MSDS 0008 Material Safety Data Sheet Page 1 of 7

CATALINA
PACIFIC
CONCRETE
2025 E. FINANCIAL WAY,P.O. BOX 5025, GLENDORA, CA 91741 ? PHONE (626) 852-6200 ? FAX (626) 963-9630

SECTION 1 - IDENTIFICATION

Product Name: Previous MSDS:

Ready-Mix Concrete, Freshly Mixed Unhardened This MSDS supersedes all previous versions.
Concrete
Revision Date:
Supplier/Manufacturer: 08-02-02
Catalina Pacific Concrete
2025 East Financial Way Chemical Name/Synonyms:
Glendora, California 91741 Ready-Mix Concrete, Freshly Mixed Unhardened
(626) 852-6200 Concrete.
Prepared By: Chemical Family:
Grady Calcium compounds
Silica compounds

SECTION 2 - COMPONENTS

Hazardous Ingredients: Total Dust Respirable Dust

Portland cement (CAS# 65997-15-1) - approximately 2% to 26% by weight.
ACGIH TLV 10 mg/m3
OSHA PEL 15 mg/m3 5 mg/m3
OSHA PEL 50 mppcf (crystalline silica < 1%)
Cal/OSHA PEL 10 mg/m3 5 mg/m3
Aggregates (CAS# none ) - approximately 36% to 92% by weight. (natural sand and gravel)
ACGIH TLV 10 mg/m3
OSHA PEL 15 mg/m3 5 mg/m3
3
Cal/OSHA PEL 10 mg/m 5 mg/m3
Flyash (CAS# 68131-74-8) - approximately 0% to 25% by weight.
ACGIH TLV 10 mg/m3
OSHA PEL 15 mg/m3 5 mg/m3
3
Cal/OSHA PEL 10 mg/m 5 mg/m3
Crystalline Silica (CAS# 14808-60-7) - approximately 5% to 13% by weight.
ACGIH TLV 0.1 mg/m3
3
OSHA PEL 2 mg/m (30 mg/m3 / (13% SiO2 +2))
OSHA PEL 0.7 mg/m3 (10 mg/m3 / (13% SiO2 +2))
OSHA PEL 13.8 mppcf (250 / (13% SiO2 +5)) mppcf
Cal/OSHA PEL 0.3 mg/m3 0.1 mg/m3
Water (CAS# 77321-85) - approximately 6% to 13% by weight.
Trace Elements:
Ready-Mix concrete is made from materials mined from the earth. Trace amounts of naturally occurring,
elements might be detected during chemical analysis of these materials.
MSDS 0008 Page 2 of 7

SECTION 3 - HAZARDS IDENTIFICATION

Emergency Overview:
Short term exposure to wet concrete is not likely to cause an immediate hazard. However, exposure of
sufficient duration to wet concrete can cause serious, potentially irreversible tissue (skin or eye) damage in the
form of chemical (caustic) burns. The same type of tissue damage can occur if wet or moist areas of the body
are exposed for sufficient duration to the dry ingredients in unhardened concrete.
Routes of Exposure:
Eye Contact
Exposure to airborne dust during the handling or mixing of the dry ingredients in Ready-Mix concrete may
cause immediate or delayed irritation or inflammation.
Eye contact by splashes of wet concrete may cause effects ranging from moderate eye irritation to chemical
burns and blindness. Such exposures require immediate first aid (see Section 4) and medical attention to
prevent significant damage to the eye.
Skin Contact
Discomfort or pain cannot be relied upon to alert a person to a hazardous skin exposure. Consequently, the
only effective means of avoiding skin injury or illness involves minimizing skin contact, particularly contact
with wet concrete. Exposed persons may not feel discomfort until hours after the exposure has ended and
significant injury has occurred.
Exposure during the handling or mixing of the dry ingredients in Ready-Mix concrete may cause drying of
the skin with consequent mild irritation or more significant effects attributable to aggravation of other
conditions. Exposure to wet concrete may cause more severe skin effects including thickening, cracking or
fissuring of the skin. Prolonged exposure can cause severe skin damage in the form of (caustic) chemical
burns.
Some individuals may exhibit an allergic response upon exposure to wet concrete. The response may
appear in a variety of forms ranging from a mild rash to severe skin ulcers. Persons already sensitized may
react to their first contact with the product. Other persons may first experience this effect after years of
contact with wet unhardened concrete products.
Ingestion
Although inadvertent ingestion of small quantities of wet concrete or its dry ingredients are not known to be
harmful, accidental ingestion of larger quantities can be harmful and requires immediate medical attention.
Inhalation
The ingredients in Ready-Mix concrete contain crystalline silica. Exposure to these ingredients in excess of
the applicable TLV or PEL (see Section 2) may cause or aggravate other lung conditions.
Exposure to the dry ingredients in Ready-Mix concrete may cause irritation to the moist mucous membranes
of the nose, throat, and upper respiratory system
Medical Conditions which May be Aggravated by Inhalation or Dermal Exposure:
Pre-existing upper respiratory and lung diseases by exposure to the dry ingredients.
Persons with unusual (hyper) sensitivity to chemicals, dusts, and metallic compounds may experience adverse
reactions to wet concrete.
Carcinogenic Potential:
Ready-Mix concrete is not listed as a carcinogen by NTP, OSHA, or IARC. It may, however, contain trace
amounts of substances listed as carcinogens by these organizations including but not limited to: crystalline
silica, hexavalent chromium, lead compounds, mercury compounds, nickel compounds, and possibly other
chemicals which may result in exposures which require the following warming pursuant to California Proposition
65:
WARNING: This product contains chemicals known to the State of California to cause cancer, birth
defects, or other reproductive harm.
MSDS 0008 Page 3 of 7

SECTION 4 - FIRST AID

Eyes:
Immediately flush eyes thoroughly with water. Continue flushing eye for at least 15 minutes, including under
lids, to remove all particles. Call physician immediately.
Skin:
Wash skin with cool water and pH-neutral soap or a mild detergent intended for use on skin. Seek medical
treatment in all cases of prolonged exposure to wet concrete, liquids from wet concrete products, or prolonged
wet skin exposure to the dry ingredients in Ready-Mix concrete.
Ingestion:
Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately.
Inhalation of Airborne Dust:
Remove to fresh air. Seek medical help if coughing and other symptoms do not subside. (Inhalation of gross
amounts of the dry ingredients in Ready-Mix concrete requires immediate medical attention.)

SECTION 5 - FIRE & EXPLOSION DATA

Flash Point....................................................... None Extinguishing Media ..................... Not Combustible

Lower Explosive Limit .................................... None Special Fire Fighting Procedures .................. None
Upper Explosive Limit .................................... None Hazardous Combustion Products ................. None
Auto Ignition Temperature ........... Not Combustible Unusual Fire & Explosion Hazards ............... None

SECTION 6 - ACCIDENTAL RELEASE MEASURES

Collect dry material using a scoop. Avoid actions that cause dust to become airborne. Avoid inhalation of dust and
contact with skin.
Scrape up wet material and place in an appropriate container. Allow the wet concrete to "harden" before disposal.
Do not attempt to wash wet concrete down sewers or storm drains.
Wear appropriate personal protective equipment as described in Section 8.
Dispose of waste material according to local, state and federal regulations.

SECTION 7 - HANDLING & STORAGE

Normal temperatures and pressures do not affect the material.

Promptly remove dusty clothing or clothing which is wet with concrete and launder before reuse. Wash thoroughly
after exposure to dust or wet concrete mixtures.

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

Eye Protection:
When engaged in activities where wet concrete or its dry ingredients could contact the eye, wear safety glasses
with side shields or goggles. In extremely dusty environments and unpredictable environments, wear unvented
or indirectly vented goggles to avoid eye irritation or injury. Contact lenses should not be worn when working
 with wet concrete or its dry ingredients.

MSDS 0008 Page 4 of 7

SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION (continued)

Skin Protection:
Prevention is essential to avoiding potentially severe skin injury. Avoid contact with unhardened (wet) concrete
products or its dry ingredients. If contact occurs, promptly wash affected area with soap and water. Where
prolonged exposure to unhardened concrete products might occur, wear impervious clothing and gloves to
eliminate skin contact. Where required, wear boots that are impervious to water to eliminate foot and ankle
exposure.
Do not rely on barrier creams; barrier creams should not be used in place of gloves.
Periodically wash areas contacted by wet cement or its dry ingredients with a pH neutral soap and water. Wash
again at the end of the work. If irritation occurs, immediately wash the affected area and seek treatment. If
clothing becomes saturated with wet concrete, it should be removed and replaced with clean dry clothing.
Respiratory Protection:
Avoid actions that cause dust exposure to occur. Use local or general ventilation to control exposures below
applicable exposure limits.
NIOSH or MSHA approved particulate filter respirators should be used in the context of respiratory protection
program meeting the requirements of the OSHA respiratory protection standard [29 CFR 1910.134] to control
exposures when ventilation or other controls are inadequate or discomfort or irritation is experienced.
Respirator and/or filter cartridge selection should be based on American National Standards Institute (ANSI)
Standards Z88.2 Practices for Respiratory Protection.
Ventilation:
Use local exhaust or general dilution ventilation to control exposure within applicable limits.

SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES

Appearance........................... Gray Granular Mixture Vapor Pressure .................................Not Applicable

Odor................................................ No Distinct Odor Vapor Density ....................................Not Applicable
Physical State ................................................. Liquid Boiling Point ......................................Not Applicable
Specific Gravity (H2O = 1) ..................... 1.70 to 3.00 Melting Point......................................Not Applicable
pH (in water) (ASTM D 1293-95) .................. 12 to 13 Evaporation Rate...............................Not Applicable
Solubility in Water ........................... Slightly Soluble

SECTION 10 - STABILITY & REACTIVITY

Stability: Hazardous Decomposition:

Stable. Will not spontaneously occur. Adding water
results in hydration and produces (caustic)
Conditions to Avoid: calcium hydroxide.
Unintentional contact with water.
Hazardous Polymerization:
Incompatibility: Will not occur.
Wet Ready-Mix concrete is alkaline. As such it is
incompatible with acids, ammonium salts and
aluminum metal.
MSDS 0008 Page 5 of 7

SECTION 11 - TOXICOLOGICAL INFORMATION

NIOSH conducted a study, "The Mortality of U.S. Portland Cement and Quarry Workers" (March 1985) which found:
"There is no excess mortality from all causes of death, lung cancer, non-malignant respiratory disease, or ischemic
heart disease" among workers studied.

SECTION 12 - ECOLOGICAL INFORMATION

Ecotoxicity: Relevant Physical and Chemical Properties:

No recognized unusual toxicity to plants or (See Sections 9 and 10.)
animals.

SECTION 13 - DISPOSAL

Dispose of waste material according to local, state and federal regulations. (Since Ready-Mix concrete is stable,
uncontaminated unused dry material may be saved for future use.)

SECTION 14 - TRANSPORTATION DATA

Hazardous Materials Description/Proper Shipping Identification Number:

Name: Not Applicable
Ready-Mix concrete is not hazardous under U.S.
Department of Transportation (DOT) regulations. Required Label Text:
Not Applicable
Hazard Class:
Not Applicable Hazardous Substances/Reportable Quantities
(RQ):
Not Applicable

SECTION 15 - OTHER REGULATORY INFORMATION

Status under OSHA Hazard Communication Standard, 29 CFR 1910.1200:

Unhardened Ready-Mix concrete is considered a "hazardous chemical" under this regulation, and should be
included in the employers hazard communication program.
Reportable Quantities Under the Clean Water Act, CERCLA, and EPCRA, 40 CFR 117, 302 and 355:
Unhardened Ready-Mix concrete is not Listed.
Hazard Category and Applicability of EPCRA Hazardous Substance Inventory Reporting, 40 CFR 370:
Unhardened Ready-Mix concrete qualifies as a "hazardous substance".
Applicability of EPCRA Toxic Chemical Release Inventory (TRI) Reporting. 40 CFR 372:
Unhardened Ready-Mix concrete is not a TRI listed chemical, however TRI listed constituents are present in
concentrations below the Supplier Notification De Minimus Levels.
Status Under the Toxic Substances Control Act, 40 CFR 710:
Unhardened Ready-Mix concrete and the chemicals present in Unhardened Ready-Mix concrete are on the
TSCA inventory list.
MSDS 0008 Page 6 of 7

SECTION 15 - OTHER REGULATORY INFORMATION (Continued)

Status under the Federal Hazardous Substances Act and Its Regulations:
Unhardened Ready-Mix concrete is a "hazardous substance" subject to the following labeling requirements for
consumer use:
WARNING: INJURIOUS TO EYES. CAUSES SKIN IRRITATION. READ THIS WARNING BEFORE USING.

Contains Portland Cement

Contact with wet (unhardened concrete, mortar, wet cement, or cement mixtures) can cause skin irritation,
severe chemical burns, or serious eye damage. Avoid contact with eyes and skin. Wear waterproof gloves,
a fully buttoned long-sleeved shirt, full-length trousers, and tight fitting eye protection when working with
these materials. If you have to stand in wet concrete, use waterproof boots that are tight at tops and high
enough to keep concrete from flowing into them. If you are finishing concrete wear knee pads to protect
knees. Wash wet concrete, mortar, wet cement, or cement mixtures from your skin with fresh, clean water
immediately after contact. Indirect contact through clothing can be as serious as direct contact, so promptly
rinse out wet concrete, mortar, wet cement, or cement mixtures from clothing. Seek immediate medical
attention if you have persistent or severe discomfort. In case of eye contact, flush with plenty of water for at
least 15 minutes. Consult a physician immediately.
KEEP OUT OF REACH OF CHILDREN.
USER AGREES TO CONVEY THIS WARNING TO ALL PERSONS WHO MAY PURCHASE, USE OR
COME IN CONTACT WITH WET (UNHARDENED) CONCRETE, MORTAR, WET CEMENT OR CEMENT
MIXTURES
Status under Workplace Hazardous Materials Information System (WHMIS), Canada:
Unhardened Ready-Mix concrete is considered to be a hazardous material under the Hazardous Products Act
as defined by the Controlled Products Regulations (Class E - Corrosive Material) and is therefore subject to the
labeling and MSDS requirements of the Workplace Hazardous Materials Information System (WHMIS).
Status under Canadian Environmental Protection Act:
Not Listed.

SECTION 16 - OTHER INFORMATION

Other Important Information:

Ready Mix concrete should only be used by knowledgeable persons. A key to using the product safely requires
the user to recognize that portland cement chemically reacts with water, and that some of the intermediate
products of this reaction (that is, those present while a concrete product is "setting") pose a far more severe
hazard than does portland cement itself.
While the information provided in this material safety data sheet is believed to provide a useful summary of the
hazards of unhardened (wet) Ready-Mix concrete as it is commonly used, the sheet cannot anticipate and
provide all of the information that might be needed in every situation. Inexperienced product users should
obtain proper training before using this product.
In particular, the data furnished in this sheet does not address hazards that may be posed by materials other
than natural sands and gravels mixed with portland cement and flyash to produce Ready-Mix concrete products.
Users should review other relevant material safety data sheets before working with this portland cement
concrete.
MSDS 0008 Page 7 of 7

SECTION 16 - OTHER INFORMATION (Continued)

Abbreviations:

ACGIH
American Conference of Governmental MSDS
Industrial Hygienists Material Safety Data Sheet

ANSI MSHA
American National Standards Institute Mine Safety and Health Administration

Cal/OSHA NIOSH
California Division of Occupational Safety National Institute of Occupational Safety and
and Health Administration Health

CAS NTP
Chemical Abstract Service National Toxicology Program

CERCLA OSHA
Federal Comprehensive Environmental Occupational Safety and Health
Response, Compensation, and Liability Act Administration
(Superfund) PEL
CFR Permissable Exposure Limit
Code of Federal Regulations RQ
DOT Reportable Quantities
Department of Transportation SiO2
EPCRA Crystalline Silica, Quartz
Emergency Planning and Community Right- TLV
to-Know Act of 1986 Threshold Limit Values
IARC TRI
International Agency for Research on Cancer Toxic Release Inventory
3
m TSCA
Cubic Meter Toxic Substance Control Act
mg WHMIS
Milligram Workplace Hazardous Materials Information
mppcf System
Million Particles per Cubic Foot

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY
OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY
CATALINA PACIFIC CONCRETE , except that the product shall conform to contracted specifications. The information provided
herein was believed by Catalina Pacific Concrete to be accurate at the time of preparation or prepared from sources believed to
be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information to comply
with all laws and procedures applicable to the safe handling and use of the product and to determine the suitability of the product
for its intended use. Buyer's exclusive remedy shall be for damages and no claim of any kind, whether as to product delivered or
for non-delivery of product, and whether based on contract, breach of warranty, negligence, or otherwise shall be greater in
amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be
liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or
otherwise.