SAFETY DATA SHEET

1. Identification
Product identifier Lead Iodide (PbI2)
Other means of identification
SDS number 1MK
Materion Code 1MK
CAS number 10101-63-0
Synonyms LEAD IODIDE * Lead iodide (PbI2) * LEAD(II) IODIDE * Lead diiodide
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name Materion Advanced Chemicals Inc.
Address 407 N 13th Street
1316 W. St. Paul Avenue
Milwaukee, WI 53233
United States
Telephone 414.212.0257
E-mail advancedmaterials@materion.com
Contact person Noreen Atkinson
Emergency phone number Chemtrec 800.424.9300

2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Acute toxicity, oral Category 4
Acute toxicity, inhalation Category 4
Carcinogenicity Category 2
Reproductive toxicity (fertility, the unborn Category 1A
child)
Specific target organ toxicity, repeated Category 2
exposure
Environmental hazards Hazardous to the aquatic environment, acute Category 1
hazard
Hazardous to the aquatic environment, Category 1
long-term hazard
OSHA defined hazards Not classified.

Label elements

Signal word Danger

Hazard statement Harmful if swallowed. Harmful if inhaled. Suspected of causing cancer. May damage fertility. May
damage the unborn child. May cause damage to organs through prolonged or repeated exposure.
Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Material name: Lead Iodide (PbI2) SDS US

1MK Version #: 03 Revision date: 01-11-2018 Issue date: 07-13-2016 1/9

 Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not breathe dust. Wash thoroughly after handling. Do not eat, drink or smoke
when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the
environment. Wear protective gloves/protective clothing/eye protection/face protection.
Response If swallowed: Call a poison center/doctor if you feel unwell. If inhaled: Remove person to fresh air
and keep comfortable for breathing. If exposed or concerned: Get medical advice/attention. Call a
poison center/doctor if you feel unwell. Rinse mouth. Collect spillage.
Storage Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information For further information, please contact the Product Stewardship Department at +1.800.862.4118.

3. Composition/information on ingredients
Substances
Chemical name Common name and synonyms CAS number %
Lead Iodide (PbI2) LEAD IODIDE 10101-63-0 90 - 100
Lead iodide (PbI2)
LEAD(II) IODIDE
Lead diiodide

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or
artificial respiration if needed. Call a POISON CENTER or doctor/physician if you feel unwell.
Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact Do not rub eyes. Rinse with water. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Get medical advice/attention if you feel unwell.
Most important Dusts may irritate the respiratory tract, skin and eyes. Prolonged exposure may cause chronic
symptoms/effects, acute and effects.
delayed
Indication of immediate medical Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim
attention and special treatment under observation. Symptoms may be delayed.
needed
General information IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in
attendance.

5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting Use water spray to cool unopened containers.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.

Material name: Lead Iodide (PbI2) SDS US

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6. Accidental release measures
Personal precautions, protective Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
equipment and emergency appropriate protective equipment and clothing during clean-up. Do not breathe dust. Use a
procedures NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding
the exposure limits. Ensure adequate ventilation. Local authorities should be advised if significant
spillages cannot be contained. For personal protection, see section 8 of the SDS.
Methods and materials for Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Collect dust
containment and cleaning up using a vacuum cleaner equipped with HEPA filter. This material is classified as a water pollutant
under the Clean Water Act and should be prevented from contaminating soil or from entering
sewage and drainage systems which lead to waterways. Stop the flow of material, if this is without
risk.

Large Spills: Wet down with water and dike for later disposal. Shovel the material into waste
container. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.

Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. Wipe
up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual
contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Minimize dust generation and accumulation. Do not breathe dust. Avoid
prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Pregnant or
breastfeeding women must not handle this product. Should be handled in closed systems, if
possible. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective
equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe
good industrial hygiene practices.
Conditions for safe storage, Store locked up. Store in original tightly closed container. Store in a well-ventilated place. Store
including any incompatibilities away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Material Type Value

Lead Iodide (PbI2) (CAS TWA 0.05 mg/m3

10101-63-0)
US. ACGIH Threshold Limit Values
Material Type Value Form

Lead Iodide (PbI2) (CAS TWA 0.05 mg/m3

10101-63-0)
0.01 ppm Inhalable fraction and
vapor.
US. California Code of Regulations, Title 8, Section 5155. Airborne Contaminants
Material Type Value Form

Lead Iodide (PbI2) (CAS PEL 0.05 mg/m3 Dust and fume.
10101-63-0)
TWA 0.03 mg/m3 Dust and fume.

Material name: Lead Iodide (PbI2) SDS US

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Biological limit values
ACGIH Biological Exposure Indices
Material Value Determinant Specimen Sampling Time

Lead Iodide (PbI2) (CAS 300 µg/l Lead Blood *

10101-63-0)
* - For sampling details, please see the source document.
Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
If engineering measures are not sufficient to maintain concentrations of dust particulates below the
Occupational Exposure Limit (OEL), suitable respiratory protection must be worn. If material is
ground, cut, or used in any operation which may generate dusts, use appropriate local exhaust
ventilation to keep exposures below the recommended exposure limits.
Control parameters Follow standard monitoring procedures.
Individual protection measures, such as personal protective equipment
Eye/face protection Chemical respirator with organic vapor cartridge, full facepiece, dust and mist filter.

Skin protection
Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
supplier.

Other Wear suitable protective clothing. Use of an impervious apron is recommended.

Respiratory protection Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels
exceeding the exposure limits. Chemical respirator with organic vapor cartridge, full facepiece,
dust and mist filter.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene considerations Keep away from food and drink. Always observe good personal hygiene measures, such as
washing after handling the material and before eating, drinking, and/or smoking.

9. Physical and chemical properties

Appearance
Physical state Solid.
Form Powder.
Color Not available.
Odor Not available.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 755.6 °F (402 °C)
Initial boiling point and boiling 1601.6 °F (872 °C)
range
Flash point Not available.
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure < 0.0000001 kPa at 25 °C
Material name: Lead Iodide (PbI2) SDS US

1MK Version #: 03 Revision date: 01-11-2018 Issue date: 07-13-2016 4/9

Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 6.16 g/cm3
Explosive properties Not explosive.
Molecular formula I2-Pb
Molecular weight 461.01 g/mol
Oxidizing properties Not oxidizing.
Specific gravity 6.16

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation Harmful if inhaled. May cause damage to organs through prolonged or repeated exposure by
inhalation.
Skin contact Dust or powder may irritate the skin.
Eye contact Dust may irritate the eyes.
Ingestion Harmful if swallowed.
Symptoms related to the Dusts may irritate the respiratory tract, skin and eyes.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity Harmful if inhaled. Harmful if swallowed.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity Suspected of causing cancer.

Material name: Lead Iodide (PbI2) SDS US

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 IARC Monographs. Overall Evaluation of Carcinogenicity
Lead Iodide (PbI2) (CAS 10101-63-0) 2A Probably carcinogenic to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Lead Iodide (PbI2) (CAS 10101-63-0) Reasonably Anticipated to be a Human Carcinogen.
Reproductive toxicity May damage fertility. May damage the unborn child.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - May cause damage to organs through prolonged or repeated exposure.
repeated exposure
Aspiration hazard Not an aspiration hazard.
Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation may
be harmful. Prolonged exposure may cause chronic effects.

12. Ecological information

Ecotoxicity Very toxic to aquatic life with long lasting effects.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches
with chemical or used container. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.

14. Transport information

DOT
UN number UN2291
UN proper shipping name Lead compounds, soluble, n.o.s. (Lead Iodide (PbI2) RQ = 10 LBS), MARINE POLLUTANT
Transport hazard class(es)
Class 6.1(PGIII)
Subsidiary risk -
Label(s) 6.1
Packing group III
Environmental hazards
Marine pollutant Yes
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions 138, IB8, IP3, T1, TP33
Packaging exceptions 153
Packaging non bulk 213

Material name: Lead Iodide (PbI2) SDS US

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 Packaging bulk 240
IATA
UN number UN2291
UN proper shipping name Lead compound, soluble, n.o.s. (Lead Iodide (PbI2))
Transport hazard class(es)
Class 6.1(PGIII)
Subsidiary risk -
Packing group III
Environmental hazards No.
ERG Code 6L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Other information
Passenger and cargo Allowed with restrictions.
aircraft
Cargo aircraft only Allowed with restrictions.
IMDG
UN number UN2291
UN proper shipping name LEAD COMPOUND, SOLUBLE, N.O.S. (Lead Iodide (PbI2)), MARINE POLLUTANT
Transport hazard class(es)
Class 6.1(PGIII)
Subsidiary risk -
Packing group III
Environmental hazards
Marine pollutant Yes
EmS F-A, S-A
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
DOT

IATA; IMDG

Material name: Lead Iodide (PbI2) SDS US

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Marine pollutant

General information IMDG Regulated Marine Pollutant. DOT Regulated Marine Pollutant.

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Lead Iodide (PbI2) (CAS 10101-63-0) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Lead Iodide (PbI2) (CAS 10101-63-0) Reproductive toxicity
Central nervous system
Kidney
Blood
Acute toxicity
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Lead Iodide (PbI2) (CAS 10101-63-0)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Clean Water Act (CWA) Hazardous substance
Section 112(r) (40 CFR Priority pollutant
68.130) Toxic pollutant
Safe Drinking Water Act 0 mg/l
(SDWA) 0.015 mg/l
US state regulations
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Lead Iodide (PbI2) (CAS 10101-63-0) Listed: October 1, 1992

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 US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a))
Lead Iodide (PbI2) (CAS 10101-63-0)

16. Other information, including date of preparation or last revision

Issue date 07-13-2016
Revision date 01-11-2018
Version # 03

Disclaimer Materion Advanced Chemicals Inc. cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use.
This document has been prepared using data from sources considered to be technically reliable
and the information is believed to be correct. Materion makes no warranties, expressed or implied,
as to the accuracy of the information contained herein. Materion cannot anticipate all conditions
under which this information and its products may be used and the actual conditions of use are
beyond its control. The user is responsible to evaluate all available information when using this
product for any particular use and to comply with all Federal, State, Provincial and Local laws,
statutes and regulations.

Material name: Lead Iodide (PbI2) SDS US

1MK Version #: 03 Revision date: 01-11-2018 Issue date: 07-13-2016 9/9