Ardrox 6025: Safety Data Sheet

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Ardrox 6025
Version: 4.1 Revision Date 18.07.2013 Print Date 19.07.2013
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier

Trade name : Ardrox 6025
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Cleaning agent
stance/Mixture
Recommended restrictions : None known.
on use
1.3 Details of the supplier of the safety data sheet

Company : Chemetall Ltd
Denbigh Road
Bletchley Milton Keynes MK1 1PB
Telephone : 01908 649333
Telefax : 01908 373939
Contact person product safety

Telephone : +49(0)6971652832
E-mail address : msds.de@chemetall.com
1.4 Emergency telephone number

Emergency telephone : 01908 649333
number
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)
Skin corrosion, Category 1B H314: Causes severe skin burns and eye damage.
Classification (67/548/EEC, 1999/45/EC)
Corrosive R34: Causes burns.
2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)
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SAFETY DATA SHEET
Ardrox 6025
Hazard pictograms :
Signal word : Danger
Hazard statements : H314 Causes severe skin burns and eye damage.
Precautionary statements : Prevention:

P260 Do not breathe dust/ fume/ gas/ mist/ va-
pours/ spray.
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/ protective clothing/
eye protection/ face protection.
Response:
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do
NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take
off immediately all contaminated clothing.
Rinse skin with water/ shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with wa-
ter for several minutes. Remove contact
lenses, if present and easy to do. Continue
rinsing.
P308 IF exposed or concerned:
P310 Immediately call a POISON CENTER or
doctor/ physician.
Disposal:
P501 Dispose of contents/ container to an ap-
proved waste disposal plant.
Additional Labelling:
EUH208 Contains: Benzothiazole-2-thiol May produce an allergic reaction.
Labelling according to EC Directives (1999/45/EC)

Hazard pictograms :
Corrosive
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SAFETY DATA SHEET
Ardrox 6025
R-phrase(s) : R34 Causes burns.
S-phrase(s) : S23 Do not breathe gas/fumes/vapour/spray.

S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immedi-
ately with plenty of water and seek medical
advice.
S36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S45 In case of accident or if you feel unwell,
seek medical advice immediately (show
the label where possible).
S60 This material and its container must be
disposed of as hazardous waste.
Detergents Regulation EC : Anionic surfactants less than 5 %

907/2006
Sensitising components : Benzothiazole-2-thiol

May produce an allergic reaction.
2.3 Other hazards

Classification "corrosive" due to the extreme pH value.
SECTION 3: Composition/information on ingredients

3.1 Substances
not applicable
3.2 Mixtures
Chemical nature : Aqueous solution of alkali salts and surfactants.
Hazardous components
Chemical Name CAS-No. Classification Classification Concentration
EC-No. (67/548/EEC) (REGULATION [%]
Registration num- (EC) No
ber 1272/2008)
Benzenesulfonic acid, 127184-52-5 Xn; R22 Acute Tox. 4; >= 2.5 - < 10
Na-salt H302
Sodium xylene sulpho- 1300-72-7 Xi; R36 Eye Irrit. 2; >= 1 - < 2.5
nate 215-090-9 H319
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SAFETY DATA SHEET
Ardrox 6025
2-Butoxyethanol 111-76-2 Xn; R20/21/22 Acute Tox. 4; >= 1 - < 2.5

203-905-0 H332
01-2119475108-36 Xi; R36/38
Acute Tox. 4;
H312
Acute Tox. 4;
H302
Eye Irrit. 2;
H319
Skin Irrit. 2;
H315
Potassium silicate 1312-76-1 Xi; R36/38 Eye Irrit. 2; >= 1 - < 2.5
215-199-1 H319
01-2119456888-17
Skin Irrit. 2;
H315
Trisodium phosphate 10101-89-0 Xi; R36/37/38 Eye Irrit. 2; >= 1 - < 2.5
dodecahydrate 01-2119489800-32 H319
STOT SE 3;
H335
Skin Irrit. 2;
H315
Trisodium- 5064-31-3 Carc.Cat.3; R40 Carc. 2; H351 >= 0.1 - < 1

nitrilotriacetate 225-768-6
01-2119519239-36 Xn; R22 Acute Tox. 4;
H302
Xi; R36
Eye Irrit. 2;
H319
Benzothiazole-2-thiol 149-30-4 R43 Skin Sens. 1; >= 0.1 - < 0.25

205-736-8 H317
N; R50-R53
Aquatic Chronic
1; H410
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SAFETY DATA SHEET
Ardrox 6025
WEL substance :
2-(3- 34590-94-8 Not a hazard- >= 1 - < 2.5
Methoxypro- 252-104-2 ous substance
poxy)propan-1-ol 01-2119450011-60 or mixture ac-
cording to
Regulation (EC)
No. 1272/2008.
For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
For the full text of the Notas mentioned in this Section, see Section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures

General advice : First-aid crew: Ensure self-protection.
Move out of dangerous area.
Take off contaminated clothing and shoes immediately.
If inhaled : Move to fresh air.

If symptoms persist, call a physician.
In case of skin contact : Wash off with soap and plenty of water.
Call a physician immediately.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Risks : corrosive effects
If swallowed, severe burns in the oral cavity and throat as well
as danger of perforation of the digestive tract and stomach.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
For specialist advice physicians should contact the Poisons
Information Service.
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SAFETY DATA SHEET
Ardrox 6025
SECTION 5: Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media : Carbon dioxide (CO2)
Dry powder
Alcohol-resistant foam
Water spray
Unsuitable extinguishing : High volume water jet

media
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire- : May form toxic gases on heating or in case of fire.
fighting Carbon monoxide
Carbon dioxide (CO2)
Sulphur oxides
5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters
Further information : Use water spray to cool unopened containers.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Ensure adequate ventilation.
Wear personal protective equipment.
6.2 Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.
Inform the relevant authorities if it enters sewers, aquatic envi-
ronment or soil.
6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Ensure adequate ventilation.
Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).
6.4 Reference to other sections

See chapter 8 and 13
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SAFETY DATA SHEET
Ardrox 6025
SECTION 7: Handling and storage
7.1 Precautions for safe handling

Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms.
Have eye wash bottle or eye rinse ready at the work place.
Advice on protection against : Normal measures for preventive fire protection.

fire and explosion
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage : Keep containers tightly closed in a cool, well-ventilated place.
areas and containers Store in a place accessible by authorized persons only.
Further information on stor- : Protect from frost.

age conditions
Storage period : 36 month
Storage temperature : > 0 °C
7.3 Specific end uses

Specific use(s) : Cleaning agent
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Control pa-
Components CAS-No. Value Update Basis
rameters
2- 111-76-2 TWA 20 ppm 2000-06-16 2000/39/EC
Butoxyetha- 98 mg/m3
nol
Further informa- : skin: Identifies the possibility of significant uptake through the skin
tion Indicative
111-76-2 STEL 50 ppm 2000-06-16 2000/39/EC

246 mg/m3
tion Indicative
111-76-2 TWA 25 ppm 2005-04-06 GB EH40
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SAFETY DATA SHEET
Ardrox 6025
Further informa- : Sk: Can be absorbed through skin. The assigned substances are those for which there are
tion concerns that dermal absorption will lead to systemic toxicity.
111-76-2 STEL 50 ppm 2005-04-06 GB EH40
2-(3- 34590-94- TWA 50 ppm 2000-06-16 2000/39/EC

Methoxypro- 8 308 mg/m3
poxy)propan-
1-ol
tion Indicative
34590-94- TWA 50 ppm 2005-04-06 GB EH40

8 308 mg/m3
Where no specific short-term exposure limit is listed, a figure three times the long-term expo-
sure should be used
DNEL/DMEL
Trisodium-nitrilotriacetate : End Use: DNEL, Workers
Exposure routes: Inhalation
Potential health effects: Short-term exposure, Systemic effects
Value: 5.25 mg/m3
End Use: DNEL, Workers

Potential health effects: Long-term exposure, Systemic effects
Value: 3.5 mg/m3
Benzothiazole-2-thiol : End Use: Workers, DNEL

Potential health effects: Acute systemic effects
Value: 70.4 mg/m3
End Use: DNEL, Workers

Potential health effects: Long-term systemic effects
Value: 8.8 mg/m3
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SAFETY DATA SHEET
Ardrox 6025
2-(3- : End Use: DNEL, Industrial use, Workers

Methoxypropoxy)propan-1-ol Exposure routes: Skin contact
Potential health effects: Chronic effects, Systemic effects
Value: 65 mg/kg bw/d
End Use: DNEL, Industrial use, Workers

Potential health effects: Chronic effects, Systemic effects
Value: 310 mg/m3
PNEC
Trisodium-nitrilotriacetate : Fresh water
Value: 0.93 mg/l
Marine water
Value: 0.093 mg/l
Behaviour in waste water treatment plants

Value: 540 mg/l
Fresh water sediment

Value: 3.64 mg/kg
Marine sediment
Value: 0.364 mg/kg
Soil
Value: 0.182 mg/kg
Benzothiazole-2-thiol : Fresh water

Value: 0.0041 mg/l
Marine water
Value: 0.00041 mg/l

Value: 0.3 mg/l

Value: 0.0321 mg/kg
Marine sediment
Value: 0.00321 mg/kg
Soil
Value: 0.0239 mg/kg
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SAFETY DATA SHEET
Ardrox 6025
2-(3- : Fresh water

Methoxypropoxy)propan-1-ol Value: 19 mg/l
Marine water
Value: 1.9 mg/l

Value: 4168 mg/l

Value: 70.2 mg/kg
Marine sediment
Value: 7.02 mg/kg
Soil
Value: 2.74 mg/kg
8.2 Exposure controls

Engineering measures
Ensure adequate ventilation, especially in confined areas.
Personal protective equipment

Respiratory protection : In case of insufficient ventilation wear suitable respiratory
equipment.
Recommended Filter type:
A-P2
Hand protection : Neoprene gloves

Protective gloves complying with EN 374.
Please observe the instructions regarding permeability and
breakthrough time which are provided by the supplier of the
gloves. Also take into consideration the specific local condi-
tions under which the product is used, such as the danger of
cuts, abrasion, and the contact time.
Eye protection : Eye protection (EN 166)

Tightly fitting safety goggles
Have eye wash bottle or eye rinse ready at the work place.
Skin and body protection : Chemical resistant protective clothing according to DIN EN
13034 (Type 6)
Hygiene measures : Take off contaminated clothing and shoes immediately.

Keep away from food, drink and animal feedingstuffs.
Wash hands before breaks and immediately after handling the
product.
Avoid contact with skin and eyes.
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SAFETY DATA SHEET
Ardrox 6025
Do not breathe vapour.

Do not breathe spray.
Environmental exposure controls

General advice : Do not flush into surface water or sanitary sewer system.
Inform the relevant authorities if it enters sewers, aquatic envi-
ronment or soil.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance : liquid
Colour : green
Odour : characteristic
Flash point : not applicable
pH : 12.3
at
20 °C
(undiluted)
Solidification tempera- : ca. -2 °C

ture/range
Boiling point/boiling range : ca. 100 °C
Density : 1.055 g/cm3

at 20 °C
Water solubility : soluble
Viscosity, dynamic : 5 mPa*s

at 20 °C
9.2 Other information

Explosivity : no explosion risk
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SAFETY DATA SHEET
Ardrox 6025
Directive 1999/13/EC on the : Value: 51.3 g/l

limitation of emissions of
volatile organic compounds
SECTION 10: Stability and reactivity
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : None known.
10.4 Conditions to avoid

Conditions to avoid : Protect from frost.
10.5 Incompatible materials

Materials to avoid : Strong acids
10.6 Hazardous decomposition products

Risk of decomposition. : No decomposition if stored and applied as directed.
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Acute oral toxicity : Acute toxicity estimate: > 2,000 mg/kg
Method: Calculation method
Acute oral toxicity

Sodium xylene sulphonate : LD50: > 2,000 mg/kg
Species: rat
2-Butoxyethanol : LD50: 1,746 mg/kg

Species: rat
Trisodium phosphate do- : LD50: > 2,000 mg/kg

decahydrate Species: rat
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SAFETY DATA SHEET
Ardrox 6025
Trisodium-nitrilotriacetate : LD50: 1,000 - 2,000 mg/kg

Species: rat
Benzothiazole-2-thiol : LD50: > 2,000.0 mg/kg

Species: rat
2-(3- : LD50: 5,135 mg/kg

Methoxypropoxy)propan-1-ol Species: rat
Acute inhalation toxicity : Acute toxicity estimate: > 20 mg/l

vapour
Exposure time: 4 h
Acute inhalation toxicity

Trisodium-nitrilotriacetate : LC50: > 5 mg/l
Exposure time: 4 h
Species: rat
Information taken from reference works and the literature.
Acute dermal toxicity : Acute toxicity estimate: > 2,000 mg/kg

Acute dermal toxicity

Sodium xylene sulphonate : LD50: > 2,000 mg/kg
Species: rabbit
2-Butoxyethanol : LD50: > 2,000 mg/kg

Species: guinea pig
Method: OECD Test Guideline 402
Trisodium-nitrilotriacetate : LD50: > 10,000 mg/kg

Species: rabbit
Benzothiazole-2-thiol : LD50: > 2,000.0 mg/kg

Species: rabbit
2-(3- : LD50: 9,510 mg/kg

Methoxypropoxy)propan-1-ol Species: rabbit
Skin corrosion/irritation
Skin irritation : Causes severe burns.
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SAFETY DATA SHEET
Ardrox 6025
Serious eye damage/eye irritation

Eye irritation : Causes serious eye damage.
Respiratory or skin sensitisation

Sensitisation : Contains one or more substance(s) classified as sensitising.
Germ cell mutagenicity

Remarks
Trisodium-nitrilotriacetate : Animal testing did not show any mutagenic effects.
Carcinogenicity
Remarks
Trisodium-nitrilotriacetate : Limited evidence of a carcinogenic effect.
Teratogenicity
Remarks
Trisodium-nitrilotriacetate : Animal testing did not show any effects on foetal develop-
ment.
Reproductive toxicity
Remarks
Trisodium-nitrilotriacetate : Animal testing did not show any effects on fertility.
Toxicology Assessment
Acute effects : If swallowed, severe burns in the oral cavity and throat as well
as danger of perforation of the digestive tract and stomach.
SECTION 12: Ecological information
12.1 Toxicity
Ecotoxicology studies for the product are not available.
Toxicity to fish
Sodium xylene sulphonate : LC50: > 1,000 mg/l
Exposure time: 96 h
Species: Fish
2-Butoxyethanol : LC50: 1,490 mg/l

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SAFETY DATA SHEET
Ardrox 6025
Exposure time: 96 h
Species: Lepomis macrochirus (Bluegill sunfish)
Trisodium phosphate do- : LC0: 2,400 mg/l

decahydrate Exposure time: 48 h
Species: Leuciscus idus (Golden orfe)
Trisodium-nitrilotriacetate : flow-through test LC50: > 100 mg/l

Exposure time: 96 h
Species: Pimephales promelas (Fathead minnow)
2-(3- : LC50: 10,000 mg/l

Methoxypropoxy)propan-1-ol Exposure time: 96 h
Species: Pimephales promelas (fathead minnow)
Toxicity to daphnia and other aquatic invertebrates

Sodium xylene sulphonate : static test EC50: > 1,000 mg/l
Exposure time: 48 h
Species: Daphnia
2-Butoxyethanol : EC50: 1,720 mg/l

Exposure time: 24 h
Species: Daphnia
Trisodium-nitrilotriacetate : EC50: 98 mg/l

Exposure time: 96 h
Species: Gammarus salinus (seawater shrimp)
2-(3- : LC50: 1,919 mg/l

Species: Daphnia magna (Water flea)
NOEC: 0.5 mg/l

Exposure time: 22 d
Species: Daphnia magna (Water flea)
Toxicity to algae
Sodium xylene sulphonate : static test EC50: > 230 mg/l
Exposure time: 96 h
Species: Algae
ErC50: 310 mg/l

Exposure time: 72 h
Species: Algae
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SAFETY DATA SHEET
Ardrox 6025
2-Butoxyethanol : Cell multiplication inhibition test EC0: 900 mg/l

Exposure time: 168 h
Species: Scenedesmus quadricauda (Green algae)
Trisodium-nitrilotriacetate : static test EC50: > 91.5 mg/l

Exposure time: 72 h
Species: Scenedesmus capricornutum (fresh water algae)
Method: Tested according to Directive 92/69/EEC.
Benzothiazole-2-thiol : EC50: 0.23 mg/l

Exposure time: 96 h
Species: Pseudokirchneriella subcapitata
2-(3- : EC50: 1,000 mg/l

Species: Selenastrum capricornutum (green algae)
Toxicity to bacteria
2-Butoxyethanol : EC0: 700 mg/l
Exposure time: 16 h
Species: Pseudomonas putida
Trisodium-nitrilotriacetate : EC50: 3,200 - 5,600 mg/l

Exposure time: 8 h
Species: .
Pseudomonas fluorescens
2-(3- : Growth inhibition
Methoxypropoxy)propan-1-ol EC10: 4,168 mg/l
Species: Pseudomonas putida
12.2 Persistence and degradability
Biodegradability : The surfactants contained in this preparation comply with the

biodegradability criteria as laid down in Regulation (EC)
No.907/2006 on detergents.
Biodegradability
2-Butoxyethanol : 100 %
Testing period: 28 d
Readily biodegradable
Zahn-Wellens Test; EG 88/302
Trisodium-nitrilotriacetate : 90 - 100 %
Method: OECD Test Guideline 301B
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SAFETY DATA SHEET
Ardrox 6025
rapidly biodegradable
12.3 Bioaccumulative potential
Bioaccumulation : Bioaccumulation is unlikely.
Bioaccumulation
Trisodium-nitrilotriacetate : Species: Brachydanio rerio (Zebra danio)
Exposure time: 96 h
Bioconcentration factor (BCF): < 3
Accumulation in aquatic organisms is unlikely.
12.4 Mobility in soil
Distribution among environ- : no data available

mental compartments
12.5 Results of PBT and vPvB assessment
This mixture does not contain substances considered to be persistent, bioaccumulating and toxic
(PBT)., This mixture does not contain substances considered to be very persistent and very bioac-
cumulating (vPvB).
12.6 Other adverse effects
Additional ecological informa- : water endangering
tion Do not flush into surface water or sanitary sewer system.
Even leakage of small amounts in the subsoil can contaminate
drinking water.
SECTION 13: Disposal considerations
13.1 Waste treatment methods

Product : Dispose of in accordance with local regulations.
Contaminated packaging : Dispose of as unused product.
Waste Code : Waste codes should be assigned by the user, preferably in

discussion with the waste disposal authorities.
SECTION 14: Transport information
ADR
UN number : 1719
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SAFETY DATA SHEET
Ardrox 6025
UN proper shipping name : CAUSTIC ALKALI LIQUID, N.O.S. Potassium silicate

Transport hazard class(es) : 8
Packing group : III
Classification Code : C5
Hazard Identification Number : 80
Limited Quantity (LQ) Inner : 5.00 L
Packaging
Maximum quantity : 30.00 KG
Labels : 8
Tunnel restriction code : (E)
Environmentally hazardous : no
IATA
UN number : 1719
Description of the goods : Caustic alkali liquid, n.o.s. Potassium silicate
Class : 8
Packing group : III
Labels : 8
IATA_C
Packing instruction (cargo : 856
aircraft)
Packing instruction (LQ) : Y841
Maximum quantity : 60.00 L
IATA_P
Packing instruction (passen- : 852
ger aircraft)
Packing instruction (LQ) : Y841
Maximum quantity : 5.00 L
IMDG
UN number : 1719
Description of the goods : CAUSTIC ALKALI LIQUID, N.O.S. Potassium silicate
Class : 8
Packing group : III
Labels : 8
EmS Number 1 : F-A
EmS Number 2 : S-B
Marine pollutant : no
RID
UN number : 1719
Description of the goods : CAUSTIC ALKALI LIQUID, N.O.S. Potassium silicate
Transport hazard class(es) : 8
Packing group : III
Classification Code : C5
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SAFETY DATA SHEET
Ardrox 6025
Hazard Identification Number : 80

Labels : 8
Limited Quantity (LQ) Inner : 5.00 L
Packaging
Maximum quantity : 30.00 KG
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REACH - Candidate List of : This product does not contain substances of very high con-
Substances of Very High cern (Regulation (EC) No 1907/2006 (REACH), Article 57).
Concern for Authorisation
(Article 59).
Water contaminating class : WGK 2 water endangering

(Germany) VWVWS A4
Other regulations : The product is classified and labelled in accordance with EC

directives or respective national laws.
Regional or national implementations of GHS may not imple-
ment all hazard classes and categories.
15.2 Chemical Safety Assessment

For a mixture it is not mandatory to include an exposure scenario in the material safety data sheet.
The necessary safety - related information is stated in the first 16 sections.
SECTION 16: Other information

Full text of R-phrases referred to under sections 2 and 3
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R22 Harmful if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R36/37/38 Irritating to eyes, respiratory system and skin.
R36/38 Irritating to eyes and skin.
R40 Limited evidence of a carcinogenic effect.
R43 May cause sensitisation by skin contact.
R50 Very toxic to aquatic organisms.
R53 May cause long-term adverse effects in the aquatic environment.
Full text of H-Statements referred to under sections 2 and 3.

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SAFETY DATA SHEET
Ardrox 6025
H302 Harmful if swallowed.

H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H410 Very toxic to aquatic life with long lasting effects.
Further information
The information provided is based on our current knowledge and experience and apply to the product
as delivered. Regarding the product properties, these are not guaranteed. The delivery of this safety
datasheet does not free the recipient of the product from his own responsibility to follow the relevant
rules and regulations concerning this product.
20 / 20
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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

Contact person product safety

1.4 Emergency telephone number

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

2.2 Label elements

Signal word : Danger

Precautionary statements : Prevention:

Labelling according to EC Directives (1999/45/EC)

R-phrase(s) : R34 Causes burns.

S-phrase(s) : S23 Do not breathe gas/fumes/vapour/spray.

Detergents Regulation EC : Anionic surfactants less than 5 %

Sensitising components : Benzothiazole-2-thiol

2.3 Other hazards

SECTION 3: Composition/information on ingredients

2-Butoxyethanol 111-76-2 Xn; R20/21/22 Acute Tox. 4; >= 1 - < 2.5

Trisodium- 5064-31-3 Carc.Cat.3; R40 Carc. 2; H351 >= 0.1 - < 1

Benzothiazole-2-thiol 149-30-4 R43 Skin Sens. 1; >= 0.1 - < 0.25

SECTION 4: First aid measures

4.1 Description of first aid measures

If inhaled : Move to fresh air.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Unsuitable extinguishing : High volume water jet

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

6.3 Methods and materials for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on protection against : Normal measures for preventive fire protection.

Further information on stor- : Protect from frost.

Storage temperature : > 0 °C

7.3 Specific end uses

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

111-76-2 STEL 50 ppm 2000-06-16 2000/39/EC

111-76-2 TWA 25 ppm 2005-04-06 GB EH40

111-76-2 STEL 50 ppm 2005-04-06 GB EH40

2-(3- 34590-94- TWA 50 ppm 2000-06-16 2000/39/EC

34590-94- TWA 50 ppm 2005-04-06 GB EH40

End Use: DNEL, Workers

Benzothiazole-2-thiol : End Use: Workers, DNEL

End Use: DNEL, Workers

2-(3- : End Use: DNEL, Industrial use, Workers

End Use: DNEL, Industrial use, Workers

Behaviour in waste water treatment plants

Fresh water sediment

Benzothiazole-2-thiol : Fresh water

Behaviour in waste water treatment plants

Fresh water sediment

2-(3- : Fresh water

Behaviour in waste water treatment plants