Revision date: 26/07/2019 Revision: 3 Supersedes date: 28/06/2016

SAFETY DATA SHEET

CONBEXTRA BB92

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name CONBEXTRA BB92

Product number 1148306UK9

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Cementitous Grouts

1.3. Details of the supplier of the safety data sheet

Supplier Fosroc Limited
Drayton Manor Business Park
Coleshill Road
Tamworth
Staffordshire
B78 3XN
England
Tel: +44 (0) 1827 262222
Fax: +44 (0) 1827 262444
enquiryuk@fosroc.com

1.4. Emergency telephone number

Emergency telephone +44 (0) 1827 265 279 (Monday-Sunday 24 hours a day)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1 - H317 STOT SE 3 - H335

Environmental hazards Not Classified

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H315 Causes skin irritation.

H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.

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Precautionary statements P264 Wash contaminated skin thoroughly after handling.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/ container in accordance with national regulations.

Contains ORDINARY PORTLAND CEMENT, CALCIUM SULFOALUMINATE CLINKER

Supplementary precautionary P261 Avoid breathing vapour/ spray.

statements P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P310 Immediately call a POISON CENTER/ doctor.
P312 Call a POISON CENTRE/doctor if you feel unwell.
P321 Specific treatment (see medical advice on this label).
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

SILICA SAND 30-60%

CAS number: 14808-60-7 EC number: 238-878-4

Classification Classification (67/548/EEC or 1999/45/EC)

Not Classified -

ORDINARY PORTLAND CEMENT 30-60%

CAS number: 65997-15-1 EC number: 266-043-4

Classification
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
Skin Sens. 1 - H317
STOT SE 3 - H335

CALCIUM SULFOALUMINATE CLINKER 1-5%

CAS number: 12005-25-3

Classification
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
Skin Sens. 1 - H317
STOT SE 3 - H335

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CALCIUM CARBONATE 1-5%

CAS number: 471-34-1 EC number: 207-439-9

Classification
Not Classified

SILICA FLOUR (100 - 325 micron) <1%

CAS number: 14808-60-7 EC number: 238-878-4

Classification
Eye Irrit. 2 - H319
STOT SE 3 - H335
STOT RE 2 - H373

2,6-DI-tert-BUTYL-4-METHYLPHENOL <1%
CAS number: 128-37-0
M factor (Chronic) = 1

Classification
Aquatic Chronic 1 - H410

ALUMINIUM POWDER (STABILIZED) <1%

CAS number: 7429-90-5 EC number: 231-072-3 REACH registration number: 01-
2119529243-45-XXXX

Classification
Flam. Sol. 1 - H228
Water-react. 2 - H261

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Remove affected person from source of contamination. Move affected person to fresh air at
once. Get medical attention.

Ingestion Rinse mouth thoroughly with water. Get medical attention if any discomfort continues.

Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash
skin thoroughly with soap and water. Get medical attention if irritation persists after washing.

Eye contact Remove affected person from source of contamination. Rinse with water. Remove contact
lenses, if present and easy to do. Continue rinsing. Continue to rinse for at least 15 minutes
and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation Frequent inhalation of dust over a long period of time increases the risk of developing lung
diseases.

Ingestion Ingestion of large doses may result in irritation to the gastrointestinal tract.

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Skin contact May have an irritating effect on moist skin after prolonged contact, or may cause dermatitis
after repeated contact.Prolonged skin contact with wet preparation may cause serious burns
without pain being felt, including through clothing.

Eye contact Eye contact may cause serious and potentially irreversible injuries.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards No unusual fire or explosion hazards noted.

Hazardous combustion No known hazardous decomposition products.

products

5.3. Advice for firefighters

Protective actions during No specific firefighting precautions known.
firefighting

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid inhalation of dust. Avoid contact with eyes and prolonged skin contact. Wear protective
clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Environmental precautions Avoid discharge into drains or watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Avoid generation and spreading of dust. Collect and place in suitable waste disposal
containers and seal securely. Label the containers containing waste and contaminated
materials and remove from the area as soon as possible. Flush contaminated area with plenty
of water.

6.4. Reference to other sections

Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. Collect and
dispose of spillage as indicated in Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Observe any occupational exposure limits for the product or ingredients. Avoid inhalation of
dust and contact with skin and eyes.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep only in
the original container.

7.3. Specific end use(s)

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Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
SILICA SAND
Long-term exposure limit (8-hour TWA): WEL 0,1 mg/m³
ORDINARY PORTLAND CEMENT
Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ inhalable dust
Long-term exposure limit (8-hour TWA): WEL 4 mg/m³ respirable dust
CALCIUM SULFOALUMINATE CLINKER
Long-term exposure limit (8-hour TWA): ACGIH/TLV:0.1 mg/m3 res
TLV - Threshold Limit Value 10 mg/m³
CALCIUM CARBONATE
Long-term exposure limit (8-hour TWA): 10 mg/m³ inhalable dust
Long-term exposure limit (8-hour TWA): 4 mg/m³ respirable dust
SILICA FLOUR (100 - 325 micron)
Long-term exposure limit (8-hour TWA): WEL 0,1 mg/m³
2,6-DI-tert-BUTYL-4-METHYLPHENOL
Long-term exposure limit (8-hour TWA): WEL 10 mg/m³
ALUMINIUM POWDER (STABILIZED)
Long-term exposure limit (8-hour TWA): WEL 4 mg/m³ respirable dust
Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ inhalable dust
WEL = Workplace Exposure Limit

Ingredient comments WEL = Workplace Exposure Limits

ORDINARY PORTLAND CEMENT (CAS: 65997-15-1)

DNEL Workers - Inhalation; Short term : 3 mg/m³

2,6-DI-tert-BUTYL-4-METHYLPHENOL (CAS: 128-37-0)

DNEL Workers - Inhalation; Long term systemic effects: 3.5 mg/m³

Workers - Dermal; Long term systemic effects: 0.5 mg/kg/day

PNEC - Fresh water; 0.199 µg/l

- marine water; 0.0199 µg/l

ALUMINIUM POWDER (STABILIZED) (CAS: 7429-90-5)

DNEL Workers - Oral; Long term systemic effects: 3 mg/m³

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate ventilation. Avoid inhalation of dust. Observe any occupational exposure
controls limits for the product or ingredients.

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Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Dust-resistant, chemical
splash goggles. (conform EN 166)

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. It is recommended that gloves are made
of the following material: Polyvinyl chloride (PVC). Butyl rubber. Nitrile rubber.

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Do not smoke in work area. Wash at the end of each work shift and before eating, smoking
and using the toilet. Wash promptly if skin becomes contaminated. Promptly remove any
clothing that becomes contaminated. When using do not eat, drink or smoke.

Respiratory protection Protection against nuisance dust must be used when the airborne concentration exceeds 10
mg/m3. Particulate filter, type P2.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Dusty powder.

Colour Grey.

Odour Odourless.

Odour threshold Not relevant.

pH pH (concentrated solution): >12

Melting point >1250°C

Initial boiling point and range Not applicable.

Flash point Not applicable.

Evaporation rate Not applicable.

Evaporation factor Not applicable.

Flammability (solid, gas) Not applicable.

Upper/lower flammability or The product is not flammable.

explosive limits

Vapour pressure Not applicable.

Vapour density Not applicable.

Relative density 1.6 @ 20°C

Solubility(ies) Slightly soluble in water. Hardens in contact with water.

Auto-ignition temperature Not determined.

Decomposition Temperature Not determined.

Viscosity Not applicable.

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.

of a flame

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Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.

Comments Information given is applicable to the product as supplied.

9.2. Other information

Other information Not available.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Reactions with the following materials may generate heat: Water.

10.2. Chemical stability

Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

Possibility of hazardous Not known. Will not polymerise.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid contact with water.

10.5. Incompatible materials

Materials to avoid Strong acids.

10.6. Hazardous decomposition products

Hazardous decomposition No known hazardous decomposition products.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Skin sensitisation
Skin sensitisation This product contains a chromate reducing agent to reduce the risk of allergic dermatitis
causes by chromium (VI). This product has a shelf life. If not stored in accordance with
packaging instructions (sealed and dry), there is an increased risk of the presence of
hexavalent chromate leading to an increased risk of an allergic reaction.

Inhalation Dust may irritate the respiratory system. Symptoms following overexposure may include the
following: Coughing.

Eye contact Dust in the eyes will cause irritation.

SECTION 12: Ecological information

Ecotoxicity Not regarded as dangerous for the environment. The product may affect the acidity (pH) of
water which may have hazardous effects on aquatic organisms.

12.1. Toxicity
Toxicity Not considered toxic to fish.

12.2. Persistence and degradability

Persistence and degradability The product is not expected to be biodegradable.

12.3. Bioaccumulative potential

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Bioaccumulative potential The product is not bioaccumulating.

12.4. Mobility in soil

Mobility The product hardens to a solid, immobile substance.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Waste should be treated as controlled waste. Dispose of waste to licensed waste disposal site
in accordance with the requirements of the local Waste Disposal Authority.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. Reuse or recycle products wherever possible. Note that fully
cured material is not considered as hazardous waste.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

14.1. UN number
Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Control of Substances Hazardous to Health Regulations 2002 (SI 2002 No. 2677) (as
amended).

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EU legislation Commission Regulation (EU) No 453/2010 of 20 May 2010.

Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information Only trained personnel should use this material.

Revision comments Revised formulation.

Revision date 26/07/2019

Revision 3

Supersedes date 28/06/2016

Hazard statements in full H228 Flammable solid.

H261 In contact with water releases flammable gases.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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