ACTA UNIVERSITATIS AGRICULTURAE ET SILVICULTURAE MENDELIANAE BRUNENSIS

Volume 62 105 Number 5, 2014

http://dx.doi.org/10.11118/actaun201462051015

EXCESSIVE ADDITIVE EFFECT

ON ENGINE OIL VISCOSITY

Vojtěch Kumbár1, Jiří Votava1

1
Department of Technology and Automobile Transport, Faculty of Agronomy, Mendel University in Brno,
Zemědělská 1, 613 00 Brno, Czech Republic

Abstract

KUMBÁR VOJTĚCH, VOTAVA JIŘÍ. 2014. Excessive Additive Effect On Engine Oil Viscosity. Acta
Universitatis Agriculturae et Silviculturae Mendelianae Brunensis, 62(5): 1015–1020.

The main goal of this paper is excessive additive (for oil filling) effect on engine oil dynamic viscosity.
Research is focused to commercially distribute automotive engine oil with viscosity class 15W–
40 designed for vans. There were prepared blends of new and used engine oil without and with oil
additive in specific ratio according manufacturer’s recommendations. Dynamic viscosity of blends
with additive was compared with pure new and pure used engine oil. The temperature dependence
dynamic viscosity of samples was evaluated by using rotary viscometer with standard spindle.
Concern was that the oil additive can moves engine oil of several viscosity grades up. It is able to lead
to failure in the engine. Mathematical models were used for fitting experimental values of dynamic
viscosity. Exponential fit function was selected, which was very accurate because the coefficient
of determination R2 achieved high values (0.98–0.99). These models are able to predict viscosity
behaviour blends of engine oil and additive.

Keywords: oil additive, dynamic viscosity, engine oil, temperature

INTRODUCTION with higher flow resistance, slower flow and thus

The dynamic viscosity is one of critical behaviour higher resistance against movement of lubricated
of automobile engine oil as state in (Maggi, 2006) surfaces (Luksa, 1990). There is a general practice
and (Kumbár et al., 2013). In this time exist many that range of ± 20% of viscosity value is accepted
and many additives which is can influence to flow for engine oil use. This value was set for large diesel
behaviour of liquids. Ohmo and Matsumoto (2013) engines (Covitch, 2007). In case of gasoline engines,
write about molybdenum dialkyldithiocarbamate, the higher tolerance (for lower values) is acceptable,
Thomas et al. (2012) prefer transesterification also with regard to shearing instability of recently
with alcohols, Quinchia et al. (2009) and Nassar produced oils. Total decrease of viscosity up to 30%
and Ahmed (2010) use polymeric additives, is thus acceptable. The viscosity value, which is too
and Akhmedov et al. (2007) write about viscosity low as a result of failure in the injection system and/
additives to oils based on copolymers of alkyl or water in fuel, can lead to unacceptable thinning
methacrylates and allyl monomers. of lubricating layer (Zhang et al., 2011).
Engine oils with higher value of viscosity create This article addresses issues connected with
a thicker oil layer than oils with lower viscosity. the temperature dependence dynamic viscosity
The metal surfaces thus do not contact each other, of new and used engine oil with oil additive.
unless there is a larger irregularity or roughness
(Mang and Dresel, 2001). As it is presented in Černý MATERIAL AND METHODS
and Mašek (2010), the viscosity is a measure The analyses were performed using
of fluidity of liquids. The oils characterized by lower the automotive engine oil Mogul (produced
viscosity are more fluid (tenuous) and have lower in the Czech Republic) designed for vans. This oil is
internal resistance against flow. The higher viscosity characterised by its producer as all-purpose, multi-
(thicker oil), on the other hand, is connected grade oil intended for new types of petrol and diesel

1015
1016 Vojtěch Kumbár, Jiří Votava

engines. Its properties are 15W-40 viscosity class, by selection of spindle and its rotation velocity.
A3/B3 ACEA Standard, SH/CF API Standard, Relevant evaluation of the results is conditioned by
and 501.01/505.00 VW Standard. The used engine detailed knowledge of tested material. It is necessary
oil was taken from Renault Kangoo, 1.4i (55 kW), to classify the material in a correct way (Kumbár
manufactured in 1999, with oil raid 15,100 km. Oil and Dostál, 2014).
additive was Oil Treatment (produced in the USA), The sample oil was measured in temperature
which is characterized by sentence: “fights friction range −5 °C to +95 °C using standard spindle of R3
to help protect against engine wear by providing type, which is the most suitable spindle for this kind
a thicker cushion between moving engine parts”. of test specification. The spindle speed (revolutions
The recommended oil-additive ratio is 1:10. per minute) was selected to 30 rpm.
Measuring of temperature dependence
of dynamic viscosity of given engine oil and blends
RESULTS AND DISCUSSION
was performed using rotational viscometer
Anton Paar DV–3P. This experimental device Temperature dependence dynamic viscosity
measures the torque of rotating spindle placed into of new engine oil, used engine oil, new engine
the sample. The viscometer detects the resistance oil with additive, used engine oil with additive,
against rotation of cylinder or disc surrounded and pure additive was evaluated in temperature
by measured fluid. The rotating cylinder or disc range −5 °C to +95 °C. The comparison of dynamic
is connected with electric motor sha via viscosity values of all samples engine oil and pure
defined springs. The sha is rotating by set speed additive is shown in the Tab. I.
(expressed in rotations per minute). The angle The temperature dependence dynamic viscosity
of swing is electronically monitored and offers of samples without additive was measured
the precise information on sha (spindle) position. and fitted, as it can be seen in Fig. 1 and Fig. 2.
The measured data are used for calculation The temperature dependence dynamic viscosity
of dynamic viscosity expressed in mPa·s. In case of samples with additive was measured, as it can
of fluids with constant viscosity is the resistance be seen in Fig. 3 and Fig. 4. The temperature
against movement increased with spindle size. dependence dynamic viscosity of pure additive is
The range of measuring and rheological properties shown in the Fig. 5.
determination can be customized according It can be seen that additive has excessive
to specific measuring and experimental conditions effect on the engine oil viscosity. We can say that

I: Comparison of dynamic viscosity values (p > 0.05)

Dynamic viscosity, mPa.s
New engine oil Used engine oil
Temperature, °C New engine oil Used engine oil Additive
+ additive + additive
−5 3,043 ± 152 2,575 ± 129 5,135 ± 257 4,824 ± 241 75,827 ± 3,791
0 1,729 ± 86 1347 ± 67 2,950 ± 148 3,139 ± 157 48,973 ± 2,449
5 990 ± 50 804 ± 40 1,791 ± 90 1,898 ± 95 33,866 ± 1,693
10 690 ± 34 561 ± 28 1,142 ± 57 1,122 ± 56 26,347 ± 1,317
15 471 ± 24 380 ± 19 820 ± 41 799 ± 40 18,543 ± 927
20 347 ± 17 278 ± 14 518 ± 26 617 ± 31 13,737 ± 687
25 276 ± 14 237 ± 12 373 ± 19 482 ± 24 11,064 ± 553
30 207 ± 10 182 ± 9 296 ± 15 370 ± 19 8,139 ± 407
35 152 ± 8 142 ± 7 243 ± 12 289 ± 14 5,755 ± 288
40 116 ± 6 114 ± 6 202 ± 10 227 ± 11 4,326 ± 216
45 98 ± 5 97 ± 5 164 ± 8 186 ± 9 3,560 ± 178
50 81 ± 4 82 ± 4 141 ± 7 163 ± 8 3,069 ± 153
55 69 ± 3 72 ± 4 126 ± 6 143 ± 7 2,536 ± 127
60 61 ± 3 65 ± 3 114 ± 6 124 ± 6 2,046 ± 102
65 55 ± 3 59 ± 3 104 ± 5 107 ± 5 1,824 ± 91
70 51 ± 3 53 ± 3 98 ± 5 102 ± 5 1,645 ± 82
75 48 ± 2 49 ± 2 93 ± 5 96 ± 5 1,449 ± 72
80 46 ± 2 46 ± 2 87 ± 4 89 ± 4 1,297 ± 65
85 45 ± 2 41 ± 2 85 ± 4 87 ± 4 1,232 ± 62
90 44 ± 2 39 ± 2 78 ± 4 84 ± 4 1,160 ± 58
95 43 ± 2 39 ± 2 76 ± 4 81 ± 4 1,095 ± 55
 Excessive Additive Effect On Engine Oil Viscosity 1017

1: Temperature dependence dynamic viscosity of new engine oil

2: Temperature dependence dynamic viscosity of used engine oil

3: Temperature dependence dynamic viscosity of new engine oil with additive

the additive moves blends of several viscosity grades At 40 °C it is from 116 to over 200 mPa·s and at 95 °C
up. The decrease dynamic viscosity is around 60– it is from 43 to about 80 mPa·s. If we pour additive
70 times for all samples in temperature range −5 °C to used engine oil the dynamic viscosity at 0 °C
to +95 °C. It is expect but if we pour oil additive increase from 1,347 to about 3,000 mPa·s. At 40 °C
to engine oil filling in recommended ratio 1:10 it is from 116 to over 200 mPa·s and at 95 °C it is
the viscosity increased too much. from 43 to about 80 mPa·s.
If we pour additive to new engine oil the dynamic
viscosity at 0 °C increase from 1,729 to 3,000 mPa·s.
1018 Vojtěch Kumbár, Jiří Votava

4: Temperature dependence dynamic viscosity of used engine oil with additive

5: Temperature dependence dynamic viscosity of additive

The temperature dependence dynamic viscosity CONCLUSIONS

of all samples was modeled using exponential fit The role of engine oil in the engine operation
function. The general formula was used: is of multipurpose character. None of the oil
 = A × ek×t, (1) characteristics or physical properties can be
preferred and/or increased to the exclusion
where of other. The dynamic viscosity is one of critical
 .......dynamic viscosity [mPa·s], physical behaviour of automobile engine oil.
t ........temperature [°C], The temperature dependence dynamic viscosity
A ......coefficient [mPa·s], of new engine oil, used engine oil, new engine
k .......coefficient [°C−1]. oil with additive, used engine oil with additive,
The values of coefficients and determination and additive was evaluated using the rotary
coefficient R2 are shown in the Tab. II. viscometer. It was found significant temperature
dependence viscosity of all samples. This
dependence was modelling using exponential
fit function, which was very accurate because

II: Values of coefficients A, k and determination coefficient R2

A, mPa·s k, °C−1 R2
New engine oil 1,825 −0.0967 0.9894
Used engine oil 1,495 −0.1011 0.9823
New engine oil + additive 3,100 −0.0966 0.9925
Used engine oil + additive 3,100 −0.0866 0.9918
Additive 51,860 −0.0681 0.9936
 Excessive Additive Effect On Engine Oil Viscosity 1019

the coefficient of determination R2 achieved high to used engine oil the dynamic viscosity at 0 °C
values (0.98–0.99). The decrease dynamic viscosity is increase from 1,347 to about 3,000 mPa·s. At 40 °C
around 60–70 times for all samples in temperature it is from 116 to over 200 mPa·s and at 95 °C it is
range −5 °C to +95 °C. It is expect but if we pour oil from 43 to about 80 mPa·s. The main conclusion
additive to engine oil filling in recommended ratio of this article is not matter if we pour the additive
1:10 the viscosity increased too much. If we pour to new or used engine oil, but important is that
additive to new engine oil the dynamic viscosity the additive is able to moves engine oil of several
at 0 °C increase from 1,729 to 3,000 mPa·s. At 40 °C viscosity grades up. It may not be in accordance with
it is from 116 to over 200 mPa·s and at 95 °C it is manufacturer’s recommendations and it can lead
from 43 to about 80 mPa·s. If we pour additive to failure in the engine.

SUMMARY
This paper deals with excessive additive (for oil filling) effect on engine oil dynamic viscosity. The role
of engine oil in the engine operation is of multipurpose character. None of the oil characteristics
or physical properties can be preferred and/or increased to the exclusion of other. The dynamic
viscosity is one of critical physical behaviour of automobile engine oil. Research is focused
to commercially distribute automotive engine oil with viscosity class 15W–40 designed for vans.
There were prepared blends of new and used engine oil without and with oil additive in specific
ratio according manufacturer’s recommendations. Dynamic viscosity of blends with additive was
compared with pure new and pure used engine oil. The temperature dependence dynamic viscosity
of samples was evaluated by using rotary viscometer with standard spindle. It was found significant
temperature dependence viscosity of all samples. This dependence was modelling using exponential
fit function, which was very accurate because the coefficient of determination R2 achieved high values
(0.98–0.99). The decrease dynamic viscosity is around 60–70 times for all samples in temperature
range −5 °C to +95 °C. It is expect but if we pour oil additive to engine oil filling in recommended ratio
1:10 the viscosity increased too much. If we pour additive to new engine oil the dynamic viscosity
at 0 °C increase from 1,729 to 3,000 mPa·s. At 40 °C it is from 116 to over 200 mPa·s and at 95 °C it
is from 43 to about 80 mPa·s. If we pour additive to used engine oil the dynamic viscosity at 0 °C
increase from 1,347 to about 3,000 mPa·s. At 40 °C it is from 116 to over 200 mPa·s and at 95 °C it is
from 43 to about 80 mPa·s. The main conclusion of this article is not matter if we pour the additive
to new or used engine oil, but important is that the additive is able to moves engine oil of several
viscosity grades up. It may not be in accordance with manufacturer’s recommendations and it can
lead to failure in the engine.

Acknowledgement
The research has been supported by the project TP 4/2014 “Analysis of degradation processes
of modern materials used in agricultural technology“, financed by IGA AF MENDELU.

REFERENCES LUKSA, A. 1990. Viscosity properties of base

AKHMEDOV, A. I., GASANOVA E. I., GAMIDOVA lubricating oils containing mineral oil, synthetic
D. S., ISAKOV E. I. 2007. Viscosity additives ester oil and polymeric additives. Journal of Synthetic
to lubricating oils, based on alkyl methacrylates Lubrication, 7(3): 188–192.
and allyl monomers. Russian Journal of Applied MAGGI, C. P. 2006. Advantages of Kinematic
Chemistry, 80(8): 1441–1442. Viscosity Measurement in Used Oil Analysis.
ČERNÝ, J., MAŠEK, P. 2010. Quality changes of new Practicing Oil Analysis, 5: 38–52.
engine oil filling [in Czech]. Fuels, 2(1): 1–3. MANG, T., DRESEL, W. 2001. Lubricants
COVITCH, M. J. 2007. Lubricant additive effects and Lubrication. 1. Ed. Weinheim: Wiley-vch.
on engine oil pumpability at low temperatures – NASSAR, A. M., AHMED, N. S. 2010. Study
detergents and high ethylene olefin copolymer the influence of some polymeric additives as
viscosity modifiers. Tribology Transactions, 50(1): viscosity index improvers, pour point depressants
68–73. and dispersants for lube oil. Petroleum Science
KUMBÁR, V., SABALIAUSKAS, A. 2013. Low- and Technology, 28(1): 13–26.
temperature behaviour of the engine oil. Acta OHNO, H., MATSUMOTO, S. 2013. Effect of base
Universitatis Agriculturae et Silviculturae Mendelianae oil viscosity and anti-wear additive of grease
Brunensis, 61(6): 1763–1767. on rolling fatigue of ball type linear motion rolling
KUMBÁR, V., DOSTÁL, P. 2014. Temperature bearing. Seimitsu Kogaku Kaishi/Journal of the Japan
dependence density and kinematic viscosity Society for Precision Engineering, 79(2): 159–164.
of petrol, bioethanol and their blends. Pakistan QUINCHIA, L. A., DELGADO, M. A., VALENCIA,
Journal of Agricultural Sciences, 51(1): 175–179. C., FRANCO, J. M., GALLEGOS, C. 2009.
Viscosity modification of high-oleic sunflower
1020 Vojtěch Kumbár, Jiří Votava

oil with polymeric additives for the design of new TRÁVNÍČEK, P., JUNGA, P. 2014. Thixotropic
biolubricant formulations. Environmental Science behaviour of thickened sewage sludge. Journal
and Technology, 43(6): 2060–2065. of Environmental Health Science and Engineering,
THOMAS, T. P., BIRNEY, D. M., AULD, D. L. 12(72): 1–6.
2012. Viscosity reduction of castor oil esters ZHANG, J., GAO, H., NI, G. 2011. Piston-ring
by the addition of diesel, safflower oil esters and cylinder-liner lubrication in internal
and additives. Industrial Crops and Products, 36(1): combustion engines based on thermo-
267–270. hydrodynamic. Chinese Journal of Mechanical
Engineering (English Edition), 24(6): 971–975.

Contact information
Vojtěch Kumbár: vojtech.kumbar@mendelu.cz
Jiří Votava: jiri.votava@mendelu.cz