0% found this document useful (0 votes)
108 views5 pages

Sample Mass and Energy Balance

Download as docx, pdf, or txt
Download as docx, pdf, or txt
Download as docx, pdf, or txt
You are on page 1/ 5

Distillation Column

vertical shell - where the separation of liquid components is carried out.

trays/plates and/or packings- used to enhance component separations

reboiler -to provide the necessary vaporization for the distillation process

condenser- to cool and condense the vapor leaving the top of the column

reflux drum- to hold the condensed vapor from the top of the column so that liquid
(reflux) can be recycled back to the column
Sample Mass and Energy Balance

ṁ3

1.0 kgmol A

ṁ 1

0.03 kgmol B

0.97 kgmol C

kgmol ˙ kgmol
ṁ 2=5300 m4 =1200
hr hr

( 1−x 2 ) kg A 0.70 kgmol A

x 2 kgmol B ( 0.3−x 4 ) kgmol B


x 4 kg C

ṁ5

0.60 kg B

0.40 kgmol C

90% C exits in ṁ 5

Overall Balance:

kgmol ˙ kgmol
˙
m 1+ 5300 =m 3+ 1200 + ṁ 5 (1)
hr hr

B bal:

0.03 m 1+ x2 ( 5300 )=( 0.3−x 4 ) ( 1200 ) +0.60 ṁ 5 (2)

C bal:

˙ ) +0.40 ṁ (3)
0.97 m1=x 4 ( 1200 5

Since ṁ 3 is half the flowrate of ṁ 1

m3=0.5
˙ ṁ1

0.90 ¿
m 5=2.1825
˙ ṁ 1

From eq (1) Substitute ṁ 3 and ṁ 5

m1+ 5300=0.5 ṁ1˙+1200+2.1835


˙ ṁ1 (1)

kgmol
ṁ 1=2435.40
hr
˙ kgmol
m5=5315.27
hr
˙ k gmol
m3=1217.7
hr

From eq (3) Substitute ṁ 1 and ṁ 5

˙ ) +0.40 ṁ
0.97 m1=x 4 ( 1200 5

0.97 ( 2435.40 ) =x˙4 ( 1200 )+ 0.40(5315.27)

x 4 =0.1969

From eq (2) Substitute x 4 , ṁ 1 and ṁ 5

0.03 m 1+ x2 ( 5300 )=( 0.3−x 4 ) ( 1200 ) +0.60 ṁ 5

˙
0.03(2435.4 )+ x 2 ( 5300 )=( 0.3−0.1969 ) ( 1200 )+ 0.60 (5315.27¿) ¿

x 2=0.6113

Pressure: 1 atm

ΔH = QR + QC

hA = CpL,C5(TA − TF) = (39.7)(309 − 303)(1.8) = 428.8 Btu/lbmol

hB = CpL,C6(TB − TF) = (51.7)(342 − 303)(1.8) = 3,629.3 Btu/lbmol

QR = AhA + QC + BhB = (1,500)( 3,629.3) + 4.574×107 + (1,000)(428.8) = 5.1613×107 Btu/hr


kg
ṁ 3=1217.7
hr

1.0 kg A

kg
ṁ 1=2435.4
hr

0.03 kg B

0.97 kg C

kg ˙ kg
ṁ 2=5300 m4 =1200
hr hr

0.3887 kg A 0.70 kg A

0.6113 kg B 0.1031 kg B

0.1969 kg C

ṁ5

0.60 kg B

0.40 kg C

Reflux

Reflux is a process that involves simultaneous heating the chemical reaction for a
particular amount of time and continually cooling the vapor produced back into liquid
form, with the use of a condenser. The vaporthat was produced above the reaction will
continually undergo condensation, returning to the flask as a condensate. Through this
process, the temperature of the chemical reaction will remain constant.
Process Flow Diagram (Naphtha to Olefins)

You might also like