SAFETY DATA SHEET

1. Identification
Product identifier LPS® CFC Free (Aerosol)
Other means of identification
Part Number 03116
Recommended use A fast drying industrial cleaning solvent designed to remove soil and other contaminants.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Manufacturer
Company name ITW Pro Brands
Address 4647 Hugh Howell Rd.
Tucker, GA 30084
Country (U.S.A.)
Tel: +1 770-243-8800
In Case of Emergency 1-800-424-9300 (inside U.S.)
+001 703-527-3887 (outside U.S.)
Website www.lpslabs.com
E-mail lpssds@itwprobrands.com

2. Hazard(s) identification
Physical hazards Flammable aerosols Category 1
Gases under pressure Compressed gas
Health hazards Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Reproductive toxicity (fertility) Category 2
Specific target organ toxicity, single exposure Category 3 narcotic effects
Environmental hazards Not classified.
OSHA defined hazards Not classified.

Label elements

Signal word Danger

Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin
irritation. Causes serious eye irritation. Suspected of damaging fertility or the unborn child. May
cause drowsiness or dizziness.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not
spray on an open flame or other ignition source. Avoid breathing dust/fume/gas/mist/vapors/spray.
Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective
gloves/protective clothing/eye protection/face protection.
Response IF exposed or concerned: Get medical advice/attention. If on skin: Wash with plenty of
water/soap. Take off contaminated clothing and wash before reuse. If skin irritation occurs: Get
medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell.

Material name: LPS® CFC Free (Aerosol) SDS US

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 Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Store in a
well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
2-Methylpentane 107-83-5 70 - 80
Isopropanol 67-63-0 5 - 15
Pentane 109-66-0 1 - 10
Carbon Dioxide 124-38-9 1-5
N-Hexane 110-54-3 0.1 - 1
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or
artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance.
Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device. Call a physician if symptoms develop or persist.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and
shoes. Get medical attention if irritation develops and persists.
Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses.
Call a physician or Poison Control Center immediately.
Ingestion Call a physician or poison control center immediately. Only induce vomiting at the instruction of
medical personnel. Never give anything by mouth to an unconscious person. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs.
Most important Irritation of eyes and mucous membranes. Symptoms may include stinging, tearing, redness,
symptoms/effects, acute and swelling, and blurred vision. Defatting of the skin. Vapors have a narcotic effect and may cause
delayed headache, fatigue, dizziness and nausea. Narcosis. Behavioral changes. Prolonged exposure may
cause chronic effects.
Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special Symptoms may be delayed.
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. In the case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible). Wash contaminated clothing before reuse.

5. Fire-fighting measures
Suitable extinguishing media Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide,
sand or earth may be used for small fires only.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from By heating and fire, harmful vapors/gases may be formed. Vapors may form explosive mixtures
the chemical with air. Vapors may travel considerable distance to a source of ignition and flash back.
Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with
and precautions for firefighters face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protective
clothing will only provide limited protection.
Fire fighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and
equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so
without risk. Water runoff can cause environmental damage.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move
container from fire area if it can be done without risk. In the event of fire and/or explosion do not
breathe fumes.
General fire hazards Extremely flammable aerosol.

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6. Accidental release measures
Personal precautions, Consider initial downwind evacuation for at least 500 meters (1/3 mile). Immediately evacuate
protective equipment and personnel to safe areas. Keep people away from and upwind of spill/leak. Keep out of low areas.
emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear
appropriate personal protective equipment. Do not touch damaged containers or spilled material
unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use
appropriate containment to avoid environmental contamination. Local authorities should be
advised if significant spillages cannot be contained. Use personal protection recommended in
Section 8 of the SDS.
Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
containment and cleaning up precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material. This material is classified as a water pollutant
under the Clean Water Act and should be prevented from contaminating soil or from entering
sewage and drainage systems which lead to waterways.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Use foam to blanket spilled material. Following
product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills in original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic
environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid
discharge into drains, water courses or onto the ground. Use appropriate containment to avoid
environmental contamination.

7. Handling and storage

Precautions for safe handling Should be handled in closed systems, if possible. Vapors may form explosive mixtures with air. Do
not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. Minimize fire risks from flammable and combustible materials
(including combustible dust and static accumulating liquids) or dangerous reactions with
incompatible materials. Use non-sparking tools and explosion-proof equipment.

Avoid contact during pregnancy/while nursing. Do not breathe mist or vapor. Do not taste or
swallow. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure.

Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good
industrial hygiene practices. When using, do not eat, drink or smoke. Wash hands thoroughly after
handling. Avoid release to the environment. Do not empty into drains.
Conditions for safe storage, Level 3 Aerosol.
including any incompatibilities
Store locked up. Keep away from heat, sparks and open flame. Eliminate sources of ignition.

Keep container tightly closed. Store in a cool, dry place out of direct sunlight. Store in a
well-ventilated place. Keep in an area equipped with sprinklers.

8. Exposure controls/personal protection

Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value
Carbon Dioxide (CAS PEL 9000 mg/m3
124-38-9)
5000 ppm
Isopropanol (CAS 67-63-0) PEL 980 mg/m3
400 ppm
N-Hexane (CAS 110-54-3) PEL 1800 mg/m3
500 ppm
Pentane (CAS 109-66-0) PEL 2950 mg/m3
1000 ppm

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 US. ACGIH Threshold Limit Values
Components Type Value
2-Methylpentane (CAS STEL 1000 ppm
107-83-5)
TWA 500 ppm
Carbon Dioxide (CAS STEL 30000 ppm
124-38-9)
TWA 5000 ppm
Isopropanol (CAS 67-63-0) STEL 400 ppm
TWA 200 ppm
N-Hexane (CAS 110-54-3) TWA 50 ppm
Pentane (CAS 109-66-0) TWA 1000 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
Carbon Dioxide (CAS STEL 54000 mg/m3
124-38-9)
30000 ppm
TWA 9000 mg/m3
5000 ppm
Isopropanol (CAS 67-63-0) STEL 1225 mg/m3
500 ppm
TWA 980 mg/m3
400 ppm
N-Hexane (CAS 110-54-3) TWA 180 mg/m3
50 ppm
Pentane (CAS 109-66-0) Ceiling 1800 mg/m3
610 ppm
TWA 350 mg/m3
120 ppm
Biological limit values
ACGIH Biological Exposure Indices
Components Value Determinant Specimen Sampling Time
Isopropanol (CAS 67-63-0) 40 mg/l Acetone Urine *
N-Hexane (CAS 110-54-3) 0.4 mg/l 2,5-Hexanedio Urine *
n, without
hydrolysis
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
N-Hexane (CAS 110-54-3) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
N-Hexane (CAS 110-54-3) Can be absorbed through the skin.
Appropriate engineering Explosion-proof general and local exhaust ventilation. Provide eyewash station.
controls
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles). Eye wash fountain is recommended.

Skin protection
Hand protection For prolonged or repeated skin contact use suitable protective gloves. Chemical resistant gloves
are recommended.
Other Avoid contact with the skin. Wear appropriate chemical resistant clothing.
Respiratory protection No personal respiratory protective equipment normally required. Use a NIOSH/MSHA approved
respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits.
Thermal hazards None known.
General hygiene When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
considerations as washing after handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove contaminants.

Material name: LPS® CFC Free (Aerosol) SDS US

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9. Physical and chemical properties
Appearance Liquid.
Physical state Gas.
Form Aerosol.
Color Clear water-white
Odor Solvent.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 140.9 °F (60.5 °C) dispensed liquid
range
Flash point < 1.4 °F (< -17.0 °C) Tag Closed Cup
Evaporation rate < 1 (Ethyl Ether = 1)
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower 0.6 %
(%)
Flammability limit - upper 7%
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 352.53 mm Hg @ 38ºC
Vapor density ~3 (air = 1)
Relative density Not available.
Solubility(ies)
Solubility (water) < 10 % w/w
Partition coefficient >1
(n-octanol/water)
Auto-ignition temperature 582.8 °F (306 °C)
Decomposition temperature Not available.
Viscosity < 3 cSt @ 25ºC
Other information
Heat of combustion > 30 kJ/g
Percent volatile 100 %
Specific gravity 0.64 - 0.67 @ 20ºC
VOC 96.2 % per U.S, State and Federal Consumer Product Regulations; 669 g/L per SCAQMD Rule 102

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Risk of ignition. Instability caused by elevated temperatures.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Avoid temperatures exceeding the flash point.
Incompatible materials Strong oxidizing agents. Isocyanates. Acids. Chlorine.
Hazardous decomposition Carbon oxides.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea.
Skin contact Causes skin irritation. Frequent or prolonged contact may defat and dry the skin, leading to
discomfort and dermatitis.

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 Eye contact Causes serious eye irritation.
Ingestion May cause discomfort if swallowed.
Symptoms related to the Skin irritation. Defatting of the skin. Irritating to eyes and respiratory system. Symptoms may
physical, chemical and include stinging, tearing, redness, swelling, and blurred vision. Vapors have a narcotic effect and
toxicological characteristics may cause headache, fatigue, dizziness and nausea. Symptoms of overexposure may be
headache, dizziness, tiredness, nausea and vomiting.
Information on toxicological effects
Acute toxicity Narcotic effects.
Components Species Test Results
Isopropanol (CAS 67-63-0)
Acute
Oral
LD50 Rat 4.7 g/kg
N-Hexane (CAS 110-54-3)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg, 4 Hours
Pentane (CAS 109-66-0)
Acute
Oral
LD50 Rat > 2000 mg/kg
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
ACGIH Carcinogens
Isopropanol (CAS 67-63-0) A4 Not classifiable as a human carcinogen.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity Suspected of damaging fertility or the unborn child.
Specific target organ toxicity - Narcotic effects.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not likely, due to the form of the product.
Chronic effects None known.
Further information None known.

12. Ecological information

Ecotoxicity Toxic to aquatic life with long lasting effects.
Components Species Test Results
Isopropanol (CAS 67-63-0)
Aquatic
Fish LC50 Bluegill (Lepomis macrochirus) > 1400 mg/l, 96 hours

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 Components Species Test Results
N-Hexane (CAS 110-54-3)
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) 2.101 - 2.981 mg/l, 96 hours
Persistence and degradability Not inherently biodegradable.
Bioaccumulative potential No data available for this product.
Partition coefficient n-octanol / water (log Kow)
LPS® CFC Free (Aerosol) >1
2-Methylpentane 3.74
Isopropanol 0.05
N-Hexane 3.9
Pentane 3.39
Mobility in soil Readily absorbed into soil.
Other adverse effects None known.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material
and its container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Hazardous waste code D001: Waste Flammable material with a flash point <140 F
D003: Waste Reactive material
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport information

DOT
UN number UN1950
UN proper shipping name Aerosols, flammable
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Label(s) 2.1
Packing group Not available.
Environmental hazards
Marine pollutant No
Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
Packaging exceptions 306
Packaging non bulk None
Packaging bulk None
IATA
UN number UN1950
UN proper shipping name Aerosols, flammable
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Packing group Not available.
Environmental hazards No.
ERG Code 2X
Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
Other information
Passenger and cargo Allowed with restrictions.
aircraft

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 Cargo aircraft only Allowed with restrictions.
IMDG
UN number UN1950
UN proper shipping name AEROSOLS, flammable, MARINE POLLUTANT
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Label(s) 2.1
Packing group Not available.
Environmental hazards
Marine pollutant Yes
EmS F-D, S-U
Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code
DOT

IATA; IMDG

Marine pollutant

General information IMDG Regulated Marine Pollutant.

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
N-Hexane (CAS 110-54-3) Listed.

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 SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
N-Hexane (CAS 110-54-3)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Pentane (CAS 109-66-0)
Safe Drinking Water Act Not regulated.
(SDWA)
FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace
Isopropanol (CAS 67-63-0) Low priority
US state regulations
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
Isopropanol (CAS 67-63-0)
N-Hexane (CAS 110-54-3)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 05-18-2016
Revision date 08-21-2017
Version # 03

Material name: LPS® CFC Free (Aerosol) SDS US

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Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Revision information Regulatory Information: Risk Phrases - Labeling
GHS: Classification

Material name: LPS® CFC Free (Aerosol) SDS US

03116 Version #: 03 Revision date: 08-21-2017 Issue date: 05-18-2016 10 / 10