SOLUTIONS AND COLLOIDS

PAPERS)

(AKU PAST

1. Which of the following is not property of colloidal solution?

2015]

[MAY

A. They exhibit Tyndale effect

B. they form heterogeneous mixture

C. they are invisible to naked eye

paper

D. they can be easily filtered through filter

2. Which of the following is an example of immiscible solution in liquid phase?

[MAY 2015]
A. phenol-water system
C. Benzene-water system

B. nicotine-water system
D. triethylamine-water system

3. How many moles of sodium chloride are present in 300 cm3 of 2 M solution ?
[MAY 2014]
A. 0.15

B. 0.6

C. 150

D. 600

4. Toothpaste is an example of colloidal solution because its particles

2014]
A. cans scatter a beam of light

B. can be seen with naked eye

C. can form homogenous mixture

D. cannot pass through filter paper

5. Which of the following process is shown in the given figure?

2014]
A. effusion
B. osmosis
C. diffusion
D. Reverse osmosis

[MAY

[MAY

6. Which of the following characteristics of colloids distinguish it from solution?

[SEP 2014]
A. dispersion of light (Tyndale effect)

B. settlement of particles on standing

C. visibility of particles to naked eye

paper

D. filtration of particles through filter

7. The cryoscopic constant of solution is the ration of depression in freezing point to

[SEP 2014]
A. molarity
solvent

B. molality

C. mole fraction of solute D. mole fraction of

8. Which of the liquid is partially miscible in water?

A. ammonia

B. benzene

C. alcohol

[SEP 2014]
D. ether

9. The strength of solution containing 9gm of glucose per 500 cm 3 will be

2013]
A. 0.01

B. 0.1 M

C. 1.0 M

[MAY

D. 1.8 M

10. All of the following characteristics of oil make it insoluble in water except it is
[MAY 2013]
A. Hydrophilic in nature

B. less dense than water

C. non polar in nature

D. covalently bonded

11. Starch when dissolved in water forms a colloidal solution because particles of
starch [MAY 2013]
A. dissolves uniformly forming homogenous mixture
B. when filtered remain on filter paper
C. can be seen with naked eye in water
D. scatters the path of light rays
12. 10 % (w/v) solution of NaCl is equal to

[SEP 2013]

A. 90 gm of NaCl in 10 cm3 solution

B. 10 gm of NaCl in 90 cm3 solution

C. 10 gm of NaCl in 100 cm3 solution

D. 100 gm of NaCl in 10 cm3 solution

13. All of the followings liquids are immiscible in water except

[SEP 2013]

A. benzene
carbondisulphide

B. ethyl alchohal

C. tetrachloromethane

D.

14. What will happen to the vapor pressure and boiling point when the
concentration of non volatile solute is increased in solution?
[SEP 2013]

15. Which of the following shows

minimum Tyndale effect?
[MAY 2012]
A. Lyophilic
C. Hydrophobic

B. Lyophobic

D. THIXOTROPHIC

16. Which of the following is the elevation of boiling point for water?

[MAY 2012]

A. 0.52 Co kg mol-1 B. 0.86 Co kg mol-1 C. 1.04 Co kg mol-1 D. 1.15 Co kg mol-1

17. A doctor described a skin treatment by dissolving 2.45 10 -6 gms of herbal
powder in 1 kg of glycerin. Which of the following is the correct concentration of
herbal powder in glycerin in ppm? [SEP 2012]
A. 2.45 103

B. 2.45 10-3

C. 2.45 106

D. 2.45 10-6

18. 18 gm of glucose is dissolved in 1 kg of water in saucepan. Which of the

following is the expected temperature for water to boil (assuming 1 atm pressure)?
[SEP 2012]
A. 100 Co

B. 100.052 Co

C. 100.43 Co

D. 100.52Co

19. If the dispersed medium is colloidal system is taken as gas , then the system is
called [MAY 2011]
A. hydrosol B. Aquasol

C. Aerosol

D. benzosol

20. Which of the following one mole solution will have greatest osmotic pressure?
[MAY 2011]
A. KCl

B.CaCl2

C.HNO3

D. Sugar

21. The cryoscopic constant of solution is the ratio of depression in freezing point to
[MAY 2011]
A. molarity

B. molality

C. mole fraction of solute D. mole fraction of solvent

22. Two aq. Solutions A and B have been separated by semi permeable membrane
.If the vapor pressure of solution A is higher than that of B ,then water will
[SEP 2011]
A. flow from A to B
B. flow from B to A
C. flow at the same rate from A to B and B to A
D. not flow from A to B
23. Which of the following solution will have lowest freezing point?
[SEP 2011]
A. I M NaCl

B. I M Glucose

C. 0.1 M Na2SO4

D. 0.1 M Ca(NO3)2

24. In which of the following processes does salt react with water and liberate free
acid and base
[SEP 2011]
A. hydration

B. hydrolysis

C. nitration

D. solvation

25. Colloidal solutions are intermediate between true solutions and suspension.
These solutions are best purified by
[MAY 2010]
A. filtration

B. distillation

C. Crystallization

D. dialysis technique

26. When an animal bladder filled with sugar solution is put into water, the water
passes through the bladder and burst it. This happens due to
[MAY 2010]
A. osmotic pressure

B. atmospheric pressure

C. vapor pressure of water

D. polar nature of sugar molecules

27. Which of the following is balanced neutralization reaction that leads to the
formation of an acidic salt?
[SEP 2010]
A. HCl + NaOH
B. H2SO3 +NaOH

NaCl + H 2O
NaHSO 3 + H2O

C. H2SO4 + 2KOH

K 2SO4 + 2 H2O

D. H3PO4 + KOH

K 2HPO4 + 2 H2O

28. The boiling point of solution containing 1 gm of substance X in 50 gm of ether is

1k higher than that of pure ether .If the ebullioscopic constant of pure ether per Kg
is 2 then the molecular mass of X is
[SEP 2010]
A. 30

B. 40

C. 50

D. 140

29.How many grams of HCl are needed to prepare 5 M HCl solution in 1 liter ? [SEP
2010]
A. 3.65 10 gms

B. 1.82 102 gms C. 36.5 104 gms D. 1.82 105 gms

30. Which of the following is the colligative property of solution?

[SEP 2010]

A. internal energy B. internal pressure

pressure

D. vapor

C. Osmotic pressure

31. All of the following give an acidic solution in water except

2010]
A. AlCl3

B. CuSO4

C. NH4Cl

[SEP
D. Na2CO3

32. One molal solution contain one mole of solute in

2009]

[MAY

A. 1000 g of solvent

B. one liter of solvent

C. One liter of solution

D. 22.4 liter of the solution

33. The opposite reaction of neutralization is

A. hydration

B. hydrolysis

[MAY 2009]

C. dehydration

D. electrolysis

34. The pair of compounds which cannot exist together in the solution?
[MAY 2009]
A. NaHCO3 and NaOH

B. Na2CO3 and NaHCO3

C. Na2CO3 and NaOH

D. NaHCO3 and NaCl

35. FIVE liter sodium chloride solution contains 10 moles of solute. What is the
molarity? [SEP 2009]

A. 2M

B. 2.5 M

C. 5 M

D. 12.5 M

36. All of the followings are examples of colloidal solution except

[SEP 2009]
A. fog

B. jelly

C. milk

D. tomato juice

37. Which of the following property is the same for isotonic solution?
[SEP 2009]
A. density

B. normality C. critical temperature

D. osmotic pressure

Q.NO.2
1. Given below is an instruction of process of osmosis. Fig. P shows the original
setup. After some time the system reaches its equilibrium as shown in fig. Q. A
piston is then used to apply force on the solution which results in the setup shown in
the
figure R.

a. H
o
w
is the process of osmosis occurring in fig P. different from R
b. Give a reason why solution of column in the fig Q , once it has reached
equilibrium does not rise higher

2. Define solubility .using graph describe in detail types of solubility curves shown
for each salt.also deduce the following from the graph .
a. grams of undissolved potassium dichromate that settles at the bottom of the
beaker when 70 gm of it is mixed in 100 gm of water at temperature of 50 C o

b. Type of potassium chloride solution as saturated or unsaturated or super

saturated when 50 gm of it is dissolved in 100 gm of water at 80 C o

3. Calculate the molarity of 18 gm NaOH in 500 ml water?

4. Define colligative property of solution .explain in detail with the help of an
example and Raoults law statement (including mathematical expression) how
lowering of vapor pressure is a colligative property?
5. State any two factors for the lowering of vapor pressure of solution?

6. 15 gm of organic solid with empirical formula CH2O is dissolved in 16 gm of

ethanol. The boiling point of this solution is 80.82 C o .the boiling point of pure
ethanol is 79 Co and the molal boiling point constant is 1.75 C o /m .Calculate
a. relative molar mass

b. molecular formula of organic solid

also give a reason why boiling point of solution is higher than that of pure ethanol .
7. Write any four distinguishing characteristics between true solution and colloidal
solution giving two examples of each.

8. Calculate the molarity of 400 cm3 HCl solution neutralized exactly by 19.25 gm of
6 dm3 of anhydrous sodium carbonate.
9. Write the difference between hydrophilic and hydrophobic molecules
10. Briefly describe how colloidal particles stay suspended in liquid while particles in
suspension settle down ?
11. Identify and describe the process in the following fig.

12. Prove that mole fraction of each component of solution in which 5.8 g of glucose
and 8.2 g of urea are dissolved in 56 gm of water is equal to one.

13. Define solubility. Describe solubility curve of potassium nitrate, sodium chloride,
cerium sulphate and sodium sulphate as shown in the graph of solubility vs
temperature.

14. What is the freezing point of 0.45 molal solution of nonvolatile solution ion
water?
(Kf of water is 1.86 Co m-1 )
15. How many grams of KI must be dissolved in 500 gms of water to produce 0.060
molal KI solution
16. State Raolults law with three definitions by the help of mathematical expression
17. Explain why one mole of sodium chloride depresses the freezing point of water
of one kg of water almost twice as much as one mole of glycerin.
18. Define colloids and explain its four types with examples.
19. Differentiate between hydration and hydrolysis
20. The vapour pressure of water at 303 K is 284 torr. Calculate the vapor pressure
of solution containing 50 gms of urea in 1000 gms of water at the same
temperature?
21. Define hydrates. Identify the factors on which formation of hydrates depends.
22. Derive a mathematical relationship that helps to determine the molar mass of
non-volatile and non-electrolyte solute in volatile solvent.
23. The boiling point of pure water is 99.725 Co . to a sample of 500g of water are
added 20 gm of solute having molecular mass of 58 gm /mol to form solution.

Calculate the boiling point of solution. Molal boiling point constant Kb for water is
0.52 Co
24. The freezing point of pure camphor is 178.4 C o. Find the freezing point of
solution containing 3g of non-volatile compound having molecular mass of 140
g/mol in 50 gm of camphor. The molal freezing point constant of camphor is 37.7 C o
25. What Is meant by hydrolysis. Using chemical equation explain the type of each
of following salts on the basis of hydrolysis?
a. Aluminium chloride

b.sodium chloride

26. 81 gm of an organic compound was dissolved in 150 gm of water. The

depression in freezing point was found to be 5.58 C o and molal freezing point of
water is 1.86 Co m-1 .calculate the relative molar mass of the organic compound.