MSDS Nemo 6153 - English - Mar14
MSDS Nemo 6153 - English - Mar14
MSDS Nemo 6153 - English - Mar14
Page: 1/18
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 15.10.2013 Version: 1.0
Product: Nemo 6153
(ID no. 30603801/SDS_GEN_EU/EN)
Date of print 17.10.2013
Nemo 6153
1.2. Relevant identified uses of the substance or mixture and uses advised against
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Fuel and Lubricant Solutions
Asp. Tox. 1
Flam. Liq. 3
Skin Corr./Irrit. 2
Eye Dam./Irrit. 1
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 15.10.2013 Version: 1.0
Product: Nemo 6153
(ID no. 30603801/SDS_GEN_EU/EN)
Date of print 17.10.2013
Skin Sens. 1
Carc. 2
STOT SE 3 (Vapours may cause drowsiness and dizziness.)
Aquatic Chronic 2
Possible Hazards:
Limited evidence of a carcinogenic effect.
Irritating to skin.
Risk of serious damage to eyes.
May cause sensitization by skin contact.
Harmful: may cause lung damage if swallowed.
Vapours may cause drowsiness and dizziness.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
For the classifications not written out in full in this section the full text can be found in section 16.
Pictogram:
Signal Word:
Danger
Hazard Statement:
H318 Causes serious eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
Hazard determining component(s) for labelling: NAPHTHALENE, Fatty acids, C8-18 and C18-
unsatd., reaction products with diethanolamine and propylene oxide
Hazard symbol(s)
Xn Harmful.
R-phrase(s)
R40 Limited evidence of a carcinogenic effect.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R65 Harmful: may cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S53 Avoid exposure - obtain special instructions before use.
S23.3 Do not breathe vapour/spray.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S51 Use only in well-ventilated areas.
S62 If swallowed, do not induce vomiting: seek medical advice immediately
and show this container or label.
S61 Avoid release to the environment. Refer to special instructions/safety
data sheets.
Hazard determining component(s) for labelling: NAPHTHALENE, Fatty acids, C8-18 and C18-
unsatd., reaction products with diethanolamine and propylene oxide
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.
Not applicable
3.2. Mixtures
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 15.10.2013 Version: 1.0
Product: Nemo 6153
(ID no. 30603801/SDS_GEN_EU/EN)
Date of print 17.10.2013
Chemical nature
This product contains the 3 a.m. substances in the concentrations as stated. A preparation of these
substances has been tested and is to be labelled according to the test results:
Skin Corr./Irrit. 2
Aquatic Chronic 3
H315, H412
Fatty acids, C8-18 and C18-unsatd., reaction products with diethanolamine and propylene oxide
Content (W/W): >= 5 % - <= 10 % Skin Corr./Irrit. 2
CAS Number: 1000817-22-0 Eye Dam./Irrit. 1
REACH registration number: 01- Skin Sens. 1B
2119962886-18 H318, H315, H317
naphthalene
Content (W/W): >= 2 % - <= 3 % Acute Tox. 4 (oral)
CAS Number: 91-20-3 Carc. 2
EC-Number: 202-049-5 Aquatic Acute 1
INDEX-Number: 601-052-00-2 Aquatic Chronic 1
M-factor acute: 1
M-factor chronic: 1
H302, H351, H400, H410
Hazardous ingredients
according to Directive 1999/45/EC
This product contains the 3 a.m. substances in the concentrations as stated. A preparation of these
substances has been tested and is to be labelled according to the test results:
Hazard symbol(s): Xi
R-phrase(s): 38, 52/53
Fatty acids, C8-18 and C18-unsatd., reaction products with diethanolamine and propylene oxide
Content (W/W): >= 5 % - <= 10 %
CAS Number: 1000817-22-0
REACH registration number: 01-2119962886-18
Hazard symbol(s): Xi, N
R-phrase(s): 38, 41, 43, 51/53
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 15.10.2013 Version: 1.0
Product: Nemo 6153
(ID no. 30603801/SDS_GEN_EU/EN)
Date of print 17.10.2013
2-Ethylhexan-1-ol
Content (W/W): > 15 % - < 25 %
CAS Number: 104-76-7
EC-Number: 203-234-3
REACH registration number: 01-2119487289-20
Hazard symbol(s): Xn
R-phrase(s): 20, 36/37/38
naphthalene
Content (W/W): >= 2 % - <= 3 %
CAS Number: 91-20-3
EC-Number: 202-049-5
INDEX-Number: 601-052-00-2
Hazard symbol(s): Xn, N
R-phrase(s): 22, 40, 50/53
Carc. Cat. 3
For the classifications not written out in full in this section, including the indication of danger, the
hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact:
Wash thoroughly with soap and water.
On ingestion:
Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical
attention.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 15.10.2013 Version: 1.0
Product: Nemo 6153
(ID no. 30603801/SDS_GEN_EU/EN)
Date of print 17.10.2013
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.
91-20-3: naphthalene
TWA value 50 mg/m3 ; 10 ppm (OEL (EU))
indicative
95-63-6: 1,2,4-trimethylbenzene (Content (W/W): 3 % - 4 %)
TWA value 100 mg/m3 ; 20 ppm (OEL (EU))
indicative
108-67-8: mesitylene; 1,3,5-trimethylbenzene (Content (W/W): 0.2 % - 0.5 %)
TWA value 100 mg/m3 ; 20 ppm (OEL (EU))
indicative
104-76-7: 2-Ethylhexan-1-ol
64742-82-1: kerosine (petroleum)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
fluoroelastomer (FKM) - 0.7 mm coating thickness
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 15.10.2013 Version: 1.0
Product: Nemo 6153
(ID no. 30603801/SDS_GEN_EU/EN)
Date of print 17.10.2013
Polyethylene-Laminate (PE laminate) - ca. 0.1 mm coating thickness
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2,
corresponding > 30 minutes of permeation time according to EN 374)
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
Form: liquid
Colour: yellowish
Odour: product specific
Odour threshold:
No applicable information available.
pH value:
not applicable
Melting point: < -30 °C
(1,013 hPa)
boiling temperature: > 100 °C
(1,013 hPa)
Flash point: > 55 °C (DIN EN 22719; ISO 2719)
Evaporation rate:
Value can be approximated from
Henry's Law Constant or vapor
pressure.
Flammability: Flammable.
Lower explosion limit: 2.9 %(V) (DIN 51649-1, air)
(20 °C)
Upper explosion limit: 12.4 %(V) (DIN 51649-1, air)
(20 °C)
Ignition temperature: > 200 °C (DIN 51794)
Vapour pressure: 20 hPa
(50 °C)
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 15.10.2013 Version: 1.0
Product: Nemo 6153
(ID no. 30603801/SDS_GEN_EU/EN)
Date of print 17.10.2013
4 hPa
(20 °C)
Density: 0.879 g/cm3 (ISO 2811-3)
(15 °C)
Solubility in water: insoluble
Solubility (qualitative) solvent(s): aromatic hydrocarbons
soluble
Partitioning coefficient n-octanol/water (log Kow):
Study scientifically not justified.
Self ignition: not self-igniting
Hygroscopy: Non-hygroscopic
Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.
Peroxides: 0.000 %
The product does not contain peroxides.
Substances to avoid:
strong oxidizing agents
Acute toxicity
Experimental/calculated data:
LD50 rat (oral): > 2,000 mg/kg
Irritation
Experimental/calculated data:
Skin corrosion/irritation rabbit: Irritant. (OECD Guideline 404)
Respiratory/Skin sensitization
Experimental/calculated data:
skin sensitizing
Assessment of mutagenicity:
Based on the ingredients, there is no suspicion of a mutagenic effect.
Carcinogenicity
Assessment of carcinogenicity:
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 15.10.2013 Version: 1.0
Product: Nemo 6153
(ID no. 30603801/SDS_GEN_EU/EN)
Date of print 17.10.2013
Limited evidence of a carcinogenic effect. The product has not been tested. The statement has been
derived from the properties of the individual components.
Reproductive toxicity
Aspiration hazard
The product has not been tested. The statements on toxicology have been derived from the
properties of the individual components.
Toxicity to fish:
LC50 (96 h) 1 - 10 mg/l, Fish
According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance
fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/very
bioaccumulative) criteria.
The product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on
substances that deplete the ozone layer.
Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.
Land transport
ADR
UN number UN1993
UN proper shipping name: FLAMMABLE LIQUID, N.O.S. (contains SOLVENT NAPHTHA,
NAPHTHALENE)
Transport hazard class(es): 3, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for Tunnel code: D/E
user: SP 640 E
RID
UN number UN1993
UN proper shipping name: FLAMMABLE LIQUID, N.O.S. (contains SOLVENT NAPHTHA,
NAPHTHALENE)
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 15.10.2013 Version: 1.0
Product: Nemo 6153
(ID no. 30603801/SDS_GEN_EU/EN)
Date of print 17.10.2013
Transport hazard class(es): 3, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for SP 640 E
user:
Sea transport
IMDG
UN number: UN 1993
UN proper shipping name: FLAMMABLE LIQUID, N.O.S. (contains SOLVENT NAPHTHA,
NAPHTHALENE)
Transport hazard class(es): 3, EHSM
Packing group: III
Environmental hazards: yes
Marine pollutant: YES
Special precautions for None known
user:
Air transport
IATA/ICAO
UN number: UN 1993
UN proper shipping name: FLAMMABLE LIQUID, N.O.S. (contains SOLVENT NAPHTHA,
NAPHTHALENE)
Transport hazard class(es): 3
Packing group: III
Environmental hazards: No Mark as dangerous for the environment is needed
Special precautions for None known
user:
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 15.10.2013 Version: 1.0
Product: Nemo 6153
(ID no. 30603801/SDS_GEN_EU/EN)
Date of print 17.10.2013
14.1. UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.
Assessment of the hazard classes according to UN GHS criteria (most recent version):
Skin Corr./Irrit. 2
Eye Dam./Irrit. 1
Skin Sens. 1
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 15.10.2013 Version: 1.0
Product: Nemo 6153
(ID no. 30603801/SDS_GEN_EU/EN)
Date of print 17.10.2013
Aquatic Chronic 2
Aquatic Acute 2
Asp. Tox. 1
STOT SE 3 (Vapours may cause drowsiness and dizziness.)
Carc. 2
Flam. Liq. 3
Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases,
and the hazard statements, if mentioned in section 2 or 3:
Xn Harmful.
Xi Irritant.
N Dangerous for the environment.
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
38 Irritating to skin.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
41 Risk of serious damage to eyes.
43 May cause sensitization by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
67 Vapours may cause drowsiness and dizziness.
20 Harmful by inhalation.
36/37/38 Irritating to eyes, respiratory system and skin.
22 Harmful if swallowed.
40 Limited evidence of a carcinogenic effect.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Asp. Tox. Aspiration hazard
Flam. Liq. Flammable liquid
Skin Corr./Irrit. Skin corrosion/irritation
Eye Dam./Irrit. Serious eye damage/eye irritation
Skin Sens. Skin sensitization
Carc. Carcinogenicity
STOT SE Specific target organ toxicity — single exposure
Aquatic Chronic Hazardous to the aquatic environment - chronic
Acute Tox. Acute toxicity
Aquatic Acute Hazardous to the aquatic environment - acute
Carc. Cat. 3 Carcinogenic substances Category 3: Substances which cause concern
for man owing to possible carcinogenic effects.
H304 May be fatal if swallowed and enters airways.
EUH066 Repeated exposure may cause skin dryness or cracking.
H315 Causes skin irritation.
H412 Harmful to aquatic life with long lasting effects.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
H336 May cause drowsiness or dizziness.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H302 Harmful if swallowed.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 15.10.2013 Version: 1.0
Product: Nemo 6153
(ID no. 30603801/SDS_GEN_EU/EN)
Date of print 17.10.2013
H351 Suspected of causing cancer.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.