Safety Data Sheet

Hempaline Defend 630 Base

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830 - Europe

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : Hempaline Defend 630 Base
Product identity : 3782910500
Product type : epoxy phenolic paint for tank linings (base for 2-component product)

1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : buildings and metal industry.
Ready-for-use mixture : 37821 = 37829 3 Ltr / 9780F 1 Ltr 37820 = 37829 3 Ltr / 9780S 1 Ltr
Identified uses : Industrial applications, Used by spraying.

1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details : HEMPEL A/S Emergency telephone number (with hours of operation)
Lundtoftegårdsvej 91
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 - 17.00)
Denmark See section 4 First aid measures.
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue : 19 October 2016
Date of previous issue : No previous validation.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1
Aquatic Chronic 2, H411 AQUATIC HAZARD (LONG-TERM) - Category 2
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Warning

Hazard statements : H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements :
Prevention : Avoid breathing vapors, spray or mists. Wear protective gloves/protective clothing/eye protection/face
protection.
Response : IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical attention.
Hazardous ingredients : formaldehyde, polymer with (chloromethyl)oxirane and phenol
1,6-hexanediol diglycidylether
Supplemental label elements : Contains epoxy constituents. May produce an allergic reaction.
Special packaging requirements
Containers to be fitted with child- Not applicable.
resistant fastenings :
Tactile warning of danger : Not applicable.

2.3 Other hazards

Other hazards which do not result None known.
in classification :

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SECTION 3: Composition/information on ingredients

3.2 Mixtures
.

Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type

formaldehyde, polymer with REACH #: 01-2119454392-40 ≥25 - ≤50 Skin Irrit. 2, H315 - [1]
(chloromethyl)oxirane and EC: 500-006-8 Skin Sens. 1, H317
phenol CAS: 9003-36-5 Aquatic Chronic 2, H411
1,6-hexanediol diglycidylether REACH #: 01-2119463471-41 ≥5 - <10 Skin Irrit. 2, H315 - [1]
EC: 240-260-4 Eye Irrit. 2, H319
CAS: 16096-31-4 Skin Sens. 1, H317
Aquatic Chronic 3, H412
amide wax REACH #: 01-2119545465-35 ≥1 - ≤3 Aquatic Chronic 3, H412 - [1]
EC: 907-495-0
See Section 16 for the full text of the H statements declared .
above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern

SECTION 4: First aid measures

4.1 Description of first aid measures

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If unconscious, place in recovery position and
seek medical advice.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to
the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed

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SECTION 4: First aid measures

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used: waterjet.

5.2 Special hazards arising from the substance or mixture

Hazards from the substance or In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic
mixture : to aquatic life with long lasting effects. Fire water contaminated with this material must be contained
and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides sulfur oxides halogenated
compounds metal oxide/oxides

5.3 Advice for firefighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or without suitable training.

6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if
released in large quantities.

6.3 Methods and materials for containment and cleaning up

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Contaminated absorbent material may pose the same hazard as the spilled product.

6.4 Reference to other sections

See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Contains epoxy constituents. Avoid all possible skin contact with epoxy and amine containing products, they may cause allergic reactions.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources.
Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized
access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)

See separate Product Data Sheet for recommendations or industrial sector specific solutions.

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SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Product/ingredient name Exposure limit values

No exposure limit value known.

Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure
to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Derived effect levels
No DNELs/DMELs available.

Predicted effect concentrations

No PNECs available.

8.2 Exposure controls

Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.

Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles.
Hand protection : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type.
Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator. Wear
appropriate respirator when ventilation is inadequate. Be sure to use approved/certified respirator or
equivalent. It is not possible to specify precise filter type, since the actual work situation is unknown.
Supplier of respirators should be contacted in order to find the appropriate filter.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

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SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state : Liquid.
Odor : Amine-like.
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : -20.6°C This is based on data for the following ingredient: formaldehyde, polymer with (chloromethyl)
oxirane and phenol
Boiling point/boiling range : Testing not relevant or not possible due to nature of the product.
Flash point : Closed cup: 149°C (300.2°F)
Evaporation rate : Testing not relevant or not possible due to nature of the product.
Flammability : Not available.
Lower and upper explosive No specific data.
(flammable) limits :
Vapor pressure : 0.08 kPa This is based on data for the following ingredient: formaldehyde, polymer with (chloromethyl)
oxirane and phenol
Vapor density : Testing not relevant or not possible due to nature of the product.
Relative density : 1.561 g/cm³
Solubility(ies) : Insoluble in the following materials: cold water and hot water.
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature : Testing not relevant or not possible due to nature of the product.
Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Viscosity : Testing not relevant or not possible due to nature of the product.
Explosive properties : Testing not relevant or not possible due to nature of the product.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.

9.2 Other information

Solvent(s) % by weight : Weighted average: 1 %
Water % by weight : Weighted average: 0 %
VOC content : 10.1 g/l
TOC Content : Weighted average: 6 g/l
Solvent Gas : Weighted average: 0.004 m³/l

SECTION 10: Stability and reactivity

10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability

The product is stable.

10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid

No specific data.

10.5 Incompatible materials

10.6 Hazardous decomposition products

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides sulfur oxides halogenated compounds metal oxide/oxides

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SECTION 11: Toxicological information

11.1 Information on toxicological effects

Epoxy and amine containing products can cause skin disorders such as allergic eczema. The allergy may arise after only a short exposure
period.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
formaldehyde, polymer with LD50 Dermal Rabbit >2000 mg/kg -
(chloromethyl)oxirane and phenol
LD50 Oral Rat >2000 mg/kg -
1,6-hexanediol diglycidylether LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat 2190 mg/kg -
amide wax LC50 Inhalation Dusts and mists Rat 5110 mg/m³ 4 hours
LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat >2000 mg/kg -
Acute toxicity estimates
Route ATE value
No known significant effects or critical hazards.

Irritation/Corrosion
Product/ingredient name Result Species Score Exposure
formaldehyde, polymer with Skin - Mild irritant Rabbit - 24 hours 500 microliters
(chloromethyl)oxirane and phenol
1,6-hexanediol diglycidylether Skin - Irritant Rabbit - -
Eyes - Irritant Rabbit - -
amide wax Skin - Mild irritant Rabbit - -
Eyes - Mild irritant Rabbit - -
Sensitizer
Product/ingredient name Route of exposure Species Result
1,6-hexanediol diglycidylether skin Guinea pig Sensitizing

Mutagenic effects
No known significant effects or critical hazards.

Carcinogenicity
No known significant effects or critical hazards.

Reproductive toxicity
No known significant effects or critical hazards.

Teratogenic effects
No known significant effects or critical hazards.

Specific target organ toxicity (single exposure)

Product/ingredient name Category Route of exposure Target organs
No known data avaliable in our database.

Specific target organ toxicity (repeated exposure)

Product/ingredient name Category Route of exposure Target organs
No known data avaliable in our database.

Aspiration hazard
Product/ingredient name Result
No known data avaliable in our database.

Information on the likely routes of exposure

Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
Sensitization : Contains formaldehyde, polymer with (chloromethyl)oxirane and phenol, 1,6-hexanediol diglycidylether.
May produce an allergic reaction.

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SECTION 11: Toxicological information

Other information : No additional known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Do not allow to enter drains or watercourses. Toxic to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
formaldehyde, polymer with Acute EC50 2.54 mg/l Fish 96 hours
(chloromethyl)oxirane and phenol
Acute LC50 1.8 mg/l Algae 72 hours
Acute LC50 2.55 mg/l Daphnia 48 hours
1,6-hexanediol diglycidylether Acute EC50 23.1 mg/l Algae 48 hours
Acute LC50 47 mg/l Daphnia 48 hours
Acute LC50 30 mg/l Fish 96 hours
amide wax Acute EC50 43.2 mg/l Algae 72 hours
Acute EC50 94.9 mg/l Daphnia 48 hours
Acute LC50 >100 mg/l Fish 96 hours
Acute NOEC 37 mg/l Algae 72 hours

12.2 Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
formaldehyde, polymer with OECD 301B Ready 16 % - Not readily - 28 days - -
(chloromethyl)oxirane and phenol Biodegradability - CO₂ Evolution
Test
1,6-hexanediol diglycidylether OECD 301D Ready 47 % - Inherent - 28 days 2 mg/l -
Biodegradability - Closed Bottle Test
amide wax OECD 301D 301D Ready 63 % - Readily - 28 days - -
Biodegradability - Closed Bottle Test

Product/ingredient name Aquatic half-life Photolysis Biodegradability

formaldehyde, polymer with - - Not readily
(chloromethyl)oxirane and phenol
1,6-hexanediol diglycidylether - - Inherent
amide wax - - Readily

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
formaldehyde, polymer with (chloromethyl)oxirane and phenol 2.7 - low
1,6-hexanediol diglycidylether 0.822 3.57 low
amide wax 8.6 - high

12.4 Mobility in soil

Soil/water partition coefficient No known data avaliable in our database.
(KOC) :
Mobility : No known data avaliable in our database.

12.5 Results of PBT and vPvB assessment

PBT : Not applicable.
vPvB : Not applicable.

12.6 Other adverse effects

No known significant effects or critical hazards.

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SECTION 13: Disposal considerations

13.1 Waste treatment methods

The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose
of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction.
European waste catalogue no. (EWC) is given below.
European waste catalogue (EWC) : 08 01 11*
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.

SECTION 14: Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN no. Proper shipping name Transport hazard class(es) PG* Env* Additional information

ADR/RID UN3082 ENVIRONMENTALLY HAZARDOUS 9 III Yes. This product is not regulated
Class SUBSTANCE, LIQUID, N.O.S. as a dangerous good when
(formaldehyde, polymer with transported in sizes of ≤5 L
(chloromethyl)oxirane and phenol) or ≤5 kg, provided the
packagings meet the general
provisions of 4.1.1.1, 4.1.1.2
and 4.1.1.4 to 4.1.1.8.

Tunnel code
(E)

IMDG UN3082 ENVIRONMENTALLY HAZARDOUS 9 III Yes. This product is not regulated
Class SUBSTANCE, LIQUID, N.O.S. as a dangerous good when
(formaldehyde, polymer with transported in sizes of ≤5 L
(chloromethyl)oxirane and phenol). or ≤5 kg, provided the
(formaldehyde, polymer with packagings meet the general
(chloromethyl)oxirane and phenol) provisions of 4.1.1.1, 4.1.1.2
and 4.1.1.4 to 4.1.1.8.

Emergency schedules
(EmS)
F-A, S-F

IATA UN3082 ENVIRONMENTALLY HAZARDOUS 9 III Yes. This product is not regulated
Class SUBSTANCE, LIQUID, N.O.S. as a dangerous good when
(formaldehyde, polymer with transported in sizes of ≤5 L
(chloromethyl)oxirane and phenol) or ≤5 kg, provided the
packagings meet the general
provisions of 5.0.2.4.1, 5.0.2.
6.1.1 and 5.0.2.8.
PG* : Packing group
Env.* : Environmental hazards

14.6 Special precautions for user

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

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SECTION 15: Regulatory information

Not applicable.
Other EU regulations
Seveso category This product is controlled under the Seveso III Directive.
Seveso category
E2: Hazardous to the aquatic environment - Chronic 2
C9ii: Toxic for the environment

15.2 Chemical Safety Assessment

This product contains substances for which Chemical Safety Assessments are still required.

SECTION 16: Other information

Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
EUH statement = CLP-specific Hazard statement
RRN = REACH Registration Number
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
Full text of abbreviated H statements : H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Full text of classifications [CLP/GHS] : Aquatic Chronic 2, AQUATIC HAZARD (LONG-TERM) - Category 2
H411
Aquatic Chronic 3, AQUATIC HAZARD (LONG-TERM) - Category 3
H412
Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
AQUATIC HAZARD (LONG-TERM) - Category 2 Calculation method

Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

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