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    HW 10 20190827092946 1

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    Jaskirat Singh
    1. The document contains 23 chemistry questions related to topics like chemical bonding, molecular structure, hybridization, shapes of molecules, dipole moments, lattice enthalpy, hydrogen bonding and intermolecular forces. 2. The questions assess understanding of concepts like Lewis structures, octet rule, formal charges, calculating lattice enthalpy from standard enthalpy data, molecular orbital theory, hybridization and its effect on shape. 3. Several questions test the ability to explain trends in properties based on concepts like polarity, hydrogen bonding and intermolecular forces.

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    HW 10 20190827092946 1

    Uploaded by

    Jaskirat Singh
    83 views2 pages
    1. The document contains 23 chemistry questions related to topics like chemical bonding, molecular structure, hybridization, shapes of molecules, dipole moments, lattice enthalpy, hydrogen bonding and intermolecular forces. 2. The questions assess understanding of concepts like Lewis structures, octet rule, formal charges, calculating lattice enthalpy from standard enthalpy data, molecular orbital theory, hybridization and its effect on shape. 3. Several questions test the ability to explain trends in properties based on concepts like polarity, hydrogen bonding and intermolecular forces.

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    1. The document contains 23 chemistry questions related to topics like chemical bonding, molecular structure, hybridization, shapes of molecules, dipole moments, lattice enthalpy, hydrogen bonding and intermolecular forces. 2. The questions assess understanding of concepts like Lewis structures, octet rule, formal charges, calculating lattice enthalpy from standard enthalpy data, molecular orbital theory, hybridization and its effect on shape. 3. Several questions test the ability to explain trends in properties based on concepts like polarity, hydrogen bonding and intermolecular forces.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    83 views2 pages

    HW 10 20190827092946 1

    Uploaded by

    Jaskirat Singh
    1. The document contains 23 chemistry questions related to topics like chemical bonding, molecular structure, hybridization, shapes of molecules, dipole moments, lattice enthalpy, hydrogen bonding and intermolecular forces. 2. The questions assess understanding of concepts like Lewis structures, octet rule, formal charges, calculating lattice enthalpy from standard enthalpy data, molecular orbital theory, hybridization and its effect on shape. 3. Several questions test the ability to explain trends in properties based on concepts like polarity, hydrogen bonding and intermolecular forces.

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    © All Rights Reserved
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    VIS–10, DWARKA, NEW DELHI

    Name : ………………………. Class…..…XI………...


    Subject: Chemistry Date………………..

    Chemical Bonding and Molecular Structure


    Q1 Draw the Lewis dot structure for the following and state how many lone pairs
    each atom possesses?
    (i) NCl3 (ii) NO2 (iii) BF3 (iv) SF6 (v) H2CO3

    Q2 Give two examples of compounds in which the central atom has incomplete
    octet.

    international school
    venkateshwar international school

    Q3 Write the formal charge on each atom in the nitrite ion.

    Q4 Calculate the lattice enthalpy of KCl from the following data:


    (i) Sublimation of K is 89kJ/mol
    (ii) Dissociation of Cl2 to Cl is 244kJ/mol
    (iii)Ionization of K to K+ is 425kJ/mol
    (iv)Electron gain enthalpy of Cl to Cl- is -355kJ/mol
    (v)∆fH0 of KCl is -438kJ/mol
    Q5 In ammonia,NH3 molecule, four electron pairs are present but the shape is
    pyramidal and NOT tetrahedral .Why?

    Q6 Predict the dipole moment of a molecule of the type

    venkateshwar
    (i) AX4 having a square planer geometry.
    (ii) AX5 having a square pyramidal shape.
    (iii)AX6 having an octahedral geometry.

    Q7 Draw orbital representation of the following molecules:


    (i) Water
    (ii) Nitrogen molecule
    (iii)Ammonia

    Q8 On the basis of hybridization , explain the bonding and shape in :


    (i) Ethane molecule and (ii) Ethyne molecule

    Q9 Why does antibonding molecular orbital has lower energy than either of the

    VIS–10, DWARKA, NEW DELHI


    VIS–10, DWARKA, NEW DELHI

    Q10Why does anti bonding molecular orbital have higher energy than either of the
    atomic orbitals?

    Q11 Draw the MO diagram for O2 molecule. Calculate the bonding and
    antibonding electrons in O22+ ion on the basis of molecular orbital theory.

    Q12 Use molecular orbital theory to explain why does the Be2 molecule not exist?

    Q13 Explain why the bond order of N2 is greater than N2+,but the bond order of
    O 2 is less than that of O2+?

    venkateshwar international school


    venkateshwar international school

    Q14 Compare the relative stabilities of the following species and indicate their
    magnetic properties(diamagnetic or paramagnetic):
    O2+,O 2- and O - ions.
    Q15 Account for the following:
    (i) He2 is not found to exist in nature.
    (ii) N 2+ is not a diamagnetic substance.
    (iii)The dissociation energy of H2+ is almost same as that of He2+.

    Q16 The dipole moment of hydrogen halides decreases from HF to HI. Explain
    this trend.

    Q17 Boiling point of ethane is more than that of methane. Explain.

    Q18 Out of inter molecular and intramolecular hydrogen bonding which has an
    influence on the characteristics of substance?

    Q18 Out of but-1-yne and but-1-ene, has higher dipole moment and why?

    Q19 Answer the following:


    (i) CCl4 is non-polar but CH 3Cl is polar.
    (ii) SiF4 is non-polar although Si-F bonds are polar.
    (iii) A hetro-diatomic molecule is always polar.

    Q20 Explain why is o-hydroxy benzaldehyde a liquid at room temperature while p-


    hydroxy benzaldehyde is a high melting solid?

    Q21 Define lattice enthalpy. How is related to the stability of an ionic compound?

    Q22 Describe the hybridization in case of PCl5 .Why are the axial bonds longer as
    compared to equatorial bonds ?

    Q23 Explain the formation of H2 molecule on the basis of valance bond theory?

    VIS–10, DWARKA, NEW DELHI

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