------------------------------------1
1
2
0
3
0 0
4
0 0 0
5
0 0 0 0
6
0 0 0 0
7
0 0 0 0
8
0 0 0 0
9
0 0 0 0
10
0 0 0 0
1EQUATION OF STATE:
9 10
0
0 0
0 0 0
0 0 0 0
0 0 0 0 0
PENG-ROBINSON
COMPONENT PROPERTIES
-------------------COMPONENT
MOLE
TC
PC
CRITICAL ACENTRIC
OMEGA
OMEGA
PCHOR
NO. NAME WEIGHT
DEG F
PSIA
Z-FACTOR FACTOR
A
B
-- ------ ------- -------- -------- -------- -------- -------- -------- ------1 CO2
44.01
87.90 1070.90
0.2742 0.22250 0.45724 0.07780
49.6
2 C1
16.04 -116.60
667.80
0.2890 0.01260 0.45724 0.07780
71.0
3 C2
30.07
90.10
707.80
0.2850 0.09780 0.45724 0.07780
111.0
4 C3
44.10
206.00
616.30
0.2810 0.15410 0.45724 0.07780
151.0
5 NC4
58.12
305.70
550.70
0.2740 0.20150 0.45724 0.07780
191.0
6 NC5
72.15
385.70
488.60
0.2620 0.25240 0.45724 0.07780
231.0
7 C6
84.00
463.00
468.30
0.2698 0.23130 0.45724 0.07780
271.0
8 C8
108.82
585.69
411.09
0.2609 0.32000 0.45724 0.07780
351.0
9 C14
187.49
790.04
283.80
0.2411 0.50331 0.45724 0.07780
591.9
10 C30
387.42 1138.35
165.63
0.2067 0.93601 0.45724 0.07780 1236.7
NUMBER OF VOLATILE COMPONENTS:
10

------------------------------1
1
2
3
4
5
6
7
8
9
10
0.1500
0.1500
0.1500
0.1500
0.1500
0.1500
0.1500
0.1500
0.1500
0.0000
0.0000
0.0200
0.0200
0.0298
0.0387
0.0485
0.0626
0.0000
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0000
0.0000
0.0000
0.0000
0.0000
10
0.0000
0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
k-COEFFICIENT OF THE PEDERSEN ET AL. VISCOSITY CORRELATION

---------------------------------------------------------NO.
----k(1)
k(2)
k(3)
k(4)
k(5)
k(6)
k(7)
R2003.4 - Landmark
K-COEFFICIENT
--------------0.9746020E+01
0.1808340E+02
0.4126660E+04
0.4460550E+02
0.9765440E+00
0.8181340E+02
0.1564990E+05
D-181
Example Problems
BINARY INTERACTION COEFFICIENTS FOR THE

PEDERSEN ET AL. VISCOSITY CORRELATION
--------------------------------------1
1
2
3
4
5
6
7
8
9
10
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
10
0.0000
0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
CORRELATION OF SOLUBILITY OF CO2 IN WATER

----------------------------------------Rsw(pure water) = A*P*( 1 - B*sin(C*P/(C*P+1) )
A = A0 + A1*T + A2*T**2 + A3*T**3 + A4*T**4
B = B0 + B1*T + B2*T**2 + B3*T**3 + B4*T**4
C = A0 + C1*T + C2*T**2 + C3*T**3 + C4*T**4
log( Rsw[brine]/Rsw[pure water] ) = S0 * S * T**S1
where Rsw
P
T
S
in
in
in
in
A0
1.1630599
B0
0.9650900
C0
1.2803000
S0
-0.0280370
scf/stb
psia
degree F
weight percent solid
A1
-16.6303997
B1
-0.2725500
C1
-10.7566004
S1
-0.1203900
A2
111.0730515
B2
0.0923400
C2
52.6962204
A3
-376.8592529
B3
-0.1008300
C3
-222.3948822
A4
524.8891602
B4
0.0997900
C4
462.6725464
CORRELATION OF DENSITY OF CO2 SATURATED WATER

---------------------------------------------Den(lb/cu ft) = Den,1atm(lb/cuft) + 0.001 * D1 * Rsw(scf/stb)
D1 =
5.80000
IDEAL GAS STATE ENTHALPY COEFFICIENTS

------------------------------------H* = A + B*T + C*(T**2) + D*(T**3) + E*(T**4) + F*(T**5)
WHERE THE UNITS ARE
H* - BTU / LB-MOLE
T
- DEGREES RANKIN
COMPONENT
NO NAME
-- -----1 CO2
2 C1
3 C2
4 C3
5 NC4
6 NC5
7 C6
8 C8
9 C14
10 C30
A
B
C
D
---------- ---------- ---------- ---------0.210E+03 0.504E+01 0.445E-02 -0.117E-05
-0.112E+03 0.917E+01 -0.472E-02 0.679E-05
-0.631E+00 0.796E+01 -0.752E-03 0.879E-05
-0.325E+02 0.761E+01 0.415E-02 0.950E-05
0.432E+03 0.573E+01 0.156E-01 0.301E-05
0.196E+04 -0.202E+00 0.318E-01 -0.623E-05
0.000E+00 0.242E+01 0.343E-01 -0.477E-05
0.000E+00 0.392E+01 0.447E-01 -0.629E-05
0.000E+00 0.297E+01 0.741E-01 -0.974E-05
0.000E+00 0.111E+03 0.215E+00 -0.360E-04
E
F
---------- ---------0.153E-09 -0.578E-14
-0.245E-08 0.312E-12
-0.387E-08 0.548E-12
-0.472E-08 0.702E-12
-0.244E-08 0.381E-12
0.590E-09 -0.142E-13
0.000E+00 0.000E+00
0.000E+00 0.000E+00
0.000E+00 0.000E+00
0.000E+00 0.000E+00
PVT PROPERTIES FORMATTED FOR SIMULATOR INPUT HAVE BEEN WRITTEN TO UNIT
1SATURATION PRESSURE CALCULATION
-------------------------------
COMPONENT
--------CO2
C1
C2
C3
NC4
D-182
22
MOLE FRACTION
------------0.05840
0.50430
0.09650
0.08750
0.05890
Landmark - R2003.4
NC5
C6
C8
C14
C30
Example Problems
0.02950
0.02290
0.04640
0.08054
0.01507
TEMPERATURE SATURATION PRESSURE (PSIG )

DEGREES F
DATA
CALC
TYPE
----------- -------- ----------276.00
4375.000 3919.877
BP
1CALCULATED COMPOSITIONS:
-----------------------P = 3919.9 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.85827 YY = 0.64949E-01
0.22724E-01
ZX = 0.88908 XX = 0.58400E-01
0.29500E-01
KV = 0.11121E+01
0.77032E+00
1PHASE ENVELOPE CALCULATION
--------------------------
COMPONENT
--------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
TEMPERATURE
DEGREES F
-----------100.00
-90.00
-80.00
-70.00
-60.00
-50.00
-40.00
-30.00
-20.00
-10.00
0.00
10.00
20.00
30.00
40.00
50.00
60.00
70.00
80.00
90.00
100.00
110.00
120.00
130.00
140.00
150.00
160.00
170.00
180.00
190.00
200.00
210.00
220.00
230.00
240.00
250.00
260.00
R2003.4 - Landmark
0.50430E+00
0.22900E-01
0.60176E+00
0.16209E-01
0.50430E+00
0.22900E-01
0.11933E+01
0.70783E+00
DEN AT PSAT (LB/FT3)

DATA
CALC
-------- -------0.0000
28.5103
0.96500E-01
0.46396E-01
0.98682E-01
0.27810E-01
0.96500E-01
0.46396E-01
0.10226E+01
0.59941E+00
Z-FAC AT PSAT
DATA
CALC
------ -----0.0000 0.8891
0.87500E-01
0.80535E-01
0.81770E-01
0.34297E-01
0.87500E-01
0.80535E-01
0.93451E+00
0.42586E+00
0.58900E-01
0.15069E-01
0.49343E-01
0.24527E-02
0.58900E-01
0.15069E-01
0.83774E+00
0.16276E+00
MOLE FRACTION
------------0.05840
0.50430
0.09650
0.08750
0.05890
0.02950
0.02290
0.04640
0.08054
0.01507
SATURATION PRESSURE (PSIG )

ESTIMATE
COMPUTED
TYPE
-------------------** NONE FOUND **
** NONE FOUND **
** NONE FOUND **
2000.000
842.706
BUBPT
** NONE FOUND **
** NONE FOUND **
2000.000
1221.923
BUBPT
2000.000
1362.726
BUBPT
2000.000
1505.560
BUBPT
4000.000
1647.812
BUBPT
4000.000
1787.778
BUBPT
4000.000
1924.407
BUBPT
4000.000
2057.060
BUBPT
4000.000
2185.349
BUBPT
4000.000
2309.043
BUBPT
4000.000
2428.013
BUBPT
4000.000
2542.194
BUBPT
4000.000
2651.565
BUBPT
4000.000
2756.138
BUBPT
4000.000
2855.942
BUBPT
4000.000
2951.023
BUBPT
4000.000
3041.434
BUBPT
6000.000
3127.238
BUBPT
6000.000
3208.498
BUBPT
6000.000
3285.283
BUBPT
6000.000
3357.661
BUBPT
6000.000
3425.703
BUBPT
6000.000
3489.477
BUBPT
6000.000
3549.052
BUBPT
6000.000
3604.495
BUBPT
6000.000
3655.872
BUBPT
6000.000
3703.248
BUBPT
6000.000
3746.685
BUBPT
6000.000
3786.243
BUBPT
6000.000
3821.982
BUBPT
6000.000
3853.959
BUBPT
6000.000
3882.228
BUBPT
D-183
Example Problems
270.00
6000.000
3906.842
BUBPT
280.00
6000.000
3927.852
BUBPT
290.00
6000.000
3945.306
BUBPT
300.00
6000.000
3959.250
BUBPT
310.00
6000.000
3969.730
BUBPT
320.00
6000.000
3976.788
BUBPT
330.00
6000.000
3980.462
BUBPT
340.00
6000.000
3980.792
BUBPT
350.00
6000.000
3977.812
BUBPT
360.00
6000.000
3971.557
BUBPT
370.00
6000.000
3962.058
BUBPT
380.00
6000.000
3949.342
BUBPT
390.00
6000.000
3933.436
BUBPT
400.00
6000.000
3914.364
BUBPT
410.00
6000.000
3892.147
BUBPT
420.00
6000.000
3866.802
BUBPT
430.00
4000.000
3838.345
DEWPT
440.00
4000.000
3806.787
DEWPT
450.00
4000.000
3772.137
DEWPT
460.00
4000.000
3734.398
DEWPT
470.00
4000.000
3693.571
DEWPT
480.00
4000.000
3649.651
DEWPT
490.00
4000.000
3602.628
DEWPT
500.00
4000.000
3552.487
DEWPT
510.00
4000.000
3499.206
DEWPT
520.00
4000.000
3442.754
DEWPT
530.00
4000.000
3383.093
DEWPT
540.00
4000.000
3320.174
DEWPT
550.00
4000.000
3253.937
DEWPT
560.00
4000.000
3184.308
DEWPT
570.00
4000.000
3111.193
DEWPT
580.00
4000.000
3034.481
DEWPT
590.00
4000.000
2954.034
DEWPT
600.00
4000.000
2869.682
DEWPT
610.00
4000.000
2781.214
DEWPT
620.00
4000.000
2688.367
DEWPT
630.00
4000.000
2590.808
DEWPT
640.00
4000.000
2488.109
DEWPT
650.00
4000.000
2379.707
DEWPT
660.00
4000.000
2264.846
DEWPT
670.00
4000.000
2142.469
DEWPT
680.00
4000.000
2011.038
DEWPT
690.00
4000.000
1868.153
DEWPT
700.00
4000.000
1709.715
DEWPT
710.00
4000.000
1527.542
DEWPT
720.00
4000.000
1299.471
DEWPT
730.00
** NONE FOUND **
740.00
** NONE FOUND **
750.00
** NONE FOUND **
760.00
** NONE FOUND **
770.00
** NONE FOUND **
780.00
** NONE FOUND **
790.00
** NONE FOUND **
800.00
** NONE FOUND **
800.00
** NONE FOUND **
790.00
** NONE FOUND **
780.00
** NONE FOUND **
770.00
** NONE FOUND **
760.00
** NONE FOUND **
750.00
** NONE FOUND **
740.00
** NONE FOUND **
730.00
** NONE FOUND **
720.00
100.000
518.064
DEWPT
710.00
100.000
393.076
DEWPT
700.00
100.000
311.905
DEWPT
690.00
100.000
252.350
DEWPT
680.00
100.000
206.187
DEWPT
670.00
100.000
169.276
DEWPT
660.00
100.000
139.179
DEWPT
650.00
100.000
114.315
DEWPT
640.00
100.000
93.591
DEWPT
630.00
100.000
76.210
DEWPT
620.00
100.000
61.573
DEWPT
610.00
100.000
49.215
DEWPT
600.00
** ONLY DUPLICATE FOUND **
1LIQUID DENSITY CALCULATION
--------------------------
COMPONENT
---------
D-184
MOLE FRACTION
-------------
Landmark - R2003.4
Example Problems
CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
0.05840
0.50430
0.09650
0.08750
0.05890
0.02950
0.02290
0.04640
0.08054
0.01507
TEMPERATURE PRESSURE LIQUID DEN (GM/CC ) ---- Z-FACTOR ---DEGREES F

PSIG
DATA
CALC
DATA
CALC
----------- -------- -------- --------- -------- -------276.00 6000.000
0.4924
0.5079
0.00000
1.22203
4375.000
0.4530
0.4704
0.00000
0.96307
1CONSTANT COMPOSITION EXPANSION
------------------------------
COMPONENT
--------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
MOLE FRACTION
------------0.05840
0.50430
0.09650
0.08750
0.05890
0.02950
0.02290
0.04640
0.08054
0.01507
SATURATION PRESSURE:
FLASH CALCULATIONS:
VISCOSITY CORRELATION:
NEWTON-RAPHSON
NEWTON-RAPHSON
LOHRENZ, BRAY AND CLARK
TEMPERATURE
276.00 DEGREES F
OBSERVED PSAT
CALCULATED PSAT
OBSERVED Z-FACTOR AT PSAT
CALCULATED Z-FACTOR AT PSAT
OIL DENSITY AT PSAT
GAS DENSITY AT PSAT
= 4375.00 PSIG
= 3919.88 PSIG
= 0.0000
= 0.8891
= 0.4567 GM/CC
= 0.3288 GM/CC
(BUBPT)
(BUBPT)
PRES
REL. VOLUME
LIQ VOL FRAC
LIQ MOLE FRAC
------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ -----6000.0 0.9200 0.8991 0.0000 0.8991 0.0000 1.0000
5000.0 0.9613 0.9386 0.0000 0.9386 0.0000 1.0000
4500.0 0.9909 0.9638 0.0000 0.9638 0.0000 1.0000
4375.0 1.0000 0.9709 1.0000 0.9709 0.0000 1.0000
4328.0 1.0052 0.9737 0.0000 0.9737 0.0000 1.0000
4300.0 0.0000 0.9753 0.6510 0.9753 0.0000 1.0000
4267.0 1.0117 0.9773 0.0000 0.9773 0.0000 1.0000
4230.0 1.0158 0.9796 0.0000 0.9796 0.0000 1.0000
4150.0 0.0000 0.9846 0.5700 0.9846 0.0000 1.0000
4059.0 1.0368 0.9905 0.0000 0.9905 0.0000 1.0000
3960.0 0.0000 0.9972 0.5300 0.9972 0.0000 1.0000
3709.0 1.0883 1.0310 0.0000 0.8338 0.0000 0.8034
3408.0 1.1472 1.0847 0.0000 0.7258 0.0000 0.6657
2688.0 1.3595 1.2817 0.0000 0.6033 0.0000 0.4938
1962.0 1.7834 1.6740 0.0000 0.5286 0.0000 0.3834
1271.0 2.7310 2.5538 0.0000 0.4666 0.0000 0.2963
951.0 3.6866 3.4459 0.0000 0.4363 0.0000 0.2573
PRES
OIL Z-FACTOR
GAS Z-FACTOR
OIL DENSITY
GAS DENSITY
------- --------------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ ------ ------ -----6000.0 0.0000 1.2220 0.0000 0.0000 0.0000 0.5079 0.0000 0.0000
5000.0 0.0000 1.0636 0.0000 0.0000 0.0000 0.4866 0.0000 0.0000
4500.0 0.0000 0.9833 0.0000 0.0000 0.0000 0.4738 0.0000 0.0000
4375.0 0.0000 0.9631 0.0000 0.0000 0.0000 0.4704 0.0000 0.0000
4328.0 0.0000 0.9555 0.0000 0.0000 0.0000 0.4690 0.0000 0.0000
4300.0 0.0000 0.9509 0.0000 0.0000 0.0000 0.4682 0.0000 0.0000
R2003.4 - Landmark
D-185
Example Problems
4267.0
4230.0
4150.0
4059.0
3960.0
3709.0
3408.0
2688.0
1962.0
1271.0
951.0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.9456
0.9396
0.9266
0.9118
0.8956
0.8733
0.8433
0.7462
0.6158
0.4575
0.3701
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.8440
0.8303
0.8184
0.8298
0.8618
0.8842
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.4673
0.4662
0.4638
0.4611
0.4580
0.4770
0.4989
0.5393
0.5746
0.6080
0.6245
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.2989
0.2636
0.1936
0.1336
0.0829
0.0612
PRES
OIL VISCOSITY
GAS VISCOSITY
SURF TENS
------- --------------- --------------- ----------PSIG
DATA
CALC
DATA
CALC
DYNE/CM
------- ------ ------ ------ ------ ----------6000.0 0.0000 0.0850 0.0000 0.0000 0.0000E+00
5000.0 0.0000 0.0754 0.0000 0.0000 0.0000E+00
4500.0 0.0000 0.0705 0.0000 0.0000 0.0000E+00
4375.0 0.0000 0.0693 0.0000 0.0000 0.0000E+00
4328.0 0.0000 0.0688 0.0000 0.0000 0.0000E+00
4300.0 0.0000 0.0686 0.0000 0.0000 0.0000E+00
4267.0 0.0000 0.0683 0.0000 0.0000 0.0000E+00
4230.0 0.0000 0.0679 0.0000 0.0000 0.0000E+00
4150.0 0.0000 0.0671 0.0000 0.0000 0.0000E+00
4059.0 0.0000 0.0662 0.0000 0.0000 0.0000E+00
3960.0 0.0000 0.0652 0.0000 0.0000 0.0000E+00
3709.0 0.0000 0.0706 0.0000 0.0358 0.9039E-01
3408.0 0.0000 0.0776 0.0000 0.0314 0.2797E+00
2688.0 0.0000 0.0934 0.0000 0.0239 0.1355E+01
1962.0 0.0000 0.1110 0.0000 0.0190 0.3711E+01
1271.0 0.0000 0.1315 0.0000 0.0160 0.7633E+01
951.0 0.0000 0.1429 0.0000 0.0151 0.1019E+02
1OIL PHASE EXPERIMENTAL DATA
---------------------------
OIL COMP
-------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
PRESSURE - PSIG
----------------6000. 5000. 4500.
3960. 3709. 3408.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
4375.
2688.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4328.
1962.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4300.
1271.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4267.
951.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4328.
1962.
-----0.0584
0.0385
0.5043
0.2723
0.0965
0.0822
0.0875
0.0957
0.0589
4300.
1271.
-----0.0584
0.0276
0.5043
0.1803
0.0965
0.0668
0.0875
0.0889
0.0589
4267.
951.
-----0.0584
0.0215
0.5043
0.1353
0.0965
0.0557
0.0875
0.0801
0.0589
4230.
4150.
4059.
------ ------ -----0.0000 0.0000 0.0000

0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
SIMULATED OIL PHASE COMPOSITIONS

--------------------------------
OIL COMP
-------CO2
C1
C2
C3
NC4
D-186
PRESSURE - PSIG
----------------6000. 5000. 4500.
3960. 3709. 3408.
------ ------ -----0.0584 0.0584 0.0584
0.0584 0.0565 0.0540
0.5043 0.5043 0.5043
0.5043 0.4773 0.4425
0.0965 0.0965 0.0965
0.0965 0.0958 0.0947
0.0875 0.0875 0.0875
0.0875 0.0891 0.0910
0.0589 0.0589 0.0589
4375.
2688.
-----0.0584
0.0473
0.5043
0.3608
0.0965
0.0906
0.0875
0.0947
0.0589
4230.
4150.
4059.
------ ------ -----0.0584 0.0584 0.0584

0.5043 0.5043 0.5043
0.0965 0.0965 0.0965
0.0875 0.0875 0.0875
0.0589 0.0589 0.0589
Landmark - R2003.4
0.0589 0.0616 0.0650

0.0295 0.0295 0.0295
0.0295 0.0314 0.0339
C6
0.0229 0.0229 0.0229
0.0229 0.0248 0.0273
C8
0.0464 0.0464 0.0464
0.0464 0.0516 0.0587
C14
0.0805 0.0805 0.0805
0.0805 0.0935 0.1104
C30
0.0151 0.0151 0.0151
0.0151 0.0184 0.0223
1GAS PHASE EXPERIMENTAL DATA
--------------------------NC5
GAS COMP
-------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
PRESSURE - PSIG
----------------6000. 5000. 4500.
3960. 3709. 3408.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
Example Problems
0.0733
0.0295
0.0403
0.0229
0.0338
0.0464
0.0769
0.0805
0.1519
0.0151
0.0304
0.0814
0.0295
0.0478
0.0229
0.0418
0.0464
0.0999
0.0805
0.2012
0.0151
0.0393
0.0857
0.0295
0.0549
0.0229
0.0508
0.0464
0.1295
0.0805
0.2647
0.0151
0.0508
0.0835
0.0295
0.0569
0.0229
0.0550
0.0464
0.1472
0.0805
0.3061
0.0151
0.0586
4375.
2688.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4328.
1962.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4300.
1271.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4267.
951.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0295 0.0295 0.0295

0.0229 0.0229 0.0229
0.0464 0.0464 0.0464
0.0805 0.0805 0.0805
0.0151 0.0151 0.0151
4230.
4150.
4059.
------ ------ -----0.0000 0.0000 0.0000

0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
SIMULATED GAS PHASE COMPOSITIONS

-------------------------------PRESSURE - PSIG
----------------GAS COMP
6000. 5000. 4500. 4375. 4328. 4300. 4267. 4230.
3960. 3709. 3408. 2688. 1962. 1271.
951.
-------- ------ ------ ------ ------ ------ ------ ------ -----CO2
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0660 0.0671 0.0693 0.0708 0.0714 0.0712
C1
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.6148 0.6274 0.6443 0.6486 0.6408 0.6321
C2
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0992 0.1000 0.1023 0.1054 0.1090 0.1106
C3
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0811 0.0805 0.0805 0.0824 0.0869 0.0901
NC4
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0480 0.0467 0.0449 0.0449 0.0476 0.0504
NC5
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0217 0.0206 0.0189 0.0181 0.0188 0.0200
C6
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0152 0.0141 0.0123 0.0112 0.0111 0.0118
C8
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0250 0.0219 0.0167 0.0131 0.0114 0.0115
C14
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0277 0.0210 0.0109 0.0055 0.0030 0.0024
C30
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0014 0.0006 0.0001 0.0000 0.0000 0.0000
-----------------------0 P = 3709.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01
ZY = 0.84401 YY = 0.65990E-01 0.61476E+00 0.99227E-01 0.81073E-01
0.21713E-01 0.15196E-01 0.24981E-01 0.27682E-01
ZX = 0.87330 XX = 0.56543E-01 0.47727E+00 0.95833E-01 0.89073E-01
0.31406E-01 0.24785E-01 0.51636E-01 0.93468E-01
KV = 0.11671E+01 0.12881E+01 0.10354E+01 0.91019E+00
0.69137E+00 0.61312E+00 0.48380E+00 0.29617E+00
0 P = 3408.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01
R2003.4 - Landmark
4150.
4059.
------ -----0.0000 0.0000

0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.58900E-01
0.15069E-01
0.48000E-01
0.13727E-02
0.61567E-01
0.18421E-01
0.77963E+00
0.74518E-01
0.58900E-01
0.15069E-01
D-187
Example Problems
ZY = 0.83034 YY = 0.67144E-01
0.20644E-01
ZX = 0.84326 XX = 0.54009E-01
0.33947E-01
KV = 0.12432E+01
0.60811E+00
0 P = 2688.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.81840 YY = 0.69261E-01
0.18917E-01
ZX = 0.74618 XX = 0.47266E-01
0.40349E-01
KV = 0.14654E+01
0.46883E+00
0 P = 1962.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.82979 YY = 0.70775E-01
0.18139E-01
ZX = 0.61576 XX = 0.38501E-01
0.47769E-01
KV = 0.18383E+01
0.37973E+00
0 P = 1271.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.86175 YY = 0.71389E-01
0.18795E-01
ZX = 0.45748 XX = 0.27557E-01
0.54918E-01
KV = 0.25906E+01
0.34225E+00
0 P =
951.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.88421 YY = 0.71186E-01
0.19998E-01
ZX = 0.37009 XX = 0.21484E-01
0.56935E-01
KV = 0.33134E+01
0.35123E+00
1CONSTANT VOLUME DEPLETION
-------------------------
COMPONENT
--------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
0.62738E+00
0.14110E-01
0.44249E+00
0.27314E-01
0.14178E+01
0.51658E+00
0.50430E+00
0.22900E-01
0.64430E+00
0.12262E-01
0.36079E+00
0.33806E-01
0.17858E+01
0.36271E+00
0.50430E+00
0.22900E-01
0.64855E+00
0.11166E-01
0.27232E+00
0.41769E-01
0.23816E+01
0.26732E+00
0.50430E+00
0.22900E-01
0.64076E+00
0.11137E-01
0.18028E+00
0.50831E-01
0.35543E+01
0.21909E+00
0.50430E+00
0.22900E-01
0.63209E+00
0.11796E-01
0.13533E+00
0.54959E-01
0.46706E+01
0.21464E+00
0.10001E+00
0.21939E-01
0.94739E-01
0.58677E-01
0.10556E+01
0.37389E+00
0.96500E-01
0.46396E-01
0.10227E+00
0.16670E-01
0.90585E-01
0.76869E-01
0.11290E+01
0.21686E+00
0.96500E-01
0.46396E-01
0.10538E+00
0.13117E-01
0.82225E-01
0.99912E-01
0.12816E+01
0.13128E+00
0.96500E-01
0.46396E-01
0.10900E+00
0.11395E-01
0.66813E-01
0.12950E+00
0.16315E+01
0.87992E-01
0.96500E-01
0.46396E-01
0.11062E+00
0.11489E-01
0.55725E-01
0.14718E+00
0.19851E+01
0.78063E-01
0.80500E-01
0.20983E-01
0.91015E-01
0.11044E+00
0.88448E+00
0.18999E+00
0.87500E-01
0.80535E-01
0.80452E-01
0.10908E-01
0.94725E-01
0.15191E+00
0.84932E+00
0.71805E-01
0.87500E-01
0.80535E-01
0.82428E-01
0.55134E-02
0.95657E-01
0.20118E+00
0.86171E+00
0.27406E-01
0.87500E-01
0.80535E-01
0.86910E-01
0.29821E-02
0.88901E-01
0.26468E+00
0.97761E+00
0.11267E-01
0.87500E-01
0.80535E-01
0.90055E-01
0.23924E-02
0.80125E-01
0.30615E+00
0.11239E+01
0.78145E-02
0.46657E-01
0.63298E-03
0.65048E-01
0.22318E-01
0.71727E+00
0.28362E-01
0.58900E-01
0.15069E-01
0.44865E-01
0.98405E-04
0.73288E-01
0.30415E-01
0.61217E+00
0.32354E-02
0.58900E-01
0.15069E-01
0.44917E-01
0.13377E-04
0.81386E-01
0.39280E-01
0.55189E+00
0.34055E-03
0.58900E-01
0.15069E-01
0.47626E-01
0.18192E-05
0.85670E-01
0.50846E-01
0.55592E+00
0.35779E-04
0.58900E-01
0.15069E-01
0.50367E-01
0.73112E-06
0.83537E-01
0.58574E-01
0.60293E+00
0.12482E-04
MOLE FRACTION
------------0.05840
0.50430
0.09650
0.08750
0.05890
0.02950
0.02290
0.04640
0.08054
0.01507
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
276.00 DEGREES F
OBSERVED PSAT
CALCULATED PSAT
OIL DENSITY AT PSAT
GAS DENSITY AT PSAT
= 4375.00 PSIG
= 3919.88 PSIG
= 0.0000
= 0.8891
= 0.4567 GM/CC
= 0.3288 GM/CC
(BUBPT)
(BUBPT)
PRES MW(C8
-C30 )
CUM GAS PROD
LIQ VOL FRAC
LIQ MOLE FRAC
------- --------------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ ------ ------ -----4375.0 183.00
0.00 0.0000 0.0000 0.0000 1.0000 0.0000 1.0000
3700.0 138.00 156.01 0.0875 0.0323 0.5010 0.8293 0.0000 0.7978
3000.0 129.00 144.84 0.1963 0.1509 0.4500 0.6418 0.0000 0.5517
2200.0 120.00 135.08 0.3518 0.3127 0.4140 0.5405 0.0000 0.4080
1400.0 115.00 126.64 0.5273 0.4956 0.3760 0.4658 0.0000 0.3040
700.0 116.00 120.68 0.6923 0.6672 0.3330 0.4051 0.0000 0.2258
D-188
Landmark - R2003.4
Example Problems
PRES
OIL Z-FACTOR
GAS Z-FACTOR
OIL DENSITY
------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ -----4375.0 0.0000 0.9631 0.0000 0.0000 0.0000 0.4704
3700.0 0.0000 0.8725 0.8930 0.8435 0.0000 0.4778
3000.0 0.0000 0.7924 0.8580 0.8205 0.0000 0.5231
2200.0 0.0000 0.6629 0.8600 0.8234 0.0000 0.5636
1400.0 0.0000 0.4898 0.8920 0.8520 0.0000 0.6012
700.0 0.0000 0.2897 0.9390 0.8986 0.0000 0.6352
PRES
OIL VISCOSITY
GAS VISCOSITY
SURF TENS
------- --------------- --------------- ----------PSIG
DATA
CALC
DATA
CALC
DYNE/CM
------- ------ ------ ------ ------ ----------4375.0 0.0000 0.0693 0.0000 0.0000 0.0000E+00
3700.0 0.0000 0.0708 0.0000 0.0356 0.9434E-01
3000.0 0.0000 0.0865 0.0000 0.0267 0.7651E+00
2200.0 0.0000 0.1051 0.0000 0.0204 0.2773E+01
1400.0 0.0000 0.1269 0.0000 0.0165 0.6693E+01
700.0 0.0000 0.1501 0.0000 0.0144 0.1223E+02
---------------------------
OIL COMP
-------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
PRESSURE - PSIG
--------------4375. 3700. 3000.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
2200.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1400.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
700.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
2200.
-----0.0417
0.3016
0.0860
0.0962
0.0790
0.0452
0.0388
0.0911
0.1835
0.0367
1400.
-----0.0301
0.1965
0.0720
0.0933
0.0869
0.0539
0.0487
0.1208
0.2484
0.0493
700.
-----0.0165
0.0960
0.0479
0.0763
0.0857
0.0602
0.0587
0.1576
0.3347
0.0664
2200.
-----0.0686
0.6337
0.1043
0.0836
0.0000
0.0000
0.0128
0.0000
0.0000
0.0000
1400.
-----0.0695
0.6263
0.1089
0.0883
0.0000
0.0000
0.0107
0.0000
0.0000
0.0000
700.
-----0.0696
0.5813
0.1154
0.1024
0.0000
0.0000
0.0130
0.0000
0.0000
0.0000
OIL PHASE SIMULATED DATA

-----------------------PRESSURE - PSIG
--------------OIL COMP
4375. 3700. 3000.
-------- ------ ------ -----CO2
0.0584 0.0565 0.0504
C1
0.5043 0.4762 0.3965
C2
0.0965 0.0958 0.0928
C3
0.0875 0.0891 0.0933
NC4
0.0589 0.0617 0.0697
NC5
0.0295 0.0315 0.0375
C6
0.0229 0.0249 0.0309
C8
0.0464 0.0518 0.0686
C14
0.0805 0.0940 0.1334
C30
0.0151 0.0185 0.0271
---------------------------
PRODUCED
GAS COMP
-------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
PRESSURE - PSIG
--------------4375. 3700. 3000.
------ ------ -----0.0584 0.0632 0.0661
0.5043 0.6053 0.6226
0.0965 0.0996 0.1011
0.0875 0.0827 0.0824
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0229 0.0142 0.0121
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
GAS PHASE SIMULATED DATA

-----------------------PRESSURE - PSIG
R2003.4 - Landmark
D-189
Example Problems
PRODUCED --------------GAS COMP

4375. 3700. 3000. 2200. 1400.
700.
-------- ------ ------ ------ ------ ------ -----CO2
0.0000 0.0660 0.0684 0.0705 0.0720 0.0712
C1
0.0000 0.6152 0.6387 0.6475 0.6370 0.5949
C2
0.0000 0.0992 0.1012 0.1047 0.1107 0.1194
C3
0.0000 0.0811 0.0803 0.0818 0.0880 0.1033
NC4
0.0000 0.0480 0.0454 0.0447 0.0478 0.0597
NC5
0.0000 0.0217 0.0195 0.0183 0.0187 0.0234
C6
0.0000 0.0152 0.0130 0.0114 0.0110 0.0135
C8
0.0000 0.0249 0.0187 0.0140 0.0114 0.0123
C14
0.0000 0.0274 0.0145 0.0069 0.0033 0.0022
C30
0.0000 0.0013 0.0002 0.0000 0.0000 0.0000
-----------------------0 P = 3700.0 ZZ = 0.58145E-01 0.50060E+00 0.96408E-01
0.29761E-01 0.23158E-01 0.47114E-01
ZY = 0.84350 YY = 0.66029E-01 0.61522E+00 0.99249E-01
0.21676E-01 0.15159E-01 0.24878E-01
ZX = 0.87251 XX = 0.56467E-01 0.47619E+00 0.95803E-01
0.31483E-01 0.24862E-01 0.51850E-01
KV = 0.11693E+01 0.12920E+01 0.10360E+01
0.68850E+00 0.60973E+00 0.47981E+00
0 P = 3000.0 ZZ = 0.56707E-01 0.48131E+00 0.95733E-01
0.31188E-01 0.24583E-01 0.51085E-01
ZY = 0.82051 YY = 0.68447E-01 0.63869E+00 0.10124E+00
0.19543E-01 0.12957E-01 0.18684E-01
ZX = 0.79245 XX = 0.50377E-01 0.39646E+00 0.92762E-01
0.37466E-01 0.30851E-01 0.68553E-01
KV = 0.13587E+01 0.16110E+01 0.10914E+01
0.52162E+00 0.41997E+00 0.27255E+00
0 P = 2200.0 ZZ = 0.53449E-01 0.44219E+00 0.93611E-01
0.34233E-01 0.27686E-01 0.59806E-01
ZY = 0.82335 YY = 0.70544E-01 0.64749E+00 0.10475E+00
0.18257E-01 0.11403E-01 0.14039E-01
ZX = 0.66295 XX = 0.41747E-01 0.30165E+00 0.85988E-01
0.45169E-01 0.38833E-01 0.91138E-01
KV = 0.16898E+01 0.21465E+01 0.12181E+01
0.40419E+00 0.29363E+00 0.15404E+00
0 P = 1400.0 ZZ = 0.46738E-01 0.37155E+00 0.87408E-01
0.39878E-01 0.33729E-01 0.77339E-01
ZY = 0.85205 YY = 0.71963E-01 0.63705E+00 0.11072E+00
0.18660E-01 0.11016E-01 0.11440E-01
ZX = 0.48978 XX = 0.30108E-01 0.19653E+00 0.72035E-01
0.53865E-01 0.48704E-01 0.12078E+00
KV = 0.23901E+01 0.32415E+01 0.15371E+01
0.34642E+00 0.22618E+00 0.94716E-01
0 P =
700.0 ZZ = 0.34098E-01 0.25633E+00 0.70891E-01
0.48357E-01 0.44159E-01 0.11090E+00
ZY = 0.89862 YY = 0.71237E-01 0.59490E+00 0.11942E+00
0.23443E-01 0.13514E-01 0.12287E-01
ZX = 0.28967 XX = 0.16516E-01 0.96040E-01 0.47917E-01
0.60151E-01 0.58667E-01 0.15759E+00
KV = 0.43132E+01 0.61942E+01 0.24922E+01
0.38974E+00 0.23035E+00 0.77968E-01
1SEPARATOR CALCULATION
---------------------
COMPONENT
--------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
0.59265E-01
0.15527E-01
0.47952E-01
0.13406E-02
0.61675E-01
0.18548E-01
0.77750E+00
0.72275E-01
0.61198E-01
0.17665E-01
0.45430E-01
0.22334E-03
0.69699E-01
0.27068E-01
0.65180E+00
0.82512E-02
0.65070E-01
0.21817E-01
0.44750E-01
0.26613E-04
0.78981E-01
0.36734E-01
0.56659E+00
0.72446E-03
0.71341E-01
0.29725E-01
0.47769E-01
0.28050E-05
0.86882E-01
0.49319E-01
0.54982E+00
0.56874E-04
0.77348E-01
0.45060E-01
0.59699E-01
0.41661E-06
0.85703E-01
0.66393E-01
0.69658E+00
0.62749E-05
MOLE FRACTION
------------0.05840
0.50430
0.09650
0.08750
0.05890
0.02950
0.02290
0.04640
0.08054
0.01507
FLASH CALCULATIONS:
D-190
0.87715E-01
0.82307E-01
0.81050E-01
0.27446E-01
0.89135E-01
0.93990E-01
0.90930E+00
0.29201E+00
0.88755E-01
0.91776E-01
0.80272E-01
0.14510E-01
0.93328E-01
0.13343E+00
0.86011E+00
0.10875E+00
0.90382E-01
0.11176E+00
0.81844E-01
0.69045E-02
0.96226E-01
0.18354E+00
0.85054E+00
0.37620E-01
0.91230E-01
0.15106E+00
0.88040E-01
0.33392E-02
0.93333E-01
0.24844E+00
0.94329E+00
0.13440E-01
0.84991E-01
0.22787E+00
0.10332E+00
0.21795E-02
0.76312E-01
0.33471E+00
0.13540E+01
0.65117E-02
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
276.0 DEGREES F
OBSERVED PSAT
4375.0 PSIG (BUBPT)
OBSERVED DNSAT
0.4530 GM/CC
Landmark - R2003.4
Example Problems
STANDARD TEMP
STANDARD PRES
=
=
OBSERVED OIL FVF

CALCULATED OIL FVF
=
=
CALCULATED API GRAV. =

CALCULATED TOTAL GOR =
CALCULATED TOTAL OGR =
PRES
-----PSIG
-----385.0
50.0
0.0
80.0 DEGREES F
0.0 PSIG
2.8520 RB/STB
2.5873 RB/STB
65.4
2481.75 SCF/STB
402.94 STB/MMSCF
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------80.0
0.
1718.
2187.
2080.
80.0
0.
240.
294.
260.
80.0
0.
141.
173.
141.
SEP FVF
--------------DATA
CALC
----------0.0000 1.2104
0.0000 1.0860
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.7853
0.0000 1.1306
0.0000 1.6646
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------385.0
80.0
0.3765
0.3464
0.0000
0.1676
0.0000
0.6850
50.0
80.0
0.2927
0.2646
0.0000
0.0319
0.0000
0.7066
0.0
80.0
0.2434
0.2201
0.0000
0.0080
0.0000
0.7179
-----------0STAGE 1
ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.89705 YY = 0.77918E-01 0.72223E+00 0.10926E+00 0.64760E-01 0.19967E-01
0.40294E-02 0.14266E-02 0.40843E-03 0.74285E-05 0.11024E-09
ZX = 0.16763 XX = 0.21577E-01 0.93151E-01 0.72430E-01 0.13040E+00 0.13235E+00
0.77554E-01 0.63413E-01 0.13316E+00 0.23246E+00 0.43499E-01
KV = 0.36111E+01 0.77533E+01 0.15085E+01 0.49661E+00 0.15087E+00
0.51956E-01 0.22497E-01 0.30672E-02 0.31956E-04 0.25343E-08
0STAGE 2
ZZ = 0.21577E-01 0.93151E-01 0.72430E-01 0.13040E+00 0.13235E+00
0.77554E-01 0.63413E-01 0.13316E+00 0.23246E+00 0.43499E-01
ZY = 0.96343 YY = 0.78657E-01 0.36824E+00 0.21530E+00 0.22541E+00 0.87496E-01
0.17586E-01 0.58968E-02 0.13948E-02 0.14788E-04 0.14542E-11
ZX = 0.03188 XX = 0.39153E-02 0.80307E-02 0.28222E-01 0.10100E+00 0.14623E+00
0.96110E-01 0.81210E-01 0.17393E+00 0.30439E+00 0.56959E-01
KV = 0.20089E+02 0.45854E+02 0.76289E+01 0.22317E+01 0.59833E+00
0.18298E+00 0.72612E-01 0.80193E-02 0.48582E-04 0.25530E-10
0STAGE 3
ZZ = 0.39153E-02 0.80307E-02 0.28222E-01 0.10100E+00 0.14623E+00
0.96110E-01 0.81210E-01 0.17393E+00 0.30439E+00 0.56959E-01
ZY = 0.98105 YY = 0.22053E-01 0.46657E-01 0.14585E+00 0.39294E+00 0.28681E+00
0.73227E-01 0.26165E-01 0.62325E-02 0.59725E-04 0.43413E-11
ZX = 0.00802 XX = 0.25188E-03 0.22896E-03 0.44624E-02 0.42038E-01 0.11784E+00
0.10073E+00 0.92328E-01 0.20780E+00 0.36586E+00 0.68463E-01
KV = 0.87554E+02 0.20378E+03 0.32685E+02 0.93474E+01 0.24339E+01
0.72695E+00 0.28340E+00 0.29993E-01 0.16325E-03 0.63411E-10
0REGRESSION ITERATION
1
REGRESSION VARIABLE SUMMARY

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------10
1.00000000
0.45723553
0.00000000
11
1.00000000
0.07779608
0.00000000
1
1.00000000
0.45723553
0.00000000
2
1.00000000
0.07779608
0.00000000
3
1.00000000
0.45723553
0.00000000
4
1.00000000
0.07779608
0.00000000
5
1.00000000
0.45723553
0.00000000
6
1.00000000
0.07779608
0.00000000
7
1.00000000
0.03866500
0.00000000
8
1.00000000
0.04854700
0.00000000
9
1.00000000
0.06259800
0.00000000
0OBJECTIVE FUNCTION VALUE
=
5.360378E+00
0WEIGHTED ROOT MEAN SQUARE ERROR =
2.711884E-01
2

--------------------------0INDEX
X
VARIABLE
-------------------------
R2003.4 - Landmark
DELTA X
-----------
DELTA VAR.
----------0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
DELTA VAR.
-----------
D-191
Example Problems
10
0.98997035
0.45264962
-0.01002965
11
1.04435557
0.08124677
0.04435557
1
0.90126155
0.41208880
-0.09873845
2
1.07204499
0.08340089
0.07204499
3
0.94565441
0.43238680
-0.05434559
4
0.93319920
0.07259924
-0.06680080
5
1.02656261
0.46938090
0.02656261
6
0.93464197
0.07271148
-0.06535803
7
0.93414702
-0.02718798
-0.06585298
8
0.97176036
0.02030736
-0.02823964
9
0.97397476
0.03657275
-0.02602524
=
1.455389E+00
1.413068E-01
3

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------10
0.96465912
0.44107643
-0.02531123
11
1.06518319
0.08286707
0.02082762
1
0.83764209
0.38299973
-0.06361946
2
1.13863163
0.08858107
0.06658664
3
0.94346149
0.43138412
-0.00219292
4
0.91548948
0.07122149
-0.01770971
5
1.01735580
0.46517122
-0.00920680
6
0.92699430
0.07211652
-0.00764767
7
0.90343984
-0.05789516
-0.03070717
8
0.92895679
-0.02249621
-0.04280357
9
0.95359810
0.01619609
-0.02037666
=
1.354564E-01
4.310953E-02
4

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------10
0.94260968
0.43099464
-0.02204945
11
1.08721713
0.08458123
0.02203394
1
0.86752181
0.39666180
0.02987972
2
1.19543167
0.09299989
0.05680004
3
0.97647782
0.44648035
0.03301633
4
0.92776461
0.07217645
0.01227513
5
1.03034410
0.47110993
0.01298830
6
0.92510856
0.07196982
-0.00188574
7
0.81251216
-0.14882284
-0.09092768
8
0.89463450
-0.05681850
-0.03432229
9
0.90486958
-0.03253242
-0.04872851
=
8.724715E-02
3.459785E-02
5

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------10
0.92296783
0.42201369
-0.01964185
11
1.10989433
0.08634542
0.02267720
1
0.90098962
0.41196447
0.03346781
2
1.22570971
0.09535541
0.03027804
3
0.96016769
0.43902278
-0.01631013
4
0.91223191
0.07096806
-0.01553270
5
1.02029570
0.46651545
-0.01004840
6
0.91115266
0.07088410
-0.01395590
7
0.76458625
-0.19674875
-0.04792591
8
0.86455731
-0.08689569
-0.03007719
9
0.86497927
-0.07242273
-0.03989031
=
6.186933E-02
2.913474E-02
6

--------------------------0INDEX
X
VARIABLE
------------------------10
0.90677868
0.41461143
D-192
DELTA X
-----------0.01618915
-0.00458591
0.00345069
-0.04514673
0.00560482
-0.02484874
-0.00519684
0.01214537
-0.00508460
-0.06585298
-0.02823964
-0.02602524
DELTA VAR.
-----------0.01157319
0.00162031
-0.02908908
0.00518018
-0.00100268
-0.00137775
-0.00420968
-0.00059496
-0.03070717
-0.04280357
-0.02037666
DELTA VAR.
-----------0.01008179
0.00171415
0.01366207
0.00441882
0.01509624
0.00095496
0.00593871
-0.00014670
-0.09092768
-0.03432229
-0.04872851
DELTA VAR.
-----------0.00898095
0.00176420
0.01530267
0.00235551
-0.00745757
-0.00120838
-0.00459449
-0.00108571
-0.04792591
-0.03007719
-0.03989031
DELTA VAR.
-----------0.00740225
Landmark - R2003.4
11
1.11604213
1
0.91216884
2
1.23515489
3
0.96130164
4
0.90734805
5
1.01059323
6
0.90911537
7
0.74530347
8
0.83687662
9
0.86876650
0WEIGHTED ROOT MEAN SQUARE
7
Example Problems
0.08682370
0.00614780
0.41707601
0.01117922
0.09609020
0.00944518
0.43954127
0.00113395
0.07058812
-0.00488387
0.46207913
-0.00970247
0.07072561
-0.00203729
-0.21603153
-0.01928278
-0.11457638
-0.02768069
-0.06863551
0.00378722
=
5.889369E-02
ERROR =
2.842548E-02

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------10
0.94186743
0.43065526
0.03508875
11
1.13515688
0.08831075
0.01911474
1
0.92113529
0.42117579
0.00896645
2
1.23979827
0.09645144
0.00464338
3
0.97178839
0.44433618
0.01048675
4
0.91797895
0.07141516
0.01063091
5
0.97700727
0.44672244
-0.03358596
6
0.91288012
0.07101849
0.00376475
7
0.74151545
-0.21981955
-0.00378802
8
0.86170592
-0.08974708
0.02482930
9
0.92224351
-0.01515849
0.05347702
=
3.453641E-02
2.176768E-02
8

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------10
0.93694933
0.42840653
-0.00491810
11
1.13620111
0.08839199
0.00104423
1
0.93193306
0.42611291
0.01079777
2
1.25622075
0.09772904
0.01642248
3
0.97971279
0.44795950
0.00792440
4
0.91724545
0.07135810
-0.00073351
5
0.98147683
0.44876608
0.00446956
6
0.91418342
0.07111988
0.00130330
7
0.73704488
-0.22429012
-0.00447057
8
0.84689945
-0.10455355
-0.01480648
9
0.91773965
-0.01966235
-0.00450386
=
3.308461E-02
2.130524E-02
9

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------10
0.93529252
0.42764897
-0.00165681
11
1.14352670
0.08896189
0.00732559
1
0.94226198
0.43083566
0.01032891
2
1.27092965
0.09887334
0.01470890
3
0.98984704
0.45259324
0.01013425
4
0.91612139
0.07127065
-0.00112406
5
0.97408052
0.44538423
-0.00739631
6
0.90636233
0.07051143
-0.00782109
7
0.72521284
-0.23612216
-0.01183204
8
0.82900075
-0.12245225
-0.01789869
9
0.90715409
-0.03024791
-0.01058556
=
3.023602E-02
2.036741E-02
0REGRESSION ITERATION 10

--------------------------0INDEX
X
VARIABLE
------------------------10
0.92588645
0.42334818
11
1.14132524
0.08879062
R2003.4 - Landmark
DELTA X
-----------0.00940607
-0.00220146
0.00047828
0.00511154
0.00073480
0.00051848
-0.00037995
-0.00443631
-0.00015849
-0.01928278
-0.02768069
0.00378722
DELTA VAR.
----------0.01604382
0.00148705
0.00409978
0.00036124
0.00479491
0.00082704
-0.01535669
0.00029288
-0.00378802
0.02482930
0.05347702
DELTA VAR.
-----------0.00224873
0.00008124
0.00493712
0.00127760
0.00362332
-0.00005706
0.00204364
0.00010139
-0.00447057
-0.01480648
-0.00450386
DELTA VAR.
-----------0.00075755
0.00056990
0.00472275
0.00114429
0.00463374
-0.00008745
-0.00338186
-0.00060845
-0.01183204
-0.01789869
-0.01058556
DELTA VAR.
-----------0.00430079
-0.00017127
D-193
Example Problems
1
0.94503228
2
1.27235680
3
0.98606153
4
0.91171014
5
0.96882459
6
0.90097856
7
0.72560686
8
0.81855197
9
0.90279246
0WEIGHTED ROOT MEAN SQUARE
0REGRESSION ITERATION 11
0.43210234
0.00277031
0.09898437
0.00142715
0.45086237
-0.00378551
0.07092747
-0.00441125
0.44298103
-0.00525593
0.07009260
-0.00538378
-0.23572814
0.00039401
-0.13290103
-0.01044879
-0.03460954
-0.00436163
=
2.889584E-02
ERROR =
1.991091E-02
0.00126668
0.00011103
-0.00173087
-0.00034318
-0.00240320
-0.00041884
0.00039401
-0.01044879
-0.00436163

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------10
0.92588645
0.42334818
0.00000000
11
1.14132524
0.08879062
0.00000000
1
0.94503228
0.43210234
0.00000000
2
1.27235680
0.09898437
0.00000000
3
0.98606153
0.45086237
0.00000000
4
0.91171014
0.07092747
0.00000000
5
0.96882459
0.44298103
0.00000000
6
0.90097856
0.07009260
0.00000000
7
0.72560686
-0.23572814
0.00000000
8
0.81855197
-0.13290103
0.00000000
9
0.90279246
-0.03460954
0.00000000
=
2.889584E-02
1.991091E-02
0TOTAL NUMBER OF FUNCTION EVALUATIONS = 141
0REGRESSION TERMINATING NORMALLY:
THE DISTANCE MOVED WAS LESS THAN TOL2 =
0.00100
1EQUATION OF STATE: PENG-ROBINSON
DELTA VAR.
----------0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
-------------------COMPONENT
MOLE
TC
PC
CRITICAL ACENTRIC
OMEGA
OMEGA
PCHOR
NO. NAME WEIGHT
DEG F
PSIA
Z-FACTOR FACTOR
A
B
-- ------ ------- -------- -------- -------- -------- -------- -------- ------1 CO2
44.01
87.90 1070.90
0.2742 0.22250 0.45724 0.07780
49.6
2 C1
16.04 -116.60
667.80
0.2890 0.01260 0.42335 0.08879
71.0
3 C2
30.07
90.10
707.80
0.2850 0.09780 0.45724 0.07780
111.0
4 C3
44.10
206.00
616.30
0.2810 0.15410 0.45724 0.07780
151.0
5 NC4
58.12
305.70
550.70
0.2740 0.20150 0.45724 0.07780
191.0
6 NC5
72.15
385.70
488.60
0.2620 0.25240 0.45724 0.07780
231.0
7 C6
84.00
463.00
468.30
0.2698 0.23130 0.45724 0.07780
271.0
8 C8
108.82
585.69
411.09
0.2609 0.32000 0.43210 0.09898
351.0
9 C14
187.49
790.04
283.80
0.2411 0.50331 0.45086 0.07093
591.9
10 C30
387.42 1138.35
165.63
0.2067 0.93601 0.44298 0.07009 1236.7
10

------------------------------1
1
2
3
4
5
6
7
8
9
10
0.1500
0.1500 0.0000
0.1500 0.0000
0.1500 0.0200
0.1500 0.0200
0.1500 0.0298
0.1500-0.2357
0.1500-0.1329
0.1500-0.0346
0.0000
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0000
0.0000
0.0000
0.0000
0.0000
10
0.0000
0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000

---------------------------------------------------------NO.
----k(1)
k(2)
k(3)
k(4)
D-194
K-COEFFICIENT
--------------0.9746020E+01
0.1808340E+02
0.4126660E+04
0.4460550E+02
Landmark - R2003.4
k(5)
k(6)
k(7)
Example Problems
0.9765440E+00
0.8181340E+02
0.1564990E+05

--------------------------------------1
1
2
3
4
5
6
7
8
9
10
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
10
0.0000
0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000

A = A0 + A1*T + A2*T**2 + A3*T**3 + A4*T**4
B = B0 + B1*T + B2*T**2 + B3*T**3 + B4*T**4
C = A0 + C1*T + C2*T**2 + C3*T**3 + C4*T**4
where Rsw
P
T
S
in
in
in
in
A0
1.1630599
B0
0.9650900
C0
1.2803000
S0
-0.0280370
scf/stb
psia
degree F
A1
-16.6303997
B1
-0.2725500
C1
-10.7566004
S1
-0.1203900
A2
111.0730515
B2
0.0923400
C2
52.6962204
A3
-376.8592529
B3
-0.1008300
C3
-222.3948822
A4
524.8891602
B4
0.0997900
C4
462.6725464

D1 =
5.80000

------------------------------------H* = A + B*T + C*(T**2) + D*(T**3) + E*(T**4) + F*(T**5)
WHERE THE UNITS ARE
H* - BTU / LB-MOLE
T
- DEGREES RANKIN
COMPONENT
NO NAME
-- -----1 CO2
2 C1
3 C2
4 C3
5 NC4
6 NC5
7 C6
8 C8
9 C14
10 C30
A
B
C
D
---------- ---------- ---------- ---------0.210E+03 0.504E+01 0.445E-02 -0.117E-05
-0.112E+03 0.917E+01 -0.472E-02 0.679E-05
-0.631E+00 0.796E+01 -0.752E-03 0.879E-05
-0.325E+02 0.761E+01 0.415E-02 0.950E-05
0.432E+03 0.573E+01 0.156E-01 0.301E-05
0.196E+04 -0.202E+00 0.318E-01 -0.623E-05
0.000E+00 0.242E+01 0.343E-01 -0.477E-05
0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.171E+02 0.786E-01 -0.118E-04
0.000E+00 0.702E+01 0.153E+00 -0.199E-04
E
F
---------- ---------0.153E-09 -0.578E-14
-0.245E-08 0.312E-12
-0.387E-08 0.548E-12
-0.472E-08 0.702E-12
-0.244E-08 0.381E-12
0.590E-09 -0.142E-13
0.000E+00 0.000E+00
0.000E+00 0.000E+00
0.000E+00 0.000E+00
0.000E+00 0.000E+00
1SATURATION PRESSURE CALCULATION
-------------------------------
COMPONENT
---------
R2003.4 - Landmark
22
MOLE FRACTION
-------------
D-195
Example Problems
CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
0.05840
0.50430
0.09650
0.08750
0.05890
0.02950
0.02290
0.04640
0.08054
0.01507
TEMPERATURE SATURATION PRESSURE (PSIG )

DEGREES F
DATA
CALC
TYPE
----------- -------- ----------276.00
4375.000 4376.455
BP
-----------------------P = 4376.5 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.96892 YY = 0.59654E-01
0.28343E-01
ZX = 0.98144 XX = 0.58400E-01
0.29500E-01
KV = 0.10215E+01
0.96078E+00
1PHASE ENVELOPE CALCULATION
--------------------------
COMPONENT
--------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
TEMPERATURE
DEGREES F
-----------100.00
-90.00
-80.00
-70.00
-60.00
-50.00
-40.00
-30.00
-20.00
-10.00
0.00
10.00
20.00
30.00
40.00
50.00
60.00
70.00
80.00
90.00
100.00
110.00
120.00
130.00
140.00
150.00
160.00
170.00
180.00
190.00
200.00
210.00
D-196
0.50430E+00
0.22900E-01
0.52080E+00
0.21689E-01
0.50430E+00
0.22900E-01
0.10327E+01
0.94712E+00
DEN AT PSAT (LB/FT3)

DATA
CALC
-------- -------0.0000
28.8245
0.96500E-01
0.46396E-01
0.97188E-01
0.46595E-01
0.96500E-01
0.46396E-01
0.10071E+01
0.10043E+01
Z-FAC AT PSAT
DATA
CALC
------ -----0.0000 0.9814
0.87500E-01
0.80535E-01
0.86811E-01
0.70472E-01
0.87500E-01
0.80535E-01
0.99213E+00
0.87505E+00
0.58900E-01
0.15069E-01
0.57363E-01
0.11089E-01
0.58900E-01
0.15069E-01
0.97390E+00
0.73585E+00
MOLE FRACTION
------------0.05840
0.50430
0.09650
0.08750
0.05890
0.02950
0.02290
0.04640
0.08054
0.01507
SATURATION
ESTIMATE
-------6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
6000.000
PRESSURE (PSIG )
COMPUTED
TYPE
------------1598.823
BUBPT
1508.558
BUBPT
1482.259
BUBPT
1501.492
BUBPT
1553.468
BUBPT
1629.061
BUBPT
1721.601
BUBPT
1826.118
BUBPT
1938.845
BUBPT
2056.891
BUBPT
2178.017
BUBPT
2300.479
BUBPT
2422.914
BUBPT
2544.262
BUBPT
2663.699
BUBPT
2780.592
BUBPT
2894.458
BUBPT
3004.935
BUBPT
3111.751
BUBPT
3214.710
BUBPT
3313.667
BUBPT
3408.526
BUBPT
3499.218
BUBPT
3585.705
BUBPT
3667.965
BUBPT
3745.991
BUBPT
3819.792
BUBPT
3889.381
BUBPT
3954.782
BUBPT
4016.023
BUBPT
4073.137
BUBPT
4126.159
BUBPT
Landmark - R2003.4
Example Problems
220.00
6000.000
4175.130
BUBPT
230.00
6000.000
4220.089
BUBPT
240.00
6000.000
4261.079
BUBPT
250.00
6000.000
4298.143
BUBPT
260.00
6000.000
4331.326
BUBPT
270.00
6000.000
4360.671
BUBPT
280.00
6000.000
4386.223
BUBPT
290.00
6000.000
4408.026
BUBPT
300.00
6000.000
4426.125
BUBPT
310.00
6000.000
4440.562
BUBPT
320.00
6000.000
4451.379
DEWPT
330.00
6000.000
4458.619
DEWPT
340.00
6000.000
4462.322
DEWPT
350.00
6000.000
4462.528
DEWPT
360.00
6000.000
4459.273
DEWPT
370.00
6000.000
4452.597
DEWPT
380.00
6000.000
4442.532
DEWPT
390.00
6000.000
4429.113
DEWPT
400.00
6000.000
4412.373
DEWPT
410.00
6000.000
4392.339
DEWPT
420.00
6000.000
4369.040
DEWPT
430.00
6000.000
4342.502
DEWPT
440.00
6000.000
4312.748
DEWPT
450.00
6000.000
4279.796
DEWPT
460.00
6000.000
4243.667
DEWPT
470.00
6000.000
4204.373
DEWPT
480.00
6000.000
4161.926
DEWPT
490.00
6000.000
4116.333
DEWPT
500.00
6000.000
4067.596
DEWPT
510.00
6000.000
4015.715
DEWPT
520.00
4000.000
3960.683
DEWPT
530.00
6000.000
3902.487
DEWPT
540.00
6000.000
3841.108
DEWPT
550.00
6000.000
3776.520
DEWPT
560.00
6000.000
3708.686
DEWPT
570.00
6000.000
3637.562
DEWPT
580.00
6000.000
3563.091
DEWPT
590.00
6000.000
3485.201
DEWPT
600.00
6000.000
3403.804
DEWPT
610.00
6000.000
3318.792
DEWPT
620.00
6000.000
3230.031
DEWPT
630.00
6000.000
3137.358
DEWPT
640.00
6000.000
3040.569
DEWPT
650.00
6000.000
2939.411
DEWPT
660.00
6000.000
2833.563
DEWPT
670.00
6000.000
2722.619
DEWPT
680.00
6000.000
2606.044
DEWPT
690.00
6000.000
2483.130
DEWPT
700.00
4000.000
2352.902
DEWPT
710.00
4000.000
2213.963
DEWPT
720.00
4000.000
2064.204
DEWPT
730.00
4000.000
1900.159
DEWPT
740.00
4000.000
1715.403
DEWPT
750.00
4000.000
1495.015
DEWPT
760.00
4000.000
1176.379
DEWPT
770.00
** NONE FOUND **
780.00
** NONE FOUND **
790.00
** NONE FOUND **
800.00
** NONE FOUND **
800.00
** NONE FOUND **
790.00
** NONE FOUND **
780.00
** NONE FOUND **
770.00
** NONE FOUND **
760.00
100.000
694.696
DEWPT
750.00
100.000
489.484
DEWPT
740.00
100.000
380.506
DEWPT
730.00
100.000
305.100
DEWPT
720.00
100.000
248.303
DEWPT
710.00
100.000
203.643
DEWPT
700.00
100.000
167.614
DEWPT
690.00
100.000
138.061
DEWPT
680.00
100.000
113.544
DEWPT
670.00
100.000
93.048
DEWPT
660.00
100.000
75.822
DEWPT
650.00
100.000
61.291
DEWPT
640.00
100.000
49.007
DEWPT
630.00
620.00
610.00
600.00
1LIQUID DENSITY CALCULATION
R2003.4 - Landmark
D-197
Example Problems
--------------------------
COMPONENT
--------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
MOLE FRACTION
------------0.05840
0.50430
0.09650
0.08750
0.05890
0.02950
0.02290
0.04640
0.08054
0.01507
TEMPERATURE PRESSURE LIQUID DEN (GM/CC ) ---- Z-FACTOR ---DEGREES F

PSIG
DATA
CALC
DATA
CALC
----------- -------- -------- --------- -------- -------276.00 6000.000
0.4924
0.4989
0.00000
1.24402
4375.000
0.4530
0.4617
0.00000
0.98120
------------------------------
COMPONENT
--------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
MOLE FRACTION
------------0.05840
0.50430
0.09650
0.08750
0.05890
0.02950
0.02290
0.04640
0.08054
0.01507
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
276.00 DEGREES F
OBSERVED PSAT
CALCULATED PSAT
OIL DENSITY AT PSAT
GAS DENSITY AT PSAT
= 4375.00 PSIG
= 4376.45 PSIG
= 0.0000
= 0.9814
= 0.4617 GM/CC
= 0.4367 GM/CC
(BUBPT)
(BUBPT)
PRES
REL. VOLUME
LIQ VOL FRAC
LIQ MOLE FRAC
------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ -----6000.0 0.9200 0.9254 0.0000 0.9254 0.0000 1.0000
5000.0 0.9613 0.9665 0.0000 0.9665 0.0000 1.0000
4500.0 0.9909 0.9927 0.0000 0.9927 0.0000 1.0000
4375.0 1.0000 1.0001 1.0000 0.9672 0.0000 0.9666
4328.0 1.0052 1.0049 0.0000 0.6967 0.0000 0.6869
4300.0 0.0000 1.0078 0.6510 0.6563 0.0000 0.6431
4267.0 1.0117 1.0113 0.0000 0.6278 0.0000 0.6111
4230.0 1.0158 1.0153 0.0000 0.6067 0.0000 0.5866
4150.0 0.0000 1.0244 0.5700 0.5787 0.0000 0.5519
4059.0 1.0368 1.0353 0.0000 0.5596 0.0000 0.5262
3960.0 0.0000 1.0479 0.5300 0.5456 0.0000 0.5057
3709.0 1.0883 1.0843 0.0000 0.5235 0.0000 0.4689
3408.0 1.1472 1.1382 0.0000 0.5063 0.0000 0.4361
2688.0 1.3595 1.3369 0.0000 0.4725 0.0000 0.3703
1962.0 1.7834 1.7349 0.0000 0.4364 0.0000 0.3076
1271.0 2.7310 2.6357 0.0000 0.3943 0.0000 0.2460
951.0 3.6866 3.5558 0.0000 0.3692 0.0000 0.2147
PRES
OIL Z-FACTOR
GAS Z-FACTOR
OIL DENSITY
GAS DENSITY
------- --------------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ ------ ------ -----6000.0 0.0000 1.2440 0.0000 0.0000 0.0000 0.4989 0.0000 0.0000
D-198
Landmark - R2003.4
5000.0
4500.0
4375.0
4328.0
4300.0
4267.0
4230.0
4150.0
4059.0
3960.0
3709.0
3408.0
2688.0
1962.0
1271.0
951.0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Example Problems
1.0832
1.0017
0.9817
0.9844
0.9842
0.9831
0.9813
0.9760
0.9683
0.9585
0.9293
0.8882
0.7709
0.6268
0.4606
0.3712
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.9683
0.9556
0.9498
0.9438
0.9376
0.9258
0.9140
0.9026
0.8787
0.8572
0.8292
0.8286
0.8542
0.8758
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.4777
0.4651
0.4625
0.4779
0.4836
0.4892
0.4945
0.5040
0.5127
0.5208
0.5375
0.5540
0.5879
0.6202
0.6539
0.6729
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.4358
0.4179
0.4106
0.4031
0.3957
0.3816
0.3675
0.3535
0.3216
0.2868
0.2128
0.1471
0.0910
0.0669
PRES
OIL VISCOSITY
GAS VISCOSITY
SURF TENS
------- --------------- --------------- ----------PSIG
DATA
CALC
DATA
CALC
DYNE/CM
------- ------ ------ ------ ------ ----------6000.0 0.0000 0.0807 0.0000 0.0000 0.0000E+00
5000.0 0.0000 0.0719 0.0000 0.0000 0.0000E+00
4500.0 0.0000 0.0675 0.0000 0.0000 0.0000E+00
4375.0 0.0000 0.0667 0.0000 0.0596 0.4477E-04
4328.0 0.0000 0.0713 0.0000 0.0555 0.1137E-02
4300.0 0.0000 0.0731 0.0000 0.0539 0.2507E-02
4267.0 0.0000 0.0750 0.0000 0.0524 0.4840E-02
4230.0 0.0000 0.0768 0.0000 0.0509 0.8419E-02
4150.0 0.0000 0.0802 0.0000 0.0482 0.1985E-01
4059.0 0.0000 0.0836 0.0000 0.0457 0.3953E-01
3960.0 0.0000 0.0869 0.0000 0.0434 0.6991E-01
3709.0 0.0000 0.0943 0.0000 0.0386 0.1967E+00
3408.0 0.0000 0.1026 0.0000 0.0339 0.4677E+00
2688.0 0.0000 0.1232 0.0000 0.0254 0.1879E+01
1962.0 0.0000 0.1482 0.0000 0.0196 0.4900E+01
1271.0 0.0000 0.1811 0.0000 0.0161 0.1004E+02
951.0 0.0000 0.2031 0.0000 0.0150 0.1357E+02
---------------------------
OIL COMP
-------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
PRESSURE - PSIG
----------------6000. 5000. 4500.
3960. 3709. 3408.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
4375.
2688.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4328.
1962.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4300.
1271.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4267.
951.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4230.
4150.
4059.
4328.
1962.
-----0.0575
0.0352
0.4919
0.2536
4300.
1271.
-----0.0571
0.0251
0.4870
0.1697
4267. 4230. 4150. 4059.

951.
------ ------ ------ -----0.0567 0.0563 0.0556 0.0548
0.0194
0.4821 0.4771 0.4677 0.4581
0.1277
------ ------ -----0.0000 0.0000 0.0000

0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000

--------------------------------
OIL COMP
-------CO2
C1
R2003.4 - Landmark
PRESSURE - PSIG
----------------6000. 5000. 4500.
3960. 3709. 3408.
------ ------ -----0.0584 0.0584 0.0584
0.0540 0.0521 0.0498
0.5043 0.5043 0.5043
0.4485 0.4256 0.3989
4375.
2688.
-----0.0584
0.0434
0.5037
0.3312
D-199
Example Problems
C2
0.0965 0.0965 0.0965

0.0940 0.0927 0.0911
0.0875 0.0875 0.0875
0.0898 0.0906 0.0916
NC4
0.0589 0.0589 0.0589
0.0641 0.0663 0.0689
NC5
0.0295 0.0295 0.0295
0.0335 0.0352 0.0373
C6
0.0229 0.0229 0.0229
0.0271 0.0289 0.0311
C8
0.0464 0.0464 0.0464
0.0466 0.0474 0.0491
C14
0.0805 0.0805 0.0805
0.1157 0.1307 0.1485
C30
0.0151 0.0151 0.0151
0.0268 0.0303 0.0336
--------------------------C3
GAS COMP
-------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
PRESSURE - PSIG
----------------6000. 5000. 4500.
3960. 3709. 3408.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0965
0.0860
0.0875
0.0933
0.0590
0.0755
0.0295
0.0430
0.0229
0.0372
0.0464
0.0560
0.0809
0.1938
0.0152
0.0405
0.0960
0.0771
0.0880
0.0926
0.0601
0.0821
0.0304
0.0499
0.0238
0.0451
0.0463
0.0677
0.0881
0.2478
0.0180
0.0490
0.0958
0.0619
0.0882
0.0847
0.0605
0.0849
0.0307
0.0564
0.0242
0.0541
0.0462
0.0832
0.0911
0.3186
0.0191
0.0612
0.0956
0.0513
0.0884
0.0756
0.0610
0.0820
0.0311
0.0580
0.0245
0.0582
0.0462
0.0902
0.0942
0.3675
0.0202
0.0702
4375.
2688.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4328.
1962.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4300.
1271.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4267.
951.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0953 0.0949 0.0944

0.0886 0.0890 0.0894
0.0614 0.0623 0.0632
0.0314 0.0321 0.0328
0.0249 0.0256 0.0264
0.0462 0.0463 0.0464
0.0973 0.1033 0.1094
0.0213 0.0233 0.0251
4230.
4150.
4059.
------ ------ -----0.0000 0.0000 0.0000

0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000

-------------------------------PRESSURE - PSIG
----------------GAS COMP
6000. 5000. 4500. 4375. 4328. 4300. 4267. 4230.
3960. 3709. 3408. 2688. 1962. 1271.
951.
-------- ------ ------ ------ ------ ------ ------ ------ -----CO2
0.0000 0.0000 0.0000 0.0597 0.0605 0.0608 0.0611 0.0614
0.0629 0.0640 0.0651 0.0672 0.0687 0.0693 0.0691
C1
0.0000 0.0000 0.0000 0.5213 0.5315 0.5354 0.5392 0.5428
0.5614 0.5738 0.5858 0.6061 0.6157 0.6135 0.6073
C2
0.0000 0.0000 0.0000 0.0972 0.0976 0.0978 0.0980 0.0982
0.0991 0.0998 0.1006 0.1027 0.1051 0.1078 0.1089
C3
0.0000 0.0000 0.0000 0.0868 0.0864 0.0862 0.0861 0.0859
0.0852 0.0847 0.0843 0.0841 0.0852 0.0884 0.0907
NC4
0.0000 0.0000 0.0000 0.0573 0.0564 0.0560 0.0556 0.0553
0.0535 0.0523 0.0511 0.0491 0.0486 0.0504 0.0526
NC5
0.0000 0.0000 0.0000 0.0283 0.0276 0.0273 0.0270 0.0268
0.0254 0.0244 0.0234 0.0216 0.0205 0.0207 0.0217
C6
0.0000 0.0000 0.0000 0.0216 0.0209 0.0206 0.0203 0.0200
0.0186 0.0176 0.0165 0.0145 0.0130 0.0127 0.0133
C8
0.0000 0.0000 0.0000 0.0466 0.0467 0.0467 0.0467 0.0467
0.0462 0.0455 0.0443 0.0408 0.0369 0.0344 0.0344
C14
0.0000 0.0000 0.0000 0.0701 0.0639 0.0614 0.0591 0.0567
0.0446 0.0362 0.0280 0.0139 0.0062 0.0028 0.0021
C30
0.0000 0.0000 0.0000 0.0110 0.0086 0.0077 0.0069 0.0062
0.0030 0.0016 0.0008 0.0001 0.0000 0.0000 0.0000
-----------------------0 P = 4375.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01
ZY = 0.96834 YY = 0.59695E-01 0.52134E+00 0.97211E-01 0.86789E-01
0.28305E-01 0.21649E-01 0.46600E-01 0.70142E-01
ZX = 0.98170 XX = 0.58355E-01 0.50371E+00 0.96475E-01 0.87525E-01
D-200
4150.
4059.
------ -----0.0619 0.0624

0.5494 0.5556
0.0985 0.0988
0.0856 0.0854
0.0547 0.0541
0.0263 0.0258
0.0195 0.0191
0.0466 0.0464
0.0525 0.0485
0.0050 0.0039
0.58900E-01
0.15069E-01
0.57313E-01
0.10960E-01
0.58955E-01
Landmark - R2003.4
0 P =
4328.0
ZY = 0.95556
ZX = 0.98442
0 P =
4300.0
ZY = 0.94982
ZX = 0.98416
0 P =
4267.0
ZY = 0.94378
ZX = 0.98312
0 P =
4230.0
ZY = 0.93764
ZX = 0.98133
0 P =
4150.0
ZY = 0.92581
ZX = 0.97600
0 P =
4059.0
ZY = 0.91403
ZX = 0.96830
0 P =
3960.0
ZY = 0.90265
ZX = 0.95853
0 P =
3709.0
ZY = 0.87873
ZX = 0.92927
0 P =
3408.0
ZY = 0.85719
ZX = 0.88819
0 P =
2688.0
ZY = 0.82916
ZX = 0.77087
R2003.4 - Landmark
Example Problems
0.29541E-01
KV = 0.10230E+01
0.95815E+00
ZZ = 0.58400E-01
0.29500E-01
YY = 0.60478E-01
0.27585E-01
XX = 0.57453E-01
0.30373E-01
KV = 0.10527E+01
0.90823E+00
ZZ = 0.58400E-01
0.29500E-01
YY = 0.60779E-01
0.27310E-01
XX = 0.57080E-01
0.30715E-01
KV = 0.10648E+01
0.88914E+00
ZZ = 0.58400E-01
0.29500E-01
YY = 0.61076E-01
0.27040E-01
XX = 0.56697E-01
0.31066E-01
KV = 0.10772E+01
0.87040E+00
ZZ = 0.58400E-01
0.29500E-01
YY = 0.61363E-01
0.26778E-01
XX = 0.56311E-01
0.31418E-01
KV = 0.10897E+01
0.85232E+00
ZZ = 0.58400E-01
0.29500E-01
YY = 0.61890E-01
0.26302E-01
XX = 0.55567E-01
0.32097E-01
KV = 0.11138E+01
0.81946E+00
ZZ = 0.58400E-01
0.29500E-01
YY = 0.62398E-01
0.25844E-01
XX = 0.54800E-01
0.32792E-01
KV = 0.11387E+01
0.78813E+00
ZZ = 0.58400E-01
0.29500E-01
YY = 0.62887E-01
0.25406E-01
XX = 0.54014E-01
0.33502E-01
KV = 0.11643E+01
0.75834E+00
ZZ = 0.58400E-01
0.29500E-01
YY = 0.63962E-01
0.24443E-01
XX = 0.52100E-01
0.35228E-01
KV = 0.12277E+01
0.69387E+00
ZZ = 0.58400E-01
0.29500E-01
YY = 0.65074E-01
0.23448E-01
XX = 0.49770E-01
0.37327E-01
KV = 0.13075E+01
0.62817E+00
ZZ = 0.58400E-01
0.29500E-01
YY = 0.67217E-01
0.21558E-01
XX = 0.43404E-01
0.43007E-01
0.22943E-01
0.10350E+01
0.94361E+00
0.50430E+00
0.22900E-01
0.53154E+00
0.20896E-01
0.49189E+00
0.23813E-01
0.10806E+01
0.87748E+00
0.50430E+00
0.22900E-01
0.53541E+00
0.20607E-01
0.48704E+00
0.24172E-01
0.10993E+01
0.85252E+00
0.50430E+00
0.22900E-01
0.53920E+00
0.20324E-01
0.48209E+00
0.24540E-01
0.11185E+01
0.82819E+00
0.50430E+00
0.22900E-01
0.54284E+00
0.20049E-01
0.47714E+00
0.24909E-01
0.11377E+01
0.80489E+00
0.50430E+00
0.22900E-01
0.54940E+00
0.19548E-01
0.46768E+00
0.25621E-01
0.11747E+01
0.76298E+00
0.50430E+00
0.22900E-01
0.55560E+00
0.19067E-01
0.45810E+00
0.26352E-01
0.12128E+01
0.72357E+00
0.50430E+00
0.22900E-01
0.56144E+00
0.18605E-01
0.44845E+00
0.27098E-01
0.12519E+01
0.68658E+00
0.50430E+00
0.22900E-01
0.57379E+00
0.17589E-01
0.42559E+00
0.28916E-01
0.13482E+01
0.60826E+00
0.50430E+00
0.22900E-01
0.58581E+00
0.16531E-01
0.39890E+00
0.31136E-01
0.14686E+01
0.53092E+00
0.50430E+00
0.22900E-01
0.60608E+00
0.14463E-01
0.33119E+00
0.37249E-01
0.46389E-01
0.10076E+01
0.10046E+01
0.96500E-01
0.46396E-01
0.97649E-01
0.46678E-01
0.95977E-01
0.46267E-01
0.10174E+01
0.10089E+01
0.96500E-01
0.46396E-01
0.97820E-01
0.46687E-01
0.95768E-01
0.46234E-01
0.10214E+01
0.10098E+01
0.96500E-01
0.46396E-01
0.97991E-01
0.46682E-01
0.95551E-01
0.46214E-01
0.10255E+01
0.10101E+01
0.96500E-01
0.46396E-01
0.98159E-01
0.46660E-01
0.95331E-01
0.46210E-01
0.10297E+01
0.10097E+01
0.96500E-01
0.46396E-01
0.98474E-01
0.46573E-01
0.94898E-01
0.46252E-01
0.10377E+01
0.10069E+01
0.96500E-01
0.46396E-01
0.98787E-01
0.46422E-01
0.94441E-01
0.46372E-01
0.10460E+01
0.10011E+01
0.96500E-01
0.46396E-01
0.99097E-01
0.46209E-01
0.93961E-01
0.46579E-01
0.10547E+01
0.99206E+00
0.96500E-01
0.46396E-01
0.99820E-01
0.45479E-01
0.92740E-01
0.47435E-01
0.10763E+01
0.95877E+00
0.96500E-01
0.46396E-01
0.10064E+00
0.44318E-01
0.91141E-01
0.49083E-01
0.11043E+01
0.90291E+00
0.96500E-01
0.46396E-01
0.10270E+00
0.40767E-01
0.85962E-01
0.55969E-01
0.80894E-01
0.99160E+00
0.86708E+00
0.87500E-01
0.80535E-01
0.86367E-01
0.63854E-01
0.88016E-01
0.88138E-01
0.98127E+00
0.72448E+00
0.87500E-01
0.80535E-01
0.86209E-01
0.61438E-01
0.88217E-01
0.91133E-01
0.97724E+00
0.67415E+00
0.87500E-01
0.80535E-01
0.86055E-01
0.59056E-01
0.88420E-01
0.94206E-01
0.97325E+00
0.62688E+00
0.87500E-01
0.80535E-01
0.85908E-01
0.56749E-01
0.88622E-01
0.97301E-01
0.96938E+00
0.58323E+00
0.87500E-01
0.80535E-01
0.85647E-01
0.52529E-01
0.89004E-01
0.10327E+00
0.96228E+00
0.50865E+00
0.87500E-01
0.80535E-01
0.85404E-01
0.48476E-01
0.89387E-01
0.10940E+00
0.95545E+00
0.44309E+00
0.87500E-01
0.80535E-01
0.85180E-01
0.44601E-01
0.89767E-01
0.11566E+00
0.94890E+00
0.38562E+00
0.87500E-01
0.80535E-01
0.84723E-01
0.36231E-01
0.90645E-01
0.13072E+00
0.93467E+00
0.27717E+00
0.87500E-01
0.80535E-01
0.84324E-01
0.27956E-01
0.91607E-01
0.14853E+00
0.92049E+00
0.18822E+00
0.87500E-01
0.80535E-01
0.84068E-01
0.13920E-01
0.93337E-01
0.19383E+00
0.15211E-01
0.97214E+00
0.72055E+00
0.58900E-01
0.15069E-01
0.56361E-01
0.85962E-02
0.60057E-01
0.18019E-01
0.93845E+00
0.47706E+00
0.58900E-01
0.15069E-01
0.55998E-01
0.77407E-02
0.60510E-01
0.19136E-01
0.92544E+00
0.40452E+00
0.58900E-01
0.15069E-01
0.55644E-01
0.69348E-02
0.60973E-01
0.20246E-01
0.91260E+00
0.34252E+00
0.58900E-01
0.15069E-01
0.55302E-01
0.61936E-02
0.61436E-01
0.21325E-01
0.90016E+00
0.29044E+00
0.58900E-01
0.15069E-01
0.54684E-01
0.49502E-02
0.62323E-01
0.23284E-01
0.87743E+00
0.21260E+00
0.58900E-01
0.15069E-01
0.54096E-01
0.39031E-02
0.63226E-01
0.25124E-01
0.85559E+00
0.15535E+00
0.58900E-01
0.15069E-01
0.53538E-01
0.30416E-02
0.64141E-01
0.26826E-01
0.83469E+00
0.11339E+00
0.58900E-01
0.15069E-01
0.52338E-01
0.16301E-02
0.66333E-01
0.30291E-01
0.78901E+00
0.53814E-01
0.58900E-01
0.15069E-01
0.51140E-01
0.75735E-03
0.68935E-01
0.33576E-01
0.74186E+00
0.22556E-01
0.58900E-01
0.15069E-01
0.49124E-01
0.10495E-03
0.75527E-01
0.40520E-01
D-201
Example Problems
KV = 0.15486E+01
0.50127E+00
1962.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.82856 YY = 0.68706E-01
0.20454E-01
ZX = 0.62675 XX = 0.35205E-01
0.49859E-01
KV = 0.19516E+01
0.41023E+00
0 P = 1271.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.85425 YY = 0.69279E-01
0.20717E-01
ZX = 0.46057 XX = 0.25062E-01
0.56415E-01
KV = 0.27643E+01
0.36722E+00
0 P =
951.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.87580 YY = 0.69054E-01
0.21713E-01
ZX = 0.37119 XX = 0.19432E-01
0.57982E-01
KV = 0.35537E+01
0.37448E+00
------------------------0 P =
COMPONENT
--------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
0.18300E+01
0.38829E+00
0.50430E+00
0.22900E-01
0.61568E+00
0.13046E-01
0.25363E+00
0.45077E-01
0.24275E+01
0.28942E+00
0.50430E+00
0.22900E-01
0.61347E+00
0.12713E-01
0.16975E+00
0.54117E-01
0.36140E+01
0.23492E+00
0.50430E+00
0.22900E-01
0.60727E+00
0.13262E-01
0.12767E+00
0.58151E-01
0.47566E+01
0.22807E+00
0.11947E+01
0.72839E+00
0.96500E-01
0.46396E-01
0.10513E+00
0.36922E-01
0.77070E-01
0.67717E-01
0.13641E+01
0.54524E+00
0.96500E-01
0.46396E-01
0.10779E+00
0.34382E-01
0.61917E-01
0.83212E-01
0.17408E+01
0.41318E+00
0.96500E-01
0.46396E-01
0.10887E+00
0.34433E-01
0.51266E-01
0.90152E-01
0.21235E+01
0.38195E+00
0.90069E+00
0.71813E-01
0.87500E-01
0.80535E-01
0.85240E-01
0.62295E-02
0.92586E-01
0.24777E+00
0.92065E+00
0.25143E-01
0.87500E-01
0.80535E-01
0.88416E-01
0.28347E-02
0.84693E-01
0.31864E+00
0.10440E+01
0.88962E-02
0.87500E-01
0.80535E-01
0.90744E-01
0.20778E-02
0.75636E-01
0.36751E+00
0.11997E+01
0.56539E-02
0.65041E+00
0.25900E-02
0.58900E-01
0.15069E-01
0.48577E-01
0.11536E-04
0.82133E-01
0.48957E-01
0.59144E+00
0.23563E-03
0.58900E-01
0.15069E-01
0.50400E-01
0.11857E-05
0.84948E-01
0.61243E-01
0.59330E+00
0.19361E-04
0.58900E-01
0.15069E-01
0.52579E-01
0.41087E-06
0.82019E-01
0.70185E-01
0.64107E+00
0.58541E-05
MOLE FRACTION
------------0.05840
0.50430
0.09650
0.08750
0.05890
0.02950
0.02290
0.04640
0.08054
0.01507
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
276.00 DEGREES F
OBSERVED PSAT
CALCULATED PSAT
OIL DENSITY AT PSAT
GAS DENSITY AT PSAT
= 4375.00 PSIG
= 4376.45 PSIG
= 0.0000
= 0.9814
= 0.4617 GM/CC
= 0.4367 GM/CC
(BUBPT)
(BUBPT)
PRES MW(C8
-C30 )
CUM GAS PROD
LIQ VOL FRAC
LIQ MOLE FRAC
------- --------------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ ------ ------ -----4375.0 183.00 175.94 0.0000 0.0001 0.0000 0.9672 0.0000 0.9666
3700.0 138.00 148.25 0.0875 0.0811 0.5010 0.5229 0.0000 0.4677
3000.0 129.00 134.26 0.1963 0.1903 0.4500 0.4767 0.0000 0.3889
2200.0 120.00 122.90 0.3518 0.3455 0.4140 0.4287 0.0000 0.3124
1400.0 115.00 115.80 0.5273 0.5267 0.3760 0.3790 0.0000 0.2416
700.0 116.00 112.60 0.6923 0.6997 0.3330 0.3290 0.0000 0.1802
PRES
OIL Z-FACTOR
GAS Z-FACTOR
OIL DENSITY
------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ -----4375.0 0.0000 0.9817 0.0000 0.9683 0.0000 0.4625
3700.0 0.0000 0.9281 0.8930 0.8780 0.0000 0.5380
3000.0 0.0000 0.8258 0.8580 0.8380 0.0000 0.5746
2200.0 0.0000 0.6794 0.8600 0.8265 0.0000 0.6117
1400.0 0.0000 0.4959 0.8920 0.8474 0.0000 0.6496
700.0 0.0000 0.2917 0.9390 0.8922 0.0000 0.6891
D-202
Landmark - R2003.4
Example Problems
PRES
OIL VISCOSITY
GAS VISCOSITY
SURF TENS
------- --------------- --------------- ----------PSIG
DATA
CALC
DATA
CALC
DYNE/CM
------- ------ ------ ------ ------ ----------4375.0 0.0000 0.0667 0.0000 0.0596 0.4477E-04
3700.0 0.0000 0.0946 0.0000 0.0384 0.2028E+00
3000.0 0.0000 0.1145 0.0000 0.0287 0.1129E+01
2200.0 0.0000 0.1410 0.0000 0.0212 0.3777E+01
1400.0 0.0000 0.1765 0.0000 0.0166 0.9029E+01
700.0 0.0000 0.2239 0.0000 0.0143 0.1687E+02
---------------------------
OIL COMP
-------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
PRESSURE - PSIG
--------------4375. 3700. 3000.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
2200.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1400.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
700.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
2200.
-----0.0381
0.2788
0.0807
0.0936
0.0802
0.0475
0.0422
0.0622
0.2290
0.0477
1400.
-----0.0272
0.1840
0.0663
0.0886
0.0862
0.0555
0.0520
0.0766
0.3019
0.0617
700.
-----0.0147
0.0906
0.0427
0.0697
0.0821
0.0604
0.0616
0.0893
0.4062
0.0827
2200.
-----0.0686
0.6337
0.1043
0.0836
0.0000
0.0000
0.0128
0.0000
0.0000
0.0000
1400.
-----0.0695
0.6263
0.1089
0.0883
0.0000
0.0000
0.0107
0.0000
0.0000
0.0000
700.
-----0.0696
0.5813
0.1154
0.1024
0.0000
0.0000
0.0130
0.0000
0.0000
0.0000
2200.
-----0.0685
0.6138
0.1047
0.0849
0.0486
0.0206
0.0133
0.0375
0.0081
1400.
-----0.0696
0.6119
0.1090
0.0893
0.0505
0.0206
0.0126
0.0333
0.0032
700.
-----0.0685
0.5795
0.1146
0.1008
0.0605
0.0249
0.0149
0.0346
0.0017

-----------------------PRESSURE - PSIG
--------------OIL COMP
4375. 3700. 3000.
-------- ------ ------ -----CO2
0.0584 0.0520 0.0463
C1
0.5037 0.4248 0.3609
C2
0.0965 0.0927 0.0885
C3
0.0875 0.0907 0.0928
NC4
0.0590 0.0664 0.0726
NC5
0.0295 0.0353 0.0404
C6
0.0229 0.0290 0.0344
C8
0.0464 0.0475 0.0523
C14
0.0809 0.1312 0.1737
C30
0.0152 0.0304 0.0381
---------------------------
PRODUCED
GAS COMP
-------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
PRESSURE - PSIG
--------------4375. 3700. 3000.
------ ------ -----0.0584 0.0632 0.0661
0.5043 0.6053 0.6226
0.0965 0.0996 0.1011
0.0875 0.0827 0.0824
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0229 0.0142 0.0121
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000

------------------------
PRODUCED
GAS COMP
-------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
R2003.4 - Landmark
PRESSURE - PSIG
--------------4375. 3700. 3000.
------ ------ -----0.0597 0.0640 0.0664
0.5213 0.5742 0.5989
0.0972 0.0998 0.1018
0.0868 0.0847 0.0841
0.0573 0.0523 0.0498
0.0283 0.0244 0.0223
0.0216 0.0176 0.0153
0.0466 0.0454 0.0422
0.0701 0.0360 0.0190
D-203
Example Problems
C30
0.0110 0.0016 0.0003 0.0000 0.0000 0.0000
-----------------------0 P = 4375.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01
0.29500E-01 0.22900E-01 0.46396E-01
ZY = 0.96834 YY = 0.59695E-01 0.52134E+00 0.97211E-01
0.28305E-01 0.21649E-01 0.46600E-01
ZX = 0.98170 XX = 0.58355E-01 0.50371E+00 0.96475E-01
0.29541E-01 0.22943E-01 0.46389E-01
KV = 0.10230E+01 0.10350E+01 0.10076E+01
0.95815E+00 0.94361E+00 0.10046E+01
0 P = 3700.0 ZZ = 0.57907E-01 0.49814E+00 0.96205E-01
0.29948E-01 0.23371E-01 0.46479E-01
ZY = 0.87798 YY = 0.63997E-01 0.57418E+00 0.99845E-01
0.24411E-01 0.17555E-01 0.45448E-01
ZX = 0.92813 XX = 0.52032E-01 0.42479E+00 0.92695E-01
0.35289E-01 0.28981E-01 0.47474E-01
KV = 0.12300E+01 0.13517E+01 0.10771E+01
0.69175E+00 0.60574E+00 0.95733E+00
0 P = 3000.0 ZZ = 0.56759E-01 0.48456E+00 0.95444E-01
0.30985E-01 0.24466E-01 0.47051E-01
ZY = 0.83801 YY = 0.66418E-01 0.59887E+00 0.10185E+00
0.22261E-01 0.15250E-01 0.42241E-01
ZX = 0.82582 XX = 0.46310E-01 0.36089E+00 0.88520E-01
0.40423E-01 0.34436E-01 0.52254E-01
KV = 0.14342E+01 0.16594E+01 0.11505E+01
0.55071E+00 0.44286E+00 0.80839E+00
0 P = 2200.0 ZZ = 0.53981E-01 0.45391E+00 0.93253E-01
0.33441E-01 0.27106E-01 0.49310E-01
ZY = 0.82653 YY = 0.68472E-01 0.61378E+00 0.10468E+00
0.20631E-01 0.13333E-01 0.37526E-01
ZX = 0.67936 XX = 0.38111E-01 0.27881E+00 0.80733E-01
0.47470E-01 0.42192E-01 0.62217E-01
KV = 0.17966E+01 0.22014E+01 0.12967E+01
0.43462E+00 0.31601E+00 0.60314E+00
0 P = 1400.0 ZZ = 0.47985E-01 0.39346E+00 0.87221E-01
0.38371E-01 0.32676E-01 0.55432E-01
ZY = 0.84737 YY = 0.69648E-01 0.61187E+00 0.10902E+00
0.20558E-01 0.12553E-01 0.33313E-01
ZX = 0.49594 XX = 0.27207E-01 0.18397E+00 0.66317E-01
0.55457E-01 0.51978E-01 0.76648E-01
KV = 0.25600E+01 0.33260E+01 0.16439E+01
0.37070E+00 0.24150E+00 0.43463E+00
0 P =
700.0 ZZ = 0.36180E-01 0.28622E+00 0.71461E-01
0.46156E-01 0.42928E-01 0.67430E-01
ZY = 0.89224 YY = 0.68470E-01 0.57955E+00 0.11457E+00
0.24862E-01 0.14887E-01 0.34613E-01
ZX = 0.29174 XX = 0.14651E-01 0.90646E-01 0.42720E-01
0.60354E-01 0.61624E-01 0.89311E-01
KV = 0.46733E+01 0.63936E+01 0.26819E+01
0.41194E+00 0.24158E+00 0.38755E+00
---------------------
COMPONENT
--------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
0.58900E-01
0.15070E-01
0.57313E-01
0.10960E-01
0.58955E-01
0.15211E-01
0.97214E+00
0.72055E+00
0.59482E-01
0.16257E-01
0.52298E-01
0.15938E-02
0.66411E-01
0.30400E-01
0.78750E+00
0.52428E-01
0.60785E-01
0.18415E-01
0.49821E-01
0.25343E-03
0.72646E-01
0.38062E-01
0.68580E+00
0.66582E-02
0.63682E-01
0.22776E-01
0.48565E-01
0.24599E-04
0.80240E-01
0.47695E-01
0.60525E+00
0.51576E-03
0.68723E-01
0.31492E-01
0.50513E-01
0.19020E-05
0.86190E-01
0.61697E-01
0.58606E+00
0.30828E-04
0.73451E-01
0.49641E-01
0.60519E-01
0.20785E-06
0.82073E-01
0.82737E-01
0.73738E+00
0.25121E-05
MOLE FRACTION
------------0.05840
0.50430
0.09650
0.08750
0.05890
0.02950
0.02290
0.04640
0.08054
0.01507
FLASH CALCULATIONS:
D-204
0.87500E-01
0.80537E-01
0.86789E-01
0.70142E-01
0.87525E-01
0.80894E-01
0.99160E+00
0.86708E+00
0.87746E-01
0.84463E-01
0.84709E-01
0.35959E-01
0.90675E-01
0.13125E+00
0.93421E+00
0.27397E+00
0.88243E-01
0.93295E-01
0.84058E-01
0.18980E-01
0.92771E-01
0.17369E+00
0.90609E+00
0.10927E+00
0.89036E-01
0.11350E+00
0.84899E-01
0.80824E-02
0.93568E-01
0.22896E+00
0.90735E+00
0.35300E-01
0.88937E-01
0.15570E+00
0.89297E-01
0.32343E-02
0.88591E-01
0.30195E+00
0.10080E+01
0.10711E-01
0.82108E-01
0.24443E+00
0.10079E+00
0.17465E-02
0.69655E-01
0.40623E+00
0.14469E+01
0.42993E-02
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
276.0 DEGREES F
OBSERVED PSAT
4375.0 PSIG (BUBPT)
OBSERVED DNSAT
0.4530 GM/CC
STANDARD TEMP
STANDARD PRES
=
=
80.0 DEGREES F
0.0 PSIG
Landmark - R2003.4
OBSERVED OIL FVF

CALCULATED OIL FVF
Example Problems
=
=
CALCULATED API GRAV. =

CALCULATED TOTAL GOR =
CALCULATED TOTAL OGR =
PRES
-----PSIG
-----385.0
50.0
0.0
2.8520 RB/STB
2.7888 RB/STB
59.1
2724.96 SCF/STB
366.98 STB/MMSCF
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------80.0
0.
1783.
2187.
2259.
80.0
0.
261.
294.
292.
80.0
0.
174.
173.
174.
SEP FVF
--------------DATA
CALC
----------0.0000 1.2669
0.0000 1.1190
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.8041
0.0000 1.1812
0.0000 1.8612
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------385.0
80.0
0.3765
0.3414
0.0000
0.1652
0.0000
0.6962
50.0
80.0
0.2927
0.2563
0.0000
0.0314
0.0000
0.7236
0.0
80.0
0.2434
0.2055
0.0000
0.0080
0.0000
0.7416
-----------0STAGE 1
ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.90303 YY = 0.77703E-01 0.71530E+00 0.10955E+00 0.65623E-01 0.20470E-01
0.41623E-02 0.14786E-02 0.57141E-02 0.22666E-05 0.00000E+00
ZX = 0.16517 XX = 0.21160E-01 0.97222E-01 0.71328E-01 0.12971E+00 0.13304E+00
0.78384E-01 0.64228E-01 0.12488E+00 0.23591E+00 0.44142E-01
KV = 0.36722E+01 0.73574E+01 0.15358E+01 0.50593E+00 0.15386E+00
0.53102E-01 0.23021E-01 0.45756E-01 0.96080E-05 0.00000E+00
0STAGE 2
ZZ = 0.21160E-01 0.97222E-01 0.71328E-01 0.12971E+00 0.13304E+00
0.78384E-01 0.64228E-01 0.12488E+00 0.23591E+00 0.44142E-01
ZY = 0.96098 YY = 0.73985E-01 0.36439E+00 0.20596E+00 0.22278E+00 0.88951E-01
0.18117E-01 0.60952E-02 0.19721E-01 0.55682E-05 0.19770E-12
ZX = 0.03145 XX = 0.36348E-02 0.85898E-02 0.26665E-01 0.98830E-01 0.14767E+00
0.98377E-01 0.83513E-01 0.15977E+00 0.31417E+00 0.58786E-01
KV = 0.20355E+02 0.42421E+02 0.77240E+01 0.22542E+01 0.60237E+00
0.18415E+00 0.72985E-01 0.12344E+00 0.17724E-04 0.33630E-11
0STAGE 3
ZZ = 0.36348E-02 0.85898E-02 0.26665E-01 0.98830E-01 0.14767E+00
0.98377E-01 0.83513E-01 0.15977E+00 0.31417E+00 0.58786E-01
ZY = 0.97689 YY = 0.17548E-01 0.42425E-01 0.11997E+00 0.34938E+00 0.28097E+00
0.75911E-01 0.27638E-01 0.86140E-01 0.22523E-04 0.58072E-12
ZX = 0.00796 XX = 0.19677E-03 0.22905E-03 0.36097E-02 0.36920E-01 0.11473E+00
0.10393E+00 0.97320E-01 0.17796E+00 0.39179E+00 0.73312E-01
KV = 0.89182E+02 0.18522E+03 0.33235E+02 0.94631E+01 0.24490E+01
0.73042E+00 0.28399E+00 0.48403E+00 0.57489E-04 0.79212E-11
R2003.4 - Landmark
D-205
Example Problems
1
******************************************************************************
*
*
*
DDDDDD
EEEEEEE
SSSSS
KK
KK TTTTTTTT OOOOO
PPPPPP
*
*
DD
DD EE
SS
SS KK KK
TT
OO
OO PP
PP
*
*
DD
DD EE
SS
KK KK
TT
OO
OO PP
PP
*
*
DD
DD EEEEE
SSSSS
KKKK
TT
OO
OO PPPPPP
*
*
DD
DD EE
SS KK KK
TT
OO
OO PP
*
*
DD
DD EE
SS
SS KK KK
TT
OO
OO PP
*
*
DDDDDD
EEEEEEE
SSSSS
KK
KK
TT
OOOOO
PP
*
*
*
*
PPPPPP
VV
VV TTTTTTTT
*
*
PP
PP
V
V
TT
*
*
PP
PP
VV VV
TT
*
*
PPPPPP
V V
TT
*
*
PP
VVVV
TT
*
*
PP
VV
TT
*
*
PP
VV
TT
*
*
*
*
*
*
*
*
COPYRIGHT 1984, 1985, 1986, 1987, 1988
*
*
1989, 1990, 1991, 1992, 1993
*
*
1994, 1995, 1996, 1997, 1998
*
*
*
*
ALL RIGHTS RESERVED
*
*
*
*
VERSION 1998.0.0
CREATED 01 MAR 1998
*
*
*
*
LL
AAAAA
N
NN DDDDDD
M
M AAAAA
RRRRRR
KK
KK *
*
LL
AA
AA NN
NN DD
DD MM
MM AA
AA RR
RR KK KK
*
*
LL
AA
AA NNN NN DD
DD M M M M AA
AA RR
RR KK KK
*
*
LL
AAAAAAA NN N NN DD
KKKK
*
*
LL
AA
AA NN NNN DD
DD M
M AA
AA RR RR
KK KK
*
*
LL
AA
AA NN
NN DD
DD M
M AA
AA RR RR
KK KK
*
*
LLLLLLL AA
AA NN
N DDDDDD
M
M AA
AA RR
RR KK
KK *
*
*
*
GGGGG
RRRRRR
AAAAA
PPPPPP
HH
HH
IIII
CCCCC
SSSSS
*
*
GG
GG RR
RR AA
AA PP
PP HH
HH
II
CC
CC SS
SS *
*
GG
RR
RR AA
AA PP
PP HH
HH
II
CC
SS
*
*
GG
RRRRRR
AAAAAAA PPPPPP
HHHHHHH
II
CC
SSSSS
*
*
GG GGG RR RR
AA
AA PP
HH
HH
II
CC
SS *
*
GG
GG RR RR
AA
AA PP
HH
HH
II
CC
CC SS
SS *
*
GGGGG
RR
RR AA
AA PP
HH
HH
IIII
CCCCC
SSSSS
*
*
*
*****************************************************************************
1
**********************************************
*
*
*
*
*
*
*
*
*
*
*
VERSION 1998.0.0
*
*
*
*
COPYRIGHT 1984, 1985, 1986, 1987, 1988
*
*
1989, 1990, 1991, 1992, 1993
*
*
1994, 1995, 1996, 1997, 1998
*
*
*
*
ALL RIGHTS RESERVED
*
*
*
**********************************************
SEQUENCE
NUMBER
-------- ---------------------------------------------------------------------
1
2
3
4
5
6
D-206
X
C
-----------------------------X
C
DESKTOP-PVT EXAMPLE PROBLEM #1
X
C
X
C
TO MATCH VISCOSITY ONLY
X
C
BY ADJUSTING ZC
X
C
-----------------------------X
C
X
C
R REGRESS
R VARIABLE MIN
INIT
MAX
R
1
.25
1.
1.75
R
2
.25
1.
1.75
R
3
.25
1.
1.75
R
4
.25
1.
1.75
Landmark - R2003.4
7 R
X
8 R
9 R
X
10 R
11 R
12 R
13 R
14 R
15 R
X
16 R
X
X
X
X
X
X
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
R2003.4 - Landmark
Example Problems
5
.25
1.
1.75
C
IMAX
IPRINT H
TOL1
TOL2
TOL3
10
0
X
X
X
X
C
COMP
MW
TC
PC
ZC
ACENTRIC
OMEGAA
OMEGAB
C1
X
X
X
1
X
X
X
C6
X
X
X
2
X
X
X
C8
X
X
X
3
X
X
X
C14
X
X
X
4
X
X
X
C30
X
X
X
5
X
X
X
C
ENDREG
C
C
C -----------------------------------------------C EQUATION OF STATE DATA PRODUCED FROM DESKTOP-PVT
C -----------------------------------------------C
EOS PR
COMPONENTS
CO2 C1 C2 C3 NC4 NC5 C6 C8 C14 C30
PROPERTIES F
PSIA
COMP
MW
TC
PC
ZC
ACENTRIC OMEGAA
OMEGAB
PCHOR
CO2
44.01
87.90 1070.90 0.2742 0.2225 0.4572355 0.0777961
49.6
C1
16.04 -116.60 667.80 0.2890 0.0126 0.4233482 0.0887906
71.0
C2
30.07
90.10 707.80 0.2850 0.0978 0.4572355 0.0777961 111.0
C3
44.10
206.00 616.30 0.2810 0.1541 0.4572355 0.0777961 151.0
NC4
58.12
305.70 550.70 0.2740 0.2015 0.4572355 0.0777961 191.0
NC5
72.15
385.70 488.60 0.2620 0.2524 0.4572355 0.0777961 231.0
C6
84.00
463.00 468.30 0.2698 0.2313 0.4572355 0.0777961 271.0
C8
108.82
585.69 411.09 0.2609 0.3200 0.4321023 0.0989844 351.0
C14
187.49
790.04 283.80 0.2411 0.5033 0.4508624 0.0709275 591.9
C30
387.42 1138.35 165.63 0.2067 0.9360 0.4429810 0.0700926 1236.7
DJK C1
CO2
0.1500000
DJK C2
CO2
0.1500000
C1
0.0000000
DJK C3
CO2
0.1500000
C1
0.0000000
C2
0.0000000
DJK NC4
CO2
0.1500000
C1
0.0200000
C2
0.0100000
C3
0.0100000
DJK NC5
CO2
0.1500000
C1
0.0200000
C2
0.0100000
C3
0.0100000
NC4
0.0000000
DJK C6
CO2
0.1500000
C1
0.0298000
C2
0.0100000
C3
0.0100000
NC4
0.0000000
NC5
0.0000000
DJK C8
CO2
0.1500000
C1
-0.2357281
C2
0.0100000
C3
0.0100000
NC4
0.0000000
NC5
0.0000000
C6
0.0000000
DJK C14
CO2
0.1500000
C1
-0.1329010
C2
0.0100000
C3
0.0100000
NC4
0.0000000
NC5
0.0000000
C6
0.0000000
C8
0.0000000
DJK C30
CO2
0.1500000
C1
-0.0346095
D-207
Example Problems
63
64
65
66
67
68
69
C2
C3
NC4
NC5
C6
C8
C14
0.0100000
0.0100000
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
C
ENDEOS
X
C
X PVTFILE
X
C
X
C -----------------------------X
C CONSTANT COMPOSITION EXPANSION
X
C -----------------------------X
C
X
C NOTE: XLIQ IS USED BECAUSE DATA IS DEFINED AS
X
C
LIQUID VOLUME AT PRESSURE RELATIVE TO
X
C
VOLUME AT SATURATION PRESSURE.
X
C
71
CCEXP
72
COMPOSITION 0.0584
0.5043
0.0965
0.0875 0.0589
73
0.046396 0.080535 0.015069
74
TEMP 276
F
75
BUBPT 4375 PSIG
76
PRES
VREL
SLIQ
ZG
VISO
77
6200
X
X
X
.106
78
5780
X
X
X
.102
79
5415
X
X
X
.098
80
4980
X
X
X
.095
81
4620
X
X
X
.093
82
4375
X
X
X
.091
83
4225
X
X
X
.099
84
4100
X
X
X
.101
85
3900
X
X
X
.105
86
3700
X
X
X
.109
87
3400
X
X
X
.114
88
3000
X
X
X
.125
89
2600
X
X
X
.137
90
2200
X
X
X
.153
91
1800
X
X
X
.172
92
1400
X
X
X
.199
93
1000
X
X
X
.231
94
700
X
X
X
.260
95
0
X
X
X
.821
X
C
96
END
------------------------70
0.0295 0.0229
VISG
X
X
X
X
X
X
X
X
X
.026
X
.022
X
.018
X
.015
X
.014
X
CONTROL VARIABLES
----------------IMAX
---10
IPRINT
-----0
H
------0.2000
TOL1
------0.0010
TOL2
------0.0010
TOL3
------0.0100

----------------------------------------VARIABLE
-------1
2
3
4
5
MINIMUM
------0.2500
0.2500
0.2500
0.2500
0.2500
INITIAL
------1.0000
1.0000
1.0000
1.0000
1.0000
MAXIMUM
------1.7500
1.7500
1.7500
1.7500
1.7500

------------------------------COMPONENT
NO. NAME
--- -----1
CO2
D-208
MW
---0
TC
---0
PC
---0
ZC
---0
ACENTRIC
FACTOR
-------0
OMEGA
A
----0
OMEGA
B
----0
PCHOR
----0
VSHFT
-----0
Landmark - R2003.4
2
3
4
5
6
7
8
9
10
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
Example Problems
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
2
3
4
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
THERE ARE NO REGRESSION VARIABLES CORRESPONDING TO

BINARY INTERACTION COEFFICIENTS.

D
E
0
0

K-COEFFICIENT
REGRESSION VARIABLE
------------------------------k(1)
0
k(2)
0
k(3)
0
k(4)
0
k(5)
0
k(6)
0
k(7)
0
-----------------------------------------------------------------1
1
2
0
3
0 0
4
0 0 0
5
0 0 0 0
6
0 0 0 0
7
0 0 0 0
8
0 0 0 0
9
0 0 0 0
10
0 0 0 0
1EQUATION OF STATE:
9 10
0
0 0
0 0 0
0 0 0 0
0 0 0 0 0
PENG-ROBINSON
-------------------COMPONENT
MOLE
TC
PC
CRITICAL ACENTRIC
OMEGA
OMEGA
PCHOR
NO. NAME WEIGHT
DEG F
PSIA
Z-FACTOR FACTOR
A
B
-- ------ ------- -------- -------- -------- -------- -------- -------- ------1 CO2
44.01
87.90 1070.90
0.2742 0.22250 0.45724 0.07780
49.6
2 C1
16.04 -116.60
667.80
0.2890 0.01260 0.42335 0.08879
71.0
3 C2
30.07
90.10
707.80
0.2850 0.09780 0.45724 0.07780
111.0
4 C3
44.10
206.00
616.30
0.2810 0.15410 0.45724 0.07780
151.0
5 NC4
58.12
305.70
550.70
0.2740 0.20150 0.45724 0.07780
191.0
6 NC5
72.15
385.70
488.60
0.2620 0.25240 0.45724 0.07780
231.0
7 C6
84.00
463.00
468.30
0.2698 0.23130 0.45724 0.07780
271.0
8 C8
108.82
585.69
411.09
0.2609 0.32000 0.43210 0.09898
351.0
9 C14
187.49
790.04
283.80
0.2411 0.50330 0.45086 0.07093
591.9
10 C30
387.42 1138.35
165.63
0.2067 0.93600 0.44298 0.07009 1236.7
10

------------------------------1
1
2
3
R2003.4 - Landmark
10
0.1500
0.1500 0.0000
D-209
Example Problems
4
5
6
7
8
9
10
0.1500 0.0000
0.1500 0.0200
0.1500 0.0200
0.1500 0.0298
0.1500-0.2357
0.1500-0.1329
0.1500-0.0346
0.0000
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000

---------------------------------------------------------NO.
----k(1)
k(2)
k(3)
k(4)
k(5)
k(6)
k(7)
K-COEFFICIENT
--------------0.9746020E+01
0.1808340E+02
0.4126660E+04
0.4460550E+02
0.9765440E+00
0.8181340E+02
0.1564990E+05

--------------------------------------1
1
2
3
4
5
6
7
8
9
10
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
10
0.0000
0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000

A = A0 + A1*T + A2*T**2 + A3*T**3 + A4*T**4
B = B0 + B1*T + B2*T**2 + B3*T**3 + B4*T**4
C = A0 + C1*T + C2*T**2 + C3*T**3 + C4*T**4
where Rsw
P
T
S
in
in
in
in
A0
1.1630599
B0
0.9650900
C0
1.2803000
S0
-0.0280370
scf/stb
psia
degree F
A1
-16.6303997
B1
-0.2725500
C1
-10.7566004
S1
-0.1203900
A2
111.0730515
B2
0.0923400
C2
52.6962204
A3
-376.8592529
B3
-0.1008300
C3
-222.3948822
A4
524.8891602
B4
0.0997900
C4
462.6725464

D1 =
5.80000

------------------------------------H* = A + B*T + C*(T**2) + D*(T**3) + E*(T**4) + F*(T**5)
WHERE THE UNITS ARE
H* - BTU / LB-MOLE
T
- DEGREES RANKIN
COMPONENT
NO NAME
A
B
C
D
E
F
-- ------ ---------- ---------- ---------- ---------- ---------- ---------1 CO2
0.210E+03 0.504E+01 0.445E-02 -0.117E-05 0.153E-09 -0.578E-14
2 C1
-0.112E+03 0.917E+01 -0.472E-02 0.679E-05 -0.245E-08 0.312E-12
D-210
Landmark - R2003.4
3
4
5
6
7
8
9
10
C2
C3
NC4
NC5
C6
C8
C14
C30
Example Problems
-0.631E+00 0.796E+01 -0.752E-03 0.879E-05 -0.387E-08 0.548E-12

-0.325E+02 0.761E+01 0.415E-02 0.951E-05 -0.472E-08 0.702E-12
0.432E+03 0.573E+01 0.156E-01 0.301E-05 -0.244E-08 0.381E-12
0.196E+04 -0.202E+00 0.318E-01 -0.623E-05 0.590E-09 -0.142E-13
0.000E+00 0.242E+01 0.343E-01 -0.477E-05 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.171E+02 0.786E-01 -0.118E-04 0.000E+00 0.000E+00
0.000E+00 0.702E+01 0.153E+00 -0.199E-04 0.000E+00 0.000E+00
------------------------------
COMPONENT
--------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
22
MOLE FRACTION
------------0.05840
0.50430
0.09650
0.08750
0.05890
0.02950
0.02290
0.04640
0.08054
0.01507
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
276.00 DEGREES F
OBSERVED PSAT
CALCULATED PSAT
OIL DENSITY AT PSAT
GAS DENSITY AT PSAT
= 4375.00 PSIG
= 4376.41 PSIG
= 0.0000
= 0.9814
= 0.4617 GM/CC
= 0.4367 GM/CC
(BUBPT)
(BUBPT)
PRES
REL. VOLUME
LIQ VOL FRAC
LIQ MOLE FRAC
------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ -----6200.0 0.0000 0.9185 0.0000 1.0000 0.0000 1.0000
5780.0 0.0000 0.9334 0.0000 1.0000 0.0000 1.0000
5415.0 0.0000 0.9479 0.0000 1.0000 0.0000 1.0000
4980.0 0.0000 0.9674 0.0000 1.0000 0.0000 1.0000
4620.0 0.0000 0.9860 0.0000 1.0000 0.0000 1.0000
4375.0 0.0000 1.0001 0.0000 0.9680 0.0000 0.9676
4225.0 0.0000 1.0159 0.0000 0.5950 0.0000 0.5838
4100.0 0.0000 1.0303 0.0000 0.5505 0.0000 0.5367
3900.0 0.0000 1.0560 0.0000 0.5105 0.0000 0.4955
3700.0 0.0000 1.0857 0.0000 0.4816 0.0000 0.4678
3400.0 0.0000 1.1398 0.0000 0.4439 0.0000 0.4353
3000.0 0.0000 1.2356 0.0000 0.3941 0.0000 0.3979
2600.0 0.0000 1.3711 0.0000 0.3416 0.0000 0.3626
2200.0 0.0000 1.5697 0.0000 0.2859 0.0000 0.3281
1800.0 0.0000 1.8769 0.0000 0.2278 0.0000 0.2936
1400.0 0.0000 2.3917 0.0000 0.1686 0.0000 0.2580
1000.0 0.0000 3.3740 0.0000 0.1107 0.0000 0.2197
700.0 0.0000 4.9100 0.0000 0.0703 0.0000 0.1877
0.0
0.00 280.93 0.0000 0.0007 0.0000 0.0741
PRES
OIL Z-FACTOR
GAS Z-FACTOR
OIL DENSITY
GAS DENSITY
------- --------------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ ------ ------ -----6200.0 0.0000 1.2759 0.0000 0.0000 0.0000 0.5027 0.0000 0.0000
5780.0 0.0000 1.2089 0.0000 0.0000 0.0000 0.4946 0.0000 0.0000
5415.0 0.0000 1.1503 0.0000 0.0000 0.0000 0.4871 0.0000 0.0000
4980.0 0.0000 1.0800 0.0000 0.0000 0.0000 0.4773 0.0000 0.0000
4620.0 0.0000 1.0213 0.0000 0.0000 0.0000 0.4683 0.0000 0.0000
4375.0 0.0000 0.9817 0.0000 0.9684 0.0000 0.4625 0.0000 0.4358
4225.0 0.0000 0.9810 0.0000 0.9368 0.0000 0.4952 0.0000 0.3947
4100.0 0.0000 0.9719 0.0000 0.9192 0.0000 0.5089 0.0000 0.3737
3900.0 0.0000 0.9521 0.0000 0.8963 0.0000 0.5251 0.0000 0.3455
R2003.4 - Landmark
D-211
Example Problems
3700.0
3400.0
3000.0
2600.0
2200.0
1800.0
1400.0
1000.0
700.0
0.0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.9281
0.8870
0.8247
0.7548
0.6771
0.5906
0.4941
0.3855
0.2936
0.0086
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.8780
0.8567
0.8377
0.8277
0.8258
0.8322
0.8474
0.8721
0.8977
0.9962
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.5380
0.5544
0.5737
0.5918
0.6096
0.6276
0.6471
0.6697
0.6909
0.7800
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.3205
0.2859
0.2436
0.2044
0.1678
0.1334
0.1010
0.0705
0.0489
0.0011
PRES
OIL VISCOSITY
GAS VISCOSITY
SURF TENS
------- --------------- --------------- ----------PSIG
DATA
CALC
DATA
CALC
DYNE/CM
------- ------ ------ ------ ------ ----------6200.0 0.1060 0.0824 0.0000 0.0000 0.0000E+00
5780.0 0.1020 0.0788 0.0000 0.0000 0.0000E+00
5415.0 0.0980 0.0756 0.0000 0.0000 0.0000E+00
4980.0 0.0950 0.0718 0.0000 0.0000 0.0000E+00
4620.0 0.0930 0.0686 0.0000 0.0000 0.0000E+00
4375.0 0.0910 0.0667 0.0000 0.0596 0.4442E-04
4225.0 0.0990 0.0770 0.0000 0.0507 0.8978E-02
4100.0 0.1010 0.0821 0.0000 0.0468 0.2973E-01
3900.0 0.1050 0.0887 0.0000 0.0422 0.9333E-01
3700.0 0.1090 0.0946 0.0260 0.0384 0.2028E+00
3400.0 0.1140 0.1028 0.0000 0.0338 0.4770E+00
3000.0 0.1250 0.1139 0.0220 0.0287 0.1112E+01
2600.0 0.1370 0.1259 0.0000 0.0246 0.2146E+01
2200.0 0.1530 0.1393 0.0180 0.0212 0.3689E+01
1800.0 0.1720 0.1549 0.0000 0.0186 0.5869E+01
1400.0 0.1990 0.1739 0.0150 0.0166 0.8859E+01
1000.0 0.2310 0.1993 0.0000 0.0152 0.1296E+02
700.0 0.2600 0.2268 0.0140 0.0143 0.1715E+02
0.0 0.8210 0.3676 0.0000 0.0126 0.3715E+02
---------------------------
OIL COMP
-------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
PRESSURE - PSIG
----------------6200. 5780. 5415.
3400. 3000. 2600.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
4980.
2200.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4620.
1800.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4375.
1400.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4225.
1000.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4100.
700.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
3900.
0.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4620.
1800.
-----0.0584
0.0331
0.5043
0.2349
0.0965
0.0743
0.0875
0.0917
4375.
1400.
-----0.0584
0.0272
0.5037
0.1862
0.0965
0.0655
0.0875
0.0871
4225.
1000.
-----0.0563
0.0203
0.4765
0.1342
0.0953
0.0531
0.0886
0.0774
4100.
700.
-----0.0551
0.0146
0.4623
0.0936
0.0946
0.0407
0.0892
0.0643
3900.
0.
-----0.0536
0.0003
0.4428
0.0016
0.0937
0.0009
0.0900
0.0018
3700.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

--------------------------------
OIL COMP
-------CO2
C1
C2
C3
D-212
PRESSURE - PSIG
----------------6200. 5780. 5415.
3400. 3000. 2600.
------ ------ -----0.0584 0.0584 0.0584
0.0497 0.0463 0.0425
0.5043 0.5043 0.5043
0.3982 0.3615 0.3223
0.0965 0.0965 0.0965
0.0911 0.0885 0.0851
0.0875 0.0875 0.0875
0.0916 0.0927 0.0934
4980.
2200.
-----0.0584
0.0381
0.5043
0.2802
0.0965
0.0806
0.0875
0.0933
3700.
-----0.0520
0.4248
0.0927
0.0907
Landmark - R2003.4
NC4
0.0589 0.0589 0.0589

0.0690 0.0726 0.0764
0.0295 0.0295 0.0295
0.0374 0.0404 0.0438
C6
0.0229 0.0229 0.0229
0.0312 0.0344 0.0381
C8
0.0464 0.0464 0.0464
0.0491 0.0524 0.0571
C14
0.0805 0.0805 0.0805
0.1490 0.1735 0.1998
C30
0.0151 0.0151 0.0151
0.0337 0.0375 0.0414
--------------------------NC5
GAS COMP
-------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
PRESSURE - PSIG
----------------6200. 5780. 5415.
3400. 3000. 2600.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
Example Problems
0.0589
0.0801
0.0295
0.0475
0.0229
0.0423
0.0464
0.0633
0.0805
0.2287
0.0151
0.0459
0.0589
0.0833
0.0295
0.0515
0.0229
0.0471
0.0464
0.0710
0.0805
0.2619
0.0151
0.0513
0.0590
0.0851
0.0295
0.0553
0.0229
0.0524
0.0464
0.0802
0.0809
0.3028
0.0152
0.0584
0.0615
0.0828
0.0315
0.0579
0.0250
0.0576
0.0462
0.0892
0.0977
0.3589
0.0215
0.0686
0.0628
0.0752
0.0325
0.0568
0.0260
0.0600
0.0463
0.0930
0.1067
0.4215
0.0243
0.0803
0.0647
0.0028
0.0339
0.0029
0.0275
0.0044
0.0467
0.0060
0.1193
0.7760
0.0277
0.2033
0.0664
4980.
2200.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4620.
1800.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4375.
1400.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4225.
1000.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4100.
700.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
3900.
0.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
3700.
0.0353
0.0290
0.0475
0.1312
0.0304
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

-------------------------------PRESSURE - PSIG
----------------GAS COMP
6200. 5780. 5415. 4980. 4620. 4375. 4225. 4100.
3400. 3000. 2600. 2200. 1800. 1400. 1000.
700.
-------- ------ ------ ------ ------ ------ ------ ------ -----CO2
0.0000 0.0000 0.0000 0.0000 0.0000 0.0597 0.0614 0.0622
0.0651 0.0664 0.0674 0.0683 0.0689 0.0693 0.0691 0.0685
C1
0.0000 0.0000 0.0000 0.0000 0.0000 0.5213 0.5433 0.5529
0.5861 0.5987 0.6078 0.6137 0.6163 0.6149 0.6085 0.5992
C2
0.0000 0.0000 0.0000 0.0000 0.0000 0.0972 0.0982 0.0986
0.1007 0.1018 0.1030 0.1043 0.1057 0.1073 0.1087 0.1094
C3
0.0000 0.0000 0.0000 0.0000 0.0000 0.0868 0.0859 0.0855
0.0843 0.0840 0.0841 0.0847 0.0858 0.0876 0.0904 0.0929
NC4
0.0000 0.0000 0.0000 0.0000 0.0000 0.0573 0.0553 0.0543
0.0511 0.0498 0.0490 0.0486 0.0487 0.0498 0.0522 0.0551
NC5
0.0000 0.0000 0.0000 0.0000 0.0000 0.0283 0.0267 0.0260
0.0234 0.0223 0.0214 0.0207 0.0204 0.0205 0.0215 0.0232
C6
0.0000 0.0000 0.0000 0.0000 0.0000 0.0217 0.0200 0.0193
0.0165 0.0153 0.0143 0.0134 0.0128 0.0127 0.0131 0.0143
C8
0.0000 0.0000 0.0000 0.0000 0.0000 0.0466 0.0467 0.0465
0.0443 0.0424 0.0403 0.0381 0.0362 0.0347 0.0343 0.0356
C14
0.0000 0.0000 0.0000 0.0000 0.0000 0.0702 0.0565 0.0502
0.0278 0.0191 0.0127 0.0082 0.0052 0.0033 0.0022 0.0018
C30
0.0000 0.0000 0.0000 0.0000 0.0000 0.0110 0.0061 0.0043
0.0007 0.0003 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000
-----------------------0 P = 4375.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01
ZY = 0.96835 YY = 0.59694E-01 0.52132E+00 0.97210E-01 0.86790E-01
0.28306E-01 0.21651E-01 0.46600E-01 0.70152E-01
ZX = 0.98169 XX = 0.58357E-01 0.50373E+00 0.96476E-01 0.87524E-01
0.29540E-01 0.22942E-01 0.46389E-01 0.80883E-01
KV = 0.10229E+01 0.10349E+01 0.10076E+01 0.99161E+00
0.95823E+00 0.94372E+00 0.10046E+01 0.86733E+00
0 P = 4225.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01
R2003.4 - Landmark
3900.
0.
-----0.0632
0.0631
0.5647
0.5445
0.0993
0.1042
0.0851
0.0944
0.0532
0.0634
0.0252
0.0316
0.0183
0.0244
0.0461
0.0496
0.0424
0.0249
0.0026
0.0000
3700.
-----0.0640
0.5742
0.0998
0.0847
0.0523
0.0244
0.0176
0.0454
0.0360
0.0016
0.58900E-01
0.15069E-01
0.57314E-01
0.10964E-01
0.58953E-01
0.15207E-01
0.97220E+00
0.72102E+00
0.58900E-01
D-213
Example Problems
0.29500E-01
ZY = 0.93685 YY = 0.61399E-01
0.26746E-01
ZX = 0.98105 XX = 0.56262E-01
0.31463E-01
KV = 0.10913E+01
0.85007E+00
0 P = 4100.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.91916 YY = 0.62178E-01
0.26042E-01
ZX = 0.97194 XX = 0.55138E-01
0.32485E-01
KV = 0.11277E+01
0.80167E+00
0 P = 3900.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.89634 YY = 0.63161E-01
0.25160E-01
ZX = 0.95206 XX = 0.53552E-01
0.33919E-01
KV = 0.11794E+01
0.74176E+00
0 P = 3700.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.87798 YY = 0.63997E-01
0.24412E-01
ZX = 0.92813 XX = 0.52032E-01
0.35289E-01
KV = 0.12300E+01
0.69176E+00
0 P = 3400.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.85671 YY = 0.65101E-01
0.23423E-01
ZX = 0.88702 XX = 0.49706E-01
0.37384E-01
KV = 0.13097E+01
0.62655E+00
0 P = 3000.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.83772 YY = 0.66370E-01
0.22293E-01
ZX = 0.82474 XX = 0.46337E-01
0.40408E-01
KV = 0.14323E+01
0.55168E+00
0 P = 2600.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.82766 YY = 0.67434E-01
0.21376E-01
ZX = 0.75484 XX = 0.42519E-01
0.43780E-01
KV = 0.15860E+01
0.48826E+00
0 P = 2200.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.82577 YY = 0.68297E-01
0.20706E-01
ZX = 0.67708 XX = 0.38134E-01
0.47507E-01
KV = 0.17910E+01
0.43586E+00
0 P = 1800.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.83218 YY = 0.68933E-01
0.20361E-01
ZX = 0.59061 XX = 0.33058E-01
0.51488E-01
KV = 0.20852E+01
0.39546E+00
0 P = 1400.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.84737 YY = 0.69263E-01
0.20512E-01
ZX = 0.49413 XX = 0.27159E-01
0.55348E-01
KV = 0.25502E+01
0.37061E+00
0 P = 1000.0 ZZ = 0.58400E-01
0.29500E-01
D-214
0.22900E-01
0.54329E+00
0.20015E-01
0.47651E+00
0.24956E-01
0.11401E+01
0.80200E+00
0.50430E+00
0.22900E-01
0.55293E+00
0.19276E-01
0.46231E+00
0.26029E-01
0.11960E+01
0.74054E+00
0.50430E+00
0.22900E-01
0.56465E+00
0.18346E-01
0.44284E+00
0.27538E-01
0.12751E+01
0.66621E+00
0.50430E+00
0.22900E-01
0.57418E+00
0.17555E-01
0.42480E+00
0.28981E-01
0.13517E+01
0.60575E+00
0.50430E+00
0.22900E-01
0.58610E+00
0.16505E-01
0.39818E+00
0.31197E-01
0.14719E+01
0.52905E+00
0.50430E+00
0.22900E-01
0.59865E+00
0.15284E-01
0.36150E+00
0.34427E-01
0.16560E+01
0.44396E+00
0.50430E+00
0.22900E-01
0.60782E+00
0.14253E-01
0.32233E+00
0.38100E-01
0.18857E+01
0.37410E+00
0.50430E+00
0.22900E-01
0.61373E+00
0.13425E-01
0.28021E+00
0.42302E-01
0.21903E+01
0.31736E+00
0.50430E+00
0.22900E-01
0.61628E+00
0.12849E-01
0.23487E+00
0.47082E-01
0.26240E+01
0.27292E+00
0.50430E+00
0.22900E-01
0.61492E+00
0.12654E-01
0.18617E+00
0.52367E-01
0.33031E+01
0.24165E+00
0.50430E+00
0.22900E-01
0.46396E-01
0.98180E-01
0.46656E-01
0.95302E-01
0.46211E-01
0.10302E+01
0.10096E+01
0.96500E-01
0.46396E-01
0.98650E-01
0.46496E-01
0.94644E-01
0.46310E-01
0.10423E+01
0.10040E+01
0.96500E-01
0.46396E-01
0.99276E-01
0.46057E-01
0.93673E-01
0.46741E-01
0.10598E+01
0.98538E+00
0.96500E-01
0.46396E-01
0.99845E-01
0.45448E-01
0.92695E-01
0.47474E-01
0.10771E+01
0.95733E+00
0.96500E-01
0.46396E-01
0.10067E+00
0.44283E-01
0.91095E-01
0.49137E-01
0.11051E+01
0.90123E+00
0.96500E-01
0.46396E-01
0.10178E+00
0.42396E-01
0.88514E-01
0.52450E-01
0.11498E+01
0.80831E+00
0.96500E-01
0.46396E-01
0.10297E+00
0.40295E-01
0.85132E-01
0.57120E-01
0.12095E+01
0.70545E+00
0.96500E-01
0.46396E-01
0.10428E+00
0.38146E-01
0.80565E-01
0.63291E-01
0.12944E+01
0.60271E+00
0.96500E-01
0.46396E-01
0.10574E+00
0.36150E-01
0.74268E-01
0.71048E-01
0.14238E+01
0.50882E+00
0.96500E-01
0.46396E-01
0.10729E+00
0.34659E-01
0.65461E-01
0.80151E-01
0.16390E+01
0.43242E+00
0.96500E-01
0.46396E-01
0.80535E-01
0.85890E-01
0.56461E-01
0.88647E-01
0.97695E-01
0.96890E+00
0.57793E+00
0.87500E-01
0.80535E-01
0.85508E-01
0.50231E-01
0.89219E-01
0.10670E+00
0.95841E+00
0.47078E+00
0.87500E-01
0.80535E-01
0.85059E-01
0.42441E-01
0.89986E-01
0.11933E+00
0.94524E+00
0.35567E+00
0.87500E-01
0.80535E-01
0.84709E-01
0.35960E-01
0.90675E-01
0.13125E+00
0.93421E+00
0.27399E+00
0.87500E-01
0.80535E-01
0.84315E-01
0.27758E-01
0.91632E-01
0.14900E+00
0.92015E+00
0.18629E+00
0.87500E-01
0.80535E-01
0.84040E-01
0.19091E-01
0.92737E-01
0.17353E+00
0.90622E+00
0.11002E+00
0.87500E-01
0.80535E-01
0.84121E-01
0.12688E-01
0.93440E-01
0.19980E+00
0.90026E+00
0.63503E-01
0.87500E-01
0.80535E-01
0.84655E-01
0.81791E-02
0.93325E-01
0.22870E+00
0.90710E+00
0.35763E-01
0.87500E-01
0.80535E-01
0.85772E-01
0.51628E-02
0.91657E-01
0.26188E+00
0.93580E+00
0.19714E-01
0.87500E-01
0.80535E-01
0.87633E-01
0.32634E-02
0.87117E-01
0.30277E+00
0.10059E+01
0.10779E-01
0.87500E-01
0.80535E-01
0.15069E-01
0.55260E-01
0.61040E-02
0.61495E-01
0.21459E-01
0.89861E+00
0.28445E+00
0.58900E-01
0.15069E-01
0.54350E-01
0.43383E-02
0.62829E-01
0.24334E-01
0.86505E+00
0.17828E+00
0.58900E-01
0.15069E-01
0.53228E-01
0.26203E-02
0.64676E-01
0.27746E-01
0.82300E+00
0.94440E-01
0.58900E-01
0.15069E-01
0.52299E-01
0.15939E-02
0.66410E-01
0.30399E-01
0.78751E+00
0.52434E-01
0.58900E-01
0.15069E-01
0.51111E-01
0.74180E-03
0.69005E-01
0.33656E-01
0.74069E+00
0.22041E-01
0.58900E-01
0.15069E-01
0.49845E-01
0.25353E-03
0.72604E-01
0.37492E-01
0.68654E+00
0.67623E-02
0.58900E-01
0.15069E-01
0.48967E-01
0.81257E-04
0.76361E-01
0.41415E-01
0.64125E+00
0.19620E-02
0.58900E-01
0.15069E-01
0.48551E-01
0.24376E-04
0.80093E-01
0.45877E-01
0.60618E+00
0.53134E-03
0.58900E-01
0.15069E-01
0.48741E-01
0.68466E-05
0.83343E-01
0.51309E-01
0.58482E+00
0.13344E-03
0.58900E-01
0.15069E-01
0.49804E-01
0.18258E-05
0.85060E-01
0.58402E-01
0.58552E+00
0.31262E-04
0.58900E-01
0.15069E-01
Landmark - R2003.4
ZY = 0.87207 YY = 0.69117E-01
0.21506E-01
ZX = 0.38550 XX = 0.20333E-01
0.57895E-01
KV = 0.33992E+01
0.37147E+00
0 P =
700.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.89770 YY = 0.68521E-01
0.23189E-01
ZX = 0.29363 XX = 0.14603E-01
0.56812E-01
KV = 0.46923E+01
0.40817E+00
0 P =
0.0 ZZ = 0.58400E-01
0.29500E-01
ZY = 0.99620 YY = 0.63053E-01
0.31627E-01
ZX = 0.00863 XX = 0.27662E-03
0.29244E-02
KV = 0.22794E+03
0.10815E+02
1
Example Problems
0.60849E+00
0.13131E-01
0.13423E+00
0.57598E-01
0.45333E+01
0.22798E+00
0.50430E+00
0.22900E-01
0.59920E+00
0.14324E-01
0.93613E-01
0.60014E-01
0.64008E+01
0.23867E+00
0.50430E+00
0.22900E-01
0.54454E+00
0.24382E-01
0.16170E-02
0.43890E-02
0.33676E+03
0.55553E+01
0.10872E+00
0.34338E-01
0.53087E-01
0.89226E-01
0.20480E+01
0.38484E+00
0.96500E-01
0.46396E-01
0.10938E+00
0.35638E-01
0.40741E-01
0.92953E-01
0.26849E+01
0.38340E+00
0.96500E-01
0.46396E-01
0.10415E+00
0.49629E-01
0.91596E-03
0.60019E-02
0.11371E+03
0.82690E+01

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------1
1.00000000
0.28900000
0.00000000
2
1.00000000
0.26980001
0.00000000
3
1.00000000
0.26089999
0.00000000
4
1.00000000
0.24110000
0.00000000
5
1.00000000
0.20670000
0.00000000
=
1.243284E+00
1.912255E-01
2

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------1
1.01423220
0.29311311
0.01423220
2
0.97102764
0.26198326
-0.02897236
3
0.92489923
0.24130620
-0.07510077
4
1.01792504
0.24542173
0.01792504
5
1.22315734
0.25282662
0.22315734
=
7.612905E-01
1.496359E-01
3

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------1
1.12402743
0.32484393
0.10979523
2
0.94937711
0.25614195
-0.02165054
3
0.84873991
0.22143624
-0.07615932
4
0.86975197
0.20969720
-0.14817307
5
1.52833219
0.31590626
0.30517485
=
6.590943E-01
1.392305E-01
4

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------1
1.08466183
0.31346727
-0.03936561
2
1.01153286
0.27291157
0.06215575
3
0.98691399
0.25748585
0.13817408
4
0.76975791
0.18558863
-0.09999406
5
1.74977833
0.36167918
0.22144614
=
6.407836E-01
1.372828E-01
5
R2003.4 - Landmark
0.90354E-01
0.21680E-02
0.77362E-01
0.35889E+00
0.11679E+01
0.60410E-02
0.87500E-01
0.80535E-01
0.92858E-01
0.17548E-02
0.64314E-01
0.42146E+00
0.14438E+01
0.41635E-02
0.87500E-01
0.80535E-01
0.94360E-01
0.24868E-01
0.18038E-02
0.77595E+00
0.52312E+02
0.32049E-01
0.52173E-01
0.48206E-06
0.82794E-01
0.68591E-01
0.63015E+00
0.70280E-05
0.58900E-01
0.15069E-01
0.55131E-01
0.18709E-06
0.75210E-01
0.80280E-01
0.73302E+00
0.23304E-05
0.58900E-01
0.15069E-01
0.63390E-01
0.53901E-06
0.28099E-02
0.20331E+00
0.22559E+02
0.26511E-05
DELTA VAR.
----------0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
DELTA VAR.
----------0.00411311
-0.00781674
-0.01959379
0.00432173
0.04612662
DELTA VAR.
----------0.03173082
-0.00584131
-0.01986997
-0.03572453
0.06307964
DELTA VAR.
-----------0.01137666
0.01676962
0.03604962
-0.02410857
0.04577292
D-215
Example Problems

--------------------------0INDEX
X
VARIABLE
DELTA X
DELTA VAR.
--------------------------------------------1
1.07657204
0.31112933
-0.00808978
-0.00233795
2
1.61547698
0.43585570
0.60394412
0.16294413
3
0.76115014
0.19858406
-0.22576386
-0.05890179
4
0.76010579
0.18326150
-0.00965212
-0.00232713
5
1.74977833
0.36167918
0.00000000
0.00000000
=
6.355456E-01
1.367206E-01
0TOTAL NUMBER OF FUNCTION EVALUATIONS =
34
THE RELATIVE CHANGE IN THE OBJECTIVE FUNCTION WAS LESS THAN TOL3 =
0.01000
-------------------COMPONENT
MOLE
TC
PC
CRITICAL ACENTRIC
OMEGA
OMEGA
PCHOR
NO. NAME WEIGHT
DEG F
PSIA
Z-FACTOR FACTOR
A
B
-- ------ ------- -------- -------- -------- -------- -------- -------- ------1 CO2
44.01
87.90 1070.90
0.2742 0.22250 0.45724 0.07780
49.6
2 C1
16.04 -116.60
667.80
0.3111 0.01260 0.42335 0.08879
71.0
3 C2
30.07
90.10
707.80
0.2850 0.09780 0.45724 0.07780
111.0
4 C3
44.10
206.00
616.30
0.2810 0.15410 0.45724 0.07780
151.0
5 NC4
58.12
305.70
550.70
0.2740 0.20150 0.45724 0.07780
191.0
6 NC5
72.15
385.70
488.60
0.2620 0.25240 0.45724 0.07780
231.0
7 C6
84.00
463.00
468.30
0.4359 0.23130 0.45724 0.07780
271.0
8 C8
108.82
585.69
411.09
0.1986 0.32000 0.43210 0.09898
351.0
9 C14
187.49
790.04
283.80
0.1833 0.50330 0.45086 0.07093
591.9
10 C30
387.42 1138.35
165.63
0.3617 0.93600 0.44298 0.07009 1236.7
10

------------------------------1
1
2
3
4
5
6
7
8
9
10
0.1500
0.1500 0.0000
0.1500 0.0000
0.1500 0.0200
0.1500 0.0200
0.1500 0.0298
0.1500-0.2357
0.1500-0.1329
0.1500-0.0346
0.0000
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0000
0.0000
0.0000
0.0000
0.0000
10
0.0000
0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000

---------------------------------------------------------NO.
----k(1)
k(2)
k(3)
k(4)
k(5)
k(6)
k(7)
K-COEFFICIENT
--------------0.9746020E+01
0.1808340E+02
0.4126660E+04
0.4460550E+02
0.9765440E+00
0.8181340E+02
0.1564990E+05

--------------------------------------1
1
2
3
4
5
6
7
8
9
10
D-216
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
10
0.0000
0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
Landmark - R2003.4
Example Problems

A = A0 + A1*T + A2*T**2 + A3*T**3 + A4*T**4
B = B0 + B1*T + B2*T**2 + B3*T**3 + B4*T**4
C = A0 + C1*T + C2*T**2 + C3*T**3 + C4*T**4
where Rsw
P
T
S
in
in
in
in
A0
1.1630599
B0
0.9650900
C0
1.2803000
S0
-0.0280370
scf/stb
psia
degree F
A1
-16.6303997
B1
-0.2725500
C1
-10.7566004
S1
-0.1203900
A2
111.0730515
B2
0.0923400
C2
52.6962204
A3
-376.8592529
B3
-0.1008300
C3
-222.3948822
A4
524.8891602
B4
0.0997900
C4
462.6725464

D1 =
5.80000

------------------------------------H* = A + B*T + C*(T**2) + D*(T**3) + E*(T**4) + F*(T**5)
WHERE THE UNITS ARE
H* - BTU / LB-MOLE
T
- DEGREES RANKIN
COMPONENT
NO NAME
-- -----1 CO2
2 C1
3 C2
4 C3
5 NC4
6 NC5
7 C6
8 C8
9 C14
10 C30
A
B
C
D
---------- ---------- ---------- ---------0.210E+03 0.504E+01 0.445E-02 -0.117E-05
-0.112E+03 0.917E+01 -0.472E-02 0.679E-05
-0.631E+00 0.796E+01 -0.752E-03 0.879E-05
-0.325E+02 0.761E+01 0.415E-02 0.951E-05
0.432E+03 0.573E+01 0.156E-01 0.301E-05
0.196E+04 -0.202E+00 0.318E-01 -0.623E-05
0.000E+00 0.242E+01 0.343E-01 -0.477E-05
0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.171E+02 0.786E-01 -0.118E-04
0.000E+00 0.702E+01 0.153E+00 -0.199E-04
E
F
---------- ---------0.153E-09 -0.578E-14
-0.245E-08 0.312E-12
-0.387E-08 0.548E-12
-0.472E-08 0.702E-12
-0.244E-08 0.381E-12
0.590E-09 -0.142E-13
0.000E+00 0.000E+00
0.000E+00 0.000E+00
0.000E+00 0.000E+00
0.000E+00 0.000E+00
------------------------------
COMPONENT
--------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
MOLE FRACTION
------------0.05840
0.50430
0.09650
0.08750
0.05890
0.02950
0.02290
0.04640
0.08054
0.01507
FLASH CALCULATIONS:
R2003.4 - Landmark
22
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
276.00 DEGREES F
OBSERVED PSAT
CALCULATED PSAT
= 4375.00 PSIG
= 4376.41 PSIG
= 0.0000
(BUBPT)
(BUBPT)
D-217
Example Problems
CALCULATED Z-FACTOR AT PSAT =

OIL DENSITY AT PSAT
=
GAS DENSITY AT PSAT
=
0.9814
0.4617 GM/CC
0.4367 GM/CC
PRES
REL. VOLUME
LIQ VOL FRAC
LIQ MOLE FRAC
------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ -----6200.0 0.0000 0.9185 0.0000 1.0000 0.0000 1.0000
5780.0 0.0000 0.9334 0.0000 1.0000 0.0000 1.0000
5415.0 0.0000 0.9479 0.0000 1.0000 0.0000 1.0000
4980.0 0.0000 0.9674 0.0000 1.0000 0.0000 1.0000
4620.0 0.0000 0.9860 0.0000 1.0000 0.0000 1.0000
4375.0 0.0000 1.0001 0.0000 0.9680 0.0000 0.9676
4225.0 0.0000 1.0159 0.0000 0.5950 0.0000 0.5838
4100.0 0.0000 1.0303 0.0000 0.5505 0.0000 0.5367
3900.0 0.0000 1.0560 0.0000 0.5105 0.0000 0.4955
3700.0 0.0000 1.0857 0.0000 0.4816 0.0000 0.4678
3400.0 0.0000 1.1398 0.0000 0.4439 0.0000 0.4353
3000.0 0.0000 1.2356 0.0000 0.3941 0.0000 0.3979
2600.0 0.0000 1.3711 0.0000 0.3416 0.0000 0.3626
2200.0 0.0000 1.5697 0.0000 0.2859 0.0000 0.3281
1800.0 0.0000 1.8769 0.0000 0.2278 0.0000 0.2936
1400.0 0.0000 2.3917 0.0000 0.1686 0.0000 0.2580
1000.0 0.0000 3.3740 0.0000 0.1107 0.0000 0.2197
700.0 0.0000 4.9100 0.0000 0.0703 0.0000 0.1877
0.0
0.00 280.93 0.0000 0.0007 0.0000 0.0741
PRES
OIL Z-FACTOR
GAS Z-FACTOR
OIL DENSITY
GAS DENSITY
------- --------------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ ------ ------ -----6200.0 0.0000 1.2759 0.0000 0.0000 0.0000 0.5027 0.0000 0.0000
5780.0 0.0000 1.2089 0.0000 0.0000 0.0000 0.4946 0.0000 0.0000
5415.0 0.0000 1.1503 0.0000 0.0000 0.0000 0.4871 0.0000 0.0000
4980.0 0.0000 1.0800 0.0000 0.0000 0.0000 0.4773 0.0000 0.0000
4620.0 0.0000 1.0213 0.0000 0.0000 0.0000 0.4683 0.0000 0.0000
4375.0 0.0000 0.9817 0.0000 0.9684 0.0000 0.4625 0.0000 0.4358
4225.0 0.0000 0.9810 0.0000 0.9368 0.0000 0.4952 0.0000 0.3947
4100.0 0.0000 0.9719 0.0000 0.9192 0.0000 0.5089 0.0000 0.3737
3900.0 0.0000 0.9521 0.0000 0.8963 0.0000 0.5251 0.0000 0.3455
3700.0 0.0000 0.9281 0.0000 0.8780 0.0000 0.5380 0.0000 0.3205
3400.0 0.0000 0.8870 0.0000 0.8567 0.0000 0.5544 0.0000 0.2859
3000.0 0.0000 0.8247 0.0000 0.8377 0.0000 0.5737 0.0000 0.2436
2600.0 0.0000 0.7548 0.0000 0.8277 0.0000 0.5918 0.0000 0.2044
2200.0 0.0000 0.6771 0.0000 0.8258 0.0000 0.6096 0.0000 0.1678
1800.0 0.0000 0.5906 0.0000 0.8322 0.0000 0.6276 0.0000 0.1334
1400.0 0.0000 0.4941 0.0000 0.8474 0.0000 0.6471 0.0000 0.1010
1000.0 0.0000 0.3855 0.0000 0.8721 0.0000 0.6697 0.0000 0.0705
700.0 0.0000 0.2936 0.0000 0.8977 0.0000 0.6909 0.0000 0.0489
0.0 0.0000 0.0086 0.0000 0.9962 0.0000 0.7800 0.0000 0.0011
PRES
OIL VISCOSITY
GAS VISCOSITY
SURF TENS
------- --------------- --------------- ----------PSIG
DATA
CALC
DATA
CALC
DYNE/CM
------- ------ ------ ------ ------ ----------6200.0 0.1060 0.0886 0.0000 0.0000 0.0000E+00
5780.0 0.1020 0.0844 0.0000 0.0000 0.0000E+00
5415.0 0.0980 0.0807 0.0000 0.0000 0.0000E+00
4980.0 0.0950 0.0763 0.0000 0.0000 0.0000E+00
4620.0 0.0930 0.0727 0.0000 0.0000 0.0000E+00
4375.0 0.0910 0.0705 0.0000 0.0612 0.4442E-04
4225.0 0.0990 0.0855 0.0000 0.0507 0.8978E-02
4100.0 0.1010 0.0931 0.0000 0.0465 0.2973E-01
3900.0 0.1050 0.1028 0.0000 0.0418 0.9333E-01
3700.0 0.1090 0.1109 0.0260 0.0381 0.2028E+00
3400.0 0.1140 0.1215 0.0000 0.0336 0.4770E+00
3000.0 0.1250 0.1344 0.0220 0.0288 0.1112E+01
2600.0 0.1370 0.1476 0.0000 0.0248 0.2146E+01
2200.0 0.1530 0.1621 0.0180 0.0215 0.3689E+01
1800.0 0.1720 0.1791 0.0000 0.0188 0.5869E+01
1400.0 0.1990 0.2006 0.0150 0.0168 0.8859E+01
1000.0 0.2310 0.2305 0.0000 0.0152 0.1296E+02
700.0 0.2600 0.2641 0.0140 0.0144 0.1715E+02
0.0 0.8210 0.8003 0.0000 0.0126 0.3715E+02
---------------------------
D-218
Landmark - R2003.4
OIL COMP
-------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
C30
PRESSURE - PSIG
----------------6200. 5780. 5415.
3400. 3000. 2600.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
Example Problems
4980.
2200.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4620.
1800.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4375.
1400.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4225.
1000.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4100.
700.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
3900.
0.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4980.
2200.
-----0.0584
0.0381
0.5043
0.2802
0.0965
0.0806
0.0875
0.0933
0.0589
0.0801
0.0295
0.0475
0.0229
0.0423
0.0464
0.0633
0.0805
0.2287
0.0151
0.0459
4620.
1800.
-----0.0584
0.0331
0.5043
0.2349
0.0965
0.0743
0.0875
0.0917
0.0589
0.0833
0.0295
0.0515
0.0229
0.0471
0.0464
0.0710
0.0805
0.2619
0.0151
0.0513
4375.
1400.
-----0.0584
0.0272
0.5037
0.1862
0.0965
0.0655
0.0875
0.0871
0.0590
0.0851
0.0295
0.0553
0.0229
0.0524
0.0464
0.0802
0.0809
0.3028
0.0152
0.0584
4225.
1000.
-----0.0563
0.0203
0.4765
0.1342
0.0953
0.0531
0.0886
0.0774
0.0615
0.0828
0.0315
0.0579
0.0250
0.0576
0.0462
0.0892
0.0977
0.3589
0.0215
0.0686
4100.
700.
-----0.0551
0.0146
0.4623
0.0936
0.0946
0.0407
0.0892
0.0643
0.0628
0.0752
0.0325
0.0568
0.0260
0.0600
0.0463
0.0930
0.1067
0.4215
0.0243
0.0803
3900.
0.
-----0.0536
0.0003
0.4428
0.0016
0.0937
0.0009
0.0900
0.0018
0.0647
0.0028
0.0339
0.0029
0.0275
0.0044
0.0467
0.0060
0.1193
0.7760
0.0277
0.2033
4980.
2200.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4620.
1800.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4375.
1400.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4225.
1000.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
4100.
700.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
3900.
0.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
3700.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

-------------------------------PRESSURE - PSIG
----------------OIL COMP
6200. 5780. 5415.
3400. 3000. 2600.
-------- ------ ------ -----CO2
0.0584 0.0584 0.0584
0.0497 0.0463 0.0425
C1
0.5043 0.5043 0.5043
0.3982 0.3615 0.3223
C2
0.0965 0.0965 0.0965
0.0911 0.0885 0.0851
C3
0.0875 0.0875 0.0875
0.0916 0.0927 0.0934
NC4
0.0589 0.0589 0.0589
0.0690 0.0726 0.0764
NC5
0.0295 0.0295 0.0295
0.0374 0.0404 0.0438
C6
0.0229 0.0229 0.0229
0.0312 0.0344 0.0381
C8
0.0464 0.0464 0.0464
0.0491 0.0524 0.0571
C14
0.0805 0.0805 0.0805
0.1490 0.1735 0.1998
C30
0.0151 0.0151 0.0151
0.0337 0.0375 0.0414
---------------------------
GAS COMP
-------CO2
C1
C2
C3
NC4
NC5
C6
C8
C14
R2003.4 - Landmark
PRESSURE - PSIG
----------------6200. 5780. 5415.
3400. 3000. 2600.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
3700.
-----0.0520
0.4248
0.0927
0.0907
0.0664
0.0353
0.0290
0.0475
0.1312
0.0304
3700.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
D-219
Example Problems
C30
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

-------------------------------PRESSURE - PSIG
----------------GAS COMP
6200. 5780. 5415. 4980. 4620. 4375. 4225. 4100.
3400. 3000. 2600. 2200. 1800. 1400. 1000.
700.
-------- ------ ------ ------ ------ ------ ------ ------ -----CO2
0.0000 0.0000 0.0000 0.0000 0.0000 0.0597 0.0614 0.0622
0.0651 0.0664 0.0674 0.0683 0.0689 0.0693 0.0691 0.0685
C1
0.0000 0.0000 0.0000 0.0000 0.0000 0.5213 0.5433 0.5529
0.5861 0.5987 0.6078 0.6137 0.6163 0.6149 0.6085 0.5992
C2
0.0000 0.0000 0.0000 0.0000 0.0000 0.0972 0.0982 0.0986
0.1007 0.1018 0.1030 0.1043 0.1057 0.1073 0.1087 0.1094
C3
0.0000 0.0000 0.0000 0.0000 0.0000 0.0868 0.0859 0.0855
0.0843 0.0840 0.0841 0.0847 0.0858 0.0876 0.0904 0.0929
NC4
0.0000 0.0000 0.0000 0.0000 0.0000 0.0573 0.0553 0.0543
0.0511 0.0498 0.0490 0.0486 0.0487 0.0498 0.0522 0.0551
NC5
0.0000 0.0000 0.0000 0.0000 0.0000 0.0283 0.0267 0.0260
0.0234 0.0223 0.0214 0.0207 0.0204 0.0205 0.0215 0.0232
C6
0.0000 0.0000 0.0000 0.0000 0.0000 0.0217 0.0200 0.0193
0.0165 0.0153 0.0143 0.0134 0.0128 0.0127 0.0131 0.0143
C8
0.0000 0.0000 0.0000 0.0000 0.0000 0.0466 0.0467 0.0465
0.0443 0.0424 0.0403 0.0381 0.0362 0.0347 0.0343 0.0356
C14
0.0000 0.0000 0.0000 0.0000 0.0000 0.0702 0.0565 0.0502
0.0278 0.0191 0.0127 0.0082 0.0052 0.0033 0.0022 0.0018
C30
0.0000 0.0000 0.0000 0.0000 0.0000 0.0110 0.0061 0.0043
0.0007 0.0003 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000
-----------------------0 P = 4375.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01
ZY = 0.96835 YY = 0.59694E-01 0.52132E+00 0.97210E-01 0.86790E-01
0.28306E-01 0.21651E-01 0.46600E-01 0.70152E-01
ZX = 0.98169 XX = 0.58357E-01 0.50373E+00 0.96476E-01 0.87524E-01
0.29540E-01 0.22942E-01 0.46389E-01 0.80883E-01
KV = 0.10229E+01 0.10349E+01 0.10076E+01 0.99161E+00
0.95823E+00 0.94372E+00 0.10046E+01 0.86733E+00
0 P = 4225.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01
ZY = 0.93685 YY = 0.61399E-01 0.54329E+00 0.98180E-01 0.85890E-01
0.26746E-01 0.20015E-01 0.46656E-01 0.56461E-01
ZX = 0.98105 XX = 0.56262E-01 0.47651E+00 0.95302E-01 0.88647E-01
0.31463E-01 0.24956E-01 0.46211E-01 0.97695E-01
KV = 0.10913E+01 0.11401E+01 0.10302E+01 0.96890E+00
0.85007E+00 0.80200E+00 0.10096E+01 0.57793E+00
0 P = 4100.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01
ZY = 0.91916 YY = 0.62178E-01 0.55293E+00 0.98650E-01 0.85508E-01
0.26042E-01 0.19276E-01 0.46496E-01 0.50231E-01
ZX = 0.97194 XX = 0.55138E-01 0.46231E+00 0.94644E-01 0.89219E-01
0.32485E-01 0.26029E-01 0.46310E-01 0.10670E+00
KV = 0.11277E+01 0.11960E+01 0.10423E+01 0.95841E+00
0.80167E+00 0.74054E+00 0.10040E+01 0.47078E+00
0 P = 3900.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01
ZY = 0.89634 YY = 0.63161E-01 0.56465E+00 0.99276E-01 0.85059E-01
0.25160E-01 0.18346E-01 0.46057E-01 0.42441E-01
ZX = 0.95206 XX = 0.53552E-01 0.44284E+00 0.93673E-01 0.89986E-01
0.33919E-01 0.27538E-01 0.46741E-01 0.11933E+00
KV = 0.11794E+01 0.12751E+01 0.10598E+01 0.94524E+00
0.74176E+00 0.66621E+00 0.98538E+00 0.35567E+00
0 P = 3700.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01
ZY = 0.87798 YY = 0.63997E-01 0.57418E+00 0.99845E-01 0.84709E-01
0.24412E-01 0.17555E-01 0.45448E-01 0.35960E-01
ZX = 0.92813 XX = 0.52032E-01 0.42480E+00 0.92695E-01 0.90675E-01
0.35289E-01 0.28981E-01 0.47474E-01 0.13125E+00
KV = 0.12300E+01 0.13517E+01 0.10771E+01 0.93421E+00
0.69176E+00 0.60575E+00 0.95733E+00 0.27399E+00
0 P = 3400.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01
ZY = 0.85671 YY = 0.65101E-01 0.58610E+00 0.10067E+00 0.84315E-01
0.23423E-01 0.16505E-01 0.44283E-01 0.27758E-01
ZX = 0.88702 XX = 0.49706E-01 0.39818E+00 0.91095E-01 0.91632E-01
0.37384E-01 0.31197E-01 0.49137E-01 0.14900E+00
KV = 0.13097E+01 0.14719E+01 0.11051E+01 0.92015E+00
D-220
3900.
0.
-----0.0632
0.0631
0.5647
0.5445
0.0993
0.1042
0.0851
0.0944
0.0532
0.0634
0.0252
0.0316
0.0183
0.0244
0.0461
0.0496
0.0424
0.0249
0.0026
0.0000
3700.
-----0.0640
0.5742
0.0998
0.0847
0.0523
0.0244
0.0176
0.0454
0.0360
0.0016
0.58900E-01
0.15069E-01
0.57314E-01
0.10964E-01
0.58953E-01
0.15207E-01
0.97220E+00
0.72102E+00
0.58900E-01
0.15069E-01
0.55260E-01
0.61040E-02
0.61495E-01
0.21459E-01
0.89861E+00
0.28445E+00
0.58900E-01
0.15069E-01
0.54350E-01
0.43383E-02
0.62829E-01
0.24334E-01
0.86505E+00
0.17828E+00
0.58900E-01
0.15069E-01
0.53228E-01
0.26203E-02
0.64676E-01
0.27746E-01
0.82300E+00
0.94440E-01
0.58900E-01
0.15069E-01
0.52299E-01
0.15939E-02
0.66410E-01
0.30399E-01
0.78751E+00
0.52434E-01
0.58900E-01
0.15069E-01
0.51111E-01
0.74180E-03
0.69005E-01
0.33656E-01
0.74069E+00
Landmark - R2003.4
0 P =
ZY =
ZX =
0 P =
ZY =
ZX =
0 P =
ZY =
ZX =
0 P =
ZY =
ZX =
0 P =
ZY =
ZX =
0 P =
ZY =
ZX =
0 P =
ZY =
ZX =
0 P =
ZY =
ZX =
R2003.4 - Landmark
0.62655E+00
3000.0 ZZ = 0.58400E-01
0.29500E-01
0.83772 YY = 0.66370E-01
0.22293E-01
0.82474 XX = 0.46337E-01
0.40408E-01
KV = 0.14323E+01
0.55168E+00
2600.0 ZZ = 0.58400E-01
0.29500E-01
0.82766 YY = 0.67434E-01
0.21376E-01
0.75484 XX = 0.42519E-01
0.43780E-01
KV = 0.15860E+01
0.48826E+00
2200.0 ZZ = 0.58400E-01
0.29500E-01
0.82577 YY = 0.68297E-01
0.20706E-01
0.67708 XX = 0.38134E-01
0.47507E-01
KV = 0.17910E+01
0.43586E+00
1800.0 ZZ = 0.58400E-01
0.29500E-01
0.83218 YY = 0.68933E-01
0.20361E-01
0.59061 XX = 0.33058E-01
0.51488E-01
KV = 0.20852E+01
0.39546E+00
1400.0 ZZ = 0.58400E-01
0.29500E-01
0.84737 YY = 0.69263E-01
0.20512E-01
0.49413 XX = 0.27159E-01
0.55348E-01
KV = 0.25502E+01
0.37061E+00
1000.0 ZZ = 0.58400E-01
0.29500E-01
0.87207 YY = 0.69117E-01
0.21506E-01
0.38550 XX = 0.20333E-01
0.57895E-01
KV = 0.33992E+01
0.37147E+00
700.0 ZZ = 0.58400E-01
0.29500E-01
0.89770 YY = 0.68521E-01
0.23189E-01
0.29363 XX = 0.14603E-01
0.56812E-01
KV = 0.46923E+01
0.40817E+00
0.0 ZZ = 0.58400E-01
0.29500E-01
0.99620 YY = 0.63053E-01
0.31627E-01
0.00863 XX = 0.27662E-03
0.29244E-02
KV = 0.22794E+03
0.10815E+02
Example Problems
0.52905E+00
0.50430E+00
0.22900E-01
0.59865E+00
0.15284E-01
0.36150E+00
0.34427E-01
0.16560E+01
0.44396E+00
0.50430E+00
0.22900E-01
0.60782E+00
0.14253E-01
0.32233E+00
0.38100E-01
0.18857E+01
0.37410E+00
0.50430E+00
0.22900E-01
0.61373E+00
0.13425E-01
0.28021E+00
0.42302E-01
0.21903E+01
0.31736E+00
0.50430E+00
0.22900E-01
0.61628E+00
0.12849E-01
0.23487E+00
0.47082E-01
0.26240E+01
0.27292E+00
0.50430E+00
0.22900E-01
0.61492E+00
0.12654E-01
0.18617E+00
0.52367E-01
0.33031E+01
0.24165E+00
0.50430E+00
0.22900E-01
0.60849E+00
0.13131E-01
0.13423E+00
0.57598E-01
0.45333E+01
0.22798E+00
0.50430E+00
0.22900E-01
0.59920E+00
0.14324E-01
0.93613E-01
0.60014E-01
0.64008E+01
0.23867E+00
0.50430E+00
0.22900E-01
0.54454E+00
0.24382E-01
0.16170E-02
0.43890E-02
0.33676E+03
0.55553E+01
0.90123E+00
0.96500E-01
0.46396E-01
0.10178E+00
0.42396E-01
0.88514E-01
0.52450E-01
0.11498E+01
0.80831E+00
0.96500E-01
0.46396E-01
0.10297E+00
0.40295E-01
0.85132E-01
0.57120E-01
0.12095E+01
0.70545E+00
0.96500E-01
0.46396E-01
0.10428E+00
0.38146E-01
0.80565E-01
0.63291E-01
0.12944E+01
0.60271E+00
0.96500E-01
0.46396E-01
0.10574E+00
0.36150E-01
0.74268E-01
0.71048E-01
0.14238E+01
0.50882E+00
0.96500E-01
0.46396E-01
0.10729E+00
0.34659E-01
0.65461E-01
0.80151E-01
0.16390E+01
0.43242E+00
0.96500E-01
0.46396E-01
0.10872E+00
0.34338E-01
0.53087E-01
0.89226E-01
0.20480E+01
0.38484E+00
0.96500E-01
0.46396E-01
0.10938E+00
0.35638E-01
0.40741E-01
0.92953E-01
0.26849E+01
0.38340E+00
0.96500E-01
0.46396E-01
0.10415E+00
0.49629E-01
0.91596E-03
0.60019E-02
0.11371E+03
0.82690E+01
0.18629E+00
0.87500E-01
0.80535E-01
0.84040E-01
0.19091E-01
0.92737E-01
0.17353E+00
0.90622E+00
0.11002E+00
0.87500E-01
0.80535E-01
0.84121E-01
0.12688E-01
0.93440E-01
0.19980E+00
0.90026E+00
0.63503E-01
0.87500E-01
0.80535E-01
0.84655E-01
0.81791E-02
0.93325E-01
0.22870E+00
0.90710E+00
0.35763E-01
0.87500E-01
0.80535E-01
0.85772E-01
0.51628E-02
0.91657E-01
0.26188E+00
0.93580E+00
0.19714E-01
0.87500E-01
0.80535E-01
0.87633E-01
0.32634E-02
0.87117E-01
0.30277E+00
0.10059E+01
0.10779E-01
0.87500E-01
0.80535E-01
0.90354E-01
0.21680E-02
0.77362E-01
0.35889E+00
0.11679E+01
0.60410E-02
0.87500E-01
0.80535E-01
0.92858E-01
0.17548E-02
0.64314E-01
0.42146E+00
0.14438E+01
0.41635E-02
0.87500E-01
0.80535E-01
0.94360E-01
0.24868E-01
0.18038E-02
0.77595E+00
0.52312E+02
0.32049E-01
0.22041E-01
0.58900E-01
0.15069E-01
0.49845E-01
0.25353E-03
0.72604E-01
0.37492E-01
0.68654E+00
0.67623E-02
0.58900E-01
0.15069E-01
0.48967E-01
0.81257E-04
0.76361E-01
0.41415E-01
0.64125E+00
0.19620E-02
0.58900E-01
0.15069E-01
0.48551E-01
0.24376E-04
0.80093E-01
0.45877E-01
0.60618E+00
0.53134E-03
0.58900E-01
0.15069E-01
0.48741E-01
0.68466E-05
0.83343E-01
0.51309E-01
0.58482E+00
0.13344E-03
0.58900E-01
0.15069E-01
0.49804E-01
0.18258E-05
0.85060E-01
0.58402E-01
0.58552E+00
0.31262E-04
0.58900E-01
0.15069E-01
0.52173E-01
0.48206E-06
0.82794E-01
0.68591E-01
0.63015E+00
0.70280E-05
0.58900E-01
0.15069E-01
0.55131E-01
0.18709E-06
0.75210E-01
0.80280E-01
0.73302E+00
0.23304E-05
0.58900E-01
0.15069E-01
0.63390E-01
0.53901E-06
0.28099E-02
0.20331E+00
0.22559E+02
0.26511E-05
D-221
Example Problems
D.2 Example 2
The following example demonstrates the use of DESKTOP-PVT to
calculate equation-of-state parameters to match surface separation
measurements. Included is a standard laboratory report for a gas
condensate sample; with a constant composition expansion test, a constant
volume depletion test, and separation tests for each gas sample from the
constant volume depletion test.
The DESKTOP-PVT listing, which follows the laboratory report, shows the
final step in the fluid analysis process. In this step, a set of separator
equation-of-state parameters, a and b, are calculated, distinct from the
reservoir parameters. The reservoir parameters have been calculated by
regression in a previous run and are used as the starting values for this
run. The data that is matched in this run is derived from page 5 of the
laboratory report.
D.2.1 Lab Report

GOOD OIL COMPANY
Condensate No. 7 Well
Productive Field
Samson County, Texas
RFL 82000
Good Oil Company
P.O. Box 100
Oil City, TX
Attention: Mr. John Jones
Subject:

Product Field
Samson County, Texas
RFL 82000
Gentlemen:
D-222
Landmark - R2003.4
Example Problems
Samples of separator liquid and vapor were collected rom the subject well by a representative of Core
Laboratories, Inc. on March 23, 1982. The samples represent production from the Pay Sand and they
were collected for use in a reservoir fluid study. Presented in the following report are the results of this
study as requested by Good Oil Company.
Using the factors shown on page one, the producing gas/luiquid ratio was claculated to be 4697 cubic
feet of separator gas at 14.65 psia and 60 F. per barrel of stock tank liquid at 60F. The separator liquid
shrinkage factor was determined experimentally in the laboratory and the producing ratio was found to
be equivalent to 3944 standard cubic feet of separator gas per barrel of separator liquid at 440 psig and
60F. The separator products were then physically recombined in this gas/liquid ratio and the resulting
fluid was used for teh entire study. The measured hydrocarbon compositions of the separator products
were used in conjunction with the producing gas/liquid ratio to calculate the hydrocarbon composition
of the well stream material. All of the aforementioned compositional data may be found on page two.
A small quantity of the reservoir fluid was then charged to a high pressure visual cell and thermally
expanded to the reported reservoir temperature of 256F. During a constant composition expansion at
this temperature, the fluid exhibited a retrograde dew point at 6010 psig. The results of the pressurevolume measurements at 256F may be found on page three, along with the deviation factor
measurements at the dew point pressure and above.
A large smaple of the reservoir fluid was then charged to a high pressure visual cell at 256F and the
volume at the dew point was determined. A simulated constant volume depletion was then performed
by making a series of expansions and constant pressure displacements, with each displacement
terminating at the original saturated volume. The well stream displaced at each displacement level was
charged to low temperature fractional distillation equipment for volume measurement and
compositional analysis. The results of the constant volume depletion at the reservoir temperature may
be found on page four.
The smooth well stream compositons were then used with published equilibrium ratios to calculate the
comulative and instantaneous surface recoveries tha may be expected during pressure depletion of teh
reseroivr. The cumulative recovery calculatiosn were based upon one MMSCF of oroginal fluid and
they are presented on page five. A summary of the instantaneous surface recovery calculatiosn is given
on page six.
Good Oil Company
Page Two
Visual measurements of the retrograde condensate were performed at several points during the constant
composition expansion and at each point during the constant voluem depletion at the reservoir
temperature. The maximum observed volume of retrograde condensate was 25.0 percent of the
hydrocarbon pore space. A tabulation of the retrograde liquid measurements may be found on page
seven; a graphical interpretation of these data is given on page twelve.
R2003.4 - Landmark
D-223
Example Problems
Thank you for the opportunity to be of service to Good Oil Company. Shoudl you have any quetion or if
we may be of further assistanc ein any manner, please feel free to call upon us.
Very truly yours,
CORE LABORATORIES, INC.
Manager
D-224
Landmark - R2003.4
R2003.4 - Landmark
Example Problems
D-225
Example Problems
D-226
Landmark - R2003.4
R2003.4 - Landmark
Example Problems
D-227
Example Problems
D-228
Landmark - R2003.4
R2003.4 - Landmark
Example Problems
D-229
Example Problems
D-230
Landmark - R2003.4
R2003.4 - Landmark
Example Problems
D-231
Example Problems
D-232
Landmark - R2003.4
R2003.4 - Landmark
Example Problems
D-233
Example Problems
D-234
Landmark - R2003.4
R2003.4 - Landmark
Example Problems
D-235
Example Problems
D-236
Landmark - R2003.4
Example Problems
D.2.2 Sample File

1
*******************************************************************************
*
*
*
DDDDDD
EEEEEEE
SSSSS
KK
KK TTTTTTTT OOOOO
PPPPPP
*
*
DD
DD EE
SS
SS KK KK
TT
OO
OO PP
PP
*
*
DD
DD EE
SS
KK KK
TT
OO
OO PP
PP
*
*
DD
DD EEEEE
SSSSS
KKKK
TT
OO
OO PPPPPP
*
*
DD
DD EE
SS KK KK
TT
OO
OO PP
*
*
DD
DD EE
SS
SS KK KK
TT
OO
OO PP
*
*
DDDDDD
EEEEEEE
SSSSS
KK
KK
TT
OOOOO
PP
*
*
*
*
PPPPPP
VV
VV TTTTTTTT
*
*
PP
PP
V
V
TT
*
*
PP
PP
VV VV
TT
*
*
PPPPPP
V V
TT
*
*
PP
VVVV
TT
*
*
PP
VV
TT
*
*
PP
VV
TT
*
*
*
*
*
*
*
*
COPYRIGHT 1984, 1985, 1986, 1987, 1988
*
*
1989, 1990, 1991, 1992, 1993
*
*
1994, 1995, 1996, 1997, 1998
*
*
*
*
ALL RIGHTS RESERVED
*
*
*
*
VERSION 1998.0.0
CREATED 01 MAR 1998
*
*
*
*
LL
AAAAA
N
NN DDDDDD
M
M AAAAA
RRRRRR
KK
KK
*
*
LL
AA
AA NN
NN DD
DD MM
MM AA
AA RR
RR KK KK
*
*
LL
AA
AA NNN NN DD
DD M M M M AA
AA RR
RR KK KK
*
*
LL
AAAAAAA NN N NN DD
KKKK
*
*
LL
AA
AA NN NNN DD
DD M
M AA
AA RR RR
KK KK
*
*
LL
AA
AA NN
NN DD
DD M
M AA
AA RR RR
KK KK
*
*
LLLLLLL AA
AA NN
N DDDDDD
M
M AA
AA RR
RR KK
KK
*
*
*
*
GGGGG
RRRRRR
AAAAA
PPPPPP
HH
HH
IIII
CCCCC
SSSSS
*
*
GG
GG RR
RR AA
AA PP
PP HH
HH
II
CC
CC SS
SS
*
*
GG
RR
RR AA
AA PP
PP HH
HH
II
CC
SS
*
*
GG
RRRRRR
AAAAAAA PPPPPP
HHHHHHH
II
CC
SSSSS
*
*
GG GGG RR RR
AA
AA PP
HH
HH
II
CC
SS
*
*
GG
GG RR RR
AA
AA PP
HH
HH
II
CC
CC SS
SS
*
*
GGGGG
RR
RR AA
AA PP
HH
HH
IIII
CCCCC
SSSSS
*
*
*
******************************************************************************
1
*********************************************
*
*
*
*
*
*
*
*
*
*
*
VERSION 1998.0.0
*
*
*
*
COPYRIGHT 1984, 1985, 1986, 1987, 1988
*
*
1989, 1990, 1991, 1992, 1993
*
*
1994, 1995, 1996, 1997, 1998
*
*
*
*
ALL RIGHTS RESERVED
*
*
*
*********************************************
SEQUENCE
NUMBER
-------- --------------------------------------------------------------------X
X
X
X
X
X
X
X
X
X
R2003.4 - Landmark
C
C
C
C
C
C
C
C
C
C
------------------------EOSPAK EXAMPLE PROBLEM #2

GAS CONDENSATE EXAMPLE
------------------------------------------------MATCH SEPARATOR DATA ONLY
WITH NEW OMEGAA, OMEGAB
-------------------------
D-237
Example Problems
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
D-238
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
R
X
R
R
R
R
R
R
R
R
R
R
R
R
R
X
R
R
X
R
R
R
R
R
R
R
X
R
X
X
X
X
X
X
C
C
C ------------------------C REGRESSION VARIABLES ARE:
C
(1) OMEGA
C1
C
(2) OMEGB
C1
C
(3) OMEGA
C2
C
(4) OMEGB
C2
C
(5) OMEGA
C8
C
(6) OMEGB
C8
C
(7) OMEGA
C14
C
(8) OMEGB
C14
C
(9) OMEGB
C20
C (10) OMEGB
C20
C (11) OMEGB
C34
C (12) OMEGB
C34
C ------------------------C
REGRESS
C
VARIABLE MIN
INIT
MAX
1
.5
1.0
1.5
2
.5
1.0
1.5
3
.5
1.0
1.5
4
.5
1.0
1.5
5
.5
1.0
1.5
6
.5
1.0
1.5
7
.5
1.0
1.5
8
.5
1.0
1.5
9
.5
1.0
1.5
10
.5
1.0
1.5
11
.5
1.0
1.5
12
.5
1.0
1.5
C
IMAX
IPRINT H
TOL1
TOL2
TOL3
10
0
X
X
X
X
C
COMP
MW
TC
PC
ZC
ACENTRIC
OMEGAA
OMEGAB
C1
X
X
X
X
X
1
2
C2
X
X
X
X
X
3
4
C8
X
X
X
X
X
5
6
C14
X
X
X
X
X
7
8
C20
X
X
X
X
X
9
10
C34
X
X
X
X
X
11
12
C
ENDREG
C
C
C ---------------------------------------C INITIALIZE AFTER SPLIT OF HEAVY FRACTION
C ---------------------------------------C
EOS PR
COMPONENTS
N2 C1 C2 C3 NC4 NC5 C6 C8 C14 C20 C34
PROPERTIES
COMP
MW
TC
PC
ZC
ACENTRIC
OMEGAA
OMEGAB
N2
28.01 -232.40 493.00 0.2910 0.0372 0.4572355 0.0777961
35.0
C1
16.04 -116.60 667.80 0.2890 0.0126 0.4572355 0.0777961
71.0
C2
30.07
90.10 707.80 0.2850 0.0978 0.4572355 0.0777961 111.0
C3
44.10
206.00 616.30 0.2810 0.1541 0.4572355 0.0777961 151.0
NC4
58.12
305.70 550.70 0.2740 0.2015 0.4572355 0.0777961 191.0
NC5
72.15
385.70 488.60 0.2620 0.2524 0.4572355 0.0777961 231.0
C6
84.00
463.00 468.30 0.2698 0.2313 0.4572355 0.0777961 271.0
C8
109.30
602.85 415.02 0.2618 0.3227 0.4047023 0.0816778 351.0
C14
183.86
807.42 282.76 0.2350 0.4996 0.4554216 0.0759684 591.9
C20
279.75 1000.71 207.54 0.2156 0.7045 0.4356328 0.0799298 833.7
C34
438.36 1238.40 150.02 0.1979 1.0493 0.4635509 0.0735474 1397.9
DJK C1
N2
0.1200000
DJK C2
N2
0.1200000
C1
0.0000000
DJK C3
N2
0.1200000
C1
0.0000000
C2
0.0000000
DJK NC4
N2
0.1200000
C1
0.0200000
C2
0.0100000
Landmark - R2003.4
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
DJK
DJK
DJK
DJK
DJK
DJK
X
82
X
X
X
X
X
X
X
X
83
84
85
86
87
88
89
90
91
92
X
X
X
X
X
X
X
X
X
R2003.4 - Landmark
Example Problems
C3
NC5
N2
C1
C2
C3
NC4
C6
N2
C1
C2
C3
NC4
NC5
C8
N2
C1
C2
C3
NC4
NC5
C6
C14
N2
C1
C2
C3
NC4
NC5
C6
C8
C20
N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C34
N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
0.0100000
0.1200000
0.0200000
0.0100000
0.0100000
0.0000000
0.1200000
0.0298000
0.0100000
0.0100000
0.0000000
0.0000000
0.1200000
0.1346893
0.0100000
0.0100000
0.0000000
0.0000000
0.0000000
0.1200000
0.0357530
0.0100000
0.0100000
0.0000000
0.0000000
0.0000000
0.0000000
0.1200000
0.0164643
0.0100000
0.0100000
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
0.1200000
0.0848269
0.0100000
0.0100000
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
C
ENDEOS
C
PVTFILE
C
C
C ------------------------C CONSTANT VOLUME DEPLETION
C ------------------------C
CVDEP
COMPOSITION 0.0011
0.6893
0.0864
0.0534
0.0348 0.0178
0.064447 0.020473 0.010029 0.004951
TEMP 256
F
DEWPT 6010 PSIG
PRES
6010
5000
4000
3000
2100
1200
MW C8 C34
X
X
X
X
X
X
ZGAS
X
X
X
X
X
X
VPROD
X
X
X
X
X
X
SLIQ
X
X
X
X
X
X
C
C
C ------------------------------C SEPARATOR TESTS
C FLASH EACH CVDEP GAS TO SURFACE
C ------------------------------C
C ------------------------C ORIGINAL GAS AT PSAT=6010
0.0173
700
X
X
X
X
D-239
Example Problems
X
X
93
94
95
96
97
98
99
100
101
102
103
104
X
X
X
X
X
105
106
107
108
109
110
111
112
113
114
115
116
X
X
X
X
X
117
118
119
120
121
122
123
124
125
126
127
128
X
X
X
X
X
129
130
131
132
133
134
135
136
137
138
139
140
X
X
X
X
X
141
142
143
144
145
146
147
148
149
150
151
D-240
C ------------------------C
SEP
CVDEPY 1
TEMP
256
F
DEWPT 6010 PSIG
TSTD
75.
PSTD
0.
API
49.3
GORT
4699.7
PRES
TEMP
GORSP
GORST
450.
75.
X
4276.1
100.
75.
X
212.0
0.
75.
X
211.6
C
C ---------------------------C GAS FROM 5000. PSIG IN CVDEP
C ---------------------------C
SEP
CVDEPY 2
TEMP
256
F
DEWPT 5000 PSIG
TSTD
75.
PSTD
0.
API
51.7
GORT
5727.2
PRES
TEMP
GORSP
GORST
450.
75.
X
5277.0
100.
75.
X
223.0
0.
75.
X
227.2
C
C ---------------------------C
SEP
CVDEPY 3
TEMP
256
F
DEWPT 4000 PSIG
TSTD
75.
PSTD
0.
API
55.4
GORT
8399
PRES
TEMP
GORSP
GORST
450.
75.
X
7828.0
100.
75.
X
248.0
0.
75.
X
263.0
C
C ---------------------------C
SEP
CVDEPY 4
TEMP
256
F
DEWPT 3000 PSIG
TSTD
75.
PSTD
0.
API
60.4
GORT
14396.6
PRES
TEMP
GORSP
GORST
450.
75.
X
13774.0
100.
75.
X
289.6
0.
75.
X
333.0
C
C ---------------------------C
SEP
CVDEPY 5
TEMP
256
F
DEWPT 2100 PSIG
TSTD
75.
PSTD
0.
API
64.6
GORT
20564.2
PRES
TEMP
GORSP
GORST
450.
75.
X
19863.0
100.
75.
X
304.8
SVF
X
X
X
GRVG
X
X
X
SVF
X
X
X
GRVG
X
X
X
SVF
X
X
X
GRVG
X
X
X
SVF
X
X
X
GRVG
X
X
X
SVF
X
X
GRVG
X
X
Landmark - R2003.4
Example Problems
152
0.
75.
X
396.4
C
C ---------------------------C
153
SEP
154
CVDEPY 6
155
TEMP
256
F
156
DEWPT 1200 PSIG
157
TSTD
75.
158
PSTD
0.
159
API
67.5
160
GORT
22972.4
161
PRES
TEMP
GORSP
GORST
162
450.
75.
X
22121.0
163
100.
75.
X
369.8
164
0.
75.
X
481.6
X
C
X
C ---------------------------X
C GAS FROM 700. PSIG IN CVDEP
X
C ---------------------------X
C
165
SEP
166
CVDEPY 7
167
TEMP
256
F
168
DEWPT 700 PSIG
169
TSTD
75.
170
PSTD
0.
171
API
68.6
172
GORT
20400.
173
PRES
TEMP
GORSP
GORST
174
450.
75.
X
19475.0
175
100.
75.
X
366.8
176
0.
75.
X
558.2
X
C
177
END
-------------------------
X
X
X
X
X
SVF
X
X
X
GRVG
X
X
X
SVF
X
X
X
GRVG
X
X
X
CONTROL VARIABLES
----------------IMAX
---10
IPRINT
-----0
H
------0.2000
TOL1
------0.0010
TOL2
------0.0010
TOL3
------0.0100

----------------------------------------VARIABLE
-------1
2
3
4
5
6
7
8
9
10
11
12
MINIMUM
------0.5000
0.5000
0.5000
0.5000
0.5000
0.5000
0.5000
0.5000
0.5000
0.5000
0.5000
0.5000
INITIAL
------1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
MAXIMUM
------1.5000
1.5000
1.5000
1.5000
1.5000
1.5000
1.5000
1.5000
1.5000
1.5000
1.5000
1.5000

------------------------------COMPONENT
NO. NAME
--- -----1
N2
2
C1
3
C2
4
C3
R2003.4 - Landmark
MW
---0
0
0
0
TC
---0
0
0
0
PC
---0
0
0
0
ZC
---0
0
0
0
ACENTRIC
FACTOR
-------0
0
0
0
OMEGA
A
----0
1
3
0
OMEGA
B
----0
2
4
0
PCHOR
----0
0
0
0
VSHFT
-----0
0
0
0
D-241
Example Problems
5
6
7
8
9
10
11
NC4
NC5
C6
C8
C14
C20
C34
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
7
9
11
0
0
0
6
8
10
12
0
0
0
0
0
0
0
0
0
0
0
0
0
0
THERE ARE NO REGRESSION VARIABLES CORRESPONDING TO

BINARY INTERACTION COEFFICIENTS.

D
E
0
0

K-COEFFICIENT
REGRESSION VARIABLE
------------------------------k(1)
0
k(2)
0
k(3)
0
k(4)
0
k(5)
0
k(6)
0
k(7)
0
-----------------------------------------------------------------1
1
2
0
3
0 0
4
0 0 0
5
0 0 0 0
6
0 0 0 0
7
0 0 0 0
8
0 0 0 0
9
0 0 0 0
10
0 0 0 0
11
0 0 0 0
1EQUATION OF STATE:
9 10 11
0
0 0
0 0 0
0 0 0 0
0 0 0 0 0
0 0 0 0 0
PENG-ROBINSON
-------------------COMPONENT
MOLE
TC
PC
CRITICAL ACENTRIC
OMEGA
OMEGA
PCHOR
NO. NAME WEIGHT
DEG F
PSIA
Z-FACTOR FACTOR
A
B
-- ------ ------- -------- -------- -------- -------- -------- -------- ------1 N2
28.01 -232.40
493.00
0.2910 0.03720 0.45724 0.07780
35.0
2 C1
16.04 -116.60
667.80
0.2890 0.01260 0.45724 0.07780
71.0
3 C2
30.07
90.10
707.80
0.2850 0.09780 0.45724 0.07780
111.0
4 C3
44.10
206.00
616.30
0.2810 0.15410 0.45724 0.07780
151.0
5 NC4
58.12
305.70
550.70
0.2740 0.20150 0.45724 0.07780
191.0
6 NC5
72.15
385.70
488.60
0.2620 0.25240 0.45724 0.07780
231.0
7 C6
84.00
463.00
468.30
0.2698 0.23130 0.45724 0.07780
271.0
8 C8
109.30
602.85
415.02
0.2618 0.32270 0.40470 0.08168
351.0
9 C14
183.86
807.42
282.76
0.2350 0.49960 0.45542 0.07597
591.9
10 C20
279.75 1000.71
207.54
0.2156 0.70450 0.43563 0.07993
833.7
11 C34
438.36 1238.40
150.02
0.1979 1.04930 0.46355 0.07355 1397.9
11

------------------------------1
11
1
2
D-242
10
0.1200
Landmark - R2003.4
3
4
5
6
7
8
9
10
11
0.1200
0.1200
0.1200
0.1200
0.1200
0.1200
0.1200
0.1200
0.1200
Example Problems
0.0000
0.0000
0.0200
0.0200
0.0298
0.1347
0.0358
0.0165
0.0848
0.0000
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000

---------------------------------------------------------NO.
----k(1)
k(2)
k(3)
k(4)
k(5)
k(6)
k(7)
K-COEFFICIENT
--------------0.9746020E+01
0.1808340E+02
0.4126660E+04
0.4460550E+02
0.9765440E+00
0.8181340E+02
0.1564990E+05

--------------------------------------1
11
1
2
3
4
5
6
7
8
9
10
11
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
10
0.0000
0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000

A = A0 + A1*T + A2*T**2 + A3*T**3 + A4*T**4
B = B0 + B1*T + B2*T**2 + B3*T**3 + B4*T**4
C = A0 + C1*T + C2*T**2 + C3*T**3 + C4*T**4
where Rsw
P
T
S
in
in
in
in
A0
1.1630599
B0
0.9650900
C0
1.2803000
S0
-0.0280370
scf/stb
psia
degree F
A1
-16.6303997
B1
-0.2725500
C1
-10.7566004
S1
-0.1203900
A2
111.0730515
B2
0.0923400
C2
52.6962204
A3
-376.8592529
B3
-0.1008300
C3
-222.3948822
A4
524.8891602
B4
0.0997900
C4
462.6725464

D1 =
5.80000

------------------------------------H* = A + B*T + C*(T**2) + D*(T**3) + E*(T**4) + F*(T**5)
WHERE THE UNITS ARE
H* - BTU / LB-MOLE
T
- DEGREES RANKIN
COMPONENT
R2003.4 - Landmark
D-243
Example Problems
NO
-1
2
3
4
5
6
7
8
9
10
11
NAME
-----N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
A
B
C
D
---------- ---------- ---------- ----------0.262E+02 0.715E+01 -0.498E-03 0.445E-06
-0.112E+03 0.917E+01 -0.472E-02 0.679E-05
-0.631E+00 0.796E+01 -0.752E-03 0.879E-05
-0.325E+02 0.761E+01 0.415E-02 0.951E-05
0.432E+03 0.573E+01 0.156E-01 0.301E-05
0.196E+04 -0.202E+00 0.318E-01 -0.623E-05
0.000E+00 0.242E+01 0.343E-01 -0.477E-05
0.000E+00 0.252E+01 0.436E-01 -0.568E-05
0.000E+00 0.278E+01 0.725E-01 -0.949E-05
0.000E+00 0.827E+02 0.166E+00 -0.285E-04
0.000E+00 0.109E+03 0.228E+00 -0.367E-04
E
F
---------- ----------0.902E-10 0.445E-14
-0.245E-08 0.312E-12
-0.387E-08 0.548E-12
-0.472E-08 0.702E-12
-0.244E-08 0.381E-12
0.590E-09 -0.142E-13
0.000E+00 0.000E+00
0.000E+00 0.000E+00
0.000E+00 0.000E+00
0.000E+00 0.000E+00
0.000E+00 0.000E+00
-------------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
22
MOLE FRACTION
------------0.00110
0.68930
0.08640
0.05340
0.03480
0.01780
0.01730
0.06445
0.02047
0.01003
0.00495
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
256.00 DEGREES F
OBSERVED PSAT
CALCULATED PSAT
OIL DENSITY AT PSAT
GAS DENSITY AT PSAT
= 6010.00 PSIG
= 6010.24 PSIG
= 0.0000
= 1.1358
= 0.5479 GM/CC
= 0.4046 GM/CC
(DEWPT)
(DEWPT)
PRES MW(C8
-C34 )
CUM GAS PROD
LIQ VOL FRAC
LIQ MOLE FRAC
------- --------------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ ------ ------ -----6010.0
0.00 158.00 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
5000.0
0.00 146.47 0.0000 0.0767 0.0000 0.1162 0.0000 0.0861
4000.0
0.00 134.08 0.0000 0.1837 0.0000 0.2365 0.0000 0.1696
3000.0
0.00 121.63 0.0000 0.3339 0.0000 0.2833 0.0000 0.1840
2100.0
0.00 114.72 0.0000 0.4998 0.0000 0.2716 0.0000 0.1556
1200.0
0.00 111.46 0.0000 0.6836 0.0000 0.2424 0.0000 0.1185
700.0
0.00 110.61 0.0000 0.7882 0.0000 0.2207 0.0000 0.0963
PRES
OIL Z-FACTOR
GAS Z-FACTOR
OIL DENSITY
------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ -----6010.0 0.0000 1.4430 0.0000 1.1357 0.0000 0.5479
5000.0 0.0000 1.2753 0.0000 0.9979 0.0000 0.5470
4000.0 0.0000 1.0554 0.0000 0.8935 0.0000 0.5314
3000.0 0.0000 0.8751 0.0000 0.8448 0.0000 0.5451
2100.0 0.0000 0.6958 0.0000 0.8426 0.0000 0.5721
1200.0 0.0000 0.4684 0.0000 0.8766 0.0000 0.6054
700.0 0.0000 0.3087 0.0000 0.9095 0.0000 0.6269
PRES
OIL VISCOSITY
GAS VISCOSITY
SURF TENS
------- --------------- --------------- ----------PSIG
DATA
CALC
DATA
CALC
DYNE/CM
------- ------ ------ ------ ------ ----------6010.0 0.0000 0.1062 0.0000 0.0562 0.2480E-01
5000.0 0.0000 0.1037 0.0000 0.0453 0.9043E-01
D-244
Landmark - R2003.4
4000.0 0.0000 0.0945 0.0000

3000.0 0.0000 0.0994 0.0000
2100.0 0.0000 0.1122 0.0000
1200.0 0.0000 0.1308 0.0000
700.0 0.0000 0.1437 0.0000
---------------------------
Example Problems
OIL COMP
-------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
PRESSURE - PSIG
--------------6010. 5000. 4000.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0341
0.0244
0.0184
0.0148
0.0136
0.2844E+00
0.1195E+01
0.3412E+01
0.7802E+01
0.1147E+02
3000.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
2100.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1200.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
700.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
3000.
-----0.0005
0.4316
0.0811
0.0624
0.0518
0.0315
0.0357
0.1545
0.0807
0.0441
0.0261
2100.
-----0.0004
0.3288
0.0744
0.0640
0.0585
0.0383
0.0453
0.2002
0.1042
0.0551
0.0308
1200.
-----0.0002
0.2008
0.0582
0.0589
0.0625
0.0454
0.0574
0.2632
0.1400
0.0730
0.0405
700.
-----0.0001
0.1191
0.0416
0.0484
0.0590
0.0476
0.0642
0.3077
0.1725
0.0898
0.0498
3000.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
2100.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1200.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
700.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
3000.
-----0.0012
0.7560
0.0878
0.0510
0.0303
0.0142
0.0124
0.0409
0.0049
0.0013
0.0000
2100.
-----0.0013
0.7692
0.0895
0.0512
0.0295
0.0131
0.0108
0.0332
0.0019
0.0003
0.0000
1200.
-----0.0012
0.7662
0.0930
0.0540
0.0311
0.0133
0.0104
0.0299
0.0008
0.0001
0.0000
700.
-----0.0012
0.7450
0.0968
0.0591
0.0357
0.0156
0.0122
0.0339
0.0005
0.0000
0.0000

-----------------------PRESSURE - PSIG
--------------OIL COMP
6010. 5000. 4000.
-------- ------ ------ -----N2
0.0008 0.0008 0.0007
C1
0.5712 0.5398 0.5090
C2
0.0841 0.0833 0.0833
C3
0.0559 0.0569 0.0591
NC4
0.0404 0.0424 0.0456
NC5
0.0221 0.0237 0.0263
C6
0.0232 0.0254 0.0287
C8
0.0962 0.1071 0.1218
C14
0.0426 0.0526 0.0628
C20
0.0213 0.0280 0.0352
C34
0.0424 0.0399 0.0275
---------------------------
PRODUCED
GAS COMP
-------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
PRESSURE - PSIG
--------------6010. 5000. 4000.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000

------------------------
PRODUCED
GAS COMP
-------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
R2003.4 - Landmark
PRESSURE - PSIG
--------------6010. 5000. 4000.
------ ------ -----0.0011 0.0011 0.0012
0.6893 0.7034 0.7284
0.0864 0.0867 0.0871
0.0534 0.0531 0.0521
0.0348 0.0341 0.0324
0.0178 0.0172 0.0159
0.0173 0.0165 0.0148
0.0644 0.0604 0.0519
0.0205 0.0174 0.0113
0.0100 0.0083 0.0045
0.0049 0.0017 0.0002
D-245
Example Problems
-----------------------0 P = 6010.0 ZZ = 0.11000E-02
0.17800E-01
0.49510E-02
ZY = 1.13573 YY = 0.11000E-02
0.17800E-01
0.49499E-02
ZX = 1.44300 XX = 0.84286E-03
0.22074E-01
0.42434E-01
KV = 0.13051E+01
0.80639E+00
0.11665E+00
0 P = 5000.0 ZZ = 0.10974E-02
0.17847E-01
0.52248E-02
ZY = 0.99794 YY = 0.11312E-02
0.17240E-01
0.16524E-02
ZX = 1.27534 XX = 0.76882E-03
0.23745E-01
0.39947E-01
KV = 0.14714E+01
0.72605E+00
0.41366E-01
0 P = 4000.0 ZZ = 0.10854E-02
0.18096E-01
0.58817E-02
ZY = 0.89351 YY = 0.11890E-02
0.15948E-01
0.21612E-03
ZX = 1.05542 XX = 0.69051E-03
0.26283E-01
0.27483E-01
KV = 0.17219E+01
0.60678E+00
0.78638E-02
0 P = 3000.0 ZZ = 0.10491E-02
0.18977E-01
0.72056E-02
ZY = 0.84483 YY = 0.12464E-02
0.14185E-01
0.10406E-04
ZX = 0.87513 XX = 0.53223E-03
0.31536E-01
0.26060E-01
KV = 0.23418E+01
0.44979E+00
0.39929E-03
0 P = 2100.0 ZZ = 0.97947E-03
0.20926E-01
0.95947E-02
ZY = 0.84259 YY = 0.12591E-02
0.13101E-01
0.45219E-06
ZX = 0.69580 XX = 0.36010E-03
0.38258E-01
0.30845E-01
KV = 0.34966E+01
0.34243E+00
0.14660E-04
0 P = 1200.0 ZZ = 0.83708E-03
0.25343E-01
0.15169E-01
ZY = 0.87658 YY = 0.12246E-02
0.13323E-01
0.14629E-07
ZX = 0.46839 XX = 0.18994E-03
0.45415E-01
0.40500E-01
KV = 0.64474E+01
0.29336E+00
0.36122E-06
0 P =
700.0 ZZ = 0.67811E-03
0.30161E-01
0.22665E-01
ZY = 0.90953 YY = 0.11587E-02
0.15594E-01
0.23308E-08
ZX = 0.30874 XX = 0.10211E-03
D-246
0.68930E+00 0.86400E-01 0.53400E-01 0.34800E-01

0.17300E-01 0.64447E-01 0.20473E-01 0.10029E-01
0.68930E+00 0.86400E-01 0.53400E-01 0.34800E-01
0.17300E-01 0.64446E-01 0.20472E-01 0.10029E-01
0.57116E+00 0.84098E-01 0.55871E-01 0.40384E-01
0.23151E-01 0.96162E-01 0.42557E-01 0.21262E-01
0.12068E+01 0.10274E+01 0.95577E+00 0.86172E+00
0.74724E+00 0.67018E+00 0.48105E+00 0.47166E+00
0.68813E+00 0.86376E-01 0.53428E-01 0.34860E-01
0.17364E-01 0.64781E-01 0.20724E-01 0.10170E-01
0.70339E+00 0.86692E-01 0.53067E-01 0.34083E-01
0.16533E-01 0.60424E-01 0.17446E-01 0.83360E-02
0.53976E+00 0.83300E-01 0.56928E-01 0.42410E-01
0.25436E-01 0.10712E+00 0.52589E-01 0.27991E-01
0.13032E+01 0.10407E+01 0.93218E+00 0.80365E+00
0.64998E+00 0.56406E+00 0.33174E+00 0.29781E+00
0.68284E+00 0.86284E-01 0.53596E-01 0.35176E-01
0.17699E-01 0.66464E-01 0.21966E-01 0.10908E-01
0.72843E+00 0.87079E-01 0.52140E-01 0.32444E-01
0.14810E-01 0.51948E-01 0.11260E-01 0.45355E-02
0.50904E+00 0.83251E-01 0.59150E-01 0.45592E-01
0.28714E-01 0.12181E+00 0.62782E-01 0.35206E-01
0.14310E+01 0.10460E+01 0.88149E+00 0.71162E+00
0.51577E+00 0.42647E+00 0.17935E+00 0.12883E+00
0.66636E+00 0.85941E-01 0.54177E-01 0.36266E-01
0.18883E-01 0.72237E-01 0.25822E-01 0.13086E-01
0.75596E+00 0.87803E-01 0.51024E-01 0.30346E-01
0.12448E-01 0.40862E-01 0.48630E-02 0.12523E-02
0.43156E+00 0.81061E-01 0.62437E-01 0.51778E-01
0.35743E-01 0.15445E+00 0.80743E-01 0.44094E-01
0.17517E+01 0.10832E+01 0.81721E+00 0.58606E+00
0.34827E+00 0.26456E+00 0.60228E-01 0.28402E-01
0.63225E+00 0.84773E-01 0.55168E-01 0.38517E-01
0.21552E-01 0.85166E-01 0.33743E-01 0.17331E-01
0.76923E+00 0.89462E-01 0.51187E-01 0.29474E-01
0.10831E-01 0.33243E-01 0.19316E-02 0.28130E-03
0.32884E+00 0.74387E-01 0.63986E-01 0.58547E-01
0.45300E-01 0.20017E+00 0.10420E+00 0.55097E-01
0.23392E+01 0.12027E+01 0.79997E+00 0.50344E+00
0.23908E+00 0.16607E+00 0.18537E-01 0.51056E-02
0.55443E+00 0.79984E-01 0.55836E-01 0.42840E-01
0.28010E-01 0.11728E+00 0.52903E-01 0.27368E-01
0.76619E+00 0.93017E-01 0.54018E-01 0.31076E-01
0.10437E-01 0.29893E-01 0.76430E-03 0.54545E-04
0.20080E+00 0.58219E-01 0.58873E-01 0.62487E-01
0.57356E-01 0.26321E+00 0.13997E+00 0.72982E-01
0.38158E+01 0.15977E+01 0.91754E+00 0.49732E+00
0.18197E+00 0.11357E+00 0.54603E-02 0.74738E-03
0.46027E+00 0.71690E-01 0.54223E-01 0.46345E-01
0.35844E-01 0.15846E+00 0.78777E-01 0.40882E-01
0.74495E+00 0.96767E-01 0.59100E-01 0.35748E-01
0.12158E-01 0.33947E-01 0.54904E-03 0.24940E-04
0.11910E+00 0.41635E-01 0.48379E-01 0.59045E-01
Landmark - R2003.4
Example Problems
0.47617E-01 0.64232E-01 0.30769E+00 0.17253E+00 0.89848E-01

0.49829E-01
KV = 0.11348E+02 0.62549E+01 0.23242E+01 0.12216E+01 0.60544E+00
0.32749E+00 0.18928E+00 0.11033E+00 0.31823E-02 0.27758E-03
0.46775E-07
---------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
MOLE FRACTION
------------0.00110
0.68930
0.08640
0.05340
0.03480
0.01780
0.01730
0.06445
0.02047
0.01003
0.00495
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
OBSERVED PSAT
CALCULATED PSAT
=
=
6010.0 PSIG (DEWPT)

6010.0 PSIG (DEWPT)
CALCULATED ZSAT
1.1357
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
OBSERVED API GRAV.

CALCULATED API GRAV.
OBSERVED TOTAL GOR
CALCULATED TOTAL GOR
CALCULATED TOTAL OGR
=
=
=
=
=
PRES
-----PSIG
-----450.0
100.0
0.0
256.0 DEGREES F
75.0 DEGREES F
0.0 PSIG
0.7732 RB/MSCF
49.3
73.7
4699.70 SCF/STB
4301.24 SCF/STB
232.49 STB/MMSCF
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0.
3314.
4276.
3942.
75.0
0.
161.
212.
178.
75.0
0.
180.
212.
180.
SEP FVF
--------------DATA
CALC
----------0.0000 1.1897
0.0000 1.1102
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.6744
0.0000 0.8606
0.0000 1.5898
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------450.0
75.0
0.0000
0.2169
0.0000
0.1934
0.0000
0.6576
100.0
75.0
0.0000
0.1814
0.0000
0.0532
0.0000
0.6753
0.0
75.0
0.0000
0.1456
0.0000
0.0077
0.0000
0.6890
-----------0STAGE 1
ZZ = 0.11000E-02 0.68930E+00 0.86400E-01 0.53400E-01 0.34800E-01
0.17800E-01 0.17300E-01 0.64446E-01 0.20472E-01 0.10029E-01
0.49499E-02
ZY = 0.89574 YY = 0.13830E-02 0.84615E+00 0.90488E-01 0.41072E-01 0.14055E-01
0.31343E-02 0.14398E-02 0.22787E-02 0.15766E-05 0.11410E-07
0.92737E-10
ZX = 0.19339 XX = 0.78230E-04 0.12297E+00 0.71639E-01 0.97915E-01 0.10971E+00
0.70755E-01 0.74567E-01 0.28892E+00 0.94389E-01 0.46240E-01
0.22823E-01
KV = 0.17678E+02 0.68812E+01 0.12631E+01 0.41946E+00 0.12811E+00
0.44298E-01 0.19309E-01 0.78869E-02 0.16703E-04 0.24676E-06
0.40633E-08
0STAGE 2
ZZ = 0.78230E-04 0.12297E+00 0.71639E-01 0.97915E-01 0.10971E+00
0.70755E-01 0.74567E-01 0.28892E+00 0.94389E-01 0.46240E-01
0.22823E-01
ZY = 0.95671 YY = 0.44740E-03 0.63002E+00 0.19600E+00 0.11547E+00 0.40803E-01
0.84444E-02 0.36043E-02 0.52113E-02 0.18073E-05 0.67078E-08
R2003.4 - Landmark
D-247
Example Problems
0.19420E-15
ZX = 0.05325 XX = 0.60958E-05
0.82930E-01
0.27283E-01
KV = 0.73395E+02
0.10183E+00
0.71181E-14
0STAGE 3
ZZ = 0.60958E-05
0.82930E-01
0.27283E-01
ZY = 0.98210 YY = 0.30658E-04
0.58554E-01
0.55640E-15
ZX = 0.00766 XX = 0.52481E-07
0.88927E-01
0.33996E-01
KV = 0.58416E+03
0.65845E+00
0.16367E-13
---------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
0.23890E-01 0.47339E-01 0.94485E-01 0.12317E+00

0.88433E-01 0.34436E+00 0.11283E+00 0.55276E-01
0.26372E+02 0.41404E+01 0.12221E+01 0.33128E+00
0.40757E-01 0.15133E-01 0.16017E-04 0.12135E-06
0.23890E-01 0.47339E-01 0.94485E-01 0.12317E+00
0.88433E-01 0.34436E+00 0.11283E+00 0.55276E-01
0.11865E+00 0.21149E+00 0.32532E+00 0.22111E+00
0.26509E-01 0.38336E-01 0.10728E-04 0.31899E-07
0.57399E-03 0.69515E-02 0.37691E-01 0.99073E-01
0.10367E+00 0.41965E+00 0.14059E+00 0.68876E-01
0.20671E+03 0.30423E+02 0.86311E+01 0.22318E+01
0.25571E+00 0.91351E-01 0.76309E-04 0.46313E-06
MOLE FRACTION
------------0.00113
0.70339
0.08669
0.05307
0.03408
0.01724
0.01653
0.06042
0.01745
0.00834
0.00165
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
OBSERVED PSAT
CALCULATED PSAT
=
=
5000.0 PSIG (DEWPT)

5000.0 PSIG (DEWPT)
CALCULATED ZSAT
0.9979
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
OBSERVED API GRAV.

OBSERVED TOTAL GOR
=
=
=
=
=
PRES
-----PSIG
-----450.0
100.0
0.0
256.0 DEGREES F
75.0 DEGREES F
0.0 PSIG
0.8016 RB/MSCF
51.7
75.9
5727.20 SCF/STB
5205.93 SCF/STB
192.09 STB/MMSCF
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0.
3958.
5277.
4806.
75.0
0.
176.
223.
198.
75.0
0.
202.
227.
202.
SEP FVF
--------------DATA
CALC
----------0.0000 1.2145
0.0000 1.1249
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.6763
0.0000 0.8657
0.0000 1.6085
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------450.0
75.0
0.0000
0.1968
0.0000
0.1830
0.0000
0.6476
100.0
75.0
0.0000
0.1637
0.0000
0.0503
0.0000
0.6670
0.0
75.0
0.0000
0.1300
0.0000
0.0072
0.0000
0.6815
-----------0STAGE 1
ZZ = 0.11312E-02 0.70339E+00 0.86692E-01 0.53067E-01 0.34083E-01
0.17240E-01 0.16533E-01 0.60424E-01 0.17446E-01 0.83360E-02
0.16524E-02
D-248
Landmark - R2003.4
Example Problems
ZY = 0.89515 YY = 0.13886E-02
0.32986E-02
0.00000E+00
ZX = 0.18305 XX = 0.80856E-04
0.74141E-01
0.83969E-02
KV = 0.17173E+02
0.44491E-01
0.00000E+00
0STAGE 2
ZZ = 0.80856E-04
0.74141E-01
0.83969E-02
ZY = 0.95622 YY = 0.45038E-03
0.89072E-02
0.76468E-16
ZX = 0.05029 XX = 0.62914E-05
0.87304E-01
0.10091E-01
KV = 0.71587E+02
0.10203E+00
0.75777E-14
0STAGE 3
ZZ = 0.62914E-05
0.87304E-01
0.10091E-01
ZY = 0.98170 YY = 0.30345E-04
0.61869E-01
0.21869E-15
ZX = 0.00722 XX = 0.53220E-07
0.93900E-01
0.12708E-01
KV = 0.57018E+03
0.65888E+00
0.17208E-13
---------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
0.12549E+00 0.72154E-01 0.99785E-01 0.11368E+00

0.77832E-01 0.29743E+00 0.88645E-01 0.42359E-01
0.67335E+01 0.12508E+01 0.41711E+00 0.12825E+00
0.19459E-01 0.79201E-02 0.17152E-04 0.24226E-06
0.12549E+00 0.72154E-01 0.99785E-01 0.11368E+00
0.77832E-01 0.29743E+00 0.88645E-01 0.42359E-01
0.62735E+00 0.19466E+00 0.11705E+00 0.42403E-01
0.37978E-02 0.53836E-02 0.17376E-05 0.61684E-08
0.24224E-01 0.47434E-01 0.96302E-01 0.12807E+00
0.92770E-01 0.35636E+00 0.10653E+00 0.50907E-01
0.25898E+02 0.41039E+01 0.12154E+01 0.33110E+00
0.40938E-01 0.15107E-01 0.16310E-04 0.12117E-06
0.24224E-01 0.47434E-01 0.96302E-01 0.12807E+00
0.92770E-01 0.35636E+00 0.10653E+00 0.50907E-01
0.11544E+00 0.20422E+00 0.32269E+00 0.22777E+00
0.28090E-01 0.39875E-01 0.10381E-04 0.29477E-07
0.56734E-03 0.67705E-02 0.37590E-01 0.10221E+00
0.10954E+00 0.43844E+00 0.13416E+00 0.64109E-01
0.20347E+03 0.30164E+02 0.85846E+01 0.22285E+01
0.25643E+00 0.90948E-01 0.77377E-04 0.45979E-06
MOLE FRACTION
------------0.00119
0.72843
0.08708
0.05214
0.03244
0.01595
0.01481
0.05195
0.01126
0.00454
0.00022
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
OBSERVED PSAT
CALCULATED PSAT
=
=
4000.0 PSIG (DEWPT)

4000.0 PSIG (DEWPT)
CALCULATED ZSAT
0.8935
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
OBSERVED API GRAV.

OBSERVED TOTAL GOR
=
=
=
=
=
PRES
-----PSIG
-----450.0
100.0
0.0
R2003.4 - Landmark
0.84499E+00 0.90254E-01 0.41621E-01 0.14580E-01

0.15146E-02 0.23557E-02 0.15204E-05 0.10262E-07
256.0 DEGREES F
75.0 DEGREES F
0.0 PSIG
0.8697 RB/MSCF
55.4
78.4
8399.00 SCF/STB
7264.77 SCF/STB
137.65 STB/MMSCF
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0.
5440.
7828.
6807.
75.0
0.
193.
248.
222.
75.0
0.
236.
263.
236.
SEP FVF
--------------DATA
CALC
----------0.0000 1.2513
0.0000 1.1489
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.6798
0.0000 0.8754
0.0000 1.6434
D-249
Example Problems
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------450.0
75.0
0.0000
0.1597
0.0000
0.1716
0.0000
0.6368
100.0
75.0
0.0000
0.1324
0.0000
0.0469
0.0000
0.6578
0.0
75.0
0.0000
0.1032
0.0000
0.0067
0.0000
0.6735
-----------0STAGE 1
ZZ = 0.11890E-02 0.72843E+00 0.87079E-01 0.52140E-01 0.32444E-01
0.15948E-01 0.14810E-01 0.51948E-01 0.11260E-01 0.45355E-02
0.21612E-03
ZY = 0.89406 YY = 0.13991E-02 0.84289E+00 0.89848E-01 0.42551E-01 0.15566E-01
0.36127E-02 0.16483E-02 0.24890E-02 0.12436E-05 0.69671E-08
0.00000E+00
ZX = 0.17163 XX = 0.83619E-04 0.12638E+00 0.72512E-01 0.10258E+00 0.12123E+00
0.80834E-01 0.84040E-01 0.31211E+00 0.70482E-01 0.28393E-01
0.13529E-02
KV = 0.16732E+02 0.66692E+01 0.12391E+01 0.41480E+00 0.12840E+00
0.44692E-01 0.19613E-01 0.79747E-02 0.17644E-04 0.24538E-06
0.00000E+00
0STAGE 2
ZZ = 0.83619E-04 0.12638E+00 0.72512E-01 0.10258E+00 0.12123E+00
0.80834E-01 0.84040E-01 0.31211E+00 0.70482E-01 0.28393E-01
0.13529E-02
ZY = 0.95527 YY = 0.45677E-03 0.62142E+00 0.19346E+00 0.11976E+00 0.45322E-01
0.97676E-02 0.41354E-02 0.56789E-02 0.14143E-05 0.41884E-08
0.13203E-16
ZX = 0.04693 XX = 0.65148E-05 0.24095E-01 0.47520E-01 0.99033E-01 0.13691E+00
0.95518E-01 0.10055E+00 0.37543E+00 0.85046E-01 0.34259E-01
0.16325E-02
KV = 0.70112E+02 0.25791E+02 0.40710E+01 0.12093E+01 0.33103E+00
0.10226E+00 0.41128E-01 0.15127E-01 0.16629E-04 0.12225E-06
0.80878E-14
0STAGE 3
ZZ = 0.65148E-05 0.24095E-01 0.47520E-01 0.99033E-01 0.13691E+00
0.95518E-01 0.10055E+00 0.37543E+00 0.85046E-01 0.34259E-01
0.16325E-02
ZY = 0.98095 YY = 0.29399E-04 0.10755E+00 0.19298E+00 0.31794E+00 0.23992E+00
0.68073E-01 0.30899E-01 0.42602E-01 0.85528E-05 0.20228E-07
0.37789E-16
ZX = 0.00671 XX = 0.52571E-07 0.52784E-03 0.64459E-02 0.37217E-01 0.10782E+00
0.10327E+00 0.12022E+00 0.46941E+00 0.10906E+00 0.43934E-01
0.20935E-02
KV = 0.55923E+03 0.20376E+03 0.29938E+02 0.85429E+01 0.22251E+01
0.65918E+00 0.25702E+00 0.90757E-01 0.78423E-04 0.46042E-06
0.18051E-13
---------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
MOLE FRACTION
------------0.00125
0.75596
0.08780
0.05102
0.03035
0.01418
0.01245
0.04086
0.00486
0.00125
0.00001
FLASH CALCULATIONS:
D-250
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
256.0 DEGREES F
OBSERVED PSAT
CALCULATED PSAT
=
=
3000.0 PSIG (DEWPT)

3000.0 PSIG (DEWPT)
CALCULATED ZSAT
0.8448
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
75.0 DEGREES F
0.0 PSIG
1.0601 RB/MSCF
Landmark - R2003.4
Example Problems
OBSERVED API GRAV.

OBSERVED TOTAL GOR
PRES
-----PSIG
-----450.0
100.0
0.0
=
=
=
=
=
60.4
81.2
14396.60 SCF/STB
11376.03 SCF/STB
87.90 STB/MMSCF
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0.
8318. 13774. 10839.
75.0
0.
212.
290.
251.
75.0
0.
286.
333.
286.
SEP FVF
--------------DATA
CALC
----------0.0000 1.3030
0.0000 1.1844
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.6846
0.0000 0.8887
0.0000 1.6893
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------450.0
75.0
0.0000
0.1174
0.0000
0.1605
0.0000
0.6250
100.0
75.0
0.0000
0.0969
0.0000
0.0436
0.0000
0.6476
0.0
75.0
0.0000
0.0736
0.0000
0.0062
0.0000
0.6646
-----------0STAGE 1
ZZ = 0.12464E-02 0.75596E+00 0.87803E-01 0.51024E-01 0.30346E-01
0.14185E-01 0.12448E-01 0.40862E-01 0.48630E-02 0.12523E-02
0.10406E-04
ZY = 0.89252 YY = 0.14007E-02 0.83970E+00 0.89755E-01 0.43718E-01 0.16903E-01
0.40582E-02 0.18263E-02 0.26405E-02 0.56448E-06 0.00000E+00
0.00000E+00
ZX = 0.16048 XX = 0.85843E-04 0.12614E+00 0.73124E-01 0.10598E+00 0.13145E+00
0.90349E-01 0.92339E-01 0.32834E+00 0.41435E-01 0.10672E-01
0.88672E-04
KV = 0.16316E+02 0.66568E+01 0.12274E+01 0.41252E+00 0.12859E+00
0.44918E-01 0.19779E-01 0.80421E-02 0.13623E-04 0.00000E+00
0.00000E+00
0STAGE 2
ZZ = 0.85843E-04 0.12614E+00 0.73124E-01 0.10598E+00 0.13145E+00
0.90349E-01 0.92339E-01 0.32834E+00 0.41435E-01 0.10672E-01
0.88672E-04
ZY = 0.95393 YY = 0.46117E-03 0.61236E+00 0.19316E+00 0.12318E+00 0.49259E-01
0.10981E-01 0.45825E-02 0.60158E-02 0.85239E-06 0.16061E-08
0.93165E-18
ZX = 0.04360 XX = 0.67033E-05 0.23618E-01 0.47814E-01 0.10235E+00 0.14878E+00
0.10708E+00 0.11084E+00 0.39630E+00 0.50171E-01 0.12922E-01
0.10737E-03
KV = 0.68797E+02 0.25928E+02 0.40398E+01 0.12035E+01 0.33109E+00
0.10255E+00 0.41342E-01 0.15180E-01 0.16990E-04 0.12429E-06
0.86770E-14
0STAGE 3
ZZ = 0.67033E-05 0.23618E-01 0.47814E-01 0.10235E+00 0.14878E+00
0.10708E+00 0.11084E+00 0.39630E+00 0.50171E-01 0.12922E-01
0.10737E-03
ZY = 0.97993 YY = 0.27715E-04 0.96730E-01 0.17973E+00 0.31034E+00 0.25549E+00
0.76921E-01 0.34760E-01 0.46004E-01 0.52531E-05 0.78878E-08
0.26800E-17
ZX = 0.00621 XX = 0.50423E-07 0.46785E-03 0.60464E-02 0.36496E-01 0.11499E+00
0.11663E+00 0.13493E+00 0.50722E+00 0.66055E-01 0.17014E-01
0.14137E-03
KV = 0.54964E+03 0.20676E+03 0.29724E+02 0.85033E+01 0.22218E+01
0.65950E+00 0.25761E+00 0.90699E-01 0.79526E-04 0.46361E-06
0.18958E-13
---------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
MOLE FRACTION
------------0.00126
0.76923
0.08946
0.05119
0.02947
0.01310
0.01083
0.03324
0.00193
0.00028
0.00000
FLASH CALCULATIONS:
R2003.4 - Landmark
NEWTON-RAPHSON
NEWTON-RAPHSON
D-251
Example Problems
TEMPERATURE
OBSERVED PSAT
CALCULATED PSAT
=
=
2100.0 PSIG (DEWPT)

2100.0 PSIG (DEWPT)
CALCULATED ZSAT
0.8426
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
1.4802 RB/MSCF
OBSERVED API GRAV.

OBSERVED TOTAL GOR
=
=
=
=
=
64.6
83.3
20564.20 SCF/STB
15748.16 SCF/STB
63.50 STB/MMSCF
PRES
-----PSIG
-----450.0
100.0
0.0
256.0 DEGREES F
75.0 DEGREES F
0.0 PSIG
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0. 11201. 19863. 15137.
75.0
0.
228.
305.
277.
75.0
0.
333.
396.
333.
SEP FVF
--------------DATA
CALC
----------0.0000 1.3514
0.0000 1.2181
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.6894
0.0000 0.9014
0.0000 1.7231
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------450.0
75.0
0.0000
0.0932
0.0000
0.1541
0.0000
0.6164
100.0
75.0
0.0000
0.0766
0.0000
0.0417
0.0000
0.6404
0.0
75.0
0.0000
0.0567
0.0000
0.0059
0.0000
0.6583
-----------0STAGE 1
ZZ = 0.12591E-02 0.76923E+00 0.89462E-01 0.51187E-01 0.29474E-01
0.13101E-01 0.10831E-01 0.33243E-01 0.19316E-02 0.28130E-03
0.45219E-06
ZY = 0.89090 YY = 0.13797E-02 0.83534E+00 0.90991E-01 0.45161E-01 0.18087E-01
0.44119E-02 0.19422E-02 0.26854E-02 0.36809E-06 0.00000E+00
0.00000E+00
ZX = 0.15409 XX = 0.86187E-04 0.12631E+00 0.74596E-01 0.10978E+00 0.14022E+00
0.97597E-01 0.97269E-01 0.33041E+00 0.20713E-01 0.30170E-02
0.48497E-05
KV = 0.16009E+02 0.66136E+01 0.12198E+01 0.41137E+00 0.12900E+00
0.45206E-01 0.19967E-01 0.81273E-02 0.17771E-04 0.00000E+00
0.00000E+00
0STAGE 2
ZZ = 0.86187E-04 0.12631E+00 0.74596E-01 0.10978E+00 0.14022E+00
0.97597E-01 0.97269E-01 0.33041E+00 0.20713E-01 0.30170E-02
0.48497E-05
ZY = 0.95260 YY = 0.45294E-03 0.60174E+00 0.19492E+00 0.12720E+00 0.52756E-01
0.11951E-01 0.48747E-02 0.61075E-02 0.43630E-06 0.46354E-09
0.54337E-19
ZX = 0.04171 XX = 0.66792E-05 0.23241E-01 0.48512E-01 0.10601E+00 0.15918E+00
0.11616E+00 0.11730E+00 0.40072E+00 0.25203E-01 0.36710E-02
0.59010E-05
KV = 0.67814E+02 0.25892E+02 0.40180E+01 0.11999E+01 0.33143E+00
0.10288E+00 0.41558E-01 0.15242E-01 0.17312E-04 0.12627E-06
0.92080E-14
0STAGE 3
ZZ = 0.66792E-05 0.23241E-01 0.48512E-01 0.10601E+00 0.15918E+00
0.11616E+00 0.11730E+00 0.40072E+00 0.25203E-01 0.36710E-02
0.59010E-05
ZY = 0.97916 YY = 0.25493E-04 0.87968E-01 0.16983E+00 0.30474E+00 0.26813E+00
0.84132E-01 0.37547E-01 0.47622E-01 0.27421E-05 0.23134E-08
0.15735E-18
ZX = 0.00594 XX = 0.47015E-07 0.42280E-03 0.57433E-02 0.35951E-01 0.12077E+00
0.12746E+00 0.14541E+00 0.52519E+00 0.34086E-01 0.49651E-02
0.79813E-05
KV = 0.54223E+03 0.20806E+03 0.29571E+02 0.84765E+01 0.22203E+01
0.66009E+00 0.25821E+00 0.90675E-01 0.80446E-04 0.46593E-06
0.19715E-13
---------------------
COMPONENT
---------
D-252
MOLE FRACTION
-------------
Landmark - R2003.4
Example Problems
N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
0.00122
0.76619
0.09302
0.05402
0.03108
0.01332
0.01044
0.02989
0.00076
0.00005
0.00000
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
OBSERVED PSAT
CALCULATED PSAT
=
=
1200.0 PSIG (DEWPT)

1200.0 PSIG (DEWPT)
CALCULATED ZSAT
0.8766
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
2.6634 RB/MSCF
OBSERVED API GRAV.

OBSERVED TOTAL GOR
=
=
=
=
=
67.5
84.5
22972.40 SCF/STB
18261.86 SCF/STB
54.76 STB/MMSCF
PRES
-----PSIG
-----450.0
100.0
0.0
256.0 DEGREES F
75.0 DEGREES F
0.0 PSIG
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0. 12425. 22121. 17557.
75.0
0.
246.
370.
311.
75.0
0.
395.
482.
395.
SEP FVF
--------------DATA
CALC
----------0.0000 1.4130
0.0000 1.2613
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.6965
0.0000 0.9193
0.0000 1.7545
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------450.0
75.0
0.0000
0.0871
0.0000
0.1497
0.0000
0.6097
100.0
75.0
0.0000
0.0710
0.0000
0.0405
0.0000
0.6351
0.0
75.0
0.0000
0.0504
0.0000
0.0058
0.0000
0.6543
-----------0STAGE 1
ZZ = 0.12246E-02 0.76619E+00 0.93017E-01 0.54018E-01 0.31076E-01
0.13323E-01 0.10437E-01 0.29893E-01 0.76430E-03 0.54545E-04
0.14629E-07
ZY = 0.88834 YY = 0.13334E-02 0.82721E+00 0.94477E-01 0.48030E-01 0.19616E-01
0.47215E-02 0.19990E-02 0.26079E-02 0.17035E-06 0.16900E-09
0.15890E-19
ZX = 0.14969 XX = 0.84456E-04 0.12673E+00 0.77721E-01 0.11676E+00 0.15116E+00
0.10346E+00 0.98863E-01 0.31582E+00 0.87718E-02 0.62614E-03
0.16794E-06
KV = 0.15788E+02 0.65275E+01 0.12156E+01 0.41135E+00 0.12977E+00
0.45636E-01 0.20220E-01 0.82577E-02 0.19420E-04 0.26991E-06
0.94622E-13
0STAGE 2
ZZ = 0.84456E-04 0.12673E+00 0.77721E-01 0.11676E+00 0.15116E+00
0.10346E+00 0.98863E-01 0.31582E+00 0.87718E-02 0.62614E-03
0.16794E-06
ZY = 0.95064 YY = 0.42762E-03 0.58366E+00 0.19990E+00 0.13494E+00 0.57304E-01
0.12820E-01 0.50253E-02 0.59274E-02 0.18994E-06 0.99191E-10
0.20080E-20
ZX = 0.04048 XX = 0.63651E-05 0.22748E-01 0.49919E-01 0.11263E+00 0.17252E+00
0.12409E+00 0.12022E+00 0.38634E+00 0.10768E-01 0.76862E-03
0.20615E-06
KV = 0.67182E+02 0.25658E+02 0.40044E+01 0.11981E+01 0.33215E+00
0.10331E+00 0.41802E-01 0.15342E-01 0.17640E-04 0.12905E-06
0.97404E-14
0STAGE 3
ZZ = 0.63651E-05 0.22748E-01 0.49919E-01 0.11263E+00 0.17252E+00
0.12409E+00 0.12022E+00 0.38634E+00 0.10768E-01 0.76862E-03
0.20615E-06
ZY = 0.97841 YY = 0.21911E-04 0.77744E-01 0.15934E+00 0.30179E+00 0.28309E+00
R2003.4 - Landmark
D-253
Example Problems
0.90889E-01
0.58638E-20
ZX = 0.00579 XX = 0.40729E-07
0.13759E+00
0.29002E-06
KV = 0.53796E+03
0.66056E+00
0.20219E-13
---------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
0.39575E-01 0.47546E-01 0.12278E-05 0.50618E-09

0.37413E-03 0.54047E-02 0.35667E-01 0.12754E+00
0.15302E+00 0.52417E+00 0.15148E-01 0.10813E-02
0.20780E+03 0.29481E+02 0.84614E+01 0.22196E+01
0.25862E+00 0.90707E-01 0.81055E-04 0.46812E-06
MOLE FRACTION
------------0.00116
0.74495
0.09677
0.05910
0.03575
0.01559
0.01216
0.03395
0.00055
0.00002
0.00000
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
256.0 DEGREES F
OBSERVED PSAT
CALCULATED PSAT
=
=
700.0 PSIG (DEWPT)

700.0 PSIG (DEWPT)
CALCULATED ZSAT
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
4.7379 RB/MSCF
OBSERVED API GRAV.

OBSERVED TOTAL GOR
=
=
=
=
=
68.6
85.0
20400.00 SCF/STB
15713.30 SCF/STB
63.64 STB/MMSCF
PRES
-----PSIG
-----450.0
100.0
0.0
0.9095
75.0 DEGREES F
0.0 PSIG
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0. 10141. 19475. 14918.
75.0
0.
263.
367.
342.
75.0
0.
453.
558.
453.
SEP FVF
--------------DATA
CALC
----------0.0000 1.4711
0.0000 1.3020
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.7035
0.0000 0.9364
0.0000 1.7751
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------450.0
75.0
0.0000
0.1063
0.0000
0.1471
0.0000
0.6059
100.0
75.0
0.0000
0.0858
0.0000
0.0398
0.0000
0.6324
0.0
75.0
0.0000
0.0587
0.0000
0.0057
0.0000
0.6530
-----------0STAGE 1
ZZ = 0.11587E-02 0.74495E+00 0.96767E-01 0.59100E-01 0.35748E-01
0.15594E-01 0.12158E-01 0.33947E-01 0.54904E-03 0.24940E-04
0.23308E-08
ZY = 0.88576 YY = 0.12868E-02 0.81849E+00 0.98618E-01 0.51311E-01 0.20930E-01
0.48687E-02 0.19950E-02 0.25001E-02 0.86227E-07 0.00000E+00
0.00000E+00
ZX = 0.14710 XX = 0.82106E-04 0.12690E+00 0.81212E-01 0.12456E+00 0.16029E+00
0.10574E+00 0.97570E-01 0.29825E+00 0.51628E-02 0.23456E-03
0.21921E-07
KV = 0.15673E+02 0.64499E+01 0.12143E+01 0.41195E+00 0.13057E+00
0.46044E-01 0.20447E-01 0.83828E-02 0.16702E-04 0.00000E+00
0.00000E+00
0STAGE 2
ZZ = 0.82106E-04 0.12690E+00 0.81212E-01 0.12456E+00 0.16029E+00
0.10574E+00 0.97570E-01 0.29825E+00 0.51628E-02 0.23456E-03
D-254
Landmark - R2003.4
0.21921E-07
ZY = 0.94870 YY = 0.40065E-03
0.13255E-01
0.27535E-21
ZX = 0.03981 XX = 0.59865E-05
0.12784E+00
0.27159E-07
KV = 0.66925E+02
0.10368E+00
0.10139E-13
0STAGE 3
ZZ = 0.59865E-05
0.12784E+00
0.27159E-07
ZY = 0.97790 YY = 0.18858E-04
0.94613E-01
0.80964E-21
ZX = 0.00573 XX = 0.35118E-07
0.14320E+00
0.39716E-07
KV = 0.53698E+03
0.66069E+00
0.20386E-13
1
Example Problems
0.56494E+00 0.20575E+00 0.14370E+00 0.61239E-01

0.50264E-02 0.56854E-02 0.11442E-06 0.38273E-10
0.22225E-01 0.51453E-01 0.11998E+00 0.18396E+00
0.11968E+00 0.36816E+00 0.63965E-02 0.29061E-03
0.25420E+02 0.39987E+01 0.11977E+01 0.33288E+00
0.41997E-01 0.15443E-01 0.17887E-04 0.13170E-06
0.22225E-01 0.51453E-01 0.11998E+00 0.18396E+00
0.11968E+00 0.36816E+00 0.63965E-02 0.29061E-03
0.69564E-01 0.15160E+00 0.30219E+00 0.29467E+00
0.40447E-01 0.46895E-01 0.76006E-06 0.19958E-09
0.33569E-03 0.51468E-02 0.35732E-01 0.13277E+00
0.15632E+00 0.51670E+00 0.93538E-02 0.42498E-03
0.20723E+03 0.29456E+02 0.84569E+01 0.22193E+01
0.25874E+00 0.90757E-01 0.81257E-04 0.46962E-06

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------1
1.00000000
0.45723549
0.00000000
2
1.00000000
0.07779610
0.00000000
3
1.00000000
0.45723549
0.00000000
4
1.00000000
0.07779610
0.00000000
5
1.00000000
0.40470231
0.00000000
6
1.00000000
0.08167780
0.00000000
7
1.00000000
0.45542160
0.00000000
8
1.00000000
0.07596840
0.00000000
9
1.00000000
0.43563280
0.00000000
10
1.00000000
0.07992980
0.00000000
11
1.00000000
0.46355090
0.00000000
12
1.00000000
0.07354740
0.00000000
=
1.679652E+00
1.931984E-01
2

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------1
1.05807516
0.48378951
0.05807516
2
1.00578144
0.07824588
0.00578144
3
1.03854436
0.47485934
0.03854436
4
0.96320736
0.07493378
-0.03679264
5
0.98036518
0.39675605
-0.01963482
6
0.91240908
0.07452357
-0.08759092
7
0.92536204
0.42142986
-0.07463796
8
0.86941433
0.06604802
-0.13058567
9
0.88389513
0.38505370
-0.11610487
10
0.96139524
0.07684413
-0.03860476
11
1.01929798
0.47249649
0.01929798
12
1.00219008
0.07370847
0.00219008
=
1.927524E-01
6.544758E-02
3

--------------------------0INDEX
X
VARIABLE
------------------------1
1.00831572
0.46103773
2
0.95194119
0.07405731
3
1.01731469
0.46515238
4
0.94602114
0.07359676
5
0.96725544
0.39145050
6
0.88771670
0.07250675
7
0.76052873
0.34636121
8
0.79531472
0.06041879
9
0.79762999
0.34747378
10
0.87585282
0.07000674
R2003.4 - Landmark
DELTA X
-----------0.04975944
-0.05384025
-0.02122967
-0.01718622
-0.01310975
-0.02469238
-0.16483332
-0.07409960
-0.08626514
-0.08554242
DELTA VAR.
----------0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
DELTA VAR.
----------0.02655403
0.00044977
0.01762385
-0.00286232
-0.00794626
-0.00715423
-0.03399174
-0.00992038
-0.05057909
-0.00308567
0.00894560
0.00016107
DELTA VAR.
-----------0.02275178
-0.00418856
-0.00970696
-0.00133702
-0.00530554
-0.00201682
-0.07506865
-0.00562923
-0.03757992
-0.00683739
D-255
Example Problems
11
0.92818115
0.43025921
-0.09111683
12
0.93485284
0.06875600
-0.06733724
=
3.557250E-02
2.811583E-02
4

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------1
0.88572667
0.40498566
-0.12258905
2
0.83975833
0.06532992
-0.11218287
3
0.96162778
0.43969034
-0.05568691
4
0.89331498
0.06949642
-0.05270616
5
0.97830964
0.39592417
0.01105421
6
0.90262912
0.07372476
0.01491242
7
0.68898795
0.31377999
-0.07154077
8
0.73874626
0.05612137
-0.05656847
9
0.81462195
0.35487604
0.01699196
10
0.90117960
0.07203110
0.02532679
11
0.82399837
0.38196518
-0.10418278
12
0.85023717
0.06253273
-0.08461567
=
2.448444E-02
2.332592E-02
5

--------------------------0INDEX
X
VARIABLE
DELTA X
----------------------------------1
0.89961195
0.41133451
0.01388529
2
0.85107701
0.06621047
0.01131869
3
0.94547576
0.43230507
-0.01615202
4
0.87211691
0.06784730
-0.02119807
5
0.98407055
0.39825562
0.00576091
6
0.90729010
0.07410546
0.00466098
7
0.64885019
0.29550039
-0.04013776
8
0.69119770
0.05250918
-0.04754856
9
0.86678491
0.37759993
0.05216296
10
0.94697215
0.07569129
0.04579254
11
0.82480039
0.38233696
0.00080202
12
0.85193643
0.06265771
0.00169926
=
2.374324E-02
2.297015E-02
6
-0.04223729
-0.00495248
DELTA VAR.
-----------0.05605207
-0.00872739
-0.02546203
-0.00410033
0.00447366
0.00121801
-0.03258121
-0.00429742
0.00740226
0.00202436
-0.04829402
-0.00622326
DELTA VAR.
----------0.00634885
0.00088055
-0.00738528
-0.00164913
0.00233145
0.00038070
-0.01827960
-0.00361219
0.02272390
0.00366019
0.00037178
0.00012498

--------------------------0INDEX
X
VARIABLE
DELTA X
DELTA VAR.
--------------------------------------------1
0.90630162
0.41439326
0.00668966
0.00305875
2
0.85618720
0.06660803
0.00511018
0.00039755
3
0.93154384
0.42593490
-0.01393192
-0.00637017
4
0.85376455
0.06641955
-0.01835236
-0.00142774
5
0.99064943
0.40091811
0.00657888
0.00266249
6
0.91212830
0.07450063
0.00483820
0.00039517
7
0.61727793
0.28112170
-0.03157226
-0.01437869
8
0.66037347
0.05016752
-0.03082423
-0.00234167
9
0.90299119
0.39337258
0.03620628
0.01577264
10
0.97210443
0.07770011
0.02513229
0.00200882
11
0.82696906
0.38334225
0.00216867
0.00100529
12
0.85380072
0.06279482
0.00186429
0.00013711
=
2.355461E-02
2.287872E-02
0TOTAL NUMBER OF FUNCTION EVALUATIONS =
76
THE RELATIVE CHANGE IN THE OBJECTIVE FUNCTION WAS LESS THAN TOL3 =
0.01000
-------------------COMPONENT
MOLE
TC
PC
CRITICAL ACENTRIC
OMEGA
OMEGA
PCHOR
NO. NAME WEIGHT
DEG F
PSIA
Z-FACTOR FACTOR
A
B
-- ------ ------- -------- -------- -------- -------- -------- -------- ------1 N2
28.01 -232.40
493.00
0.2910 0.03720 0.45724 0.07780
35.0
2 C1
16.04 -116.60
667.80
0.2890 0.01260 0.41439 0.06661
71.0
3 C2
30.07
90.10
707.80
0.2850 0.09780 0.42593 0.06642
111.0
D-256
Landmark - R2003.4
4
5
6
7
8
9
10
11
C3
NC4
NC5
C6
C8
C14
C20
C34
Example Problems
44.10
58.12
72.15
84.00
109.30
183.86
279.75
438.36
206.00
305.70
385.70
463.00
602.85
807.42
1000.71
1238.40
616.30
550.70
488.60
468.30
415.02
282.76
207.54
150.02
0.2810
0.2740
0.2620
0.2698
0.2618
0.2350
0.2156
0.1979
0.15410
0.20150
0.25240
0.23130
0.32270
0.49960
0.70450
1.04930
0.45724
0.45724
0.45724
0.45724
0.40092
0.28112
0.39337
0.38334
0.07780
0.07780
0.07780
0.07780
0.07450
0.05017
0.07770
0.06279
151.0
191.0
231.0
271.0
351.0
591.9
833.7
1397.9
11

------------------------------1
11
1
2
3
4
5
6
7
8
9
10
11
0.1200
0.1200
0.1200
0.1200
0.1200
0.1200
0.1200
0.1200
0.1200
0.1200
0.0000
0.0000
0.0200
0.0200
0.0298
0.1347
0.0358
0.0165
0.0848
0.0000
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
10
0.0000
0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000

---------------------------------------------------------NO.
----k(1)
k(2)
k(3)
k(4)
k(5)
k(6)
k(7)
K-COEFFICIENT
--------------0.9746020E+01
0.1808340E+02
0.4126660E+04
0.4460550E+02
0.9765440E+00
0.8181340E+02
0.1564990E+05

--------------------------------------1
11
1
2
3
4
5
6
7
8
9
10
11
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
10
0.0000
0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000

A = A0 + A1*T + A2*T**2 + A3*T**3 + A4*T**4
B = B0 + B1*T + B2*T**2 + B3*T**3 + B4*T**4
C = A0 + C1*T + C2*T**2 + C3*T**3 + C4*T**4
where Rsw
P
T
S
in
in
in
in
A0
1.1630599
B0
0.9650900
C0
R2003.4 - Landmark
scf/stb
psia
degree F
A1
-16.6303997
B1
-0.2725500
C1
A2
111.0730515
B2
0.0923400
C2
A3
-376.8592529
B3
-0.1008300
C3
A4
524.8891602
B4
0.0997900
C4
D-257
Example Problems
1.2803000
S0
-0.0280370
-10.7566004
S1
-0.1203900
52.6962204
-222.3948822
462.6725464

D1 =
5.80000

------------------------------------H* = A + B*T + C*(T**2) + D*(T**3) + E*(T**4) + F*(T**5)
WHERE THE UNITS ARE
H* - BTU / LB-MOLE
T
- DEGREES RANKIN
COMPONENT
NO NAME
-- -----1 N2
2 C1
3 C2
4 C3
5 NC4
6 NC5
7 C6
8 C8
9 C14
10 C20
11 C34
A
B
C
D
---------- ---------- ---------- ----------0.262E+02 0.715E+01 -0.498E-03 0.445E-06
-0.112E+03 0.917E+01 -0.472E-02 0.679E-05
-0.631E+00 0.796E+01 -0.752E-03 0.879E-05
-0.325E+02 0.761E+01 0.415E-02 0.951E-05
0.432E+03 0.573E+01 0.156E-01 0.301E-05
0.196E+04 -0.202E+00 0.318E-01 -0.623E-05
0.000E+00 0.242E+01 0.343E-01 -0.477E-05
0.000E+00 0.656E+01 0.463E-01 -0.683E-05
0.000E+00 0.462E+02 0.557E-01 -0.936E-05
0.000E+00 0.541E+02 0.143E+00 -0.225E-04
0.000E+00 0.165E+02 0.174E+00 -0.237E-04
E
F
---------- ----------0.902E-10 0.445E-14
-0.245E-08 0.312E-12
-0.387E-08 0.548E-12
-0.472E-08 0.702E-12
-0.244E-08 0.381E-12
0.590E-09 -0.142E-13
0.000E+00 0.000E+00
0.000E+00 0.000E+00
0.000E+00 0.000E+00
0.000E+00 0.000E+00
0.000E+00 0.000E+00
-------------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
22
MOLE FRACTION
------------0.00110
0.68930
0.08640
0.05340
0.03480
0.01780
0.01730
0.06445
0.02047
0.01003
0.00495
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
256.00 DEGREES F
OBSERVED PSAT
CALCULATED PSAT
OIL DENSITY AT PSAT
GAS DENSITY AT PSAT
= 6010.00 PSIG
= 6009.87 PSIG
= 0.0000
= 1.0361
= 0.6283 GM/CC
= 0.4435 GM/CC
(DEWPT)
(DEWPT)
PRES MW(C8
-C34 )
CUM GAS PROD
LIQ VOL FRAC
LIQ MOLE FRAC
------- --------------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ ------ ------ -----6010.0
0.00 158.00 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
5000.0
0.00 147.90 0.0000 0.0807 0.0000 0.1025 0.0000 0.0776
4000.0
0.00 136.62 0.0000 0.1946 0.0000 0.2491 0.0000 0.1866
3000.0
0.00 124.28 0.0000 0.3533 0.0000 0.2997 0.0000 0.2035
2100.0
0.00 117.31 0.0000 0.5189 0.0000 0.2797 0.0000 0.1680
1200.0
0.00 113.64 0.0000 0.6938 0.0000 0.2463 0.0000 0.1274
700.0
0.00 112.50 0.0000 0.7910 0.0000 0.2242 0.0000 0.1047
D-258
Landmark - R2003.4
Example Problems
PRES
OIL Z-FACTOR
GAS Z-FACTOR
OIL DENSITY
------- --------------- --------------- --------------PSIG
DATA
CALC
DATA
CALC
DATA
CALC
------- ------ ------ ------ ------ ------ -----6010.0 0.0000 0.0000 0.0000 1.0361 0.0000 0.0000
5000.0 0.0000 1.1383 0.0000 0.9196 0.0000 0.6265
4000.0 0.0000 0.9219 0.0000 0.8378 0.0000 0.5893
3000.0 0.0000 0.7636 0.0000 0.8192 0.0000 0.6065
2100.0 0.0000 0.6056 0.0000 0.8367 0.0000 0.6432
1200.0 0.0000 0.4041 0.0000 0.8802 0.0000 0.6862
700.0 0.0000 0.2634 0.0000 0.9141 0.0000 0.7133
PRES
OIL VISCOSITY
GAS VISCOSITY
SURF TENS
------- --------------- --------------- ----------PSIG
DATA
CALC
DATA
CALC
DYNE/CM
------- ------ ------ ------ ------ ----------6010.0 0.0000 0.0000 0.0000 0.0693 0.0000E+00
5000.0 0.0000 0.1943 0.0000 0.0523 0.2388E+00
4000.0 0.0000 0.1472 0.0000 0.0364 0.5777E+00
3000.0 0.0000 0.1605 0.0000 0.0245 0.2443E+01
2100.0 0.0000 0.2020 0.0000 0.0182 0.6613E+01
1200.0 0.0000 0.2693 0.0000 0.0148 0.1418E+02
700.0 0.0000 0.3241 0.0000 0.0136 0.2030E+02
---------------------------
OIL COMP
-------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
PRESSURE - PSIG
--------------6010. 5000. 4000.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
3000.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
2100.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1200.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
700.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
3000.
-----0.0005
0.4277
0.0849
0.0624
0.0520
0.0317
0.0358
0.1687
0.0740
0.0387
0.0235
2100.
-----0.0003
0.3204
0.0785
0.0640
0.0591
0.0386
0.0455
0.2199
0.0957
0.0495
0.0285
1200.
-----0.0002
0.1922
0.0617
0.0585
0.0628
0.0456
0.0573
0.2899
0.1282
0.0660
0.0376
700.
-----0.0001
0.1127
0.0445
0.0480
0.0595
0.0478
0.0639
0.3413
0.1560
0.0803
0.0458
3000.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
2100.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1200.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
700.
-----0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

-----------------------PRESSURE - PSIG
--------------OIL COMP
6010. 5000. 4000.
-------- ------ ------ -----N2
0.0000 0.0007 0.0007
C1
0.0000 0.5283 0.5089
C2
0.0000 0.0850 0.0860
C3
0.0000 0.0557 0.0586
NC4
0.0000 0.0418 0.0451
NC5
0.0000 0.0234 0.0260
C6
0.0000 0.0252 0.0284
C8
0.0000 0.1189 0.1320
C14
0.0000 0.0551 0.0596
C20
0.0000 0.0223 0.0296
C34
0.0000 0.0436 0.0251
---------------------------
PRODUCED
GAS COMP
-------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
R2003.4 - Landmark
PRESSURE - PSIG
--------------6010. 5000. 4000.
------ ------ -----0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
D-259
Example Problems

-----------------------PRESSURE - PSIG
PRODUCED --------------GAS COMP
6010. 5000. 4000. 3000. 2100. 1200.
700.
-------- ------ ------ ------ ------ ------ ------ -----N2
0.0011 0.0011 0.0012 0.0013 0.0013 0.0012 0.0012
C1
0.6893 0.7028 0.7337 0.7675 0.7800 0.7734 0.7491
C2
0.0864 0.0865 0.0865 0.0869 0.0890 0.0938 0.0992
C3
0.0534 0.0532 0.0521 0.0506 0.0509 0.0544 0.0603
NC4
0.0348 0.0342 0.0322 0.0296 0.0287 0.0309 0.0362
NC5
0.0178 0.0173 0.0158 0.0136 0.0125 0.0129 0.0155
C6
0.0173 0.0166 0.0146 0.0117 0.0100 0.0099 0.0118
C8
0.0644 0.0599 0.0477 0.0330 0.0251 0.0223 0.0257
C14
0.0205 0.0176 0.0108 0.0046 0.0021 0.0012 0.0010
C20
0.0100 0.0090 0.0051 0.0014 0.0004 0.0001 0.0000
C34
0.0050 0.0017 0.0002 0.0000 0.0000 0.0000 0.0000
-----------------------0 P = 5000.0 ZZ = 0.10972E-02 0.68811E+00 0.86390E-01 0.53417E-01
0.17841E-01 0.17358E-01 0.64849E-01 0.20729E-01
0.52363E-02
ZY = 0.91963 YY = 0.11316E-02 0.70285E+00 0.86520E-01 0.53206E-01
0.17329E-01 0.16636E-01 0.59863E-01 0.17555E-01
0.16985E-02
ZX = 1.13827 XX = 0.72412E-03 0.52833E+00 0.84978E-01 0.55707E-01
0.23400E-01 0.25189E-01 0.11891E+00 0.55141E-01
0.43596E-01
KV = 0.15628E+01 0.13303E+01 0.10181E+01 0.95509E+00
0.74055E+00 0.66044E+00 0.50343E+00 0.31837E+00
0.38961E-01
0 P = 4000.0 ZZ = 0.10817E-02 0.68165E+00 0.86376E-01 0.53602E-01
0.18135E-01 0.17755E-01 0.67270E-01 0.22129E-01
0.59512E-02
ZY = 0.83782 YY = 0.12070E-02 0.73374E+00 0.86485E-01 0.52107E-01
0.15768E-01 0.14554E-01 0.47741E-01 0.10835E-01
0.18504E-03
ZX = 0.92190 XX = 0.66609E-03 0.50892E+00 0.86013E-01 0.58561E-01
0.25985E-01 0.28371E-01 0.13204E+00 0.59586E-01
0.25074E-01
KV = 0.18121E+01 0.14418E+01 0.10055E+01 0.88979E+00
0.60679E+00 0.51299E+00 0.36158E+00 0.18184E+00
0.73797E-02
0 P = 3000.0 ZZ = 0.10333E-02 0.66059E+00 0.86254E-01 0.54336E-01
0.19257E-01 0.19252E-01 0.75686E-01 0.26434E-01
0.74098E-02
ZY = 0.81925 YY = 0.12788E-02 0.76750E+00 0.86871E-01 0.50613E-01
0.13563E-01 0.11655E-01 0.32974E-01 0.45857E-02
0.67563E-05
ZX = 0.76358 XX = 0.49854E-03 0.42771E+00 0.84912E-01 0.62447E-01
0.31660E-01 0.35800E-01 0.16873E+00 0.74028E-01
0.23537E-01
KV = 0.25651E+01 0.17944E+01 0.10231E+01 0.81049E+00
0.42840E+00 0.32556E+00 0.19543E+00 0.61945E-01
0.28706E-03
0 P = 2100.0 ZZ = 0.94777E-03 0.61949E+00 0.85319E-01 0.55503E-01
0.21591E-01 0.22425E-01 0.93107E-01 0.34798E-01
0.99611E-02
ZY = 0.83674 YY = 0.12818E-02 0.77995E+00 0.88973E-01 0.50948E-01
0.12477E-01 0.10036E-01 0.25091E-01 0.21441E-02
0.31500E-06
ZX = 0.60560 XX = 0.32527E-03 0.32042E+00 0.78508E-01 0.63993E-01
0.38579E-01 0.45517E-01 0.21988E+00 0.95659E-01
0.28526E-01
KV = 0.39406E+01 0.24342E+01 0.11333E+01 0.79614E+00
0.32341E+00 0.22048E+00 0.11411E+00 0.22414E-01
0.11042E-04
0 P = 1200.0 ZZ = 0.78722E-03 0.53166E+00 0.80471E-01 0.56116E-01
0.26527E-01 0.29593E-01 0.13356E+00 0.53998E-01
0.15648E-01
ZY = 0.88017 YY = 0.12290E-02 0.77336E+00 0.93811E-01 0.54429E-01
0.12945E-01 0.98698E-02 0.22251E-01 0.11631E-02
0.14524E-07
ZX = 0.40407 XX = 0.16664E-03 0.19216E+00 0.61734E-01 0.58486E-01
0.45603E-01 0.57295E-01 0.28989E+00 0.12821E+00
0.37626E-01
KV = 0.73752E+01 0.40244E+01 0.15196E+01 0.93064E+00
0.28387E+00 0.17226E+00 0.76757E-01 0.90719E-02
0.38602E-06
D-260
0.34851E-01
0.10119E-01
0.34215E-01
0.89987E-02
0.41754E-01
0.22271E-01
0.81944E+00
0.40405E+00
0.35222E-01
0.10823E-01
0.32231E-01
0.51466E-02
0.45144E-01
0.29649E-01
0.71396E+00
0.17358E+00
0.36614E-01
0.13134E-01
0.29550E-01
0.14069E-02
0.52001E-01
0.38679E-01
0.56826E+00
0.36375E-01
0.39325E-01
0.17533E-01
0.28740E-01
0.35851E-03
0.59056E-01
0.49542E-01
0.48665E+00
0.72365E-02
0.44160E-01
0.27490E-01
0.30857E-01
0.89250E-04
0.62844E-01
0.65978E-01
0.49101E+00
0.13527E-02
Landmark - R2003.4
Example Problems
0 P =
700.0 ZZ = 0.61832E-03
0.31663E-01
0.22931E-01
ZY = 0.91407 YY = 0.11501E-02
0.15491E-01
0.30733E-08
ZX = 0.26337 XX = 0.88272E-04
0.47784E-01
0.45788E-01
KV = 0.13029E+02
0.32419E+00
0.67119E-07
---------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
0.43043E+00 0.71773E-01 0.54153E-01 0.47860E-01

0.37894E-01 0.18377E+00 0.78649E-01 0.40263E-01
0.74913E+00 0.99157E-01 0.60333E-01 0.36209E-01
0.11758E-01 0.25682E-01 0.10384E-02 0.48430E-04
0.11274E+00 0.44477E-01 0.47994E-01 0.59475E-01
0.63946E-01 0.34134E+00 0.15601E+00 0.80350E-01
0.66447E+01 0.22294E+01 0.12571E+01 0.60880E+00
0.18388E+00 0.75239E-01 0.66557E-02 0.60274E-03
MOLE FRACTION
------------0.00110
0.68930
0.08640
0.05340
0.03480
0.01780
0.01730
0.06445
0.02047
0.01003
0.00495
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
OBSERVED PSAT
CALCULATED PSAT
=
=
6010.0 PSIG (DEWPT)

6009.9 PSIG (DEWPT)
CALCULATED ZSAT
1.0361
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
OBSERVED API GRAV.

OBSERVED TOTAL GOR
=
=
=
=
=
PRES
-----PSIG
-----450.0
100.0
0.0
256.0 DEGREES F
75.0 DEGREES F
0.0 PSIG
0.7069 RB/MSCF
49.3
49.3
4699.70 SCF/STB
4821.75 SCF/STB
207.39 STB/MMSCF
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0.
3677.
4276.
4410.
75.0
0.
181.
212.
202.
75.0
0.
210.
212.
210.
SEP FVF
--------------DATA
CALC
----------0.0000 1.1991
0.0000 1.1187
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.6686
0.0000 0.8577
0.0000 1.5410
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------450.0
75.0
0.0000
0.2203
0.0000
0.1708
0.0000
0.7397
100.0
75.0
0.0000
0.1845
0.0000
0.0470
0.0000
0.7601
0.0
75.0
0.0000
0.1475
0.0000
0.0067
0.0000
0.7817
-----------0STAGE 1
ZZ = 0.11000E-02 0.68930E+00 0.86400E-01 0.53400E-01 0.34800E-01
0.17800E-01 0.17300E-01 0.64447E-01 0.20473E-01 0.10029E-01
0.49510E-02
ZY = 0.90200 YY = 0.13921E-02 0.85010E+00 0.88272E-01 0.41045E-01 0.13704E-01
0.29832E-02 0.13410E-02 0.11549E-02 0.51466E-05 0.47522E-07
0.30446E-10
ZX = 0.17082 XX = 0.66049E-04 0.12016E+00 0.79776E-01 0.97128E-01 0.10947E+00
0.70242E-01 0.73785E-01 0.28846E+00 0.92916E-01 0.45525E-01
0.22474E-01
KV = 0.21077E+02 0.70746E+01 0.11065E+01 0.42259E+00 0.12519E+00
R2003.4 - Landmark
D-261
Example Problems
0.42471E-01
0.13547E-08
ZZ = 0.66049E-04
0.70242E-01
0.22474E-01
ZY = 0.95871 YY = 0.38432E-03
0.83108E-02
0.62559E-15
ZX = 0.04695 XX = 0.43982E-05
0.82238E-01
0.26828E-01
KV = 0.87381E+02
0.10106E+00
0.23319E-13
0STAGE 3
ZZ = 0.43982E-05
0.82238E-01
0.26828E-01
ZY = 0.98324 YY = 0.21760E-04
0.58242E-01
0.20457E-14
ZX = 0.00673 XX = 0.31013E-07
0.88274E-01
0.33576E-01
KV = 0.70165E+03
0.65978E+00
0.60928E-13
--------------------0STAGE
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
0.12016E+00 0.79776E-01 0.97128E-01 0.10947E+00

0.73785E-01 0.28846E+00 0.92916E-01 0.45525E-01
0.62271E+00 0.20444E+00 0.11713E+00 0.40815E-01
0.34893E-02 0.27090E-02 0.83136E-05 0.36914E-07
0.22817E-01 0.55627E-01 0.93253E-01 0.12276E+00
0.87401E-01 0.34381E+00 0.11091E+00 0.54343E-01
0.27292E+02 0.36753E+01 0.12561E+01 0.33247E+00
0.39922E-01 0.78794E-02 0.74956E-04 0.67928E-06
0.22817E-01 0.55627E-01 0.93253E-01 0.12276E+00
0.87401E-01 0.34381E+00 0.11091E+00 0.54343E-01
0.11148E+00 0.24142E+00 0.32122E+00 0.22123E+00
0.26030E-01 0.20308E-01 0.54877E-04 0.19423E-06
0.51580E-03 0.88941E-02 0.35912E-01 0.97997E-01
0.10284E+00 0.42518E+00 0.13880E+00 0.68013E-01
0.21613E+03 0.27144E+02 0.89445E+01 0.22575E+01
0.25312E+00 0.47763E-01 0.39537E-03 0.28558E-05
MOLE FRACTION
------------0.00113
0.70285
0.08652
0.05321
0.03421
0.01733
0.01664
0.05986
0.01756
0.00900
0.00170
FLASH CALCULATIONS:
D-262
0.18174E-01 0.40036E-02 0.55390E-04 0.10439E-05
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
256.0 DEGREES F
OBSERVED PSAT
CALCULATED PSAT
=
=
5000.0 PSIG (DEWPT)

5000.0 PSIG (DEWPT)
CALCULATED ZSAT
0.9196
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
OBSERVED API GRAV.

OBSERVED TOTAL GOR
=
=
=
=
=
75.0 DEGREES F
0.0 PSIG
0.7409 RB/MSCF
51.7
52.2
5727.20 SCF/STB
5718.73 SCF/STB
174.86 STB/MMSCF
PRES
-----PSIG
-----450.0
100.0
0.0
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0.
4310.
5277.
5267.
75.0
0.
195.
223.
221.
75.0
0.
231.
227.
231.
PRES
-----PSIG
-----450.0
TEMP
-----F
-----75.0
LIQ. MOLE FRACTION

-----------------DATA
CALC
-------- -------0.0000
0.2012
SEP FVF
--------------DATA
CALC
----------0.0000 1.2219
0.0000 1.1324
0.0000 1.0000
LIQ. Z-FACTOR
-----------------DATA
CALC
-------- -------0.0000
0.1635
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.6704
0.0000 0.8624
0.0000 1.5571
LIQ. DENSITY,GM/CC
-----------------DATA
CALC
-------- -------0.0000
0.7251
Landmark - R2003.4
Example Problems
100.0
75.0
0.0000
0.1676
0.0000
0.0449
0.0000
0.0
75.0
0.0000
0.1326
0.0000
0.0064
0.0000
-----------0STAGE 1
ZZ = 0.11316E-02 0.70285E+00 0.86520E-01 0.53206E-01
0.17329E-01 0.16636E-01 0.59863E-01 0.17555E-01
0.16985E-02
ZY = 0.90147 YY = 0.13994E-02 0.84895E+00 0.88121E-01 0.41608E-01
0.31306E-02 0.14054E-02 0.11830E-02 0.50285E-05
0.00000E+00
ZX = 0.16350 XX = 0.68525E-04 0.12278E+00 0.80162E-01 0.99254E-01
0.73701E-01 0.77108E-01 0.29285E+00 0.87237E-01
0.84425E-02
KV = 0.20422E+02 0.69145E+01 0.10993E+01 0.41921E+00
0.42478E-01 0.18227E-01 0.40397E-02 0.57642E-04
0.00000E+00
0STAGE 2
ZZ = 0.68525E-04 0.12278E+00 0.80162E-01 0.99254E-01
0.73701E-01 0.77108E-01 0.29285E+00 0.87237E-01
0.84425E-02
ZY = 0.95826 YY = 0.38801E-03 0.62024E+00 0.20298E+00 0.11881E+00
0.87464E-02 0.36659E-02 0.27719E-02 0.80991E-05
0.25159E-15
ZX = 0.04489 XX = 0.45682E-05 0.23193E-01 0.55575E-01 0.95339E-01
0.86704E-01 0.91810E-01 0.35092E+00 0.10470E+00
0.10133E-01
KV = 0.84939E+02 0.26742E+02 0.36523E+01 0.12462E+01
0.10088E+00 0.39930E-01 0.78990E-02 0.77356E-04
0.24830E-13
0STAGE 3
ZZ = 0.45682E-05 0.23193E-01 0.55575E-01 0.95339E-01
0.86704E-01 0.91810E-01 0.35092E+00 0.10470E+00
0.10133E-01
ZY = 0.98291 YY = 0.21738E-04 0.10903E+00 0.23321E+00 0.31979E+00
0.61409E-01 0.27492E-01 0.20912E-01 0.53763E-04
0.81977E-15
ZX = 0.00642 XX = 0.31837E-07 0.51367E-03 0.86439E-02 0.36037E-01
0.93387E-01 0.10880E+00 0.43811E+00 0.13235E+00
0.12810E-01
KV = 0.68279E+03 0.21227E+03 0.26979E+02 0.88741E+01
0.65758E+00 0.25268E+00 0.47732E-01 0.40623E-03
0.63997E-13
---------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
0.34215E-01
0.89987E-02
0.14202E-01
0.45003E-07
0.11368E+00
0.44727E-01
0.12493E+00
0.10062E-05
0.11368E+00
0.44727E-01
0.42393E-01
0.35221E-07
0.12795E+00
0.53681E-01
0.33134E+00
0.65612E-06
0.12795E+00
0.53681E-01
0.22808E+00
0.18616E-06
0.10149E+00
0.67863E-01
0.22473E+01
0.27432E-05
MOLE FRACTION
------------0.00121
0.73374
0.08649
0.05211
0.03223
0.01577
0.01455
0.04774
0.01083
0.00515
0.00019
FLASH CALCULATIONS:
R2003.4 - Landmark
0.7467
0.7693
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
256.0 DEGREES F
OBSERVED PSAT
CALCULATED PSAT
=
=
4000.0 PSIG (DEWPT)

4000.0 PSIG (DEWPT)
CALCULATED ZSAT
0.8378
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
OBSERVED API GRAV.

OBSERVED TOTAL GOR
=
=
=
=
=
75.0 DEGREES F
0.0 PSIG
0.8129 RB/MSCF
55.4
56.0
8399.00 SCF/STB
8331.60 SCF/STB
120.02 STB/MMSCF
D-263
Example Problems
PRES
-----PSIG
-----450.0
100.0
0.0
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0.
6205.
7828.
7816.
75.0
0.
213.
248.
246.
75.0
0.
270.
263.
270.
SEP FVF
--------------DATA
CALC
----------0.0000 1.2595
0.0000 1.1579
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.6742
0.0000 0.8733
0.0000 1.5940
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------450.0
75.0
0.0000
0.1560
0.0000
0.1547
0.0000
0.7072
100.0
75.0
0.0000
0.1294
0.0000
0.0423
0.0000
0.7299
0.0
75.0
0.0000
0.1003
0.0000
0.0060
0.0000
0.7541
-----------0STAGE 1
ZZ = 0.12070E-02 0.73374E+00 0.86485E-01 0.52107E-01 0.32231E-01
0.15768E-01 0.14554E-01 0.47741E-01 0.10835E-01 0.51466E-02
0.18504E-03
ZY = 0.90029 YY = 0.14170E-02 0.84649E+00 0.87647E-01 0.42765E-01 0.15397E-01
0.34967E-02 0.15544E-02 0.12235E-02 0.41383E-05 0.33090E-07
0.00000E+00
ZX = 0.15474 XX = 0.71057E-04 0.12375E+00 0.80203E-01 0.10265E+00 0.12330E+00
0.82152E-01 0.84881E-01 0.29940E+00 0.69428E-01 0.32989E-01
0.11861E-02
KV = 0.19942E+02 0.68405E+01 0.10928E+01 0.41663E+00 0.12488E+00
0.42564E-01 0.18312E-01 0.40864E-02 0.59606E-04 0.10030E-05
0.00000E+00
0STAGE 2
ZZ = 0.71057E-04 0.12375E+00 0.80203E-01 0.10265E+00 0.12330E+00
0.82152E-01 0.84881E-01 0.29940E+00 0.69428E-01 0.32989E-01
0.11861E-02
ZY = 0.95720 YY = 0.39382E-03 0.61353E+00 0.20110E+00 0.12222E+00 0.46043E-01
0.97900E-02 0.40608E-02 0.28603E-02 0.66299E-05 0.25880E-07
0.37628E-16
ZX = 0.04233 XX = 0.47267E-05 0.23095E-01 0.55358E-01 0.98624E-01 0.13917E+00
0.97023E-01 0.10149E+00 0.36034E+00 0.83694E-01 0.39768E-01
0.14298E-02
KV = 0.83319E+02 0.26565E+02 0.36328E+01 0.12392E+01 0.33083E+00
0.10090E+00 0.40012E-01 0.79379E-02 0.79215E-04 0.65076E-06
0.26316E-13
0STAGE 3
ZZ = 0.47267E-05 0.23095E-01 0.55358E-01 0.98624E-01 0.13917E+00
0.97023E-01 0.10149E+00 0.36034E+00 0.83694E-01 0.39768E-01
0.14298E-02
ZY = 0.98211 YY = 0.20899E-04 0.10100E+00 0.21805E+00 0.31531E+00 0.24382E+00
0.69033E-01 0.30815E-01 0.21909E-01 0.44549E-04 0.13905E-06
0.12240E-15
ZX = 0.00605 XX = 0.31089E-07 0.47573E-03 0.81197E-02 0.35708E-01 0.10879E+00
0.10515E+00 0.12201E+00 0.45860E+00 0.10798E+00 0.51315E-01
0.18450E-02
KV = 0.67223E+03 0.21231E+03 0.26854E+02 0.88301E+01 0.22412E+01
0.65652E+00 0.25256E+00 0.47773E-01 0.41256E-03 0.27097E-05
0.66343E-13
---------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
MOLE FRACTION
------------0.00128
0.76750
0.08687
0.05061
0.02955
0.01356
0.01166
0.03297
0.00459
0.00141
0.00001
FLASH CALCULATIONS:
D-264
TEMPERATURE
OBSERVED PSAT
CALCULATED PSAT
=
=
NEWTON-RAPHSON
NEWTON-RAPHSON
256.0 DEGREES F
3000.0 PSIG (DEWPT)
3000.0 PSIG (DEWPT)
Landmark - R2003.4
Example Problems
CALCULATED ZSAT
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
1.0185 RB/MSCF
OBSERVED API GRAV.

OBSERVED TOTAL GOR
=
=
=
=
=
60.4
60.3
14396.60 SCF/STB
14352.94 SCF/STB
69.67 STB/MMSCF
PRES
-----PSIG
-----450.0
100.0
0.0
0.8192
75.0 DEGREES F
0.0 PSIG
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0. 10453. 13774. 13745.
75.0
0.
232.
290.
278.
75.0
0.
330.
333.
330.
SEP FVF
--------------DATA
CALC
----------0.0000 1.3150
0.0000 1.1980
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.6796
0.0000 0.8889
0.0000 1.6444
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------450.0
75.0
0.0000
0.1045
0.0000
0.1455
0.0000
0.6875
100.0
75.0
0.0000
0.0864
0.0000
0.0396
0.0000
0.7109
0.0
75.0
0.0000
0.0649
0.0000
0.0056
0.0000
0.7368
-----------0STAGE 1
ZZ = 0.12788E-02 0.76750E+00 0.86871E-01 0.50613E-01 0.29550E-01
0.13563E-01 0.11655E-01 0.32974E-01 0.45857E-02 0.14069E-02
0.67563E-05
ZY = 0.89859 YY = 0.14196E-02 0.84271E+00 0.87606E-01 0.44111E-01 0.17064E-01
0.40568E-02 0.17733E-02 0.12602E-02 0.26451E-05 0.45370E-08
0.00000E+00
ZX = 0.14549 XX = 0.72199E-04 0.12309E+00 0.80568E-01 0.10632E+00 0.13653E+00
0.95012E-01 0.96324E-01 0.30470E+00 0.43854E-01 0.13462E-01
0.64645E-04
KV = 0.19663E+02 0.68462E+01 0.10874E+01 0.41491E+00 0.12498E+00
0.42697E-01 0.18410E-01 0.41359E-02 0.60316E-04 0.33703E-06
0.00000E+00
0STAGE 2
ZZ = 0.72199E-04 0.12309E+00 0.80568E-01 0.10632E+00 0.13653E+00
0.95012E-01 0.96324E-01 0.30470E+00 0.43854E-01 0.13462E-01
0.64645E-04
ZY = 0.95564 YY = 0.39392E-03 0.60281E+00 0.20053E+00 0.12620E+00 0.51105E-01
0.11378E-01 0.46383E-02 0.29391E-02 0.42560E-05 0.10781E-07
0.21526E-17
ZX = 0.03957 XX = 0.47669E-05 0.22542E-01 0.55424E-01 0.10215E+00 0.15444E+00
0.11254E+00 0.11554E+00 0.36795E+00 0.53044E-01 0.16283E-01
0.78195E-04
KV = 0.82636E+02 0.26742E+02 0.36180E+01 0.12355E+01 0.33091E+00
0.10110E+00 0.40144E-01 0.79878E-02 0.80236E-04 0.66209E-06
0.27529E-13
0STAGE 3
ZZ = 0.47669E-05 0.22542E-01 0.55424E-01 0.10215E+00 0.15444E+00
0.11254E+00 0.11554E+00 0.36795E+00 0.53044E-01 0.16283E-01
0.78195E-04
ZY = 0.98100 YY = 0.19095E-04 0.89453E-01 0.20039E+00 0.30605E+00 0.26438E+00
0.80771E-01 0.35849E-01 0.23062E-01 0.29126E-04 0.59710E-07
0.70064E-17
ZX = 0.00563 XX = 0.28447E-07 0.41335E-03 0.74832E-02 0.34716E-01 0.11808E+00
0.12305E+00 0.14190E+00 0.48201E+00 0.70577E-01 0.21668E-01
0.10405E-03
KV = 0.67124E+03 0.21641E+03 0.26778E+02 0.88157E+01 0.22390E+01
0.65642E+00 0.25265E+00 0.47846E-01 0.41268E-03 0.27556E-05
0.67334E-13
---------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
R2003.4 - Landmark
MOLE FRACTION
------------0.00128
0.77995
0.08897
0.05095
0.02874
0.01248
0.01004
D-265
Example Problems
C8
C14
C20
C34
0.02509
0.00214
0.00036
0.00000
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
OBSERVED PSAT
CALCULATED PSAT
=
=
2100.0 PSIG (DEWPT)

2100.0 PSIG (DEWPT)
CALCULATED ZSAT
0.8367
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
1.4566 RB/MSCF
OBSERVED API GRAV.

OBSERVED TOTAL GOR
=
=
=
=
=
64.6
64.0
20564.20 SCF/STB
20503.80 SCF/STB
48.77 STB/MMSCF
PRES
-----PSIG
-----450.0
100.0
0.0
256.0 DEGREES F
75.0 DEGREES F
0.0 PSIG
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0. 14472. 19863. 19808.
75.0
0.
250.
305.
309.
75.0
0.
387.
396.
387.
SEP FVF
--------------DATA
CALC
----------0.0000 1.3687
0.0000 1.2366
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.6851
0.0000 0.9038
0.0000 1.6805
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------450.0
75.0
0.0000
0.0803
0.0000
0.1404
0.0000
0.6722
100.0
75.0
0.0000
0.0660
0.0000
0.0381
0.0000
0.6962
0.0
75.0
0.0000
0.0480
0.0000
0.0054
0.0000
0.7232
-----------0STAGE 1
ZZ = 0.12818E-02 0.77995E+00 0.88973E-01 0.50948E-01 0.28740E-01
0.12477E-01 0.10036E-01 0.25091E-01 0.21441E-02 0.35851E-03
0.31500E-06
ZY = 0.89676 YY = 0.13874E-02 0.83730E+00 0.89527E-01 0.45741E-01 0.18414E-01
0.44699E-02 0.19117E-02 0.12497E-02 0.16139E-05 0.00000E+00
0.00000E+00
ZX = 0.14041 XX = 0.71757E-04 0.12338E+00 0.82628E-01 0.11055E+00 0.14696E+00
0.10415E+00 0.10305E+00 0.29806E+00 0.26675E-01 0.44633E-02
0.39216E-05
KV = 0.19335E+02 0.67863E+01 0.10835E+01 0.41375E+00 0.12530E+00
0.42917E-01 0.18551E-01 0.41927E-02 0.60503E-04 0.00000E+00
0.00000E+00
0STAGE 2
ZZ = 0.71757E-04 0.12338E+00 0.82628E-01 0.11055E+00 0.14696E+00
0.10415E+00 0.10305E+00 0.29806E+00 0.26675E-01 0.44633E-02
0.39216E-05
ZY = 0.95409 YY = 0.38086E-03 0.58973E+00 0.20339E+00 0.13076E+00 0.55243E-01
0.12566E-01 0.50099E-02 0.29115E-02 0.26554E-05 0.36174E-08
0.13844E-18
ZX = 0.03811 XX = 0.46672E-05 0.22162E-01 0.56416E-01 0.10617E+00 0.16687E+00
0.12403E+00 0.12433E+00 0.36212E+00 0.32464E-01 0.54320E-02
0.47728E-05
KV = 0.81603E+02 0.26610E+02 0.36053E+01 0.12316E+01 0.33106E+00
0.10132E+00 0.40295E-01 0.80401E-02 0.81795E-04 0.66594E-06
0.29006E-13
0STAGE 3
ZZ = 0.46672E-05 0.22162E-01 0.56416E-01 0.10617E+00 0.16687E+00
0.12403E+00 0.12433E+00 0.36212E+00 0.32464E-01 0.54320E-02
0.47728E-05
ZY = 0.98018 YY = 0.17084E-04 0.80460E-01 0.18846E+00 0.29918E+00 0.27924E+00
0.89778E-01 0.39438E-01 0.23412E-01 0.18545E-04 0.20559E-07
0.45127E-18
ZX = 0.00543 XX = 0.25642E-07 0.36984E-03 0.70567E-02 0.34020E-01 0.12487E+00
0.13683E+00 0.15606E+00 0.48873E+00 0.44592E-01 0.74625E-02
0.65569E-05
KV = 0.66626E+03 0.21755E+03 0.26707E+02 0.87942E+01 0.22363E+01
0.65612E+00 0.25271E+00 0.47904E-01 0.41589E-03 0.27550E-05
D-266
Landmark - R2003.4
Example Problems
0.68824E-13
---------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
MOLE FRACTION
------------0.00123
0.77336
0.09381
0.05443
0.03086
0.01295
0.00987
0.02225
0.00116
0.00009
0.00000
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
OBSERVED PSAT
CALCULATED PSAT
=
=
1200.0 PSIG (DEWPT)

1200.0 PSIG (DEWPT)
CALCULATED ZSAT
0.8802
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
2.6533 RB/MSCF
OBSERVED API GRAV.

OBSERVED TOTAL GOR
=
=
=
=
=
67.5
66.9
22972.40 SCF/STB
23520.92 SCF/STB
42.52 STB/MMSCF
PRES
-----PSIG
-----450.0
100.0
0.0
256.0 DEGREES F
75.0 DEGREES F
0.0 PSIG
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0. 15687. 22121. 22698.
75.0
0.
274.
370.
354.
75.0
0.
469.
482.
469.
SEP FVF
--------------DATA
CALC
----------0.0000 1.4469
0.0000 1.2920
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.6939
0.0000 0.9260
0.0000 1.7162
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------450.0
75.0
0.0000
0.0765
0.0000
0.1367
0.0000
0.6583
100.0
75.0
0.0000
0.0620
0.0000
0.0371
0.0000
0.6834
0.0
75.0
0.0000
0.0430
0.0000
0.0053
0.0000
0.7124
-----------0STAGE 1
ZZ = 0.12290E-02 0.77336E+00 0.93811E-01 0.54429E-01 0.30857E-01
0.12945E-01 0.98698E-02 0.22251E-01 0.11631E-02 0.89250E-04
0.14524E-07
ZY = 0.89373 YY = 0.13250E-02 0.82707E+00 0.94347E-01 0.49097E-01 0.20170E-01
0.48187E-02 0.19792E-02 0.11871E-02 0.97211E-06 0.00000E+00
0.00000E+00
ZX = 0.13667 XX = 0.70068E-04 0.12447E+00 0.87329E-01 0.11883E+00 0.15995E+00
0.11111E+00 0.10518E+00 0.27669E+00 0.15201E-01 0.11673E-02
0.18997E-06
KV = 0.18910E+02 0.66446E+01 0.10804E+01 0.41318E+00 0.12610E+00
0.43369E-01 0.18818E-01 0.42903E-02 0.63952E-04 0.00000E+00
0.00000E+00
0STAGE 2
ZZ = 0.70068E-04 0.12447E+00 0.87329E-01 0.11883E+00 0.15995E+00
0.11111E+00 0.10518E+00 0.27669E+00 0.15201E-01 0.11673E-02
0.18997E-06
ZY = 0.95168 YY = 0.35266E-03 0.56682E+00 0.21069E+00 0.13987E+00 0.60688E-01
0.13608E-01 0.52068E-02 0.27638E-02 0.15780E-05 0.96346E-09
0.73215E-20
ZX = 0.03712 XX = 0.43990E-05 0.21682E-01 0.58662E-01 0.11394E+00 0.18302E+00
0.13377E+00 0.12841E+00 0.34034E+00 0.18733E-01 0.14386E-02
0.23412E-06
R2003.4 - Landmark
D-267
Example Problems
KV = 0.80169E+02
0.10173E+00
0.31273E-13
0STAGE 3
ZZ = 0.43990E-05
0.13377E+00
0.23412E-06
ZY = 0.97933 YY = 0.14251E-04
0.98106E-01
0.23942E-19
ZX = 0.00532 XX = 0.21639E-07
0.14961E+00
0.33813E-06
KV = 0.65861E+03
0.65574E+00
0.70806E-13
---------------------
COMPONENT
--------N2
C1
C2
C3
NC4
NC5
C6
C8
C14
C20
C34
0.26143E+02 0.35916E+01 0.12275E+01 0.33159E+00

0.40548E-01 0.81207E-02 0.84240E-04 0.66973E-06
0.21682E-01 0.58662E-01 0.11394E+00 0.18302E+00
0.12841E+00 0.34034E+00 0.18733E-01 0.14386E-02
0.69757E-01 0.17584E+00 0.29473E+00 0.29631E+00
0.42149E-01 0.23086E-01 0.11396E-04 0.56672E-08
0.32269E-03 0.66021E-02 0.33616E-01 0.13269E+00
0.16674E+00 0.48130E+00 0.27050E-01 0.20777E-02
0.21617E+03 0.26634E+02 0.87675E+01 0.22331E+01
0.25279E+00 0.47966E-01 0.42131E-03 0.27276E-05
MOLE FRACTION
------------0.00115
0.74913
0.09916
0.06033
0.03621
0.01549
0.01176
0.02568
0.00104
0.00005
0.00000
FLASH CALCULATIONS:
NEWTON-RAPHSON
NEWTON-RAPHSON
TEMPERATURE
256.0 DEGREES F
OBSERVED PSAT
CALCULATED PSAT
=
=
700.0 PSIG (DEWPT)

700.0 PSIG (DEWPT)
CALCULATED ZSAT
STANDARD TEMP
STANDARD PRES
=
=
CALCULATED GAS FVF
4.7230 RB/MSCF
OBSERVED API GRAV.

OBSERVED TOTAL GOR
=
=
=
=
=
68.6
68.3
20400.00 SCF/STB
19823.30 SCF/STB
50.45 STB/MMSCF
PRES
-----PSIG
-----450.0
100.0
0.0
0.9141
75.0 DEGREES F
0.0 PSIG
TEMP
GOR (SEP)
GOR (ST)
------ --------------- --------------F
DATA
CALC
DATA
CALC
------ ----------- ----------75.0
0. 12336. 19475. 18865.
75.0
0.
299.
367.
404.
75.0
0.
555.
558.
555.
SEP FVF
--------------DATA
CALC
----------0.0000 1.5292
0.0000 1.3495
0.0000 1.0000
GAS GRAVITY
-------------DATA
CALC
---------0.0000 0.7027
0.0000 0.9478
0.0000 1.7409
PRES
TEMP
LIQ. MOLE FRACTION
LIQ. Z-FACTOR
LIQ. DENSITY,GM/CC
------ ------ ------------------ ------------------ -----------------PSIG
F
DATA
CALC
DATA
CALC
DATA
CALC
------ ------ -------- -------- -------- -------- -------- -------450.0
75.0
0.0000
0.0968
0.0000
0.1342
0.0000
0.6495
100.0
75.0
0.0000
0.0775
0.0000
0.0365
0.0000
0.6759
0.0
75.0
0.0000
0.0509
0.0000
0.0053
0.0000
0.7075
-----------0STAGE 1
ZZ = 0.11501E-02 0.74913E+00 0.99157E-01 0.60333E-01 0.36209E-01
0.15491E-01 0.11758E-01 0.25682E-01 0.10384E-02 0.48430E-04
0.30733E-08
ZY = 0.89059 YY = 0.12661E-02 0.81602E+00 0.99862E-01 0.53040E-01 0.21741E-01
0.49794E-02 0.19684E-02 0.11185E-02 0.73892E-06 0.54602E-09
0.67778E-20
ZX = 0.13418 XX = 0.68106E-04 0.12529E+00 0.92582E-01 0.12834E+00 0.17114E+00
D-268
Landmark - R2003.4
0STAGE
ZY = 0.94922
ZX = 0.03652
0STAGE
ZY = 0.97873
ZX = 0.00528
R2003.4 - Landmark
Example Problems
0.11353E+00
0.31736E-07
KV = 0.18590E+02
0.43861E-01
0.21357E-12
ZZ = 0.68106E-04
0.11353E+00
0.31736E-07
YY = 0.32467E-03
0.14133E-01
0.13227E-20
XX = 0.41030E-05
0.13832E+00
0.39652E-07
KV = 0.79131E+02
0.10217E+00
0.33358E-13
ZZ = 0.41030E-05
0.13832E+00
0.39652E-07
YY = 0.11937E-04
0.10282E+00
0.43436E-20
XX = 0.18244E-07
0.15683E+00
0.60328E-07
KV = 0.65427E+03
0.65561E+00
0.72000E-13
0.10306E+00 0.25477E+00 0.10716E-01 0.50010E-03

0.65133E+01 0.10786E+01 0.41328E+00 0.12703E+00
0.19098E-01 0.43902E-02 0.68957E-04 0.10918E-05
0.12529E+00 0.92582E-01 0.12834E+00 0.17114E+00
0.10306E+00 0.25477E+00 0.10716E-01 0.50010E-03
0.54283E+00 0.21882E+00 0.15046E+00 0.65626E-01
0.52015E-02 0.26045E-02 0.11557E-05 0.42304E-09
0.21126E-01 0.61090E-01 0.12282E+00 0.19746E+00
0.12748E+00 0.31768E+00 0.13388E-01 0.62485E-03
0.25695E+02 0.35819E+01 0.12250E+01 0.33234E+00
0.40803E-01 0.81986E-02 0.86317E-04 0.67702E-06
0.21126E-01 0.61090E-01 0.12282E+00 0.19746E+00
0.12748E+00 0.31768E+00 0.13388E-01 0.62485E-03
0.61097E-01 0.16626E+00 0.29397E+00 0.30987E+00
0.43329E-01 0.22637E-01 0.86458E-05 0.25786E-08
0.28457E-03 0.62519E-02 0.33585E-01 0.13885E+00
0.17135E+00 0.47152E+00 0.20365E-01 0.95066E-03
0.21470E+03 0.26594E+02 0.87530E+01 0.22316E+01
0.25287E+00 0.48008E-01 0.42454E-03 0.27124E-05
D-269
Example Problems
D-270
Landmark - R2003.4
Appendix
E
References
1. Katz, D.L., and Firoozabadi, A.: "Predicting Phase Behavior of
Condensate / Crude-Oil Systems Using Methane Interaction
Coefficients," J. Pet Tech, (Nov. 1978), 1649-1655; Trans., AIME, 228.
2. Lohrenz, J., Bray, B.G. , and Clark, C. R.: "Calculating Viscosities of
Reservoir Fluids From Their Compositions, " J. Pet Tech. (Oct. 1964),
1171-1176.
3. Whitson, C. H.: "Characterizing Hydrocarbon Plus Fractions," Soc. Pet.
Eng. J. (Aug. 1983), 683-694.
4. Nghiem, L.X., and Li, Y.K.: "Effects of Phase Behavior on CO2
Displacement Efficiency at Low Temperatures: Model Studies with an
Equation of State," SPE Res.Eng. (July, 1986) Vol. 1 , No. 4, 414-422.
5. Reid, R.C., Prausnitz, J.M., and Sherwood, T.K.: The Properties of
Gases and Liquids. McGraw-Hill Book Company, Third Edition, 1977.
6. Passut, C.A. and Danner, R. P.: I & EC Process Design and
Development, 11, 543 (1972).
7. Hwang, P.K. and Daubert, T.E.: I & EC Process Design and
Development, 13, 193 (1974).
8. Edminster, W.C. and Lee, B.I.: Applied Hydrocarbon
Thermodynamics, Vol. 1, Second Edition, Gulf Publishing Co., 1984.
9. Kesler, M.G. and Lee, B. I.: " Hydrocarbon Processing", 55(3), 153,
(1976).
10. Pedersen, K. S., Fredenslund, A., and Christensen, P.L.: "Viscosity of
Crude Oils," Chem. Eng. Sci., 39, pp. 1011-1016 (1984).
11. Pedersen, K.S. and Fredenslund, A.: "An Improved Corresponding
States Model for the Prediction of Oil and Gas Viscosities and Thermal
Conductivities," Chem. Eng. Sci., pp. 182-187 (1987).
12. Twu, C.H.: "Internally Consistent Correlation for Predicting Liquid
Viscosities of Petroleum Fractions," Ind. Eng. Chem. Process Des. Dev.,
(1985) 24, 1287-1293.
R2003.4 - Landmark
E-269
References
13. Twu, C.H.: "Generalized Method for Predicting Viscosities of

Petroleum Fractions," AICHE J., (Dec. 1986) 32, 2091-2094.
14. Malinin, S.D. and Savelyeva, N.I.: "The Solubility of CO2 in NaCl
and CaCl2 Solutions at 25, 50, and 75 Under Elevated CO2
Pressures," Geochemistry International, (1972) 410-418.
15. Malinin, S.D. and Kurovskaya, N.A.: "Solubility of CO2 in Chloride
Solutions at Elevated Temperatures and CO2 Pressures," Geochemistry
International, (1975) 199-201.
16. McRee, B.C.: "CO2 : How It Works, Where It Works," Petroleum
Engineers, (Nov. 1977) 52-63.
17. Rowe, A.M. and Chou, J.C.: "Pressure-Volume-TemperatureConcentration Relation of Aqueous NaCl Solutions," J. of Chemical and
Engineering Data, Vol. 15, No. 1 (1970) 61-66.
18. Parkinson, W.J. and De Nevers, N.: "Partial Model Volume of Carbon
Dioxide in Water Solutions," I & EC Fundamentals, Vol. 8, No. 4 (Nov.
1969) 709-713.
19. Sayegh, S.G. and Najman, J.: "Phase Behavior Measurements of CO2 SO2 -Brine Mixtures," The Canadian Journal of Chemical Engineering, Vol.
65 (April 1987)314-320.
20. Osif, T.L.: "The Effects of Salt, Gas, Temperature, and Pressure on the
Compressibility of Water," SPE Reservoir Engineering, Vol. 3, No. 1 (Feb.
1988) 175-181.
21. Kestin, J., Khalifa, H.E., Abe, Y, Grimes, C.E., Sookiazian, H. and
Wakeham, W.A.: "Effect of Pressure on the Viscosity of Aqueous NaCl
Solutions in the Temperature Range 20-150 C", J. of Chemical and
Engineering Data, Vol. 23, No. 4 (1978) 328-336.
22. Wiebe, R: "The Binary System Carbon Dioxide-Water Under Pressure,"
Chemical Reviews, 29 (1941) 475-481.
E-270
Landmark - R2003.4
000000Keyword
Index
C
CCEXP 3-44
CCEXPX 9-133
CCEXPY 9-133
CCEXPZ 9-133
CO2COR 2-20
CO2TAB 3-84
COMP 5-107
COMPONENTS 2-8
CVDEP 3-48
CVDEPX 9-133
CVDEPY 9-133
CVDEPZ 9-133
E
ENDEOS 2-23
ENDREG 5-111
ENTHL 3-64
ENTHV 3-64
ENVELOPE 3-62
ENVPT 3-77
EOS 2-6
EOS Data Card 2-6
G
GIBBS 8-125
H
HIDEAL 2-22
DBUGF 8-130
DBUGS 8-130
DIFF 3-56
DIFFX 9-133
DIFFY 9-133
DIFFZ 9-133
DISTIL 3-69
DJK 2-12
DJKCOR 2-13
DPFAC 8-129
DPMAX 8-129
DPMIN 8-129
DPMXS 8-126
DRIFT 8-128
DXMXF 8-128
DXMXS 8-126
IMAX 5-106
R2003.4 - Landmark
K
KNTMXF 8-128
KNTMXS 8-126
KVCOR 2-17
KVFILE 2-25
L
LBC 8-131
LIQDEN 3-36
Keyword Index-271
Keyword Index
MCSVAP 3-87
MCVAP 3-59
TOLKS 8-126
TOLPS 8-126
TOLS 8-126
TOLXF 8-128
TOLXS 8-126
NEWTON 8-125
Output 2-25
VARIABLE 5-105
VISC 3-42
VISK 2-14, 2-15
VISKJ 2-15
VISOIL PEDERSON 2-14
VISPE 8-131
VP 3-38
PROPERTIES 2-9
PSAT 3-40
PSATW 3-67
PVTFILE 2-24
WATPRP 3-66
WINOIL 2-25
Z
R
REGRESS 5-105
RPS 8-131
ZFACTOR 3-34
ZGRAD 3-80
ZGRADX 9-133
ZGRADY 9-133
ZGRADZ 9-133
S
SEP 4-98
SEPARATOR 4-95
SPLIT 7-118
SS 8-125
SWELL 3-54
SWELLLY 9-133
SWELLX 9-133
SWELLZ 9-133
T
THERMAL 2-26
TOLF 8-128
TOLKF 8-128
Keyword Index-272
Landmark - R2003.4
000000Subject Index
B
binary interaction coefficients
how specified 2-12
input in thermal option 2-26
bounded variables
how established B-149
bubble point
how calculated 3-40
use in phase envelope calculation 3-62
bubble point pressure
of oil in the presence of water 3-67
C
carbon dioxide
water saturation 3-84
carbon dioxide saturated water
specifying properties for 2-18
carbon dioxide solubility 2-18
complete phase envelope
calculation of 3-77
component characteristics
how specified 2-9
component identification codes 2-5
component names
how specified 2-8
components
pseudo 6-113
composition
alternative specification 9-133
expansion of 3-43
R2003.4 - Landmark
hydrocarbon 3-79
constant composition
in multiple contact vaporization 3-59
constant composition expansion procedure 343
constant volume depletion
how specified 3-48
corresponding states principle 2-15
D
data
how input 1-2
overview for DESKTOP-PVT 1-1
data sets
how handled 3-33
density
of liquid 3-36
of water 3-66
depth
effect on composition 3-79
DESKTOP-PVT
purpose of 1-1
dew point
how calculated 3-40
use in phase envelope calculation 3-62
differential expansion
how specified 3-55
distillation test 2-17
how specified 3-69
E
eigenvalues A-141
enthalpy
of ideal gas state 2-22
Subject-273
Subject
of water 3-66
equation of state
end of property data 2-23
how specified 2-6
properties
how adjusted 5-103
types defined 2-5
use to predict PVT properties 2-5
expansion
differential 3-55
expansion test
setting tolerances 8-129
H
heavy component composition
variations 3-79
heavy fractions
characterization of 7-117
example 7-123
how grouped 2-5
hydrocarbon composition
variation with depth 3-79
I
F
flash calculation
pressure intervals 8-129
selection of alternative methods 8-125
specifying output 8-130
tolerances 8-128
fluid properties
how defined 2-5
fluid samples
variation in composition 3-33
fluid viscosity
calculation methods 8-131
fluids
type allowed 1-1
formation volume factor 2-18
FORTRAN file assignments 1-3
free field input 1-2
fugacity coefficient
of water 3-66
G
gas
z-factor 3-33
Gauss-Newton minimization A-139
advantages of A-140
disadvantages of A-141
Gibbs energy minimization 8-125
Subject-274
ideal gas state enthalpy 2-22

input data
how formatted 1-2
K
Kestin et al. correlation 2-20
K-values
specifying for components 2-17
writing output for 2-25
L
laboratory procedures
how simulated 3-33
least-squares function
unconstrained minimum of A-137
least-squares method A-142
liquid
water properties 3-66
liquid density 3-36
liquid viscosity
how to specify 3-42
Lohrenz, Bray, and Clark correlation 3-42
alternatives to 2-15
Lohrenz, Bray, and Clark viscosity correlation
8-131
Landmark - R2003.4
M
mathematical models
how to develop 1-1
minimization variables
bounds of B-149
mixing rules 2-12
multiple contact steam vaporization test 3-86
multiple contact vaporization test
how specified 3-59
multistage surface separation facilities
how modeled 4-95
N
near-critical reservoirs 3-79
Newton- Raphson method 8-125
nonlinear regression
control parameters 5-106
how used 5-103
nonlinear regression package 1-1
Subject
pressure
bubble point of oil 3-67
saturation 3-40
vapor 3-38
production
how to analyze 1-1
properties
carbon dioxide saturated water 3-84
equation of state 5-103
of water 3-66
writing output for 2-24
properties data 2-9
properties table 2-9
PSAT 3-40
pseudo components
as composition output 3-59
pseudoization
how specified 6-113
PVT properties
how generated 1-1
how predicted 2-5
R
O
oil-cycling process 3-59
output files
how to write for PVT properties 2-24
writing for K-values 2-25
P
Passut-Danner 2-22
Pedersen et al. viscosity correlation 8-131
how specified 2-15
Peng-Robinson equation of state 2-5, 2-6
phase behavior calculation
default values 8-125
phase envelope
calculation of 3-62
complete 3-77
predictive mode
how used 1-1
R2003.4 - Landmark
real gas law 3-33

Redlich-Kwong equation of state 2-5, 2-6
regression
use in separator test 4-97
regression variables
how assigned 5-107
initial value 5-105
Reid, Prausnitz and Sherwood 8-131
rotational discrimination
algorithm used A-144
method used A-142
S
salinity 2-18
saturation pressure
calculation defaults 8-125
how specified 3-40
in composition expansion procedure 3-43
saturation pressure calculation
Subject-275
Subject
tolerances 8-126
saturation pressure test
specifying output for 8-130
separator battery
how specified 4-95
separator test
how calculated 4-97
Soave-Redlich-Kwong equation of state 2-5, 26
steam vaporization test
multiple contact 3-86
sum-of-squares objective function A-139
surface separation facilities
how modeled 4-95
swelling test 3-54
T
ternary diagrams
how constructed 3-59
thermal option 2-26
Twu viscosity correlation 8-131
U
units
default 3-33
specifying for pressure and temp 3-33
VIP-ENCORE
using DESKTOP-PVT to generate data for
1-1
viscosity
fluid, calculation of 8-131
of CO2 saturated water 2-20
of liquid or vapor 3-42
of water 3-66
viscosity correlation 8-131
how specified 2-15
volume
constant volume depletion 3-48
W
water
how properties specified 3-66
water properties
warning 3-67
water viscosity 2-20
water-in-oil option
selection of 2-25
Whitsons method 7-117
Z
z-factor
of gas 3-33
Zudkevitch-Joffe-Redlich-Kwong equation of
state 2-5, 2-6
V
vapor pressure
of a pure component 3-38
vapor viscosity
how to specify 3-42
vaporization
multiple contact 3-59
vaporization test
multiple contact steam 3-86
variable boundaries
how established B-149
VIP-COMP
using DESKTOP-PVT data in 1-1
Subject-276
Landmark - R2003.4

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DESKTOP-PVTKeyword

Part No. 159678 R2003.4

Landmark Graphics Corporation

DESKTOP-PVT KEYWORD REFERENCE MANUAL

2.15 Thermal Option (THERMAL) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-26

Simulating Laboratory Measurements

Simulating Multistage Separators

Automatic Parameter Adjustment

DESKTOP-PVT KEYWORD REFERENCE MANUAL

5.2 EOS Property Adjustment (REGRESS) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-105

Heavy Fraction Characterization

DESKTOP-PVT KEYWORD REFERENCE MANUAL

The Establishment of Bounds on Variables

One-Dimensional Search Procedure

About This Manual

Simulating Laboratory Measurement.

Simulating Multistage Separators.

Automatic Parameter Adjustment.

Heavy Fraction Characterization.

About This Manual

DESKTOP-PVT KEYWORD REFERENCE MANUAL

DESKTOP-PVT Users Manual. Characterizing equations of state for

1.1 Overview of the Data

DESKTOP-PVT Keyword Reference Manual

1.2 Free Field Input

DESKTOP-PVT Keyword Reference Manual

1.3 FORTRAN File Assignments

Figure 1-1: DESKTOP-PVT I/O Structure

DESKTOP-PVT Keyword Reference Manual

DESKTOP-PVT KEYWORD REFERENCE MANUAL

2.2 Equation of State (EOS)

Original Peng-Robinson equation-of-state.

Soave Redlich-Kwong equation-of-state.

Three-parameter version of RK, PR, PRORIG and

The original Peng-Robinson equation of state uses the same

DESKTOP-PVT KEYWORD REFERENCE MANUAL

if VSHFT is also included on the PROPERTIES card.

DESKTOP-PVT KEYWORD REFERENCE MANUAL

2.3 Component Names (Components)

Component name. An alphameric label containing up to 6 characters. Using a name contained in

Number of volatile components. Use only in

Define the components in a fluid system that contains carbon dioxide,

DESKTOP-PVT KEYWORD REFERENCE MANUAL

2.4 Component Characteristics (PROPERTIES)

cmpi mwi tci pci zci wi

Alpha label indicating that the units of all temperature

Degrees Fahrenheit, F. This is the

DESKTOP-PVT KEYWORD REFERENCE MANUAL

Alpha label indicating that the units of the critical

Psia. This the default.

Component name for component i. Must be identical

The molecular weight of component i.

Critical temperature of component i.

Critical pressure of component i.

Critical z-factor of component i. (This property

Acentric factor of component i.

constant in the original formulations of the equations

Parachor for component i, g

Dimensionless volume shift parameter. (This property