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    Material Safety Data Sheet: Zenith

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    Fery Febryanto
    This document provides a material safety data sheet for nickel sulfamate from Zenith Chemical Corporation. It lists nickel sulfamate as the main ingredient and identifies health hazards such as irritation from inhalation, skin contact, and eye contact. It also notes that nickel is considered a possible carcinogen. The document provides handling, storage, exposure, and disposal information and identifies the product as toxic and potentially sensitizing if in contact with skin.

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    Material Safety Data Sheet: Zenith

    Uploaded by

    Fery Febryanto
    153 views5 pages
    This document provides a material safety data sheet for nickel sulfamate from Zenith Chemical Corporation. It lists nickel sulfamate as the main ingredient and identifies health hazards such as irritation from inhalation, skin contact, and eye contact. It also notes that nickel is considered a possible carcinogen. The document provides handling, storage, exposure, and disposal information and identifies the product as toxic and potentially sensitizing if in contact with skin.

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    Zenith

    Original Title

    Komposisi kimia

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    This document provides a material safety data sheet for nickel sulfamate from Zenith Chemical Corporation. It lists nickel sulfamate as the main ingredient and identifies health hazards such as irritation from inhalation, skin contact, and eye contact. It also notes that nickel is considered a possible carcinogen. The document provides handling, storage, exposure, and disposal information and identifies the product as toxic and potentially sensitizing if in contact with skin.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    153 views5 pages

    Material Safety Data Sheet: Zenith

    Uploaded by

    Fery Febryanto
    This document provides a material safety data sheet for nickel sulfamate from Zenith Chemical Corporation. It lists nickel sulfamate as the main ingredient and identifies health hazards such as irritation from inhalation, skin contact, and eye contact. It also notes that nickel is considered a possible carcinogen. The document provides handling, storage, exposure, and disposal information and identifies the product as toxic and potentially sensitizing if in contact with skin.

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    © All Rights Reserved
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    ZENITH

    MATERIAL SAFETY DATA SHEET


    1. Identification of the substance/preparation and of the company/undertaking
    Identification of the product
    Product name: Nickel Sulfamate
    Manufacturer/supplier identification
    Company: Zenith Chemical Corporation
    Contact for information: Tel 886-4-26811521; FAX 886-4-26816523

    Emergency telephone No.: Tel. 886-4-26811521

    2. Hazards identification
    Inhalation of nickel sulfamate mist can cause irritation of the upper respiratory tract. Skin contact
    may be irritating and can cause allergic dermatitis (“nickel itch”) characterized by itching, erythematic,
    and skin eruption. Eye contact with dust pr solutions may cause irritation. Ingestion of nickel salts can
    cause nausea, vomiting, and giddiness. The NTP and IARC list “nickel and certain nickel compounds”
    as suspected carcinogens. This is based in part on epidemiological evidence of excess incidences of
    nasal and lung cancer in populations of workers exposed to nickel or nickel compounds. The specific
    nickel compounds responsible have not been identified.

    ****************N.F.P.A.************************
    Degree of hazard Emergency hazard rating
    4=extreme Health <2>
    3=High Fire <0>
    2=Moderate Reactivity <0>
    1=Slight Specific hazard < >
    0=insignificant
    ***********************************************
    Hazard Label

    3. Composition/information on ingredients
    Molecular formula: Ni(NH2SO3)2.XH2O CAS No.: 13770-89-3 60%
    Molecular formula: Water CAS No. 7732-18-5 40%

    Synonyms: Nickel Sulfamate Solution; Liquid Nickel Sulfamate

    1
    ZENITH

    4. First aid measures


    Skin Contact:
    Immediately wash contaminated skin with plenty of water. Removecontaminated clothing and footwear.
    Wash clothing before reuse.Discard footwear if it cannot be decontaminated. If irritation continues, seek
    medical attention.
    Eye Contact:
    Flush eyes with plenty of water, holding lids apart to ensure flushing of entire surface to prevent or relieve
    irritation. If irritation persists, seek medical attention.
    Ingestion:
    Never give anything by mouth to an unconscious person, obtain immediate medical attention. If vomiting
    occurs spontaneously, keep airway clear. If swallowed DO NOT INDUCE VOMITING, give large amounts
    of water. Seek immediate medical attention.
    Inhalation:
    Remove person from contaminated area. If breathing has stopped, resuscitate and administer oxygen if
    available. Seek immediate medical attention.

    5. Fire-fighting measures
    Flash Point Not Applicable
    Special Fire-Fighting Procedures:
    Wear self-contained breathing apparatus (SCBA) and complete personal protective equipment when
    potential for exposure to vapors or products of combustion exists.
    Unusual Fire-Fighting Hazards:
    Thermal decomposition may yield toxic sulfur and metal oxides.
    Extinguishing Media:
    This product is not combustible.As appropriate for surrounding fire.

    6. Accidental release measures


    Avoid contact with skin, eyes, and clothing. Wear protective equipment (see Section 8). Do not breathe mist
    or vapors. Contain spill and soak up in suitable absorbent. Shovel up into plastic-lined steel containers and
    cover. Dispose of in accordance with Local, State and Federal regulations.

    7. Handling and storage


    Store in a cool dry place. Loosen cover cautiously when opening.
    Additional Information: Store above freezing temperature.
    Work/Hygienic Practices:Do not consume, handle or store food, beverages or tobacco in areas where this
    product is present. Emergency eye wash and safety shower should be available. Wash thoroughly after
    handling.

    8. Exposure controls/personal protection


    Occupational Exposure Limits:ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL
    NICKEL SULFAMATE:0.10 mg/M3 NA NA NA 1.00 mg/M3
    Exposure limits for soluble nickel compounds are as Ni, inhalablefraction.
    Respirator:
    Use NIOSH approved respirator when air concentration is greater than the TLV or PEL.
    Use cartridge filter for acid mist.
    Eye Protection: Safety glasses recommended.

    2
    ZENITH

    Protective Clothing or Equipment:Wear full protective work clothing.Neoprene gloves.Butyl rubber gloves
    Ventilation:Local exhaust recommended.

    9. Physical and chemical properties


    Form: Liquid
    Colour: Clear, bluish-green liquid
    Odour: Odorless
    PH value:4.4-4.7
    Melting temperature: NA
    Boiling temperature: NA
    Ignition temperature: NA
    flash point :NA
    Explosion limits :NA
    Relative vapour density: NA
    Density:1.54
    Solubility in water 100%

    10. Stability and reactivity


    Conditions to be avoided: No information available. Do not evaporate to dryness.
    Substances to be avoided: Strong acids.
    Hazardous decomposition products:. In a fire: toxic sulfur oxides, metal fumes.
    Hazardous polymerization: Cannot occur
    Stability: stable

    11. Toxicological information


    Actual toxicity: LD50 (oral, mouse): 250mg/kg
    Further toxicological information:
    The following applies to soluble nickel compounds in general: inorganic nickel has an astringent
    effect on mucous membranes. Sensitization with allergic manifestations is possible in predisposed
    persons. In some cases nickel dermatitis may manifast itself. Depending on the water-solubility, nickel
    and its compounds display a more or less distinct carcinogenicity, with the readily soluble nickel
    compounds obviously entailing the lesser risk.

    3
    ZENITH

    12. Ecological information


    Ecotoxic effects:
    the following applies to nickel salts in general: Biological effects: dissolved Ni toxic for aquatic organisms.
    Fish: L. idus L50: 570mg/l; lethal concentration for fish 1mg/l in soft water; in hard water P. promelas LD50
    27mg/l; bacteria: Ps. Putida toxic from 0.0025 mg/l up; algae: Sc. quadricauda toxic from 1.3mg/l up;M.
    aeruginosa toxic from 0.005mg/l up; E. sulcatum toxic from 0.14mg/l up; U. pardcczi toxic from 0.042 mg/l
    up; arthropods: D. magna LC50: 11mg/l (all values referring to dissolved Ni)
    Further ecologic data: Do not allow to enter waters, waste water, or soil.

    13.Disposal considerations
    Product:
    Chemical residues generally count as special waste. The disposal of the latter is regulated in the country
    through corresponding laws and regulations. We recommend that you contact either the authorities in charge
    or approved waste disposal companies which will advise you on how to dispose of special waste.
    Packaging:
    Disposal in compliance with official regulations. Handle contaminated packaging in the same way as the
    substance itself. If not officially specified differently, non-contaminated packaging may be treated like
    household waste or recycled.

    14. Transport information


    Transport over land ADR/RID and GGVS/GGVE (Germany)
    River transport
    Sea transport
    Air transport
    UN / ID NO. ：UN3082

    15. Regulatory information


    Labeling according to directives
    symbol: T Toxic
    R-phrases: 25-43 Toxic if swallowed. May cause sensitization by skin contact.
    S-phrases: 24-37-45 Avoid contact with skin. Wear suitable gloves. On case of accident or if you
    feel unwell, seek medical advice immediately.(show the label where possible)

    4
    ZENITH

    16. Other information


    Produced by: Zenith Chemical Corporation
    Address :No.9, Youe-6 Rd., Youth Industrial District, Tachia City, Taichang Hsien, 437,
    Taiwan, R.O.C.

    The information contained herein is based on the present state of our knowledge. It
    characterizes the product with regard to the appropriate safety precautions. It does
    not represent a guarantee of the properties of the product. Recipients are advised to
    confirm in advance
    7. Identification of need that the information
    of the substance/preparation it current,
    and of the applicability suitable to
    company/undertaking
    their current circumstances.

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